Language selection

Search

Patent 2375897 Summary

Third-party information liability

Some of the information on this Web page has been provided by external sources. The Government of Canada is not responsible for the accuracy, reliability or currency of the information supplied by external sources. Users wishing to rely upon this information should consult directly with the source of the information. Content provided by external sources is not subject to official languages, privacy and accessibility requirements.

Claims and Abstract availability

Any discrepancies in the text and image of the Claims and Abstract are due to differing posting times. Text of the Claims and Abstract are posted:

  • At the time the application is open to public inspection;
  • At the time of issue of the patent (grant).
(12) Patent: (11) CA 2375897
(54) English Title: LIQUID DISCHARGE METHOD AND LIQUID DISCHARGE APPARATUS
(54) French Title: METHODE D'EJECTION DE LIQUIDE ET APPAREIL CORRESPONDANT
Status: Expired and beyond the Period of Reversal
Bibliographic Data
(51) International Patent Classification (IPC):
  • B41J 2/04 (2006.01)
(72) Inventors :
  • KASHINO, TOSHIO (Japan)
  • ISHINAGA, HIROYUKI (Japan)
  • YOSHIHIRA, AYA (Japan)
  • KUDO, KIYOMITSU (Japan)
  • ASAKAWA, YOSHIE (Japan)
  • TANEYA, YOICHI (Japan)
  • SUGIYAMA, HIROYUKI (Japan)
  • SHIMAZU, SATOSHI (Japan)
(73) Owners :
  • CANON KABUSHIKI KAISHA
(71) Applicants :
  • CANON KABUSHIKI KAISHA (Japan)
(74) Agent: SMART & BIGGAR LP
(74) Associate agent:
(45) Issued: 2003-09-16
(22) Filed Date: 1997-06-06
(41) Open to Public Inspection: 1997-12-07
Examination requested: 2002-03-20
Availability of licence: N/A
Dedicated to the Public: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): No

(30) Application Priority Data:
Application No. Country/Territory Date
8-145683 (Japan) 1996-06-07
9-144013 (Japan) 1997-06-02

Abstracts

English Abstract


A liquid discharge method far discharging a liquid
through a discharge port for discharging the liquid
utilizing a bubble by displacing a movable separation
film for always substantially separating a first liquid
flow path in communication with said discharge port for
discharging the liquid from a second liquid flow path
comprising a bubble-generating region for generating
the bubble in said liquid, on the upstream side of said
discharge port with respect to flow of the liquid in
said first liquid flow path, comprises a step of
displacing a downstream portion of said movable
separation film toward said discharge port relatively
more than an upstream portion of said movable
separation film with respect to a direction of the flow
of the liquid.


Claims

Note: Claims are shown in the official language in which they were submitted.


-136-
What is claimed is:
1. A liquid discharging method for discharging liquid from a
discharge port by displacing, using a bubble generated at a
bubble generation area, a continuous movable separation film
without an end near the bubble generation area, the continuous
movable separation film substantially separating from each other
a first liquid flow path communicating with the discharge port
for discharging the liquid and a second liquid flow path having
the bubble generation area, said method comprising the steps of:
generating a bubble in the bubble generation area; and
displacing the continuous movable separation film from an
initial state substantially without stretch in accordance with
said generating step to discharge the liquid from the discharge
port,
wherein, in the initial state, at least a part of the
continuous movable separation film projects into the second
liquid flow path.
2. A liquid discharging method according to claim 1, wherein the
discharge port is provided downstream of the bubble generation
area with respect to a flow direction of the liquid in the first
liquid flow path.
3. A liquid discharging method according to claim 2, wherein the
liquid is discharged in a direction parallel to the flow
direction.
4. A liquid discharging method according to claim 1, wherein the
liquid is discharged in a direction perpendicular to the flow
direction.

-137-
5. A liquid discharging method according to claim 1, wherein
the movable separation film has a maximum volume caused by
displacement of a convex portion, and the maximum volume is
less than a maximum expansion of the bubble.
6. A liquid discharging method according to claim 1, wherein a
distance by which the movable separation film projects into
the first liquid flow path or the second liquid flow path
increases moving downstream along a length of the movable
separation film toward the discharge port.
7. A liquid discharging head comprising:
a first liquid flow path communicating with a discharge
port
for discharging liquid;
a second liquid flow path having a bubble generation area
for generating a bubble in the liquid; and
a continuous movable separation film substantially
separating from each other said first liquid flow path and
said second liquid flow path, the continuous movable
separation film being displaced from an initial state by the
bubble generated at the bubble generation area to discharge
the liquid from the discharge port,
wherein the continuous movable separation film comprises
a thin film without substantial elasticity and without an end
near the bubble generation area, and
when the movable separation film is in the initial state,
at least a part of the continuous movable separation film
projects into said second liquid flow path.
8. A liquid discharging head according to claim 7, wherein the
discharge port is provided downstream of the bubble generation
area with respect to a flow direction of the liquid in said
first liquid flow path.

Description

Note: Descriptions are shown in the official language in which they were submitted.


CA 02375897 2002-03-20
LIQUID DISCHARGE METHOD AND LIQUID DISCHARGE APPARATUS
BACKGROUND OF THE INVENTION
Field of the Invention
The present invention relates to a liquid
discharge method and a liquid discharge apparatus for
discharging a desired liquid by generation of bubble by
thermal energy or the like and, more particularly, to a
liquid discharge method and a liquid discharge
apparatus using a movable separation film arranged to
be displaced utilizing the generation of bubble.
It is noted here that "recording" in the present
invention means not only provision of an image having
meaning, such as characters or graphics, on a recorded
medium, but also provision of an image having no
meaning, such as patterns, on the medium.
Related Background Art
One of the conventionally known recording methods
is an ink jet recording method for imparting energy~of
heat or the like to ink so as to cause a state change
accompanied by a quick volume change of ink (generation
of bubble), thereby discharging the ink through an
discharge port by acting force based on this state
change, and depositing the ink on a° recorded medium,
thereby forming an image, which is so called as a
bubble jet recording method. A recording apparatus
using this bubble jet recording method is normally

CA 02375897 2002-03-20
- 2 -
provided, as disclosed in the bulletin of Japanese
Patent Publication No. 61-59911 or in the bulletin of
Japanese Patent Publication No. 61-59914, with an
discharge port for discharging the ink, an ink flow
path in communication with this discharge port, and a
heat-generating member (an electrothermal transducer)
as energy generating means for discharging the ink
located in the ink flow path.
The above recording method permits high-quality
images to be recorded at high speed and with low noise
and in addition, because a head for carrying out this
recording method can have discharge ports for
discharging the ink as disposed in high density, it has
many advantages; for example, high-resolution recorded
images or even color images can be obtained readily by
compact apparatus. Therefore, this bubble jet
recording method is used in many office devices
including printers, copiers, facsimile machines, and so
on in recent years and further is becoming to be used
for industrial systems such as textile printing
apparatus.
On the other hand, the conventional bubble jet
recording method sometimes experienced occurrence of
deposits due to scorching of ink on the surface of the
heat-generating member, because heating was repeated in
a contact state of the heat-generating member with the
ink. In the case of the liquid to be discharged being

CA 02375897 2002-03-20
3 _
a liquid easy to deteriorate due to heat or a liquid
not easy to generate a sufficient bubble, good
discharge is not achieved in some cases by formation of
bubble by direct heating with the aforementioned heat-
s generating member.
Against it, the present applicant proposed a
method for discharging an discharge liquid by
generating a bubble in a bubble-generating liquid by
thermal energy through a flexible film for separating
the bubble-generating liquid from the discharge liquid,
in the bulletin of Japanese Laid-open Patent
Application No. 55-81172. The configuration of the
flexible film and the bubble-generating liquid in this
method is such that the flexible film is formed in a
part of nozzle, whereas the bulletin of Japanese Laid-
open Patent Application No. 59-26270 discloses the
configuration using a large film for separating the
entire head into upper and lower spaces. This large
film is provided for the purpose of being placed
between two plates forming the liquid paths and thereby
preventing the liquids in the two liquid paths from
being mixed with each other.
On the other hand, countermeasures for giving a
specific feature to the bubble-generating liquid itself
and taking bubble-generating characteristics into
consideration include the one disclosed in the bulletin

CA 02375897 2002-03-20
of Japanese Laid-open Patent Application No. 5-229122
using a lower-boiling-point liquid than the boiling
point of the discharge liquid, and the one disclosed in
the bulletin of Japanese Laid-open Patent Application
No. 4-329148 using a liquid having electric
conductivity as the bubble-generating liquid.
However, the liquid discharge methods using the
conventional separation film as described above are the
structure of dust separating the bubble-generating
liquid from the discharge liquid or simply an
improvement of the bubble-generating liquid itself, and
they are not at the level of practical use yet.
SUMMARY OF THE INVENTION
The present inventors have researched mainly
liquid droplets discharged in discharge of liquid
droplet using the separation film and came to the
conclusion that the efficiency of liquid discharge
based on formation of bubble by thermal energy was
lowered because of intervention of change of the
separation film, so that it had not been applied to
practical use.
Therefore, the present inventors came to study the
liquid discharge method and apparatus that achieved the
higher level of liquid discharge while taking advantage
of the effect by the separation function of the
separation film.

CA 02375897 2002-03-20
- 5 -
The present invention has been accomplished during
this study and provides breakthrough liquid discharge
method and apparatus that are improved in the discharge
efficiency for discharge of liquid droplet and that
stabilize and enhance the volume of liquid droplet
discharged or the discharge rate.
The present invention can improve the discharge
efficiency in the liquid discharge method and apparatus
using a liquid discharging head comprising a first
liquid flow path for discharge liquid in communication
with an discharge port, a second liquid flow path
containing a bubble-generating liquid so as to be
capable of supplying or moving the bubble-generating
liquid and having a bubble-generating region, and a
movable separation film for separating the first and
second liquid flow paths from each other, and having a
region of displacement of the movable separation film
upstream of the discharge port with respect to a
direction of flow of the discharge liquid in the first
liquid flow path.
Particularly, the present inventors found out the
following problem. When the space becoming the bubble-
generating region is a small space, that is, when the
bubble-generating region itself, though being formed on
the upstream side of the discharge port with respect to
the direction of flow of the discharge liquid, has the
width and length close to those of the heat-generating

CA 02375897 2002-03-20
- 6 -
portion, in generation of bubble in the bubble-
generating region, the movable film is displaced with
generation of bubble only in the perpendicular
direction to the direction of discharge of the
discharge liquid, so that sufficient discharge rates
cannot be attained. This resulted in the problem that
the efficient discharge operation was not achieved.
Noting that the cause of this problem is that the same
bubble-generating liquid is always used repetitively
only in the small space closed, the present invention
also realizes the efficient discharge operation.
A first object of the present invention is to
provide a liquid discharge method and a liquid
discharge apparatus employing the structure for
substantially separating or, more preferably, perfectly
separating the discharge liquid from the bubble-
generating liquid by the movable film, wherein in
deforming the movable film by force generated by
pressure of bubble generation to transmit the pressure
to the discharge liquid, the pressure is prevented from
leaking to upstream and the pressure is guided toward
the discharge port, whereby high discharge force can be
achieved without degrading the discharge efficiency.
A second object of the present'invention is to
provide a liquid discharge method and a liquid
discharge apparatus that can decrease an amount of
deposits depositing on the heat-generating member and

CA 02375897 2002-03-20
that can discharge the liquid at high efficiency
without thermally affecting the discharge liquid, by
the above-stated structure.
A third object of the present invention is to
provide a liquid discharge method and a liquid
discharge apparatus having wide freedom of selection,
irrespective of the viscosity of the discharge liquid
and the formulation of material thereof.
For achieving the above objects, the present
invention provides a liquid discharge method having a
step of displacing a movable separation film for always
substantially separating a first liquid flow path in
communication with an discharge port for discharging a
liquid from a second liquid flow path comprising a
bubble-generating region for generating a bubble in
said liquid, on the upstream side of said discharge
port with respect to flow of the liquid in said first
liquid flow path,
said liquid discharge method comprising a step of
displacing a downstream portion of said movable
separation film toward said discharge port relatively
more than an upstream portion of said movable
separation film with respect to a direction of the flow
of said liquid.
Here, if the above step is carried out after
midway of a growing process of bubble, a further
increase will be achieved in the discharge amount. If

CA 02375897 2002-03-20
the above step is carried out continuously
substantially after the initial stage of the growing
process of bubble, a further increase will be achieved
in the discharge rate.
The displacement of the movable separation film
can be controlled as desired or as stabilized by
direction regulating means for regulating the
displacement of the movable separation film in the
above step.
Specific structures for carrying out the above
displacing step, which is the feature of the present
invention as described above, include those in the
embodiments described hereinafter. In addition, the
present invention involves all that can achieve the
above displacing step by other structures included in
the technological concept of the present invention.
Further, if the shape of the movable separation
film is preliminarily determined or if the movable
separation film is provided with a slack portion, the
movable separation film itself will not need to extend
with generation of bubble, which raises the discharge
efficiency and which permits the movable separation
film itself to regulate the displacement.
If the displacement of the movable separation film
is regulated by regulating the growth of bubble in the
second liquid flow path, direct action will take place
on the bubble itself, whereby the displacement of the

CA 02375897 2002-03-20
g _
movable separation film is regulated from the initial
stage of generation of bubble.
Here is a typical example of the structure of the
device according to the present invention. The
"direction regulating means" stated herein includes all
arrangements of the movable separation film itself (for
example, distribution of modulus of elasticity, a
combination of a deformably extending portion with a
non-deforming portion, etc.), all arrangements of the
second liquid flow path itself (control of the heat-
generating member or the bubble itself, etc.), an
additional member acting on the movable separation
film, structures of the first liquid flow path, and all
combinations thereof. The typical structure according
to the present invention is a liquid discharge
apparatus having at least a first liquid flow path in
communication with an discharge port for discharging a
liquid, a second liquid flow path comprising a bubble-
generating region for generating a bubble in said
liquid, and a movable separation film for always
substantially separating said first liquid flow path
from said second liquid flow path,
said liquid discharge apparatus comprising
direction regulating means for displacing said movable
separation film on an upstream side of said discharge
port with respect to flow of the liquid in said first
liquid flow path and for displacing a downstream

CA 02375897 2002-03-20
- 10 -
portion of said movable separation film toward said
discharge port relatively more than an upstream portion
of said movable separation film with respect to a
direction of the flow of said liquid.
In the present invention of the above structure,
the movable separation film provided above the bubble-
generating region is displaced into the first liquid
flow path with generation and growth of the bubble in
the bubble-generating region. On that occasion, the
downstream portion of the movable separation film is
displaced into the first liquid flow path more than the
upstream portion of the movable separation film, so
that the pressure due to the generation of bubble is
guided toward the discharge port of the first liquid
flow path. By this, the liquid in the first liquid
flow path is discharged efficiently through the
discharge port with generation of bubble.
In the case wherein the deforming region of the
movable separation film is provided with a slack
portion, the slack portion is displaced in a curved
shape with generation and growth of bubble and,
therefore, the volume of the bubble acts more
effectively on deformation of the movable separation
film, thereby discharging the liquid more efficiently.
In the case wherein a movable member is provided
adjacent to the movable separation film on the first
liquid flow path side of the movable separation film

CA 02375897 2002-03-20
- 11 -
and wherein the movable member has a free end on the
downstream side of an upstream edge of a portion facing
the bubble-generating region and a fulcrum on the
upstream side of the free end, the displacement of the
movable separation film to the second liquid flow path
is suppressed upon collapse of bubble, which prevents
movement of liquid to upstream, thereby improving
refilling characteristics and decreasing crosstalk.
When the shape of the second liquid flow path is
one capable of readily guiding the pressure due to the
bubble generated in the bubble-generating region to the
discharge port, the liquid in the first liquid flow
path can be discharged through the discharge port
efficiently by generation of bubble.
When the shape of the first liquid flow path is
such that the height is smaller upstream than
downstream, the downstream portion of the movable
separation film is displaced more into the first liquid
flow path than the upstream portion of the movable
separation film, whereby the pressure due to the
generation of bubble is guided to the discharge port of
the first liquid flow path, so that the liquid in the
first liquid flow path is discharged efficiently
through the discharge port by the generation of bubble.
When the movable separation film is formed so that
the thickness thereof on the downstream side is smaller
than that on the upstream side, the movable separation

CA 02375897 2002-03-20
- 12 -
film becomes easier to deform toward the discharge port
with growth of bubble in the bubble-generating region,
whereby the liquid in the first liquid flow path is
discharged efficiently through the discharge port.
When the movable separation film is provided with
a convex portion which projects into the second liquid
flow path upon non-generation of bubble and which
projects into the first liquid flow path upon
generation of bubble, the pressure due to generation of
bubble in the bubble-generating region is guided to the
discharge port of the first liquid flow path by the
convex portion, whereby the liquid in the first liquid
flow path is discharged efficiently through the
discharge port by the generation of bubble. Further,
if the volume inside the convex portion is smaller than
the maximum expansion volume of the bubble generated in
the bubble-generating region, the amount of
displacement of the convex portion will be kept
constant even with dispersion in the expansion volume
of bubble due to the discharge characteristics of
liquid, thus realizing good discharge without
dispersion between nozzles.
BRIEF DESCRIPTION OF THE DRAWINGS
Figs. lA, 1B, 1C, 1D and lE are cross-sectional
views along the flow path direction for explaining the
first embodied form of the liquid discharge method

CA 02375897 2002-03-20
- 13 -
according to the present invention;
Figs. 2A, 2B, 2C, 2D and 2E are cross-sectional
views along the flow path direction for explaining the
second embodied form of the liquid discharge method
according to the present invention;
Figs. 3A, 3B, and 3C are cross-sectional views
along the flow path direction for explaining steps of
displacement of the movable separation film in the
liquid discharge method of the present invention;
Figs. 4A, 4B and 4C are cross-sectional views
along the flow path direction to show the first
embodiment of the liquid discharge method and the
liquid discharge apparatus according to the present
invention, wherein Fig. 4A is a drawing to show a state
upon non-generation of bubble, Fig. 4B is a drawing to
show a state upon generation of bubble (upon
discharge), and Fig. 4C is a drawing to show a state
upon collapse of bubble;
Figs. 5A and 5B are longitudinal cross-sectional
views each to show a structural example of the liquid
discharge apparatus of the present invention, wherein
Fig. 5A is a drawing to show a device with a protecting
film described hereinafter and Fig. 5B is a drawing to
show a device without the protecting film;
Fig. 6 is a drawing to show the waveform of
voltage applied to an electric resistance layer shown
in Figs. 5A and 5B;

CA 02375897 2002-03-20
_ 14 -
Fig. 7 is a schematic drawing to show a structural
example of the liquid discharge apparatus according to
the present invention;
Fig. 8 is an exploded, perspective view to show a
structural example of the liquid discharge apparatus
according to the present invention;
Figs. 9A, 9B and 9C are drawings to show the
second embodiment of the liquid discharge apparatus
according to the present invention, wherein Fig. 9A is
a cross-sectional view along the flow path direction
upon non-generation of bubble, Fig. 9B is a cross-
sectional view along the flow path direction upon
generation of bubble, and Fig. 9C is a drawing obtained
by observing the first flow path from the second flow
path side of the drawing shown in Fig. 9A;
Figs. 10A, lOB, lOC, lOD, l0E and lOF are cross-
sectional views along the flow path direction to show
the second embodiment of the liquid discharge method
and the liquid discharge apparatus according to the
present invention;
Figs. 11A and 11B are drawings to show
characteristics of the movable separation film used in
the liquid discharge apparatus of the present
invention, wherein Fig. 11A is a drawing to show the
relation between pressure f of a bubble generated in
the bubble-generating region and stress F of the
movable separation film against it and Fig. 11B is a

