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Patent 2744840 Summary

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(12) Patent: (11) CA 2744840
(54) English Title: CO2 REFRIGERATION SYSTEM
(54) French Title: SYSTEME FRIGORIFIQUE PAR CO2
Status: Granted
Bibliographic Data
(51) International Patent Classification (IPC):
  • F25B 9/00 (2006.01)
(72) Inventors :
  • DUBE, SERGE (Canada)
(73) Owners :
  • 9245-5864 QUEBEC INC. (Canada)
(71) Applicants :
  • DUBE, SERGE (Canada)
(74) Agent: NORTON ROSE FULBRIGHT CANADA LLP/S.E.N.C.R.L., S.R.L.
(74) Associate agent:
(45) Issued: 2014-01-28
(22) Filed Date: 2009-10-23
(41) Open to Public Inspection: 2010-04-29
Examination requested: 2011-06-22
Availability of licence: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): No

(30) Application Priority Data:
Application No. Country/Territory Date
61/107,689 United States of America 2008-10-23
61/166,884 United States of America 2009-04-06
61/184,021 United States of America 2009-06-04

Abstracts

English Abstract

A CO2 refrigeration system comprises a refrigeration circuit in which circulates CO2 refrigerant between a compression stage in which the CO2 refrigerant is compressed. A condensation stage is provided in which the CO2 refrigerant releases heat and is accumulated in a condensation reservoir. An evaporation stage is provided in which the CO2 refrigerant is expanded to a gaseous state to absorb heat from a fluid for refrigeration, with at least a portion of CO2 refrigerant exiting the evaporation stage being directed to a supra-compression circuit comprising a supra-compression stage in which the portion of CO2 refrigerant is compressed. A heat exchanger is provided by which the compressed CO2 refrigerant is in a heat-exchange relation with a secondary-refrigerant circuit, such that the compressed CO2 refrigerant releases heat to a secondary refrigerant used for heating purposes. Pressure-regulating means control a pressure of the compressed CO2 refrigerant being returned to the condensation stage.


French Abstract

Un système frigorifique par CO2 comprenant un circuit de réfrigération où circule du réfrigérant au CO2 après un étage de compression dans lequel le réfrigérant au CO2 est comprimé. Un étage de condensation est utilisé, dans lequel le réfrigérant au CO2 dégage la chaleur et est accumulé dans un réservoir de condensation. Un étage d'évaporation est utilisé, dans lequel le réfrigérant au CO2 est dilaté en un état gazeux pour absorber de la chaleur d'un fluide pour la réfrigération, au moins une partie du réfrigérant au CO2 sortant de l'étage d'évaporation étant dirigé vers un circuit de surcompression comprenant un étage de surcompression dans lequel la partie de réfrigérant au CO2 est comprimée. Un échangeur de chaleur est utilisé, par lequel le réfrigérant au CO2 comprimé est dans une relation d'échange de chaleur avec un circuit de réfrigérant secondaire, de sorte que le réfrigérant au CO2 comprimé dégage de la chaleur vers un réfrigérant secondaire utilisé à des fins de chauffage. Des moyens de régulation de pression commandent la pression du réfrigérant au CO2 comprimé étant retourné vers l'étage de condensation.

Claims

Note: Claims are shown in the official language in which they were submitted.


CLAIMS:
1. A CO2 refrigeration system comprising: a
refrigeration circuit in which circulates CO2
refrigerant between at least a first CO2 compression
stage and CO2 supra-compression stage in which the CO2
refrigerant is compressed to at least a supra-compressed
condition, a gas cooling stage in which the supra-
compressed CO2 refrigerant releases heat, a condensation
reservoir in which a portion of the CO2 refrigerant is
accumulated in a liquid state, a pressure-regulating
unit in a line between the gas cooling stage and the
condensation reservoir to cause a pressure drop from the
supra-compressed condition of the CO2 refrigerant in the
gas cooling stage to the condensation reservoir, an
evaporation stage in which the CO2 refrigerant from the
condensation reservoir absorbs heat from a fluid for
refrigeration; and a defrost circuit comprising a
defrost line extending from at least one of the
compression stages to the evaporation stage for
directing compressed CO2 refrigerant to at least one
evaporator of the evaporation stage to absorb heat in
defrosting the at least one evaporator, and further
wherein a pressure-control unit in the defrost line to
reduce a pressure of the CO2 defrost refrigerant when
the defrost line directs CO2 defrost refrigerant from
the CO2 supra-compression stage to the at least one
evaporator for defrost.
2. The CO2 refrigeration system according to
claim 1, wherein the defrost circuit comprises at least
one defrost accumulator connected to the at least one
evaporator for receiving the CO2 defrost refrigerant
exiting the at least one evaporator prior to returning
the CO2 defrost refrigerant to the refrigeration
circuit.
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3. The CO2 refrigeration system according to
claim 2, further comprising a line between the defrost
accumulator and the condensation reservoir to return the
CO2 defrost refrigerant to the condensation reservoir.
4. The CO2 refrigeration system according to
claim 1, further comprising a line between the at least
one evaporator, and the first CO2 compression stage, for
returning the CO2 defrost refrigerant to the
refrigeration circuit.
5. The CO2 refrigeration system according to
claim 1, further comprising a suction accumulator
between the compression stages, with a portion of the
CO2 refrigerant exiting the first CO2 compression stage
being directed to the CO2 supra-compression stage via
the suction accumulator.
6. The CO2 refrigeration system according to
claim 5, further comprising a line between the at least
one evaporator, and the suction accumulator between the
compression stages, for returning the CO2 defrost
refrigerant to the refrigeration circuit.
7. The CO2 refrigeration system according to
claim 5, further comprising another suction accumulator
upstream of the first compression stage to separate
liquid and gaseous portions from the CO2 refrigerant
such that gaseous CO2 refrigerant is fed to the first
compression stage.
8. The CO2 refrigeration system according to
claim 7, wherein the other suction accumulator receives
an other portion of the CO2 refrigerant exiting the
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evaporation stage to then feed said other portion of the
CO2 refrigerant to the first compression stage.
9. The CO2 refrigeration system according to
claim 7, wherein the suction accumulator between
compression stages receives CO2 refrigerant exiting
medium-temperature evaporators of the evaporation stage,
and wherein the other suction accumulator receives CO2
refrigerant exiting low-temperature evaporators of the
evaporation stage.
10. The CO2 refrigeration system according to
claim 1, further comprising a suction accumulator
upstream of the first compression stage to accumulate
CO2 refrigerant being fed to the compression stage, the
suction accumulator connected to the evaporators so as
to receive at least a portion of the CO2 defrost
refrigerant exiting from the at least one evaporator.
11. The CO2 refrigeration system according to
claim 1, further comprising a line between the at least
one evaporator and the condensation reservoir to return
the CO2 defrost refrigerant to the condensation
reservoir.
12. The CO2 refrigeration system according to
claim 1, further comprising a pump between the
condensation reservoir and the evaporation stage to
direct CO2 refrigerant to the evaporation stage.
13. The CO2 refrigeration system according to
claim 1, further comprising a pressure-relief system for
the evaporators of the evaporation stage, the pressure
relief system exhausting CO2 refrigerant from any one of
the evaporators when a pressure of refrigerant in the
refrigeration coil reaching a given threshold.
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14. The CO2 refrigeration system according to
claim 7, further comprising a pressure-relief system for
the evaporators of the evaporation stage, the pressure-
relief system exhausting defrost CO2 refrigerant from
any one of the evaporators when a pressure of
refrigerant in the refrigeration coil reaching a given
threshold, the pressure-relief system directing excess-
pressure defrost CO2 refrigerant to any one of the
suction accumulators.
15. The CO2 refrigeration system according to
claim 7, further comprising a pressure-relief valve for
the one of the suction accumulators receiving the
excess-pressure defrost CO2 refrigerant.
16. The CO2 refrigeration system according to
claim 1, further comprising a line between the
evaporation stage and the compression stage to return
the CO2 defrost refrigerant to the compression stage.
17. The CO2 refrigeration system according to
claim 16, further comprising a heat exchanger in said
line to vaporize the CO2 defrost refrigerant returning
to the compression stage.
18. The CO2 refrigeration system according to any
one of claims 1 to 17, wherein the first CO2 compression
stage is a dedicated compressor in parallel to
compressors of the CO2 supra-compression stage.
19. The CO2 refrigeration system according to any
one of claims 1 to 18, wherein the at least one
compression stage comprises at least one compressor
compressing the CO2 refrigerant to a transcritical
condition.
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Description

