Note: Descriptions are shown in the official language in which they were submitted.
U-10,397 ~5578
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Background of the Invention
The present invention constitutes a specific improvement
over the invention defined in U.S. Patent No. 3-,264,200 patented
August 2, 1966, and assigned to the Assignee of the present
,
invention. ` -~
In Patent No. 3,264/200, there is disclosed an improved
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method of and bath for the electrodeposition of ductile, low- -
stress nickel plate from an aqueous acidic nickel plating bath
containing at least one nickel salt, which nickel salt is ~-~
selected from the group consisting of nickel sulfate, nickel
sulfamate, nickel ~luoborate, nickel bromide and nickel chloride.
~he nickel salks are present in amounts conventional in the art,
e.g., up to about 100 grams per liter of NiC12.6H2O. The patent
discloses the addition to such baths of a specific aryl sulfon
compound, namely metasulfobenzoic acid or its derivatives, such
as Ni-carboxy benzene sulfonic acid can be utilized.
An aldehyde, such as chloral h~drate or formaldehyde, may
be added to the patented bath for grain refinement and to reduce
the sulfur content of the bath.
The general purpose of nickel electroplating, of course, is
to yield a semi~bright deposit having the desirable characteristics
of ductility, uniformly fine grained appearance, and good leveling
characteristics. Normally, these objectives are met by the use ~`
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of coumarin and other additives. However, the deposit from a
nickel solution containing co~arin generally deteriorates during
use due to the gradual accumulation of the degradation products
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of the coumarin itseIf. These degradation products, such as . ~ .
~elilotic acid and related compounds, are ~etrimental to the ~
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U~10,397 ~557~
leveling and ductility of the deposit. As a result, these
deposits must be removed by batch carbon treatments at
periodic intervals, adding to the expense o~ the operation and
normally resulting in time consuming, shortened scheduled pro-
duction runs.
The bath of Patent No. 3,264,200 was developed to reduce
the problems encountered in the accumulation of coumarin degrada-
tion products.~ Generally, a bath containing metasulfoben~oic
acid and its derivatives, particularly wherein aldehydes are
) incorporated, gives a fine lustrous nickel deposit which is
ductile and o ine grained appearance. However, the lev~ling
characteristics are substantially reduced. The presence of the
aldehydes also appears to detract from the leveling characteristics
of the nickel deposit.
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i If it were possible to develop a process and bath which is
~ree of coumarin, thereby avoiding the accumulation of the coumarin
degradation products, yet which yields the excellent leveling
characteristics of coumarin-containing baths, an important forward
step in the art of nickel electrocleposition could be made.
Brief Summary of the Present Invention
The present invention utilizes a specific combination of
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compounds which results in nlckel deposits which are fine grained,
lustrous, and ductile and which have markedly improved leveling
characteristics. Although the leveling characteristics of the
bath of the present invention are not quite as good as those
obtained through the use of coumarin, the present invention does
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permit continuous use of the nickel solution without the accumu-
lation of those deleterious degradation products which are
developed in coumarin solutions. The deposiks from the solutions
of the present invention generally contain less than about 0.005%
sulfur. - '
More specifically, the present inven1,ion is directed to
the addition to baths such as those defined in Patent No. 3,264,200
of a combination of three specific compositions or compounds. The
nickel-containing and pH-controlling elements o~ the bath are
0 conventional and may be of any desired type, as defined in the
noted patent.
The bath of the present invention may be of the W~tts or
modified Watts type containing nickel sulfate; of the sulfamate
type; of the nickel fluoborate type; of the nickel bromide type;
or of the nickel chloride type.
The pH of the bath is controlled by the use of boric acid
(H3BO3); and an aldehyde, such as formaldehyde and/or chloral
hydrate may be added, as above explained.
The specific addition agents of the present invention have
0 a conjunctive affect and are used in combination. Specifically,
these three ingredients include~
I, An aryl sulfon, specifically metsulfobenzoic acid
or its nicke~ salts such as Ni-carboxy benzene
sulfonic acid. This ingredient is present in an
amount ranging from about 0,l to about l0 grams
per liter of the bath.