CA 02375897 2002-03-20
- 15 -
graph to show characteristics of the stress F of the
movable separation film against volume change of bubble
shown in Fig. 11A;
Figs. 12A and 128 are drawings to show the fourth
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 12A is a cross-
sectional view along the flow path direction and Fig.
12B is a top plan view;
Figs. 13A and 13H are cross-sectional views along
the flow path direction to show the fifth embodiment of
the liquid discharge method and the liquid discharge
apparatus according to the present invention, wherein
Fig. 13A is a drawing to show a state upon non-
generation of bubble and Fig. 13B is a drawing to show
a state upon generation of bubble (upon discharge);
Fig. 14 is a perspective view, partly broken, of
the liquid discharge apparatus shown in Figs. 13A and
13B;
Figs. 15A,. 15B, 15C and 15D are drawings for
explaining the operation of the liquid discharge
apparatus shown in Figs. 13A, 13B and Fig. 14;
Figs. 16A, 16B and 16C are drawings for explaining
the relationship of location between thick portion 205a
of movable separation film 205 and 'second liquid flow
path 204 in the liquid discharge apparatus shown in
Figs. 13A, 13B to Figs. 15A, 15B, 15C and 15D, wherein
Fig. 16A is a top plan view of the thick portion 205a,

CA 02375897 2002-03-20
- 16 -
Fig. 16B is a top plan view of the second liquid flow
path 204 without the movable separation film 205, and
Fig. 16C is a schematic view to show the relation of
location between the thick portion 205a and the second
liquid flow path 204 as superimposed;
Fig. 17 is a schematic view to show a structural
example of the liquid discharge apparatus according to
the present invention;
Fig. 18 is an exploded, perspective view to show a
structural example of the liquid discharge apparatus
according to the present invention;
Figs. 19A, 19B, 19C, 19D and 19E are drawings for
explaining steps for producing the movable separation
film in the liquid discharge apparatus shown in Figs.
13A, 13B to Fig. 18;
Figs. 20A and 20B are cross-sectional views along
the flow path direction to show the sixth embodiment of
the liquid discharge method and the liquid discharge
apparatus according to the present invention, wherein
Fig. 20A is a drawing to show a state upon non-
generation of bubble and Fig. 20B is a drawing to show
a state upon generation of bubble (upon discharge);
Figs. 21A, 21H, 21C and 21D are drawings for
explaining the liquid discharge method in a
modification of the liquid discharge apparatus shown in
Figs. 20A and 20B;
Figs. 22A and 22B are cross-sectional views along

CA 02375897 2002-03-20
- 17 -
the flow path direction to show the seventh embodiment
of the liquid discharge apparatus according to the
present invention, wherein Fig. 22A is a drawing to
show a state upon non-generation of bubble and Fig. 22H
is a drawing to show a state upon generation of bubble
( upon discharge ) ;
Figs. 23A and 23B are cross-sectional views along
the flow path direction to show the eighth embodiment
of the liquid discharge method and the liquid discharge
apparatus according to the present invention, wherein
Fig. 23A is a drawing to show a state upon non-
generation of bubble and Fig. 23B is a drawing to show
a state upon generation of bubble (upon discharge);
Figs. 24A and 24B are cross-sectional views along
the flow path direction to show the ninth embodiment of
the liquid discharge method and the liquid discharge
apparatus according to the present invention, wherein
Fig. 24A is a drawing to show a state upon non-
generation of bubble and Fig. 24H is a drawing to show
a state upon generation of bubble (upon discharge);
Figs. 25A, 25H and 25C are drawings to show the
tenth embodiment of the liquid discharge apparatus
according to the present invention, wherein Fig. 25A is
a cross-sectional view along the flow path direction to
show a state upon non-generation of bubble, Fig. 25B is
a cross-sectional view along the flow path direction to
show a state upon generation of bubble (upon

CA 02375897 2002-03-20
- 18 -
discharge), and Fig. 25C is a drawing to show the
structure of the second liquid flow path;
Figs. 26A and 26B are cross-sectional views along
the flow path direction to show the eleventh embodiment
of the liquid discharge method and the liquid discharge
apparatus according to the present invention, wherein
Fig. 26A is a drawing to show a state upon non-
generation of bubble and Fig. 26B is a drawing to show
a state upon generation of bubble (upon discharge);
Figs. 27A and 27B are cross-sectional views along
the flow path direction to show modifications of the
liquid discharge apparatus shown in Figs. 26A and 26B,
wherein Fig. 27A is a drawing to show a modification in
which a part of the second liquid flow path wall is
formed in a stepped shape and Fig. 27B is a drawing to
show a modification in which a part of the second
liquid flow path wall is formed in a curved shape;
Figs. 28A and 28B are drawings to show the twelfth
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 28A is a top
plan view to show the positional relation between the
second liquid flow path and the heat-generating member
and Fig. 28H is a perspective view of the positional
relation of Fig. 28A and wherein the discharge port is
disposed on the left side in Fig. 28A;
Figs. 29A, 29B and 29C are drawings for explaining
the discharge operation in the liquid discharge

CA 02375897 2002-03-20
- 19 -
apparatus shown in Figs. 28A and 28B, wherein Fig. 29A
includes cross-sectional views along 29A - 29A shown in
Fig. 28A, Fig. 29B includes cross-sectional views along
29B - 29B shown in Fig. 28A, and Fig. 29C includes
cross-sectional views along 29C - 29C shown in Fig.
28A;
Figs. 30A, 30B and 30C are drawings to show
modifications of the liquid discharge apparatus shown
in Figs. 28A and 28H, wherein Fig. 30A is a drawing to
show a modification in which the width of the second
liquid flow path near the heat-generating member
gradually increases stepwise from upstream to
downstream, Fig. 30B is a drawing to show a
modification in which the width of the second liquid
flow path near the heat-generating member gradually
increases in a curved shape from upstream to
downstream, and Fig. 30C is a drawing to show a
modification in which the width of the second liquid
flow path near the heat-generating member gradually
increases in an opposite curved shape to that of Fig.
30B from upstream to downstream;
Figs. 31A, 31B, 31C, 31D and 31E are drawings for
explaining the operation of the liquid discharge
apparatus to show the thirteenth embodiment of the
liquid discharge apparatus according to the present
invention;
Figs. 32A, 32B, 32C and 32D are drawings for

CA 02375897 2002-03-20
- 20 -
explaining the relation of location among the heat-
generating member, the second liquid flow path, and a
movable separation film displacement regulating member
in the liquid discharge apparatus shown in Figs. 31A to
31E, wherein Fig. 32A is a drawing to show the
positional relation between the heat-generating member
and the second liquid flow path, Fig. 328 a.s a top plan
view of the movable separation film displacement
regulating member, Fig. 32C is a drawing to show the
relation of location among the heat-generating member,
the second liquid flow path, and the movable separation
film displacement regulating member, and Fig. 32D is a
drawing to show displaceable areas of the movable
separation film;
Fig. 33 is a cross-sectional view along the flow
path direction to show the fourteenth embodiment of the
liquid discharge apparatus according to the present
invention;
Figs. 34A, 34B, 34C and 34D are drawings for
explaining the operation of the liquid discharge
apparatus shown in Fig. 33;
Fig. 35 is a top plan view of the second liquid
flow path without the movable separation film, which is
a drawing for explaining the structure of the second
liquid flow path in the liquid discharge apparatus
shown in Fig. 33 and Figs. 34A, 34B, 34C and 34D;
Fig. 36 is a cross-sectional view along the flow

CA 02375897 2002-03-20
y - 21 -
path direction to show the fifteenth embodiment of the
liquid discharge apparatus according to the present
invention, which shows a state upon generation of
bubble;
Figs. 37A, 37B, 37C and 37D are drawings for
explaining the operation of the liquid discharge
apparatus shown in Fig. 36;
Fig. 38 is a cross-sectional view along the flow
path direction to show the sixteenth embodiment of the
liquid discharge method and the liquid discharge
apparatus according to the present invention, which
shows a state upon generation of bubble;
Fig. 39 is a cross-sectional view along the flow
path direction to show the seventeenth embodiment of
the liquid discharge method and the liquid discharge
apparatus according to the present invention, which
shows a state upon generation of bubble;
Figs. 40A and 40B are cross-sectional views along
the flow path direction to show the eighteenth
embodiment of the liquid discharge method and the
liquid discharge apparatus according to the present
invention, wherein Fig. 40A is a drawing to show a
state upon non-generation of bubble and Fig. 40B is a
drawing to show a state upon generation of bubble;
Fig. 41 is a cross-sectional view along the flow
path direction to show the nineteenth embodiment of the
liquid discharge method and the liquid discharge

CA 02375897 2002-03-20
- 22 -
apparatus according to the present invention, which
shows a state upon generation of bubble;
Figs. 42A and 42B are cross-sectional, schematic
views along the flow path direction to show the
twentieth embodiment of the liquid discharge method and
the liquid discharge apparatus according to the present
invention, wherein Fig. 42A is a drawing to show a
state upon non-discharge and Fig. 42B is a drawing to
show a state upon discharge;
Figs. 43A and 43B are cross-sectional views along
the flow path direction to show the twenty first
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 43A is a
lateral, cross-sectional view and Fig. 43B is a
longitudinal, cross-sectional view;
Figs. 44A and 44B are cross-sectional views along
the flow path direction to show the twenty second
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 44A is a
lateral, cross-sectional view and Fig. 44B is a
longitudinal, cross-sectional view;
Figs. 45A, 45B, 45C, 45D and 45E are drawings for
explaining a process for producing the movable
separation film shown in Figs. 44A 'and 44B;
Figs. 46A and 46B are cross-sectional views along
the flow path direction to show the twenty third
embodiment of the liquid discharge apparatus according

CA 02375897 2002-03-20
- 23 -
to the present invention, wherein Fig. 46A is a
lateral, cross-sectional view and Fig. 46B is a
longitudinal, cross-sectional view;
Figs. 47A, 47B, 47C, 47D and 47E are drawings for
explaining a process for producing the movable
separation film shown in Figs. 46A and 46B;
Figs. 48A and 48B are drawings to show a like form
of the movable separation film shown in Figs. 46A and
46B and Figs..47A, 47B, 47C, 47D and 47E, wherein Fig.
48A is a lateral, cross-sectional view and Fig. 48B is
a longitudinal, cross-sectional view and wherein the
discharge port is located on the left side in the
drawing;
Figs. 49A and 49B are cross-sectional views along
the flow path direction to show the twenty fourth
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 49A is a
lateral, cross-sectional view and Fig. 49B is a
longitudinal, cross-sectional view;
Figs. 50A and 50H are cross-sectional views along
the flow path direction to show the twenty fifth
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 50A is a
lateral, cross-sectional view and Fig. 50B is a
longitudinal, cross-sectional view;
Figs. 51A, 51H, 51C and 51D are drawings for
explaining a process for producing the movable

CA 02375897 2002-03-20
- 24 -
separation film shown in Figs. 50A and 50H; and
Figs. 52A and 52B are cross-sectional views along
the flow path direction to show an application example
wherein the present invention is applied to an
arrangement of the discharge port disposed on the
downstream side of the bubble-generating region so that
the liquid is discharged in the direction perpendicular
to the flow direction of the liquid in the first liquid
flow path, wherein Fig. 52A is a drawing to show a
state upon non-generation of bubble and Fig. 52B is a
drawing to show a state upon generation of bubble.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The embodiments of the present invention will be
described, but, prior thereto, the basic concept of
discharge, which is the basis of the present invention,
will be described with two embodied forms.
Figs. lA to lE through Figs. 3A to 3C are drawings
for explaining embodiments of the liquid discharge
method according to the present invention, wherein the
discharge port is disposed in the end area of the first
liquid flow path and wherein the displaceable area of
the movable separation film capable of being displaced
according to growth of the bubble generated is present
on the upstream side of the discharge port (with
respect to the flow direction of the discharge liquid
in the first liquid flow path). The second liquid flow

CA 02375897 2002-03-20
- 25 -
path contains the bubble-generating liquid or is filled
with the bubble-generating liquid (preferably, capable
of being refilled therewith and more preferably,
capable of moving the bubble-generating liquid) and the
second liquid flow path has a generating region of
bubble.
In the present example, this bubble-generating
region is also located in the upstream area of the
discharge port with respect to the flow direction of
the discharge liquid described above. In addition, the
separation film is longer than the electrothermal
transducer forming the bubble-generating region and has
a movable area and a fixed portion, not illustrated,
between the upstream edge of the electrothermal
transducer with respect to the above flow direction and
a common liquid chamber of the first liquid flow path,
preferably, at the upstream edge. Accordingly, the
substantially movable range of the separation film is
understood from Figs. lA to lE through Figs. 3A to 3C.
The states of the movable separation film in these
figures are elements representing all obtained from the
elasticity and the thickness of the movable separation
film itself, or another additional structure.
(First embodied form)
Figs. lA to lE are cross-sectional views along the
flow path direction for explaining the first embodied
form (an example having the displacing step of the

CA 02375897 2002-03-20
_ 26 _
present invention from midway of the discharge step) of
the liquid discharge method according to the present
invention.
In the present form, as shown in Figs. lA to lE,
the inside of the first liquid flow path 3 in direct
communication with the discharge port 1 is filled with
a first liquid supplied from first common liquid
chamber 143 and the second liquid flow path 4 having
the bubble-generating region 7 is filled with the
bubble-generating liquid for generating the bubble as
receiving the thermal energy from the heat-generating
member 2. The movable separation film 5 for separating
the first liquid flow path 3 from the second liquid
flow path 4 is provided between the first liquid flow
path 3 and the second liquid flow path 4. The movable
separation film 5 is fixed in close contact with
orifice plate 9, so that the liquids in the respective
liquid flow paths are prevented from mixing herein with
each other.
When displaced by the bubble generated in the
bubble-generating region 7, the movable separation film
5 normally has no directivity or rather, the
displacement thereof sometimes proceeds to the common
liquid chamber with higher freedom °of displacement.
In the present invention, noting this motion of
the movable separation film 5, the movable separation
film 5 itself is provided with means for regulating the

CA 02375897 2002-03-20
_ 27 _
direction of displacement, acting thereon directly or
indirectly, whereby the displacement (movement,
expansion, or extension, or the like) of the movable
separation film 5 caused by the bubble is directed
toward the discharge port.
In the initial state shown in Fig. lA, the liquid
inside the first liquid flow path 3 is retracted to
near the discharge port 1 by capillary attraction. In
the present form, the discharge port 1 is located
downstream of the projection area of the heat-
generating member 2 onto the first liquid flow path 3
with respect to the flow direction of the liquid in the
liquid flow path 3.
In this state, when the thermal energy appears in
the heat-generating member 2 (a heating resistor member
having the shape of 40 pm x 105 um in the present
form), the heat-generating member 2 is heated quickly
and the surface in contact with the second liquid in
the bubble-generating region 7 heats the second liquid
to generate bubbles (Fig. 1B). The bubbles 6 generated
by this heating generation of bubble are those based on
the film boiling phenomenon as described in United
States Patent No. 4,723,129 and are generated together
all over the surface of the heat-generating member as
carrying very high pressure. The pressure generated at
this time propagates in the form of pressure wave in
the second liquid in the second liquid flow path 4 to

CA 02375897 2002-03-20
_ 28 _
act on the movable separation film 5, thereby
displacing the movable separation film 5 and starting
discharge of the first liquid in the first liquid flow
path 3.
As the bubbles 6 generated over the entire surface
of the heat-generating member 2 grow quickly, they
become of a film shape (Fig. 1C). The expansion of the
bubble 6 by the very high pressure in the initial stage
of generation further displaces the movable separation
film 5, which promotes discharge of the first liquid in
the first liquid flow path 3 through the discharge port
1.
Further growth of the bubble 6 thereafter
increases the displacement of the movable separation
film 5 (Fig. 1D). Up to the state shown in Fig. 1D,
the movable separation film 5 continues extending so
that displacement of upstream portion 5A becomes nearly
equal to displacement of downstream portion 5B with
respect to central portion 5C of the area of the
movable separation film facing the heat-generating
member 2.
After that, with further growth of the bubble 6,
the bubble 6 and the movable separation film 5 having
continuously been displaced are displaced so that the
downstream portion 5B is displaced relatively greater
toward the discharge port than the upstream portion 5A,
whereby the first liquid in the first liquid flow path

CA 02375897 2002-03-20
- 29 -
3 is moved directly toward the discharge port 1 (Fig.
1E).
The discharge efficiency is increased further by
the step wherein the movable separation film 5 is
displaced toward the discharge port on the downstream
side so that the liquid is directly moved toward the
discharge port as described above. Further, movement
of the liquid to upstream is decreased relatively,
' which is effective in refilling of liquid
(replenishment from upstream) into the nozzle,
especially into the displacement area of the movable
separation film 5.
When the movable separation film 5 itself is also
displaced toward the discharge port so as to change
from Fig. 1D to Fig. lE, as shown in Fig. 1D and Fig.
lE, the discharge efficiency and refilling efficiency
described above can be further increased and it causes
transport of the first liquid in the projection area of
the heat-generating member 2 in the first liquid flow
path 3 toward the discharge port, thus increasing the
discharge amount.
(Second embodied form)
Figs. 2A to 2E are cross-sectional views along the
flow path direction for explaining °the second embodied
form (an example having the displacing step of the
present invention from the initial stage) of the liquid
discharge method according to the present invention.

CA 02375897 2002-03-20
- 30 -
The present form also has the basically similar
structure to the first embodied form, wherein, as shown
in Figs. 2A to 2E, the inside of the first liquid flow
path 13 in direct communication with the discharge port
11 is filled with the first liquid supplied from the
first common liquid chamber 143 and the second liquid
flow path 14 having the bubble-generating region 17 is
filled with the bubble-generating liquid for generating
the bubble as receiving the thermal energy from the
heat-generating member 12. The movable separation film
for separating the first liquid flow path 13 from
the second liquid flow path 14 is provided between the
first liquid flow path 13 and the second liquid flow
path 14. The movable separation film 15 is fixed in
15 close contact with the orifice plate 19, so that the
liquids in the respective liquid flow paths are
prevented from mixing herein with each other.
In the initial state shown in Fig. 2A, the liquid
in the first liquid flow path 13 is retracted to near
the discharge port 11 by capillary attraction,
similarly as in Fig. lA. In the present form, the
discharge port 11 is located on the downstream side of
the projection area of the heat-generating member 12
onto the first liquid flow path 13.'
In this state, when the thermal energy appears in
the heat-generating member 12 (a heating resistor
member having the shape of 40 um x 115 um in the

CA 02375897 2002-03-20
- 31 -
present form), the heat-generating member 12 is heated
quickly and the surface in contact with the second
liquid in the bubble-generating region 17 heats the
second liquid to generate bubbles (Fig. 2B). The
bubbles 16 generated by this hearting generation of
bubble are those based on the film boiling phenomenon
as described in United States Patent No. 4,723,129 and
are generated together all over the surface of the
heat-generating member as carrying very high pressure.
The pressure generated at this time propagates in the
form of pressure wave in the second liquid in the
second liquid flow path 14 to act on the movable
separation film 15, thereby displacing the movable
separation film 15 and starting discharge of the first
liquid in the first liquid flow path 13.
As the bubbles 16 generated over the entire
surface of the heat-generating member 12 grow quickly,
they become of a film shape (Fig. 2C). The expansion
of the bubble 16 by the very high pressure in the
initial stage of generation further displaces the
movable separation film 15, which promotes discharge of
the first liquid in the first liquid flow path 13
through the discharge port 11. At this time, as shown
in Fig. 2C, the movable separation film 15 is displaced
from the initial stage so that in the movable area,
displacement of the downstream portion 15B is
relatively greater than that of the upstream portion

CA 02375897 2002-03-20
y - 32 -
15A. This efficiently moves the first liquid in the
first liquid flow path 13 toward the discharge port 11
from the beginning.
After that, with further growth of the bubble 16,
the displacement of film 15 and the growth of bubble is
promoted from the state of Fig. 2C, and thus the
displacement of the movable separation film 15 also
increases therewith (Fig. 2D). Especially, the
downstream portion 15B of the movable area is displaced
greater toward the discharge port than the upstream
portion 15A and the central portion 15C, whereby the
first liquid in the first liquid flow path 13 is
directly accelerated to move toward the discharge port.
In addition, since displacement of the upstream portion
15A is not much during the whole process, movement of
the liquid to upstream is decreased.
Therefore, the discharge efficiency, especially
the discharge rate, can be increased and it is
advantageous in refilling of liquid to nozzle and in
stabilization of the volume of droplet of discharge
liquid.
After that, with further growth of the bubble 16,
the downstream portion 15H and central portion 15C of
the movable separation film 15 are further displaced to
extend toward the discharge port, thereby achieving the
above-stated effect, i.e., the increase in the
discharge efficiency and discharge rate (Fig. 2E).

