Note: Descriptions are shown in the official language in which they were submitted.
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PRODUCT FOR PRE-TREATMENT AND LAUNDERING OF STAINED FABRIC
FIELD OF THE INVENTION
A product for pre-treatment and laundering of a stained fabric.
BACKGROUND OF THE INVENTION
Treating stained garments is an aspect of laundering that could be improved.
There are a
variety of commercially available approaches for treating stains. In one
approach the consumer
merely washes with a detergent touted as having the ability to treat stains.
Such an approach
tends to work satisfactorily if the stains are light and not greasy. If the
stains are heavy,
particularly heavy greasy stains, the stains might not be removed because the
chemical
ingredients of detergent are diluted in the wash and are not concentrated at
the stain. This can
leave the consumer dissatisfied when, at the end of the wash cycle, the stains
are still visible.
The prospects for successful stain treatment after washing are limited,
particularly if the failure is
not detected until after drying the stained garment.
In another approach to treating stains, a separate stain treatment aid may be
applied to the
stain, e.g., by spraying or squirting the stain treatment aid directly on the
stain or using a wipe
impregnated with a stain treatment aid to scrub a stain. Some stain treatment
aids include a
motorized brush or scrubbing implement to assist with treating the stain in
the fabric. This
approach, however, requires the consumer to purchase and use multiple products
- detergent,
stain treatment aid, and any accompanying devices. The consumer must store all
of these items
near the washing machine, frequently in an unsightly gathering of laundry
products. The
consumer must remember to treat stains prior to placing stained garments in
the washing
machine. The consumer must locate the stain treatment aid and manipulate the
packaging or
device to apply the stain treatment aid to the stain. After applying the stain
treatment aid, the
consumer must then open the laundry detergent, measure out an appropriate
dose, and deliver the
dose of detergent to the washing machine. Finally, the consumer must store the
laundry
detergent. This multistep process is a less than desirable consumer
experience, particularly given
all the other demands on the consumef s time.
In yet another approach, some liquid detergents may be used to pre-treat
stains through
the local application of a small quantity of detergent to the stained portion
of the garment.
However, it can be difficult to pour a small quantity of detergent and apply
it to a stain, when the
detergent package is not designed for such pretreat dosing. Also, consumers
may not remember
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to pretreat stains, when there is no signal or reminder to pretreat associated
with the detergent.
Finally, the use of a neat portion of liquid detergent may not provide for the
consumer-desired
removal of a wide range of stains. For example, exposing a stained fabric to
the high level of
hydrophobic surfactants found in some liquid detergents may provide for good
greasy stain
removal, but it may not provide for good bleachable stain (e.g., beverage
stain) removal.
With these limitations in mind, there is a continuing unaddressed need for a
product and
approach for treating stains that intuitively suggests to the consumer to
treat stains properly, is
intuitive for the consumer to remember to apply, is simple to apply, and that
provides effective
removal of a variety of stains with a single product. The present invention
addresses the
aforementioned needs by providing an "all-in-one' product for pre-treatment
and laundering of
fabric. This all-in-one product comprises a novel combination of a cap and a
detergent
composition that allows for the removal of a wide range of stains, as
described in greater detail
hereinafter.
SUMMARY OF THE INVENTION
The present invention attempts to solve one more of the aforementioned needs
by
providing, in one aspect of the invention, a product for pre-treatment and
laundering of fabric
having a stained portion, the product comprising a pourable aqueous detergent
composition and a
cap for dispensing said pourable aqueous detergent composition:
A. the pourable aqueous detergent composition comprising:
a) a hydrophobic surfactant system having a Hydrophilic Index of from about 6
to
about 9;
B. the cap comprising:
a) a base having a base interior and a base exterior opposing said base
interior, said base
interior having a periphery; and
b) a vessel wall having an interior surface and an exterior surface opposing
said interior
surface, the vessel wall extending from the periphery to a rim, the interior
surface and the
base interior defining a pour volume, the base interior forming a closed end
of said pour
volume;
wherein:
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i. the cap is sealingly engaged to a container containing said detergent
composition
by a connector disposed on said cap and a corresponding receiver disposed on
an
opening of said container;
ii. the pour volume is sized and dimensioned to provide for a unit dose of the
detergent composition; and
iii. the cap further comprises a plurality of first surface irregularities at
a location selected from
the group consisting of: on the rim, on the base exterior, between the
connector disposed on the
cap and the rim, and combinations thereof.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a schematic of a cap having first surface irregularities.
FIG. 2 is a schematic illustrating ribs.
FIG. 3 is a schematic illustrating nubs.
FIG. 4 is a schematic illustrating bristles.
FIG. 5 is a schematic illustrating rings.
FIG. 6 is a schematic of a cap having a pouring ledge, aperture, and first
surface
irregularities.
FIG. 7 is a schematic of a cap having a pouring ledge, aperture, and first
surface
irregularities.
FIG. 8 is a schematic of a cap having second surface irregularities.
FIG. 9 is a schematic of a cap having second surface irregularities.
FIG. 10 is a schematic of a cap having a spout.
FIG. 11 is a schematic of a cap having a spout.
FIG. 12 is a schematic of a cap having second surface irregularities and a
spout.
FIG. 13 is a schematic of a cap having first surface irregularities, a pouring
ledge, an
aperture, and an apex.
FIG. 14 is a schematic of a cap having a first region and a second region on
the base
exterior.
FIG. 15 is profile view of the cap shown in FIG. 14.
