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Patent 2440306 Summary

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Claims and Abstract availability

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(12) Patent Application: (11) CA 2440306
(54) English Title: OIL WELL PERFORATOR LINER WITH HIGH PROPORTION OF HEAVY METAL
(54) French Title: COLONNE DE PERFORATEUR DE PUITS DE PETROLE A PROPORTION ELEVEE EN METAL LOURD
Status: Deemed Abandoned and Beyond the Period of Reinstatement - Pending Response to Notice of Disregarded Communication
Bibliographic Data
(51) International Patent Classification (IPC):
  • F42B 1/032 (2006.01)
(72) Inventors :
  • CLARK, NATHAN G. (United States of America)
  • LEIDEL, DAVID JOHN (United States of America)
(73) Owners :
  • HALLIBURTON ENERGY SERVICE, INC.
(71) Applicants :
  • HALLIBURTON ENERGY SERVICE, INC. (United States of America)
(74) Agent: NORTON ROSE FULBRIGHT CANADA LLP/S.E.N.C.R.L., S.R.L.
(74) Associate agent:
(45) Issued:
(86) PCT Filing Date: 2002-03-08
(87) Open to Public Inspection: 2002-09-26
Availability of licence: N/A
Dedicated to the Public: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): Yes
(86) PCT Filing Number: PCT/US2002/007028
(87) International Publication Number: WO 2002075099
(85) National Entry: 2003-09-08

(30) Application Priority Data:
Application No. Country/Territory Date
09/810,792 (United States of America) 2001-03-16

Abstracts

English Abstract


A shaped charge apparatus having an improved liner for a shaped charge
constructed from a combination of powdered heavy metal and metal binder.
Powdered heavy metal and metal binder is formed into a rigid shaped charge
liner under very high pressure. The metal binder may be in powdered form or
may be used to coat the powdered heavy metal particles prior to formation. The
liner may also contain a relatively small percentage of other material to
enhance lubrication or corrosion resistance.


French Abstract

L'invention concerne un appareil pour charge creuse équipé d'une colonne améliorée destinée à une charge creuse construite à partir d'une combinaison de métal lourd en poudre et de liant métallique. Ce métal lourd en poudre et ce liant métallique sont transformés en une colonne de charge creuse rigide à très haute pression. Le liant métallique peut se présente sous forme de poudre ou peut être utilisé afin de revêtir les particules métalliques lourdes poudreuses avant la fabrication. Cette colonne peut également contenir un pourcentage relativement faible d'autres matières afin d'améliorer la lubrification ou la résistance à la corrosion.

Claims

Note: Claims are shown in the official language in which they were submitted.


WHAT IS CLAIMED:
1. A liner for a shaped charge comprising:
a mixture of powdered heavy metal and powdered binder metal formed into a
rigid body
wherein
the percentage of heavy metal in the mixture is within a range of
approximately 90.0%
to 99.98% by weight.
2. A liner for a shaped charge according to claim 1 wherein
the heavy metal powder is chosen from the group consisting of tungsten,
tantalum,
hafnium, silver, gold, platinum, copper, or any mixture thereof.
3. A liner for a shaped charge according to claim 1 wherein
the heavy metal consists essentially of tungsten.
4. A liner for a shaped charge according to claim 1 wherein
the percentage of heavy metal in the mixture is within a range of
approximately 99.0%
to 99.98% by weight.
5. A liner for a shaped charge according to claim 1 wherein
the binder metal is chosen from the group consisting of copper, lead, zinc,
tin, and
bismuth.
8

6. A liner for a shaped charge according to claim 1 wherein
the binder metal consists essentially of lead.
7. A liner for a shaped charge according to claim 1 wherein
the mixture further comprises approximately 0.02% to 1.0% lubricant by weight.
8. A liner for a shaped charge according to claim 7 where in
the lubricant comprises powdered graphite.
9. A liner for a shaped charge according to claim 7 wherein
the lubricant comprises oil.
10. A liner for a shaped charge according to claim 1 wherein
the percentage of heavy metal in the mixture is approximately 93.0%.
11. A liner for a shaped charge comprising:
heavy metal powder, coated with a binder metal, formed into a rigid body.
12. A liner for a shaped charge according to claim 11 wherein
the heavy metal powder is chosen from the group consisting of tungsten,
tantalum,
hafnium, platinum, silver, gold, copper, or any mixture thereof.
9