CA 02375897 2002-03-20
- 33 -
Especially, in the shape of the movable separation film
15 in this case, displacement and extension in the
width direction of the liquid flow path also increases
in addition to that shown by the cross-sectional shape,
so that an increase of the action area takes place to
move the first liquid in the first liquid flow path 13
toward the discharge port, which synergistically
increases the discharge efficiency. Particularly, the
displacement shape of the movable separation film 15 at
this time will be referred to as a nose shape, because
it is similar to the shape of human nose. This nose
shape includes the "S" shape, as shown in Fig. 2E,
wherein point B, which was located upstream in the
initial state, is located downstream of point A, which
was located downstream in the initial state, and the
shape, as shown in Fig. lE, wherein these points A, B
are located at equivalent positions.
(Form of displacement of the movable separation film)
Figs. 3A to 3C are cross-sectional views along the
flow path direction for explaining steps of
displacement of the movable separation film in the
liquid discharge method of the present invention.
In the present form, especially, since description
is given as focusing attention on the movable range and
the change of displacement of the movable separation
film, the bubble, the first liquid flow path, and the
discharge port are not illustrated but the basic

CA 02375897 2002-03-20
y - 34 -
structure in either figure is such that the bubble-
generating region 27 is near the projection area of the
heat-generating member 22 in the second liquid flow
path 24 and that the second liquid flow path 24 and the
first liquid flow path 23 are always substantially
separated from each other by the movable separation
film 25, specifically, throughout the period of from
the beginning to the end of displacement. With respect
to the border at the downstream edge (denoted by line H
in the drawing) of the heat-generating member 22, the
discharge port is provided on the downstream side while
the supply portion of the first liquid is on the
upstream side. In this form and after, "upstream" and
"downstream" are defined based on the central portion
of the movable range of the movable separation film
with respect to the flow direction of the liquid in the
flow path.
The example shown in Fig. 3A has from the
beginning the step wherein the movable separation film
25 is displaced in the order of (1), (2) and (3) in the
drawing from the initial state whereby the downstream
side is displaced more than the upstream side.
Especially, it enhances the discharge efficiency and
has such action that the downstream displacement causes
such movement as to push the first liquid in the first
liquid flow path 23 toward the discharge port, thus
increasing the discharge rate. In Fig. 3A the above

CA 02375897 2002-03-20
- 35 -
movable range is substantially constant.
In the example shown in Fig. 3B, as the movable
separation film 25 is displaced in the order of (1),
(2) and (3) in the drawing, the movable range of the
movable separation film 25 moves or expands toward the
discharge port. In this form the upstream side of the
above movable range is fixed. In this example, since
the downstream side is displaced more than the upstream
side and since the growth of bubble itself is directed
toward the discharge port; the discharge efficiency can
be enhanced furthermore.
In the example shown in Fig. 3C, displacement of
the movable separation film 25 is such that the
upstream side and the downstream side are displaced
equally or the upstream side is displaced a little
larger from. the initial state (1) to the state
indicated by (2) in the drawing, but with further
growth of the bubble as shown from (3) to (4) in the
drawing, the downstream side is displaced more than the
upstream side. This can also move the first liquid in
the upstream part of the movable range toward the
discharge port, whereby the discharge efficiency can be
increased and the discharge amount can also be
increased.
Further, in the step indicated by in Fig. 3C,
since a certain point U on the movable separation film
25 is displaced toward the discharge port farther than

CA 02375897 2002-03-20
- 36 -
point D, which was located downstream thereof in the
initial state, the discharge efficiency is improved
furthermore by the inflated portion projecting to the
discharge port. This shape will be called the nose
shape as described above.
The present invention includes the liquid
discharge methods having the steps as described above,
but it is noted that the examples shown in Figs. 3A to
3C are not always independent of each other and that
the present invention also includes steps having
components of the respective examples. The step having
the nose shape can be introduced not only to the
example shown in Fig. 3C, but also to the examples
shown in Figs. 3A and 3B. The movable separation film
used in Figs. 3A to 3C may be preliminarily provided
with a slack portion, irrespective of whether it has
capability of expansion and contraction. It is also
noted that the thickness of the movable separation film
in the drawing does not have specific, dimensional
meaning.
Embodiments
The embodiments of the present invention will be
described with reference to the drawings.
The "direction regulating means" in the present
specification is directed to at least either one of
means based on the structure or feature of the movable
separation film itself, the action or arrangement

CA 02375897 2002-03-20
- 37 -
relation of the bubble-generating means to the movable
separation film, the flow resistance relation around
the bubble-generating region, a member directly or
indirectly acting on the movable separation film, and a
member (means) for regulating displacement or extension
of the movable separation film, and includes all for
achieving the "displacement" defined by the present
application. Accordingly, the present invention
includes embodiments having a plurality of (two or
more) the above direction regulating means, of course.
Although the embodiments described below will not show
an arbitrary combination of plural direction regulating
means clearly, it is noted that the present invention
is by no means intended to be limited to the following
embodiments.
(Embodiment 1)
Figs. 4A to 4C are cross-sectional views along the
flow path direction to show the first embodiment of the
liquid discharge method and the liquid discharge
apparatus according to the present invention, wherein
Fig. 4A is a drawing to show the state upon non-
generation of bubble, Fig. 4B is a drawing to show the
state upon generation of bubble (upon discharge), and
Fig. 4C is a drawing to show the state upon collapse of
bubble.
In the present embodiment, as shown in Fig. 4A,
the second liquid flow path 104 for bubble-generating

CA 02375897 2002-03-20
- 38 -
liquid is provided on substrate 110 provided with heat-
generating member 102 (a heating resistor member in the
shape of 40 um x 105 um in the present embodiment) for
giving the thermal energy for generating the bubble to
the liquid, and the first liquid flow path 103 for
discharge liquid in direct communication with the
discharge port 101 is provided above it. The movable
separation film 105 made of a thin film with elasticity
is provided between the first liquid flow path 103 and
the second liquid flow path 104, so that the movable
separation film 105 separates the discharge liquid in
the first liquid flow path 103 from the bubble-
generating liquid in the second liquid flow path 104.
The movable separation film 105 is disposed as opposed
to the heat-generating member 102 and faces at least a
part of the bubble-generating region 107 in which the
bubble is generated by heat in the heat-generating
member 102. Further provided on the first liquid flow
path 103 side of the movable separation film 105 is
movable member 131 as the direction regulating means
adjacent to the movable separation film 105, and the
movable member 131 has free end 131a above the bubble-
generating region 107 and fulcrum 131b on the upstream
side of the free end 131a.
The free end 131a of the movable member 131 does
not always have to be located in the portion facing the
bubble-generating region 107, but it may be one

CA 02375897 2002-03-20
_ 39 _
provided downstream of fulcrum 131b and arranged to
guide extension of the movable separation film 105
toward the discharge port 101. More preferably, it is
opposed through the movable separation film 105 to at
least a part of the heat-generating member 102, whereby
the displacement of the movable separation film 105 can
be controlled efficiently. Particularly, if the
movakile member 131 is arranged so that the free end
131a thereof is located at the position opposite to the
movable separation film 105 on the downstream side of
the center of the area of the heat-generating member
102 or the bubble-generating region 107, the movable
member 131 can make expanding components perpendicular
to the heat-generating member 102 concentrated toward
the discharge port 101, thus greatly improving the
discharge efficiency. In the case wherein the free end
131a is provided on the downstream side of the bubble-
generating region 107, the discharge efficiency is
improved, because the free end 131a is displaced more
greatly so as to displace the movable separation film
105 more toward the discharge port 101.
Now, when heat is generated in the heat-generating
member 102, the bubble 106 is generated in the bubble-
generating region 107 on the heat-generating member
102, whereby the movable separation film 105 is
displaced into the first liquid flow path 103. Here,
the displacement of the movable separating film 105 is

CA 02375897 2002-03-20
- 40 -
regulated by the movable member 131. Since the movable
member 131 is provided with the free end 131a above the
bubble-generating region 107 and the fulcrum 131b
upstream thereof, the movable separation film 105 is
displaced more on the downstream side than on the
upstream side (Fig. 4B). Namely, the desired
deformation and displacement can be attained on a
stable basis by the direction regulating means for
regulating the direction of displacement of the movable
separation film.
In this way, with growth of bubble 106 the
downstream portion of the movable separation film 105
is displaced greater, whereby the growth of bubble 106
is transmitted mainly toward the discharge port 101, so
that the discharge liquid in the first liquid flow path
103 is discharged efficiently from the discharge port
101.
After that, the bubble 106 contracts to return the
movable separation film 105 to the position before
displacement.
In this case, the movable separation film 105 is
shifted to the second liquid flow path 104 from the
position before displacement by the pressure caused by
the disappearance of bubbles. However, in this
embodiment, the displacement of the movable separation
film 105 to the second liquid flow path is restricted
since the movable separation film 105 is integrally

CA 02375897 2002-03-20
- 41 -
provided on the movable member 131 (Fig. 4C).
Therefore, the pressure at the side of the movable
member 131 is limited to decrease so that the
retraction of the meniscus is restricted and the
refilling properties are improved.
The movable member 131 restricts movement of the
liquid to upstream, thereby achieving the effects
including an improvement in the refilling
characteristics, decrease of crosstalk, and so on.
As described above, the structure of the present
embodiment can discharge the discharge liquid, using
the different liquids as the discharge liquid and as
the bubble-generating liquid. Therefore, the present
embodiment can well discharge even high-viscosity
liquid such as polyethylene glycol, which was
insufficient to generate the bubble with application of
heat and which thus had insufficient discharge force
heretofore, by supplying this liquid to the first
liquid flow path 103 and supplying another liquid with
good bubble-generating property (for example, a mixture
of ethanol . water = 4 . 6 having the viscosity of
about 1 to 2 cP) as the bubble-generating liquid to the
second liquid flow path 104.
By selecting the bubble-generating liquid from
those that form no deposits of scorching or the like on
the surface of the heat-generating member with

CA 02375897 2002-03-20
- 42 -
application of heat, bubble generation can be
stabilized and good discharge can be carried out.
Further, since the structure of the liquid
discharge apparatus according to the present invention
also achieves the effects as described in the above-
stated embodiment, the liquid such as the high-
viscosity liquid can be discharged at further higher
discharge efficiency and under further higher ejection
force.
In the case of the liquid weak against heat being
used, if this liquid is supplied as the discharge
liquid to the first liquid flow path 103 and another
liquid resistant against thermal deterioration and easy
to generate the bubble is supplied to the second liquid
flow path 104, the thermally weak liquid can be
discharged at high discharge efficiency and under high
discharge force as described above without thermally
damaging the liquid weak against heat.
Next explained is the configuration of the element
substrate 110 in which the heat-generating member 102
for supplying heat to the liquid is mounted.
Figs. 5A and 5B show longitudinal, cross-sectional
views each to show a structural example of the liquid
discharge apparatus according to the present invention,
wherein Fig. 5A shows the device with a protection film
as detailed hereinafter and Fig. 5B the device without
the protection film.

CA 02375897 2002-03-20
- 43 -
Above the element substrate 110 there are provided
the second liquid flow path 104, the movable separation
film 105 to be a partition wall, the movable member
131, the first liquid flow path 103, and a grooved
member 132 having a groove for forming the first liquid
flow path 103, as shown in Figs. 5A and 5B.
The element substrate 110 has patterned wiring
electrodes 110c 0.2-1.0 um thick of aluminum (A1) or
the like and patterned electric resistance layer 110d
0.01-0.2 um thick of hafnium boride (HfB2), tantalum
nitride (TaN), tantalum aluminum (TaAl) or the like
constituting the heat-generating member on silicon
oxide film or silicon nitride film 110e for electric
insulation and thermal accumulation formed on base 110f
of silicon or the like. The resistance layer 110d
generates heat when a voltage is applied to the
resistance layer 110d through the two wiring electrodes
110c so as to let an electric current flow in the
resistance layer 110d. A protection layer 110b of
silicon dioxide, silicon nitride, or the like 0.1-0.2
um thick is provided on the resistance layer 110d
between the wiring electrodes 110c, and in addition, an
anti-cavitation layer 110a of tantalum or the like 0.1-
0.6 um thick is formed thereon to protect the
resistance layer 110d from various liquids such as ink.
Particularly, the pressure and shock wave
generated upon bubble generation and collapse is so

CA 02375897 2002-03-20
- 44 -
strong that the durability of the oxide film hard and
relatively fragile is considerably deteriorated.
Therefore, a metal material such as tantalum (Ta) or
the like is used as a material for the anti-cavitation
layer 110a.
The protection layer stated above may be omitted
depending upon the combination of liquid, liquid flow
path structure, and resistance material, an example of
which is shown in Fig. 5B.
The material for the resistance layer not
requiring the protection layer may be, for example, an
iridium-tantalum-aluminum (Ir-Ta-A1) alloy or the like.
Particularly, since the present invention uses the
liquid for generation of bubble separated from the
discharge liquid and being suitable for generation of
bubble, it is advantageous in the case without the
protection layer as described.
Thus, the structure of the heat-generating member
102 in the foregoing embodiment may be that including
only the resistance layer 110d (heat-generating
portion) between the wiring electrodes 110c, or may be
that including the protection layer for protecting the
resistance layer 110d.
In this embodiment, the heat-generating member 102
has a heat generation portion having the resistance
layer which generates heat in response to the electric
signal. Without having to be limited to this, any

CA 02375897 2002-03-20
- 45 -
means well suffices if it creates the bubble enough to
discharge the discharge liquid, in the bubble-
generating liquid. For example, the heat generation
portion may be in the form of a photothermal transducer
which generates heat upon receiving light such as
laser, or a heat-generating element having the heat
generation portion which generates heat upon receiving
high frequency wave.
Function elements such as a transistor, a diode, a
latch, a shift register, and so on for selectively
driving the electrothermal transducer may also be
integrally built in the aforementioned element
substrate 110 by the semiconductor fabrication process,
in addition to the electrothermal transducer comprised
of the resistance layer 110d constituting the heat-
generating portion and the wiring electrodes 110c for
supplying the electric signal to the resistance layer
110c.
In order to drive the heat generation portion of
the electrothermal transducer on the above-described
element substrate 110 so as to discharge the liquid, a
rectangular pulse is applied through the wiring
electrodes 110c to the resistance layer 110d to quickly
heat the resistance layer 110d between the wiring
electrodes 110c. Fig. 6 is a diagram to show the
waveform of the voltage applied to the resistance layer
110d shown in Figs. 5A and 5B.

CA 02375897 2002-03-20
- 46 -
With the liquid discharge apparatus of the
foregoing embodiment, the electric signal was applied
to the heat-generating member under the conditions:
the voltage 24 V, the pulse width 7 usec, the electric
current 150 mA, and the frequency 6 kHz to drive it,
whereby the ink as the liquid was discharged through
the discharge port, based on the operation described
above. However, the conditions of the driving signal
in the present invention are not limited to the above,
but any driving signal may be used if it can properly
generate the bubble in the bubble-generating liquid.
Next described is a structural example of the
liquid discharge apparatus which has two common liquid
chambers, while decreasing the number of components,
which can introduce the different liquids to the
respective common liquid chambers while well separating
from each other, and which can decrease the cost.
Although Figs. 5A and 5B and Fig. 6 were described
in the form of Embodiment 1, the structure of the
substrate can also be applied to the present invention
including the following embodiments and other forms.
Fig. 7 is a schematic diagram to show a structural
example of the liquid discharge apparatus according to
the present invention, wherein the same constituents as
those in the example shown in Figs. 4A to 4C and Figs.
5A and 5B are denoted by the same reference numbers,
and the detailed description thereof is thus omitted

CA 02375897 2002-03-20
_ 47 _
herein.
The grooved member 132 in the liquid discharge
apparatus shown in Fig. 7 is schematically comprised of
orifice plate 135 having discharge ports 101, a
plurality of grooves forming a plurality of first
liquid flow paths 103, and a recessed portion forming
first common liquid chamber 143, communicating in
common with the plurality of first liquid flow paths
103, for supplying the liquid (the discharge liquid) to
the first liquid flow path 103.
The plurality of first liquid flow paths 103 are
formed by joining the movable separation film 105, at
least a part of which is bonded to the movable member
131, to the lower part of the grooved member 132. The
grooved member 132 is provided with first liquid supply
path 133 running from the top thereof into the first
common liquid chamber 143 and is also provided with
second liquid supply path 134 running from the top
thereof through the movable member 131 and movable
separation film 105 into the second common liquid
chamber 144.
The first liquid (the discharge liquid) is
supplied through the first liquid supply path 133 and
the first common liquid chamber 143 to the first liquid
flow paths 103, as indicated by arrow C in Fig. 7,
while the second liquid (the bubble-generating liquid)
is supplied through the second liquid supply path 134

CA 02375897 2002-03-20
- 48 -
and the second common liquid chamber 144 to the second
liquid flow paths 104, as indicated by arrow D in Fig.
7.
The present embodiment is arranged so that the
second liquid supply path 134 is disposed in parallel
to the first liquid supply path 133, but the present
invention is not limited to this. For example, any
arrangement may be applied as long as the second liquid
supply path 134 is formed through the movable
separation film 105 disposed outside the first common
liquid chamber 143 and in communication with the second
common liquid chamber 144.
The thickness (the diameter) of the second liquid
supply path 134 is determined in consideration of the
supply amount of the second liquid and the shape of the
second liquid supply path 134 does not always have to
be circular, but may be rectangular.
The second common liquid chamber 144 can be formed
by partitioning the grooved member 132 by the movable
separation film 105. As a method of the formation, the
second common liquid chamber 144 and the second liquid
flow paths 104 may be formed by making the frame of
common liquid chamber and the walls of the second
liquid paths of a dry film on the substrate 110 and
bonding the substrate 110 to a combined body of the
movable separation film 105 with the grooved member 132
to which the movable separation film 105 is fixed.

