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Patent 2416638 Summary

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(12) Patent: (11) CA 2416638
(54) English Title: GEL PRODUCTS FORMING SYSTEM AND METHODS OF PREPARATION
(54) French Title: SYSTEME DE FORMATION DE PRODUITS GELIFIES ET PROCEDES DE PREPARATION
Status: Term Expired - Post Grant Beyond Limit
Bibliographic Data
(51) International Patent Classification (IPC):
  • A23G 3/02 (2006.01)
  • A23G 3/00 (2006.01)
(72) Inventors :
  • FLICKINGER, GREGORY (United States of America)
  • ZIETLOW, PHILIP K. (United States of America)
  • STINSON, JAMES L. (United States of America)
  • VAN LENGERICH, BERNHARD (United States of America)
  • ROY, SOUMYA (United States of America)
(73) Owners :
  • GENERAL MILLS, INC.
(71) Applicants :
  • GENERAL MILLS, INC. (United States of America)
(74) Agent: SMART & BIGGAR LP
(74) Associate agent:
(45) Issued: 2011-01-04
(86) PCT Filing Date: 2001-09-25
(87) Open to Public Inspection: 2002-04-04
Examination requested: 2006-05-11
Availability of licence: N/A
Dedicated to the Public: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): Yes
(86) PCT Filing Number: PCT/US2001/030228
(87) International Publication Number: WO 2002026048
(85) National Entry: 2003-01-27

(30) Application Priority Data:
Application No. Country/Territory Date
09/669,660 (United States of America) 2000-09-26

Abstracts

English Abstract


Methods of preparing a gelled dried sweetened products comprise the steps in
sequence of: providing a hot fluid gelable base blend at near finish % solids,
and depositining the fluid gelable base blend into shaped cavities. The
present methods can further comprise the steps of rapidly curing the base
blend to form gelled shaped pieces; and, separating the gelled shaped pieces
from the shaped cavities to form quantities of shaped pieces. Depositing a
gelable base blend at near finish solids content is possible by completely
hydrating any gel hydrocolloids prior to addition to other wet and dry
ingredients.


French Abstract

L'invention concerne des procédés de préparation de produits édulcorés gélifiés sous forme sèche consistant à réaliser un mélange de base gélifiable fluide dont l'humidité est à quelques % près celle du produit final, et à déposer ce mélange dans des cavités formées. Ces procédés peuvent aussi consister à faire durcir rapidement le mélange de base afin de préparer des pièces gélifiées avec forme, puis à séparer ces pièces formées des cavités pour obtenir des quantités de pièces formées. Le dépôt d'un mélange de base gélifiable dont l'humidité est à quelques % près celle du produit fini est possible en raison de l'hydratation complète de tout hydrocolloïde de gélification avant son addition à d'autres ingrédients secs ou humides.

Claims

Note: Claims are shown in the official language in which they were submitted.


CLAIMS:
1. A process for preparing a gelled food product,
comprising the steps of:
(A) providing a pumpable gelable base blend at or
near finish % solids;
(B) cooling shaped cavities of a mold bed to
below room temperature;
(C) depositing the pumpable gelable base blend
into the cooled, shaped cavities; and
(D) curing the base blend to form gelled shaped
pieces.
2. The process of claim 1, wherein step (D) is
carried out by rapidly curing the base blend to form gelled
shaped pieces.
3. The process of claim 1 or 2, wherein the shaped
cavities are formed in a silicone or plastic mould, or in a
mould fabricated from a thermoplastic.
4. The process of claim 3, wherein the shaped
cavities are formed in a plastic mould immediately before
filling.
5. The process of claim 1 or 2, wherein the shaped
cavities are formed in a bed of powdered starch, with at
least a portion of the starch having been replaced with
powdered sugar.
6. The process of claim 5, wherein all the starch is
replaced with powdered sugar.

7. The process of claim 5 or 6, wherein one or both
of (a) at least a portion of the sugar is dextrose
monohydrate and (b) at least a portion of the sugar is
sucrose.
8. The process of any one of claims 1 to 7,
additionally comprising the step of:
(E) separating the gelled shaped pieces from the
shaped cavities to form quantities of shaped pieces.
9. The process of claim 8, additionally comprising
the step of:
(F) packaging at least one of the shaped pieces
in a package fabricated from a flexible film.
10. The process of any one of claims 1 to 8, wherein
the curing step (D) is practiced for a cure time ranging
from about 1 to 200 minutes.
11. The process of claim 10, wherein the cure time
ranges from about 1 to 60 minutes.
12. The process of claim 11, wherein the cure time
ranges from about 1 to 30 minutes.
13. The process of claim 12, wherein the cure time
ranges from about 1 to 10 minutes.
14. The process of any one of claims 1 to 13, wherein
step (A) comprises the substep of mixing wet and dry
ingredients to form a homogenous base blend comprising at
least one gelling agent.
15. The process of claim 14, wherein at least a
portion of the mixing is practiced in a mixer evaporator.
21