13. A liner for a shaped charge according to claim 11 wherein
the heavy metal comprises tungsten.
14. A liner for a shaped charge according to claim 11 wherein
the binder metal is chosen from the group consisting of copper, tin, zinc,
lead, bismuth
or any mixture thereof.
15. A liner for a shaped charge according to claim 11 wherein
the percentage of heavy metal in the heavy metal powder is within a range of
approximately 90.0% to 99.98% by weight.
16. A liner for a shaped charge according to claim 11 wherein
the percentage of heavy metal in the heavy metal liner is approximately 93.0%.
17. A liner for a shaped charge according to claim 11 wherein
the percentage of heavy metal is within a range of approximately 99.0% to
99.98% by
weight.
18. A liner for a shaped charge according to claim 11 wherein
the heavy metal powder, coated with binder metal, is mixed with approximately
0.02%
- 1.0% lubricant by weight.
10

19. A liner for a shaped charge according to claim 18 wherein
the lubricant comprises powdered graphite.
20. A liner for a shaped charge according to claim 18 where in
the lubricant comprises oil.
21. A liner for a shaped charge comprising:
a mixture of powdered heavy metal, powdered metal binder, and a heavy metal
powder
coated with a binder metal formed into a rigid body.
22. A liner for a shaped charge according to claim 21 wherein
the rigid body is substantially conical.
23. A liner for a shaped charge according to claim 21 wherein
the rigid body is substantially conical.
24. A liner for a shaped charge according to claim 21 wherein
the rigid body is substantially conical.
25. A liner for a shaped charge according to claim 21 wherein
the percentage of heavy metal in the mixture is within a range of
approximately 90.0%
to 99.98% by weight.
11

26. A liner for a shaped charge according to claim wherein
the percentage of heavy metal in the mixture is approximately 93.0%.
27. A liner for a shaped charge according to claim 21 where
the heavy metal powder is chosen from the group consisting of tungsten,
tantalum,
hafnium, silver, gold, platinum, copper, or any mixture thereof.
28. A liner for a shaped charge according to claim 21 wherein
the heavy metal consists of essentially of tungsten.
29. A liner for a shaped charge according to claim 21 wherein
the percentage of heavy metal in the mixture is within a range of
approximately 99.0%
to 99.98% by weight.
30. A liner for a shaped charge according to claim 21 wherein
the binder metal is chosen from the group consisting of copper, lead, zinc,
tin, and
bismuth.
31. A liner for a shaped charge according to claim 21 wherein
the binder metal consists essentially of lead.
32. A liner for a shaped charge according to claim 21 wherein
the mixture further comprises approximately 0.02% to 1.0% lubricant by weight.
12

33. A liner for a shaped charge according to claim 21 wherein
the lubricant comprises powdered graphite.
34. A liner for a shaped charge according to claim 21 wherein
the lubricant comprises oil.
35. A liner for a shaped charge according to claim 21 wherein
the mixture is compressively formed.
36. A liner for a shaped charge according to claim 1 wherein
the mixture is compressively formed.
37. A liner for a shaped charge according to claim 11 wherein
the mixture is compressively formed.
13

Description

Note: Descriptions are shown in the official language in which they were submitted.