CA 02375897 2002-03-20
_ 49 _
Fig. 8 is an exploded, perspective view to show a
structural example of the liquid discharge apparatus
according to the present invention.
In the present embodiment, the element substrate
110 provided with a plurality of electrothermal
transducers as the heat-generating member 102 for
generating heat for generating the bubble by film
boiling in the bubble-generating liquid as described
above is disposed on support body 136 made of metal
such as aluminum.
Provided above the element substrate 110 are a
plurality of grooves for forming the second liquid flow
paths 104 as made of dry film DF, a recessed portion
forming the second common liquid chamber (common
bubble-generating liquid chamber) 144, communicating
with the plurality of second liquid flow paths 104, for
supplying the bubble-generating liquid to each of the
second liquid flow paths 104, and the movable
separation film 105 to which the movable members 131
described above are bonded.
The grooved member 132 has grooves for forming the
first liquid flow paths (discharge liquid flow paths)
103 when bonded with the movable separation film 105, a
recessed portion for forming the first common liquid
chamber (common discharge liquid chamber) 143,
communicating with the discharge liquid flow paths, for
supplying the discharge liquid to each of the first

CA 02375897 2002-03-20
- 50 -
liquid flow paths 103, first liquid supply path
(discharge liquid supply path) 133 for supplying the
discharge liquid to the first common liquid chamber
143, and second liquid supply path (bubble-generating
liquid supply path) 134 for supply the bubble-
generating liquid to the second common liquid chamber
144. The second liquid supply path 134 is connected
with a communication passage running through the
movable member 131 and the movable separation film 105
disposed outside the first common liquid chamber 133,
into the second common liquid chamber 144, and this
communication passage permits the bubble-generating
liquid to be supplied to the second common liquid
chamber 144 without mixing with the discharge liquid.
The positional relation among the element
substrate 110, the movable member 131, the movable
separation film 105, and the grooved member 132 is such
that the movable member 131 is located corresponding to
the heat-generating member 102 of the element substrate
110 and the first liquid flow path 103 is disposed
corresponding to this movable member 131. Although the
present embodiment showed an example wherein a second
liquid supply path 134 is provided in one grooved
member 132, plural paths may be provided depending upon
the supply amount of liquid. Further, the cross-
sectional area of flow path of each of the first liquid
supply path 133 and the second liquid supply path 134

CA 02375897 2002-03-20
- 51 -
may be determined in proportion to the supply amount.
By such optimization of the flow path cross-sectional
area, the components forming the grooved member 132
etc. can be further compactified.
As described above, the present embodiment is
arranged so that the second liquid supply path 134 for
supplying the second liquid to the second liquid flow
path 104 and the first liquid supply path 133 for
supplying the first liquid to the first liquid flow
path 103 are formed in the grooved top plate as the
common grooved member 132, whereby the number of
components can be decreased and the number of steps and
the cost can be decreased.
Because of the structure in which the supply of
the second liquid to the second common liquid chamber
144 in communication with the second liquid flow paths
104 is carried out by the second liquid flow paths 104
in such a direction as to penetrate the movable
separation film 105 separating the first liquid from
the second liquid, only one step is sufficient for
bonding of the movable separation film 105, the grooved
member 132, and the substrate 110 with the heat-
generating member 102 formed therein, which enhances
ease of fabrication and the bonding-accuracy and which
achieves good discharge.
Since the second liquid is supplied into the
second common liquid chamber 144 as penetrating the

CA 02375897 2002-03-20
- 52 -
movable separation film 105, the supply of the second
liquid to the second liquid flow paths 104 becomes
certain and the sufficient supply amount can be
assured, thus enabling stable discharge.
As described above, since the present invention
employs the configuration having the movable separation
film 105 to which the movable member 131 is bonded, the
liquid can be discharged under higher discharge force,
at higher discharge efficiency, and at higher speed
than by the conventional liquid discharge apparatuss.
The bubble-generating liquid may be the liquid having
the above-mentioned properties; specifically, it may be
selected from methanol, ethanol, n-propanol,
isopropanol, n-hexane, n-heptane, n-octane, toluene,
xylene, methylene dichloride, trichlene, Freon TF,
Freon BF, ethyl ether, dioxane, cyclohexane, methyl
acetate, ethyl acetate, acetone, methyl ethyl ketone,
water, and mixtures thereof.
The discharge liquid may be selected from various
liquids, free from possession of the bubble-generating
property and the thermal property thereof. Further,
the discharge liquid may be selected from liquids with
low bubble-generating property, discharge of which was
difficult before, liquids likely to be modified or
deteriorated by heat, and liquids with high viscosity.
However, the discharge liquid is preferably a
liquid without a property to hinder the discharge of

CA 02375897 2002-03-20
- 53 -
liquid, the generation of bubble, the operation of the
movable separation film and the movable member, and so
on by the discharge liquid itself or by reaction
thereof with the bubble-generating liquid.
For example, high-viscosity ink or the like may be
used as the discharge liquid for recording.
Other discharge liquids applicable include liquids
weak against heat such as pharmaceutical products and
perfumes.
Recording was conducted as discharging the
discharge liquid in combinations of the bubble-
generating liquid and the discharge liquid in the
following compositions. The recording results
confirmed that the liquids with viscosity of ten and
several cP, discharge of which was difficult by the
conventional liquid discharge apparatuss, were
discharged well, of course, and the liquid even with
very high viscosity of 150 cP was also discharged well,
thus obtaining high-quality recorded objects.
Rubble-generating liquid 1
Ethanol 40 wt%
Water 60 wt%
Bubble-generating liquid 2
Water 100 wt%
Bubble-generating liquid 3
Isopropyl alcohol 10 wt%
Water 90 wt%

CA 02375897 2002-03-20
- 54 -
Discharge liquid 1 (pigment ink of approximately 15
cP)
Carbon black 5 wt%
Styrene-acrylic acid-ethyl acrylate copolymer
separating material (acid value 140 and weight
average molecular weight 8000) 1 wt%
Monoethanol amine 0.25 wt %
Glycerine 6.9 wt%
Thio diglycol 5 wt%
Ethanol 3 wt%
Water 16.75 wt%
Discharge liquid 2 (55 cP)
Polyethylene glycol 200 100 wt%
Discharge liquid 3 (150 cP)
Polyethylene glycol 600 100 wt%
Incidentally, in the case of the liquids
conventionally regarded as not easy to eject, because
of their low discharge speeds, dispersion of discharge
directivity was enhanced so as to degrade the impact
accuracy of dot on recording sheet and unstable
discharge caused dispersion in the discharge amount,
which made it not easy to obtain a high-quality image.
The structure in the embodiment as described above,
however, can generate the bubble sufficiently and
stably by using the bubble-generating liquid. This can
enhance the impact accuracy of liquid droplet and can
stabilize the ink discharge amount, so that the quality

CA 02375897 2002-03-20
- 55 -
of recorded image can be improved remarkably.
Next described are fabrication steps of the liquid
discharge apparatus according to the present invention.
Roughly describing, the device was fabricated in
such a way that the walls of the second liquid flow
paths were formed on the element substrate, the movable
separation film was attached thereonto, and the grooved
member having the grooves etc. for forming the first
liquid flow paths was attached further thereonto.
Alternatively, the device was fabricated in such a way
that after forming the walls of the second liquid flow
paths, the grooved member to which the movable
separation film with the movable member bonded thereto
was attached was joined onto the walls.
Further, the process for producing the second
liquid flow paths will be described in detail.
First, elements for electrothermal conversion each
having the heat-generating member of hafnium boride,
tantalum nitride, or the like were formed on an element
substrate (silicon wafer), using the same fabrication
system as that for semiconductors, and thereafter the
surface of the element substrate was cleaned for the
purpose of improving adherence with a photosensitive
resin in the next step. The adherence can be improved
further by subjecting the surface of element substrate
to surface modification by ultraviolet-ozone or the
like and thereafter spin- coating the thus modified

CA 02375897 2002-03-20
- 56 -
surface, for example, with a liquid of silane coupling
agent (available from Nihon Unica: A189) diluted in 1
by weight with ethyl alcohol.
Then the surface was cleaned and an ultraviolet-
sensitive resin film (available from Tokyo Ohka: dry
film, Ordil SY-318) DF was laminated on the adherence-
enhanced substrate.
Next, photomask PM was placed on the dry film DF
and ultraviolet rays were radiated to portions to be
left as the second flow path walls in the dry film DF
through the photomask PM. This exposure step was
carried out in the exposure dose of about 600 mJ/cmz,
using MPA-600 available from CANON INC.
Then the dry film DF was developed with a
developer comprised of xylene and butyl cellosolve
acetate (available from Tokyo Ohka: BMRC-3) to dissolve
unexposed portions, so that the portions hardened by
exposure were formed as the wall portions of the second
liquid flow paths. Further, the residue remaining on
the surface of element substrate was removed by
processing it for about 90 seconds by an oxygen plasma
ashing system (available from Alcantec Inc.: MAS-800)
and then ultraviolet irradiation under 100 mJ/cm2 was
further carried out at 150 °C for 2 hours to harden the
exposed portions completely.
By the above method, the second liquid flow paths
can be uniformly formed with accuracy in a plurality of

CA 02375897 2002-03-20
- 57 -
heater boards (element substrates) obtained by dividing
the above silicon substrate. Specifically, the silicon
substrate was cut and divided into the respective
heater boards by a dicing machine (available from Tokyo
Seimitsu: AWD-4000) to which a diamond blade 0.05 mm
thick was attached. Each heater board separated was
fixed on an aluminum base plate with adhesive
(available from Toray: SE4400).
Then the heater board was connected to a printed
board preliminarily joined onto the aluminum base
plate, by aluminum wires of the diameter of 0.05 mm.
Next positioned and joined to the heater board
thus obtained was a joint body of the grooved member
with the movable separation film by the aforementioned
method. Specifically, the grooved member having the
movable separation film was positioned to the heater
board, they were engaged and fixed by stop springs,
thereafter supply members for ink and bubble-generating
liquid were joined and fixed onto the aluminum base
plate, and gaps between the aluminum wires and gaps
among the grooved member, the heater board, and the
supply members for ink and bubble-generating liquid
were sealed with silicon sealant (available from
Toshiba Silicone: TSE399), thus completing the second
liquid flow paths.
By forming the second liquid flow paths by the
above process, the accurate flow paths can be obtained

CA 02375897 2002-03-20
- 58 -
without positional deviation relative to the heaters of
each heater board. Particularly, by preliminarily
joining the grooved member with the movable separation
film in the previous step, the position accuracy can be
enhanced between the first liquid flow path and the
movable member. Then stable discharge is achieved by
these high-accuracy fabrication techniques so as to
enhance the quality of print. In addition, since the
flow paths can be formed en bloc on the wafer, the
devices can be mass-produced at low cost.
The present embodiment employed the ultraviolet-
curing dry film for forming the second liquid flow
paths, but it is also possible to obtain the element
substrate by using a resin material having an
absorption band in the ultraviolet region, especially
near 248 nm, curing it after lamination, and directly
removing the resin in the portions to become the second
liquid flow paths by excimer laser.
The first liquid flow paths etc. were formed by
joining the combined body of the substrate with the
movable separation film described above to the grooved
top plate having the orifice plate with discharge
ports, the grooves for forming the first liquid flow
paths, and the recessed portion for forming the first
common liquid chamber, communicating in common with the
plurality of first liquid flow paths, for supplying the
first liquid to each flow path. The movable separation

CA 02375897 2002-03-20
- 59 -
film is fixed by being pinched by this grooved top
plate and the second liquid flow path walls. The
movable separation film is not fixed only to the
substrate, but it may be also positioned and fixed to
the substrate after fixed to the grooved top plate.
Preferable examples of the material for the
movable member to be the direction regulating means
include durable materials, for example, metals such as
silver, nickel, gold, iron, titanium, aluminum,
platinum, tantalum, stainless steel, or phosphor
bronze, alloys thereof, resin materials, for example,
those having the nitryl group such as acrylonitrile,
butadiene, or styrene, those having the amide group
such as polyamide, those having the carboxyl group such
as polycarbonate, those having the aldehyde group such
as polyacetal, those having the sulfone group such as
polysulfone, those such as liquid crystal polymers, and
chemical compounds thereof; and materials having
durability against the ink, for example, metals such as
gold, tungsten, tantalum, nickel, stainless steel,
titanium, alloys thereof, materials coated with such
metal, resin materials having the amide group such as
polyamide, resin materials having the aldehyde group
such as polyacetal, resin materials having the ketone
group such as polyetheretherketone, resin materials
having the imide group such as polyimide, resin
materials having the hydroxyl group such as phenolic

CA 02375897 2002-03-20
- 60 -
resins, resin materials having the ethyl group such as
polyethylene, resin materials having the alkyl group
such as polypropylene, resin materials having the epoxy
group such as epoxy resins, resin materials having the
amide group such as melamine resins, resin materials
having the methylol group such as xylene resins,
chemical compounds thereof, ceramic materials such as
silicon dioxide, and chemical compounds thereof.
Preferable examples of the material for the
movable separation film 105 include, in addition to the
aforementioned polyimide, resin materials having high
heat-resistance, high anti-solvent property, good
moldability, elasticity, and capability of forming a
thin film, typified by recent engineering plastics,
such as polyethylene, polypropylene, polyamide,
polyethylene terephthalate, melamine resins, phenolic
resins, polybutadiene, polyurethane,
polyetheretherketone, polyether Sulfone, polyallylate,
silicone rubber, and polysulfone, and chemical
compounds thereof.
The thickness of the movable separation film 105
can be determined in consideration of the material and
the shape and the like thereof from the viewpoints that
the strength as a partition wall should be assured and
that expansion and contraction takes place well, and it
is desirably approximately 0.5 um to 10 um.
(Embodiment 2)

CA 02375897 2002-03-20
- 61 -
Figs. 9A to 9C are drawings to show the second
embodiment of the liquid discharge apparatus of the
present invention, wherein Fig. 9A is a cross-sectional
view along the flow path direction upon nan-generation
of bubble, Fig. 9B is a cross-sectional view along the
flow path direction upon generation of bubble, and Fig.
9C is a drawing to show a view of the first flow path
observed from the second flow path side of the drawing
shown in Fig. 9A.
In the present embodiment as shown in Figs. 9A and
9C, the second liquid flow path 104 for bubble-
generating liquid is provided on the substrate 110
provided with the heat-generating member 102 (the
heating resistor member in the shape of 40 um x 105 um
in the present embodiment) for supplying the thermal
energy for generating the bubble in the liquid, and the
first liquid flow path 103 for discharge liquid in
direct communication with the discharge port 101 is
provided above it. The movable member 131 is provided
as the direction regulating means, which has the free
end on the downstream side of the upstream edge of the
bubble-generating region 107, and the fulcrum on the
upstream side thereof. The movable member 131 and the
movable separation film 105, provided in an opening
portion between the first liquid flow path 103 and the
second liquid flow path 104, are bonded with each other
at bonding portion 131c, which forms a part of the free

CA 02375897 2002-03-20
- 62 -
end side of the movable member 131, whereby the first
liquid flow path 103 and the second liquid flow path
104 are always separated substantially from each other.
When heat is generated in the heat-generating
member 102, the bubble 106 is generated in the bubble-
generating region 107 on the heat-generating member
102. This displaces the movable separation film 105
into the first liquid flow path 103, whereupon the
displacement of the movable separation film 105 is
controlled by the movable member 131. Since the
movable member 131 has the free end above the bubble-
generating region 107 and the fulcrum upstream thereof,
the movable separation film 105 is displaced more on
the downstream side than on the upstream side (Fig.
9B).
In this way, the downstream portion of the movable
separation film 105 is displaced greater with growth of
bubble 106, whereby the pressure due to generation of
bubble 106 is transmitted mainly to the discharge port
101, thereby efficiently discharging the discharge
liquid in the first liquid flow path 103 from the
discharge port 101. Since the movable separation film
does not have to cover the entire surface, the cost can
be decreased.
(Embodiment 3)
Figs. l0A to lOF are cross-sectional views along
the flow,path direction to show the third embodiment of

CA 02375897 2002-03-20
- 63 -
the liquid discharge method and the liquid discharge
apparatus according to the present invention.
In the present embodiment, as shown in Fig. 10A,
the second liquid flow path 114 for bubble-generating
liquid is provided on the substrate 130 provided with
the heat-generating member 112 (the heating resistor
member in the shape of 40 Nm x 105 Nm in the present
embodiment) for supplying the thermal energy for
generating the bubble in the liquid, and the first
liquid flow path 113 for discharge liquid in direct
communication with the discharge port 111 is provided
above it. The movable separation film 115 made of a
thin film with elasticity is provided between the first
liquid flow path 113 and the second liquid flow path
114. The movable separation film 115 separates the
discharge liquid in the first liquid flow path 113 from
the bubble-generating liquid in the second liquid flow
path 114. The movable separation film 115 is disposed
opposite to the heat-generating member 112 and faces at
least a part of the bubble-generating region 117 where
the bubble is generated by the heat generated in the
heat-generating member 112. Further provided on the
first liquid flow path 113 side of the movable
separation film 115 is the movable member 151 as the
direction regulating means, which has the free end 151a
on the downstream side of the upstream edge of the
bubble-generating region 117, and the fulcrum 151b on

CA 02375897 2002-03-20
- 64 -
the upstream side of the free end 151a and which is
disposed adjacent to the movable separation film 115.
The movable separation film 115 and the movable member
151 may be bonded to each other at the bonding portion
151c, which becomes a part of the free end 151a side of
the movable member 151 (on the upstream side of the
bubble-generating region 117). In the movable member
151, a portion between the bonding portion 151c and the
fulcrum 151b is a curved portion 151d curved on the
first liquid flow path 113 side.
The liquid discharge operation in the liquid
discharge apparatus constructed as described above will
be described, but, prior thereto, characteristics of
the movable separation film 115 shown in Figs. l0A to
lOF will be described.
Figs. 11A and 11H are drawings to show the
characteristics of the movable separation film used in
the liquid discharge apparatus according to the present
invention, wherein Fig. 11A is a drawing to show the
relationship between pressure f of the bubble generated
in the bubble-generating region and stress F of the
movable separation film against it and Fig. 11B is a
graph to show the characteristics of the stress F of
the movable separation film against volume change of
bubble shown in Fig. 11A.
As shown in Figs. 11A and 11B, the stress of the
movable separation film exponentially increases with

CA 02375897 2002-03-20
- 65 -
increasing volume V$ of the bubble as far as the volume
VB of the bubble is small in the initial stage of
generation of bubble. With total expansion of bubble
the film thickness of the movable separation film
becomes smaller and the stress becomes weaker. Thus,
the stress turns to decreasing after reaching a certain
inflection point.
Now returning to Figs. 10A to lOF, the liquid
discharge operation in the present embodiment will be
described.
When heat is generated in the heat-generating
member 112, the bubble 116 is generated in the bubble-
generating region 117 on the heat-generating member
112, whereby the part of the movable separation film
115 below the curved portion 151d of the movable member
151 starts extending (Fig. lOB).
With further growth of the bubble 116, the movable
separation film 115 further extends to start being
displaced into the first liquid flow path 113 (Fig.
lOC).
After that, with further growth of the bubble 116,
the movable separation film 115 becomes about to be
displaced further into the first liquid flow path 113,
but because the upstream side is fixed by the fulcrum
151b, the displacement is restricted there, so that the
downstream side being the free end 151a side is
displaced greater (Fig. lOD).

