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Patent 1066869 Summary

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Claims and Abstract availability

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(12) Patent: (11) CA 1066869
(21) Application Number: 1066869
(54) English Title: METALLURGICAL COMPOSITIONS
(54) French Title: COMPOSITIONS METALLURGIQUES
Status: Term Expired - Post Grant Beyond Limit
Bibliographic Data
Abstracts

English Abstract


ABSTRACT OF THE DISCLOSURE
It is known to fill errosion holes in ingot mould
bottoms, and other holes in ferrous metal bodies, with metal
produced in situ by exothermic reaction. By the present
invention, the exothermic composition is used in conjunction
with a particulate refractory material. The refractory is
bound by a matrix of solidified slag, produced by the reaction,
to form a non-metallic filling having a working surface
providing a high resistance to thermal shock. A metal phase
is produced by the reaction but is merely incidental.


Claims

Note: Claims are shown in the official language in which they were submitted.


The embodiments of the invention in which an exclu-
sive property or privilege is claimed are defined as follows:
1. A method of repairing a body of ferrous metal by filling
the surface forming a cavity in said body which method
comprises introducing into the cavity a heat generating
composition in the form of a first metal in particulate
metallic form and a second metal in the form of a compound
reactable exothermically with the first metal to yield the
second metal in the fused metallic state and a molten slag
containing the first metal in an oxidised state,
exothermically reacting the composition in the cavity to
form the molten slag and fused second metal therein, also
introducing into the cavity a non-metallic refractory
material in the form of particles, and allowing the second
metal and the slag to set to the solid state with the slag
binding the particles of refractory material together, so
that the cavity is filled at least partially by solidified
material having an upper zone of solid slag and bound
refractory material and a lower zone of solidified second metal.
2. A method according to claim 1 in which the particulate
refractory material is introduced into the hole in admixture
with the heat generating composition.
3. A method according to claim 1 in which the particulate
refractory material is added to the slag whilst the slag is
in the molten state in the hole.
4. A method according to claim 1 in which the heat
generating composition is a mixture of aluminium powder and
ferric oxide.

5. A method according to claim 1 in which the refractory
material is of the fired clay type.
6. A method according to claim 6 in which the refractory
material is firebrick material which has been reduced to
particulate form.
7. A method according to claim 1 in which the refractory
material is present in an amount of from 15 to 30% based on
the total weight of the composition.
8. A method according to claim 1 in which the body of
ferrous metal is formed of cast iron.
9. A method according to claim 8 in which the body of
ferrous metal is an ingot mould base.
10. A method of repairing a body of ferrous metal by
filling the surface forming a cavity in said body, said
method comprising the steps of introducing into the cavity
a heat generating composition in the form of a first metal
in particulate metallic form and a second metal in the form
of a compound reactable exothermically with the first metal
to yield the second metal in the fused metallic state and a
molten slag containing the first metal in an oxidized state,
exothermically reacting the composition in the cavity to form
the molten slag and fused second metal therein, also
introducing into the cavity a non-metallic refractory
material in the form of particles, and allowing the second
metal and the slag to set to the solid state so that the
cavity is filled at least partially by solidified material
having an upper zone of solid slag and refractory material
and a lower zone of solidified second metal.

11. A composition for use in the filling of a hole in a
ferrous metal body which comprises (1) a mixture reactable on
ignition to yield a molten slag containing a first metal in
an oxidised state and a second metal in the fused metallic
state by reaction of the first metal provided in particulate
metallic form with the second metal provided in the form of
a compound reactable exothermically with the first metal and
(2) a refractory material of the ceramic type in particulate
form and present in an amount such as to be bound together
by the slag when the slag has solidified by cooling.
12. A composition according to Claim 11 in which the
refractory material is firebrick which has been reduced to
the particulate form.
13. A composition according to either of Claims 11 or 12
in which the refractory material has been sieved to a particle
size of less than one eighth inch.
14. A composition according to either of Claims 11 or 12
in which the refractory material has been sieved to pass a
half inch sieve but to be retained on an eighth inch sieve.
15. A composition according to either of Claims 11 or 12
in which the first metal is aluminium and the second metal
is iron in the form of ferric or other iron oxide.
15. A composition according to either of Claims 11 or 12
in which the refractory material is present in an amount of
from 15 to 30% by weight based on the total weight of the
composition.

Description

Note: Descriptions are shown in the official language in which they were submitted.


r~he pre~ent invention relates -to the repairing o~
~e.rrous metal bodies, egO mould components, by heat
~enexatin~ compositions.
~ in~ot mould usually con6ists of an open ended cas-t
iron bod~ eg~ o~ rectangular cross section, sligh-tly
tapered internally to facilitate removal o~ the solidified
ingot~ Tbe mould i~ set on a cas* iron ba~e which forms the
bottom of the mouldin~ cavity. ~his same base is used with
moulds of different sizes which are arranged centrall~ located
on the base. ~he molten metal poured in from the top of the
mould in castin~ the ingots thus tends always to impinge
upon the same region of the base. ~he resulting progressive
erosion eventually produces a hole o~ unacceptable depth.
~he present in~ention is based upon the discovery that
an acceptable rapair may be achieved by filling the hole to ~ -
produce a workin~ sur~ace of a wear-resisting no~-metallic
inorganic material ~ormed in situ~
In accordance with one aspect of the present invention
, ,
there is pxovided a method of repairing a body of ~errous -
metal by filling the surface forming~ a cavit~ in said bod~
which method comprises in-troducing into the ca~ity a heat
generating composition in the form o~ a ~irst metal in
particulate metallic form a~d a second metal i~ the form of
a compound reactable exothermically with the first metal to
25~ yield the second metal i~ the fused metallic ~tate a~d a
~ molten slag cont~ining the first metal in an oxidi~ed ~tate,
, ~ , .
~ exothermicall~ reacting the compositio~ in the cavity to
:
form the molten ~la~ and fused second metal therei~ also
~ introducin~ into the ca~it~-a no~-metallic re~ractor~ materail
; 3~ ~ in the form of particlesi 9 and allowing the second me-tal and
the sla~ to set to the solid s-tate with the islag bin~ing the