16. The process of claim 14 or 15, wherein step (A)
further comprises the substeps of providing a hydrated
gelling agent solution comprising about 5% to 50% gelling
agent and balance moisture and admixing the hydrated gelling
agent solution with the wet and dry ingredients.
17. The process of any one of claims 14 to 16, wherein
at least a portion of the gelling agent is a starch.
18. The process of claim 17, wherein the starch is a
thin boiling starch or a high amylose starch.
19. The process of any one of claims 14 to 16, wherein
at least a portion of the gelling agent is a gel forming
hydrocolloid.
20. The process of claim 19, wherein the gel forming
hydrocolloid is a thermosetting hydrocolloid, an acid
setting hydrocolloid or a calcium setting hydrocolloid.
21. The process of claim 20, wherein the calcium
setting hydrocolloid is kappa carrageenan.
22. The process of any one of claims 14 to 16, wherein
a portion of the gelling agent is a gel forming hydrocolloid
and a portion of the gelling agent is a gel forming starch,
a high amylose starch or a mixture thereof.
23. The process of claim 14 or 15, wherein step (A)
comprises forming an aqueous dispersion of ungelatinized
starch and admixing the aqueous dispersion of ungelatinized
starch with the wet and dry ingredients to form a
homogeneous base blend.
24. The process of claim 17, 18 or 23, wherein the
base blend is heated and cooked to at least partially
22

gelatinize the starch to form a cooked gelable hot fluid
base blend.
25. The process of claim 24, wherein moisture is
removed from the cooked gelable hot fluid base blend, at
least a portion of the moisture being removed under vacuum
or atmospheric venting.
26. The process of claim 24 or 25, wherein at least a
portion of the heating is supplied by steam injected into
the base blend.
27. The process of any one of claims 1 to 26, wherein
at least a portion of the base blend is fruit solids.
28. The process of claim 27, wherein the fruit solids
are admixed with the base blend after at least a portion of
the moisture is removed under vacuum.
29. The process of any one of claims 1 to 28, wherein
at least a portion of step (A) is practiced in at least one
twin screw processor.
30. The process of any one of claims 1 to 29, wherein
in step (A), the gelable base blend ranges in temperature
from about 80°C to about 150°C.
31. The process of any one of claims 1 to 30, wherein
the gelable base blend has a solids content of about 80%
to 90%.
32. The process of any one of claims 1 to 31, wherein
the gelable base blend has a sugars content of about 50%
to 85%.
33. The process of any one of claims 1 to 32, wherein
the base blend is fortified with about 0.5% to 5% of
23

calcium, at least a portion of which is supplied by calcium
phosphate, calcium carbonate, or a mixture thereof.
34. The process of claim 33, wherein the calcium has a
particle size of less than 100 microns.
35. The process of any one of claims 1 to 34, wherein
the base blend is fortified with at least one of a vitamin,
a mineral, a botanical, a nutriceutical, a therapeutic
agent, a pharmaceutical agent, or a mixture thereof.
36. The process of any one of claims 1 to 35, wherein
step (A) comprises the substep of admixing a color or flavor
solution into the gelable base blend prior to step (C).
37. The process of any one of claims 1 to 36, wherein
step (A) comprises the substep of admixing an edible organic
acid solution into the gelable base blend prior to step (C),
at least a portion of the gelable base blend comprising an
acid setting hydrocolloid.
38. The process of any one of claims 1 to 37, wherein
at least a portion of the gelable base blend comprises a
calcium setting hydrocolloid and wherein step (A) comprises
the substep of admixing a soluble calcium ion solution into
the gelable base blend prior to step (C).
39. The process of any one of claims 1 to 38,
comprising the step of dividing the hot fluid gelable base
blend into a plurality of substreams and admixing a color or
flavor solution into at least one substream of the gelable
base blend prior to step (C) to form a flavored or colored
substream.
40. The process of claim 39, wherein at least one
substream is aerated to about 0.1 to 0.9 g/cc.
24

41. The process of claim 39 or 40, wherein each
substream is filled in separate shaped cavities.
42. The process of any one of claims 1 to 41, wherein
the shaped cavities are formed in a bed of powdered starch,
sugar(s) or a mixture thereof.
43. The process of claim 42, wherein the bed is
powdered sugar.
44. The process of claim 43, wherein at least a
portion of the powdered sugar is dextrose monohydrate.
45. The process of any one of claims 42 to 44, wherein
step (B) comprises the substeps of:
cooling the powdered bed to below room temperature to form a
cooled powdered bed; and
forming shaped cavities in the cooled powdered bed; and
wherein step (C) comprises:
filling the cavities in the cooled powdered bed with the
pumpable gelable base blend.
46. The process of claim 45, wherein the bed is cooled
to a temperature ranging from about -50°C to about 25°C.
47. The process of claim 46, wherein the bed is cooled
to a temperature ranging from about -50°C to about 5°C.
48. The process of any one of claims 1 to 47, wherein
the shaped cavities are each adapted to receive about 1
to 100g of the hot fluid gelable base blend.

Description

Note: Descriptions are shown in the official language in which they were submitted.


