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Patent 2581393 Summary

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(12) Patent Application: (11) CA 2581393
(54) English Title: METHOD AND SYSTEM FOR MODIFYING A USED HYDROCARBON FLUID TO CREATE A CYLINDER OIL
(54) French Title: PROCEDE ET SYSTEME DE MODIFICATION D'UN FLUIDE HYDROCARBURE UTILISE POUR CREER UNE HUILE POUR CYLINDRES
Status: Deemed Abandoned and Beyond the Period of Reinstatement - Pending Response to Notice of Disregarded Communication
Bibliographic Data
(51) International Patent Classification (IPC):
  • C10M 17/00 (2006.01)
  • C10M 17/00 (2006.01)
(72) Inventors :
  • NATOLI, GUISEPPE (Italy)
  • POMETTO, GIULIO GIOVANNI (Italy)
  • BONCIOLINI, ALFIO (Italy)
  • PETERSEN, HANS HEINRICH (Denmark)
  • DRAGSTED, JORN (Denmark)
  • LINDEGAARD, NIELS-HENRIK (Denmark)
  • OLESEN, CLAUS MARTIN (Denmark)
  • DAMM, KLAUS-WERNER (United States of America)
(73) Owners :
  • A.P. MOLLER-MAERSK A/S
(71) Applicants :
  • A.P. MOLLER-MAERSK A/S (Denmark)
(74) Agent: NORTON ROSE FULBRIGHT CANADA LLP/S.E.N.C.R.L., S.R.L.
(74) Associate agent:
(45) Issued:
(86) PCT Filing Date: 2004-12-07
(87) Open to Public Inspection: 2006-03-30
Availability of licence: N/A
Dedicated to the Public: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): Yes
(86) PCT Filing Number: PCT/DK2004/000846
(87) International Publication Number: DK2004000846
(85) National Entry: 2007-03-22

(30) Application Priority Data:
Application No. Country/Territory Date
04 388 064.0 (European Patent Office (EPO)) 2004-09-24

Abstracts

English Abstract


This invention relates to a method (and a corresponding system) of creating a
cylinder oil, the method comprising modification of at least one initial fluid
(101) by determining the TBN(s) of the at least one initial fluid, determining
a desired TBN of a cylinder oil (102) and adjusting the TBN(s) of the at least
one initial fluid (101) accordingly by blending the at least one initial fluid
(101) with suited additive(s) (103). In this way, a method (and system) for
modifying initial fluid(s) to create a cylinder oil by adjusting TBN is
obtained. This provides significant economical benefits since lubricants that
otherwise would have to be disposed of can be re-used as a total-loss cylinder
lubricant. Further cylinder oil does not have to be purchased. The oil(s) used
to blend the cylinder oil is/are of more consistent quality as it is
replenished contrary to the traditional practice which reduces machinery wear,
etc. Thus, the replenishment of the initial fluid(s) provides enhanced and
consistent performance of the initial fluids resulting in greatly reduced
component wear and equipment lifecycle cost. Even further, a more
environmentally friendly method/system is provided since waste, in the form of
spent oil(s) that is discarded after prolonged use, is reduced as it is
converted into a cylinder oil.


French Abstract

Cette invention concerne un procédé (et un système correspondant) visant à créer une huile pour cylindres, ce procédé consistant à modifier au moins un premier fluide initial (101), en déterminant le ou les nombres TBN du fluide initial, en déterminant le nombre TBN recherché d'une huile pour cylindres (102) et en ajustant le ou les nombres TBN du fluide initial (101) en conséquence, par mélange du fluide initial (101) avec un ou des additifs appropriés (103). On obtient ainsi un procédé (et un système) permettant de modifier le ou les fluides initiaux de façon à créer une huile pour cylindres en ajustant le nombre TBN. Ce procédé comporte des avantages économiques importants, dès lors que des lubrifiants, qui sinon auraient dus être mis au rebut, peuvent être réutilisés comme lubrifiant pour cylindres à perte totale. Ce procédé permet en outre d'éviter de devoir acheter une huile pour cylindres. L'huile utilisée pour être mélangée à l'huile pour cylindres est d'une qualité plus constante, dès lors qu'elle est réapprovisionnée, contrairement à la pratique traditionnelle, ce qui réduit l'usure du moteur, notamment. Ainsi, le réapprovisionnement en fluide initial assure des performances accrues et constantes des fluides initiaux, ce qui entraîne une réduction de l'usure des composants et une diminution des coûts de l'équipement pendant sa durée de vie. En outre, ce procédé et ce système sont plus respectueux de l'environnement, dès lors que les déchets, sous la forme d'huile épuisée mise au rebut après une utilisation prolongée, sont réduits puisqu'ils sont convertis en huile pour cylindres.