:
~0~;6869
: particles o~ re~rac-tory materi~l together, so thnt the cavity
is f`illed at least partially by solidified material having an
upper ~one of solid sla~ and ~ound refractory material and a
lower zone o~ solidi~ied second metal.
In accordance wi-th another aspect o~ the present invention
there is provided a compo~ition for use i.n the filling of a
hole in a ferrous metal body which compri.seæ (1) a mixture
reactable o~ i~nition to yield a molte~ ~lag containi~g a
`~ Pirst metal in an oxidised s-tate and a second metal in the
fused metallic state by reaction of the first metal pro~ided i~
: particulate metallic form with the second metal provided in the .
form of a compound reactable exothermically with the first
metal and (2) a refractory material of the ceramic type in ;
~ particulate ~orm and present in an amount such as to be bound
,~ 15 together b~ the sla~ when the slag has solidified by cooling.
,.; ~hermite has bee~ used previousl~ for the present purpose 7 ~:
j but in such a manner as to ~ill the hole with a weld button of
: mietallic iron. ~he slag produced ~y the exothermic reaction ~ ~
`, i3 aD u~wanted product which is discarded. ~he re~ult is : ~:
,'J~ 20 imperfe¢t in that the molten metal ca~ fuse with the metal of
the button so ~hat the button is pulled out of the hole when
,, the i~got is stripped from the ba~e. In contrast the present ~::
-~ compo~ition is used in such a manner that the hole is ~inished
" . ~ :
,, ~ with the refractory material bound b~ the ~lag. Underlying the
slag is a weld-button producod a~ a b~-product o~ the reaction.
Its presence is incide~tal and the working surPace i~ provided :
by the bound refrac~ory material which providos the workin~
.~ . ~ .. .
surface and has a high resistanoe to thermal shock. A~ the
3:: bound re~rac~ory material is wor~ awsy with continued use, it ~ .
ma~ be re~iaired us~ng appropriate amounts o~ the composition
1 - 3 - :
~ B :
. .
~ - .~ - . .. - .
... . . . . . . . . . . . . . . .

66~69
including the re~`rac-tory adcli-tlon, be~`ore the weld butt;on is
exposed~
~he refrac~ory material of the composition may be of the
:Eired-clay or other ceramic type. aonvenien-tly, there may be
used firebrick (e~g. reco~ered from steelwork~) which has been
reduced to particulate form, e.g~ by crushing~ Al-ter~ative
refxactory ma-terials are siliconicarbide, magnesite, alumino
silicates, burned dolomite~ alumina and mixtures o~ these
materials. Magnesite is attractive because o~ its favourablR
cowe~ficient o~ expansion. ~he particle size is not critical,
a~d for mo~ purposes a suitable finish is obtained using
particulate ~irebrick or other refractory material of coarse
grade. Good results have been obtained with firebrick sieved
to less tha~ one-eigh~h inch. Improved resul-ts have been ~-
obtained with firebrick granulss which pas~ a half inch sieve
but are retained on an eighth inch sieve, probably because of
the avoidance of fine particles ha~ing a relatively high
solubility in the slag~
~ suitable proportion of -the re~ractor~ material may be
2~ asoer~ained b~ simple experiment. Using crushed ~irsbrick in
an amount of from 15 to 30~, preferably about 20% based on the
weight o~ the composition gives satis~actor~ results with
thermite containi~g from 60 to 70~ by weigh-t o~ aluminium
calculatea at A1203
Accordin~ to a modification uf the method a~ hereinbefore
de~cribed7 the particulate r~fraGtory material or a part thereo~
i~ introduced into -the ~la~ formed in the bole whilst the slag
i~ sti11 in the molten sta~e. ~ypicall~ the re~ractor~ material
i5 mixed with the slag by stirring~
'rhe acoompanying self-explanatory drawing is given i~ order
to illustrate the invention~
~ 4 _
~, .

1~668~;~
In the drawings:
Figure 1 is a plan view of an inyot mould base haviny
an erosion hole filled with a particula-te composition
according to the invention, and
Figure 2 is a vertical cross-section along the line
2-2 of Figure 1.
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Representative Drawing

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Administrative Status

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Event History

Description Date
Inactive: Expired (old Act Patent) latest possible expiry date 1996-11-27
Grant by Issuance 1979-11-27

Abandonment History

There is no abandonment history.

Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
GORICON METALLURGICAL SERVICES LIMITED
Past Owners on Record
None
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Abstract 1994-05-01 1 47
Claims 1994-05-01 3 124
Drawings 1994-05-01 1 31
Descriptions 1994-05-01 4 200