Note: Claims are shown in the official language in which they were submitted.
THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A temperature indicator for measuring temperature,
particularly useful as a steam trap monitor, consisting
essentially of:
a layer of paper-backed foil having a viewing area;
a layer of adhesive corresponding to said layer of
paper-backed foil located adjacent thereof;
a transparent tape located adjacent to said layer of
adhesive and continuing across the viewing area in said layer of
adhesive and said layer of paper-backed foil;
an absorbent layer containing a composition of matter
consisting essentially of:
(1) a solvent (I) consisting of a single substance or a
mixture of substances adapted to change from a solid state at
substantially a predetermined temperature to a liquid state; and
(2) an indicator system (II) consisting of one or more
substances different from (I), and inert to (I), further charac-
terized in that
(a) (II) is soluble in (I) when the latter is in the
liquid state; and
(b) (II) changes color visible to the naked eye when
(I) passes from the solid to the liquid state or from the liquid
to the solid state;
a layer of paper-backed foil located adjacent said
absorbent layer and the portions of said transparent tape not in
direct communication with said absorbent layer; and
a layer of adhesive located adjacent said layer of
paper-backed foil.
14
2. The temperature indicator according to claim l wherein
the solubility of the indicator system (II) in the solvent (I),
when the latter is in the solid state, is so much lower than the
solubility of (II) in (I), when the latter is in the liquid
state, that (II) is partly or entirely separated while (I) passes
from the liquid to the solid state.
3. The temperature indicator according to claim 1
wherein said composition of matter exhibits a sharp color change
upon transition from a liquid state to a solid state or from a
solid state to a liquid state capable of being supercooled for
at least several minutes, and consists essentially of
(a) a solvent adapted to change from a solid state at
a predetermined temperature to a liquid state, and
(b) an effective amount of at least one organic moiety
dissolved in and inert towards said solvent to form a solid
solution when the composition is in the solid state and adapted
to change the color of the composition visible to the naked eye
upon the change of state of the solvent at substantially the
predetermined temperature when so dissolved, and selected from
one or more of the group consisting of
(1) a group of single compounds consisting of the
following classes of compounds: cyanine, monoazo, disazo, tri-
aryl-methane, xanthene, sulphone, phthalein, acridine, quinoline,
azine, oxazine, thiazine, anthraquinone, indigoid, and the
following individual compounds: Aurantia, Orasol orange RLN,
Diamin green B, Direct green G, Fast red salt 3 GL, Fast blue
salt BB, Fast garnet salt GBC, Carta yellow G 180%, Murexide,
Savinyl blue GLS, Irgalith blue GLSM, phthalocyanine, and
Alcannin,
(2) mixtures of
(a) one or more organic acid compounds having a
pK of less than about four, and
(b) one or more basic dyes or basic indicators,
(3) mixtures of
(a) one or more organic acids having a pK of
less than about 2, and
(b) one or more acid dyes or acidic indicators,
(4) mixtures of
(a) one or more organic acid compounds having a
pK of less than about 4, and
(b) one or more of a group III body of compounds
consisting of pinacyanol iodide, 1,1'-diethyl-2,2'-cyanine iodide,
quinaldine red, pinacyanol chloride, thionin, methylene blue,
cresol red, chlorophenol red, neutral red iodide, neutral red
chloride, crystal violet, acridin orange, Orasol Orange RLN