CA 02375897 2002-03-20
- 66 -
In this way, the downstream portion of the movable
separation film 115 is displaced greater with growth of
the bubble 116, whereby the pressure due to the
generation of bubble 116 is transmitted mainly toward
the discharge port 111, thereby efficiently discharging
the discharge liquid in the first liquid flow path 113
from the discharge port 111.
In this state the stress on the movable separation
film 115 is maintained at point C in Fig. 11B on the
upstream side because of restriction of extension and
at point E in Fig. 11B on the downstream side because
of the more enhancement of extension. In the stress
distribution over the whole of the movable separation
film 115, therefore, the stress on the upstream side is
greater than that on the downstream side.
With contraction of the bubble 116 thereafter the
movable separation film 115 becomes about to return to
the position before displacement (Fig. 10E), whereupon
because of the stress distribution as described above,
the contraction speed is fast on the upstream side of
bubble 116 while the contraction speed is slow on the
downstream side. Thus, the stress distribution over
the whole of the movable separation film 115 makes such
a shift as to gradually decrease the stress on the
upstream side and as to gradually increase the stress
on the downstream side.
Because of the negative pressure upon collapse of

CA 02375897 2002-03-20
- 67 -
bubble, the portion of the movable separation film 115
below the curved portion 151d of the movable member 151
becomes displaced into the second liquid flow path 104
past the position before displacement. However, since
the curved portion 151d of the movable member 151 is
provided, the reduction of pressure is suppressed on
the first liquid flow path 113 side, which suppresses
back of meniscus and improves the refilling
characteristics (Fig. lOF).
Further, the movable member 151 restricts movement
of the liquid to upstream, thereby achieving the
effects including the improvement in the refilling
characteristics, the reduction of crosstalk, and so on.
(Embodiment 4)
Figs. 12A and 12B are drawings to show the fourth
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 12A is a cross-
sectional view along the flow path direction and Fig.
12B is a top plan view.
The present embodiment, as shown in Figs. 12A and
12B, is different from the first embodiment in that the
movable member 161 is formed in such a trapezoid shape
as to decrease the width toward downstream where the
free end 161a is located, and the other structure is
the same as in the first embodiment.
In the liquid discharge apparatus constructed as
described above, since the movable member 161 is formed

CA 02375897 2002-03-20
- 68 -
in such a trapezoid shape as to narrow the width toward
downstream, the movable member 161 is easy to deform
and the movable separation film 105 is displaced
efficiently by the pressure of bubble generated in the
bubble-generating region 107.
Therefore, the present embodiment can achieve
enhancement of discharge efficiency and increase of
discharge amount.
The above-stated effects can be enhanced further
if the free end 161a in the present embodiment is
arranged, more preferably, as located on the upstream
side of the center of the heat-generating member 102.
(Embodiment 5)
Figs. 13A and 13B are cross-sectional views along
the flow path direction to show the fifth embodiment of
the liquid discharge method and the liquid discharge
apparatus according to the present invention, wherein
Fig. 13A is a drawing to show a state upon non-
generation of bubble and Fig. 13B is a drawing to show
a state upon generation of bubble (upon discharge).
Fig. 14 is a perspective view, partly broken, of the
liquid discharge apparatus shown in Figs. 13A and 13B.
In the present embodiment, as shown in Figs. 13A
and 13B and Fig. 14, similar to Embodiment 1, the
second liquid flow path 204 for bubble-generating
liquid is provided on the substrate 210 provided with
the heat-generating member 202 (the heating resistor

CA 02375897 2002-03-20
- 69 -
member in the shape of 40 um x 105 um in the present
embodiment) for supplying the thermal energy for
generating the bubble in the liquid, and the first
liquid flow path 203 for discharge liquid in direct
communication with the discharge port 201 is provided
above it. Further, the movable separation film 205
made of a thin film with elasticity is provided between
the first liquid flow path 203 and the second liquid
flow path 204. The movable separation film 205
separates the discharge liquid in the first liquid flow
path 203 from the bubble-generating liquid in the
second liquid flow path 204.
Here, the movable separation film 205 in the
portion located in the projection area above the
surface of the heat-generating member 202 has thick
portion 205a as the direction regulating means, facing
opposite to the heat-generating member 202 and having
the free end on the discharge port 202 side, and slack
portion 205c on the discharge port 201 side of the free
end. As described below, the movable separation film
205 operates so that the thick portion 205a is
displaced into the first liquid flow path 203 with
generation of bubble in the bubble-generating liquid
and so that deformation on the discharge port 201 side
becomes greater because of the slack portion 205c (Fig.
13B). Since the present embodiment does not need to
expand the movable separation film because of provision

CA 02375897 2002-03-20
- 70 -
of the slack portion, the discharge efficiency can be
enhanced.
Recess portion 205b is formed on the opposite side
to the discharge port 201 with respect to the thick
portion 205a of the movable separation film 205 and is
a hinge portion for facilitating the displacement of
the thick portion 205a. The recess portion 205b may be
omitted depending upon the thickness or the material of
the thick portion 205a, if the thick portion 205a is
easy to displace.
However, the recess portion 205b is the portion
functioning as fulcrum 205d upon displacement of the
thick portion 205b, and thus the fulcrum 205d is formed
as a place to become a starting point of displacement
even in the case of the structure without the recess
portion 205b.
The thick portion 205a is located the distance of
approximately 10 to 15 um apart from the heat-
generating member 202 so as to cover the heat-
generating member 202 at the position opposite to the
heat-generating member 202, while having the fulcrum
205d on the upstream side of flow of the liquid,
flowing from the common liquid chamber (not
illustrated) through the thick portion 205a to the
discharge port 201 by the discharge operation of
liquid, and the free end on the downstream side of this
fulcrum 205d. The space between the heat-generating

CA 02375897 2002-03-20
- 71 -
member 202 and the thick portion 205a is the bubble-
generating region 207.
When heat is generated in the heat-generating
member 202, the heat acts on the bubble-generating
liquid in the bubble-generating region 207 between the
thick portion 205a of the movable separation film 205
and the heat-generating member 202, thereby generating
the bubble based on the film boiling phenomenon in the
bubble-generating liquid. The pressure based on the
generation of bubble preferentially acts on the movable
separation film 205, and the movable separation film
205 is displaced so that the thick portion 205a opens
greatly to the discharge port 201.about the recess
portion 205b, as shown in Fig. 13B. By this, the
pressure due to the bubble generated in the bubble-
generating region 207 is guided to the discharge port
201.
Further, in the case wherein a bellows portion is
provided in the movable separation film on the side of
the direction regulating means, the free-end-side
movable separation film of the direction regulating
means swells more toward the discharge port by the
pressure upon generation of bubble because of less
limitation on swelling than in the case of the movable
separation film being also provided on the side. Thus,
such an arrangement can achieve higher discharge
efficiency and higher discharge force.

CA 02375897 2002-03-20
- 72 -
In this case, when the direction regulating means
is closed, the bellows portion of the movable
separation film is closed substantially hermetically,
thereby shutting off the first liquid from the second
liquid. Since the first liquid flow path walls can
prevent the pressure upon generation of bubble from
leaking through the side of the direction regulating
means to the outside upon displacement of the movable
separation film, the discharge efficiency and discharge
force are not degraded in comparison with the case
without the bellows portion.
The discharge operation of the liquid discharge
apparatus constructed as described above will be
described in detail.
Figs. 15A to 15D are drawings for explaining the
operation of the liquid discharge apparatus shown in
Figs. 13A and 13B and Fig. 14.
In Fig. 15A, energy such as electric energy is not
applied to the heat-generating member 202 yet, so that
no heat is generated in the heat-generating member 202.
The thick portion 205a is located at the first position
nearly parallel to the substrate 201.
An important point herein is that the thick
portion 205a is provided at the position where it faces
at least the downstream portion of the bubble generated
by the heat in the heat-generating member 202. Namely,
for the downstream portion of the bubble to act on the

CA 02375897 2002-03-20
_ 73 _
thick portion 205a, the thick portion 205a is placed at
least up to the position downstream of the center of
the area of the heat-generating member 202 (downstream
of a line passing the center of the area of the heat-
s generating member 202 and perpendicularly intersecting
the direction of the length of flow path) in the
structure of liquid flow path.
Here, when the electric energy or the like is
applied to the heat-generating member 202, the heat-
generating member 202 generates heat and part of the
bubble-generating liquid filling the inside of the
bubble-generating region 207 is heated thereby, thus
generating the bubble 206 by film boiling. When the
bubble 206 is generated, the slack portion 205c of the
movable separation film 205 is extended so that the
thick portion 205a is displaced from the first position
to the second position so as to guide propagation of
the pressure of bubble 206 toward the discharge port,
by the pressure based on generation of bubble 206 (Fig.
15B).
An important point herein is that the free end of
the thick portion 205a of the movable separation film
205 is positioned on the downstream side (on the
discharge port side) and the fulcrum 205d is located on
the upstream side (on the common liquid chamber side)
whereby at least a part of the thick portion 205a faces
the downstream portion of the heat-generating member

CA 02375897 2002-03-20
- ~4 -
202, i.e., the downstream portion of bubble 206, as
described above.
With further growth of bubble 206, the thick
portion 205a of the movable separation film 205 is
further displaced into the first liquid flow path 203
according to the pressure upon generation of bubble.
With this, the free-end-side slack portion 205c swells
greatly in the discharge direction while the fulcrum-
side slack portion 205c is pulled by swelling force of
the thick portion 205a toward the discharge port, thus
assisting the shift thereof. As a result, the bubble
206 thus generated grows more downstream than upstream,
so that the thick portion 205a moves greatly over the
first position (Fig. 15C).
In this way, the thick portion 205a of the movable
separation film 205 is gradually displaced into the
first liquid flow path 203 according to the growth of
bubble 206, whereby the bubble 206 grows to the free
end side so as to inflate the slack portion 205c
greatly toward the discharge port, and the pressure due
to generation of bubble 206 is directed uniformly
toward the discharge port 201. This enhances the
discharge efficiency of liquid through the discharge
port 201. The movable separation film 205, while
guiding the bubble-generating pressure toward the
discharge port 201, becomes little hindrance against
transmission thereof, and thus the propagation

CA 02375897 2002-03-20
_ 75 _
direction of pressure and the growing direction of
bubble 206 can be controlled efficiently depending upon
the magnitude of the pressure propagating.
After that, when the bubble 206 contracts to
disappear because of the decrease of internal pressure
of bubble characteristic to the film boiling phenomenon
described above, the thick portion 205a of the movable
separation film 205 displaced up to the second position
returns to the initial position (the first position)
shown in Fig. 15A because of the negative pressure upon
contraction of bubble 206 and the restoring force based
on the spring property of the movable separation film
205 itself (Fig. 15D). Upon collapse of bubble, in
order to compensate for the volume of the liquid
ejected, the liquid flows into the space from upstream,
i.e., from the common liquid chamber side as indicated
by VD1, Vnz and from the discharge port 201 side as
indicated by V~.
As described above, since in the structure of the
present embodiment the direction regulating means
provided in the movable separation film lets the
pressure propagate efficiently toward the discharge
port, the liquid weak against heat, the high-viscosity
liquid, or the like can be discharged at higher
discharge efficiency and under higher discharge force.
Figs. 16A to 16C are drawings for explaining the
relationship of location between the thick portion 205a

CA 02375897 2002-03-20
- 76 -
of the movable separation film 205 and the second
liquid flow path 204 in the liquid discharge apparatus
shown in Figs. 13A and 13B and Figs. 15A to 15D,
wherein Fig. 16A is a top plan view of the thick
portion 205a, Fig. 16B is a top plan view of the second
liquid flow path 204 without the movable separation
film 205, and Fig. 16C is a schematic view of the
positional relation between the thick portion 205a and
the second liquid flow path 204 as superimposed. In
either view the discharge port 201 is located on the
bottom side.
The second liquid flow path 204 has constricted
portions 209 before and after the heat-generating
member 202, thereby being formed in such chamber
(bubble-generating chamber) structure as to prevent the
pressure upon generation of bubble from escaping
through the second liquid flow path 204. In the
present invention, since the bubble-generating liquid
is separated completely from the discharge liquid by
the movable separation film 205, consumption of the
bubble-generating liquid is equal to substantially
zero. However, the bubble-generating liquid, though a
little amount, is replenished for the purposes of
compensating for vaporization of the bubble-generating
liquid under circumstances of physical distribution and
storage and of removing bubbles remaining in the
bubble-generating chamber after long-term continuous

CA 02375897 2002-03-20
- 77 -
operation. Accordingly, the gap in the constricted
portions 209 can be set very narrow, several um to ten
and several um, the pressure upon generation of bubble
occurring in the second liquid flow path 204 can be
directed as concentrated to the movable separation film
205 with little escape thereof to the surroundings, and
the liquid in the first liquid flow path 203 can be
discharged at high efficiency and under high discharge
force by the displacement of the thick portion 205a of
the movable separation film 205 into the first liquid
flow path 203 by this pressure. Here, the downstream
constricted portion 209 of the bubble-generating
chamber of the second liquid flow path 204 is a flow
path for extracting bubbles remaining in the bubble-
generating chamber therefrom.
The shape of the second liquid flow path 204 is
not limited to the above-stated structure, but it may
be any shape that can effectively transmit the pressure
upon generation of bubble to the movable separation
film.
The present embodiment is arranged so that the
heat-generating member 202 is the one having the shape
of 40 pm x 105 um and the movable separation film 205
is provided in such a state as to cover the bubble-
generating chamber in which the heat-generating member
202 is provided, but without having to be limited to
these, the size, shape, and location of the heat-

CA 02375897 2002-03-20
- 78 -
generating member 202 and the movable separation film
205 in the present invention may be determined
arbitrarily from shapes and locations by which the
pressure upon generation of bubble can be utilized
effectively as the discharge pressure.
In the present embodiment the flow path walls for
forming the second liquid flow path 204 are formed by
laminating the photosensitive resin (dry film) 15 um
thick on the substrate 210 and patterning it, but the
present invention is not limited to this. As in
Embodiment 1, the material for the flow path walls may
be any material that has solvent resistivity against
the bubble-generating liquid and that can readily form
the shape of flow path walls.
Next described is a structural example of the
liquid discharge apparatus that has two common liquid
chambers, that can introduce the different liquids to
the respective common liquid chambers as separating
them well from each other, and that can be made at
reduced cost, while decreasing the number of
components.
Fig. 17 is a schematic view to show a structural
example of the liquid discharge apparatus according to
the present invention, wherein the same constituents as
those in the example shown in Figs. 13A and 13B to
Figs. 16A to 16C are denoted by the same reference
symbols, and the detailed description thereof is

CA 02375897 2002-03-20
_ 79 _
omitted herein.
As in Embodiment 1, the grooved member 232 in the
liquid discharge apparatus shown in Fig. 17 is
schematically composed of the discharge ports, orifice
plate 235, a plurality of grooves forming a plurality
of first liquid flow paths 203, and a recessed portion
for forming the first common liquid chamber 243,
communicating in common with the plurality of first
liquid flow paths 203, for supplying the liquid (the
discharge liquid) to each first liquid flow path 203.
The plurality of first liquid flow paths 203 are
formed by joining the movable separation film 205 to
the lower portion of this grooved member 232 so that
the inside thereof generally faces the heat-generating
member. The grooved member 232 is provided with the
first liquid supply path 233 running from the top
thereof into the first common liquid chamber 243 and
also with the second liquid supply path 234 running
from the top thereof through the movable separation
film 205 into the second common liquid chamber 244.
The first liquid is supplied through the first
liquid supply path 233 and through the first common
liquid chamber 243 to the first liquid flow paths 203,
as shown by arrow C in Fig. 17, whi°le the second liquid
(the bubble-generating liquid) is supplied through the
second liquid supply path 234 and through the second
common liquid chamber 244 to the second liquid flow

CA 02375897 2002-03-20
- 80 -
paths 204, as shown by arrow D in Fig. 17.
Fig. 18 is an exploded, perspective view to show a
structural example of the liquid discharge apparatus
according to the present invention.
Also in the present embodiment, the element
substrate 210 provided with a plurality of heat-
generating members 202 is provided on the support body
236 made of the metal such as aluminum as in Embodiment
1.
Provided above the element substrate 210 are a
plurality of grooves for forming the second liquid flow
paths 204 constructed of the second liquid path walls,
the recessed portion for forming the second common
liquid chamber (common bubble-generating liquid
chamber) 244, communicating with the plurality of
second liquid flow paths 204, for supplying the bubble-
generating liquid to each of the second liquid flow
paths 204, .and the movable separation film 205 having
the thick portion 205a described above.
The grooved member 232 has the grooves for forming
the first liquid flow paths (discharge liquid flow
paths) 203 when ,joined with the movable separation film
205, the recessed portion for forming the first common
liquid chamber (common discharge liquid chamber) 243,
communicating with the discharge liquid flow paths, for
supplying the discharge liquid to each of the first
liquid flow paths 203, the first liquid supply path

CA 02375897 2002-03-20
- 81 -
(discharge liquid supply path) 233 for supplying the
discharge liquid to the first common liquid chamber
243, and the second liquid flow path (bubble-generating
liquid supply path) 234 for supplying the bubble-
s generating liquid to the second common liquid chamber
244. The second liquid supply path 234 is connected to
a communication passage communicating with the second
common liquid chamber 244 as passing through the
movable separation film 205 disposed outside the first
common liquid chamber 243, so that the bubble-
generating liquid can be supplied to the second common
liquid chamber 243 through this communication passage
without mixing with the discharge liquid.
The positional relation among the element
substrate 210, the movable separation film 205, and the
grooved member 232 is such that the thick portion 205a
is located corresponding to the heat-generating member
202 of the element substrate 210 and that the first
liquid flow path 203 is provided corresponding to this
thick portion 205a.
Next described is the process for fabricating the
movable separation film having the thick portion
described above.
The movable separation film having the thick
portion is made of a polyimide resin and is produced by
the following process.
Figs. 19A to 19E are drawings for explaining

CA 02375897 2002-03-20
j
- 82 -
fabrication steps of the movable separation film in the
liquid discharge apparatus shown in Figs. 13A and 13B
to Fig. 18.
First, a mirror wafer of silicon having portions
to become slacks of the movable separation film, which
are made of metal or resin, is coated with a release
agent and thereafter it is subjected to spin coating
with liquid polyimide resin described above to form a
film approximately 3 um thick (Fig. 19B).
Then this film is cured by ultraviolet irradiation
and thereafter it is subjected to further spin coating
to form another layer.
Next, the second resin layer is subjected to
exposure in the portion to become the thick portion
205a and development is carried out (Fig. 19C).
This forms the thick portion 205a on the thin film
(Fig. 19D).
After that, this film is peeled off from the
mirror wafer and is positioned and attached onto the
substrate in which the second liquid flow path
described above is formed, thereby making the movable
separation film on the substrate (Fig. 19E).
(Embodiment 6)
Figs. 20A and 20B are cross-sectional views along
the flow path direction to show the sixth embodiment of
the liquid discharge method and the liquid discharge
apparatus according to the present invention, wherein

CA 02375897 2002-03-20
- 83 -
Fig. 20A is a drawing to show a state upon non-
generation of bubble and Fig. 20B is a drawing to show
a state upon generation of bubble (upon discharge).
The present embodiment, as shown in Figs. 20A and
20B, has a separate member of movable member 231 as the
direction regulating means, whereas the direction
regulating means in the example shown in Figs. 13A and
13B was a part of the movable separation film 215 for
separating the first liquid flow path 213 from the
second liquid flow path 214.
Since in the present embodiment the direction
regulating means and the movable separation film are
separate members, the slack portion is provided on the
opposite side to that in the previous embodiment. As
for the direction of the slack portion, there is no
specific limitation on the direction as long as the
pressure upon generation of bubble can inflate the
slack portion toward the discharge port.
The movable separation film 215 is formed in
uniform thickness by the similar process to that in the
fifth embodiment described above.
The movable member 231 to be the direction
regulating means was fabricated by electroforming of
nickel.
The supply of the discharge liquid and the bubble-
generating liquid may be the same as that in the fifth
embodiment. In the case of the liquid discharge

CA 02375897 2002-03-20
- 84 -
apparatus of the present embodiment, the separate body
of the direction regulating means adds one step to the
assembling process as compared with that in the fifth
embodiment, but the separate arrangement of the movable
separation film 215 and the direction regulating means
can decrease the cost per component and, effectively
utilizing the spring property of nickel, the movable
separation film inflated can be returned efficiently to
the original position.
In the present embodiment the movable member 231
was made of nickel, but the present invention is not
limited to nickel. The material for the movable member
231 may be any material having elasticity for assuring
good operation as the movable member 231.
Figs. 21A to 21D are drawings for explaining the
liquid discharge method in a modification of the liquid
discharge apparatus shown in Figs. 20A and 20B.
In the present modification as shown in Figs. 21A
to 21D, slack portion 325a is disposed on the
downstream side of the movable separation film 305
facing the heat-generating member 302 and the upstream
side of the movable separation film 305 facing the
heat-generating member 302 has the function of the
direction regulating means.
In Fig. 21A, the energy such as the electric
energy is not applied to the heat-generating member 302
yet, so that the heat is not generated in the heat-

CA 02375897 2002-03-20
.) _ 85 _
generating member 302. In this state, the slack
portion 325a is slackened on the second liquid flow
path side.
Here, when the electric energy or the like is
applied to the heat-generating member 302, the heat-
generating member 302 generates heat and part of the
bubble-generating liquid filling the inside of the
bubble-generating region 307 is heated by the heat,
thus generating the bubble 306 by film boiling. When
the bubble 306 is generated, the slack portion 325a of
the movable separation film 305 is displaced from the
first position to the second position on the first
liquid flow path 303 side so as to guide propagation of
the pressure of the bubble 306 toward the discharge
port, by the pressure based on the generation of bubble
306 (Fig. 21B).
With further growth of bubble 306, the slack
portion 325a of the movable separation film 305 is
further displaced into the first liquid flow path 303
according to the pressure upon generation of bubble
(Fig. 21C).
After that, when the bubble 306 contracts to
disappear because of the decrease of internal pressure
of bubble characteristic to the film boiling phenomenon
described above, the slack portion 305a of the movable
separation film 305 having been displaced up to the
second position returns to the initial position (the

CA 02375897 2002-03-20
- 86 -
first position) by the restoring force due to the
negative pressure upon contraction of bubble 306 and
the spring property of the movable separation film 305
itself (Fig. 21D).
(Embodiment 7)
Figs. 22A and 22B are cross-sectional views along
the flow path direction to show the seventh embodiment
of the liquid discharge apparatus according to the
present invention, wherein Fig. 22A is a drawing to
show a state upon non-generation of bubble and Fig. 22B
is a state upon generation of bubble (upon discharge).
In the present embodiment, as shown in Figs. 22A
and 22B, the second liquid flow path 304 for bubble-
generating liquid is provided on the substrate 310
provided with the heat-generating member 302 (the
heating resistor member in the shape of 40 um x 105 um
in the present embodiment) for supplying the thermal
energy for generating the bubble in the liquid, and the
first liquid flow path 303 for discharge liquid in
direct communication with the discharge port 301 is
provided above it. The movable separation film 305
made of a thin film with little elasticity is provided
between the first liquid flow path 303 and the second
liquid flow path 304 and the movable separation film
305 separates the discharge liquid in the first liquid
flow path 303 from the bubble-generating liquid in the
second liquid flow path 304.