CA 02416638 2003-01-27
WO 02/26048 PCT/US01/30228
GEL PRODUCTS FORMING SYSTEM AND
METHODS OF PREPARATION
Field of the Invention
The.present invention relates to improved food products
and to their methods of preparation. More particularly, the
present invention relates to methods for preparing
confectionery gelled food products, especially fruit based.
Background of the-Invention
The present invention provides an improvement in gelled
food products such as prepared by starch molding and to their
methods of preparation. In particular, the present invention
comprises depositing a gelable fluid mixture at or near finish
moisture into shaped starch cavities. The present invention
provides product preparation methods that importantly comprise
shorter residence times during curing than in conventional
starch molding techniques by eliminating or at least greatly
reducing drying required for obtaining the finished products.
Wholesome snacks, prepared from sweetened intermediate
moisture shelf stable fruit or "fruit snacks" herein have
recently become popular food items. These compositions are
sold in various physical forms and shapes such as: 1) in
rolled sheet form; 2) in rolled strip form; 3) in string form
mounted on a U-board; 4) soft center filled pieces, and 5) in
1

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gelled bite size pieces of various shapes or in gelled bite
size piece form prepared by starch molding.
Generally, these products are prepared from wet mixtures
of the various fruit materials and added ingredients that are
dried to desired moisture contents. The dehydrated
compositions are formed into articles of desired shapes and
sizes. In other variations, all or a portion of the fruit
material is substituted with pure sugars. Such low fruit,
high sugar formulations can be flavored with fruit flavors
and/or other flavors. Within this general similarity,
however, the particular methods of preparation, product
formulations and apparatus used to prepare particular products
vary considerably. Moreover, such variations are highly
interdependent. Formulations and method steps suitable for
one product form might or might not be suitable for another
product form due to the processing difficulties, or desired
end product attributes such as shape or texture.
Particularly popular products are in rolled sheet form
such as are sold under the Fruit Roll-Ups brand. Popular
products rolled strip form are sold under the Fruit By The
Foot brand (see also, US 5,455,053 entitled "Rolled Food Item"
issued 10/3/95). Food products in string form mounted on a U-
board are sold under the String ThingTh' mark while other
products in bite size. pieces of various shapes are sold under
various brands. (See, for.example, commonly assigned US
5,942,268 entitled "Embossed Shape Food Item" issued August
24, 1999 to Zimmermann et al.). Soft center filled pieces
products are described in US 4,853,236 entitled "Dual Textured
Food Piece Of Enhanced Stability. Using An Oil In Water
EMULSION" (issued 03/18/88 to Langler et al.) while apparatus
and fabrication methods therefor,are described in US 5,208,059
entitled "Dual Textured Food Piece Fabrication Apparatus"
(issued 06/10/92 to Dubowik et al.).
2

CA 02416638 2010-02-24
22694-1611
In particular,. the present invention provides further
improvements in the gelled food products in bite size pieces
and their starch molding methods of preparation taught in
related commonly assigned US 6,077,557 entitled "Gel Products
Fortified With Calcium And Method-Of Preparation" (issued June
20, 2000 to Gordon et al.).
In that application, a calcium slurry is prepared
and is added to other materials such as sugars and fruit,
purees to form a calcium bearing fluid gelable blend or
slurry. The calcium bearing gelable blend is then further
processed such as by forming'that blend into shaped pieces by
adding to shaped cavities in starch moulds and curing and
drying to form finished calcium fortified gelled food pieces.
Also, the present invention further provides an
improvement towards an alternative to that calcium slurry such
as is disclosed in commonly assigned US 6,663,910 entitled
"Gel Products Fortified With Calcium And Methods Of
Preparation".
In each of the ' 557- and '910 patents, the
gelable calcium bearing compositions are formed into pieces,
and cured by conventional starch molding. The. curing step
involves the formation of the gel, structure of the gelling
agents, and optional heating of the products to remove excess
moisture and eventual cooling down of the products to form a
gel that is able to withhold its individual shape. The
conventional starch molding step is practiced with extended
curing time ranging from about 16 to 48 hours. While a gel
structure forms early in the'curing step, the lengthy duration
is required by the need for substantial moisture removal from
the gel into the starch.
However, in the present invention, by virtue of the
present improved deposition of a gelable fluid at near finish
3

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moisture contents, the starch molding curing times can be
substantially reduced.
These dried fruit products are especially popular with
children, particularly as snack or convenience foods. To
continue, to.appeal to children, manufacturers must introduce
frequent changes to such products. For example, the shapes of
the products can be changed to employ currently popular
character shapes such as from a movie, television show,
cartoons, etc. An advantage of starch molding is that such
shape changes can be made quickly, cheaply, and easily.
In starch molding, shapes are-stamped into a bed of
starch forming cavities by a shaped die or tamper. 'A gelable
fluid mixture is then charged to the cavities and is allowed
to cure to harden and to dry to form thereby gelled food
products.
One problem, however, with starch molding is that holding
times for curing are lengthy and. can generally range from one
to several days. After curing the shaped pieces are removed
from the starch. Large quantities of product, starch and
holding rooms and equipment are required to provide such
lengthy holding times.
Thus, it would be desirable to reduce starch molding
curing times. One approach to reducing curing times is simply
to increase the solids content of, the fluid gelable mixture
being deposited so as to reduce degree of the drying required
and thus to reduce the curing time. However, increasing the
solids content can also increase the viscosity of the fluid
mixture, which in turn can impair the ability to properly fill
the starch cavities, and thus lead to product shape defects.
The mixture can also be prone to premature gelling causing
fouling and other processing and starch cavity mould filling
problems. Often such problems are due to inadequate hydration
4