DETAILED DESCRIPTION OF THE INVENTION
As used herein, the articles"d'and"alf when used in a claim, are understood to
mean one or
more of what is claimed or described.
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As used herein, "front-end stability agent' means an agent that is added
directly to a fabric
softener active, before the fabric softener active is hydrated and before it
is combined with the
remaining components of the fabric softener composition (e.g., perfume,
silicones, polymers).
As used herein, the terms"include7includes' and"including' are meant to be non-
limiting.
As used herein,`Ilourabld'refers to a liquid having a viscosity of less than
about 7000 cPs,
typically less than about 5000 cPS, more typically less than about 2000 cPs,
even more typically
less than about 1000 cPs, even more typically less than about 750 cPS, most
typically less than
about 600 cPs and a viscosity greater than about 50 cPs, typically greater
than about 100 cPs,
more typically greater than about 150 cPs, even more typically greater than
about 300 cPs, most
typically greater than about 350 cPs. Viscosity is measured at a shear rate of
20/s at 21 C.
Unless otherwise noted, all component or composition levels are in reference
to the active
portion of that component or composition, and are exclusive of impurities, for
example, residual
solvents or by-products, which may be present in commercially available
sources of such
components or compositions.
It should be understood that every maximum numerical limitation given
throughout this
specification includes every lower numerical limitation, as if such lower
numerical limitations
were expressly written herein. Every minimum numerical limitation given
throughout this
specification will include every higher numerical limitation, as if such
higher numerical
limitations were expressly written herein. Every numerical range given
throughout this
specification will include every narrower numerical range that falls within
such broader
numerical range, as if such narrower numerical ranges were all expressly
written herein.
Product for Pre-treatment and Laundering of a Stained Fabric
The present invention addresses the need for a product and approach for
treating stains
that intuitively suggests to the consumer to treat stains properly, is
intuitive for the consumer to
remember to apply, is simple to apply, and provides effective removal of a
variety of stains with
a single product by providing an "all-in-one' product for pre-treatment and
laundering of fabric.
This all-in-one product comprises a novel combination of a cap and a detergent
composition.
The cap serves both as a visual reminder to the consumer to pre-treat stains
and a built-in stain
treatment applicator, particularly for particulate stains, e.g., clay and
makeup. The detergent
composition is formulated to remove, in particular, greasy stains.
Specifically, the detergent
composition may include a surfactant system having a low Hydrophilic Index to
provide for the
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removal of greasy stains. Thus, the combination of the detergent composition
and the cap of the
invention enables the removal of a wide variety of stains, from greasy stains
to particulate stains.
Pourable aqueous detergent composition
5 The compositions according to the invention can dispensed in any
suitable way
including, but not limited to, being poured from a spout and/or delivered from
a squeezable
bottle.
The viscosity and the rheology of the products according to the invention will
be tuned
by one skilled in the art so that the product has a low enough viscosity to be
released in the wash
without leaving residues on fabrics, on the cap or washing machine parts, and
a high enough
viscosity so that it does not flow too easily increasing the risk of splashes
and of messiness:'
The pourable aqueous detergent composition according to the present invention
may
comprise a hydrophobic surfactant system. The detergent composition may
further comprise an
ingredient selected from a chelant system, a builder, water, an enzyme, and
other ingredients.
Hydrophobic Surfactant System
As used herein, ehydrophobic surfactant systennas a"Hydrophilic IndeK'of from
about 6
to about 9, from about 7 to about 8.5, or from about 7.5 to 8Ø Any
combination of surfactants
that provide for a hydrophobic surfactant system having a"Hydrophilic IndeK'
of from about 6 to
about 9, are of use. The detergent compositions may comprise by weight
percentage from about
5% to about 50%, from about 10% to about 42% or from about 15% to about 31% of
total
surfactant. The surfactant system comprises surfactant selected from the group
of: anionic,
nonionic, cationic, zwitterionic, amphoteric surface active agents and
mixtures thereof.
Anionic Surfactants
Suitable anionic surfactants may be any of the conventional anionic surfactant
types
typically used in liquid detergent products. Such surfactants include the
alkyl benzene sulfonic
acids and their salts as well as alkoxylated or non-alkoxylated alkyl sulfate
materials. Exemplary
anionic surfactants are the alkali metal salts of C10-C16 alkyl benzene
sulfonic acids, preferably
C11-C 14 alkyl benzene sulfonic acids. In one aspect, the alkyl group is
linear. Such linear alkyl
benzene sulfonates are known as "LAS". Such surfactants and their preparation
are described for
example in U.S. Patent Nos. 2,220,099 and 2,477,383. Especially preferred are
the sodium and
potassium linear straight chain alkylbenzene sulfonates in which the average
number of carbon
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atoms in the alkyl group is from about 11 to 14. Sodium C11-C14 LAS, e.g., C12
LAS, are a
specific example of such surfactants.
Another exemplary type of anionic surfactant comprises ethoxylated alkyl
sulfate
surfactants. Such materials, also known as alkyl ether sulfates or alkyl
polyethoxylate sulfates,
are those which correspond to the formula: R'-0-(C2H40)11-S03M wherein R is a
C8-C20 alkyl
group, n is from about 1 to 20, and M is a salt-forming cation. In a specific
embodiment, R is
Cm-C18 alkyl, n is from about 1 to 15, and M is sodium, potassium, ammonium,
alkylammonium,
or alkanolammonium. In more specific embodiments, R is a C12-C16, n is from
about 1 to 6 and
M is sodium.
