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Patent 2584189 Summary

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(12) Patent: (11) CA 2584189
(54) English Title: SOIL STABILIZATION METHOD
(54) French Title: METHODE DE STABILISATION DU SOL
Status: Granted and Issued
Bibliographic Data
(51) International Patent Classification (IPC):
  • E01C 21/00 (2006.01)
  • E01C 3/04 (2006.01)
  • E01C 7/36 (2006.01)
  • E01C 19/12 (2006.01)
  • E01C 19/22 (2006.01)
  • E01C 23/00 (2006.01)
  • E02D 3/12 (2006.01)
(72) Inventors :
  • MAIER, TERRY L. (United States of America)
(73) Owners :
  • TEAM LABORATORY CHEMICAL, LLC
(71) Applicants :
  • TEAM LABORATORY CHEMICAL, LLC (United States of America)
(74) Agent: MLT AIKINS LLP
(74) Associate agent:
(45) Issued: 2012-06-19
(22) Filed Date: 2007-04-05
(41) Open to Public Inspection: 2007-10-06
Examination requested: 2009-05-12
Availability of licence: N/A
Dedicated to the Public: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): No

(30) Application Priority Data:
Application No. Country/Territory Date
60/789,640 (United States of America) 2006-04-06

Abstracts

English Abstract

A method of use of a composition for soil stabilization is disclosed. The composition comprises a solution of soluble sodium silicate applied at the disclosed application rate to improve the load bearing capacity for a roadway. The method of the invention addresses the application of the disclosed composition to maximize stabilization of road beds.


French Abstract

La présente divulgation porte sur une méthode d'utilisation de composition pour la stabilisation du sol. La composition comprend une solution de silicate de sodium soluble appliquée au taux d'application divulgué pour améliorer la capacité de charge pour une chaussée. La méthode de la présente invention traite de l'application de la composition divulguée pour maximiser l'assise routière.

Claims

Note: Claims are shown in the official language in which they were submitted.


1. A method of soil stabilization for a road bed comprising:
providing soil stabilizer comprising 28-30 percent silicon dioxide by weight
and
8.5-9.5 percent sodium oxide by weight in an aqueous solution;
applying the soil stabilizer to the road in three steps, the steps comprising:
(i) a first step of applying the soil stabilizer to the road bed at a rate of
one gallon of the soil stabilizer per every 420-880 square yards of road
surface;
(ii) a second step of applying a mixture of road bed material and the
soil stabilizer to the road bed at a rate of one gallon of the soil stabilizer
per every
50-80 square yards of road surface; and
(iii) a third step of applying the soil stabilizer to the road bed at a rate
of one gallon of the soil stabilizer per every 360-700 square yards of road
surface.
2. The method of claim 1 wherein the road bed is compacted after each of the
steps of
applying the soil stabilizer.
3. The method of claim 2 wherein the road bed is leveled before the first step
of applying
the soil stabilizer.
4. The method of claim 3 wherein the grade and slope of the road bed is
finished before the
third step of applying the soil stabilizer.
13

5. The method of claim 2 wherein the grade and slope of the road bed is
finished before the
third step of applying the soil stabilizer.
6. The method of claim 5 wherein the road bed is compacted after the third
step of applying
the soil stabilizer until the surface of the road bed is dry.
7. The method of claim 6 wherein the second step comprises applying the
mixture of road
bed material and the soil stabilizer in lifts of one to two inches in
thickness and compacting the
road bed after each application of the mixture.
8. The method of claim 7 wherein the soil stabilizer is diluted in a ratio of
about one 55-
gallon drum of the soil stabilizer per 5,000 gallons of water before the three
application steps.
9. The method of claim 1 wherein the second step comprises applying the
mixture of road
bed material and the soil stabilizer in lifts of one to two inches in
thickness and compacting the
road bed after each application of the mixture.
10. The method of claim 1 wherein the providing step comprises providing a
soil stabilizer
comprising about 28.4 percent silicon dioxide by weight and about 8.7 percent
sodium oxide by
weight in an aqueous solution.
11. A method of soil stabilization for a road bed comprising:
14