Claims

Note: Claims are shown in the official language in which they were submitted.


11
CLAIMS:
1. A method of creating a cylinder oil, the method comprising modification of
at
least one initial fluid (101) by determining the TBN(s) of the at least one
initial
fluid, determining a desired TBN of a cylinder oil (102) and adjusting the
TBN(s)
of the at least one initial fluid (101) accordingly by blending the at least
one initial
fluid (101) with suited additive(s) (103).
2. A method according to claim 1, wherein at least one of the initial fluids
are at
least partially used oil(s).
3. A method according to claims 1 - 2, wherein the suited additive(s) comprise
at
least one base.
4. A method according to claim 3, wherein the at least one base comprises
.cndot. basic salts of alkaline or earth alkaline elements, and/or
.cndot. detergents and/or
.cndot. dispersants.
5. A method according to claims 1 - 4, wherein the cylinder oil is used in
reciprocating internal combustion engines used in marine or stationary
applications.
6. A method according to claim 5, wherein said reciprocating internal
combustion
engines are two-stroke crosshead engines.
7. A method according to claims 1 - 6, wherein the method is used offshore, on-
site or in a land based plant.
8. A method according to claims 1 - 7, wherein the cylinder oil is created
with a
TBN in response to fuel oil characteristics and/or actual engine operating
requirements.
9. A method according to claims 1 - 8, wherein the TBN of the cylinder oil is
chosen
based upon sulphur-content of the fuel oil.

12
10. A method according to claims 1- 9, wherein said initial fluid is a
hydrocarbon
fluid.
11. A method according to claim 10, wherein said hydrocarbon fluid is a
lubricant.
12 A method according to claim 11, wherein the lubricant is a used lubricant.
13. A method according to claim 12, wherein the used lubricant is selected
from a
group of hydraulic fluids, gear oils, system oils, trunk piston engine oils,
turbine oils,
heavy duty diesel oils, compressor oils and the like.
14. A method according to claims 1- 13, wherein the created cylinder oil is
based on
two-stroke engine system oil that continuously, near-continuously or
intermittently is
tapped from an existing system and where the system oil is replenished.
15. A method according to claims 1- 13, where the created cylinder oil is
based on
a mixture of lubricants that continuously, near-continuously or intermittently
are
tapped from an existing system and where the lubricants are replenished.
16. A method according to claims 1- 15, wherein the method further comprises
the
step of: using suited instrumentation in order to control the quality of the
finished
lubricant.
17. A system for providing a cylinder oil, the system comprising: an apparatus
(104)
for modifying at least one initial fluid (101) by determining the TBN(s) of
the at least
one initial fluid, determining a desired TBN of a cylinder oil (102) and
adjusting the
TBN(s) of the at least one initial fluid (101) accordingly by blending the at
least one
initial fluid (101) with suited additive(s) (103).
18. A system according to claim 17, wherein at least one of the initial fluids
are at
least partially used oil(s).

13
19 A system according to claims 17 - 18, wherein the suited additive(s)
comprise at
least one base.
20. A system according to claim 19, wherein the at least one base comprises
.cndot. basic salts of alkaline or earth alkaline elements, and/or
.cndot. detergents and/or
.cndot. dispersants.
21. A system according to claims 17 - 20, wherein the cylinder oil is used in
reciprocating internal combustion engines used in marine or stationary
applications.
22. A system according to claim 21, wherein said reciprocating internal
combustion
engines are two-stroke crosshead engines.
23. A system according to claims 17 - 22, wherein the system is used offshore,
on-
site or in a land based plant.
24. A system according to claims 17 - 23, wherein the cylinder oil is created
with a
TBN in response to fuel oil characteristics and/or actual engine operating
requirements.
25. A system according to claims 17 - 24, wherein the TBN of the cylinder oil
is
chosen based upon sulphur-content of the fuel oil.
26. A system according to claims 17 - 25, wherein said initial fluid is a
hydrocarbon
fluid.
27. A system according to claim 26, wherein said hydrocarbon fluid is a
lubricant.
28. A system according to claim 27, wherein the lubricant is a used lubricant.
29. A system according to claim 28, wherein the used lubricant is selected
from a
group of hydraulic fluids, gear oils, system oils, trunk piston engine oils,
turbine oils,
heavy duty diesel oils, compressor oils and the like.