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22694-1611
of one or more gelling agents or inadequate mixing of the
composition due to restrictions on moisture usage.
In view of the current state of the gelled food
art, there is a continuing need for new and improved
formulations and methods for preparing gelled shaped food
products.
The present invention satifies this need by
providing methods for preparing such starch molded gelled
bite size dried fruit products that are characterized by
reduced or even no drying and thus reduced curing times. In
part, the present invention involves providing a gelable
sweetened fruit fluid slurry of increased solids
intermediate product that nonetheless (has lower or
comparable viscosities) that allows for successful starch
molding.
In particular, the present invention provides
methods for preparing fortified sweetened dried gelled fruit
compositions having reduced cure times.
The present invention provides high solids content
gelable food slurry product intermediates useful in the
preparation of gelled food products.
The present invention provides techniques and
methods for providing such high solids gelable fluid
intermediate products.
It has been surprisingly discovered that the above
can be realized and superior dried sweetened fruit
preparation methods provided by preparing a high solids
content gelable fluid by the herein described techniques
that requires minimal curing times whether by reducing
setting and/or drying times. The present invention further

CA 02416638 2009-05-25
22694-1611
provides novel methods of preparation of such gel products
characterized by reductions or elimination of drying times
or by reductions or elimination of setting times.
5a

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22694-1611
Brief Description of the Drawings
The illustrative embodiment may best be described
by reference -co the accompanying drawings where:
Figure 1 is schematic flow diagram of gelled
product forming system according to a process aspect of the
present invention.
Figure 2 is schematic flow diagram of gelled
product forming system according to a process aspect of the
present invention similar to Figure 1 except that starch
cooking is performed in the same twin screw cooker processor
as performs the mixing .
Figure 3 is schematic flow diagram of gelled
product forming system according to a process aspect of the
present invention similar to Figure 1 with the substitution
of an alternative cooking apparatus.
Figure 4 is schematic flow diagram of gelled
product forming system. according to a process aspect of the
present invention similar to Figure 2 with the substitution
of an alternative cooking apparatus.
2C Summary of the Invention
In its process aspect, the present invention
resides in methods of preparing a gelled dried sweetened
product. The methods comprise the steps in sequence of:
providing a hot fluid gelable base blend at near finish %
solids, and depositing the fluid gelable base blend into
shaped cavities. The present methods can further comprise
the steps of rapidly curing the base blend to form gelled
shaped pieces; and, separating the gelled shaped pieces from
the shaped cavities to form quantities of shaped pieces.
6

CA 02416638 2009-05-25
22694-1611
According to one aspect of the present invention,
there is provided a process for preparing a gelled food
product, comprising the steps of: (A) providing a pumpable
gelable base blend at or near finish % solids; (B) cooling
shaped cavities of a mold bed to below room temperature; (C)
depositing the pumpable gelable base blend into the cooled,
shaped cavities; and (D) curing the base blend to form
gelled shaped pieces.
Detailed Description of the Invention
Referring now to Figure 1, there is shown a gelled
product forming process 10 for preparing finished gelled or
semi solid confectionery food products. The process 10
6a

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essentially comprises a first step 12 of providing a hot fluid
gelable base blend at or near finish % solids. While the
present invention finds particular suitability for use in
connection with the production of shaped gelled fruit based
products, the present invention is also suitable for use in
connection with the production of gelled or semi-solid food
products such as jelly beans, gum drops and other gelled
confections.
The present invention resides importantly in part first
step 12 in the provision of gelable base blend comprising
fully hydrated hydrocolloids and gelatinized starches at lower
moisture contents or near finish % solids that thus require
little or no drying to form finished gelled products. By
"near finish moisture contents" or equivalently "near finish %
solids" is meant that the fluidgelable base blend is within
about 1%- 2% moisture content of the finished gelled or semi
solid food product.
Step 12 generally involves mixing at least one hydrated
gelling ingredient with other wet and dry ingredients and
removing moisture to form a homogenous base blend 40. The
base blend 40 comprises at least one gelling agent and in
preferred embodiments the gelling agent comprises a blend of
gel forming starches and gel forming hydrocolloids. In those
variations employing an initially ungelatinized starch, step
12 involves heating the mixture to temperatures and for times
sufficient to cook the starch to'form the base blend 40. By
"cooking" is meant at least substantially (at least 80% of the
starch as measured by birefringence) if not all the starch has
been gelatinized.
Conveniently, one or more continuous twin screw
processors can be used to prepare the present near finish
moisture gelable fluid base blend composition 40. In one
variation of the preferred embodiment, a first low shear
smaller twin screw processor 14 can be used to prepare, and
7

CA 02416638 2003-01-27
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step 12 can comprise a substep 13 of providing, a cooked or
gelatinized gelling starch solution 16 comprising about 20% to
75% starch 18, preferably about 40% to 60% starch, and the
balance-water 20. In this variation, twin screw processor 14
is used primarily as a mixing, heating and conveying apparatus
rather than to impart shear into*th.e gelatinized starch
solution. Suitable for use herein for the smaller twin screw
processor(s) is a unit available from Readco Teldyne.
Processor 14.further functions as a pump to supply the cooked
starch solution at the elevated solids content range indicated
above. The temperature of the starch solution preferably
ranges from about 60 C to 180 C.
In one embodiment, the gel forming starch is a thin
boiling starch. Such thin boiling are highly hydrolyzed such
that aqueous solutions containing such thin boiling starches
are characterized by being thin or as having a low viscosity.
"Thin boiling starches" are an art-recognized term, such
products are widely available commercially, and the skilled
artisan will have no difficulty selecting such materials for
use herein. Preferred embodiments herein of the base blend 40
comprise about 1.5% to about 25%, preferably about 2.5% to
about 12% thin boiling starch. In variations, all or a
portion of the thin boiling starch can be substituted with a
high amylose gelling starch.
It is important that any gelling or thickening agents
added to the fluid gelable base blend be fully hydrated but
with minimal water. Conventionally-, hydrocolloids or other
gelling system ingredients are first hydrated in a solution
comprising about 95% moisture and 5% hydrocolloids. However,
in contrast, in the present invention, desirably a hydrated
gelling ingredient or blend of gelling ingredient(s) comprises
about 25%-75% moisture and about 75%-25%, ingredients.
A second smaller sized twin screw processor 22 can be
used to prepare, and step 12 can further comprise, a substep
8