CA 02440306 2003-09-08
WO 02/075099 PCT/US02/07028
OIL WELL PERFORATOR LINER WITH HIGH PROPORTION OF HEAVY METAL
TECHNICAL FIELD
A shaped charge suitable for use in a perforating tool for a subterranean well
is
described. The invention relates particularly to an improved shaped charge
liner constructed
from powdered heavy metal and binder material with a high proportion of
tungsten or similar
heavy metal.
BACKGROUND OF THE INVENTIONS
A subterranean gas or oil well typically begins with a hole bored into the
earth, which is
then lined with joined lengths of relatively large diameter metal pipe. The
casing thus formed is
generally cemented to the face of the hole to give the well integrity and a
path for producing
fluids to the surface. Conventionally, the casing and cement are subsequently
perforated with
chemical means, commonly explosives, in one or more locations of the
surrounding formation
from which it is desired to extract fluids. In general, the perforations
extend a distance into the
formation. Once of the problems inherent in the art is to maximize the depth
of penetration into
the formation.
Explosive shaped charges known in the art generally have a substantially
cylindrical or
conical shape and are used in various arrangements in perforating tools in
subterranean wells.
Generally, a tubular perforating gun adapted for insertion into a well is used
to carry a plurality
of shaped charges to a subsurface location where perforation is desired. Upon
detonation of the
shaped charges, explosive jets emanate from the shaped charges with
considerable velocity and
perforate the well casing and surrounding formation.
Liners of shaped charges have commonly been designed in an effort to maximize
penetration depth. Various metals have been used. Solid metal liners have the
disadvantage of
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introducing metal fragments into the formation, detracting from the
effectiveness of the
perforation. Compressed powdered metal liners have sometimes been used. Such
liners
disintegrate upon detonation of the shaped charge, avoiding the problems
associated with metal
fragments. It is known in the art that heavy metals are particularly suited
for use in liners.
Generally, the heavy metal is combined with one or more other metals with
suitable binding
characteristics to form rigid liners through very high compression of the
metal powders. One of
the principal problems in the art has been the attempt to increase the heavy
metal content of
liners. Such attempts are outlined in the United States Patent Numbers
5,656,791 and
5,814,758, which are incorporated herein for all purposes by this reference.
The success in the art of producing compressed powdered heavy metal liners has
been
limited by effort to identify suitable binding agents among elemental metals
and alloys.
Previous attempts in the art have increased tungsten content to approximately
80 percent. The
present invention employs binder materials in combination with tungsten powder
to produce an
improved shaped charge compressed liner with a tungsten content higher than
previously known
in the art.
SUMMARY OF THE INVENTIONS
The inventions provide shaped charge apparatus for use in a subterranean well.
In
general, the inventions contemplate an improved liner for a shaped charge
constructed from a
combination mixture of a high proportion of powdered heavy metal and selected
binder metal.
According to one aspect of the invention, a mixture of powdered tungsten and
powdered
metal binder is formed into a rigid shaped charge liner having a tungsten
content in a range of
between approximately 90% to 99.98% by weight.
2
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CA 02440306 2003-09-08
WO 02/075099 PCT/US02/07028
According to another aspect of the invention, a liner having a tungsten
content in a range
of between approximately 90% to 99.98% by weight is constructed of a binder
metal-coated
heavy metal powder formed into a rigid body.
According to a still another aspect of the invention, a liner for a shaped
charge is
constructed from a mixture of powdered tungsten and powdered metal binder
blended with a
binder metal-coated heavy metal powder formed into a substantially conical
rigid body. The
resulting liner having a tungsten metal content in a range of between
approximately 93% to
99.98% by weight.
BRIEF DESCRIPTION OF THE DRAWINGS
The accompanying drawings are incorporated into and form a part of the
specification to
illustrate several examples of the present inventions. These drawings together
with the
description serve to explain the principals of the inventions. The drawings
are only for the
purpose of illustrating preferred and alternative examples of how the
inventions can be made and
used and are not to be construed as limiting the inventions to only the
illustrated and described
examples. The various advantages and features of the present inventions will
be apparent from a
consideration of the drawings in which:
FIGURE 1 is a side elevation view of an example of an axially symmetrical
shaped
charge in accordance with the invention; and
FIGURE 2 is cross-sectional view taken along line 2-2 of Figure 1 showing an
example
of an embodiment of a shaped charge in accordance with the inventions.
DETAILED DESCRIPTION
The present inventions are described by reference to drawings showing one or
more
examples of how the inventions can be made and used. In these drawings,
reference characters
are used throughout the several views to indicate like or corresponding parts.
The drawings are
SUBSTITUTE SHEET (RULE 26)