Note: Descriptions are shown in the official language in which they were submitted.



CA 02744840 2011-06-22

CO2 REFRIGERATION SYSTEM
FIELD OF THE APPLICATION

The present application relates to refrigera-
tion systems, and more particularly to refrigeration
systems using CO2 refrigerant.

BACKGROUND OF THE ART

With the growing concern for global warming,
the use of chlorofluorocarbons (CFCs) and hydrochloro-
fluorocarbons (HCFCs) as refrigerant has been identified
as having a negative impact on the environment. These
chemicals have non-negligible ozone-depletion potential
and/or global-warming potential.
As alternatives to CFCs and HCFCs, ammonia,
hydrocarbons and CO2 are used as refrigerants. Although
is ammonia and hydrocarbons have negligible ozone-depletion
potential and global-warming potential as does CO2,
these refrigerants are highly flammable and therefore
represent a risk to local safety. On the other hand,
CO2 is environmentally benign and locally safe.

SUMMARY OF THE APPLICATION

It is therefore an aim of the present
disclosure to provide a CO2 refrigeration system that
addresses issues associated with the prior art.
Therefore, in accordance with a first
embodiment of the present application, there is provided
a CO2 refrigeration system comprising a refrigeration
circuit in which circulates CO2 refrigerant between a
compression stage in which the CO2 refrigerant is
compressed, a condensation stage in which the CO2
refrigerant releases heat and is accumulated in a
condensation reservoir, and an evaporation stage in
which the CO2 refrigerant is expanded to a gaseous state
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to absorb heat from a fluid for refrigeration, with at
least a portion of CO2 refrigerant exiting the
evaporation stage being directed to a supra-compression
circuit comprising a supra-compression stage in which
the portion of CO2 refrigerant is compressed, a heat
exchanger by which the compressed CO2 refrigerant is in
a heat-exchange relation with a secondary-refrigerant
circuit, such that the compressed CO2 refrigerant
releases heat to a secondary refrigerant used for
heating purposes, and pressure-regulating means to
control a pressure of the compressed CO2 refrigerant
being returned to the condensation stage.
Further in accordance with the first
embodiment, a defrost circuit has a line directing CO2
refrigerant from the compression stage, through a
refrigeration coil of an evaporator of the evaporation
stage to defrost the refrigeration coil, to then return
the CO2 refrigerant to the refrigeration circuit.
Still further in accordance with the first
embodiment, the CO2 refrigerant having defrosted the
refrigeration coil is subsequently directed to a defrost
reservoir, the defrost circuit further comprising a
flushing circuit to transfer accumulated liquid CO2
refrigerant from said defrost reservoir to said
condensation reservoir.
Still further in accordance with the first
embodiment, a suction accumulator is provided between a
discharge of the compression stage and a suction of the
supra compression stage, to separate liquid and gaseous
portions from the CO2 refrigerant such that gaseous CO2
refrigerant is fed to the supra compression stage.
Still further in accordance with the first
embodiment, the suction accumulator receives the portion
of the CO2 refrigerant exiting the evaporation stage to
then feed said portion of the CO2 refrigerant to the
supra-compression stage.