14
30. A system according to claims 17 - 29, wherein the created cylinder oil is
based
on two-stroke engine system oil that continuously, near-continuously or
intermittently
is tapped from an existing system and where the system oil is replenished.
31. A system according to claims 17 - 29, where the created cylinder oil is
based on
a mixture of lubricants that continuously, near-continuously or intermittently
are
tapped from an existing system and where the lubricants are replenished.
32. A system according to claims 17 - 31, wherein the system further comprises
suited instrumentation useable for controlling the quality of the finished
lubricant.

Description

Note: Descriptions are shown in the official language in which they were submitted.


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1
Method and system for modifying a used hydrocarbon fluid to create a
cylinder oil.
FIELD OF THE INVENTION
The invention relates to a method of creating an all-loss lubricant. Further,
the invention relates to a system for creating an all-loss lubricant.
BACKGROUND OF THE INVENTION
Two-stroke crosshead engines used in marine or stationary applications are
equipped with two separate lubricating oil systems. One lubricating system
comprises so-called system oil that normally is used for lubrication and
cooling of the engine's bearings and e.g. oil-cooled pistons as well as for
activation and/or control of various valves or the like. The other lubricating
system comprises an all-loss lubricant (cylinder oil) that normally is used
for
lubrication of the engine's cylinders, piston rings and piston skirt.
In typical two-stroke crosshead engines, the cylinder oil is spent
continuously
by each turn of the engine whereas the system oil in principle is not spent
(except by smaller unintentional leakages). The lubrication system
comprising the cylinder oil is also often referred to as an "all-loss"
lubrication
system as the oil is spent. The use of and various types of both system oil(s)
and cylinder oil(s) is very well known in the art.
The cylinder oil typically contains certain additives that function to reduce,
minimize or neutralise the acid level of the cylinder system.
Typical cylinder oils usually have an SAE (Society of Automotive
Engineering) viscosity equivalent to about 50 and normally have a total base
number (TBN) of about 40 to 70 for the neutralisation of acid products

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2
produced during the combustion process. Typical system oils usually have
an SAE viscosity of about 30 with a relatively low TBN content, typically
below 10. These exemplary values may vary dependent on the actual
application and the specific design of the systems that the oils are used in.
In recent two-stroke cross-head engine designs involving electronic and/or
hydraulic control and/or activation of valves, etc., the minimum performance
requirements of the system oil has been substantially increased compared to
earlier design using traditional mechanical control/activation.
In four-stroke, trunk piston (diesel) engines, however, typically use only a
single oil type for lubrication and cooling. Such engines are used as
secondary/auxiliary or propulsion engines on ships, or in stationary power
generation or liquid/gas transmission applications. Such used oils typically
have a SAE viscosity of about 30 or 40. While the system oil of two-stroke
cross-head engines typically remains within its specified performance limits
for an extended period of time, trunk piston engine oils are constantly
affected by exposure to the combustion process. However, due to the
inherent design of two-stroke cross-head engines, spent cylinder lubricants
invariably leaks past the piston rod stuffing box contaminating the system
oil.
Thus, the useful properties of both trunk piston engine and system oil
degenerate over time and finally the oils will have to be either replenished
or
completely changed. Similarly, other lubricants used on-board vessels or at
stationary sites, such as hydraulic fluids, gear oils, turbine oils, heavy
duty
diesel oils, system oils, trunk piston engine oils, compressor oils and the
like,
do deteriorate over time, due to e.g. contamination, oxidation, hydrolysis
etc.
and therefore have to be replenished or changed at certain intervals.
The performance level of lubricants is typically measured periodically and
may not go beyond certain limits if the oiled component's condition should
not be jeopardized. An important cause of performance loss is caused by