2. An alkyne diol, specifically butyne diol
(HOH2CC ' CCH2OH) or 3-Hexyne ~2, 5 diol
CH3 CH(O~)C ' C - CH~OH) CH3 being present in an
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amount ranging from about 0.05 to about 0.5
- grams per liter of the bath; and
3. A butene alcohol, specificàlly butene diol
(HOCH2CH:CHCH20H) or butenol (CH3CH:C~ICH20H)
or isomers of butenol, i.e. either 3 ~utene- ~
l-ol H2C=CHCH2CH20H or 3 butene-2-ol-
- H2C=CHCH (OH)CH3, this ingredient also being
- present in an amount ranging from about 0.05
to about 0.5 grams per liter of the bath.
3 It has been found that these three ingredients, used in
conjunction with one another, exert a synergistic affect upon
the bath in which they are incorporated so that the bath yields ~ ;
a nickel deposit which is semi-bright, ductile, of low-stress and
of rernarkably good leveling characteristics, the deposit generally
; contai.ning a maximum sul~ur content of about 0.005%, and the bath
remaining free of those decomposition products, commonly ;~
encountered in the use of coumarin as a ~ath ingredient. `
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It is, therefore, an important object of the present
invention to provide a bath for the electrodeposition of nickel
plate from an aqueous acidic nickel plating bath containing
dissolved therein an aryl sulfon, an alkyne diol and a short chain - ~-
alkene alcohol.
Another important object of the present invention is the
provision of a method of electrodeposition of ductile, low-stress ~ -
nickel plate having good leveling aharacteristics and including
the step of electrodepositing semi-bright ductile nickel from an
aqueous acidic nickel plating bath containing metasulfobenzoic
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acid or its salts, and a combination of at least one alkyne diol
and at least one alkene alcohol containing four carbon atoms.
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It is a further important object of the presen~ invention
to provide an aqueous, nickel salt containing bath for the `
electrodeposition of semi-bright nickel plate and having incor-
porated therein from about 0.1 to about io grams pex liter of
metasulfobenzoic acid or its nickel salts, from about 0.05 to
about O.S grams per liter of an alkyne diol selected from the
group consisting of butyne diol and hexyne diol, and from about
0.05 to about-0.5 grams per liter of an alkene alcohol selected
from the group consisting of butene diol, butenol and isomeric
0 forms of butenol.
Another object of the present invention is the provision
of a method of electrodepositing ductile low~stress nickel plate
from an aqueous acidic nickel plating bath containing at least
one nickel salt and metasulfobenzoic acid or its salts, rèsiding
.5 in the improvement of incorporating in the bath a mixture of an
alkene diol selected from the group consisting of butyne diol ~:
and hexyne diol, and an alkene alcohol selected from the group
consisting of butene diol, butenol, and isomeric forms of butenol. :
DETAILED DESCRIPTION OF THE PRESENT INVENTION
0 As above explained, the present invention constitutes
an improvement upon the invention disclosed and clai.med in
U.S. Patent No. 3,264,200, assigned to the assignee of the
pre.sent invention. This improvement resides in the discovery
of the synergistic effect which can be obtained from the
incorporation of a specific mixture of specific unsaturated
alcohols into the aqueous acidic nickel plating baths proposed
in said earlier patent. - .
More specifically, the earlier patent proposes the
incorporation of metasulfobenzoic acid or the nickel salt of the
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compound into a bath ~or the electrodeposition of ductile r semi-
bright nickel plate. To reduce the internal tensile stress o~
nickel deposits, particularly those deposits obtained from Watts
t~pe and sulfamate type acidic nickel electroplating baths, the
mentioned patent discloses ~he incorporation of from 0.1 to about
10 grams per liter of metasulfobenzoic acid.
Various other additions are proposed in the patent,
particularly the addition of formaldeh~de or chloral hydrate to
the bath to assist in giving uniform grain refinement and low ~
0 sulfur content, Additional additives are also disclosed, including ~-
the suggestion that other unsaturated compounds such as allyl
alcohol and but~ne diol may be added. It has now been determined ~ ;
that the addition of a combination of allyl alcohol and but~ne
diol is not completely effective to produce the desired and
~mproved leveling characteristics of the present invention.
Rather, the present invention is more particularly concerned with
the conjunctive use of a combination of three specific compounds,
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namely the metasul~obenzoic acid which is the primary additive
of Patent No. 3,364~200, and a mixture of an acetylenic alcohol
) and an alkene alcohol containing four carbon atoms.