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Still further in accordance with the first
embodiment, an other suction accumulator is provided
upstream of the compression stage to separate liquid and
gaseous portions from the CO2 refrigerant such that
gaseous CO2 refrigerant is fed to the compression stage.
Still further in accordance with the first
embodiment, the other suction accumulator receives an
other portion of the CO2 refrigerant exiting the
evaporation stage to then feed said other portion of the
CO2 refrigerant to the compression stage.
Still further in accordance with the first
embodiment, a return line is provided between the
suction accumulators to direct liquid CO2 refrigerant to
the suction accumulator upstream of the compression
stage.
Still further in accordance with the first
embodiment, the other suction accumulator receives an
other portion of the CO2 refrigerant exiting the
evaporation stage to then feed said other portion of the
CO2 refrigerant to the compression stage.
Still further in accordance with the first
embodiment, the heat-exchanger line is in heat exchange
with a discharge line of the compression stage.
Still further in accordance with the first
embodiment, a gaseous line extends from the condensation
reservoir to the suction accumulator to direct gaseous
CO2 refrigerant from the condensation reservoir to the
suction accumulator.
Still further in accordance with the first
embodiment, heat-exchanger means is provided in the
gaseous line for the gaseous CO2 refrigerant to cool
liquid CO2 refrigerant fed to the expansion stage.
Still further in accordance with the first
embodiment, an independent refrigerant circuit is in
heat-exchange relation with a discharge of the
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compression stage to cool the CO2 refrigerant
subsequently reaching the condensation reservoir.
Still further in accordance with the first
embodiment, a pressure-relief system is provided for the
evaporators of the evaporation stage, the pressure
relief system exhausting defrost CO2 refrigerant from
any one of the refrigeration coils when a pressure of
refrigerant in the refrigeration coil reaching a given
threshold.
Still further in accordance with the first
embodiment, the pressure-relief system exhausts defrost
CO2 refrigerant from any one of the refrigeration coils
when a pressure of refrigerant in the refrigeration coil
reaching a given threshold, the pressure-relief system
directing excess-pressure defrost CO2 refrigerant to any
one of the suction accumulators.
Still further in accordance with the first
embodiment, a pressure-relief valve is provided for the
one of the suction accumulators receiving the excess-
pressure defrost CO2 refrigerant.
Still further in accordance with the first
embodiment, electric coils are provided for each
evaporator of the evaporation stage to defrost the
evaporators.
Still further in accordance with the first
embodiment, the supra-compression stage compresses the
CO2 refrigerant to a transcritical state.
In accordance with a second embodiment of the
present application, there is provided a method for
relieving CO2 refrigerant pressure from evaporators
during a defrost cycle, comprising: providing a
pressure-relief valve for each evaporator line, the
pressure relief-valve opening at a pressure threshold;
feeding CO2 refrigerant to at least one evaporator in
the evaporator line to defrost the evaporator;
exhausting the evaporator from the CO2 refrigerant with
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the pressure-relief valve when the CO2 refrigerant
pressure is above the pressure threshold; and directing
the exhausted CO2 refrigerant to an accumulator in a
refrigeration cycle.
In accordance with a third embodiment of the
present application, there is provided a method for
feeding vaporized CO2 refrigerant and oil to a
compressor, comprising: collecting a mixture of liquid
CO2 refrigerant and oil from an accumulator; vaporizing
the mixture of CO2 refrigerant and oil by heating the
mixture; and feeding the feeding vaporized CO2
refrigerant and oil to a compressor.
Further in accordance with the third
embodiment, vaporizing the mixture of CO2 refrigerant
and oil comprises heating the mixture by heat-exchange
exposure to a discharge of the compressor.
Still further in accordance with the third
embodiment, collecting a mixture of liquid CO2
refrigerant and oil from an accumulator comprises
collecting the mixture from the same accumulator feeding
a compression stage with gaseous CO2 refrigerant.

BRIEF DESCRIPTION OF DRAWINGS

Fig. 1 is a block diagram of a CO2 ref rigera-
tion system in accordance with an embodiment of the
present application;
Fig. 2 is a block diagram of the CO2
refrigeration system of Fig. 1, with an example of
operating pressures for a cold climate application;
Fig. 3 is a block diagram of the CO2
refrigeration system of Fig. 1, with an example of
operating pressures for a warm climate application; and
Fig. 4 is a schematic view of a line used with
the CO2 refrigeration system, in accordance with another
embodiment of the present application.

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Fig. 5 is a block diagram of a CO2 refrigera-
tion system in accordance with another embodiment,
Fig. 6 is a schematic view of a line configu-
ration for a refrigeration unit, in accordance with yet
another embodiment of the present application;
Fig. 7 is a block diagram of a CO2 refrigera-
tion system in accordance with another embodiment, with
dedicated compression for defrost;
Fig. 8 is a block diagram of a CO2 refrigera-
tion system in accordance with another embodiment, e.g.,
for a skating rink application;
Fig. 9 is a block diagram of a CO2 refrigera-
tion system in accordance with another embodiment, with
a supra-compression providing defrost;
Fig. 10 is a block diagram of a CO2 refrigera-
tion system in accordance with another embodiment, with
cascaded compression;
Fig. 11 is a block diagram of a CO2 refrigera-
tion system in accordance with another embodiment, with
suction accumulation upstream of a supra-compression
stage;
Fig. 12 is a block diagram of a CO2 refrigera-
tion system in accordance with another embodiment, with
a heat-exchanger for defrost refrigerant; and
Fig. 13 is a schematic view of a desiccant
system in accordance with another embodiment of the
present application.

