Note: Descriptions are shown in the official language in which they were submitted.
CA 02405862 2002-10-11
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Spherical Compacted Unit Dose Softener
Field of the Invention
This invention relates to wash cycle unit dose laundry compositions for
softening or
conditioning fabrics. More particularly, this invention relates to unit dose
fabric softening
compositions which are compacted granular compositions spherical in shape and
suitable for
use in the wash cycle of an automatic washing machine.
Background of the Invention
Detergent compositions manufactured in the form of tablets of compacted
detergent
powder are known in the art. LT.S. 5,225,100, for example, describes a tablet
of compacted
powder comprising an anionic detergent compound which will adequately disperse
in the
wash water.
Although detergent compositions shaped as tablets have received much attention
in the
patent literature, the use of such tablets to provide a unit dose fabric
softener which will soften
or condition fabrics without impairing detergency is not known.
One possible option for providing a unit dose softener is to introduce the
softening
ingredients directly into the rinse cycle. But, for this type of product to be
effective several
practical requirements must be met. To begin with, the size and shape of the
unit dose
container must be readily compatible with the geometry of a wide variety of
rinse cycle
dispensers designed for home washing machines in order to insure its easy
introduction into
the dispenser.
Further, the unit dose composition must be formulated to readily dispense its
contents
upon contact with water in a period of time corresponding to the residence
time of the unit
dose in the dispenser, namely, the period of time during which water enters
and flows through
the rinse cycle dispenser. The aforementioned practical requirements have to
date not been
successfully met and therefore there remains a need in the art for a
commercially acceptable
unit dose softener capable of activation in the rinse cycle.
Wash cycle softeners are known in, the art which condition fabrics during the
period of
the wash cycle. Tablet unit doses for detergent compositions are also known.
Such tablets
are typically flat compacted unit compositions which conceptuallyoffer
numerous advantages
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to the consumer such as: ease of dosing; cleaner wash cycle dispensers
resulting from not
being dosed with Ioose powder; less bulk to carry and dispense; ease of
handling relative to
liquids; and environmental benefits attendant to reduced packaging
requirements.
But, despite these advantages. there is a major drawback which occurs in front
loading
washing machines which represent at least 90% of the European market, and are
gaining in
consumer acceptance in North America. In front loading machines, a flat
compacted object
when introduced into the wash cycle often becomes trapped within a few minutes
in the
rubber seal surrounding the window of the washing machine. Once trapped in the
seal, the
tablet tends to remain trapped until the wash cycle is over and is
consequently not dispersed in
the wash water. To overcome this problem, different approaches have been
taken.
Some tablet manufacturers provide a net or sachet designed to contain the
tablet unit
dose, and thereby avoid the problem of direct contact between the tablet and
the seal.
Another proposed solution involves providing a rapidly dispersible tablet in
the wash water by
incorporating an effervescent matrix and/or a disintegration agent into the
tablet. But, these
proposed options are generally uneconomical and often result in an unduly
fragile tablet
unable to readily withstand normal handling by the consumer without
fracturing. Thus, there
is a need for an economical unit dose tablet capable of providing conditioning
of fabrics, and
which retains its physical integrity during normal handling prior to being
introduced into the
washing machine.
Summary of the Invention
The present invention provides a unit dose laundry composition for softening
or
conditioning fabrics which is suitable as an additive to the wash cycle of an
automatic
washing machine, said unit dose composition comprising a compacted granular
composition
comprising a fabric softener or a fabric conditioner, said compacted granular
composition
being characterized by having a spherical shape and having no discrete outer
layer
surrounding said fabric softener or conditioner, which oufier layer is
comprised of an alkaline
material such that the pH of the wash water is increased upon the dissolution
of said outer
layer in said wash water.
Ln a preferred embodiment of the invention the fabric softener or conditioner
is
comprised of a fabric softening clay and an organic fatty softening material.
Especially
preferred fabric softeners comprise a clay mineral softener, such as
bentonite, in combination
with a pentaerythritol compaund as further described herein. Useful
combinations of such
softener may very from about 83%, to about 90%, by weight, of clay, and from
about 10% to
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about 17%, by weight, of fatty softening material such as a pentaerythritol
compound (often
abbreviated herein as "PEC")
In a further preferred embodiment of the invention the fabric softener or
conditioner is
free of a soap surfactant.