The alkyl ether sulfates will generally be used in the form of mixtures
comprising varying
R chain lengths and varying degrees of ethoxylation. Frequently such mixtures
will inevitably
also contain some non-ethoxylated alkyl sulfate materials, i.e., surfactants
of the above
ethoxylated alkyl sulfate formula wherein n=0. Non-ethoxylated alkyl sulfates
may also be
added separately to the compositions of this invention and used as or in any
anionic surfactant
component which may be present. Specific examples of non-alkoyxylated, e.g.,
non-ethoxylated,
alkyl ether sulfate surfactants are those produced by the sulfation of higher
C8-C20 fatty alcohols.
Conventional primary alkyl sulfate surfactants have the general formula: R0503-
M wherein R
is typically a C8-C20 alkyl group, which may be straight chain or branched
chain, and M is a
water-solubilizing cation. In specific embodiments, R is a C10-C15 alkyl
group, and M is alkali
metal, more specifically R is C12-C14 alkyl and M is sodium.
Specific, non-limiting examples of anionic surfactants useful herein include:
a) C11-C18
alkyl benzene sulfonates (LAS); b) C10-C20 primary, branched-chain and random
alkyl sulfates
(AS); c) C10-C18 secondary (2,3)-alkyl sulfates having formulae (I) and (II):
OS03- M OS03- M+
I I
C H3(C H2)x(C H)C H3 or C H3 (C H2)y (C H)C H2C H3
(I) (II)
wherein M in formulae (I) and (II) is hydrogen or a cation which provides
charge neutrality, and
all M units, whether associated with a surfactant or adjunct ingredient, can
either be a hydrogen
atom or a cation depending upon the form isolated by the artisan or the
relative pH of the system
wherein the compound is used, with non-limiting examples of preferred cations
including
sodium, potassium, ammonium, and mixtures thereof, and x is an integer of at
least about 7,
preferably at least about 9, and y is an integer of at least 8, preferably at
least about 9; d) C10-C18
alkyl alkoxy sulfates (AEzS) wherein preferably z is from 1-30; e) C10-C18
alkyl alkoxy
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carboxylates preferably comprising 1-5 ethoxy units; mid-
chain branched alkyl sulfates as
discussed in U.S. Patent Nos. 6,020,303 and 6,060,443; g) mid-chain branched
alkyl alkoxy
sulfates as discussed in U.S. Patent Nos. 6,008,181 and 6,020,303; h) modified
alkylbenzene
sulfonate (MLAS) as discussed in WO 99/05243, WO 99/05242, WO 99/05244, WO
99/05082,
WO 99/05084, WO 99/05241, WO 99/07656, WO 00/23549, and WO 00/23548.; i)
methyl ester
sulfonate (MES); and j) alpha-olefin sulfonate (AOS).
Suitable nonionic surfactants useful herein may comprise any of the
conventional
nonionic surfactant types typically used in liquid detergent products. These
include, for example,
alkoxylated fatty alcohols and amine oxide surfactants. Preferred for use in
the liquid detergent
products herein are those nonionic surfactants which are normally liquid.
Suitable nonionic
surfactants for use herein include the alcohol alkoxylate nonionic
surfactants. Alcohol
alkoxylates are materials which correspond to the general formula: R1(Cm1-
12õ,0)p0H wherein RI
is a C8-C16 alkyl group, m is from 2 to 4, and p ranges from about 2 to 12.
Preferably RI is an
alkyl group which may be primary or secondary and that contains from about 9
to about 15
carbon atoms, more preferably from about 10 to about 14 carbon atoms. In one
embodiment, the
alkoxylated fatty alcohols may also be ethoxylated materials that contain from
about 2 to about
12 ethylene oxide moieties per molecule, more preferably from about 3 to about
10 ethylene
oxide moieties per molecule.
The alkoxylated fatty alcohol materials useful in the liquid detergent
compositions herein
will frequently have a hydrophilic-lipophilic balance (HLB) which ranges from
about 3 to 17.
More preferably, the HLB of this material will range from about 6 to 15, most
preferably from
about 8 to 15. Suitable alkoxylated fatty alcohol nonionic surfactants have
been marketed under
the trade mark NEODOL by the Shell Chemical Company.
Another suitable type of nonionic surfactant useful herein comprises the amine
oxide
surfactants. Amine oxides are materials which are often referred to in the art
as "semi-polair
nonionics. Amine oxides have the formula: R2(E0)f(PO)5(BO)nN(0)(CH2R3)2.qH20.
In this
formula, R2 is a relatively long-chain alkyl moiety which can be saturated or
unsaturated, linear
or branched, and can contain from 8 to 20, preferably from 10 to 16 carbon
atoms, and is more
preferably a C12-C16 primary alkyl. R3 is a short-chain moiety, preferably
selected from
hydrogen, methyl and -CI12OH. When f+g+h is different from 0, EO is
ethyleneoxy, PO is
propyleneneoxy and BO is butyleneoxy. Exemplary amine oxide surfactants may be
illustrated
by C12-C 14 alkyldimethyl amine oxide.
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Non-limiting examples of nonionic surfactants include: a) C12-C18 alkyl
ethoxylates, such
as, NEODOL nonionic surfactants from Shell; b) C6-C12 alkyl phenol
alkoxylates wherein the
alkoxylate units are a mixture of ethyleneoxy and propyleneoxy units; c) C12-
C18 alcohol and C6-
C12 alkyl phenol condensates with ethylene oxide/propylene oxide block
polymers such as
PLURONIC from BASF; d) C14-C22 mid-chain branched alcohols (BA) as discussed
in U.S.