CA 02375897 2002-03-20
, - 87 -
Here, the movable separation film 305 in the
portion located in the projection area above the
surface of the heat-generating member 302 projects into
the second liquid flow path 304 upon non-generation of
bubble and distance L of projection from reference
surface 305B of the movable separation film is longer
on the downstream side, which is the discharge port 301
side of the first liquid flow path 303, than on the
upstream side, which is the common liquid chamber (not
shown) side, as shown in Fig. 22A. Thus, this shape is
inverted in Fig. 22B, thus achieving the displacing
step as stated in the present invention. Namely, since
the shape of the movable separation film is
preliminarily defined, desired displacement can be
achieved stably. Further, the simple structure is
achieved, because the direction regulating member is
the movable separation film itself.
The maximum volume (the sum of volumes made by the
projecting portion at each position of Fig. 22A and
Fig. 22B) caused by the displacement of convex portion
305a being the projecting portion is determined to be
larger than the maximum expansion volume of the bubble
generated in the bubble-generating region 307.
The distance between the surface of the movable
separation film 305 where the convex portion 305a is
not formed, and the surface of the heat-generating
member 302 is set to approximately 5 to 20 um. The

CA 02375897 2002-03-20
- 88 -
bubble-generating region 307 is defined between the
heat-generating member 302 and the convex portion 305a.
Here, when the electric energy or the like is
applied to the heat-generating member 302, the heat-
s generating member 302 generates heat and part of the
bubble-generating liquid filling the inside of the
bubble-generating region 307 is heated by the heat,
thus generating the bubble 306 by film boiling. When
the bubble 306 is generated, the convex portion 305a of
the movable separation film 305 is displaced from the
first position to the second position on the first
liquid flow path 303 side so as to guide propagation of
the pressure of the bubble 306 toward the discharge
port, by the pressure based on the generation of bubble
306.
In the present embodiment, since the movable
separation film 305 is formed so as to be displaced
into the first liquid flow path 303 by displacement of
the convex portion 305a, the energy upon generation of
bubble contributes more efficiently to the displacement
of the movable separation film 305, as compared with
the arrangement wherein the movable separation film 305
extends with generation of bubble to be displaced into
the first liquid flow path 303. Thus, the present
embodiment can achieve efficient discharge. Further,
since the convex portion 305a of the movable separation
film 305 is formed so that the maximum displacement

CA 02375897 2002-03-20
- 89 -
volume thereof becomes greater than the maximum
expansion volume of the bubble generated in the bubble-
generating region 407, the growth of bubble is not
regulated and further efficient discharge can be
achieved.
In the present embodiment, since the movable
separation film 305 is preliminarily projected into the
second liquid flow path 304, the displacement amount
becomes greater when the movable separation film 305 is
displaced from the first position to the second
position so as to guide propagation of pressure of
bubble 306 toward the discharge port, by the pressure
based on the generation of bubble 306, which increases
the discharge efficiency of liquid from the discharge
port 301. Since the distance L of the convex portion
305a of the movable separation film 305 is longer on
the discharge port 301 side than on the common liquid
chamber side, it is easy to transmit the pressure based
on the generation of bubble 306 to the discharge port
301 in the first liquid flow path 303 for discharge
liquid, which increases the discharge efficiency of
liquid from the discharge port 301.
After that, when the bubble 306 contracts to
disappear because of the decrease of internal pressure
of bubble characteristic to the film boiling phenomenon
described above, the convex portion 305a of the movable
separation film 305 having been displaced up to the

CA 02375897 2002-03-20
second position returns to the initial position (the
first position) by the restoring force due to the
negative pressure upon contraction of bubble 306 and
the spring property of the movable separation film 305
5 itself.
Further, since the structure of the liquid
discharge apparatus of the present invention also
achieves the effects as described in the foregoing
embodiments, the liquid such as the high-viscosity
10 liquid can be discharged at further higher discharge
efficiency and under further higher discharge force.
(Embodiment 8)
Figs. 23A and 23B are cross-sectional views along
the flow path direction to show the eighth embodiment
15 of the liquid discharge method and the liquid discharge
apparatus according to the present invention, wherein
Fig. 23A is a drawing to show a state upon non-
generation of bubble and Fig. 23B is a drawing to show
a state upon generation of bubble (upon discharge).
20 In the present embodiment, as shown in Figs. 23A
and 23B, in addition to the structure shown in Figs.
22A and 22B, the movable member 331, capable of being
displaced, for regulating displacement of the movable
separation film 305 is provided between the movable
25 separation film 305 and the first liquid flow path 303,
and the other structure is the same as in Figs. 22A and
22B. The movable member 331 is made by electroforming

CA 02375897 2002-03-20
_ 91 _
of nickel. The supply of the discharge liquid and the
bubble-generating liquid may be the same as described
in the seventh embodiment.
In the liquid discharge apparatus constructed as
described above, a large displaceable amount of the
movable separation film 305 upon generation of bubble
can also be assured stably. Further, the movable
member 331 can reinforce the action for guiding the
displacement of the movable separation film 305 toward
the discharge port. Since the movable separation film
305 is projecting into the second liquid flow path 304
upon non-generation of bubble, the liquid above the
projecting portion can also be guided to the discharge
port 301 upon generation of bubble.
The movable member 331 also helps the projecting
force of the convex portion 305a of the movable
separation film 305 into the second liquid flow path
304.
The present embodiment used nickel for the movable
member 331, but the present invention may employ any
material without having to be limited to it, if the
material has elasticity enough to assure good operation
as the movable member 331.
(Embodiment 9)
Figs. 24A and 24B are cross-sectional views along
the flow path direction to show the ninth embodiment of
the liquid discharge method and the liquid discharge

CA 02375897 2002-03-20
92
apparatus according to the present invention, wherein
Fig. 24A is a drawing to show a state upon non-
generation of bubble and Fig. 24B is a drawing to show
a state upon generation of bubble (upon discharge).
When the electric energy is applied to the heat-
generating member, the heat-generating member generates
heat and part of the bubble-generating liquid filling
the inside of the bubble-generating region is heated by
the heat, thus generating the bubble by film boiling.
On that occasion, the maximum expansion volume of
bubble is not always constant because of dispersion
elements due to the fabrication process, environmental
conditions, etc. or it may differ nozzle by nozzle.
Thus, the present embodiment, as shown in Figs.
24A and 248, is arranged so that the maximum
displacement volume of the convex portion 315a of the
movable separation film 315 is smaller than the maximum
expansion volume of the bubble 316 generated in the
bubble-generating region 307.
Specifically, since the dispersion of expansion
volume of bubble 316 due to the discharge
characteristics of liquid is ~10 %, the maximum
displacement volume of the convex portion 315a of the
movable separation film 315 is arranged to be 80 ~ or
less of the maximum expansion volume of the bubble 316
generated in the bubble-generating region 307.
This arrangement always keeps constant the

CA 02375897 2002-03-20
_ 93 _
displacement amount of the convex portion 315a of the
movable separation film 315 upon generation of bubble
even with dispersion of the expansion volume of bubble
316 due to the discharge characteristics of liquid,
whereby the discharge amount of the discharge liquid
becomes constant, thus achieving good discharge without
dispersion among nozzles.
(Embodiment 10)
Figs. 25A to 25C are drawings to show the tenth
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 25A is a cross-
sectional view along the flow path direction to show a
state upon non-generation of bubble, Fig. 25B is a
cross-sectional view along the flow path direction to
show a state upon generation of bubble (upon
discharge), and Fig. 25C is a drawing to show the
configuration of the second liquid flow path.
In the present embodiment, as shown in Figs. 25A
to 25C, the second liquid flow path 404 for bubble-
generating liquid is provided on the substrate 410
provided with the heat-generating member 402 (the
heating resistor member in the shape of 40 Nm x 105 um
in the present embodiment) for supplying the thermal
energy for generating the bubble in the liquid, and the
first liquid flow path 403 for discharge liquid in
direct communication with the discharge port 401 is
provided above it. The movable separation film 405

CA 02375897 2002-03-20
- 94 -
made of a thin film with elasticity is provided between
the first liquid flow path 403 and the second liquid
flow path 404, and the movable separation film 405
separates the discharge liquid in the first liquid flow
path 403 from the bubble-generating liquid in the
second liquid flow path 404.
When the heat-generating member 402 generates
heat, the heat acts on the bubble-generating liquid in
the bubble-generating region 407 between the movable
separation film 405 and the heat-generating member 402,
thereby generating the bubble based on the film boiling
phenomenon in the bubble-generating liquid. The
pressure based on the generation of bubble
preferentially acts on the movable separation film 405,
so that the movable separation film 405 is displaced so
as to develop greatly toward the discharge port 401.
This guides the bubble generated in the bubble-
generating region 407 toward the discharge port 401.
In the present embodiment the second liquid flow
path 404 is formed up to a further downstream position
over the bubble-generating region 407 located
immediately above the heat-generating member 402,
whereby flow resistance on the downstream side becomes
smaller than that immediately above the heat-generating
member 402, so as to make it easier to guide the
pressure due to the bubble generated by heat in the
heat-generating member 402 to downstream. Therefore,

CA 02375897 2002-03-20
_ 95 _
the movable separation film 405 is also displaced
toward the discharge port 401, thus achieving high
discharge efficiency and high discharge force.
Since direct action of the bubble itself can be
utilized by regulating growth of bubble in the second
liquid flow path, the effect appears from the initial
stage of generation of bubble.
Further, since the movable separation film 405
quickly returns to the position before displacement by
the pressure upon contraction of bubble 406 as the
bubble 406 contracts, the refilling speed of the
discharge liquid into the first liquid flow path 403 is
enhanced in addition to the control of the acting
direction of pressure, thereby achieving stable
discharge also in high-speed printing.
(Embodiment 11)
Figs. 26A and 26B are cross-sectional views along
the flow path direction to show the eleventh embodiment
of the liquid discharge method and the liquid discharge
apparatus according to the present invention, wherein
Fig. 26A is a drawing to show a state upon non-
generation of bubble and Fig. 26B is a drawing to show
a state upon generation of bubble (upon discharge).
In the present embodiment, as shown in Figs. 26A
and 26B, the wall of the second liquid flow path 411 on
the discharge port side of the heat-generating member
402 is formed in such a tapered shape as to expand

CA 02375897 2002-03-20
- 96 -
toward the discharge port, whereby the flow resistance
in and near the bubble-generating region 407 decreases
along the flow path toward the discharge port, so as to
make it easier to guide the pressure of bubble 416
generated by heat in the heat-generating member 402
toward the discharge port, thus achieving high
discharge efficiency and high discharge force,
similarly as in the tenth embodiment.
Figs. 27A and 27B are cross-sectional views along
the flow path direction to show modifications of the
liquid discharge apparatus shown in Figs. 26A and 26B,
wherein Fig. 27A is a drawing to show a modification in
which the part of the second liquid flow path wall is
formed stepwise and Fig. 27B is a drawing to show
another modification in which the part of the second
liquid flow path wall is formed in a shape with a
certain radius of curvature.
In the modification shown in Fig. 27A, the wall of
the second liquid flow path 424 on the discharge port
side of the heat-generating member 402 is formed in
such a stepped shape as to expand toward the discharge
port and in the modification shown in Fig. 27B, the
wall of the second liquid flow path 434 on the
discharge port side of the heat-generating member 402
is formed in such a shape with a certain radius of
curvature as to expand toward the discharge port. In
either case, the flow resistance in and near the

CA 02375897 2002-03-20
- 97 -
bubble-generating region 407 thus decreases toward the
discharge port, so as to make it easier to guide the
pressure of bubble generated by heat in the heat-
generating member 402 to the discharge port, thus
achieving high discharge efficiency and high discharge
force, similarly as in the embodiment shown in Figs.
26A and 26B.
(Embodiment 12)
Figs. 28A and 28B are drawings to show the twelfth
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 28A is a top
plan view to show the positional relation between the
second liquid flow path and the heat-generating member
and Fig. 28B is a perspective view of the arrangement
shown in Fig. 28A and wherein the discharge port is
located on the left side in Fig. 28A.
As shown in Figs. 28A and 28B, the second liquid
flow path in the present embodiment has such a shape
that the width of the second liquid flow path 444
gradually increases from upstream to downstream near
the heat-generating member 442, as compared with that
shown in Figs. 25A to 25C.
The discharge operation in the liquid discharge
apparatus constructed as described above will be
described in detail.
Figs. 29A to 29C are drawings for explaining the
discharge operation in the liquid discharge apparatus

CA 02375897 2002-03-20
- 98 -
shown in Figs. 28A and 28B, wherein Fig. 29A includes
cross-sectional views along 29A - 29A shown in Fig.
28A, Fig. 29B includes cross-sectional views along
29B - 29B shown in Fig. 28A, and Fig. 29C includes
cross-sectional views along 29C - 29C shown in Fig.
28A.
(I) in Figs. 29A to 29C, the electric energy is
not applied to the heat-generating member 442 yet, so
that no heat is generated in the heat-generating member
442. The movable separation film 445 is located at the
first position nearly parallel to the substrate 420.
Here, when the electric energy is applied to the
heat-generating member 442, the heat-generating member
442 generates heat and part of the bubble-generating
liquid filling the inside of the bubble-generating
region 447 is heated by the heat, thus generating the
bubble 446 by film boiling ((II) in Figs. 29A to 29C).
The heat by the heat-generating member 442 quickly
grows the bubble 446 thus generated, whereupon, because
of the shape of the second liquid flow path 444 shown
in Figs. 28A and 28B, the central portion of the bubble
grows large on the upstream side while the both end
portions thereof grow large on the downstream side,
thereby displacing the movable separation film 445
therewith ((III) in Figs. 29A to 29C).
With further growth of bubble 446, the central

CA 02375897 2002-03-20
_ 99 _
portion downstream grows largest, which displaces the
downstream portion of the movable separation film 445
greatly ((IV) in Figs. 29A to 29C).
After that, when the bubble 446 contracts to
disappear because of the decrease of the internal
pressure of bubble characteristic to the film boiling
phenomenon described above, the movable separation film
445 thus displaced returns to the initial position by
the restoring force due to the negative pressure upon
contraction of bubble 446 and the spring property of
the movable separation film 445 itself ((V) in Figs.
29A to 29C).
As described above, the pressure occurring with
generation of bubble 446 gradually becomes directed to
downstream, i.e., toward the discharge port.
This gradually decreases the flow resistance in
and near the bubble-generating region 447 toward the
discharge port, so as to make it easier to guide the
pressure of the bubble generated by heat in the heat-
generating member 442 toward the discharge port, thus
achieving high discharge efficiency and high discharge
force, similarly as in the tenth embodiment. This can
also transport the first liquid in the projection area
of the heat-generating member 442 to the discharge
port, thus increasing the discharge amount.
Figs. 30A to 30C are drawings to show
modifications of the liquid discharge apparatus shown

CA 02375897 2002-03-20
- 100 -
in Figs. 28A and 28B, wherein Fig. 30A is a drawing to
show a modification in which the width of the second
liquid flow path near the heat-generating member
gradually increases stepwise from upstream to
downstream, Fig. 30B is a drawing to show a
modification in which the width of the second liquid
flow path near the heat-generating member gradually
increases at a certain radius of curvature from
upstream to downstream, and Fig. 30C is a drawing to
show a modification in which the width of the second
liquid flow path near the heat-generating member
gradually increases at the opposite radius of curvature
to Fig. 30B from upstream to downstream. In either
drawing the discharge port is located on the left side
in the drawing.
Since in the modification shown in Fig. 30A the
width of the second liquid flow path 454 near the heat-
generating member 442 gradually increases stepwise from
upstream to downstream, since in the modification shown
in Fig. 30B the width of the second liquid flow path
464 near the heat-generating member 442 gradually
increases at the certain radius of curvature from
upstream to downstream, or since in the modification
shown in Fig. 30C the width of the second liquid flow
path 474 near the heat-generating member 442 gradually
increases at the opposite radius of curvature to Fig.
30B from upstream to downstream, the flow resistance in

CA 02375897 2002-03-20
- 101 -
and near the bubble-generating region gradually
decreases toward the discharge port in either case, so
as to make it easier to guide the pressure of the
bubble generated by heat in the heat-generating member
442 toward the discharge port, thus achieving high
discharge efficiency and high discharge force.
(Embodiment 13)
Figs. 31A to 31E are drawings for explaining the
operation of the liquid discharge apparatus to show the
thirteenth embodiment of the liquid discharge apparatus
according to the present invention.
In the present embodiment, similar to each of the
previous embodiments, the second liquid flow path 504
for bubble-generating liquid is provided on the
substrate 510 provided with the heat-generating member
502 (the heating resistor member in the shape of 40 um
x 105 um in the present embodiment) for supplying the
thermal energy for generating the bubble in the liquid,
and the first liquid flow path 503 for discharge liquid
in direct communication with the discharge port 501 is
provided above it. Further, the movable separation
film 505 made of a thin film with elasticity is
provided between the first liquid flow path 503 and the
second liquid flow path 504 and the movable separation
film 505 separates the discharge liquid in the first
liquid flow path 503 from the bubble-generating liquid
in the second liquid flow path 504. A further feature

CA 02375897 2002-03-20
- 102 -
of the present embodiment is that a movable separation
film displacement regulating member 531 having an
opening portion near the bubble-generating region 507
and arranged to restrict displacement of the movable
separation film 505 is provided on the first liquid
flow path 503 side of the movable separation film 505.
The discharge operation of the liquid discharge
apparatus of the present embodiment will be described
in detail with reference to Figs. 31A to 31E.
In Fig. 31A, the energy such as the electric
energy is not applied to the heat-generating member 502
yet, so that no heat is generated in the heat-
generating member 502. The movable separation film 505
is located at the first position nearly parallel to the
substrate 510.
An important point herein is that the center of
the opening portion of the movable separation film
displacement regulating member 531 is located
downstream of the center of the heat-generating member
502, which locates the center of the movable area of
the movable separation film 505 on the downstream side
of the center of the heat-generating member 502.
Here, when the electric energy or the like is
applied to the heat-generating member 502, the heat-
generating member 502 generates heat and part of the
bubble-generating liquid filling the inside of the
bubble-generating region 507 is heated by the heat,