DESCRIPTION OF PREFERRED EMBODIMENTS

Referring to Fig. 1, a CO2 refrigeration
system in accordance with an embodiment is illustrated
at 1. The CO2 refrigeration system 1 has a CO2
refrigeration circuit comprising a CO2 compression stage
10. CO2 refrigerant is compressed in the compression
stage 10, and is subsequently directed via line 11 to a
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condensation reservoir 12, or to a heat-reclaim
stage 13.
The condensation reservoir 12 accumulates CO2
refrigerant in a liquid and gaseous state, and is in a
heat-exchange relation with a condensation circuit that
absorbs heat from the CO2 refrigerant. The condensation
circuit is described in further detail hereinafter.
Moreover, a transcritical circuit and a defrost circuit
may supply CO2 refrigerant to the condensation reservoir
12, as is described in further detail hereinafter.
The heat-reclaim stage 13 is provided to
absorb heat from the CO2 refrigerant exiting from the
compression stage 10. The heat-reclaim stage 13 may
take various forms, such as that of a heat exchanger by
which the CO2 refrigerant is in heat exchange with an
alcohol-based refrigerant circulating in a closed loop.
As another example, the heat-reclaim stage 13 features
coils by which the CO2 refrigerant releases heat to a
water tank.
Line 14 directs CO2 refrigerant from the
condensation reservoir 12 to an evaporation stage via
expansion valves 15. As is shown in Fig. 1, the CO2
refrigerant is supplied in a liquid state by the
condensation reservoir 12 into line 14. The expansion
valves 15 control the pressure of the CO2 refrigerant,
which is then fed to either low-temperature evaporation
stage 16 or medium-temperature evaporation stage 17.
Both the evaporation stages 16 and 17 feature
evaporators associated with refrigerated enclosures,
such as closed or opened refrigerators, freezers or the
like. It is pointed out that the expansion valves 15
may be part of a refrigeration pack in the mechanical
room, as opposed to being at the refrigeration cabinets.
As a result, flexible lines (e.g., plastic non-rigid
lines) could extend from the expansion valves 15 to
diffuser upstream of the coils of the evaporation stages
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16 and 17. The valves 15 may be at the refrigeration
cabinets, at the refrigeration pack in a mechanical
room, or any other suitable location.
CO2 refrigerant exiting the low-temperature
evaporation stage 16 is directed to the CO2 compression
stage 10 via line 18 to complete a refrigeration cycle.
A heat exchanger 19 is provided in the line 18, and
ensures that the CO2 refrigerant is fed to the
compression stage 10 in a gaseous state. Other
components, such as a liquid accumulator, may be used as
an alternative to the heat exchanger 19. As described
hereinafter, the heat exchanger 19 may be associated
with a condensation circuit.
CO2 refrigerant exiting the medium-temperature
is evaporation stage 17 is directed to the transcritical
circuit as is described hereinafter.
A condensation circuit has a heat exchanger
20. The heat exchanger 20 is in fluid communication
with the condensation reservoir 12, so as to receive CO2
refrigerant in a gaseous state. The condensation
circuit is closed and comprises a condensation
refrigerant that also circulates in the heat exchanger
20 so as to absorb heat from the CO2 refrigerant.
In the condensation circuit, the condensation
refrigerant circulates between the heat exchanger 20 in
which the condensation refrigerant absorbs heat, a
compression stage 21 in which the condensation
refrigerant is compressed, and a condensation stage 22
in which the condensation refrigerant releases heat.
The compression stage 21 may use TurbocorTM compressors.
In an example, the condensation stage 22 features heat
reclaiming (e.g., using a heat exchanger with a heat-
transfer fluid) in parallel or in series with other
components of the condensation stage 22, so as to
reclaim heat from the CO2 refrigerant. Although not
shown, the condensation circuit may be used in
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conjunction with the heat exchanger 19, so as to absorb
heat from the CO2 refrigerant being directed to the
compression stage 10. In this case, the condensation
refrigerant is in a heat-exchange relation with the CO2
refrigerant.
It is pointed out that the condensation
circuit may be used with more than one CO2 refrigeration
circuit. In such a case, the condensation circuit
features a plurality of heat exchangers 20, for instance
with one for each of the CO2 refrigeration circuits.
Examples of the condensation refrigerant are
refrigerants such as R-404 and R-507, amongst numerous
examples. It is observed that the condensation circuit
may be confined to its own casing as illustrated in
is Fig. 1. Moreover, considering that the condensation
circuit is preferably limited to absorbing heat from
stages on a refrigeration pack (e.g., condensation
reservoir 12, suction header in line 18), the
condensation circuit does not contain a large volume of
refrigerant when compared to the CO2 refrigeration
circuit, of a secondary refrigerant circuit defined
hereinafter.
The transcritical circuit (i.e., supra-
compression circuit) is provided to compress the CO2
refrigerant exiting from the medium-temperature
evaporation stage 17 to a transcritical state, for
heating purposes, or supra-compressed state. In both
compression states, the CO2 refrigerant is pressurized
in view of maintaining the condensation reservoir 12 at
a high enough pressure to allow vaporized CO2
refrigerant to be circulated in the evaporation stages
16 and 17, as opposed to liquid CO2 refrigerant.
A line 30 relates the medium-temperature
evaporation stage 17 to a heat exchanger 31 and
subsequently to a supra-compression stage 32. The heat
exchanger 31 is provided to vaporize the CO2 refrigerant
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fed to the transcritical compression stage 32. The
supra-compression stage 32 features one or more
compressors (e.g., BockTM, DorinTM), that compress the CO2
refrigerant to a supra-compressed or transcritical
state.
In the transcritical state, the CO2
refrigerant is used to heat a secondary refrigerant via
heat-reclaim exchanger 34. In the heat-reclaim
exchanger 34, the CO2 refrigerant is in a heat-exchange
io relation with the secondary refrigerant circulating in
the secondary refrigerant circuit 35. The secondary
refrigerant is preferably an environmentally-sound
refrigerant, such as water or glycol, that is used as a
heat-transfer fluid. Because of the transcritical state
of the CO2 refrigerant, the secondary refrigerant
circulating in the circuit 35 reaches a high
temperature. Accordingly, due to the high temperature
of the secondary refrigerant, lines of smaller diameter
may be used for the secondary refrigerant circuit 35.
It is pointed out that the secondary refrigerant circuit
35 is the largest of the circuits of the refrigeration
system 1 in terms of quantity of refrigerant.
Therefore, the compression of the CO2 refrigerant into a
transcritical state by the transcritical circuit allows
the lines of the secondary refrigerant circuit 35 to be
reduced in terms of diameter.
A gas cooling stage 36 is provided in the
transcritical circuit. The gas cooling stage 36 absorbs
excess heat from the CO2 refrigerant in the
transcritical state, in view of re-injecting the CO2
refrigerant in the condensation reservoir 12. Although
it is illustrated in a parallel relation with the heat-
reclaim exchanger 34, the gas cooling stage 36 may be in
series therewith, or in any other suitable arrangement.
Although not shown, appropriate valves are provided so
as to control the amount of CO2 refrigerant directed to
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the gas cooling stage 36, in view of the heat demand
from the heat-reclaim exchanger 34.
In warmer climates in which the demand for
heat is smaller, the CO2 refrigerant is compressed to a
supra-compressed state, namely at a high enough pressure
to allow the expansion of the CO2 refrigerant at the
exit of the condensation reservoir 12, so as to reduce
the amount of CO2 refrigerant circulating in the
refrigeration circuit. A by-pass line is provided to
illustrate that the heat-reclaim exchanger 24 and the
gas cooling stage 36 are optional for warmer climates.
The gas cooling stage 36 may feature a fan
blowing a gas refrigerant on coils. The speed of the
fan may be controlled as a function of the heat demand
of the heat reclaim exchanger 34. For an increased
speed of the fan, there results an increase in the
temperature differential at opposite ends of the gas
cooling stage 36.
Lines 37 and 38 return the CO2 refrigerant to
the condensation reservoir 12, and thus to the
refrigeration circuit. The line 37 feeds the heat
exchanger 31 such that the CO2 refrigerant exiting the
stages 34 and 36 release heat to the CO2 refrigerant fed
to the supra-compression stage 32. Accordingly, the CO2
refrigerant fed to the supra-compression stage 32 is in
a gaseous state.
In the case of transcritical compression, a
CO2 transcritical pressure-regulating valve 39 is
provided to maintain appropriate pressures at the stages
34 and 36, and in the condensation reservoir 12. The
CO2 transcritical pressure-regulating valve 39 is for
instance a Danfosstm valve. Any other suitable pressure-
control device may be used as an alternative to the
valve 39, such as any type of valve or loop.
The condensation circuit and the supra-
compression circuit allow the condensation reservoir 12
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to store refrigerant at a relatively medium pressure.
Accordingly, no pump may be required to induce the flow
of refrigerant from the condensation reservoir 12 to the
evaporation stages 16 and 17. As CO2 refrigerant is
s vaporized downstream of the expansion valves 15, the
amount of CO2 refrigerant in the refrigeration circuit
is reduced, especially if the expansion valves 15 are in
the refrigeration pack.
It is considered to operate the supra-
compression circuit (i.e., supra compression 32) with
higher operating pressure. CO2 refrigerant has a
suitable efficiency at a higher pressure. More
specifically, more heat can be extracted when the
pressure is higher.
The refrigeration system 1 may be provided
with a refrigerant defrost system. In Fig. 1, a portion
of the CO2 refrigerant exiting from the compression
stage 10 is directed to the evaporation stages 16 and
17. Although not shown, appropriate valves and
pressure-reducing devices are provided to stop the flow
of cooling CO2 refrigerant in the evaporators in view of
the defrost. The defrost CO2 refrigerant releases heat
to defrost any frost build-up on the evaporators of the
evaporation stages 16 and/or 17.
Although not shown, other compression
configurations may be used to supply defrost refrigerant
to the evaporators, such as dedicated compressors,
cascaded compressors of the like.
Line 41 directs the defrost CO2 refrigerant
having released heat to the defrost reservoir 42. The
defrost reservoir 42 accumulates the defrost CO2
refrigerant, and features a line 43 with a control valve
(e.g., exhaust valve, check valve), so as to allow
gaseous CO2 refrigerant to be sucked back into the CO2
refrigeration circuit by the CO2 compression stage 10.
The defrost reservoir 42 is an option, as the
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evaporation stages 16 and 17 may direct the refrigerant
to other reservoirs or accumulators of any other
refrigeration system presenter herein.
A flush of the defrost reservoir 42 may be
performed periodically, so as to empty the defrost
reservoir 42. Accordingly, lines 44 and 45, with
appropriate valves, allow the flush of the liquid CO2
refrigerant from the defrost reservoir 42 to the
condensation reservoir 12.
A pressure-reducing valve 46 may be provided
in the line 40 or line 11 to regulate a pressure of the
defrost CO2 refrigerant fed to the evaporation stage 16
and/or 17 for defrost. Valves, such as check valve 47,
are as relief valves for the evaporation stages 16 and
17. For instance, in case of a power shortage, the CO2
refrigerant in the evaporators may increase in pressure.
Accordingly, the check valves 47 open at a threshold
pressure to allow the CO2 refrigerant to reach the
defrost reservoir 42.
Considering that the compressors of the CO2
compression stage 10 or of the compression stage 21 are
low-consumption compressors, these compressors may be
operated during a power outage to maintain suitable
refrigerating conditions in the evaporation stages 16
and 17. The compressors of the compression stage 21 may
also be TurbocorTM compressors.
As an alternative to the defrost circuit, the
evaporators of the evaporation stages 16 and 17 may be
equipped with electric coils for the electric defrost of
the evaporators.
In an embodiment, the casing enclosing the
condensation circuit may also comprise an air-
conditioning unit 50. Accordingly, the roof-top
equipment associated with the refrigeration system 1 is
provided in a single casing, thereby facilitating the
installation thereof. Moreover, it is considered to
- 13 -


