Language selection

Search

Patent 2269130 Summary

Third-party information liability

Some of the information on this Web page has been provided by external sources. The Government of Canada is not responsible for the accuracy, reliability or currency of the information supplied by external sources. Users wishing to rely upon this information should consult directly with the source of the information. Content provided by external sources is not subject to official languages, privacy and accessibility requirements.

Claims and Abstract availability

Any discrepancies in the text and image of the Claims and Abstract are due to differing posting times. Text of the Claims and Abstract are posted:

  • At the time the application is open to public inspection;
  • At the time of issue of the patent (grant).
(12) Patent: (11) CA 2269130
(54) English Title: IMPROVED UNIT OF EQUIPMENTS FOR THE HIGH-SPEED CONTINUOUS CASTING OF GOOD QUALITY THIN STEEL SLABS
(54) French Title: UNITE AMELIOREE D'EQUIPEMENTS SERVANT A LA COULEE CONTINUE A GRANDE VITESSE DE BRAMES D'ACIER MINCES DE BONNE QUALITE
Status: Term Expired - Post Grant Beyond Limit
Bibliographic Data
(51) International Patent Classification (IPC):
  • B22D 11/04 (2006.01)
  • B22D 11/053 (2006.01)
  • B22D 11/055 (2006.01)
  • B22D 11/14 (2006.01)
(72) Inventors :
  • MANINI, LUCIANO (Italy)
  • BIANCHI, ANDREA (Italy)
  • ARVEDI, GIOVANNI (Italy)
(73) Owners :
  • GIOVANNI ARVEDI
(71) Applicants :
  • GIOVANNI ARVEDI (Italy)
(74) Agent: BROUILLETTE LEGAL INC.
(74) Associate agent:
(45) Issued: 2006-10-10
(86) PCT Filing Date: 1997-11-12
(87) Open to Public Inspection: 1998-05-22
Examination requested: 2002-09-18
Availability of licence: N/A
Dedicated to the Public: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): Yes
(86) PCT Filing Number: PCT/IT1997/000276
(87) International Publication Number: IT1997000276
(85) National Entry: 1999-04-19

(30) Application Priority Data:
Application No. Country/Territory Date
MI96A002336 (Italy) 1996-11-12

Abstracts

English Abstract


Apparatus for the continuous casting of steel slabs, especially low thickness
slabs at high
speed, comprising a mold (1) fed by the submerged nozzle (2) and connected to
an
oscillator (3) driven by a hydraulic servocontrol, wherein the following
geometrical
relation is valid concerning both the mold and the submerged nozzle shapes and
their
mutual arrangement:
0.9 .ltoreq. (A1/S1)/(A2/S2).ltoreq. 1.1
and preferably A1/S1=A2/S2, wherein, on the mold horizontal section at the
meniscus
level, A1 is the area enclosed between the submerged nozzle and larger sides
of the mold,
and A2 is the residual area less the nozzle area, between submerged nozzle and
smaller
sides, S1 and S2 being the total sums of the mold peripheral lengths
corresponding to
each of said areas. Furthermore, at least in the mold horizontal section at
the meniscus
level, the distance between submerged nozzle and copper plates forming the
mold walls
is kept constant.


French Abstract

L'invention concerne une unité d'équipements qui sert à la coulée continue de brames d'acier, en particulier des brames de faible épaisseur obtenues à grande vitesse, et qui contient un moule (1), lequel est alimenté par une tuyère (2) immergée et est relié à un oscillateur (3) entraîné par une servocommande hydraulique. La relation géométrique (A1/S1)/(A2/S2) = 0,9 DIVIDED 1,1, dans laquelle de préférence A1/S1 = A2/S2, s'applique aux formes du moule et de la buse immergée ainsi qu'à la disposition de l'un par rapport à l'autre. Dans ladite relation géométrique, sur la section horizontale du moule au niveau du ménisque, A1 est la zone comprise entre la buse immergée et des côtés plus grands du moule, A2 est la zone résiduelle placée sur ladite section entre la buse immergée et des côtés plus petits, S1 et S2 étant les sommes totales des longueurs périphériques du moule correspondantes à chacune desdites zones. En outre, au moins dans la section horizontale du moule au niveau du ménisque, la distance entre la buse immergée et des plaques de cuivre formant les parois du moule est maintenue toujours constante.

