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Patent 1039125 Summary

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Claims and Abstract availability

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(12) Patent: (11) CA 1039125
(21) Application Number: 1039125
(54) English Title: ELECTROSTATIC DEPOSITION OF POWDER OR LIQUID DROPLETS IN AIR BY TRIBOELECTRIC OR CORONA DISCHARGE MEANS
(54) French Title: DEPOT ELECTROSTATIQUE DE POUDRE OU DE GOUTELETTES DANS L'AIR PAR DES MOYENS TRIBOELECTRIQUES OU PAR DECHARGE D'EFFET COURONNE
Status: Term Expired - Post Grant Beyond Limit
Bibliographic Data
(51) International Patent Classification (IPC):
  • B64D 1/18 (2006.01)
  • B05B 5/047 (2006.01)
(72) Inventors :
  • COFFEE, RONALD A.
(73) Owners :
  • IMPERIAL CHEMICAL INDUSTRIES LIMITED
(71) Applicants :
  • IMPERIAL CHEMICAL INDUSTRIES LIMITED (United Kingdom)
(74) Agent:
(74) Associate agent:
(45) Issued: 1978-09-26
(22) Filed Date:
Availability of licence: N/A
Dedicated to the Public: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): No

(30) Application Priority Data: None

Abstracts

English Abstract


ABSTRACT
A method and apparatus are provided for the electrostatic
deposition of solid particles or liquid droplets on to an earthed
surface.
The method involves in the vicinity of the surface to be
treated directing a flow of gas carrying electrically charged
particulate material adjacent a capacitor surface which has been
charged to a high potential by the transference of electric charges
developed on another particulate material which is being transported
round a closed circuit path including a charging region remote
from where the charge is transferred to the capacitor. Charging
of both particulate materials is preferably by triboelectricity
although corona discharge may also be used.
Apparatus comprises tubing forming a closed loop, a
compressor for circulating airborne powder round the loop, a
corona discharge needle projecting through an insulated portion
of the tubing wall and electrically connected to a toroidal capacitor
surrounding said insulated portion and a barrel associated with
a second compressor for projecting a separate supply of airborne
powder adjacent the capacitor surface.
The invention is particularly suitable for crop spraying
or dusting or the electrostatic coating of products e.g. with plastics,
and represents a more efficient and thus improved
method over known processes.


Claims

Note: Claims are shown in the official language in which they were submitted.


THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. Apparatus for electrostatically depositing particulate material
and comprising in combination a duct defining a closed loop path for a
flowing medium; means for causing a flow through the duct of a medium com-
prising particulate material suspended in a non-conducting fluid vehicle,
the arrangement being such that electrical charges are induced triboelect-
rically on the particulate material carried by the vehicle along a length of
the duct; capacitor means located outside the duct and electrically insul-
ated so as to avoid charge leakage; electrical discharge means electrically
connected to said capacitor means and located in the duct but electrically
insulated from any conducting portion of the duct for transferring electric
charge from the charged particulate material to said capacitor means, whereby
to build up a charge on an outside surface thereof; and means separate from
said duct for suspending a separate supply of particulate material in a gas
flow, electrically charging said material with a charge of the same polarity
as that induced on the outside surface of the capacitor means and projecting
the flow of charged particulate material adjacent said capacitor surface.
2. Apparatus for electrostatically depositing particulate material
and comprising in combination a duct defining a closed loop path for a
flowing medium; means for causing a flow through the duct of a medium
comprising particulate material suspended in a non-conducting fluid vehicle;
means for inducing by corona discharge an electrical charge on the particulate
material carried by the vehicle through the duct; capacitor means located
outside the duct and electrically insulated so as to avoid charge leakage;
electrical discharge means electrically connected to said capacitor means
and located in the duct but electrically insulated from any conducting por-
tion of the duct remote from said charging means for transferring electric
12

charge from the charged particulate material to said capacitor means, whereby
to build up a charge on an outside surface thereof; and means separate from
said duct for suspending a separate supply of particulate material in a gas
flow, electrically charging said material with a charge of the same polarity
as that induced on the outside surface of the capacitor means and projecting
the flow of charged particulate material adjacent said capacitor surface.
3. Apparatus as claimed in claim 2 in which the electrical charge
inducing means includes at least one electrode extending into the duct and
electrically insulated from the adjacent duct wall, and means for establish-
ing a corona discharge between said electrode and the adjacent duct wall.
4. Apparatus as claimed in claim 1 in which one part of the duct
wall is of electrically conductive material or other material capable of
dissipating electrical charge built up on said part of the duct wall and
another part of the duct wall is of electrically non-conductive material, and
the electrical discharge means extends through said non-conductive part.
5. Apparatus as claimed in claim 4 in which a part of the length of
the duct is formed of electrically non-conductive material and the capacitor
means is located adjacent that length.
6. Apparatus as claimed in claim 5 in which the duct includes two
tubes of electrically conducting material connected together by a tube of
electrically non-conductive material.
7. Apparatus as claimed in claim 6 in which the two tubes of elect-
rically conducting material extend parallel to each other and in close
proximity to each other and the tube of electrically non-conductive material
comprises a U-bend connecting the adjacent ends of said tubes of electrically
conducting material together, said capacitor means being in the form of
13