CA 02744840 2011-06-22

unite as many components of the refrigeration system 1
in a single refrigeration pack. For instance, the
compressors of the CO2 compression stage 10, the
condensation reservoir 12, the expansion valves 15, and
optionally the compressors from the supra-compression
stage 32, as well as the defrost reservoir 42 may all be
provided in a same pack, with most of the lines joining
these components. The installation is therefore
simplified by such a configuration.
In order to illustrate the operating pressures
of the CO2 refrigeration system 1 in cold and warm
climates, Figs. 2 and 3 are respectively provided with
pressure values. It is pointed out that all values are
just an illustration, whereby pressure values could be
higher or lower. Fig. 2 shows operating pressures for
the CO2 refrigeration system 1 as used in cold climates
(e.g., winter conditions in colder regions), with a
demand for heat by the secondary refrigerant circuit 35.
Fig. 3 shows operating pressures for the CO2
refrigeration system as used in warm climates (e.g.,
summer conditions, warmer regions).
Although not fully illustrated, numerous
valves are provided to control the operation of the CO2
refrigeration system 1 as described above. Moreover, a
controller ensures that the various stages of the
refrigeration system 1 operate as described, for
instance by having a plurality of sensors places
throughout the refrigeration system 1.
Referring to Fig. 3, there is illustrated a
safety valve circuit 55 so as to ensure that the
refrigerant pressure in the coils of the evaporation
stages 16 and 17 does not exceed a given maximum value
(e.g., 410 Psi), which may result in damages to the
coils. The safety valve circuits 55 extends from the
evaporation stages 16 and 17 (e.g., lines at the exit of
the coils) to the defrost reservoir 42. A safety valve
- 14 -


CA 02744840 2011-06-22

56 is provided in the circuit, and operates by
monitoring the pressure in the coils and opening as a
result of the pressure reaching the maximum value. The
defrost reservoir 42 then absorbs the excess pressure by
receiving the refrigerant. The defrost reservoir 42
subsequently discharges the refrigerant using the lines
described previously.
Referring to Fig. 4, a line that may be used
in the CO2 refrigeration system 1 is illustrated at 60.
io The line 60 is a flexible hose adapted to support the
relatively high pressures associated with CO2
refrigerant. One suitable example of flexible hose is
the "Transfer Oil" hydraulic hose by GomaxT"'. The hose
60 is rodded into a conduit of sleeves 61 of an
is insulating material, such as urethane, positioned end to
end to cover the length of hose 60. A plurality of
hoses 60 may be used with a single sleeve 61, provided
the inner diameter of the sleeve 61 is large enough to
receive the hoses 60. Therefore, by the use of flexible
20 hoses, the installation of the lines is simplified.
Previous lines required welding operation to join tubes
of metallic material.
Referring to Fig. 5, an alternative embodiment
of the CO2 refrigeration system 1 of Figs. 1-3 is
25 illustrated at 70. The CO2 refrigeration systems 1 and
70 have numerous common stages and lines, whereby like
elements will bear like reference numerals. One
difference between the CO2 refrigeration systems 1 and
70 is the absence of a condensation circuit such as the
30 one having the heat exchanger 20 in Figs. 1-3. Rather,
the CO2 refrigerant in the condensation reservoir 12 is
cooled by the transcritical circuit (i.e., supra-
compression circuit) featuring the heat exchanger 31.
Therefore, a line 71 extends from the
35 condensation reservoir 12 and directs CO2 refrigerant to
the hot side of the heat exchanger 31, which heat
- 15 -