Claims

Note: Claims are shown in the official language in which they were submitted.


What is claimed is:
1. An apparatus for continuously casting steel slabs, comprising:
.cndot. a mould having two longitudinal sides comprising copper for holding
liquid
steel, the mould being adapted to hold a predetermined amount of liquid steel
to form a top surface at a predetermined position in the mould;
.cndot. a plurality of cooling pipes each having an end disposed proximate to
the
mould, the ends of the cooling pipes collectively defining an ideal envelope
surface;
.cndot. a feeding nozzle having an outlet end adapted to be submerged in the
liquid
steel in the mould;
wherein the geometry of the nozzle and the mould as measured along a cross
section taken along the top surface at the predetermined position satisfies
the
equation:
0.9 .ltoreq. ((A1/S1)/(A2/S2)).ltoreq.1.1
wherein:
.cndot. Al is the area between the outlet end and the longitudinal sides
bounded by two lines extending generally perpendicularly between the
longitudinal sides of the mould and each intersecting one of two lateral
ends of the outlet end;
.cndot. S1 is twice the length of one longitudinal side of the mould as
measured between the two lines;
.cndot. A2 is the area enclosed by the mold not including A1 and not including
the area of the outlet end;
.cndot. S2 is the entire perimeter of the mould less S1; and
wherein a normal distance measured between the ideal envelope surface
and a corresponding mould wall is generally constant.
2. The apparatus of claim 1, wherein the geometry of the nozzle and the mould
as
measured along the top surface at the predetermined position satisfy the
equation:
0.95 .ltoreq. ((A1/S1)/(A2/S2)).ltoreq.1.05.

3. The apparatus of claim 1, wherein the geometry of the nozzle and the mould
as
measured along the top surface at the predetermined position satisfy the
equation:
((A1/S1)/(A2/S2))=1.
4. The apparatus of claim 1, wherein the normal distance is in the range of
between
about ten millimeters to about twenty-five millimeters.
5. The apparatus of claim 1, further comprising an oscillator attached to the
mould
for generating a stationary wave in the liquid metal, the stationary wave
having an
average amplitude of between about two millimeters and about ten millimeters.
6. The apparatus of claim 5, further comprising a ratio between the amplitude
of the
stationary wave as measured in millimeters and a casting speed of the
apparatus as
measured in meters per minute is less than or equal to about five.
7. The apparatus of claim 6, wherein the standard deviation of a height of an
upper
surface of the liquid metal in the mould is in the range of between about 0.7
millimeters and about 1.5 millimeters from the predetermined position.
8. The apparatus of claim 1, further comprising:
.cndot. an oscillator attached to the mould for generating a stationary wave
in the
liquid metal; and
.cndot. a controller operatively engaged with the oscillator for varying an
amplitude
of the stationary wave in the range of between about two millimeters and
about ten millimeters.
9. The apparatus of claim 8, wherein the oscillator includes a plurality of
springs that
are operated at a natural frequency of the oscillator.

Description

Note: Descriptions are shown in the official language in which they were submitted.


CA 02269130 2005-09-13
Title of the Invention
Improved unit of equipments for the high-speed continuous casting of good
quality thin
steel slabs.
Background of the Invention
The present invention relates to an improved apparatus for high-speed
continuous casting
of high quality thin steel slabs.
Conventionally, the continuous casting of the so-called "thin slabs" of steel,
up to 80 mm
thick, has been subject to quality problems, especially for casting at high
speed, e.g.
above 4.5 m/mm.
Such problems result in flaws in the slab surface, i.e., the shell, which is
formed in the
mould, as follows:
~ longitudinal cracks due to the trapping of casting powders;
~ longitudinal and transversal cracks due to a lack of lubricating and
insulating f lm
formed by "slag" (i.e., the product of casting powders being melted and
resolidified);
~ longitudinal cracks due to thermal stresses; and
~ longitudinal cracks due to the copper cooling surfaces of the mould being
discontinuous.
These problems typically affect special steels, but could be at least
partially solved by
reducing the casting speed. However, reducing casting speed would lower
productivity
and accordingly reduce plant efficiency. Another possible solution to the
above problems
could be to use an electromagnetic device, called "EMBR" (ElectroMagnetic
Brake
Ruler), capable of flattening the liquid steel waves rippling along the
meniscus inside of
the mould. However, an EMBR is very expensive and would only partially solve
the
aforementioned problems. Additionally, other problems arise from the
geometrical and