providing a soil stabilizer coinprising 28-30 percent silicon dioxide by
weight and
8.5-9.5 percent sodium oxide by weight in an aqueous solution; and
applying the soil stabilizer to the road bed at a rate of 0.018-0.027 gallons
of the
soil stabilizer per square yard of road bed.
12. The method of claim 11 wherein the soil stabilizer is diluted in a ratio
of about one 55-
gallon drum of the soil stabilizer per 5,000 gallons of water before applying
step.
13. The method of claim 12 wherein the applying step comprises applying the
mixture of
road bed material and the soil stabilizer in lifts of one to two inches in
thickness and compacting
the road bed after each application of the mixiture.
14. The method of claim 13 wherein the providing step comprises providing a
soil stabilizer
comprising about 28.4 percent silicon dioxide by weight and about 8.7 percent
sodium oxide by
weight in an aqueous solution.
15. A method of soil stabilization for a road bed comprising:
providing a soil stabilizer comprising silicon dioxide and sodium oxide
wherein
the average weight ratio of silicon dioxide to sodium oxide is between 3.2 and
3.3;
applying the soil stabilizer to the road bed in three steps, the steps
comprising:
(i) a first step of applying the soil stabilizer to the road bed at a rate of
one pound of the soil stabilizer per every 95-210 square yards of road
surface;

(ii) a second step of applying a mixture of road bed material and the
soil stabilizer to the road bed at a rate of one pound of the soil stabilizer
per every
12-20 square yards of road surface; and
(iii) a third step of applying the soil stabilizer to the road bed at a rate
of one pound of the soil stabilizer per every 80-170 square yards of road
surface.
16. The method of claim 15 wherein the soil stabilizer is diluted in water
before the steps of
applying the soil stabilizer.
17. The method of claim 15 wherein the second step comprises applying the
mixture of road
bed material and the soil stabilizer in lifts of one to two inches in
thickness and compacting the
road bed after each application of the mixture.
18. The method of claim 16 wherein the road bed is compacted after each of the
steps of
applying the soil stabilizer.
19. The method of claim 17 wherein the road bed is leveled before the first
step of applying
the soil stabilizer.
20. The method of claim 18 wherein the grade and slope of the road bed is
finished before
the third step of applying the soil stabilizer.
16

21. A method of full-depth road reclamation comprising:
crushing an existing flexible pavement section and predetermined portion of
underlying road bed;
pulverizing the crushed flexible pavement section and predetermined portion of
underlying road bed;
uniformly blending the pulverized flexible pavement section and predetermined
portion of underlying road bed;
providing a soil stabilizer comprising 28-30 percent silicon dioxide by weight
and
8.5-9,5 percent sodium oxide by weight in an aqueous solution;
applying the soil stabilizer to the uniformly blended flexible pavement
section and
predetermined portion of underlying road bed in two steps, the steps
comprising:
(i) a first step of applying a mixture of the crushed, pulverized, and
uniformly blended flexible pavement section and underlying road bed and the
soil
stabilizer to the road bed at a rate of one gallon of the soil stabilizer per
every 42-
74 square yards of road surface; and
(ii) a second step of applying the soil stabilizer to the road bed at a rate
of one gallon of the soil stabilizer per every 275-700 square yards of road
surface.
22. The method of claim 21 wherein the road bed is compacted after each of the
steps of
applying the soil stabilizer.
17

23. The method of claim 22 wherein the grade and slope of the road bed is
finished before
the second step of applying the soil stabilizer.
24. The method of claim 23 wherein the road bed is compacted after the second
step of
applying the soil stabilizer until the surface of the road bed is dry.
25. The method of claim 24 wherein the soil stabilizer is diluted in a ratio
of about one 55-
gallon drum of the soil stabilizer per 5,000 gallons of water before the two
application steps.
26. The method of claim 21 wherein the providing step comprises providing a
soil stabilizer
comprising about 28.4 percent silicon dioxide by weight and about 8.7 percent
sodium oxide by
weight in an aqueous solution.
27. A kit for soil stabilization of a road bed comprising:
a soil stabilizer comprising 28-30 percent silicon dioxide by weight and 8.5-
9.5
percent sodium oxide by weight in an aqueous solution; and
instructions for a method of application of the soil stabilizer to the road
bed, the
method comprising:
(i) a first step of applying the soil stabilizer to the road bed at a rate of
one gallon of the soil stabilizer per every 420-880 square yards of road
surface;
18