In accordance with the process aspect of the invention there is provided a
process for
softening or conditioning laundry which comprises contacted the laundry with
an effective
amount of the unit dose laundry composition defined above.
Detailed Description of the invention
The clays that are useful components of the invented products are those which
cooperate with the organic fatty softener materials to provide enhanced
softening of laundry.
Such clays include the montmorillonite-containing clays which nave swelling
properties (in
water) and which are of smectite structure, so that they deposit on fibrous
materials,
especially cotton and cotton/synthetic blends, such as cotton/polyester, to
give such fibers and
fabrics made from them a surface lubricity or softness. The best of the
smectite clays for use
in the present invention is bentonite and the best of the bentonites are those
which have a
substantial swelling capability in water, such as the sodium and potassimn
bentonites. Such
swelling bentonites are also known as western or Wyoming bentonites, which are
essentially
sodium bentonite. Other bentonites, such as calcium bentonite, are normally
non-swelling
and usually are, in themselves, unacceptable as fabric softening agents.
However, it has been
found that such non-swelling bentonites exhibit even better fabric softening
in combination
with PEC's than do the swelling bentonites, provided that there is present in
the softening
composition, a source of alkali metal or other solubilizing ion, such as
sodium (which may
come from sodium hydroxide, added to the composition, or from sodium salts,
such as
builders and fillers, which may be fixnctional components of the composition).
Among the
preferred bentonites are those of sodium and potassium, which are normally
swelling, and
calcium and magnesium, which are normally non-swelling. Of these it is
preferred to utilize
calcium (with a source of sodium being present) and sodium bentonites. The
bentonites
employed may be produced in the United States of America, such as Wyoming
bentonite, but
also may be obtained from Europe, including Italy and Spain, as calcium
bentonite, which
may be converted to sodium bentonite by treatment with sodium carbonate, or
may be
employed as calcium bentonite. Also, other montmorillonite-containing smectite
clays of
properties like those of the bentonites described may be substituted in whole
or in part for the
bentonites described herein and similar fabric softening results will be
obtained.
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The swellable bentonites and. similarly operative clays are of ultimate
particle sizes in
the micron range, e.g., 0.01 to 20 microns and of actual particle sizes in the
range of No's.
100 to 400 sieves, preferably 140 to 325 sieves, U.S. Sieve Series. The
bentonite and other
such suitable swellable clays may be agglomerated to larger particle sizes
too, such as 60 to
120 sieves, but such agglomerates are not preferred unless they include the
PEC('s) too (in
any particulate products).
A main component of the invented compositions and articles of the present
invention,
and which is used in combination with the fabric softening clay is an organic
fatty softener.
The organic softener can be anionic or nonionic fatty chains (Clo-Cz2
preferably C12-Cis).
Anionic softeners include fatty acids soaps. Preferred organic softeners are
nonionics such as
fatty esters, ethoxylated fatty esters, fatty alcohols and polyols polymers.
The organic
softener is most preferably a higher fatty acid ester of a pentaerythritol
compound, which term
is used in this specification to describe higher fatty acid esters of
pentaerythritol, higher fatty
acid esters of pentaerythritol oligomers, higher fatty acid esters of lower
alkylene oxide
derivatives of pentaerythritol and higher fatty acid esters of lower allcylene
oxide derivatives
of pentaerythritol oligomers. Pentaerythritol compound is often abbreviated as
PEC herein,
which description and abbreviation may apply to any or all of pentaerythritol,
oligomers,
thereof and allcoxylated derivatives thereof, as such, or more preferably and
more usually, as
the esters, as may be indicated by the context.
The oligomers of pentaerythritol are preferably those of two to five
pentaerythritol
moieties, more preferably 2 or 3, with such moieties being joined together
through etheric
bonds. The lower alkylene oxide derivatives thereof are preferably of ethylene
oxide or
propylene oxide monomers, dimers or polymers, which terminate in hydroxyls and
are joined
to the pentaerythritol or oligomer of pentaerythritol through etheric
linl~ages. Preferably there
will be one to ten alkylene oxide moieties in each such all~ylene oxide chain,
more preferably
2 to 6, and there will be one to ten such groups on a PEC, depending on the
oligomer. At
least one of the PEC OH groups and preferably at least two, e.g., 1 or 2 to 4,
are esterified by
a higher fatty acid or other higher aliphatic acid, which can be of an odd
number of carbon
atoms.