CA 02375897 2002-03-20
- 103 -
thus generating the bubble 506 by film boiling. Since
the center of the movable area of the movable
separation film 505 is located downstream of the center
of the heat-generating member 502, the movable
separation film 505 becomes easier to be displaced on
the downstream side of the heat-generating member 502
by the pressure of bubble 506 (Fig. 31B).
With further growth of the bubble 506, the movable
separation film 506 is further displaced into the first
liquid flow path 503 according to the pressure upon
generation of bubble. As a result, the bubble 506
generated grows greater downstream than upstream, so
that the movable separation film 505 moves greatly over
the first position (Fig. 31C).
After that, as the bubble 506 contracts because of
the decrease of internal pressure of bubble
characteristic to the film boiling phenomenon described
above, the movable separation film 505 having been
displaced up to the second position gradually returns
to the initial position (the first position) shown in
Fig. 31A by the negative pressure upon contraction of
bubble 506 (Fig. 31D).
When the bubble 506 is collapsed, the movable
separation film 505 returns to the initial position
(the first position) (Fig. 31E). Upon collapse of
bubble, in order to compensate for the volume of liquid
ejected, the liquid flows as indicated by VD1, Vpz from

CA 02375897 2002-03-20
- 104 -
upstream, i.e., from the common liquid chambers and as
indicated by V~ from the discharge port 501. At this
time, since there was the flow of liquid from the heat-
generating member 502 to downstream (to the discharge
port), the flow of Vpl, Vp2 is greater, which is useful
to increase of refilling speed and decrease of
retracting amount of meniscus.
Since the opening portion of the movable
separation film 531 is rounded in the thickness
direction as shown in Figs. 3lA to 31E, stress
concentration on the movable separation film 505 in
this portion is relieved, so as to decrease degradation
of strength, thus improving durability.
Next described is the structure and fabrication
process of the liquid discharge apparatus described
above.
Figs. 32A to 32D are drawings for explaining the
positional relation among the heat-generating member
502, the second liquid flow path 504, and the movable
separation film displacement regulating member 531 in
the liquid discharge apparatus shown in Figs. 31A to
31E, wherein Fig. 32A is a drawing to show the
positional relation between the heat-generating member
502 and the second liquid flow path 504, Fig. 32B is a
top plan view of the movable separation film
displacement regulating member 531, Fig. 32C is a
drawing to show the positional relation among the heat-

CA 02375897 2002-03-20
- 105 -
generating member 502, the second liquid flow path 504,
and the movable separation film displacement regulating
member 531, and Fig. 32D is a drawing to show the
displaceable areas of the movable separation film 505
and wherein in either drawing the discharge port is
located on the left side of the drawing.
As shown in Fig. 32D, the present embodiment is
arranged so that the downward displaceable area of the
movable separation film 505 where the movable
separation film 505 can be displaced downward is the
area surrounded by the wall of. the second liquid flow
path 504, so that the upward displaceable area of the
movable separation film 505 where the movable
separation film 505 can be displaced upward is the area
in the opening portion of the movable separation film
displacement regulating member 531, and so that the
center of the movable area of the movable separation
film 505 is located downstream of the center of the
heat-generating member 502.
As shown in Fig. 32B, the four corners of the
opening portion 531a of the movable separation film
displacement regulating member 531 are rounded, so as
to prevent the movable separation film 505 from being
broken thereby, thus improving the durability.
The second liquid flow path 504 is provided with
constricted portions 509 for the same purposes as in
the fifth embodiment, before and after the heat-

CA 02375897 2002-03-20
- 106 -
generating member 502, and a large space is given on
the discharge port 501 side of the heat-generating
member 502.
As described above, since the structure of the
present embodiment is such that the center of the
movable area of the movable separation film is located
downstream of the center of the heat-generating member
whereby the movable separation film displaced according
to the pressure upon generation of bubble grows on the
downstream side, the liquid weak against heat, the
high-viscosity liquid, or the like can be discharged at
high efficiency and under high discharge pressure. In
addition, a further increase of discharge amount is
achieved by the transport action of the liquid in the
first liquid flow path.
(Embodiment 14)
Fig. 33 is a cross-sectional view along the flow
path direction to show the fourteenth embodiment of the
liquid discharge apparatus according to the present
invention.
In the present embodiment, as shown in Fig. 33,
the second liquid flow path 604 for bubble-generating
liquid is provided on the substrate 610 provided with
the heat-generating member 602 (the heating resistor
member in the shape of 40 um x 105 um in the present
embodiment) for supplying the thermal energy for
generating the bubble in the liquid, and the first

CA 02375897 2002-03-20
- 107 -
liquid flow path 603 for discharge liquid in direct
communication with the discharge port 601 is provided
above it. Further, the movable separation film 605
made of a thin film with elasticity is provided between
the first liquid flow path 603 and the second liquid
flow path 604 and the movable separation film 605
separates the discharge liquid in the first liquid flow
path 603 from the bubble-generating liquid in the
second liquid flow path 604.
When the heat-generating member 602 generates
heat, the bubble is generated based on the film boiling
phenomenon in the bubble-generating liquid. Here, the
flow resistance R1 downstream of the center of the area
of the heat-generating member 602 is greater than the
flow resistance RZ upstream thereof in the second liquid
flow path 604, whereby among the pressure based on the
generation of bubble, components downstream of the
center of area of the heat-generating member 602
preferentially act on the movable separation film 605
while upstream components act not only on the movable
separation film 605 but also on the upstream side.
Thus, as the bubble grows continuously, the
movable separation film 605 is displaced greater toward
the discharge port 601. This guides the pressure due
to the bubble generated in the bubble-generating region
607 to the discharge port 601.
The discharge operation of the liquid discharge

CA 02375897 2002-03-20
- 108 -
apparatus constructed as described above will be
described in detail.
Figs. 34A to 34D are drawings for explaining the
operation of the liquid discharge apparatus shown in
Fig. 33.
In Fig. 34A, the energy such as the electric
energy is not applied to the heat-generating member 602
yet, so that no heat is generated in the heat-
generating member 602.
Here, when the electric energy or the like is
applied to the heat-generating member 602, the heat-
generating member 602 generates heat and part of the
bubble-generating liquid filling the inside of the
bubble-generating region 607 is heated by the heat,
thus generating the bubble 606 by film boiling. When
the bubble 606 is generated, the pressure based on the
generation of bubble 606 starts displacing the movable
separation film 605 from the first position to the
second position with propagation of bubble 606 (Fig.
34B).
An important point herein is that the flow
resistance on the downstream side is greater than that
on the upstream side so that the pressure components on
the downstream side (on the discharge port side) of the
center of area of the heat-generating member 602
preferentially act on the movable separation film 605
in the second liquid flow path 604, as described above.

CA 02375897 2002-03-20
- 109 -
With further growth of bubble 606, the horizontal
components out of the downstream pressure components
become directed upward as being subject to the
downstream flow resistance described above. This makes
the most of the downstream pressure components
preferentially act on the movable separation film 605,
thereby further displacing the movable separation film
605 into the first liquid flow path 603. With this,
the movable separation film 605 is inflated greatly
toward the discharge port 601 (Fig. 34C).
Since the bubble 606 grows to downstream so as to
inflate the movable separation film 605 greater toward
the discharge port with gradual displacement of the
downstream portion of the movable separation film 605
into the first liquid flow path 603 according to the
growth of bubble 606 as described above, the pressure
upon generation of bubble 606 is directed uniformly
toward the discharge port 601. This enhances the
discharge efficiency of liquid from the discharge port
601. In guiding the bubble-generating pressure to the
discharge port 601, the movable separation film 605
rarely impedes transmission of the pressure, so that
the propagating direction of pressure and the growing
direction of bubble 606 can be controlled efficiently
according to the magnitude of the propagating pressure.
After that, when the bubble 606 contracts to
disappear due to the decrease of internal pressure of

CA 02375897 2002-03-20
- 110 -
bubble characteristic to the film boiling phenomenon
described above, the movable separation film 605 having
been displaced up to the second position is displaced
into the second liquid flow path 604 over the first
position because of the negative pressure due to the
contraction of bubble 606 and thereafter it returns to
the initial position (the first position) shown in Fig.
34A (Fig. 34D). Upon collapse of bubble, in order to
compensate for the volume of liquid ejected, the liquid
flows into the region as indicated by VD1, VDZ from
upstream, i.e., from the common liquid chambers and as
indicated by V~ from the discharge port 401. The liquid
also flows into the region from upstream in the second
liquid flow path 604.
The structure of the liquid discharge apparatus
described above will be described.
Fig. 35 is a drawing for explaining the structure
of the second liquid flow path 604 of the liquid
discharge apparatus shown in Fig. 33 and Figs. 34A to
34D, which is a top plan view of the second liquid flow
path 604 without the movable separation film 605. The
discharge port is located on the bottom side in the
drawing.
The second liquid flow path 604 is provided with
constricted portions 609a, 609b for the same purposes
as in Embodiment 5, before and after the heat-
generating member 602, thus forming such chamber

CA 02375897 2002-03-20
- 111 -
(bubble-generating chamber) structure as to prevent the
pressure upon generation of bubble from escaping
through the second liquid flow path 604. Here, the
constricted portions 609a, 609b of the second liquid
flow path 604 are formed so that the opening portion on
the downstream side (on the discharge port side) is
narrower than the opening portion on the upstream side
(on the common liquid chamber side). By making the
opening portion narrower on the downstream side as
, described, the flow resistance in the second liquid
flow path 604 can be made larger on the downstream side
and smaller on the upstream side. This makes the
downstream components of the pressure caused by the
generation of bubble effectively and preferentially act
on the movable separation film 605, so as to displace
the movable separation film 605 into the first liquid
flow path 603, whereby the liquid in the first liquid
flow path 603 can be discharged at high efficiency and
under high discharge force. The downstream constricted
portion 609a of the bubble-generating chamber of the
second liquid flow path 604 is a passage for extracting
bubbles remaining in the bubble-generating chamber.
The shape of the second liquid flow path 604 may
be determined in any shape that can effectively
transmit the pressure upon generation of bubble to the
movable separation film 605 without being limited to
the above shape.

CA 02375897 2002-03-20
') - 112 -
As described above, since in the structure of the
present embodiment the flow resistance downstream of
the center of the area of the heat-generating member is
greater than that upstream thereof in the second liquid
flow path whereby the movable separation film displaced
by the pressure upon generation of bubble grows to
downstream, the liquid weak against heat, the high-
viscosity liquid, or the like can be discharged at high
efficiency and under high discharge pressure.
(Embodiment 15)
Fig. 36 is a cross-sectional view along the flow
path direction to show the fifteenth embodiment of the
liquid discharge apparatus according to the present
invention, which shows a state upon generation of
bubble.
In the present embodiment, as shown in Fig. 36,
the second liquid flow path 704 for bubble-generating
liquid is provided on the substrate 710 provided with
the heat-generating member 702 (the heating resistor
member in the shape of 40 pm x 105 um in the present
embodiment) for supplying the thermal energy for
generating the bubble in the liquid, and the first
liquid flow path 703 for discharge liquid in direct
communication with the discharge port 701 is provided
above it. Further, the movable separation film 705
made of a thin film with elasticity is provided between
the first liquid flow path 703 and the second liquid

CA 02375897 2002-03-20
- 113 -
flow path 704 and the movable separation film 705
separates the discharge liquid in the first liquid flow
path 703 from the bubble-generating liquid in the
second liquid flow path 704.
The most significant feature of the present
embodiment is that the height of top plate 709 forming
the first liquid flow path 703, i.e., the height of the
first liquid flow path 703 in the projection area of
the heat-generating member 702 is higher on the
downstream side where the discharge port 701 exists
than on the upstream side where the common liquid
chamber (not illustrated) exists.
In the liquid discharge apparatus constructed as
described above, when the heat-generating member 702
generates heat, the bubble 706 is generated thereby
based on the film boiling phenomenon in the bubble-
generating liquid. Here, the movable separation film
705 is displaced into the first liquid flow path 703
with generation of bubble 706, but, because the height
of the first liquid flow path is higher on the
downstream side than on the upstream side, the movable
separation film 705 is displaced into the first liquid
flow path 703 greater on the downstream side than on
the upstream side. This guides the pressure due to the
bubble 706 generated in the bubble-generating region to
the discharge port 701.
The discharge operation of the liquid discharge

CA 02375897 2002-03-20
- 114 -
apparatus constructed as described above will be
described in detail.
Figs. 37A to 37D are drawings for explaining the
operation of the liquid discharge apparatus shown in
Fig. 36.
In Fig. 37A, the energy such as the electric
energy is not applied to the heat-generating member 702
yet, so that no heat is generated in the heat-
generating member 702. The movable separat~.on film 705
is located at the first position nearly parallel to the
substrate 710.
Here, when the electric energy or the like is
applied to the heat-generating member 702, the heat-
generating member 702 generates heat and part of the
bubble-generating liquid filling the inside of the
bubble-generating region 707 is heated thereby, thus
generating the bubble 706 by film boiling. This
totally displaces the portion of the movable separation
film 705 facing the bubble-generating region 707 into
the first liquid flow path 703 (Fig. 37B).
With further growth of bubble 706, the movable
separation film 705 is displaced further into the first
liquid flow path 703 up to the second position
according to the pressure upon generation of bubble,
whereupon, because the height of the first liquid flow
path 703 is greater on the downstream side than on the
upstream side, the movable separation film 705 is

CA 02375897 2002-03-20
- 115 -
displaced more into the first liquid flow path 703 on
the downstream side than on the upstream side (Fig.
37C). Therefore, a further increase in the discharge
efficiency can be achieved.
After that, when the bubble 706 contracts to
disappear due to the decrease of internal pressure of
bubble characteristic to the film boiling phenomenon
described above, the movable separation film 705 having
been displaced up to the second position gradually
returns to the initial position (the first, position)
shown in Fig. 37A by the negative pressure due to the
contraction of bubble 706 (Fig. 37D). Upon collapse of
bubble, in order to compensate for the volume of the
liquid ejected, the liquid flows into the area from
upstream, i.e., from the common liquid chamber side and
from the discharge port 701 side.
This can prevent the meniscus from being retracted
by the decrease of volume of liquid due to the
displacement into the first liquid flow path 703,
caused when the movable separation film 705 is
displaced back to the second liquid flow path 704.
Therefore, the refilling time can be decreased.
(Embodiment 16)
Fig. 38 is a cross-sectional view along the flow
path direction to show the sixteenth embodiment of the
liquid discharge method and the liquid discharge
apparatus according to the present invention, which

CA 02375897 2002-03-20
- 116 -
shows a state upon generation of bubble.
The present embodiment is different from that
shown in Fig. 36 in the shape of the top plate 719,
i.e., in the shape of the first liquid flow path 713,
as shown in Fig. 38, and the other structure is the
same.
The top plate 719 in the present embodiment is
formed so that the height of the portion upstream of
the space above the heat-generating member 702 is
smaller than that of the other portions.
Here, the movable separation film 705 is displaced
into the first liquid flow path 713 with generation of
bubble 716, but, because the height of the first liquid
flow path 713 in the portion upstream of the area above
the heat-generating member 702 is smaller than that of
the other portions, the movable separation film 705 is
displaced more into the first liquid flow path 713 on
the downstream side than on the upstream side. This
guides the pressure due to the bubble 716 generated in
the bubble-generating region to the discharge port 701.
Since the flow resistance in the first liquid flow path
713 is higher upstream than downstream, the discharge
efficiency is increased and the supply characteristics
from upstream in the first liquid flow path are good,
thereby further improving the refilling
characteristics.
(Embodiment 17)

CA 02375897 2002-03-20
y - 117 -
Fig. 39 is a cross-sectional view along the flow
path direction to show the seventeenth embodiment of
the liquid discharge method and the liquid discharge
apparatus according to the present invention, which
shows a state upon generation of bubble.
The present embodiment, as shown in Fig. 39, is
different from that shown in Fig. 38 in that the
movable separation film 729 comes to contact the low-
height portion of the top plate 719 upon generation of
bubble and the other structure is the same.
Here, the movable separation film 725 is displaced
into the first liquid flow path 723 with generation of
bubble 736, but, because the height of the first liquid
flow path 723 in the portion upstream of the area above
the heat-generating member 702 is smaller than that of
the other portions, the movable separation film 725 is
displaced more into the first liquid flow path 723 on
the downstream side than on the upstream side. Then
with further growth of bubble 736 the movable
separation film 725 displaced into the first liquid
flow path 723 comes to contact the low-height portion
of the top plate 719 of the first liquid flow path 723
whereby the movable separation film 725 is deformed as
depressed by the top plate 719. This further displaces
the downstream portion of the movable separation film
725 greater into the first liquid flow path 723
thereby guiding the pressure due to the bubble 736

CA 02375897 2002-03-20
- 118 -
generated in the bubble-generating region to the
discharge port 701. Since the part of the top plate
719 contacts the part of the movable separation film
725, the first liquid flow path 723 is separated into
two on either side of the contact portion, which
prevents crosstalk and which prevents the pressure upon
generation of bubble from escaping to upstream, thus
increasing the discharge efficiency.
(Embodiment 18)
Figs. 40A and 40B are cross-sectional views along
the flow path direction to show the eighteenth
embodiment of the liquid discharge method and the
liquid discharge apparatus according to the present
invention, wherein Fig. 40A is a drawing to show a
state upon non-generation of bubble and Fig. 40B is a
drawing tv show a state upon generation of bubble.
The present embodiment, as shown in Figs. 40A and
40B, is different only in the movable separation film
715 from that shown in Fig. 38 and the other structure
is the same.
As shown in Figs. 40A and 40B, the movable
separation film 715 in the present embodiment has slack
portions 715a, 715b upstream and downstream of the
bubble-generating region 707 for generating the bubble
on the heat-generating member 702, thus forming the
structure with spring property.
Here, the movable separation film 715 is displaced

CA 02375897 2002-03-20
- 119 -
into the first liquid flow path 713 with generation of
bubble 726, but, because the height of the first liquid
flow path 713 in the portion upstream of the region
above the heat-generating member 702 is lower than that
of the other portions, the movable separation film 715
is displaced more into the first liquid flow path 713
on the downstream side than on the upstream side. This
guides the pressure due to the bubble 726 generated in
the bubble-generating region 707 to the discharge port
701. Since the flow resistance in the first liquid
flow path 713 is higher on the upstream side than on
the downstream side, the refilling characteristics are
improved. Since the present embodiment employs the
structure wherein the movable separation film 715 is
provided with the slack portions 715a, 715b upstream
and downstream of the bubble-generating region 707
whereby the movable separation film 715 has the spring
property, the movable separation film 715 becomes
easier to be displaced by the pressure upon generation
of bubble, thus increasing the discharge efficiency.
(Embodiment 19)
Fig. 41 is a cross-sectional view along the flow
path direction to show the nineteenth embodiment of the
liquid discharge method and the liquid discharge
apparatus according to the present invention, which
shows a state upon generation of bubble.
In the present embodiment, as shown in Fig. 41,

CA 02375897 2002-03-20
- 120 -
the second liquid flow path 704 for bubble-generating
liquid is provided on the substrate 710 provided with
the heat-generating member 702 (the heating resistor
member in the shape of 40 um x 105 um in the present
embodiment) for supplying the thermal energy for
generating the bubble in the liquid, and the first
liquid flow path 733 for discharge liquid in direct
communication with the discharge port 701 is provided
above it. Further, the movable separation film 735
made of a thin film with elasticity is provided between
the first liquid flow path 733 and the second liquid
flow path 704 and the movable separation film 735
separates the discharge liquid in the first liquid flow
path 733 from the bubble-generating liquid in the
second liquid flow path 704. In the first liquid flow
path 733 the movable member 751 having a free end in
the area above the heat-generating member 702 and a
fulcrum upstream thereof is disposed nearly in parallel
to the movable separation film 735 and at a
predetermined distance from the movable separation film
735. The distance between the movable member 751 and
the movable separation film 735 is set to be such a
separation that the free end of the movable member 751
is pushed up by the movable separation film 735 when
the movable separation film 735 is displaced into the
first liquid flow path 733 by the pressure upon
generation of bubble.