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15 of providing a high solids content hydrated hydrocolloid
solution 24 in a continuous fashion comprising about 5% to 30%
on or more gelling hydrocolloids 26, preferably about 10% to
20% hydrocolloid(s), and the balance water 28. Similar to
processor 16, processor 20 can be used to hydrate and heat
water and hydrocolloid to form hydrated hydrocolloid solution
and processor 16 feeds a surge hopper with a pump to supply
the high solids hydrated hydrocolloid solution. Substep 15 of
providing a low moisture but fully hydrated hydrocolloid
solution is important to obtaining the high % solids base
blend 40. In contrast, conventional or prior art hydrocolloid
hydration methods provides hydrocolloid solutions that have at
most about 5% hydrocolloid solids. The temperature of the
hydrated hydrocolloid solution preferably ranges from about
55 C to about 220 C.
Sufficient amounts of gelling hydrocolloids (such as
alginates, gellans, pectin, carrageenans, gelatin and mixtures
thereof) and gelable starch are employed to provide a gel
strength in the finished product of about 1 to 8 Kg/cm2 force.
Good results are obtained when the finished product comprises
about 1% to 5% starch (dry weight.basis) and about 0.5% to 2%
hydrocolloid(s). Such gelling hydrocolloids can be thermo
setting, calcium or acid setting types.
Figure 1 further depicts that first step 12 can further
comprise a substep of admixing 17 one or more sugar components
such as a dry sucrose 30, corn syrup 32, and in preferred
variations fruit materials 34, and heating to form a base
blend 40. As the mixture is heated or cooked, water 36 can be
removed such as by venting (with or without vacuum) to adjust
the mixture to desired moisture-content levels. Of course
such moisture removal can result in reductions in temperature
of the mixture. In preferred variations, heat sensitive
flavor materials such as the fruit-.34'are added after the
moisture removal 19 and any such temperature reductions to
9

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minimize exposure to elevated temperatures. However, the step
12 can involve further heating and water, removal 38 such as to
remove all or a portion of the water added associated with the
addition of the fruit '34. In still other optional variations
(and so indicated by the dotted lines), the addition of the
fruit 34 can be adjusted (whether in whole or in part) to
earlier or later in the step to facilitate moisture removal
(such as by earlier fruit addition 35) or to minimize exposure
to heat (such as by later fruit addition 37). In another
variation'(not shown), all or a portion of the fruit material
34 can be used in substitution for'all or a portion of the
water 28 used to hydrate the gelling hydrocolloid to produce
hydrated hydrocolloid supply 24'.
Figure 1 depicts that a third larger twin screw mixing
processor 39 can be employed to,admix or blend the ingredients
such as sugars 30, corn syrup 32,.-fruit 34, and other
ingredients (not shown) and cook to form a heated fluid
gelable base blend 40 having a near finish moisture content.
If desired, supplemental heating (not shown) can be provided
in the form of indirect heat (e.g., by a steam or oil jacket
or by induction heating) to the barrel of processor 39, or
supplied by injected steam (not shown) or.various forms and
combinations of heating.
Conveniently, the fruit material 34 is concentrated fruit
juice and/or puree having a solids content of about 30% to
about 85%, preferably about 65%' to about 75%.
Reference now is made briefly'.to Figure 2 that shows a
variation of step 12 in which the starch cooking substep 13 is
practiced in the larger processor 39 rather than in a separate
processor as depicted in Figure 1. In Figure 2, a "cold"
(i.e., below the temperature for starch gelling or less than
80 C) aqueous suspension of starch in water 16B is fed to
processor 39. An advantage of this-variation is that fewer
equipment units can be employed. However, the length,

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configuration and heating of processor 39 must be adjusted so
that the starch gelatinization substep 13 can be practiced in
processor 39. In these variations employing an initially
ungelatinized starch, the mixtures in processor 39 is also
heated to temperatures and times sufficient to cook the starch
at least in the first sections of processor 39. By "cooking"
is meant at least substantially if not all the starch has been
gelatinized. In a less preferred variation (not depicted)
also involving only two processors, the hydrocolloid hydration
substep 15 is practiced in processor 39 while the starch-
cooking substep is practiced in a second smaller processor or
other cooking vessel.
Fig. 1 further depicts that step 12 can further comprise
a substep of admixing 41 to the base blend 40 an edible
organic acid 42 (e.g., citric, succinic, malic, ascorbic acid
or mixtures thereof). In certain variations, the base blend
40 can comprise a gel forming hydrocolloid(s) that forms a gel
under acidic conditions. In this variation, acid addition to
the base blend 40 forms the gelable base blend 44. In other
variations wherein the base blend does not require such acidic
conditions to be gelable, the acid addition 41 can be for
providing or promoting desirable flavor. For those gel
forming gelling hydrocolloids that form gels at lower pH, the
addition of acid 42 after moisture content adjustment and just
prior to the to-be described depositing step 50 facilitates
deposition of the high solids content gelable base blend. The
later addition of the gel promoting acid depicted delays
premature gel formation or premature increases in the
viscosity of the gelable base blend 44.
The acid addition can be in the form of adding 42 a
concentrated aqueous solution 43'so as to minimize moisture
addition and thus to minimize or eliminate and require
subsequent drying. The admixture of the acid solution 43 can
be assured by employing at least one static mixer 46 or other
11