(ii) a second step of applying a mixture of road bed material and the
soil stabilizer to the road bed at a rate of one gallon of the soil stabilizer
per every
50-80 square yards of road surface; and
(iii) a third step of applying the soil stabilizer to the road bed at a rate
of one gallon of the soil stabilizer per every 360-700 square yards of road
surface.
28. A method of soil stabilization for a road bed comprising:
providing a soil stabilizer comprising 28-30 percent silicon dioxide by weight
and
8.5-9.5 percent sodium oxide by weight in an aqueous solution; and
applying the soil stabilizer to the road bed at a rate of about 0.005 gallons
of the
soil stabilizer per square yard per inch thickness of road bed.
39

Description

Note: Descriptions are shown in the official language in which they were submitted.


CA 02584189 2007-04-05
SOIL STABILIZATION METHOD
Field of the Invention
The present invention relates to reconstructing and paving roads. More
specifically, the
present invention is method of using a soluble sodium silicate composition to
stabilize soil for a
road base or sub-base applicable to the construction of new roads and the
reconstruction or
reinforcement of existing roads.
Background of the Invention
Construction and maintenance of roads, especially secondary roads, requires a
solid,
stabilized base and sub-base on which to place the road surface. Preparation
for road paving
generally includes compaction of the base or sub-base, which may comprise
clay, gravel, crushed
stone, and the like, either taken from the native materials or transported to
the site. Frequently,
the base material includes crushed concrete and asphalt from the old road base
or surface.
Whether the material is primarily reclaimed from an old road surface material,
taken from a new
or old base on site, or is made from materials transported to the site,
maximizing the stability of
the material increases the longevity of the road surface and decreases the
frequency and cost of
repairs.
Soils too weak to bear the anticipated load can be stabilized by the addition
of materials
which impart mechanical strength, such as aggregate, and by the addition of
chemical stabilizers,
which decrease water absorption and increase the cohesion of the soil matrix
by forming a
cement-like compound to hold the matrix together. The appropriate type of
stabilization and
results to be expected depend upon the soil types encountered and methods of
application of the
2

CA 02584189 2007-04-05
stabilizer and construction of the road. A range of soil compositions can
serve as good road base
material, but high strength, resistance to shear, and resistance to erosion or
swelling by water are
required. Most native soils require some extent of stabilization to achieve
these goals and
provide a proper material for road construction.
Failure to provide an adequately stabilized base results in frequent and
expensive repairs.
Various techniques and compounds are known for stabilizing the soil or fill
beneath pavement or
other construction to provide a stable, high integrity base on which to place
the pavement or
other construction. Materials commonly used for this purpose include lime and
fly-ash mixtures,
calcium chloride, sodium silicates, mixtures of molasses and fuel oil, calcium
acrylate, lignin
sulfonate, and other materials.
Chlorides are the most commonly used product for soil stabilization. Calcium
chloride
assists in the compactive process, making it possible to obtain greater
densities and greater
strengths with normal compactive efforts. A major limitation of calcium
chloride is its narrow
application range. If the calcium chloride solution is applied at a less than
specific dilution ratio
the effectiveness of the compound is diminished, while application at a higher
than necessitated
dilution ratio causes beading on the application surface and thus prevents
treatment of the target
soil. Further, the widespread use of large quantities of chlorides has been
shown to be
environmentally harmful. Finally, chlorides are extremely corrosive on road
construction and
maintenance equipment.
Resins available under various commercial names are used as soil stabilizers
and
typically comprise lignin sulfonate, which is a by-product of the pulp milling
industry. Lignin
sulfonate is also referred to as "tree sap" by those skilled in the art of
road construction- They
3