CA 02269130 2005-09-13
flow conditions occurring inside the mould, resulting in a reduction of the
operating life
of the casting nozzle (which is dipped in the liquid metal and is usually
called a
"submerged nozzle") and in a reduction of process efficiency.
From the above discussion it should be clear that the quality control problems
can not be
solved in a systematic and satisfying way by independently concentrating on
any one of
the mould, the submerged nozzle and the mould oscillating unit. The above
three
elements are so interconnected in the continuous casting process that to solve
the above-
mentioned quality problems, the three elements must be treated together. Thus,
to find an
effective solution it is important to concentrate on the mould, the submerged
nozzle, and
the mould oscillating unit as a single group.
Summary of the Invention
It is an object of the present invention to provide a casting unit that
overcomes the above-
identified problems when continuously casting thin slabs at high speed.
The improved casting unit of the present invention generally has the
characteristics
recited in claim 1.
Brief Description of the Several Views of the Drawings
Additional advantages and characteristics of a casting unit according to the
present
invention will be evident from the following detailed description of the
preferred
embodiment when examined in combination with the attached drawings, wherein:
FIG. 1 shows a diagrammatic side view of a casting unit according to the
invention
illustrating the various components of the casting unit;
2

CA 02269130 2005-09-13
FIG. 2 shows a view of only the sole upper part of the mould, combined with
the
submerged nozzle, in the direction of arrow II of FIG. 1;
FIGS. 3a-3c show the same diagrammatic view, in a cross-section, taken along
line III--
III of FIG. 2, at the meniscus, or top surface of the liquid steel level, in
order to
particularly show the geometrical relation that the mould and the submerged
nozzle must
satisfy to form a casting unit according to the present invention;
FIG. 4 shows a perspective view of the mould, diagrammatically represented
with respect
to a set of Cartesian axes;
FIGS. Sa and Sb show two diagrammatic views of the mould of FIG. 4, wherein
the ideal
envelope of the cooling system pipes is represented in longitudinal section
through a
plane parallel to the y and z axes of FIG. 4, and along line B--B of FIG. Sa,
respectively.
Detailed Description of the Invention
With reference to the drawings, FIG. 1 is a diagrammatic view of the casting
unit
according to the present invention which preferably includes a mould 1, a dip
casting
nozzle 2 (hereinafter always referred to as "submerged nozzle") and an
oscillator 3
(which is hydraulically driven and is fastened to the mould body so as not to
interfere
with the casting line). FIG. 1 shows the area occupied by the liquid steel
between the
submerged nozzle 2 and the surrounding copper walls (i.e. the two "channels"
4).
Many of the problems that occur when casting thin slabs (as opposed to
traditional
thicker slabs) result from the fact that (assuming that the volumetric flow
rate of molten
steel is constant) a reduction in slab thickness increases the amount of slab
surface
contacting the mould walls within a given amount of time and thus, an
increased amount
of lubricating "slag" is necessary.
3

CA 02269130 2005-09-13
Thus, the importance of forming the proper amount of lubricating slag
increases when the
thickness of the slabs is reduced because the slab contact surface is
inversely proportional
with the thickness of the slab. Thus, the thinner the slab is the greater the
amount of
contact between the liquid steel in the mould and the mould walls per unit
time. The
increased amount of contact between the liquid steel in the mould and the
mould walls
results in an increased need for slag. However, the interface in the mould
between the
molten steel and the casting powders (i.e., the area over which slag is
introduced) is
reduced along the middle portion of the top surface of the liquid steel where
the slag is
formed, due to the reduced thickness of the mould and area occupied by the
submersed
nozzle.
Although this problem may be partially solved by using specific casting
powders which
are capable of enhancing slag formation, conventionally configured submerged
nozzles
and mould walls are not able to maintain the required equilibrium between the
molten
slag formed by melting casting powders and the slag consumed by the slab
forming
process.
The thin mould of the present invention is capable of containing a reliable,
i.e.
sufficiently thick, submerged nozzle, and the mould preferably has its large
walls formed
with copper plates. The walls have a profile that (when viewed in the
horizontal plane,
around the meniscus level) exactly matches the profile of the submerged nozzle
and thus,
keeps a constant normal distance between the submerged nozzle and the walls.
The
relative geometry of the mould and the casting nozzle are a part of the
present invention.
To quantify the various geometries the following terms are used: A1, A2, S1
and S2.
Referring to FIG. 3b, the area A1 is the area between the casting nozzle and
the mould
walls directly above and below (as viewed in FIG. 36) the casting nozzle. The
length S 1
is the distance along the perimeter of the mould adjacent to area A 1.
Referring to FIG. 3c, the area A2 is generally equal to the total area of the
mould (as
viewed in FIG. 3c) subtracting area A1 and subtracting the area of the casting
nozzle (as
4