The higher fatty acid esters of the pentaerythritol compounds are preferably
partial
esters. And more preferably there will be at least two free hydroxyls thereon
after
esterification (on the pentaerythritol, oligomer or alkoxyalkane groups).
Frequently, the
number of such free hydroxyls is two or about two but sometimes it may.by one,
as in
pentaerythritol tristearate, or as many as eight, as in pentaerythritol
tetrapalmitate.
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The higher aliphatic or fatty acids that may be employed as esterifying acids
are those of
carbon atom contents in the range of 8 to 24, preferably 12 to 22 and more
preferably 12 to
18, e.g., lauric, myristic, palmitic, oleic, stearic and behenic acids. Such
may be mixtures of
such fatty acids, obtained from natural sources, such as tallow or coconut
oil, or from such
natural materials that have been hydrogenated. Synthetic acids of odd or even
numbers of
carbon atoms may also be employed. Of the fatty acids lauric and stearic acids
are often
preferred, and such preference may depend on the pentaerythritol compound
being esterified.
Examples of some esters (PEC's) within the present invention follow:
Monopentaerythritol Esters
CH2-Rz
Ry"' Cg2 '_ C " CH2 ' R3
CHZ- R4
Monopentaerythrital Dilaurate
R1=CH3 - (CHZ)ia -COO
RZ=CH3 - (CH2)ro -COO
R3=OH
R4=OH
Monopentaerythritol Monostearate
Rl=CH3 - (CH2)16 -COO-
RZ=OH
R3=OH
R4=OH
Monopentaerythritol Distearate
R1=CH3 - (CH2)16 -COO-
Rz=CHs - (CHZ)r6 -COO-
R3=OH
R4=OH
Monopentaerythritol Tristearate
Rl=CH3 - (CHZ)r6 -COO
R2=CH3 - (CH2)i6 -COO
R3=CH3 - (CHZ)is -COO
3 5 R4=OH
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Monopentaerythritol Monobehenate
Rl= CH3 - (CHz)zo
-COO-
Rz= OH
R3 =OH
R4 =OH
Monopentaerythritol Dibehenate
Rl=CH3 - (CHz)zo -COO
Rz=CH3 - (CHz)zo -COO
R3=OH
R4=OH
Dipentae~thritol Esters
CH20R1 CH20R2
HO CH2- C - CHZ- O '_' CH2 _-' C- CH20H
CHZOR3 CH20R4
Dipentaerythritol Tetralaurate
Rl=CH3 - (CHz)1o -CO
Rz=CH3 - (CHz)1o -CO
R3=CH3 - (CHz)io -CO
R4=CH3 - (CHz)lo -CO
Dipentaerythritol Tetrastearate
Rl=CH3 - (CHZ)ls -CO
Rz=CH3 - (CHz)16 -CO
R3=CH3 - (CHz)16 -CO
R4=CH3 - (CHz)i6 -CO
Pentaervthritol 10 Ethylene Oxide Ester
CHz- O-- (CHZ- CH20)nH
I
Rl ~ CH2 ~ C - CH2 - R2
I
CH2- O'- (CH2- CH20)n~H
withn+n'=10
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Monopentaerythritol 10 Ethylene Oxide Distearate
Ri=CH3 - (CHz)16 -COO-
RZ=CH3 - (CHZ)i6 -COO-
Pentaerythritol 4 Propylene Oxide Esters
CH2 - O - (CH2 - CH - CH20)2H
Rl - CH2 - C- CH2 - Ra
CHZ - O - (CHZ - CH - CH20)2H
Monopentaerythritol 4 Propylene Oxide Monostearate
Rl=CH3 - (CHZ)16 -COO-
RZ=OH
Monopentaerythritol 4 Propylene Oxide Distearate
Rl=CH3 - (CHZ)i6 -COO-
RZ=CH3 ' (CH2)i6 -COO-
Although in the formulas given herein some preferred pentaerythritol compounds
that
are useful in the practice of this invention are illustrated it will be
understood that various
other such pentaerythritol compounds within the description thereof herein may
be employed
too, including such as pentaerythritol dihydrogenated tallowate,
pentaerythritol ditallowate,
pentaerythritol dipalmitate, and dipentaerythritol tetratallowate.