CA 02440306 2003-09-08
WO 02/075099 PCT/US02/07028
not necessarily to scale and the proportions of certain parts have been
exaggerated to better
illustrate details and features of the invention.
The apparatus and methods of the invention are shown generally in Figures 1
and 2.
A conically symmetrical shaped charge 10 is shown. The shaped charge is sized
for a
perforating gun commonly used to perforate subterranean.wells and formations.
Typically, a
plurality of shaped charges are arranged in a substantially helical pattern on
the perforating
gun assembly. The exact size and shape of the shaped charge or the
configuration of the
perforating gun are not critical to the invention. The shaped charge 10 is
enclosed by a case
12. Generally, the case 12 is substantially cylindrical or conical. As used
herein, the term
"conical" is used to refer to shapes substantially conical or in the form of
frustum or truncated
cone. Again, the exact shape of the case is not critical to the invention. In
use, the
perforating gun (not shown) is placed in a subterranean location where
perforation of the well
casing and/or formation is desired, herein designated the target 14. The
shaped charge has a
muzzle 16, which is oriented toward the target 14, and an opposing closed end
18.
Now refernng primarily to Figure 2, the case 10 is shown in cross section,
revealing
that the closed end 18 has a relatively small aperture 20 connected to a
detonation cord 22.
The detonation cord 22 is typically operably connected to a detonation circuit
system (not
shown) known in the art. The case 10 contains a predetermined amount of high
explosives
24 generally known in the arts, for example, RDX, HMX, HNS, CL-20, NONA, BRX,
PETN, or PYX. A substantially conical liner 26 is disposed inside of case 12
between the
high explosive 24 and the muzzle 16, preferably such that the high explosive
24 fills the
volume between the casing 12 and the liner 26. The liner is typically affixed
to the case with
adhesive (not shown), but a retaining ring or spring may also be used. Upon
detonation of
the high explosive 24, the liner 26 disintegrates and the liner material is
propelled through the
muzzle 16 into the target 14. As known to those skilled in the arts, it is
advantageous for the
4
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CA 02440306 2003-09-08
WO 02/075099 PCT/US02/07028
liner to disintegrate upon detonation of the high explosive and to have the
maximum possible
mass and velocity.
Further refernng primarily to Figure 2, the liner 26 is preferably constructed
by
compressing a powdered heavy metal and powdered metal binder material under
very high
pressure to form a rigid body. The process of compressively forming the liner
from powdered
heavy metal and powdered metal binder is understood by those skilled in the
arts. Other
methods of fabrication, such as sintering may be used. The powdered heavy
metal is preferably
tungsten, but may be another metal or mixture of metals. Metals with high
density, high
ductility, and capable of achieving high acoustic velocity are preferred.
Metals chosen from the
group tungsten, tantalum, hafnium, and copper are particularly suitable.
Although other metals
may be used, cost is often a major factor. Preferably, the percentage of heavy
metal, preferably
tungsten, in the liner is within a range of approximately 99.0% to 99.98% by
weight.
Optionally, percentages within a range of approximately 90.0% to 99.98% may be
used.
The binder metal is chosen for its ability to bind together under high levels
of
compression. Typically, metals chosen from the group copper, lead, zinc, tin,
and bismuth are
used. The percentage of powdered binder metal, preferably lead, in the mixture
is preferably
within a range of approximately 0.02% to 1.0% by weight, although percentages
within a range
of approximately 0.02% to 10.0% may be used. Optionally, mixtures of binder
metals or
alloys such as those containing relatively high levels of tin or zinc may be
used.
Optionally, the liner 26 may also contain approximately 0.2% to 1.0% lubricant
by
weight. Powdered graphite is a preferred lubricant known in the arts, although
oils may also be
used. Some oils such as linseed oil or tong oil, or other unsaturated organic
compounds as
disclosed in United States Patent Number 4,794,990, which is incorporated in
its entirety for all
purposes by this reference, are thought to be helpful in preventing corrosion
of the liner.
SUBSTITUTE SHEET (RULE 26)