Orasol Navy BlueTM, Irgalith Red PRTM, Fat Red BSTM, Xylene Cyan-
ol FFTM, Rhodamine BTM, Rhodamine 6GTM, Irgalith Magenta TCBTM,
Irgalith Pink TYNCTM, Toluidine Blue OTM, Savinyl Green BTM,
Savinyl Blue RSTM, purpurin, 3,3'-diethylthiadicarbocyanine
iodide, cryptocyanine, Dicyanine ATM, Merocyanine 540TM, 4-(p-
ethoxyphenylazo)-m-phenylene diamine monohydrochloride, Yellow
Orange STM, Chrysoidan GTM, fuchsin, aurintricarboxylic acid
(ammonium salt), Victoria Blue RTM, Pyronin GTM, gallein, Erythro-
sin Yellow BlendTM, chlorophenol blue, bromophenol blue, bromo-
cresol purple, Coriphosphine OTM/ acriflavine, acridine orange,
rhoduline violet, Alizarin cyanin 2RTM, Alizarin Red STM,
alcannin, Aurantia, Direct Green GTM, Fast Red Salt 3 GLTM,
Fast Blue Salt BBTM, Fast Garnet Salt GBCTM, Carta Yellow 180
o/oTM, Murexide, Savinyl Blue GLSTM, Irgalith Blue GLSMTM, phthalo-
cyanine, Di Amingreen BTM, Alizarin Blue S, Celliton Blue Extra
neocyanine, Janus Green TM, dimethyl yellow, Fast Yellow TM, methyl
red sodium salt, Alizaxin yellow RTM, Erichrome Black TTM,
Chromotrope 2RTM, Ponceau 6RTM, Brilliant Ponceau G/R/2RTM,
chromolan yellow, Sudan Red BTM, Bismarck brown GTM, Fat Black TM,
16
Resorcin BrownTM, senzofast pink 2BLTM, Oil Red EGNTM, Euroglauc-
ine, Fuchsin NBTM, parafuchsin, Patent BlueTM, Irgalith Blue
TNCTM, Phloxin BTM, fluorescein sodium salt, Rhodamine B baseTM,
Eosin Scarlet, Eosin YellowishTM, Erythrosin extra bluish,
4,5-dibromofluorescein, ethyleosin, PhloxineTM, Cyanovin BTM,
chlorocresol green, pinacyanol bromide, 2-(p-dimethylaminostyryl)-
1-ethyl pyridinium iodide, ethyl red, nigrosine, Savinyl Blue BTM,
Orasol Blue BLNTM, Safrainin OTM, Azocarnun GTM, PhenosafranineTM,
Azocarmine BXTM, Solophenyl Brilliant Blue BLTM, Nile Blue ATM,
gallocyanine, gallamine blue, celestine blue, methylene green,
Azure A/B/CTM, Blue VIF OrganolTM, Alizarin, Nitrofast Green
GSB , quinalizarine, Oil Blue N M, Solvay purple, Ciba Blue
Indigo syntheticTM, Chromophtal Bordeaux RSTM, Acid Alizarin Red
BTM, 5-Aminofluorescein, Rose BengalTM, Martius YellowTM, Chicago
Blue 6BTM, Alcian Blue 8GXTM, cresyl violet, 4,4'-Bis(dimethyl-
amino)benzylhydrol, zinc Phthalocyanine, Sudan IIITM, Pyronin yTM,
Toluylene BlueTM, cresyl violet perchlorate, Mendola's BlueTM,
Phosphine Dye, NitronTM, cresyl violet acetate, Ceres Orange RTM,
4-phenylazo-1-naphthyl-amine, 4-(4-Dimethylamino-l-naphthalazo)-
3-methoxybenzene sulfonic acid, Bindschedler's Green M, and p-(p-
dimethylaminophenylazo)benzoic acid,
(5) mixtures of
(a) one or more basic dyes or basic indicators,
and
(b) one or more members of the group III body
of compounds, and
(6) mixtures of
(a) one or more dyes having a molecular structure
containing a lactone group, and
(b) one or more acids having a pK of about 8 to
about 12.
17
4. The temperature indicator according to claim 1. wherein
said composition of matter exhibits a sharp color change upon
transition from a liquid state to a solid state or from a solid
state to a liquid state capable of being supercooled for at
least several minutes, and is substantially free of impurities,
consisting essentially of:
(a) a solvent adapted to change from a solid state
at substantially a predetermined temperature to a liquid state;
and
(b) an effective amount of at least one organic
moiety dissolved in and inert towards said solvent to form a
solid solution when the composition is in the solid state and
adapted to change the color of the composition visible to the
naked eye
18
upon the change in state at substantially the predetermined temp-
erature when so dissolved, and selected from one or both of the
group consisting of:
(1) one or more of a group III body of compounds