CA 02584189 2011-10-04
provide cohesion to bind soil particles together, but are primarily used when
they can be
incorporated into the surface gravel.
Additives used for roadbed stabilization are disclosed by U. S. Patent No.
4,106,296
(epoxy resins), U.S. Patent No. 4,373,958 (lime kiln dust), U.S. Patent No.
5,577,338 (fly ash),
U.S. Patent No. 5,820,302 (silicate and cement), and U.S. Patent No. 6,689,204
(potassium
formate and cationic polymer). U.S. Patent No. 7,070,709, discloses various
prior art
compositions used for soil stabilization. Those products, however, have
numerous disadvantages
such as poor longevity, high cost, and environmental toxicity. The trade-offs
are either accepting
the environmental issues that come with products of longer useful life;
dealing with a shorter
lifespan for an environmentally friendly product; or paying significantly more
for
environmentally safe products with a favorable useful life.
A more acceptable method of roadbed stabilization is needed. It is an object
of this
invention to provide an improved composition and method of using the improved
composition
for soil stabilization that is both economical and environmentally sound.
Summar'of the Invention
The present invention is directed to a method of using a composition to
provide solid,
stabilized, and extremely hard bases and sub-bases for road construction. The
composition is
generally comprised of a soluble sodium silicate which, applied at the
disclosed application rate,
increases aggregate base strength for a given roadway at a faction of the cost
of existing
materials. The method of the invention addresses the application of the
disclosed composition to
-4-

CA 02584189 2007-04-05
maximize stabilization of roadbeds. The present invention addresses drawbacks
experienced
with the prior an because it provides an effective road stabilizer that is
both economical and
environmentally friendly.
Detailed Descries on of the Preferred Embodiments
The following descriptions of the present invention have been simplified to
illustrate
elements that are relevant for a clear understanding of the present invention.
The descriptions
eliminate, for purposes of clarity, elements found in typical soil stabilizers
and detailed
explanations of procedures used in road construction. Those of ordinary skill
in the art will
recognize that other elements of both the composition and method may be
desirable or necessary
to implement the present invention. Because such elements are well known in
the art and do not
facilitate a clearer understanding of present invention, a description of such
elements may not be
provided herein.
The stabilizer of thd present invention comprises a non-toxic, water soluble
chemical
composition used as a material stabilizer for road bases. The disclosed
stabilizer generally
comprises a soluble sodium silicate in a water base, otherwise known as
"waterglass." The
preferred embodiment of the stabilizer contemplates an aqueous solution
consisting of 28-30
percent silicon dioxide by weight and 8.5-9.5 percent sodium oxide by weight
with an overall
specific gravity ranging from 1.37 to 1.42 and an average viscosity of 150 at
20 C. The average
weight ratio of silicon dioxide to sodium oxide for the stabilizer should be
between 3.1 and 3.4.
A commercial version of the stabilizer is available from INEOS Silicas
Americas located in
Joliet, Illinois under the trade name Crystal 78.
5

CA 02584189 2007-04-05
Application of the stabilizer of the present invention is accomplished by the
use of
conventional spray equipment known in the an of road construction and
maintenance. It may be
gravity fed or pumped through hoses, spray nozzles, or fixed sprayers to
uniformly apply the
compound to the material to be treated. Motor-graders, asphalt grinders,
mixers, pug mills,
compactors, rollers, and other conventional road construction equipment may he
utilized to
blend, set grade, and compact the stabilized base.
Ili
A preferred embodiment of the present invention includes the application of
the stabilizer
at three steps of the road bed construction at specific application rates. In
the preferred
embodiment, it is recommended that the road bed be laid in sections of 1/4 to
1/2 mile in length.
Once the road bed has been leveled and the bed construction material has been
windrowed along
the road, the road bed is prepared by applying stabilizer to the road bed at a
rate of 20-25 gallons
per mile of 24'-30' width road surface with a depth of three inches to six
inches. The amount of
water in which the stabilizer is diluted will depend upon the type of
applicator used, size of the
water truck, and the weather conditions (temperature, humidity, wind). The
typical
recommended dilution is about 55 gallons of stabilizer per 5,000 gallons of
clean water. After
the initial application of the stabilizer, the road bed should be compacted by
any of the various
methods known in the art of road construction.
The second step of the preferred embodiment involves applying material from
the
windrow to the road bed in one to two-inch lifts. As the grader is laying
material from the
windrow across the road, the stabilizer is applied to the lift and then mixed
into the material
placed upon the road bed. The amount of stabilizer applied per lift will
depend upon the number
of lifts to be used in the road bed construction. A total of 220 gallons of
stabilizer should be
used for each mile of 24'-30' width of road surface assuming a total bed
thickness of three to six
6