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3
particle contamination. These particles include combustion by-products and
wear components, which can be partially removed by oil separators.
However, in the case of two-stroke cross-head engines, one of the sources of
contamination is spent cylinder oil leakage past the stuffing box causing both
the viscosity and base number of the system oil to increase over time, a
process that cannot be reversed by separators.
A diesel engine's frictional loss is mainly of a viscose character. An
increase
in the viscosity of the system oil will therefore result in a diminished
efficiency, increased fuel consumption and increased emissions.
In order to manufacture cylinder oil, prior art methods and systems typically
blend suited base oils and suited additives and/or an additive package to
obtain a fully formulated cylinder lubricant. This is typically done at a
dedicated lubricant blend plant and the resulting cylinder lubricant has to
the
delivered to a ship or an off-shore plant for use in engines.
Apart from the mentioned inevitable mixing of cylinder oil and system oil
prior
art methods and systems do not otherwise mix these types of oils. Further,
some prior art methods/systems also suggest a variation in lubricant flow rate
or properties in response to actual engine conditions, cf. e.g. US 6,779,505.
However, such methods and systems do not address the deterioration of oils
due to contamination or other processes and the potential to re-use these
used oils as cylinder oil.
OBJECT AND SUMMARY OF THE INVENTION
It is an object of the present invention to provide a method of creating a
cylinder oil (and a corresponding system) that solves the above-mentioned
(and other) shortcomings of prior art. A further object is to provide this in
a
cost-effective and simplified way.

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4
A further object of the present invention is to enable improved performance of
non-total loss lubricants over time and thus a more efficient use of both non-
total loss lubricants and cylinder oil.
These objects, among others, are achieved by a method of (and
corresponding system) creating a cylinder oil, the method comprising
modification of at least one initial fluid by determining the TBN(s) of the at
least one initial fluid, determining a desired TBN of a cylinder oil and
adjusting the TBN(s) of the at least one initial fluid accordingly by blending
the at least one initial fluid with suited additive(s).
In this way, a method for modifying an initial fluid to create cylinder oil by
adjusting solely TBN is obtained.
This provides significant economical benefits since lubricants that otherwise
would have to be disposed of can be re-used as a total-loss cylinder
lubricant. Furthermore, cylinder oil does not have to be purchased. The
oil(s) used to blend the cylinder oil is/are of more consistent quality as it
is
replenished (contrary to the traditional practice) which reduces machinery
wear, etc. Thus, the replenishment of the initial fluid(s) provides enhanced
and consistent performance of the initial fluids resulting in greatly reduced
component wear and equipment lifecycle cost. Even further, a more
environmentally friendly method/system is provided since waste, in the form
of spent oil(s) that is discarded after prolonged use, is reduced as it is
converted into cylinder oil.
Preferably, at least one of the initial fluids are at least partially used
oil(s).
Hereby, a fully formulated cylinder lubricant is obtained by modifying TBN of
this used initial fluid(s).

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In a preferred embodiment, the suited additive(s) comprise at least one base.
In a further preferred embodiment, the at least one base comprises
1. basic salts of alkaline or earth alkaline elements, and/or
5 2. detergents and/or
3. dispersants.
The alkaline / earth alkaline elements may be e.g. K, Na, Ca, Ba, Mg or the
like. The basic salts may belong to the inorganic chemical families of e.g.
oxides, hydroxides, carbonates, sulfates or the like. The detergents may
belong to the organic chemical families of e.g. sulfonates, salicylates,
phenates, sulfophenates, Mannich-bases and the like. The dispersants may
belong to the organic chemical families of succinimides or the like.
In a preferred embodiment, the cylinder oil is used in reciprocating internal
combustion engines used in marine or stationary applications. -
In yet another embodiment, the reciprocating internal combustion engines
are two-stroke crosshead engines.
Preferably, the method and embodiments thereof according to the present
invention is used offshore, on-site or in a land based plant.
Preferably, the cylinder oil is created with a TBN in response to fuel oil
characteristics and/or actual engine operating requirements.
In another preferred embodiment, the TBN of the cylinder oil is chosen based
upon sulphur-content of the fuel oil.
Preferably, the initial fluid is a hydrocarbon fluid. In one embodiment, the
hydrocarbon fluid is a lubricant.