a toroid fitting over the two arms of the U-bend.
8. Apparatus as claimed in claim 6 or claim 7 in which the two tubes
of electrically conductive material are twisted about one another in helical
fashion.
9. An apparatus as claimed in claim 4 including one or more earthed
needles projecting into the tube through said non-conductive part of the
duct wall each needle being upstream or downstream of said electrical dis-
charge means.
10. Apparatus as claimed in claim 4 in which at least the inner face
of said one part of the duct wall has a soft surface.
11. Apparatus as claimed in claim 10 in which said one part of the
duct wall comprises a duct length formed of resin impregnated fabric the
inner surface of which is lined with rubber.
12. Apparatus as claimed in claim 1 or claim 2 in which the inner
face of the duct for substantially the entire length thereof is of soft
electrically non-conductive material, and means are provided remote from the
electrical discharge means for removing surface charges from the wall of the
duct.
13. Apparatus as claimed in claim 12 in which said charge removing
means comprise an earthing wire extending axially of and within the duct
and/or earthed corona discharge electrodes protruding into the duct at spaced
intervals.
14. Apparatus as claimed in claim 1 or claim 2 wherein the electrical
discharge means comprise corona discharge means extending into the duct.
15. Apparatus as claimed in claim 1 or claim 2 wherein the electrical
discharge means comprise a length of duct the inner face of which is formed
14

of electrically conducting material which is electrically insulated from the
remainder of the duct and from earth.
16. An apparatus as claimed in claim 1 or claim 2 in which the
capacitor is toroidal and surrounds a part of the length of the duct.
17. An apparatus as claimed in claim 1 or claim 2 including means
for increasing the turbulence of the flow of the medium in the duct.
18. Apparatus as claimed in claim 17 in which said turbulence in-
creasing means comprise baffles located in the flow path.
19. Apparatus as claimed in claim 1 or claim 2 in which the means
for electrically charging the particulate material to be projected adjacent
said capacitor surface includes means for transferring a part of the charge
from the capacitor surface to said material.
20. Apparatus as claimed in claim 1 or claim 2 in which the means
for electrically charging the particulate material to be projected adjacent
said capacitor surface includes corona discharge means.
21. An apparatus as claimed in claim 1 or claim 2 including a re-
servoir for-the separate supply of particulate material.
22. A method of electrostatically depositing particulate material on
to an earthed surface, said method comprising in the vicinity of the earthed
surface directing a flow of gas carrying charged particulate material
adjacent to a capacitor surface which is charged to a high voltage of the
same polarity as the charge on the particulate material by transferring to
said capacitor electrical charges developed on a separate particulate material
which is being transported by a non-conducting fluid medium round a closed
circuit path which includes a region where the particles are charged remote
from where the charge is transferred to the capacitor.

23. A method as claimed in claim 22 in which the separate particulate
dielectric material is charged triboelectrically and/or by corona discharge.
24. A method as claimed in claim 22 in which the non-conducting fluid
medium is air and the separate particulate dielectric material comprises a
powdered solid.
25. A method as claimed in claim 22 for electrostatic coating of
surfaces with particulate material.
26. A method as claimed in claim 22 for applying particulate material
to vegetable matter.
16

Description

Note: Descriptions are shown in the official language in which they were submitted.