CA 02584189 2007-04-05
inches. The amount of water used for the application of the 220 gallons of
stabilizer per mile
will depend upon the type of applicator used, size of the water truck, and the
weather conditions.
Each lift of mixed material and stabilizer should be well mixed and compacted
by any of the
methods known in the art prior to application of the next lift. This process
is repeated until all
lifts have been applied (windrow has been completely used) and well compacted.
The finish
grade and slope of the bed should then be prepared.
The third step of the preferred embodiment is finishing off the road bed
surface with
additional stabilizer. The stabilizer is applied to the finished bed at a rate
of 25-30 gallons per
mile of 24'-30' width road surface with a depth of three inches to six inches.
Compaction of the
road surface should continue until the surface is dry. As with the previous
steps, the amount of
water used to dilute the 25-30 gallons of stabilizer will depend upon the type
of applicator used,
the size of the water truck, and the weather conditions.
The preferred embodiment also contemplates keeping the working surfaces wet
while
compacting. The appropriate amount of moisture for working road compaction is
well known by
those in the art of road construction. It is recommended that compactors
constantly work the
road to maximize the hardening provided by the stabilizer. Roadways may be
further enhanced
by the application of a sealant to protect the new road bed from the elements.
The preferred
embodiment contemplates using a'surface treatment coating process such as the
application of a
bituminous chip seal, otta seal (oil/gravel mixture), cement, bituminous hot
mix, or any of the
other surface treatment processes known in the art.
As road widths vary, the present invention contemplates using the following
total
stabilizer amounts for all three steps per mile of three-inch to six-inch
depth road at the ratios
described herein:
7
it

CA 02584189 2007-04-05
Road Bed Surface Width (Peet) Amount of Stabilizer (Gallons)
24-30 275
31-37 330
38-44 385
45-51 440
For a seven-inch road depth, the present invention contemplates using the
following stabilizer amounts for all three steps per mile of road at the
ratios described herein:
Road S ace Width (Feet) Amount of Stabilizer (Gallons)
24-30 330
31-37 385
38-44 440
45-51 495
For an eight-inch road depth, the present invention contemplates using the
following
stabilizer amounts for all three steps per mile of road at the ratios
described herein:
Road Bed Surface Width (Feet) Am= of Stabilizer (Gallons)
24-30 385
31-37 440
38-44 495
45-51 550
While the present invention may be used for a wide variety of aggregate
mixtures
comprising clay material, caliche soils, and sandy loam with low sand content,
it is
recommended that the soil used in constructing the road bed consist of a good
binding material
8
i'.

CA 02584189 2007-04-05
with aggregate large enough to provide a driving surface. Examples of
aggregate gradation that
provide exceptional results are provided below:
Esample Example l3
Sieve Size % Passing Sieve Size % Passing
1" 100 1" 100
3/4" 100 3/4" 100
3/8" 65-95 3/8" 50-85
#4 40-85 #4 35-80
#10 20-70 #10 20-70
#40 10-45 #40 10-40
#200 10-15 #200 10-15
Example C Exa rile D
Sieve Size % Passing Sieve Size Pas in
1" 100 3/4" 100
3/4" 95-100 #4 38-75
3/8" 65-95 #8 22-62
#4 40-75 #30 12-37
#10 25-70 #200 8-15
#40 10-45
#200 10-15
The material passing through the #200 sieve should be binding-type material
consisting of more
clay than silt (an average of 8-15 percent silt).
9