Patent No. 6,150,322; e) C14-C22 mid-chain branched alkyl alkoxylates (BAE2)
wherein z is 1-30,
as discussed in U.S. Patent Nos. 6,153,577; 6,020,303; and 6,093,856; f) alkyl-
polysaccharides as
discussed in U.S. Patent No. 4,565,647; specifically alkylpolyglycosides as
discussed in U.S.
Patent Nos. 4,483,780 and 4,483,779; g) Polyhydroxy fatty acid amides as
discussed in U.S.
Patent No. 5,332,528, WO 92/06162, WO 93/19146, WO 93/19038, and WO 94/09099;
and h)
ether capped poly(oxyalkylated) alcohol surfactants as discussed in U.S.
Patent No. 6,482,994
and WO 01/42408.
Cationic surfactants are known in the art and non-limiting examples of these
include
quaternary ammonium surfactants, which can have up to 26 carbon atoms.
Additional examples
include a) alkoxylate quaternary ammonium CAQA) surfactants as discussed in
U.S. Patent No.
6,136,769; b) dimethyl hydroxyethyl quaternary ammonium as discussed in U.S.
Patent No.
6,004,922; c) polyamine cationic surfactants as discussed in WO 98/35002, WO
98/35003, WO
98/35004, WO 98/35005, and WO 98/35006; d) cationic ester surfactants as
discussed in U.S.
Patents Nos. 4,228,042; 4,239,660; 4,260,529; and 6,022,844; and e) amino
surfactants as
discussed in U.S. Patent No. 6,221,825 and WO 00/47708, such as amido
propyldimethyl amine
CAPA).
Non-limiting examples of zwitterionic surfactants include: derivatives of
secondary and
tertiary amines, derivatives of heterocyclic secondary and tertiary amines, or
derivatives of
quaternary ammonium, quaternary phosphonium or tertiary sulfonium compounds.
See U.S.
Patent No. 3,929,678 at column 19, line 38 through column 22, line 48, for
examples of
zwitterionic surfactants; betaines, including alkyl dimethyl betaine and
cocodimethyl
amidopropyl betaine, C8 to C18 (for example from C12 to C18) amine oxides and
sulfo and
hydroxy betaines, such as N-alkyl-N,N-dimethylammino-l-propane sulfonate where
the alkyl
group can be C8 to C18 and in certain embodiments from Cio to C14.
Non-limiting examples of ampholytic surfactants include: aliphatic derivatives
of
secondary or tertiary amines, or aliphatic derivatives of heterocyclic
secondary and tertiary
amines in which the aliphatic radical can be straight- or branched-chain. One
of the aliphatic
substituents may contain at least about 8 carbon atoms, for example from about
8 to about 18
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carbon atoms, and at least one contains an anionic water-solubilizing group,
e.g. carboxy,
sulfonate, sulfate. See U.S. Patent No. 3,929,678 at column 19, lines 18-35,
for suitable
examples of ampholytic surfactants.
Nonlimiting examples of surfactant systems include the conventional C11-C18
alkyl
benzene sulfonates ("LAS") and primary, branched-chain and random C10-C20
alkyl sulfates
("AS"), the C10-C18 secondary (2,3)-alkyl sulfates of the formula
CH3(CH2)x(CHOS03-1\4+)CH3
and CH3(CH2)y(CHOS03-1\4+)CH2CH3 where x and (y + 1) are integers of at least
about 7, in
other embodiments at least about 9, and M is a water-solubilizing cation,
especially sodium,
unsaturated sulfates such as oleyl sulfate, the C10-C18 alkyl alkoxy sulfates
("AEzS"; especially
EO 1-7 ethoxy sulfates), Cio-C18 alkyl alkoxy carboxylates (especially the EO
1-5
ethoxycarboxylates), the C10-C 18 glycerol ethers, the C10-C18 alkyl
polyglycosides and their
corresponding sulfated polyglycosides, and C12-C18 alpha-sulfonated fatty acid
esters. If desired,
the conventional nonionic and amphoteric surfactants such as the C12-C18 alkyl
ethoxylates
("AE") including the narrow peaked alkyl ethoxylates and C6-C12 alkyl phenol
alkoxylates
(especially ethoxylates and mixed ethoxy/propoxlyates), C12-C18 betaines and
sulfobetaines
("sultaines"), C10-C18 amine oxides, and the like, can also be included in the
surfactant system.
The C10-C18 N-alkyl polyhydroxy fatty acid amides can also be used. See WO
92/06154. Other
sugar-derived surfactants include the N-alkoxy polyhydroxy fatty acid amides,
such as C10-C18
N-(3-methoxypropyl) glucamide. The N-propyl through N-hexyl C12-C18 glucamides
can be
used for low sudsing. C10-C20 conventional soaps may also be used. If high
sudsing is desired,
the branched-chain C10-C16 soaps may be used. Mixtures of anionic and nonionic
surfactants are
especially useful. Other conventional useful surfactants are listed in
standard texts.
Chelant System
The pourable aqueous compositions disclosed herein may include a chelant
system. In
some aspects, the chelant system comprises at least two chelants. At least one
of the chelants is
a strong binder of transition metals and provides for good removal of stains
including, but not
limited to, beverage stains. At least one of the chelants has a low calcium
binding constant,
which further improves beverage stain removal without destabilizing enzymes,
which also be
included in the composition to remove stains across a wide variety of stain
categories. In some
embodiments, the chelant system is a dual chelant system consisting of two
chelating agents. As
used herein the terms "dual chelant systeni' and tombination of chelant'
refers to at least two
chelants having different core molecular structures and does not refer to two
chelants having the
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same core molecular structure, but different associated counterions or being
different ionizable
species of the same base core structure.