consisting of pinacyanol iodide, 1,1'-diethyl-2,2'-cyanine iodide,
quinaldine red, pinacyanol chloride, thionin, methylene blue,
cresol red, chlorophenol red, neutral red iodide, neutral red
chloride, crystal violet, acridin orange, Orasol Orange RLNTM,
Orasol Navy BlueTM, Irgalith Red PRTM, Fat Red BSTM, Xylene Cyan-
ol FFTM, Rhodamine BTM, Rhodamine 6GTM, Irgalith Magenta TCBTM,
Irgalith Pink TYNCTM, Toluidine Blue OTM, Savinyl Green BTM,
Savinyl Blue RSTM, purpurin, 3,3'-diethylthiadicarbocyanine
iodide, cryptocyanine, Dicyanine ATM, Merocyanine 540TM, 4-(p-
ethoxyphenylazo)-m-phenylene diamine monohydrochloride, Yellow
Orange STM, Chrysoidan GTM, fuchsin, aurintricarboxylic acid
(ammonium salt), Victoria Blue RTM, Pyronin GTM, gallein, Erythro-
sin Yellow BlendTM, chlorophenol blue, bromophenol blue, bromo-
cresol purple, Coriphosphine OTM, acriflavine, acridine orange,
rhoduline violet, Alizarin cyanin 2RTM, Alizarin Red STM,
alcannin, Aurantia, Direct Green GTM, Fast Red Salt 3 GLTM,
Fast Blue Salt BBTM, Fast Garnet Salt GBCTM, Carta Yellow G 180
o/oTM, Murexide, Savinyl Blue GLSTM, Irgalith Blue GLSMTM, phthalo-
cyanine, Di Amingreen BTM, Alizarin Blue S, Celliton Blue Extra
neocyanine, Janus GreenTM, dimethyl yellow, Fast YellowTM, methyl
red sodium salt, Alizarin yellow RTM, Eriochrome Black TTM,
Chromotrope 2RTM, Ponceau 6RTM, Brilliant Ponceau G/R/2RTM,
chromolan yellow, Sudan Red BTM, Bismarck brown GTM, Fat BlackTM,
Resorcin BrownTM, Benzofast pink 2BLTM, Oil Red EGNTM, Euroglaucine,
Fuchsin NBTM, parafuchsin, Patent BlueTM, Irgalith Blue TNCTM,
Phloxin BTM, fluorescein sodium salt, Rhodamine B baseTM, Eosin
Scarlet, Eosin YellowishTM, Erythrosin extra bluish, 4,5-dibromo
fluorescein, ethyleosin, PhloxineTM, Cyanovin BTM, chlorocresol
19
green, pinacyanol bromide, 2-(p-dimethylaminostyry)-1-ethyl
pyridinium iodide, ethyl red, nigrosine, Savinyl Blue BTM,
Orasol Blue BLNTM, Safranin OTM, Azocarnun GTM, PhenosafranineTM,
Azocarmine BXTM, Solophenyl Brilliant Blue BLTM, Nile Blue ATM,
gallocyanine, gallamine blue, celestine blue, methylene green,
Azure A/B/CTM, Blue VIF OrganolTM, Alizarin, Nitrofast Green
GSBTM, quinalizarine, Oil Blue NTM, Solvay purple, Ciba BlueTM,
Indigo syntheticTM, Chromophtal Bordeaux RSTM, Acid Alizarin Red
BTM, 5-Aminofluorescein, Rose BengalTM, Martius YellowTM, Chicago
Blue 6BTM, Alcian Blue 8GXTM, cresyl violet, 4,4'-Bis(dimethyl-
amino)benzylhydrol, zinc Phthalocyanine, Sudan IIITM, Pyronin yTM,
Toluylene BlueTM, cresyl violet perchlorate, Mendola's BlueTM,
Phosphine Dye, NitronTM, cresyl violet acetate, Ceres Orange RTM,
4-phenylazo-1-naphthyl-amine, 4-(4-Dimethylamino-l-naphthalazo)-
3-methoxybenzene sulfonic acid, Bindschedler's GreenTM, and p-(p-
dimethylaminophenylazojbenzoic acid;
(2) a binary mixture of
(A) one or more of a group I body of
compounds soluble in said solvent consisting of the halogenated
sulfonphthaleins and the organic acids having a pK1 less than
about four; and
(B) one or more of a group II body of
compounds consisting of the aminotriphenylmethanes and their
soluble salts, 8-hydroxyquinoline, and the cyanines;
wherein the weight ratio of the group I body of
compounds to the group II body of compounds is more than or
about 3 to 1 and with the proviso that if the group II compounds
consist solely of one or more aminotriphenylmethanes or their
soluble salts, then the group I compound must be selected from
one or more of the group consisting of oxalic acid, suitable
soluble sulfonic acids, and the tetrahalogenated sulfonphthaleins,
and the other organic acids having a pK1 of less than or about 2;
and
(3) one or more of the aforesaid group III body
of compounds with one or more of the group I or group II bodies
of compounds.