CA 02744840 2011-06-22

exchanger 31 is optional and is used to vaporize the CO2
refrigerant if necessary. The line 71 may be collecting
gas CO2 refrigerant at a top of the condensation
reservoir 12 to direct the CO2 refrigerant to the heat
exchanger 31. A pressure-reducing valve 72 is provided
in line 71 to ensure that the CO2 refrigerant reaches
the heat exchanger 31 at a suitable pressure. The CO2
refrigerant goes through the supra-compression circuit
in the manner described previously, so as to lose heat,
and return to the condensation reservoir 12 primarily in
a liquid state.
It is pointed out that the configuration of
the CO2 refrigeration system 70 of Fig. 5 is such that a
single refrigerant, namely CO2 refrigerant, is used
therein.
Referring to Fig. 6, an alternative line
configuration is shown at 80, which line configuration
is typically used to supply refrigerant to large
refrigeration units (e.g., in freezer rooms). Line 81,
typically a large diameter line, diverges into a
plurality of smaller lines, from an expansion valve 82.
Each smaller line may have a valve 83, and each feeds an
own smaller refrigeration unit 84. As a result, some of
the units 84 may be turned off, so as to meet more
precisely the cool demand of an enclosure.
Referring to Fig. 7, yet another embodiment of
a CO2 refrigeration system is illustrated at 90. The CO2
refrigeration systems 1 and 90 have numerous common
stages and lines, whereby like elements will bear like
reference numerals. One difference between the CO2
refrigeration systems 1 and 90 is the presence of at
least one dedicated compressor 10' to compress defrost
refrigerant. The discharge of the dedicated compressor
10' goes at least partially to the defrost circuit,
whereas the discharge of the other compressors 10 is
directed to the refrigeration circuit. A line and valve
16 -


CA 02744840 2011-06-22

(not shown) may be used to direct some excess
refrigerant from the dedicated compressor 10' to the
refrigeration circuit. The CO2 dedicated compressor 10'
may also be used to flush the defrost reservoir 42.
As an alternative, defrost could be made by
directing refrigerant from the supra-compression
circuit, into the defrost circuit, using an appropriate
pressure-reducing valve.
Referring to Fig. 8, yet another embodiment of
a CO2 refrigeration system is illustrated at 100. The
CO2 refrigeration systems 70 (Fig. 5) and 90 have
numerous common stages and lines, whereby like elements
will bear like reference numerals. The CO2
refrigeration system 100 is well suited for applications
requiring low-temperature cooling, such as ice-skating
rinks and industrial freezer applications.
The CO2 refrigeration system 100 may be
configured to operate without the CO2 compression
stages, due to the heat removal capacity of the supra-
compression circuit. In such a configuration, a pump
may circulate the refrigerant in the refrigeration
circuit, from the condensation reservoir 12 to the low-
temperature evaporation 16. In the ice-skating rink
applications, the various heat absorbing components
(e.g., the heat reclaim stage 13, the heat reclaim
exchanger 34) may be used to melt zamboni residue in an
ice dump.. It is preferred not to use the supra-
compression circuit when the CO2 refrigeration system
100 is operated in warmer countries. The CO2
refrigeration system 100 is more efficient with CO2
compression in such climates.
Considering the nature of the refrigerant,
plastic tubing or non-rigid lines may be used as an
alternative to the rigid metallic lines previously used,
between the mechanical room and the stages of the
systems, such as the condensation stage 12 and the

- 17 -


CA 02744840 2011-06-22

evaporation stages 16 and 17. One known type of pipes
that can be used is Halcor Cusmart pipes, and features a
non-rigid copper core with a plastic insulation sleeve
about the core. Such configurations are cost-efficient
in that no weld joints are required to interconnect
pipes, as is the case for rigid metallic lines.
Gutters, for instance having a trapezoid cross-section,
may be used as a guide for lines.
Referring to Fig. 9, yet another embodiment of
a CO2 refrigeration system is illustrated at 110. The
CO2 refrigeration systems 1 and 110 have numerous common
stages and lines, whereby like elements will bear like
reference numerals. One difference between the CO2
refrigeration systems 1 and 110 is line 111 directing
CO2 refrigerant from the supra-compression stage 32 to
the evaporator stages 16 and 17 for defrost.
Accordingly, the CO2 refrigerant fed to the evaporation
stage 16/17 is at a relatively high pressure - valve 114
may be provided to lower the pressure of the CO2
refrigerant to an appropriate level (e.g., 500 Psi).
The defrost refrigerant is then directed to the defrost
reservoir 42. A valve 112 is provided to control the
amount of defrost refrigerant from the reservoir 42
reintegrating the refrigeration cycle. Moreover, in
order to maintain a suitable compression ratio in view
of the operating pressure of the condensation reservoir
12, a pressure-reducing valve 113 is provided in the
line 11, so as to reduce the pressure of the CO2
refrigerant feeding the condensation reservoir 12.
Moreover, the refrigeration system 110 has a
line 115 (with appropriate valves) selectively directing
refrigerant from the supra-compression stage 32 to the
defrost reservoir 42, to flush the reservoir 42 when
required. It is pointed out that the heat exchangers 19
and 31 are optional, as is the condensation circuit
featuring the compression stage 21.