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6
In a preferred embodiment, the lubricant is a used lubricant, i.e. a lubricant
that has at least been partially used elsewhere.
Preferably, the used lubricant is selected from a group of lubricants, such as
hydraulic fluids, gear oils, system oils, trunk piston engine oils, turbine
oils,
heavy duty diesel oils, compressor oils and the like.
In a preferred embodiment, the created cylinder oil is based on two-stroke
engine system oil that continuously, near-continuously or intermittently is
tapped from an existing system and where the system oil is replenished.
In an alternative preferred embodiment, the created cylinder oil is based on a
mixture of lubricants that continuously, near-continuously or intermittently
are
tapped from an existing system and where the lubricants are replenished.
The oils used as initial fluids may e.g. be used or could alternatively be non-
used, i.e. straight from any fresh lubricant storage tank or the like.
In another embodiment, the method further comprises the step of using
suited instrumentation in order to control the quality of the finished
lubricant.
The present invention also relates to a system corresponding to and having
the same advantages as the method of the present invention. More
specifically, the present invention also relates to a system for providing a
cylinder oil, the system comprising: an apparatus for modifying at least one
initial fluid by determining the TBN(s) of the at least one initial fluid,
determining a desired TBN of a cylinder oil and adjusting the TBN(s) of the at
least one initial fluid accordingly by blending the at least one initial fluid
with
suited additive(s).

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7
Advantageous embodiments of the system according to the present invention
are defined in the sub-claims and described in detail in the following. The
embodiments of the system correspond to the embodiments of the method
and have the same advantages for the same reasons.
BRIEF DESCRIPTION OF THE DRAWINGS
These and other aspects of the invention will be apparent from and
elucidated with reference to the illustrative embodiments shown in the
drawing, in which:
Figure 1 shows a schematic block diagram of one embodiment according to
the present invention.
DESCRIPTION OF PREFERRED EMBODIMENTS
Figure 1 shows a schematic block diagram of one embodiment according to
the present invention. Shown are an all-loss cylinder lubricant supply
comprising cylinder oil (102), base additive(s) (103) and a system oil loop
comprising at least one initial fluid (101). Further shown is a two-stroke
crosshead engine (100), a waste tank (106), a fresh system oil tank (105), a
separator (107) and a blending apparatus (104) for carrying out the present
invention.
According to the present invention the cylinder oil is created by modification
of at least one initial fluid (101) by determining the TBN(s) of the at least
one
initial fluid, determining a desired TBN of a cylinder oil (102) and adjusting
the TBN(s) of the at least one initial fluid (101) accordingly by blending the
at
least one initial fluid (101) with suited additive(s) (103). This is
preferably
done by the blending apparatus (104). Preferably, the at least one initial
fluid

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8
are at least partially used oil(s). Hereby, a fully formulated cylinder
lubricant
is obtained by modifying TBN of spent oil.
Adjusting the TBN preferably comprises adjusting at least one additive level
or adding one or more additives, where the additives comprise at least one
base comprising basic salts of alkaline or earth alkaline elements, and/or
detergents and/or dispersants.
The alkaline / earth alkaline elements may be e.g. K, Na, Ca, Ba, Mg or the
like. The basic salts may belong to the inorganic chemical families of e.g.
oxides, hydroxides, carbonates, sulfates or the like. The detergents may
belong to the organic chemical families of e.g. sulfonates, salicylates,
phenates, sulfophenates, Mannich-bases and the like. The dispersants may
belong to the organic chemical families of succinimides or the like.
As mentioned, the cylinder oil may be used in reciprocating internal
combustion engines (e.g. two-stroke crosshead engines) used in marine or
stationary applications. The creation of a cylinder oil is due to its
simplicity
and the normal availability of the required initial fluid and the additives
very
suitable for offshore or on-site applications.
The creation of the cylinder oil may also take additional aspects into
consideration such as actual engine requirements and sulphur content of the
fuel.
The used initial fluid may e.g. be hydraulic fluids, gear oils, system oils,
trunk
piston engine oils, turbine oils, heavy duty diesel oils, compressor oils and
the like.
Preferably, the initial fluid is system oil and the total-loss lubricant is
cylinder
oil.