Other fabric softening materials may be incorporated into the presently
described unit
dose laundry compositions provided they are not ecologically unacceptable and
if they do not
interfere with the fiber softening action of the clay and organic fatty
softener material. In fact,
sometimes, when antistatic action is desirable in the product, such additions
may be important
because although PEC's, for example, have some antistatic properties it is
generally
insufficient for the intended purposes. Thus, it is possible to formulate
fabric softening
compositions and articles with the PEC supplemented by other antistatic agents
and also by
fabric softeners. The foremost of such antistatic materials are the quaternary
ammonium salts
but when they axe present there can be ecological problems, due to their
alleged toxicities to
aquatic organisms. Other antistats and fabric softeners include: higher alkyl
neoalkanamides,
e.g., N-stearyl neodecanaanide; isostearamides; amines, such as N,N-
ditallowalkyl N-methyl
amine; esterified quatern.axy salts or esterquats: amidoamines; amidoquats;
irnidazolines;
imidazoliniurn salts.
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Other useful ingredients for the unit dose laundry compositions of the
invention
include disintegration materials to enhance the disintegration of the unit
dose in the wash
water. Such materials include an effervescent matrix such as citric acid
combined with
baking soda, or materials such as PVP polymer and cellulose. Granulating
agents may be
used such as polyethylene glycol; bactericides, perfumes, dyes and materials
to protect against
color fading, dye transfer, anti-pilling and anti-shrinkage. Fox purposes of
enhancing the
aesthetic properties of the final composition, cosmetic ingredients such as
dyes, micas and
waxes may be used as coating ingredients to improve the appearance and feel of
the unit dose.
Examule 1
A unit dose composition was prepared from the following ingredients:
Wei ht Percent
Clay/Pentaerythritol ditallowate 80%
(PDT) in a
ratio of 83% : 17%
Effervescent matrix of baking 17%
soda and citric
acid
Pol in 1 olidone 1%
Perfume 2%
Dye 0.03%
This method of manufacture consisted of mixing all the ingredients with the
exception
-of perfume in a Loedige-type mixer. The resulting blend was dried in an oven
and perfume
was then added to the dried powder. The powder was then compacted using an
alternative or
rotative press mounted with appropriate dyes. The weight of the spherical unit
dose was 60g
and such unit dose dispersed in water within 20 minutes when introduced in the
wash load at
the beginning of the wash in a European Miele W832 front loading washing
machine set a
Program White Colors at 40°C.
The softness provided by the unit dose compositions on terry towels, cotton
tee-shirts
and cotton kitchen towels was evaluated after cumrnulative washes and compared
with a
commercial liquid fabric softener. A 3Kg laundry ballast was used in the
machine. Softness
was evaluated by a panel of six judges using 9 replicates. The results were as
follows:
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SOFTNESS EVALUATION
Laundr Item Softness Com arison
Terry towels 1 unit dose softener composition
of the
invention provided equivalent
softness to
commercial liquid FS after 10
ciunulative
wash c cles
Cotton tea-shirts 1 unit dose softener provided
equivalent
softness to commercial liquid
FS after one
wash c cle
Cotton kitchen towels 1 unit dose softener provided
enhanced
softening relative to commercial
liquid FS
after one wash c cle
Example 2
Unit dose softener compositions were prepared as described in Example 1 to
provide
60 gram spherical softeners having a diameter of 44 mm. The typical range of
spherical dose
diameters is from about 5 to about 60 mm; preferably from about 20 to about 40
mm; and
most preferably from about 30 to about 35 mm. The dissolution behavior of the
unit dose
softener in the washing machine was compared to a compacted tablet of 35
grams. The
European washing machine and conditions of laundering were as described in
Example 1.
The spherical unit dose softener of the invention and the tablet were
introduced into the
washing machine before the start of the wash. Results were as follows:
I3ispersion Eyaluation
Both the spherical unit dose and the tablet became entrapped in the rubber
gasket of
the washing machine within a few minutes of the wash cycle. However, the
spherical unit
dose was able to readily disengage itself from the gasleet and return to the
laundry while the
tablet remained trapped in the gasket.
Out of ten wash cycles, the tablet was trapped in the rubber gasket of the
machine
every time (ten times). The average time to get stuck was about 10 minutes. In
contrast
thereto, out of ten wash cycles, the spherical unit dose softener never was
trapped in the
rubber gasket and dissolved in the wash water without difficulty.
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