The combination of chelants may be chosen by one skilled in the art to provide
for
heavy metal (e.g. Fe) sequestration without negatively impacting enzyme
stability through the
5 excessive binding of calcium ions. Non-limiting examples of chelants of
use in the present
invention are found in USPN 7445644, 7585376 and 2009/0176684A1.
Useful chelants include heavy metal chelating agents, such as
diethylenetriaminepentaacetic acid (DTPA) and/or a catechol including, but not
limited to,
TironTm. In embodiments in which a dual chelant system is used, the chelants
may be DTPA and
10 Tiron.
DTPA has the following core molecular structure:
I -
HO2C NN NCO2H
HO7C C071-1
Tiron, also known as 1,2-diydroxybenzene-3,5-disulfonic acid, is one member of
the
catechol family and has the core molecular structure shown below:
Oh I
OH
I-103S S031-1
Other sulphonated catechols are of use. In addition to the disulfonic acid,
the term"tiroff
may also include mono- or di-sulfonate salts of the acid, such as, for
example, the disodium
sulfonate salt, which shares the same core molecular structure with the
disulfonic acid.
Other chelating agents suitable for use herein can be selected from the group
consisting
of aminocarboxylates, aminophosphonates, polyfunctionally-substituted aromatic
chelating
agents and mixtures thereof. Chelants particularly of use include, but are not
limited to: HEDP
(hydroxyethanedimethylenephosphonic acid); MGDA (methylglycinediacetic acid);
and
mixtures thereof.
Without intending to be bound by theory, it is believed that the benefit of
these materials
is due in part to their exceptional ability to remove heavy metal ions from
washing solutions by
formation of soluble chelates; other benefits include inorganic film or scale
prevention. Other
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suitable chelating agents for use herein are the commercial DEQUESTTm series,
and chelants
from Monsanto, DuPont, and Nalco, Inc.
Aminocarboxylates useful as chelating agents include, but are not limited to,
ethylenediaminetetracetates, N-
(hydroxyethyl)ethylenediaminetriacetates, nitrilotriacetates,
ethylenediamine tetraproprionates, triethylenetetraaminehexacetates,
diethylenetriamine-
pentaacetates, and ethanoldiglycines, alkali metal, ammonium, and substituted
ammonium salts
thereof and mixtures thereof.
Aminophosphonates are also suitable for use as chelating agents in the
compositions of
the invention when at least low levels of total phosphorus are permitted in
detergent
compositions, and include ethylenediaminetetrakis (methylenephosphonates).
Preferably, these
aminophosphonates do not contain alkyl or alkenyl groups with more than about
6 carbon atoms.
Polyfunctionally-substituted aromatic chelating agents are also useful in the
compositions
herein. See U.S. Patent 3,812,044, issued May 21, 1974, to Connor et al.
Preferred compounds
of this type in acid form are dihydroxydisulfobenzenes such as I ,2-dihydroxy-
3,5-
disulfobenzene.
A biodegradable chelator for use herein is ethylenediamine disuccinate
("EDDS"),
especially (but not limited to) the [S,S1 isomer as described in USPN
4,704,233. The trisodium
salt is preferred though other forms, such as magnesium salts, may also be
useful.
The chelant system may be present in the pourable aqueous compositions of the
invention
at from about .2% to about .7% or from about .3% to about .6% by weight of the
detergent
compositions disclosed herein.
Builder
The compositions herein may comprise builder. Builders of use include, but are
not
limited to those materials which serve to counteract the effects of calcium,
magnesium,or other
ion, water hardness encountered during laundering using the compositions
herein. Examples of
such materials include the alkali metal citrates, succinates, malonates,
carboxymethyl succinates,
carboxylates, polycarboxylates and polyacetyl carboxylates. Specific examples
include sodium,
potassium and lithium salts of oxydisuccinic acid, mellitic acid, benzene
polycarboxylic acids,
C10-G22 fatty acids and citric acid. Other examples are organic phosphonate
type sequestering
agents such as those which have been sold by Monsanto under the Dequest trade
mark and
alkanehydroxy phosphonates. Citrate salts and C17-C18 fatty acid soaps are
highly preferred.
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Other suitable organic builders include the higher molecular weight polymers
and
copolymers known to have builder properties. For example, such materials
include appropriate
polyacrylic acid, polymaleic acid, and polyacrylic/polymaleic acid copolymers
and their salts,
such as those sold by BASF under the Sokalan trademark.
If utilized, organic builder materials will generally comprise from 0% to
about 8%, from
about 3% to about 7%, or from about 2% to 6%, by weight of the composition.
Preferred builder is selected from the group of: citric acid; fatty acid; and
mixtures
thereof. In some embodiments, citric acid is the sole builder utilized and is
present in the
compositions at a weight percentage of about 4.5% or less. Without wishing to
be bound by
theory, it is believed that the low citric acid content provides for greater
flexibility in the
formulation of compacted detergents by tying up less water and reducing cost.
In some
embodiments, citric acid is present in the composition at less than 4%, less
than 3%, less than
2% or even less than 1%.
Water
'Water as used herein refers to the total water content in the product, which
may be added
directly as water, or may be added in combination with other components of the
product. For
example, the water can be added within a paste of solution comprising other
product ingredients.