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9
In one embodiment, the created cylinder oil is based on two-stroke engine
system oil that continuously, near-continuously or intermittently is tapped
from an existing system and where the system oil is replenished.
Alternatively, the created cylinder oil is based on a mixture of oils that
continuously, near-continuously or intermittently are tapped from an existing
system and where the oils are replenished.
The oils may e.g. be used or could alternatively be non-used, i.e. straight
from any fresh lubricant storage tank or the like.
A significant advantage of the present invention is that the main engine(s)
only has to be supplied with fully-formulated, fresh system oil. The system
oil
is then used for its traditional purpose and some of the system oil is blended
with additives adjusting the TBN making it suitable for cylinder oil according
to the present invention. This increases the availability of the needed oil
geographically and increases competition between supplies of oil since all
presently known two-stroke system oils are usable as initial oil for the
cylinder oil by using the present invention. Further, since, where applicable,
other initial fluids, such as but not limited to used hydraulic, gear, trunk
piston
engine or compressor oils may be included in the process of creating cylinder
oil procurement cost will be considerably reduced .
Further, since some of initial fluids are now re-used in the manufacture of
cylinder oil (as opposed to their traditional use) they will have to be
replenished whereby the problem of gradual deterioration is minimised or
avoided.
In a preferred embodiment, a continuous, near-continuous or intermittently
tapping of the system oil from a two-stroke main engine and/or any other

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suited initial fluid is proposed to use these initial fluids as a basis for
the
creation of cylinder oil according to the present invention.
The additive(s) or additive package used by the modifier may serve several
5 purposes but will normally always be used for adjusting the oils TBN. The
process may also be used to provide flexible TBN levels as required by the
actual fuel oil properties and engine operating parameters.
The creation of cylinder oil/cylinder oil according to the present invention
is
10 due to its simplicity very well suited for on-site creation, e.g. aboard a
ship /
vessel, off-shore equipment, stationary plants, etc.
In the claims, any reference signs placed between parentheses shall not be
constructed as limiting the claim. The word "comprising" does not exclude
the presence of elements or steps other than those listed in a claim. The
word "a" or "an" preceding an element does not exclude the presence of a
plurality of such elements.

Representative Drawing
A single figure which represents the drawing illustrating the invention.
Administrative Status

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Event History

Description Date
Application Not Reinstated by Deadline 2009-12-07
Time Limit for Reversal Expired 2009-12-07
Deemed Abandoned - Failure to Respond to Maintenance Fee Notice 2008-12-08
Letter Sent 2008-04-23
Inactive: Single transfer 2008-02-19
Inactive: Cover page published 2007-05-23
Inactive: Courtesy letter - Evidence 2007-05-22
Inactive: Notice - National entry - No RFE 2007-05-16
Inactive: First IPC assigned 2007-04-17
Application Received - PCT 2007-04-16
National Entry Requirements Determined Compliant 2007-03-22
Application Published (Open to Public Inspection) 2006-03-30

Abandonment History

Abandonment Date Reason Reinstatement Date
2008-12-08

Maintenance Fee

The last payment was received on 2007-11-20

Note : If the full payment has not been received on or before the date indicated, a further fee may be required which may be one of the following

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Fee History

Fee Type Anniversary Year Due Date Paid Date
MF (application, 2nd anniv.) - standard 02 2006-12-07 2007-03-22
Basic national fee - standard 2007-03-22
MF (application, 3rd anniv.) - standard 03 2007-12-07 2007-11-20
Registration of a document 2008-02-19
Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
A.P. MOLLER-MAERSK A/S
Past Owners on Record
ALFIO BONCIOLINI
CLAUS MARTIN OLESEN
GIULIO GIOVANNI POMETTO
GUISEPPE NATOLI
HANS HEINRICH PETERSEN
JORN DRAGSTED
KLAUS-WERNER DAMM
NIELS-HENRIK LINDEGAARD
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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({010=All Documents, 020=As Filed, 030=As Open to Public Inspection, 040=At Issuance, 050=Examination, 060=Incoming Correspondence, 070=Miscellaneous, 080=Outgoing Correspondence, 090=Payment})


Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Description 2007-03-21 10 411
Drawings 2007-03-21 1 50
Claims 2007-03-21 4 123
Abstract 2007-03-21 1 92
Representative drawing 2007-05-16 1 36
Notice of National Entry 2007-05-15 1 192
Courtesy - Certificate of registration (related document(s)) 2008-04-22 1 130
Courtesy - Abandonment Letter (Maintenance Fee) 2009-02-01 1 174
Reminder - Request for Examination 2009-08-09 1 125
PCT 2007-03-21 6 200
Correspondence 2007-05-15 1 28