CA 02584189 2007-04-05
Another preferred embodiment of the present invention is the use of the
disclosed
stabilizer with full-depth reclamation. Full-depth reclamation is an in-place
recycling alternative
to road reconstruction. A reclaiming machine is used to cum an old asphalt
pavement into a road
base by uniformly pulverizing the full thickness of the old pavement and
blending it with a
portion of underlying material. The process for full depth reclamation
involves three steps: the
pulverization of the original surface and the blending of additives and
imported materials,
grading and compacting the new surface, and the application of a wearing
surface. The process
allows for correcting drainage and cross slope problems, as well as widening
the roadway.
The process usually adds bituminous emulsion, chemical or mechanical
stabilization
agents to enhance the strength of the new base that is sealed with an asphalt
friction course or a
sealing treatment, depending on expected loads. Prior art additives used in
full-depth
reclamation commonly include bituminous emulsions, but they are often used in
combination
with chemical additives like lime, portland cement, and fly ash to add
strength, as well as
mechanical additives like crushed stone, RAP, and sand to correct deficiencies
in the existing
materials. Use of the stabilizer of the present invention provides the same
benefits as with new
road construction and eliminates the same disadvantages of existing
stabilizers.
The steps in the preferred embodiment of full-depth reclamation are similar to
those used
in new road bed construction, but includes the initial steps of scarifying
(ripping) and pulverizing
existing pavement. The depth of pulverization is usually six to ten inches,
which on secondary
roads will typically include all of the surface and base, plus some part of
the subgrade. To
achieve the proper gradation after pulverization, more than one pass of the
equipment may be
necessary. For particle distribution, the final pulverized material should be
100% smaller than
two inches with 55% passing a No. 4 sieve. The material may be pulverized in
place, or may be

CA 02584189 2007-04-05
removed and windrowed along the side of the road bed for application. If the
material is
windrowed. the same steps may be used as disclosed above for new road bed
construction.
For in-place pulverization, once the existing pavement has been sufficiently
pulverized,
the material must be shaped and graded to the desired cross-section and grade.
The final base
elevation requirements may necessitate a small amount of material removal or
addition. For in-
place pulverization, once the material is properly graded, the stabilizer of
the present invention is
applied to the road bed at a rate of 240-245 gallons per mile of 24'-30' width
road surface with a
depth of three inches to six inches. As with new roadbed construction, it is
recommended that
the road bed be laid in sections of 1/4 to 1/2 mile in length. The amount of
water in which the
stabilizer is diluted will depend upon the type of applicator used, size of
the water truck, and the
weather conditions (temperature, humidity, wind). The typical recommended
dilution is about
55 gallons of stabilizer per 5,000 gallons of clean water. The stabilizer and
pulverized pavement
should then be well mixed and compacted by any of the methods known in the art
prior to
application of the next lift. The finish grade and slope of the bed should
then be prepared.
As with new road bed construction, the preferred embodiment includes finishing
off the
~~II
road bed surface with additional stabilizer. The stabilizer is applied to the
finished bed at a rate
of 25-30 gallons per mile of 24'-30' width road surface with a depth of three
inches to six inches.
Compaction of the road surface should continue until the surface is dry. As
with the previous
steps, the amount of water used to dilute the 25-30 gallons of stabilizer will
depend upon the type
of applicator used, the size of the water truck, and the weather conditions.
The preferred
embodiment contemplates using a surface treatment coating process such as the
application of a
bituminous chip seal, otta seal (oillgravel mixture), cement, bituminous hot
mix, or any of the
other surface treatment processes known in the art.
11

CA 02584189 2007-04-05
The present invention may be embodied in other specific forms without
departing from
the spirit of any of the essential attributes thereof; therefore, the
illustrated embodiment should
be considered in all respects as illustrative and not restrictive, reference
being made to the
appended claims rather than to the foregoing description to indicate the scope
of the invention.
ICI
12