Enzyme
In some embodiments, the pourable aqueous detergent compositions comprise
enzyme.
In some embodiments, the compositions of the present invention include enzymes
from about
0.00001% to about 5%, specifically from about 0.001% to about 2%, more
specifically from
about 0.00001% to about 1%, even more specifically from about 0.001% to about
0.2%, even
more specifically still from about 0.005% to about 0.1%, by weight of the
detergent composition,
of enzyme
It may be preferred for the composition to comprise at least a ternary enzyme
system
selected from protease, amylase, lipase and/or cellulase.
Lipase. Suitable lipases include those of bacterial or fungal origin.
Chemically modified
or protein engineered mutants are included. Non-limiting examples of useful
lipases include
lipases from Humicola (synonym Thermomyces), e.g., from H. lanuginosa (T.
lanuginosus) as
described in EP 258 068 and EP 305 216 or from H. insolens (see WO 96/13580, a
Pseudomonas
lipase, e.g., from P. alcaligenes or P. pseudoalcaligenes (see EP 218 272), P.
cepacia (see EP
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13
331 376), P. stutzeri (see GB 1,372,034), P. fluorescens, Pseudotnonas sp.
strain SD 705 (see
WO 95/06720 and WO 96/27002), P. wisconsinensis (see WO 96/12012), a Bacillus
lipase, e.g.,
from B. subtilis (see Dartois et al. (1993), Biochemica et Biophysica Acta,
1131, 253-360), B.
stearothertnophilus (see JP 64/744992) or B. pumilus (see WO 91/16422).
The lipase may be a "first cycle lipasd' such as those described in U.S.
Patent 6,939,702
and US PA 2009/0217464. In one aspect, the lipase is a first-wash lipase,
preferably a variant of
the wild-type lipase from Thermomyces lanuginosus comprising T231R and N233R
mutations.
The wild-type sequence is the 269 amino acids (amino acids 23-291) of the
Swissprot accession
number Swiss-Prot 059952 (derived from Thermomyces lanuginosus (Humicola
lanuginosa)).
Preferred lipases would include those sold under the trade marks Lipex ,
Lipolex and
Lipoclean by Novozymes, Bagsvaerd, Denmark.
In some embodiments, the composition comprises a variant of Thermomyces
lanuginosa
lipase having >90% identity with the wild type amino acid and comprising
substitution(s) at
T231 and/or N233, preferably T231R and/or N233R (herein:"first wash lipasd').
Protease. Suitable proteases include metalloproteases and/or serine proteases,
including
neutral or alkaline microbial serine proteases, such as subtilisins (see EC
3.4.21.62). Suitable
proteases include those of animal, vegetable or microbial origin. In one
aspect, such suitable
protease may be of microbial origin. The suitable proteases include chemically
or genetically
modified mutants of the aforementioned suitable proteases. In one aspect, the
suitable protease
may be a serine protease, such as an alkaline microbial protease or/and a
trypsin-type protease.
Non-limiting examples of suitable neutral or alkaline proteases include:
(a) subtilisins (EC 3.4.21.62), including those derived from Bacillus, such as
Bacillus lentus, B.
alkalophilus, B. subtilis, B. amyloliquefaciens, Bacillus pumilus and Bacillus
gibsonii described
in US 6,312,936, US 5,679,630, US 4,760,025, US 7,262,042 and W009/021867.
(b) trypsin-type or chymotrypsin-type proteases, such as trypsin (e.g., of
porcine or bovine
origin), including the Fusarium protease described in WO 89/06270 and the
chymotrypsin
proteases derived from Cellumonas described in WO 05/052161 and WO 05/052146.
(c) metalloproteases, including those derived from Bacillus amyloliquefaciens
described in WO
07/044993.
Preferred proteases include those derived from Bacillus gibsonii or Bacillus
Lentus.
Suitable commercially available protease enzymes include those sold under the
trade
marks Alcalase0, Savinase , Primase0, DurazymO, Polarzyme0, Kannase ,
Liquanase ,
Liquanase Ultra , Savinase Ultra , Ovozyme , Neutrase , Everlase and
Esperase0 by
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14
Novozymes A/S (Denmark), those sold under the trade marks Maxatase , Maxacal ,
Maxapem , Properase , Purafect , Purafect Prime , Purafect Ox , FN3 , FN4@,
Excellase and Purafect OXPO by Genencor International, those sold under the
trade marks
Opticlean and Optimase by Solvay Enzymes, those available from Henkel/
Kemira, namely
BLAP (sequence shown in Figure 29 of US 5,352,604 with the folowing mutations
S99D + S101
+ S103A + V1041 + G159S, hereinafter referred to as BLAP), BLAP R (BLAP with
S3T +
V4I + V199M + V2051 + L217D), BLAP X (BLAP with S3T + V4I + V2051) and BLAP
F49
(BLAP with S3T + V4I + A194P + V199M + V2051 + L217D) - all from
Henkel/Kemira; and
KAP (Bacillus alkalophilus subtilisin with mutations A230V + S256G + S259N)
from Kao.
In some embodiments, the composition comprises a subtilisin protease selected
from
BLAP, BLAP R, BLAP X or BLAP F49.
Cellulase. Suitable cellulases include those of bacterial or fungal origin.
Chemically
modified or protein engineered mutants are included. Suitable cellulases
include cellulases from
the genera Bacillus, Pseudomonas, Humicola, Fusariwn, Thielavia, Acremonium,
e.g., the fungal
cellulases produced from Humicola insolens, Myceliophthora thermophila and
Fusaritun
oxy,sporum disclosed in US 4,435,307, US 5,648,263, US 5,691,178, US 5,776,757
and WO
89/09259.