CA 02375897 2002-03-20
- 121 -
Here, the movable separation film 735 is displaced
into the first liquid flow path 703 with generation of
bubble 746. Once the upstream portion of the movable
separation film comes to near or into contact with the
movable member 751 with displacement of the movable
separation film 735 into the first liquid flow path
733, the movable member 751 restricts the displacement
of the upstream portion of the displaced portion of the
movable separation film 735, so that the movable
separation film 735 is displaced more into the first
liquid flow path 733 on the downstream side than on the
upstream side. This guides the pressure due to the
bubble 746 generated in the bubble-generating region to
the discharge port 701.
Since the present embodiment is arranged so that
the action of the movable member 751 prevents excessive
displacement of the movable separation film 735 and so
that the movable member 751 and the movable separation
film 735 are located the predetermined distance apart
from each other upon non-generation of bubble, there is
no resistance in the initial stage of displacement of
the movable separation film 735, thus making reaction
quicker.
The fifteenth to nineteenth embodiments described
above were achieved noting the flow resistance of
liquid above the movable area of the movable separation
film and in the first liquid flow path.

CA 02375897 2002-03-20
- 122 -
(Embodiment 20)
Figs. 42A and 42B are cross-sectional, schematic
views along the flow path direction to show the
twentieth embodiment of the liquid discharge method and
the liquid discharge apparatus according to the present
invention, wherein Fig. 42A is a drawing to show a
state upon non-discharge and Fig. 42B is a drawing to
show a state upon discharge.
In the present embodiment, as shown in Figs. 42A
and 42B, the second liquid flow path 804 for bubble-
generating liquid is provided on the substrate 810
provided with the heat-generating member 802 (the
heating resistor member in the shape of 40 um x 105 um
in the present embodiment) for supplying the thermal
energy for generating the bubble in the liquid, and the
first liquid flow path 803 for discharge liquid in
direct communication with the discharge port 801 is
provided above it. The movable separation film 805
made of a thin film with elasticity is provided between
the first liquid flow path 803 and the second liquid
flow path 804 and separates the discharge liquid in the
first liquid flow path 803 from the bubble-generating
liquid in the second liquid flow path 804.
Here, the movable separation film 805 is made so
that the thickness of the downstream side from the
center of the heat-generating member 802 is smaller
than the thickness of the upstream side therefrom in

CA 02375897 2002-03-20
- 123 -
the portion located in the projection area above the
surface of the heat-generating member 802, thereby
operating to deform more to the discharge port 801 upon
generation of bubble (Fig. 42H).
The shape of the movable separation film 805 may
be any shape that can direct the pressure upon
generation of bubble toward the discharge port
efficiently, without having to be limited to that shown
in Figs. 42A and 42B.
The bubble-generating region 807 is defined
between the heat-generating member 802 and the movable
separation film 805.
When the heat-generating member 802 generates
heat, the bubble is generated thereby based on the film
boiling phenomenon in the bubble-generating liquid.
The pressure based on the generation of bubble
preferentially acts on the movable separation film 805,
so that the movable separation film 805 is displaced
greater toward the discharge port 801, as shown in Fig.
42B. This guides the pressure due to the bubble
generated in the bubble-generating region 807 to the
discharge port 801.
As described above, since the structure of the
present embodiment is such that in the projection area
above the surface of the heat-generating member in the
movable separation film the thickness of the downstream
side from the center of the heat-generating member is

CA 02375897 2002-03-20
- 124 -
smaller than the thickness of the upstream side
therefrom, the pressure positively acts on the thin
portion in the movable separation film displaced by the
pressure upon generation of bubble, so ws to inflate
the movable separation film toward the discharge port,
whereby the liquid can be discharged at high discharge
efficiency and under high discharge pressure.
(Embodiment 21)
Figs. 43A and 43B are cross-sectional views along
the flow path direction to show the twenty first
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 43A is a
lateral, cross-sectional view and Fig. 43B is a
longitudinal, cross-sectional view. In the drawing the
discharge port is located on the left side thereof.
The movable separation film 815 in the present
embodiment gradually decreases its thickness from
upstream toward downstream where the discharge port is
provided. The movable separation film 815 is made of
urethane resin.
The process for fabricating the movable separation
film 815 in the present embodiment will be described.
First, the release agent is applied onto a mirror
wafer of silicon, thereafter it is subjected to spin
coating with liquid urethane resin to form a film
approximately 3 um thick, and then solvent therein is
evaporated to make the film thinner.

CA 02375897 2002-03-20
- 125 -
Then this film is peeled off from the mirror
wafer, the rear end (upstream) thereof is fixed onto
the substrate in which the second liquid flow path
described above is formed, thereafter the film is
pulled toward the discharge port so as to make the
thickness of the tip portion of film equal to 1 um, and
the film is bonded to the substrate, thus forming the
movable separation film on the substrate.
By making the movable separation film 815 in this
way, the movable separation film 815 naturally deforms
toward the discharge port with growth of bubble, so
that the discharge force can be used for discharge of
liquid efficiently. Since the movable separation film
815 in the present embodiment is excellent in response
to the growth of bubble, it can also be applied to
high-speed discharge. Since high position accuracy is
not required in bonding of the movable separation film
815, fabrication of the liquid discharge apparatus
becomes easier.
Another fabrication process of the movable
separation film 815 in the present embodiment will be
described.
First, the release agent is applied onto the
mirror wafer of silicon, thereafter the mirror wafer is
immersed in the liquid urethane resin, and it is lifted
up slowly. The film thickness can be increased
gradually by gradually decreasing the lifting speed of

CA 02375897 2002-03-20
- 126 -
mirror wafer on that occasion. After that, the solvent
is evaporated to make the film thinner.
Then this film is peeled off from the mirror
wafer, the film is positioned on the substrate in which
the second liquid flow path described above is formed,
and it is bonded to the substrate, thus forming the
movable separation film on the substrate.
By fabricating the movable separation film 815 in
this way, the movable separation film 815 naturally
deforms toward the discharge port with growth of
bubble, so that the discharge force can be used for
discharge of liquid efficiently. Since the movable
separation film 815 in the present embodiment is
excellent in response to growth of bubble, it can also
be applied to high-speed discharge.
(Embodiment 22)
Figs. 44A and 44B are cross-sectional views along
the flow path direction to show the twenty second
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 44A is a
lateral, cross-sectional view and Fig. 44B is a
longitudinal, cross-sectional view. In the drawing the
discharge port is located on the left side thereof.
As shown in Figs. 44A and 44H, the movable
separation film 825 in the present embodiment is formed
so that the thickness of the downstream side thereof is
smaller than that of the upstream side thereof with

CA 02375897 2002-03-20
- 127 -
respect to the border at a predetermined position on
the downstream side where the discharge port is
provided, from the center of the heat-generating member
802. The movable separation film 825 is made of the
polyimide resin.
The fabrication process of the movable separation
film 825 in the present embodiment will be described.
Figs. 45A to 45E are drawings for explaining the
fabrication process of the movable separation film 825
shown in Figs. 44A and 44B.
First, the release agent is applied onto the
mirror wafer 871 of silicon as shown in Fig. 45A and
thereafter it is subjected to spin coating with liquid
polyimide resin to form a film thereof approximately 2
um thick (Fig. 45B).
Then the film 872 is cured by ultraviolet
irradiation and resist 873 10 um thick is patterned
thereon (Fig. 45C).
Next, further spin coating is carried out to form
film 874 2 um thick of the polyimide resin (Fig. 45D).
After that, the film 874 is cured by ultraviolet
irradiation, the films 872, 874 thus formed are peeled
off from the mirror wafer 871, then they are positioned
on the substrate in which the second liquid flow path
described above is formed, and the films are bonded to
the substrate, thus forming the movable separation film
on the substrate (Fig. 45E).

CA 02375897 2002-03-20
- 128 -
The films 872, 874 may be made of respective
materials different from each other. Another process
may be arranged so that the film 872 is made separately
from the film 874 and they are joined with each other
in the assembling stage so as to achieve the form as in
the present embodiment.
By fabricating the movable separation film 825 in
this way, the movable separation film 825 naturally
deforms toward the discharge port with generation of
bubble, whereby the discharge force can be used for
discharge of liquid efficiently. Since the movable
separation film 825 in the present embodiment is
excellent in response to growth of bubble, it can also
be applied to high-speed discharge.
(Embodiment 23)
Figs. 46A and 46B are cross-sectional views along
the flow path direction to show the twenty third
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 46A is a
lateral, cross-sectional view and Fig. 46B is a
longitudinal, cross-sectional view. In the drawing the
discharge port is located on the left side thereof.
As shown in Figs. 46A and 46B, the movable
separation film 835 in the present embodiment is formed
so that the thickness of the downstream side thereof is
smaller than the thickness of the upstream side thereof
with respect to the border at a predetermined position

CA 02375897 2002-03-20
- 129 -
on the downstream side where the discharge port is
provided, from the center of the heat-generating member
802 and so that the thickness of the downstream side is
greater than the thickness of the upstream side with
respect to the border at a predetermine position on the
further downstream side of the downstream edge of the
heat-generating member 802. The movable separation
film 835 is made of the polyimide resin.
The fabrication process of the movable separation
film 835 in the present embodiment will be described.
Figs. 47A to 47E are drawings for explaining the
process for producing the movable separation film shown
in Figs. 46A and 46B.
First, the release agent is applied onto the
mirror wafer 871 of silicon as shown in Fig. 47A,
thereafter it is subjected to spin coating with liquid
polyimide resin to form a film approximately 3 um
thick, and the film is cured by ultraviolet irradiation
(Fig. 47B).
Then patterned resist 876 was formed over non-
etching portions on the film 875 approximately 3 um
thick described above. The resist was OFPR800
(available from Tokyo Ohka Shay.
The resist 876 was applied in the thickness of 6
pm and pre-baked at 100 °C. Exposure was carried out
using PLA600 available from CANON INC. and in the
exposure dose of 450 mJ. Development was carried out

CA 02375897 2002-03-20
- 130 -
using the developer of MND-3 (available from Tokyo Ohka
Sha) and thereafter post-baking was carried out at
120 °C (Fig. 47C).
Then the film 875 of the polyimide resin was
etched only by the thickness of 2 dam. The etching was
carried out with MAS-800 available from CANON INC. and
under such conditions as the substrate temperature of
50 °C, microwave power of 500 V~1, oxygen flow rate of
200 sccm, and pressure of 100 Pa (Fig. 47D).
Then, for removing the resist 876, the wafer was
immersed in remover 1112-A (available from Shipley Far
East Ltd.) and ultrasonic wave was applied thereto,
thereby removing the resist 876.
After that, the film 875 of the polyimide resin
was peeled off from the mirror wafer 871, it was
positioned on the substrate in which the second liquid
flow path described above was formed, and it was bonded
to the substrate, thus forming the movable separation
film on the substrate (Fig. 47E).
By fabricating the movable separation film 835 in
this way, the movable separation film 835 naturally
deforms toward the discharge port with growth of
bubble, whereby the discharge force can be used for
discharge of liquid efficiently. Since the movable
separation film 835 in the present embodiment is
excellent in response to growth of bubble, it can also
be applied to high-speed discharge.

CA 02375897 2002-03-20
- 131 -
Figs. 48A and 48B are drawings to show a similar
form of the movable separation film shown in Figs. 46A
and 46B and Figs. 47A to 47E, wherein Fig. 48A is a
lateral, cross-sectional view and Fig. 48B is a
longitudinal, cross-sectional view. In the drawing the
discharge port is disposed on the left side thereof.
As shown in Figs. 48A and 48B, the thin portion
having the smaller film thickness may be formed every
liquid flow path in the similar form of the movable
separation film shown in Figs. 46A and 46B and Figs.
47A to 47E. This arrangement makes the bubble-
generating pressure concentrated toward the discharge
port efficiently.
(Embodiment 24)
Figs. 49A and 49B are cross-sectional views along
the flow path direction to show the twenty fourth
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 49A is a
lateral, cross-sectional view and Fig. 49B is a
longitudinal, cross-sectional view. In the drawing the
discharge port is disposed on the left side thereof.
As shown in Figs. 49A and 49B, the movable
separation film 855 in the present embodiment is formed
so that the thickness of the downstream side thereof is
smaller than the thickness of the upstream side thereof
with respect to the border at a predetermined position
on the upstream side from the center of the heat-

CA 02375897 2002-03-20
- 132 -
generating member 802 and so that the thickness of the
downstream side thereof is lager than the thickness of
the upstream side thereof with respect to the border at
the downstream edge of the heat-generating member 802.
The movable separation film 855 is made of the
polyimide resin and it was fabricated by the same
process as in the twenty second embodiment.
By fabricating the movable separation film 855 in
this way, the movable separation film 855 naturally
deforms toward the discharge port with growth of
bubble, whereby the discharge force can be used for
discharge of liquid efficiently. Since the movable
separation film 855 in the present embodiment is
excellent in response to growth of bubble, it can also
be applied to high-speed discharge.
The thin portion having the smaller film thickness
may be formed every liquid flow path in a similar form,
of the present embodiment. This arrangement makes the
bubble-generating pressure concentrated to the
discharge port efficiently.
(Embodiment 25)
Figs. 50A and 50B are cross-sectional views along
the flow path direction to show the twenty fifth
embodiment of the liquid discharge apparatus according
to the present invention, wherein Fig. 50A is a
lateral, cross-sectional view and Fig. 50B is a
longitudinal, cross-sectional view. In the drawing the

CA 02375897 2002-03-20
- 133 -
discharge port is located on the left side thereof.
As shown in Figs. 50A and 50B, the movable
separation film 865 in the present embodiment has a
portion decreasing its thickness toward downstream from
the center of heat-generating member 802. The movable
separation film 865 is made of the polyimide resin.
The fabrication process of the movable separation
film 865 in the present embodiment will be described.
Figs. 51A to 51D are drawings for explaining the
fabrication process of the movable separation film 865
shown in Figs. 50A and 50B.
First, a part on silicon substrate 877 to be a
matrix mold is masked using silicon oxide 878 of a rod
shape 4 um square (Fig. 51A) and anisotropic etching is
carried out thereon (Fig. 51B).
Then the release agent is applied onto the silicon
substrate 877, thereafter it is subjected to spin
coating with liquid polyimide resin to form film 879
approximately 3 um thick, and the film is cured by
ultraviolet irradiation (Fig. 51C).
After that, the film 879 is peeled off from the
silicon substrate 877, it is positioned on the
substrate in which the second liquid flow path
described above is formed, and it is bonded to the
substrate, thus forming the movable separation film on
the substrate (Fig. 51D).
By fabricating the movable separation film 865 in

CA 02375897 2002-03-20
- 134 -
this way, the movable separation film 865 naturally
deforms toward the discharge port with growth of
bubble, whereby the discharge force can be used for
discharge of liquid efficiently. Since the movable
separation film 865 in the present embodiment is
excellent in response to the growth of bubble, it can
also be applied to high-speed discharge.
Also, the thin portion having the smaller film
thickness may be fabricated every liquid flow path in a
similar form of the present embodiment. This
arrangement makes the bubble-generating pressure
concentrated toward the discharge port efficiently.
The present invention was described using the
discharge method for discharging the liquid in the
direction parallel to the flow direction of liquid in
the first liquid flow path in the all embodiments
described above, but the present invention, without
having to be limited to the above discharge method, can
also be applied to the discharge method for discharging
the liquid in the direction perpendicular to the flow
direction of the liquid in the first liquid flow path,
provided that the discharge port is provided downstream
of the region for generating the bubble.
Figs. 52A and 52B are cross-sectional views along
the flow path direction to show an example in which the
present invention is applied to the arrangement wherein
the discharge port is located downstream of the bubble-

CA 02375897 2002-03-20
- 135 -
generating region so as to discharge the liquid in the
direction perpendicular to the flow direction of the
liquid in the first liquid flow path, wherein Fig. 52A
is a drawing to show a state upon non-generation of
bubble and Fig. 52B is a drawing to show a state upon
generation of bubble.
As shown in Figs. 52A and 52B, the same effects
can be achieved by employing the structure of each
embodiment described above in the arrangement wherein
the discharge port 901 is located in the direction
perpendicular to the flow direction of the liquid in
the first liquid flow path 903, if the discharge port
901 is located downstream of the bubble-generating
region 907.
In the present invention, the liquid in the first
liquid flow path can be discharged efficiently from the
discharge port with generation of bubble, because the
downstream portion of the movable separation film is
displaced relatively greater toward the discharge port
than the upstream portion of the movable separation
film with respect to the flow direction of the liquid.

Representative Drawing
A single figure which represents the drawing illustrating the invention.
Administrative Status

2024-08-01:As part of the Next Generation Patents (NGP) transition, the Canadian Patents Database (CPD) now contains a more detailed Event History, which replicates the Event Log of our new back-office solution.

Please note that "Inactive:" events refers to events no longer in use in our new back-office solution.

For a clearer understanding of the status of the application/patent presented on this page, the site Disclaimer , as well as the definitions for Patent , Event History , Maintenance Fee  and Payment History  should be consulted.

Event History

Description Date
Time Limit for Reversal Expired 2008-06-06
Letter Sent 2007-06-06
Grant by Issuance 2003-09-16
Inactive: Cover page published 2003-09-15
Inactive: Final fee received 2003-06-30
Pre-grant 2003-06-30
Notice of Allowance is Issued 2002-12-31
Letter Sent 2002-12-31
Notice of Allowance is Issued 2002-12-31
Inactive: Approved for allowance (AFA) 2002-12-16
Amendment Received - Voluntary Amendment 2002-11-04
Inactive: Cover page published 2002-05-21
Inactive: S.30(2) Rules - Examiner requisition 2002-05-02
Inactive: Office letter 2002-04-30
Inactive: First IPC assigned 2002-04-29
Letter sent 2002-04-16
Application Received - Regular National 2002-04-11
Letter Sent 2002-04-11
Divisional Requirements Determined Compliant 2002-04-11
Application Received - Divisional 2002-03-20
Request for Examination Requirements Determined Compliant 2002-03-20
All Requirements for Examination Determined Compliant 2002-03-20
Application Published (Open to Public Inspection) 1997-12-07

Abandonment History

There is no abandonment history.

Maintenance Fee

The last payment was received on 2003-04-04

Note : If the full payment has not been received on or before the date indicated, a further fee may be required which may be one of the following

  • the reinstatement fee;
  • the late payment fee; or
  • additional fee to reverse deemed expiry.

Please refer to the CIPO Patent Fees web page to see all current fee amounts.

Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
CANON KABUSHIKI KAISHA
Past Owners on Record
AYA YOSHIHIRA
HIROYUKI ISHINAGA
HIROYUKI SUGIYAMA
KIYOMITSU KUDO
SATOSHI SHIMAZU
TOSHIO KASHINO
YOICHI TANEYA
YOSHIE ASAKAWA
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
Documents

To view selected files, please enter reCAPTCHA code :



To view images, click a link in the Document Description column. To download the documents, select one or more checkboxes in the first column and then click the "Download Selected in PDF format (Zip Archive)" or the "Download Selected as Single PDF" button.

List of published and non-published patent-specific documents on the CPD .

If you have any difficulty accessing content, you can call the Client Service Centre at 1-866-997-1936 or send them an e-mail at CIPO Client Service Centre.


Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Representative drawing 2002-05-16 1 7
Claims 2002-11-04 2 79
Representative drawing 2002-12-18 1 6
Cover Page 2003-08-07 1 40
Description 2002-03-20 135 4,926
Drawings 2002-03-20 43 684
Abstract 2002-03-20 1 23
Claims 2002-03-20 3 107
Cover Page 2002-05-16 1 40
Acknowledgement of Request for Examination 2002-04-11 1 180
Commissioner's Notice - Application Found Allowable 2002-12-31 1 160
Maintenance Fee Notice 2007-07-18 1 172
Correspondence 2002-04-12 1 43
Correspondence 2002-04-30 1 13
Fees 2003-04-04 1 30
Correspondence 2003-06-30 1 37
Fees 2004-04-16 1 37