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Administrative Status

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Event History

Description Date
Maintenance Request Received 2020-05-12
Common Representative Appointed 2019-10-30
Common Representative Appointed 2019-10-30
Letter Sent 2019-10-11
Inactive: Single transfer 2019-10-01
Revocation of Agent Requirements Determined Compliant 2016-08-24
Inactive: Office letter 2016-08-24
Inactive: Office letter 2016-08-24
Appointment of Agent Requirements Determined Compliant 2016-08-24
Appointment of Agent Request 2016-07-12
Revocation of Agent Request 2016-07-12
Inactive: Office letter 2016-06-09
Grant by Issuance 2012-06-19
Inactive: Cover page published 2012-06-18
Pre-grant 2012-03-26
Inactive: Final fee received 2012-03-26
Notice of Allowance is Issued 2012-02-09
Letter Sent 2012-02-09
Notice of Allowance is Issued 2012-02-09
Inactive: Approved for allowance (AFA) 2012-01-31
Amendment Received - Voluntary Amendment 2011-10-04
Inactive: S.30(2) Rules - Examiner requisition 2011-08-31
Small Entity Declaration Determined Compliant 2010-03-22
Small Entity Declaration Request Received 2010-03-22
Letter Sent 2009-06-16
Letter Sent 2009-06-11
Request for Examination Requirements Determined Compliant 2009-05-12
Reinstatement Requirements Deemed Compliant for All Abandonment Reasons 2009-05-12
Small Entity Declaration Determined Compliant 2009-05-12
All Requirements for Examination Determined Compliant 2009-05-12
Amendment Received - Voluntary Amendment 2009-05-12
Request for Examination Received 2009-05-12
Small Entity Declaration Request Received 2009-05-12
Deemed Abandoned - Failure to Respond to Maintenance Fee Notice 2009-04-06
Application Published (Open to Public Inspection) 2007-10-06
Inactive: Cover page published 2007-10-05
Inactive: IPC assigned 2007-07-25
Inactive: First IPC assigned 2007-07-25
Inactive: IPC assigned 2007-07-25
Inactive: IPC assigned 2007-07-25
Inactive: IPC assigned 2007-07-25
Inactive: IPC assigned 2007-07-25
Inactive: IPC assigned 2007-07-25
Inactive: IPC assigned 2007-07-25
Application Received - Regular National 2007-05-07
Filing Requirements Determined Compliant 2007-05-07
Letter Sent 2007-05-07
Inactive: Filing certificate - No RFE (English) 2007-05-07
Small Entity Declaration Determined Compliant 2007-04-05

Abandonment History

Abandonment Date Reason Reinstatement Date
2009-04-06

Maintenance Fee

The last payment was received on 2012-03-26

Note : If the full payment has not been received on or before the date indicated, a further fee may be required which may be one of the following

  • the reinstatement fee;
  • the late payment fee; or
  • additional fee to reverse deemed expiry.

Please refer to the CIPO Patent Fees web page to see all current fee amounts.

Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
TEAM LABORATORY CHEMICAL, LLC
Past Owners on Record
TERRY L. MAIER
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
Documents

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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Description 2007-04-05 11 358
Abstract 2007-04-05 1 10
Claims 2007-04-05 6 150
Cover Page 2007-10-01 1 26
Claims 2009-05-12 7 158
Description 2011-10-04 11 359
Cover Page 2012-05-24 1 26
Maintenance fee payment 2024-03-05 25 1,011
Courtesy - Certificate of registration (related document(s)) 2007-05-07 1 105
Filing Certificate (English) 2007-05-07 1 158
Reminder of maintenance fee due 2008-12-08 1 112
Courtesy - Abandonment Letter (Maintenance Fee) 2009-06-01 1 172
Acknowledgement of Request for Examination 2009-06-11 1 174
Notice of Reinstatement 2009-06-16 1 164
Commissioner's Notice - Application Found Allowable 2012-02-09 1 162
Courtesy - Certificate of registration (related document(s)) 2019-10-11 1 121
Correspondence 2009-05-12 4 125
Fees 2009-05-12 4 125
Fees 2010-03-22 3 120
Correspondence 2010-03-22 2 62
Fees 2011-03-18 3 113
Correspondence 2012-03-26 2 60
Fees 2012-03-26 3 115
Courtesy - Office Letter 2016-06-09 2 42
Change of agent 2016-07-12 2 64
Courtesy - Office Letter 2016-08-24 1 25
Courtesy - Office Letter 2016-08-24 1 24
Maintenance fee payment 2020-05-12 2 46