CA 02269130 2005-09-13
viewed in FIG. 3c). The length S2 is equal to the length of the perimeter of
the mould
subtracting S 1.
With reference to FIGS. 3a, 3b and 3c, a normal distance is chosen so that the
ratio A1/S1
(see FIG. 2) is similar to the ratio A2/S2. The present invention requires
that A 1 /S 1 is
approximately the same as A2/S2, measured outside the submerged nozzle region
(see
FIG. 3c). Thus the equation to be satisfied is:
0.9 < (A 1 /S 1 )/(A2/S2) < 1.1, and preferably=1
For example, for a mould being 1300x65 mm and having a submerged nozzle 300 mm
wide (with a reliable thickness of 60 mm as indicated in FIGS. 3b and 3c), the
optimal
ratio A1/Sl=A2/S2 is equal to 30. Such a ratio (once the dimensions of the
submerged
nozzle and the thickness of the smaller sides have been fixed) may be used for
determining the desired mould profile in the horizontal plane at the meniscus
level of the
liquid steel in the mould. Alternatively, if the dimensions of the mould
profile are known,
the ratio may be used for determining the required profile of the submerged
nozzle.
This geometrical configuration is also important for the flow of molten steel
in the
meniscus region, since the "channels" 4 which are located between the
submerged nozzle
and the copper mould walls will be sufficiently large to prevent vortex
formation due to
the acceleration of the streams converging in the middle from the mould's
smaller sides.
Vortex formation often causes the casting powders to be trapped, resulting in
the
improper generation of slag which results in the above-mentioned defects.
Preferably, the mould used in the casting unit of the present invention has a
bend in the
longitudinal direction, as detailed in European patent 0705152 (which
disclosed a mould
having a nearly infinite bending radius in the upper region for a better
arrangement of the
submerged nozzle), while providing for the bending of the slab being formed
inside the
mould with an exit on the arc-shaped casting guide other than the vertical.
This
advantageously reduces the height of the casting unit and accordingly the
ferrostatic
5

CA 02269130 2005-09-13
forces and the risk of slab swellings. According to the aforementioned patent
application,
the bending is graded in a progressive and uniform way from the infinite
radius of the
mould inlet to the bending radius R~ corresponding to the casting guide (FIG.
1 ), thereby
preventing both exceeding stresses on the solidified external shell of the
slab and the
possibility of an imperfect contact with the copper walls of the mould.
In order to adequately solve the above problems, the unit for cooling the
mould plates is
especially important and has to be capable of withstanding the high heat
fluxes typically
occurring in the formation of thin slabs (up to 3 MW/m2, average value on the
entire
cooling surface of the mould). At the same time, cooling is preferably
enhanced in the
meniscus region in order to prevent copper cracks and to prevent thermal
stresses from
forming in the slab.
With reference to FIG. 4, when considering the specific normal heat flux (dq")
between
the surface of the casting product and the mould, the following equation can
be used:
dq" =dq/dA [W/m2
This heat flux is partially a function of the local surface temperature on the
hot surface of
the copper plates, which is dependent upon the distance from the pipes wherein
the
cooling water flows.
Referring to FIG. 4, (a system of Cartesian axes x, y, z is superimposed on
the mould,
wherein the z axis extends toward the mould bottom and the complex surface
formed by
the mould is defined as f(x,y,z)=0) the local surface temperature varies
according to the
equation t=t[f(x,y,z)].
The heat flux dq~, must be kept as constant as possible along a horizontal
line (wherein
z=z~,) belonging to the mould surface (i.e. the temperature t must be kept
virtually
constant along such a line) whereby:
6