~39~'~5
This invention relates to electrostatic deposition
of a particulate material which may be liquid droplets or a
solid in particulate, e.g. powder, form. The invention has
particular but by no means exclusive application to the
: 5 treatment of vegetable growth, e.g. as by the dusting or
spraying of crops,but it is also applicable, for example,
to the electrostatic coating of products with powder or
liquids.
In accordance with the present invention, there
is provided a method of electrostatically depositing
particulaté materia1 on to an earthed surface, said m~thod
comprising in the vicinity of the earthed surface directing
a flow of gas carry"ng charged particulate material adjacent
~o a capacitor surface which is charged to a high voltage
of the same polar- ~y as the charge on the particulate D~terial
by trarsf~rring t~ said capacitor electrical charges developed
on a separate particulate material which is being transported
by a non-conducting fluid medium round a closed circuit
path which includes a region where the particles are charged
remote from where the charge is transferred to the capacitor.
The separate particulate material may be charged
triboelectrically and/or by other means such as corona dis-
charge.
Apparatus in accordance with one aspect of the
25 invention comprises in combination
a duct defining a closed loop path for a flowing
medium;
means for causing a flow through the duct of a
medium comprising particulate material suspended
in a non-conducting fluid vehicle, the arrangement
~bi
2 - ~ -
.. . . . . . . . .. . ... . . . .. .. . . ....

1~3~5
being such that electrical charges are induced
triboelectrically on the particulate material
carried by the vehicle along a length of the
duct;
capacitor means located outside the duct and
electrically insulated so as to avoid charge
leakage;
electrical discharge means electrically cornected
to said capacitor means and located in the duct but
electrically insulated from ar,y conducting portion of
the duct for transferring electric charge from the
charged particulate material to said capacitor means,
whereby to build up a charge on an outside surface
thereof; and means separate from said duct for sus-
pending a separate supply of particulate material in
a gas flow, electrically charging said material
with a charge of the same polarity as that
induced on the outside surface of the capacitor
means and projecting the flow of charged
particulate material adjacent said capacitor
surface.
Triboelectric charging is the charging of a
body by friction contact with a different body.
The triboelectric charging of the particulate material
will generally occur primarily as a result of frictional
contact between the particles and the wall of the duct

"` ~ c;)
i~ ~
as the particulate material travels along the duct
length. However, some incidental triboelectric charging
may occur in the container or containers in which the
material is stored and from which it is transferred
into the duct, and also during the transference of the
material to the duct. Triboelectric charging may also
occur as a result of the passage of the particulate material
through the flow causing means, e.g. fluid compressor
and also as a result of the passage of the particulate
material through other portions of the duci~
In one embodiment of the invention, a part
of the duct wall is formed of electrically conductive
material or other material capable of dissipatir.g
electrical charge built up ~ said part of th~ duct
wa~l, e.g. resin impregnated fabric the inner sGrface
of which may be lined with rubber to provide a soft
inner surface to increase the triboelectric charge
produced, and another part of the duct wall is of
electrically non-conductive material, with the electrical
discharge means extending through the non-conductive
part. Generally, the electrically non-conductive part
of the duct wall will comprise a length of the duct wall
and the capacitor means is located adjacent that length.
Alternatively, the inner face of the duct for
substantially the entire length thereof may be formed of an
-- 4 --
. .

I~3~5
electrically non-conductive material such as polyethylene or poly-
methylmethacrylate since the softer nature of such materials
considerably increases the area of contact with the particulate
material which is being transported through the duct by the
flowing vehicle, thus tending to increase the triboelectric charge
produced. However, it is then necessary to prevent the build-up of
charge on the surfaces of the duct and this can be done, for exarnple,
by providing a series of earthed needles protruding through the duct
wall and spaced at appropriate intervals along the duct or by
providing an earth wire extending within the duct and axially of the
duct.
The electrical discharge means which is electrically
connected to the capacitor means may suitably comprise a corona
f discharge electrode, e.g. pOi:lt or knife edge, exten~ing into
the duct. Alternatively, it may comprise a length of duct the
inner face of which is of electrically conducting material which
- is insulated from the remainder of t~e duct ~nd from earth.
The capacitor to which the eleotrical discharge means is
connecte-l may be, for example, spherical or toroidal and may be
arranged to surround a part of the length of the duct. It has been
found that in some circumstances a higher potential can be induced
on the capacitor by providing one or more earthed needles extending
into the duct through a non-conducting part of the wall immediately
upstream and/or downstream of the electrical discharge means.
Advantageously,means such as baffles may be located in
the path of the flowing medium to increase the turbulence of the
flow and hence the level of induced triboelectric charge.
The particulate material which is conveyed in the duct
is preferably a powder and the fluid medium will usually be air.
However, it is envisaged that the particulate material could
.
- 5