In one aspect, the cellulase can include microbial-derived endoglucanases
exhibiting
endo-beta-1,4-glucanase activity (E.C. 3.2.1.4), including a bacterial
polypeptide endogenous to
a member of the genus Bacillus which has a sequence of at least 90%, 94%, 97%
and even 99%
identity to the amino acid sequence SEQ ID NO:2 in US 7,141,403 and mixtures
thereof. A
suitable endoglucanases is sold under the trade mark Celluclearg1D (Novozymes
A/S, Bagsvaerd,
Denmark). Further suitable endoglucanases are variants of the XYG1006 enzyme
described in
US 7,361,736 (Novozymes). A suitable endoglucanase is sold under the trade
mark Whitezyme
(Novozymes A/S, Bagsvaerd, Denmark).
In some embodiments, the composition comprises a cleaning cellulase belonging
to
Glycosyl Hydrolase family 45 having a molecular weight of from 17kDa to 30
kDa, for example
the endoglucanases sold under the trade mark Biotouch NCD, DCC and DCL (AB
Enzymes
Darmstadt, Germany).
Amylase. Preferably, the composition comprises an amylase with greater than
60%
identity to the AA560 alpha amylase endogenous to Bacillus sp. DSM 12649,
preferably a
variant of the AA560 alpha amylase endogenous to Bacillus sp. DSM 12649
having:
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(a) mutations at one or more of positions 9, 26, 149. 182, 186, 202, 257, 295,
299, 323, 339 and
345; and (h) optionally with one or more, preferably all of the substitutions
and/or deletions in
the following positions: 118, 183, 184, 195, 320 and 458, which if present
preferably comprise
R118K, D183*, G184*, N195F, R320K and/or R458K.
5 Suitable
commercially available amylase enzymes include Stainzyme Plus,
Stainzyme , NatalaseTM, Termamyle, Termamyl Ultra, Liquezyme SZ (all
Novozymes,
Bagsvaerd, Denmark) and Spezymee AA or UltraphlowTM (Genencor, Palo Alto,
USA).
Choline oxidase. The composition may comprise a choline oxidase enzyme such as
the
59.1 kDa choline oxidase enzyme endogenous to Arthrobacter nicotianae,
produced using the
10 techniques
disclosed in D. Ribitsch et al., Applied Microbiology and Biotechnology,
Volume 81,
Number 5, pp875-886, (2009).
Other enzymes. Other suitable enzymes are peroxidases/oxidases, which include
those of
plant, bacterial or fungal origin. Chemically modified or protein engineered
mutants are included.
Examples of useful peroxidases include peroxidases from Coprinus, e.g., from
C. cinereus, and
15 variants thereof as those described in WO 93/24618, WO 95/10602, and WO
98/15257.
Commercially available peroxidases include GUARDZYME (Novozymes A/S).
Other preferred enzymes include: pectate lyases sold under the trade marks
Pectawash ,
Pectaway0; mannanases sold under the trade marks Mannaway (all from Novozymes
A/S,
Bagsvaerd, Denmark), and Purabrite (Genencor International Inc., Palo Alto,
California);
cutinases; laccases; phospholipases; lysophospholipases; acyltransferase;
perhydrolase;
arylesterase and any mixture thereof.
Other Ingredients
Hueing Dye
In some embodiments, the pourable aqueous detergent composition comprises
hueing
dye. Any suitable hueing dye may be of use. Non-limiting examples of useful
hueing dyes
include those found in USPN: US 7,205,269; US 7,208,459; and US 7,674,757 B2.
For
example, hueing dye may be selected from the group of: triarylmethane blue and
violet basic
dyes, inethine blue and violet basic dyes, anthraquinone blue and violet basic
dyes, azo dyes
basic blue 16, basic blue 65, basic blue 66 basic blue 67, basic blue 71,
basic blue 159, basic
violet 19, basic violet 35, basic violet 38, basic violet 48, oxazine dyes,
basic blue 3, basic blue
75, basic blue 95, basic blue 122, basic blue 124, basic blue 141, Nile blue A
and xanthene dye
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basic violet 10, an alkoxylated triphenylmethane polymeric colorant; an
alkoxylated thiopene
polymeric colorant; thiazolium dye; and mixtures thereof.
Preferred hueing dyes include the whitening agents found in WO 08/87497 Al.
These
whitening agents may be characterized by the following structure (I):
H3c //N
/ \ H
...----
N N H
---- \\
S
N Ri
. N(
H3C
R2
H
(I)
Wherein R1 and R2 can independently be selected from:
a) RCH2CR'HO)x(CH2CR"HO)y111
wherein k is selected from the group consisting of H, CH3, CH20(CH2CH20)zH,
and
mixtures thereof; wherein R' is selected from the group consisting of H,
CH20(CH2CH20)zH, and mixtures thereof; wherein x + y < 5; wherein y > 1; and
wherein z = 0 to 5;
b) R1 = alkyl, aryl or aryl alkyl and R2 = RCH2CR'HO)x(CH2CR"HO)y1-11
wherein k is selected from the group consisting of H, CH3, CH20(CH2CH20)zH,
and
mixtures thereof; wherein R' is selected from the group consisting of H,
CH20(CH2CH20)zH, and mixtures thereof; wherein x + y < 10; wherein y > 1; and
wherein z = 0 to 5;
c) R1 = [CH2CH2(0R3)CH2OR41 and R2 = [CH2CH2(0 R3)CH20 Rd
wherein R3 is selected from the group consisting of H, (CH2CH20)zH, and
mixtures
thereof; and wherein z = 0 to 10;
wherein R4 is selected from the group consisting of (Ci-C16)alkyl , aryl
groups, and
mixtures thereof; and
d) wherein R1 and R2 can independently be selected from the amino addition
product of
styrene oxide, glycidyl methyl ether, isobutyl glycidyl ether,
isopropylglycidyl ether, t-
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17
butyl glycidyl ether, 2-ethylhexylgycidyl ether, and glycidylhexadecyl ether,
followed by
the addition of from 1 to 10 alkylene oxide units.