CA 02269130 2005-09-13
t=t~.f~x>Y~ zo~J = to
The above equation is obtained by keeping every point of the copper hot
surface at
generally the same normal distance Nd (which is measured along the
perpendicular with
respect to the hot surface) from the ideal surface envelope E of all the ends
of the cooling
pipes W (FIGS. Sa, Sb). Thus, Nd is constant, and experimentally it has been
found that
this constant value optimally ranges from 10 to 25 mm in order to have the
aforementioned conditions for the cooling system.
As for the submerged nozzle, besides the aforementioned dimensional conditions
with
respect to the mould, it is preferably designed to allow the optimal behavior
of the molten
steel flow, while taking into account gradual shell formation and the life of
the
submerged nozzle. In fact, it is known that, upon decreasing of the slab
thickness, the
problems concerning the motions of the liquid inside the mould increase,
resulting in the
formation of stationary waves in the meniscus region and thus a local
reduction of the
thickness of the liquid slag, which adversely affects the lubrication and the
insulation of
the shell of the slab being solidified.
The submerged nozzle for thin slabs, which is detailed in patent application
PCT/IT-
97/00135, has geometrical characteristics which result in castings having a
low energy, a
high probability of energy dissipation inside the liquid volume of the slab,
improved flow
(thereby preventing vortex formation and powder trapping), and an improved
liquid metal
level control in the mould. Furthermore the feed is steady, the flow is
substantially split
into two streams and the surfaces inside the submerged nozzle are preserved to
keep the
same shape as at the beginning of the continuous casting. Since oxide deposits
are
negligible, these good flow conditions result in a reduced amount of external
mechanical
erosion of the nozzle in the meniscus region.
According to the present invention, the optimized design of the apparatus
includes the
7

CA 02269130 2005-09-13
ratio between the amplitude of the stationary wave (measured in mm) and the
casting
speed in m/min never exceeding 5, with an average value of 3.3.
Furthermore, the standard deviation measured for the sampled signal of the
cast level in
the mould (ML), indicated as stdDEV(ML), is usually within the following
range:
stdDEV(ML)=0.7-1.5 mm
Finally, the oscillator 3 is a critical factor for the surface quality of the
slab and the
reliability of the continuous casting process. With reference to FIG. 1, the
oscillator 3
may be formed of a framework 3a being hinged to the floor and driven by a
hydraulic
servocontrol 5. Framework 3a is also hinged to a mould support 3b, thus
forming a kind
of quadrilateral together with a set of 3c fitted into both ends.
The control of the oscillator is managed by a program logic controller
allowing the
oscillator to change the oscillation parameters of the wave shape (e.g. the
wave
amplitude) between ~2 and ~10 mm. The controller continuously records the
actual value
of the casting speed so as to control the oscillation frequency based on the
above
parameters. Maximum oscillation frequencies have been obtained as high as 480-
520
strokes/mm, for the first natural frequency of the entire dynamic system of
16.7 Hz. The
flexibility is such that the oscillation parameters may be adjusted to obtain
an optimal
lubrication and surface quality depending on the casting speed.
Alternatively, the oscillator may be of the so-called "resonance" type with
the mould
being directly mounted upon flexure springs (without any lever system) and
oscillated by
a hydraulic servocontrol at a frequency close to the natural frequency of the
elastic
system.
Possible additions and/or modifications may be made by those skilled in the
art to the
above described and illustrated embodiment without departing from the scope of
the
invention. In particular, the mould itself may have in the vertical plane a
profile other
8

CA 02269130 2005-09-13
than the one disclosed in European patent 0705152 and the submerged nozzle may
be
different than the one disclosed and claimed in application PCT/IT-97/00135,
provided
that the aforementioned geometrical relations are complied with.
9

Representative Drawing
A single figure which represents the drawing illustrating the invention.
Administrative Status

2024-08-01:As part of the Next Generation Patents (NGP) transition, the Canadian Patents Database (CPD) now contains a more detailed Event History, which replicates the Event Log of our new back-office solution.

Please note that "Inactive:" events refers to events no longer in use in our new back-office solution.

For a clearer understanding of the status of the application/patent presented on this page, the site Disclaimer , as well as the definitions for Patent , Event History , Maintenance Fee  and Payment History  should be consulted.