.,5
alternativel~ be provided in the rorm of liquid droplets, for
example by providing a liquid supply and means for ato~ising the
liquid into a flowing gas stream to provide a mist which is
maintained at least while the liquid droplets are charged and
carried past the electrical discharge means.
The separate supply of particulate material which is
to be deposited electrostatically may also be a powder or liquid
droplets and usually, although not necessarily, the gas in which
this separate particulate material is suspended will be air.
Conveniently, the material is electrically charged to the same polarity
as the charge induced on the capacitor surface triboelectricaIly by
projecting it in an air stream along a duct whose inner surface is of
a suitable material. hlternatively or additionally, hcwever, the
- charging may be effec'ed other than by triboelectricity. For exampls,
a part of the charge on the capacitor surface may be used for this
purpose or c~ar~ing may be effected by corona discharge from a
separate energy source.
` When the gas-suspended flow of thus charged particulate
material is projected adjacent the charged surface of the capacitor,
it will be repelled by it and deposited on the surface of any earthed
object in the vicinity~ -
An embodiment of the invention will now be described, by
way of example, with reference to the accompanying drawing, which is
a partially broken away schematic elevational view.
Referring to the drawing, an alu~inium tube 10 is connected
between a tube 12 made of an insulating material such as
polymethylmethacrylate and one inlet 14 of a blower unit 16. The
blower unit 16 comprises two centrifugal fans driven by the same motor
but each having an air path which is completely separate from that of
the other. The outlet 18 of the blower unit 16 which is associated
with the inlet 14, is connected by a second aluminium tube 20 to the
other end of the tube 12 so as to form a completely closed duct.
The tube 12 is surrounded by a 'coroid 22 formed of electrically
-- 6 --

~3~
conductive material. A needle 24, of electrically conductive material,
electrically connects the toroid 22 with the inside of tube 12.
The inlet 26 of the other part of the blower unit 16 is connected
to a hopper 28 from which a mixture of air and a powder to be deposited can
be fed into the blower 16. The corresponding outlet 30 is connected by a
tube 32 to a nozzle 34 which directs powder into the region adjacent to the
toroid 22.
A powder such as silicon carbide is placed in the closed circuit
formed by the tubes 10, 12 and 20. In use, the blower unit 16 causes this
powder to be circulated within the closed circuit. Tribo electric or contact
/separation charging takes place due to contact and friction between the pow-
der and the walls of the tubes 10 and 20. Charge build-up on the tubes 10
and 20 doeb~lngt take place since these members are made of aluminium and are
earthed. A corona discharge forms at the tip of the needle 24 and since the
needle is electrically connected to the toroid 22 the resulting charge is
transferred to the outer surface of the toroid acts as a capacitor due to
the Faraday cage effect. Thus the toroid 22 is charged to a high voltage.
Meanwhile, a separate supply of powder from the hopper 28 is blown
by the blower unit 16 along the tube 32 where tribo electric charging takes
place. The material of which the tube 32 is made is chosen to be such that
the polarity of the charge on the powder to be deposited is the same as that
on the toroid 22. Thus, although the voltage on the particles of the powder
emerging from the nozzle 34 may be relatively low, they are strongly repelled
by the high voltage on the toroid 22 and deposited on any convenient earthed
object in the vicinity, for example the object 36 which is the article to be
coated. Thus, the closed circuit formed by the tubes 10, 12 and 20 performs
the function of charging the toroid 22 to a high voltage to establish an
electric field between the toroid 22 and an object 36 to be coated. At the
same time, the powder to be deposited is charged in the tube 32.

11~3~5
Since the particulate material flowing in the duct in which charg-
ing takes place is separate from the particles being deposited, the material
in the duct can be chosen to give optimum charging in conjunction with the
material of which the duct is made. In addition, since no material or air
need be removed from the closed circuit, it can be completely sealed thereby
reducing the risk of charge leakage and weak tribo charging, due to humidity.
Various modifications of the closed circuit part of the apparatus
can be made.
For example, an earthed needle may project into the tube 12, up-
stream and/or downstream of the needle 24 or a plurality of such needles may
be provided which may be located upstream or downstream or both upstream and
downstream of the needle 24. It has been found in some circumstances that
the provision of such needles may lead to a higher potential on the capacitor.
Baffles may be provided inside the tubes 10 and 20 to increase the
turbulence of the flow therein. These are preferably inwardly inclined in
the direction of the flow when the fan is running and are of the same mat-
erial as the tubes 10 and 20, which are also preferably of the aame material.
Instead of being made of aluminium, the tubes 10 and 20 may be
formed of another metal or of a material having a soft inner surface and
sufficient electrical conductivity to reduce the build up of stored charge on
the tube, and thereby inhibit the formation of corona discharge on the parts
of the tube where charging takes place. One suitable material is a resin-
impregnated fabric having a thin rubber lining on its inner surface.
Alternatively, the whole of the tubing fo i ng the closed circuit
may be made of an eaectrically non-conductive material. In this case, how-
ever, it is necessary to provide means for removing surface charges from the
walls of the tubes remote from the electrical discharge means. Conveniently,
this may be achieved by a coaxial earth wire extending the full length of the
tubes 10 and 20 to remove surface charge from the walls thereof. Alterna-
-- 8 --