5. The temperature indicator according to claim 4 wherein
(a) the group I body of compounds are one or more of the group
consisting of oxalic acid, bromophenol blue, bromothymol blue,
chlorophenol red, bromochlorophenol blue, bromocresol green,
3,4,5,6-tetrabromophenolsulfonphthalein, 2-naphthalene-sulfonic
acid, trichloroacetic acid, chloroanilic acid, bromophenol red,
and chlorocresol green and (b) the group II body of compounds are
one or more of the group consisting of 5-(p-dimethylaminobenzili-
dine)rhodanine, ethyl red, crystal violet, pararosaniline, para-
rosaniline acetate, 3-ethyl-2-~-5-(3-ethyl-2-benzothiazolinylidene)-
1,3-pentadienyl]-benzo-thiazolium iodide, basic fuchsin, 8-hydroxy-
quinoline, ethyl violet, brilliant green, Dicyanine A, pinacyanol
chloride, 2-(p-dimethylaminostyryl)-1-ethyl-pyridinium iodide,
3,3'-diethylthiodicarbocyanine iodide, and cryptocyanine.
6. The temperature indicator according to claim 5 wherein
the weight percentage of organic moieties soluble in the solvent
is from about 0.025 to about 0.05% of the weight of the solvent
and said soluble organic moieties.
7. The temperature indicator according to claim 5 wherein
the solvent is selected from one or more of the group consisting
of ortho-chloronitrobenzene, ortho-bromonitrobenzene, 1-thymol,
2-naphthol, 2-ethoxybenzamide, and naphthalene.
8. The temperature indicator according to claim 5 wherein
the group I compounds consist of the halogenated sulfonphthaleins
having a pK1 of about 2 and a PK2 of about 7 to about 9.
9. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of bromochlorophenol
21
blue and ethyl red.
10. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of bromochlorophenol
blue and ethyl violet.
11. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of bromophenol blue
and basic fuchsin.
12. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of bromophenol red
and brilliant green.
13. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of bromochlorophenol
blue and pinacyanol chloride.
14. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of 3,3'-diethylthio-
dicarbocyanine iodide and bromocresol purple.
15. The temperature indicator according to claim 4 whereinthe
organic moieties selected are a mixture of 3,3'-diethylthiodi-
carbocyanine iodide and bromophenol blue.
16. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of pinacyanol chloride
and 3,4,5,6-tetrabromophenolsulfonphthalein.
17. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of pinacyanol chloride
and bromocresol purple.
18. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of ethyl red and bromo-
chlorophenol blue.
22
19. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of pinacyanol chloride
and chlorocresol green.
20. The temperature indicator according to claim 4 wherein
the organic moiety selected is pinacyanol iodide.
21. The temperature indicator according to claim 4 wherein
the organic moiety selected is guinaldine red.
22. The temperature indicator according to claim 4 wherein
the organic moiety is 1,1-diethyl-2,2'-cyanine iodide.
23. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of chlorophenol blue
and ethyl red.
24. The temperature indicator according to claim 4 wherein
the organlc moieties selected are a mixture of bromophenol blue
and ethyl red.
25. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of chlorophenol red
and ethyl red.
26. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of ethyl red and
3,4,5,6-tetrabromophenolsulfonphthalein.
27. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of ethyl red and
bromophenol red.
28. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of pinacyanol chloride
and bromochlorophenol blue.
23
29. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of ethyl red and
bromocresol purple.
30. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of crystal violet and
bromophenol blue.
31. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of bromochlorophenol
blue and brilliant green.
32. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of naphthalene sul-
fonic acid and ethyl violet.
33. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of naphthalene sulfonic
acid and crystal violet.
34. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of naphthalene sulfonic
acid and ethyl red.
35. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of trichloroacetic
acid and cryptocyanine.
36. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of trichloroacetic
acid and ethyl violet.
37. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of 3-ethyl-2-[5-(3-
ethyl-2-benzothiazolinylidene)-1,3-pentadienyl]-benzothiazolium
iodide and trichloroacetic acid.
24
38. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of chloroanilic acid
and basic fuchsin.
39. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of chlorophenol red
and dicyanine A.
40. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of chlorophenol red
and cryptocyanine.
41. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of bromochlorphenol
blue and dicyanine A.
42. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of 5-p-dimethylamino-
benzylidine rhodanine and dicyanine A.
43. The temperature indicator according to claim 4 wherein
the organic moieties selected are a mixture of 5-p-dimethylamino-
benzylidine rhodanine and cryptocyanine.
44. The temperature indicator according to claim 1 wherein
the layer of paper-backed foil is a paper-backced aluminum foil.
45. The temperature indicator according to claim 1 wherein
the layer of adhesive is a silicone adhesive.
46. The temperature indicator according to claim 1 wherein
said transparent tape is a polyimide tape.
47. The temperature indicator according to claim 46 wherein
said polyimide tape also contains a silicone adhesive.
48. The temperature indicator according to claim 1 wherein
said absorbent layer has a filter paper base.
26