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mixing technique.
In another variations in which the base blend 40
comprises a gelling agent that is.calcium set (such as Kappa
carrageenan), the acid can be substituted with an aqueous
soluble calcium ion solution (e.g., 0.1% - 1% soluble calcium)
to form the gelable base blend 44. In still other variations,
since potassium ions can affect the gel strength of kappa
carageenan, a portion of the calcium solution can be
substituted with a potassium ion solution or additionally
include a potassium ion content.
Step 12 can further involve addition of supplemental
color 47 and/or flavor 48. Conveniently, the color 47 and
flavor 48 can be premixed with the acid 41 as depicted in Fig.
1. In variations, the base blend 40 can be prepared from
bland materials (e.g., apple or pear puree and/or white grape
juice) so as to have'a neutral flavor and color. If desired,
the base blend 40 can be divided into a plurality of substeams
(not shown) and different combinations of flavors 47 and
colors 48 admixed with each substream so as to conveniently
provide individually colored and flavored substeams.
In still another variation (not shown), supplemental
vitamins, minerals, nutriceuticals, botanicals, therapeutic,
and even pharmaceutical additives can be added to the base
blend (especially before static mixer 46). In one preferred
variation, high levels (e.g., about 0.5% to 5% by dry weight)
of insoluble calcium (e.g., powdered calcium phosphate and/or
calcium carbonate). In other variations, these nutritional
supplements can be further admixed with one or more additional
static mixer elements (not shown)~or employing those static
mixers used to blend colors, flavors, and or acids.
Also not shown, one or more of the substeams can be
aerated if desired or combined with aerated substeams of
similar or differently formulated compositions, e.g.,
marshmallow.
12

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In still other variations, (riot shown) air, nitrogen or
other gases can be added before the static mixers to aerated
the gelable blend 44 to densities ranging, for example from
about 0.1 to 0.8 g/cc., preferably to about 0.2 to 0.5g/cc.
Reference is now made briefly to Fig. 3 that depicts that
in still another variations of one and the same invention,
other conventional food mixing and heating processing
equipment can be employed to practice the finish heating and
mixing. Figure 3 is similar to Fig. 1 except that a mixer
evaporator 49 is used in substitution for the twin screw
processor 39 depicted in Fig 1. Equipment suitable for
practicing the cooking substep is commercially available.
Suitable for use herein is any mixing device, whether batch or
continuous, having heat transfer and mixing means. Preferred
for use to practice the cooking'step is a heated agitated
cooking vessel such as is available from Bepex Corporation.
The vessel is a jacketed horizontally extending apparatus
having a rotating axially aligned interior shaft having a
multitude of adjustable paddles extending radially from the
shaft. The rotating paddles act-as a mechanical agitator and
effectively mix the wet and dry ingredients. The paddle
arrangement and agitator tip speed combine to move the sugar
material in a thin annular spiral from the inlet to discharge
of vessel 14. The Bepex heated vessel or "turbolizer" has the
advantage since it is a relatively simple and thus less
expensive piece of equipment. Less preferred but nonetheless
also suitable for use herein to practice the cooking step is a
conventional swept surface heat exchanger. While useful, a
swept surface heat exchanger is less desirable since it is a
more complicated and thus more expensive piece of equipment
compared to a heated turbolizer. In still other variations,
one or more kettles can be used to practice the gelable base
blend preparation step.
13

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A brief reference is made now to Fig 4 which depicts a
variation similar to Fig 2 but like in the variation depicted
in Fig 3, substitutes a heating and mixing apparatus 53 in
substitution for the twin screw processor 39 of Fig. 1. In
the variation depicted in Fig. 4, the heating and mixing
apparatus 53 functions to practice the cooking of 16B the
gelling starch of the cold starch and water dispersion in a
manner comparable to that described above for Fig. 2.
In highly preferred embodiments, the gelable fluid base
blend 44 is characterized by a solid content of about 80 to
85% solids and a sugars content of about 55% to about 80%.
The solids content includes ant emulsifiers or fats added, for
example, as processing aides.
At the beginning of this depositing step 50, importantly
the gelable slurry 44 is in the form of a viscous but pumpable
fluid or plastic mass so that the compositions can take the
shape of the mould even if complexly shaped. In certain
variations, the pumpable gelable base blend 44 is in the form
of a hot fluid. If, however, the slurry 44 is too viscous or
is allowed to cool to below the gelling temperature of the
carrageenan, then the shapes taken'can be defective.
Referring now again to Figure 1, there is shown that
product forming process 10 further essentially comprises a
second step 50 of depositing the fluid gelable base blend into
shaped cavities. In preferred embodiments, the depositing
step is practiced immediately after the admixing of the gel
promoting acid addition. Good results are obtained when the
residence time between the acid admixture and the deposition
step is less than 10 seconds, preferably less than five
seconds. Practicing the depositing step immediately
thereafter minimizes the problems associated with increases in
viscosity build-up resulting from the acid addition.
The temperature of the fluid gelable base blend typically
ranges from about 50 C to about 100 C, preferably about 80 C
14