CA 02440306 2003-09-08
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The presently most preferred embodiment of the invention uses a liner 236
constructed
from a heavy metal powder coated with a binder metal, a binder metal-coated
heavy metal
powder compressively formed into a rigid body. The process of coating the
heavy metal powder
with a binder metal is understood by those skilled in the arts. The heavy
metal powder, coated
with a binder metal, is then compressed under very high pressure into a rigid
body. Presently,
tungsten and lead are preferred for the heavy metal and binder metal coating,
respectively,
although the alternative metals described above may be used. Combinations of
metals may also
be used. Preferably, the percentage of tungsten in the liner is within a range
of approximately
99.0% to 99.98% by weight, although percentages within a range of
approximately 90.0% to
99.98% may be used. The percentage of led in the mixture is preferably within
a range of
approximately 0.02% to 1.0% by weight, although percentages within a range of
approximately
0.2% to 10.0% may optionally be used.
An additional alternative embodiment of the invention uses a liner 26, which
is
construed of a combination of the elements of the first two embodiments
described. That is, a
I S mixture of heavy metal powder and powdered binder metal may be used in
combination with
binder metal-coated heavy metal powder to construct the liner 26. The same
proportions and
variations in ingredients described with reference to the first two
embodiments may be
employed with this additional embodiment as well.
The invention has many advantages attendant with raising the percentage of
heavy metal
in the liner to higher levels than have been known in the art.
The embodiments shown and described above are only exemplary. Many details are
often found in the art such as: types of high explosives, size and shape of
shaped charges, and
configuration of perforating gun assemblies. Therefore, many such details are
neither shown
nor described. It is not claimed that all of the details, parts, elements, or
steps described and
shown were invented herein. Even though numerous characteristics and
advantages of the
6
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present inventions have been set forth in the foregoing description, together
with details of
the structure and function of the inventions, the disclosure is illustrative
only, and changes
may be made in the detail, especially in matters of shape, size and
arrangement of the parts
within the principles of the inventions to the full extent indicated by the
broad general
meaning of the terms used in the attached claims.
The restrictive description and drawings of the specific examples above do not
point out
what an infringement of this patent would be, but are to provide at least one
explanation of how
to make and use the inventions. The limits of the inventions and the bounds of
the patent
protection are measured by and defined in the following claims.
7
SUBSTITUTE SHEET (RULE 26)

Representative Drawing
A single figure which represents the drawing illustrating the invention.
Administrative Status

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Event History

Description Date
Application Not Reinstated by Deadline 2007-03-08
Time Limit for Reversal Expired 2007-03-08
Deemed Abandoned - Failure to Respond to Maintenance Fee Notice 2006-03-08
Letter Sent 2004-01-12
Inactive: Single transfer 2003-11-28
Inactive: Courtesy letter - Evidence 2003-11-18
Inactive: Cover page published 2003-11-17
Inactive: Notice - National entry - No RFE 2003-11-13
Inactive: First IPC assigned 2003-10-17
Application Received - PCT 2003-10-02
National Entry Requirements Determined Compliant 2003-09-08
Application Published (Open to Public Inspection) 2002-09-26

Abandonment History

Abandonment Date Reason Reinstatement Date
2006-03-08

Maintenance Fee

The last payment was received on 2005-02-16

Note : If the full payment has not been received on or before the date indicated, a further fee may be required which may be one of the following

  • the reinstatement fee;
  • the late payment fee; or
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Fee History

Fee Type Anniversary Year Due Date Paid Date
MF (application, 2nd anniv.) - standard 02 2004-03-08 2003-09-08
Basic national fee - standard 2003-09-08
Registration of a document 2003-11-28
MF (application, 3rd anniv.) - standard 03 2005-03-08 2005-02-16
Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
HALLIBURTON ENERGY SERVICE, INC.
Past Owners on Record
DAVID JOHN LEIDEL
NATHAN G. CLARK
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Description 2003-09-07 7 281
Drawings 2003-09-07 2 43
Claims 2003-09-07 6 123
Abstract 2003-09-07 2 61
Representative drawing 2003-09-07 1 8
Notice of National Entry 2003-11-12 1 188
Courtesy - Certificate of registration (related document(s)) 2004-01-11 1 125
Courtesy - Abandonment Letter (Maintenance Fee) 2006-05-02 1 177
Reminder - Request for Examination 2006-11-08 1 118
PCT 2003-09-07 4 173
Correspondence 2003-11-12 1 27