As is explained in ~atent No, 3,26~,200, the metasulfo~
b~nzoic acid is usually neutralized with nickel hydroxide or
nickel carbonate and is added to the bath as a nickel salt. It,
however, can be added as the free acid, or as sodium or magnesium ~-
j salt. If too high a concentration of the free acid is added to
the nickel bath at one time, the pH of the bath will be substantia- --
11~ reduced. Therefore, the nickel salt of the acid is the
preferred form, where additions of concentrations greater than ~ -
about one gram per liter are added at one time. It should be
understood that when metasulfobenzoic acid is referred to herein,
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t~is expression includes the nickel salt of the compound. Even
where the free aci~ is added to the nickel bath, the metasulfo-
benzoic acid is generally in the form of the nickel salt, or the
ionized nickel salt.
The acetylenic diols which are added are preferably in
the simple unreacted diol form, since it has been found that the
derivatives thereof, such as the epichlorohydrin adduct
of butyne diol are not very effective~ The two preferred alkyne
diols are butyne 1, 4 diol, HOCH2CC a CCH20H or 3-hexyne 2, 5 diol
O CH3CH(OH)C I C-C~(OH)CH3. This ingredient is added in an amount
ranging from about 0.05 to about 0.5 grams per liter of the
solution. Short chained alkene alcohols are used in conjunction
with the alkyne diols. Specific examples include. butene diol,
(HOCH2CH:CHCEI20H), butenol, (C}I3CH:C~ICH20H) or the isomeric forms
of butenol including 3-butene-201, CH3CHOHCH:CH~, or 3 butene-l-ol,
(H2C=CHCH2C~OH). The alkene alcohols uniformly contain four
carbon atoms and, as above noted, are effective whereas other
specific unsaturated alco~ols do not work in the combination, for
example, allyl alcohol (CH2:CHCH20H) is ineffective.
It will be noted that the concentration of the alkyne
alcohol and the concentration of the alkene alcohol is defined as
falling within the same broad range. It has been found that it
is not necessary to use equal amounts of the two compounds, nor
is the utilization of a specific combination of compounds within
; a defined group essential.
If desired, any suitable type of semi-bright nickel plating
bath can be utilized, and the herein disclosed, three component
combination is effective in sulfamate, fluoborate, bromide, and
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low chloride (less than 100 grams per liter NiCl~'6H2O) baths.
The following specific examples are submitted:
EXAMPLE I
Concentration
NiS4'6H2 200-300 g/l ~.
; NiC12 6H2 15-50 g/l ~:
H3BO3 30-50 g/l
Meta sulfobenzoic
acid (Na salt) 0~2- 5 g/l ~ :
~10 Chloral hydrate 0.03-0.2 g/1
Formaldehyde 0.01-0.1 g/l ~ .
Butyne diol 0.05-0.5 g/l ..
Butene diol 0.05-0.5 g/l
EX~MPLE II . ~.
NiS04 6H2 200-300 g/l
;. - NiC12~6H2O 15-50 g~
H3BO3 30-50 g/l
Ni-caxboxy benzene g/l ~:
sulfonic acid. 1-2
-20 Butyne diol 50-150 mg/l :~.
Butene diol 100-300 mg/l
EX~MP~E III .:
,
~'! Ni(SO3NH2)2 (nickel sulfamate) 250~500 g/l
NiC12H2O 0-30 g/1 .-
H3BO3 30-50 g/l
Butyne diol 75 mg/l
Butene diol 150 mg/l
Meta sulfobenzoic acid
(Na salt) 1.5 g/l ~.
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EX~MPL~ IV `
Concentration
NiSO4 6H2 200-300 g/l
NiC12 6H2 30-60 g/l
: 5 H3BO3 ~0-50 g/l
Hexyne diol 150 mg/l
Butene diol 150 mg/l
Meta sulfobenzoic acid .
(Na salt) 2 g/l ~:
The substitution of butenol, 3-butene-2O1, or 3-butene-1-ol
for butene diol in Example II gave equivalent results. .:
In the above cited Examples, the preferred pH range is from
about 2.8 to about 4.5, and the pxeferred bath temperature may
range from liOa to 140F. The cathode current densi.ty maiy be an
~15 average of ~0 to 60 amps per square foot with air agitation.
In each instance, the Examples yielded lustrous, ductile,
! very low-stressed semi-bright nickel deposits which contain less .
than about 0.005~ sulfur, and which have remarkedly good leveling
characteristics. In each instance, the deposit which was obtained `
had improved leveling characteristics over the corresponding
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baths o~ Patent No. 3,264,200.
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