- 18 -


CA 02744840 2011-06-22

Referring to Fig. 10, yet another embodiment
of a CO2 refrigeration system is illustrated at 120.
The CO2 refrigeration systems 70 and 120 have numerous
common stages and lines, whereby like elements will bear
like reference numerals. The CO2 refrigeration system
120 has a cascaded arrangement for the two stages of CO2
compression, namely compression stage 10 and supra-
compression stage 32. More specifically, the
refrigerant discharge from the compression stage 10 is
fed to a suction accumulator 121, and CO2 refrigerant in
a gas state is sucked from a top of the accumulator 121
by the supra-compression stage 32.
The suction accumulator 121 also receives CO2
refrigerant from the evaporation stage 17, optionally
via heat exchanger 31. Gas CO2 refrigerant from the
condensation reservoir 12 may also be directed to the
suction accumulator 121. The liquid CO2 refrigerant
from the suction accumulator 121 may be directed to the
compression stage 10.
In order to maintain suitable conditions for
the refrigerant at the inlet of the compression stage, a
first suction accumulator 122 is provided downstream of
the compression stage 10, which suction accumulator 122
receives CO2 refrigerant from the suction accumulator
121 through a line (e.g., capillary) having a heat
exchanger 123 for heat exchange with a discharge of the
supracompression stage 32, or with a discharge of the
compression stage 10. Moreover, liquid refrigerant from
the suction accumulator 122 may be heated by line 124,
in heat exchange with the discharge of the compression
stage 10 or with supracompression stage 32, or simply by
using an electric heater. The line 124 may then direct
the vaporized refrigerant to the suction of the
compression stage 10. In an embodiment, the line 124
collects liquid CO2 refrigerant and oil at a bottom of
the suction accumulator 122. Accordingly, the vaporized
- 19 -


CA 02744840 2011-06-22

refrigerant has an oil content when fed to the
compressors of the compression stage 10. The oil is
then recuperated for instance in the suction accumulator
121. A similar loop may be performed to feed a mixture
of CO2 refrigerant and oil to the supra-compression
stage 32.
In the embodiment in which the line 124
directs vaporized refrigerant to the suction of the
compression stage 10, a valve 125 is provided in that
case to maintain a pressure differential between the
suction accumulator 122 and the suction of the
compression stage 10, to allow the flow of refrigerant
from line 124 into CO2 compression stage 10. It is
considered to use other components than suction
is accumulator 121, suction accumulator 122, line 124 and
heat exchanger 123 to vaporize the refrigerant, such as
a heating element, an air conditioning system, a heat
exchanger and the like. It is also considered that CO2
refrigerant leaving suction accumulator 121 and suction
accumulator 122 be directed elsewhere in the CO2
refrigeration system.
The cascaded compressor configuration of
Fig. 10 is well suited to preserve the oil in the
compression stage 10. More specifically, oil
accumulating in the suction accumulator 121 is returned
to the suction accumulator 122 via the line of heat-
exchanger 123. The oil may then be sucked with
refrigerant by the compression stage 10. Accordingly,
the oil cycles between stages 10, 121 and 122. A
similar cycle may be used for feeding an oil and
refrigerant mixture to the supra-compression stage 32.
The defrost of the evaporation stages 16 and
17 may be performed at low pressure so as to avoid
damaging the evaporator coils. Accordingly, the
refrigeration cycle 120 may be retrofitted to existing
evaporator coils, considering the relatively low defrost
- 20 -


CA 02744840 2011-06-22

pressures. The defrost CO2 refrigerant may be fed by
the compression stage 10, or by the supra compression
stage 32, with valve 46 controlling the pressure.
In order to protect the evaporator coils from
high defrost pressures, a set of lines 126 extends from
the evaporator coils to any reservoir or accumulator of
the refrigeration system 120. For instance, the lines
126 are connected to one of the accumulators 121 and 122
while being separated by a valve 127. The valve 127
opens if the pressure in the evaporator coils is above a
given threshold. Accordingly, if the defrost pressure
in the evaporator coils is too high, the defrost CO2
refrigerant is discharged to one of the accumulators 121
and 122, whereby the CO2 refrigerant stays in the
refrigeration system 120. As another safety measure, a
pressure-relief valve system 128 is provided on the
appropriate accumulators, such as 122 as shown but
alternatively on the accumulator 121 or on the
condensation reservoir 12.
For instance, the method for relieving CO2
refrigerant pressure from evaporators during a defrost
cycle comprises providing a pressure-relief valve for
each evaporator line, the pressure relief-valve opening
at a pressure threshold. CO2 refrigerant is then fed to
evaporators in the evaporator line to defrost the
evaporator. The evaporators are exhausted from the CO2
refrigerant with the pressure-relief valve when the CO2
refrigerant pressure is above the pressure threshold;
and directing the exhausted CO2 refrigerant to an
accumulator in a refrigeration cycle.
In specific conditions, it may be required to
cool the CO2 refrigerant fed to the evaporation stages
16 and/or 17 during the refrigeration cycle.
Accordingly, a heat-exchanger system 129, for instance
with an expansion valve, may direct refrigerant from the
line 71 and feed same to the heat-exchanger system 129,
- 21 -


CA 02744840 2011-06-22

to cool the CO2 refrigerant fed to the evaporation
stages 16 and/or 17.
The valve 39 is controlled (e.g., modulated)
to maximize the heat reclaim via the heat reclaim
exchanger 34. When the heat demand is high (e.g.,
during Winter in colder climates), the valve 39 may
maintain a high refrigerant pressure downstream of the
compression stage 32, to ensure the heat reclaim
exchanger 34 extracts as much heat as possible from the
CO2 refrigerant. The amount of refrigerant sent to the
gas cooling stage 36 is controlled simultaneously.
Referring to Fig. 11, yet another embodiment
of a CO2 refrigeration system is illustrated at 130.
The CO2 refrigeration systems 1 and 130 have numerous
common stages and lines, whereby like elements will bear
like reference numerals. The CO2 refrigeration system
130 is particularly well suited for hot climate
applications. In the CO2 refrigeration system 130, the
discharge of the compression stage 10 is directed to the
heat exchanger 20 prior to reaching the condensation
reservoir 12, for relatively low pressure condensation.
Alternatively, the refrigerant exiting the heat
exchanger 20 may be directed to the suction accumulator
133, thereby bypassing the condensation reservoir 12. A
gaseous portion of the CO2 refrigerant in the
condensation reservoir 12 is directed via line 131 and
pressure-reducing valve 132 into the heat exchanger 31
to reach the suction accumulator 133. The CO2
refrigerant passing through the heat exchanger 31
absorbs heat from the CO2 refrigerant exiting the supra-
compression circuit via line 134. A line 135 relates a
top of the suction accumulator 133 to the supra-
compression stage 32, to feed gaseous CO2 refrigerant to
the compressors. Liquid CO2 refrigerant may be directed
to another suction accumulator 136, at the suction of
the compression stage 10, in similar fashion to the CO2
- 22 -