Event History

Description Date
Inactive: Expired (new Act pat) 2017-11-12
Inactive: Late MF processed 2016-03-29
Letter Sent 2015-11-12
Grant by Issuance 2006-10-10
Inactive: Cover page published 2006-10-09
Inactive: Final fee received 2006-08-01
Pre-grant 2006-08-01
Inactive: IPC from MCD 2006-03-12
Inactive: IPC from MCD 2006-03-12
Notice of Allowance is Issued 2006-02-28
Letter Sent 2006-02-28
4 2006-02-28
Notice of Allowance is Issued 2006-02-28
Inactive: Approved for allowance (AFA) 2005-11-22
Amendment Received - Voluntary Amendment 2005-09-13
Revocation of Agent Requirements Determined Compliant 2005-08-03
Appointment of Agent Requirements Determined Compliant 2005-08-03
Inactive: Office letter 2005-08-03
Inactive: Office letter 2005-08-03
Revocation of Agent Request 2005-07-25
Appointment of Agent Request 2005-07-25
Inactive: S.30(2) Rules - Examiner requisition 2005-04-14
Revocation of Agent Request 2005-03-01
Appointment of Agent Request 2005-03-01
Letter Sent 2002-10-24
Request for Examination Received 2002-09-18
Request for Examination Requirements Determined Compliant 2002-09-18
All Requirements for Examination Determined Compliant 2002-09-18
Amendment Received - Voluntary Amendment 2002-09-18
Inactive: Cover page published 1999-06-17
Inactive: First IPC assigned 1999-05-19
Letter Sent 1999-05-19
Inactive: Notice - National entry - No RFE 1999-05-19
Inactive: IPC assigned 1999-05-19
Application Received - PCT 1999-05-18
Application Published (Open to Public Inspection) 1998-05-22

Abandonment History

There is no abandonment history.

Maintenance Fee

The last payment was received on 2005-10-26

Note : If the full payment has not been received on or before the date indicated, a further fee may be required which may be one of the following

  • the reinstatement fee;
  • the late payment fee; or
  • additional fee to reverse deemed expiry.

Patent fees are adjusted on the 1st of January every year. The amounts above are the current amounts if received by December 31 of the current year.
Please refer to the CIPO Patent Fees web page to see all current fee amounts.

Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
GIOVANNI ARVEDI
Past Owners on Record
ANDREA BIANCHI
LUCIANO MANINI
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
Documents

To view selected files, please enter reCAPTCHA code :



To view images, click a link in the Document Description column (Temporarily unavailable). To download the documents, select one or more checkboxes in the first column and then click the "Download Selected in PDF format (Zip Archive)" or the "Download Selected as Single PDF" button.

List of published and non-published patent-specific documents on the CPD .

If you have any difficulty accessing content, you can call the Client Service Centre at 1-866-997-1936 or send them an e-mail at CIPO Client Service Centre.


Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Representative drawing 1999-06-16 1 5
Description 1999-04-18 6 354
Abstract 1999-04-18 1 60
Claims 1999-04-18 1 57
Drawings 1999-04-18 4 64
Cover Page 1999-06-16 2 67
Description 2005-09-12 9 342
Claims 2005-09-12 2 69
Abstract 2005-09-12 1 25
Representative drawing 2005-12-06 1 9
Cover Page 2006-09-13 1 48
Reminder of maintenance fee due 1999-07-12 1 112
Notice of National Entry 1999-05-18 1 194
Courtesy - Certificate of registration (related document(s)) 1999-05-18 1 116
Reminder - Request for Examination 2002-07-14 1 128
Acknowledgement of Request for Examination 2002-10-23 1 176
Commissioner's Notice - Application Found Allowable 2006-02-27 1 162
Maintenance Fee Notice 2015-12-23 1 171
Late Payment Acknowledgement 2016-03-28 1 162
Late Payment Acknowledgement 2016-03-28 1 162
PCT 1999-04-18 9 268
Fees 2003-10-15 1 34
Fees 2002-10-14 1 31
Fees 2000-10-10 1 40
Fees 2001-10-16 1 41
Fees 1999-11-03 1 39
Fees 2004-10-25 1 31
Correspondence 2005-02-28 1 39
Correspondence 2005-07-24 2 79
Correspondence 2005-08-02 1 15
Correspondence 2005-08-02 1 18
Fees 2005-10-25 1 40
Correspondence 2006-07-31 2 57
Fees 2014-11-05 1 25