CA 02416638 2003-01-27
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to about 90 C. As noted above, the base blend 44 should be at
least plastic and preferably fluidin nature. Good results
are obtained when the base blend has a viscosity that ranges
from about 5,000 cps. to about 30',000 cps. At the deposition
temperature. Such a fluid property is helpful to minimizing
problems in shape formation of the'resultant piece in the
shaped cavities.
A variety of techniques can be used to practice the
depositing into shaped cavities step. For example, the
depositing step 50 can involve the substep of forming shaped
cavities into powdered starch beds 52 such as by using shaped
male dies or tampers (not shown) in moulders 58 and thereafter
filling the shaped starch bed cavities with the gelable fluid.
Starch molding apparatus are widely used in the confection art
and the skilled artisan will have no difficulty selecting
suitable equipment for use herein. If desired, the cavities
can be shaped and sized to receive about 1 to 10g of gelable
base blend 44 each.
In a novel variation herein, shaped cavities can be
formed in a bed of powdered sugar (whether dextrose, sucrose
or mixtures thereof) especially having a particle size of less
than 50 microns or even a combination of starch and powdered
sugar(s), e.g., a 50:50 blend of starch and sugar(s).
In another variation (not shown), the shaped cavities can
be supplied by silicone fixed shape moulds (see for example
the above referenced and incorporated US 5,208,059). In still
another variation, thermoformed plastic disposable containers
that also serve as end product packaging can provide the
shaped moulds. In this variation, at least a single piece can
be formed in each plastic mould. In a preferred variation,
the shaped plastic molds are formed immediately prior to being
filled with the gelable blend 44. For example, the plastic
mould can be fabricated from a flexible plastic film. If
desired, the plastic mould can-also be sealed so that the

CA 02416638 2003-01-27
WO 02/26048 PCT/US01/30228
plastic mould also forms the end product package. Of course,
other shaped moulds and techniques can be used to practice
step 50.
Surprisingly, in a highly preferred variation, the step
can further comprise an intermediate step of cooling the
shaped cavities to a temperature of'-less than room temperature
(i.e., about 25 C) prior to the sub-step of filling with the
hot gelable fluid. In more preferred embodiments, the shaped
cavities are cooled to a temperature of about -50 C to about
5 C prior to filling with the hot fluid gelable base blend.
Cooling prior to filling, especially of starch or powdered
sugar bed cavities, accelerates the to-be-described curing
step. Such curing step acceleration allows for not only
dramatic increase in productivity but also reductions in
equipment and facilities' costs. The starch or powdered sugar
bed can be cooled such as in a freezer or cooling room or
cooling tunnel for periods sufficient that the entire bed has
a temperature of about -50 C to-about 25 C. Cooling the
starch or powdered sugar beds to even colder temperatures can
be practiced but, at present, cooling to such even lower
temperatures is neither especially beneficial nor economically
practical. Conveniently, the cooled starch bed or powdered
sugar bed is then stamped with the shaped tampers to form
shaped cavities in the cooled.
Fig. 1 further depicts that product forming process 10
can further comprises a step 60 of rapidly curing the gelable
base disposed within or filled into the shaped cavities blend
during which the compositions are allowed to set to form
gelled or shape stable shaped pieces. During the curing step
60, the temperature of the hot fluid gelable base blend 44
cools to below the gelling temperature of at least one of the
gel forming ingredients. Good-'results are obtained when the
cure time ranges from about 0.1-200'minutes. In preferred
variations, the curing step 60 can'range from about 1 to 15
16

CA 02416638 2003-01-27
WO 02/26048 PCT/US01/30228
minutes and more preferably about 1 to about 8 minutes. In
preferred variations, the gelled pieces are cooled to
temperatures of about 25 C to about 500C. It is an advantage
of the present invention that curing times are greatly reduced
compared to conventional starch molding techniques.
Providing sufficient rest time in any convenient manner
can practice the curing step 60. For example, a conveyor belt
62 can be designed with speeds and lengths sufficient to
provide the cure time. In other variations, the filled moulds
can be placed in a storage area. Supplemental cooling can be
provided to reduce the cure time to within the desired range
such as by advancing the filled shaped moulds through a
cooling tunnel or chill room and/or by pre-chilling the moulds
before filling as described above....
For those variations involving curing in powdered starch
or sugar shaped moulds, the pieces can experience some drying
during the curing step. However, the extent of drying is much
less than conventional starch drying methods and involves
herein a drying moisture reduction-of less than 20 moisture,
preferably moisture or drying reduction of less than 1%.
Product forming process 10 can further comprises a step
separating the gelled shaped pieces from the shaped cavities
to form quantities of shaped pieces (not shown). In certain
variations wherein the shaped mould is used as part of the
products final packaging, such a step is not essential to the
preparation of finished products.-In those variations
involving starch or powdered sugar beds, the separating step
can involve such as by scalping or sifting the starch or sugar
to separate the larger shaped finished shaped pieces from the
powdered sugar or starch. It will-be appreciated that a small
portion of the starch or sugar from the curing beds might
remain with the cured pieces.
If desired, the present methods 10 can be practiced by
including recycling or recirculating the recovered starch
17