~3~.,5
tively, earthed needles may be provided to project through the walls of tubes
10 and 20 at suitably spaced intervals along the length of these tubes.
It is to be understood that the illustration of the embodiment in
the drawing is schematic and that, for example, in practice a variety of
different configurations for the tubes forming the closed circuit are pos-
sible. Thus, in one embodiment which is preferred for its ease of manipu-
lation, the two tubes 10 and 20 may extend parallel and closely adjacent
each other for at least some of their length and the tube 12 may comprise a
U-bend which connects the adjacent ends of the tubes 10 and 20. The toroid
22 may then be so constructed and arranged as to fit over the two arms of
the U-bend.
It may also be desirable to twist the tubes 10 and 20 around each
other alorg their long axes so that the flow through each of them follows a
helical path.
As an alternative, or in addition to triboelectric charging, the
- particles in the closed circuit may be charged by other means, suitably
corona discharge. In accordance with this embodiment, the apparatus com-
prises in combination
a duct defining a closed loop path for a flowing
medium;
means for causing a flow through the duct of a medium
comprising particulate material suspended

s
in a non-conducting fluid vehicle;
means for inducing an electrical charge on the
particulate material carried by the vehicle through
the duct;
- 5 capacitor means located outside the duct and electrically
insulated so as to avoid charge leakage;
electrical discharge means electrically connected to
said capacitor means and located in but electrically insulated
~ from the duct remote from said charging means for
; ~ 10 transferring electric charge from the charged particulate
material to said capacitor means, whereby to build up
- a ch~lge on an outside surface thereof; and
; means separate from said duct for suspending a separaGe
supply of pa~ticulate material in a gas flow, electrical y
charging said material with a charge of tne same polarity
- as that induced on the outside surface of the capacitor
means ~nd projecting the flow of charged particulate material
adjacent said capacitor surface.
With this embodiment, for example, one or more corona
discharge electrodes, e.g. in the form of needles or knife edges,
may extend into the charging region of the duct. Such electrodes are
electrically insulated from the adjacent waIls of the duct and a
potential difference of sufficiently high voltage to establish a
discharge is applied between the corona discharge electrode and the
adjacent walls of the duct. With conventional sharp-edge electrodes
a voltage of about 1 to 20 kV would be sufficient.
In one preferred form, the corona discharge electrode,
which may suitably comprise an electrically conducting wire extending
within and axially along a length of the duct, is earthed, and a
_ 10 -

1~3~ S
suitably high voltage, e.g. of 5-25 kV from an appropriate voltage source,
is applied to the inner face of the duct which for that length of the duct is
conductive. By this means, that part of the corona current which goes to
charge the particulate material is drawn from earth and only that part of the
current which Mows to the duct wall need pass through said voltage source.
For electrical and mechanical reasons, it is preferred that the wire is
coaxial with the duct.
The same arrangement may be used to charge the particulate material
in the tube 32, or to supplement the triboelectric charge on said material.
The invention may be used, for example, for the spraying or dusting
of crops, seed dressing, weed killing, mineral dressing, artificial pollina-
tion, the coating of metals with plastics, the coating of rubber with talc,
and the application of corrosion inhibitors such as borax to exposed metal
surfaces.
By way of example, utilising the apparatus illustrated in the
accompanying drawing in which the tubes 10, 12, 20 have an internal diameter
of 8 mm and the length of the closed loop is 2 metres, and using an air flow
velocity of about 35-S0 metres per second and a loading of 5-25 g of powder
in the airstream, potentials of up to 200kV can be obtained on the capacitor
surface.

Representative Drawing

Sorry, the representative drawing for patent document number 1039125 was not found.

Administrative Status

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Event History

Description Date
Inactive: IPC deactivated 2011-07-26
Inactive: IPC from MCD 2006-03-11
Inactive: First IPC derived 2006-03-11
Inactive: Expired (old Act Patent) latest possible expiry date 1995-09-26
Grant by Issuance 1978-09-26

Abandonment History

There is no abandonment history.

Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
IMPERIAL CHEMICAL INDUSTRIES LIMITED
Past Owners on Record
RONALD A. COFFEE
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Abstract 1994-05-19 1 29
Cover Page 1994-05-19 1 15
Claims 1994-05-19 5 162
Drawings 1994-05-19 1 12
Descriptions 1994-05-19 10 347