CA 02744840 2011-06-22

refrigeration system 120 of Fig. 10 (with appropriate
heat exchange with the discharge of stage 10 if
necessary). The supra-compression circuit is typically
used to reclaim heat, while the evaporation stages 16
and 17 are part of a HVAC unit, amongst other
possibilities.
Referring to Fig. 12, yet another embodiment
of a CO2 refrigeration system is illustrated at 140.
The CO2 refrigeration systems 1 and 140 have numerous
common stages and lines, whereby like elements will bear
like reference numerals. The CO2 refrigeration system
140 has a heat exchanger 141 collecting defrost CO2
refrigerant at the outlet of the evaporators 16/17, to
vaporize the defrost CO2 refrigerant and return same
into the refrigeration cycle, namely to feed the suction
of the compression stage 10 via line 142 or the supra-
compression stage 32 via line 143. The heat exchanger
141 allows heat exchange between the defrost CO2
refrigerant and the CO2 refrigerant exiting the supra-
compression stage 32 via lines 144, and may also be any
other heat source (e.g. electric heater, heat reclaim,
air-conditioning unit, or the like).
An air-conditioning unit 145 may be in fluid
communication with the defrost reservoir 42 so as to use
the defrost CO2 refrigerant accumulated therein for air-
conditioning purposes. The discharge of the air-
conditioning unit 145 may be returned to the suction of
the supra-compression stage 32, amongst other
possibilities. In the various refrigerant systems
described above, it is pointed out that the defrost
refrigerant may be fed to the evaporators of stages 16
and 17 from either direction (as opposed to being fed in
a direction opposed to that of refrigerant in the
refrigeration cycle). Moreover, it is considered to
provide the valves controlling the flow of defrost
refrigerant to the evaporators 16 and 17 in the
- 23 -


CA 02744840 2011-06-22

refrigeration pack, and have a plurality of lines for
each single valve.
Referring to Fig. 13, a desiccant system is
generally shown at 150. The desiccant system.150 may be
used with any of the refrigeration systems described
above, or with other refrigeration systems, to dry air
being entered into a building for ventilating or
refrigerating purposes. The desiccant system 150 is a
closed circuit in which circulates a desiccant fluid.
The system 150 has a dryer 151, upon which
exterior air flows when entering the building. The
dryer 151 is a structural device upon which the
desiccant fluid is sprayed. For instance, the dryer 151
may provide a honeycomb body. The desiccant fluid
is sprayed on the dryer 151 is in a suitable cooled state
to absorb humidity from the warm exterior air entering
the building. The desiccant fluid reaches a
substantially liquid state after the absorption of
humidity, and drips into pan 152 (or any oter
collector).
By way of a line and pump, the desiccant fluid
passes through a heating exchanger 153 to be heated.
Although not shown, the heating exchanger 153 may be
connected to one of the above-referred refrigeration
circuits, so as to provide the necessary energy to heat
the desiccant fluid. Alternatively, the heating
exchanger 153 may have an electric coil or the like.
The desiccant fluid, in a heated state, is
then sprayed onto a humidifier 154. The humidifier 154
is similar to the dryer 151 in construction, but
releases water to the exterior air. The desiccant fluid
is heated as a function of the exterior temperature, for
the desiccant fluid to release the previously-absorbed
water to the air. The liquid desiccant is then
collected in another pan 155 (or the like).

- 24 -


CA 02744840 2011-06-22

By way of a line and pump, the desiccant fluid
passes through a cooling exchanger 156 to be cooled.
Although not shown, the cooling exchanger 156 may be
connected to one of the above-referred refrigeration
circuits, so as to provide the necessary energy to cool
the desiccant fluid. The desiccant fluid is cooled as a
function of the exterior temperature, for the desiccant
to absorb water from the outdoor air entering the
building. Once it is cooled, the desiccant fluid is
directed to the dryer 151.

- 25 -

Representative Drawing
A single figure which represents the drawing illustrating the invention.
Administrative Status

For a clearer understanding of the status of the application/patent presented on this page, the site Disclaimer , as well as the definitions for Patent , Administrative Status , Maintenance Fee  and Payment History  should be consulted.

Administrative Status

Title Date
Forecasted Issue Date 2014-01-28
(22) Filed 2009-10-23
(41) Open to Public Inspection 2010-04-29
Examination Requested 2011-06-22
(45) Issued 2014-01-28

Abandonment History

There is no abandonment history.

Maintenance Fee

Last Payment of $263.14 was received on 2023-08-03


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Payment History

Fee Type Anniversary Year Due Date Amount Paid Paid Date
Request for Examination $800.00 2011-06-22
Application Fee $400.00 2011-06-22
Maintenance Fee - Application - New Act 2 2011-10-24 $100.00 2011-06-22
Maintenance Fee - Application - New Act 3 2012-10-23 $100.00 2012-08-13
Maintenance Fee - Application - New Act 4 2013-10-23 $100.00 2013-10-22
Final Fee $300.00 2013-11-13
Maintenance Fee - Patent - New Act 5 2014-10-23 $200.00 2014-07-30
Maintenance Fee - Patent - New Act 6 2015-10-23 $200.00 2015-07-28
Maintenance Fee - Patent - New Act 7 2016-10-24 $200.00 2016-10-05
Maintenance Fee - Patent - New Act 8 2017-10-23 $200.00 2017-10-04
Registration of a document - section 124 $100.00 2018-09-12
Maintenance Fee - Patent - New Act 9 2018-10-23 $200.00 2018-10-22
Maintenance Fee - Patent - New Act 10 2019-10-23 $250.00 2019-10-22
Maintenance Fee - Patent - New Act 11 2020-10-23 $250.00 2020-10-06
Maintenance Fee - Patent - New Act 12 2021-10-25 $255.00 2021-08-30
Maintenance Fee - Patent - New Act 13 2022-10-24 $254.49 2022-10-11
Maintenance Fee - Patent - New Act 14 2023-10-23 $263.14 2023-08-03
Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
9245-5864 QUEBEC INC.
Past Owners on Record
DUBE, SERGE
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Abstract 2011-06-22 1 29
Drawings 2011-06-22 13 258
Claims 2011-06-22 4 152
Description 2011-06-22 25 1,109
Representative Drawing 2011-09-02 1 15
Cover Page 2011-09-02 2 53
Claims 2012-10-23 4 147
Claims 2013-03-04 4 148
Cover Page 2014-01-03 2 53
Assignment 2011-06-22 4 170
Correspondence 2011-07-20 1 39
Prosecution-Amendment 2012-01-20 1 19
Prosecution-Amendment 2012-02-28 3 95
Prosecution-Amendment 2012-05-28 2 84
Prosecution-Amendment 2012-07-26 3 134
Prosecution-Amendment 2012-10-23 6 242
Prosecution-Amendment 2012-12-03 3 127
Prosecution-Amendment 2013-03-04 6 224
Correspondence 2013-11-13 2 68