CA 02416638 2003-01-27
WO 02/26048 PCT/US01/30228
and/or sugar to the starch bed filling sub-step (not shown).
The pieces so formed can range in size from about 2 to
log, preferably about 1 to 5g. In preferred embodiments, the
gel pieces are formed into desired shapes having an ornamental
configuration such as geometric shapes or shapes of animal,
characters, familiar objects, or-vehicles.
The individually shaped pieces can then be subsequently
packaged in conventional manner. Especially useful are
moisture sealed pouches fabricated from flexible film
packaging impermeable flexible holding about 1 to 50,
preferably about 5 to 15 individual pieces collectively
weighing about l 'to 150g, preferably 25 to 50g.
The finished products are soft, gelled pliable products
of both good flavor and eating quality. The products exhibit
good initial flavor characteristics as well as prolonged
resistance to flavor and texture degradation at room
temperature storage. The food products so formed are
characterized by being nutritious, wholesome snacks.
In further variations of the-present invention, the gel
food pieces can be provided with a-topical coating (not
shown). The methods of preparation 10 can further comprise a
step of applying a topical coating 80. In one variation, the
topical coating application step'can involve applying a
coating comprising a liquid oil optionally admixed with a wax
to provide coated finished calcium fortified food pieces
having a desirable 'shiny appearance. A blend of liquid oil
and paraffin in a weight ratio'of-about 5:1 to about 15:1 is
heated to a temperature of about 110 F to 140 F (45 C to
60 C). The oil/wax blend is applied in an enrober in a weight
ratio of gel food pieces to oil/wax coating of about 100:1 to
about 1000:1.
In another variation, the-topical coating can involve
applying (with moisture) a granular sugar coating to form a
"sugared" coating to provide a "sugared" type coated gel food
18

CA 02416638 2003-01-27
WO 02/26048 PCT/US01/30228
piece. The sugar can be a larger or granulated sugar (e.g.,
about 250 to about 500 microns in size) that is of a larger
particle size than the powdered sugar used in the powdered
sugar curing bed. In still other variations, the sugared
coating can additionally additional insoluble calcium salts.
In still other variations, the coating step can involve a
panning operation to provide a hard shell or candy coating.
In addition, the application of a granular acid such as citric
acid to the surface is possible. The weight ratio (dry basis)
of gel food piece to coating ranges from about 10:1 to about
100:1, preferably about 15:1 to about 50:1.
The gel food products so prepared can be conventionally
packaged and distributed.
19

Representative Drawing
A single figure which represents the drawing illustrating the invention.
Administrative Status

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Event History

Description Date
Inactive: Expired (new Act pat) 2021-09-27
Common Representative Appointed 2019-10-30
Common Representative Appointed 2019-10-30
Change of Address or Method of Correspondence Request Received 2018-03-28
Grant by Issuance 2011-01-04
Inactive: Cover page published 2011-01-03
Pre-grant 2010-10-04
Inactive: Final fee received 2010-10-04
Notice of Allowance is Issued 2010-04-06
Letter Sent 2010-04-06
Notice of Allowance is Issued 2010-04-06
Inactive: Approved for allowance (AFA) 2010-03-10
Amendment Received - Voluntary Amendment 2010-02-24
Inactive: S.29 Rules - Examiner requisition 2009-08-26
Inactive: S.30(2) Rules - Examiner requisition 2009-08-26
Amendment Received - Voluntary Amendment 2009-05-25
Inactive: S.30(2) Rules - Examiner requisition 2008-11-26
Letter Sent 2006-05-30
Request for Examination Received 2006-05-11
Request for Examination Requirements Determined Compliant 2006-05-11
All Requirements for Examination Determined Compliant 2006-05-11
Amendment Received - Voluntary Amendment 2006-05-11
Amendment Received - Voluntary Amendment 2003-06-25
Inactive: Cover page published 2003-03-19
Inactive: Notice - National entry - No RFE 2003-03-17
Letter Sent 2003-03-17
Application Received - PCT 2003-02-20
National Entry Requirements Determined Compliant 2003-01-27
Application Published (Open to Public Inspection) 2002-04-04

Abandonment History

There is no abandonment history.

Maintenance Fee

The last payment was received on 2010-09-01

Note : If the full payment has not been received on or before the date indicated, a further fee may be required which may be one of the following

  • the reinstatement fee;
  • the late payment fee; or
  • additional fee to reverse deemed expiry.

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Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
GENERAL MILLS, INC.
Past Owners on Record
BERNHARD VAN LENGERICH
GREGORY FLICKINGER
JAMES L. STINSON
PHILIP K. ZIETLOW
SOUMYA ROY
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
Documents

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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Drawings 2003-01-27 4 82
Representative drawing 2003-01-27 1 19
Description 2003-01-27 19 919
Abstract 2003-01-27 2 135
Claims 2003-01-27 6 235
Cover Page 2003-03-19 1 48
Description 2003-06-25 20 954
Claims 2003-06-25 7 251
Description 2009-05-25 21 930
Claims 2009-05-25 6 198
Description 2010-02-24 21 930
Representative drawing 2010-12-06 1 16
Cover Page 2010-12-06 1 49
Notice of National Entry 2003-03-17 1 200
Courtesy - Certificate of registration (related document(s)) 2003-03-17 1 130
Reminder of maintenance fee due 2003-05-27 1 107
Reminder - Request for Examination 2006-05-29 1 116
Acknowledgement of Request for Examination 2006-05-30 1 176
Commissioner's Notice - Application Found Allowable 2010-04-06 1 166
PCT 2003-01-27 7 228
Correspondence 2010-10-04 1 38