A preferred whitening agent of the present invention may be characterized by
the
following structure (II):
CH3
N H
N 411
NRCH2CWHO)x(CH2CR"HO)y1112
CH3
(II)
wherein k is selected from the group consisting of H, CH3, CH20(CH2CH20)zH,
and mixtures
thereof; wherein R' is selected from the group consisting of H,
CH20(CH2CH20)zH, and mixtures
thereof; wherein x + y < 5; wherein y? 1; and wherein z = 0 to 5.
A further preferred whitening agent of the present invention may be
characterized by the
following structure (III):
H3C CN
(CH2CF120)x(CH2CH21AH
NC =N
(CH2CH214(CH2CH2o)1H
I-13C (III)
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18
In some aspects, the whitening agent characterized by structure III is a
mixture having a
total of 5 EO groups. This structure is arrived at by the following selection
in Structure I of the
following pendant groups in'llart a' above:
R1 R2
R' R" x y R' R" x Y
a H H 3 1 H H 0 1
b H H 2 1 H H 1 1
c=b H H 1 1 H H 2 1
d=a H H 0 1 H H 3 1
Further whitening agents of use include those described in USPN 2008 34511 Al
(Unilever). A preferred agent is"Violet 13'as pictured on p. 4 of this
publication.
Structurant
In some embodiments of the present invention, the liquid laundry detergent
compositions
further comprise structurant. Structurants of use include those disclosed
in USPN
2006/0205631A1, 2005/0203213A1, 7294611, 6855680. US 6855680 defines suitable
hydroxyfunctional crystalline materials in detail. Preferred is hydrogenated
castor oil. Non-
limiting examples of useful structurants include those selected from the group
of: hydrogenated
castor oil; derivatives of hydrogenated castor oil; microfibrillar cellulose;
hydroxyfunctional
crystalline materials, long-chain fatty alcohols, 12-hydroxystearic acid;
clays; and mixtures
thereof. In some embodiments, Alternately, low molecular weight organogellants
can be used.
Such materials are defined in: Molecular Gels, Materials with Self-Assembled
Fibrillar
Networks, Edited by Richard G. Weiss and Pierre Terech.
Pearlescent Agent
In some embodiments of the present invention, the liquid laundry detergent
compositions
further comprise pearlescent agent. Pearlescent agents of use include those
described in USPN
2008/0234165A1. Non-limiting examples of pearlescent agents may be selected
from the group
of: mica; titanium dioxide coated mica; bismuth oxychloride; fish scales; mono
and diesters of
alkylene glycol of the formula:
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19
0
II -0 P
RIVC1 -R-r
J n
wherein:
a. R1 is linear or branched C12-C22 alkyl group;
b. R is linear or branched C2-C4 alkylene group;
c. P is selected from the group of: H; C1-C4 alkyl; or ¨COR2; and
d. n = 1-3.
In some embodiments, R2 is equal to R1, such that the alkylene glycol is
ethyleneglycoldistearate (EGDS).
Stains
The product of the present invention provides for effective removal of a
variety of stains.
Non-limiting examples of stains include: greasy stains (included saturated
and/or unsaturated);
outdoor stains;; red stains; beverage stains; blood; food stains; and mixtures
thereof. Non-
limiting examples of saturated greasy stains include taco grease, bacon grease
and hamburger
grease. Non-limiting examples of unsaturated stains include olive oil, canola
oil, margarine and
Italian dressing. Non-limiting examples of outdoor stains include grass and
clays (organic
and/or inorganic). Non-limiting examples of red stains include ketchup and
tomato sauce. Non-
limiting examples of beverage stains include grape juice, wine, soda and
CoolaidTM. Further
non-limiting examples of stains include cosmetics, blood, chocolate, gravy and
fruit stains.
Cap
Figure 1 illustrates an embodiment of a cap 10 for dispensing a detergent
composition
300 that can be used to pre-treat stains. The cap 10 comprises a base 20. The
base 20 has a base
interior 30 and a base exterior 40 opposing the base interior 30. The base
interior 30 has a
periphery 50. The base 20 can be a single layer of material, such as high
density polyethylene
or polypropylene, a multilayered material, a hollow member, or any other such
structure or
material having sufficient structural integrity to be used in a cap 10 for a
container 110 of
laundry detergent composition 300. The base exterior 40 can provide a surface
arrangement that
can be stably set upon another surface that is substantially flat as measured
on a scale of
centimeters, such as a table or a flat portion of a washing machine or dryer.
Such surface
arrangement can be a generally flat surface or contoured surface arrangement.
When the base
20 is set on a flat surface, detergent composition 300 from a container 110
can be poured into
CA 02798745 2013-11-19
the pour volume 100 of the cap 10 and the cap 10 will not easily tip over as
detergent
composition 300 is poured into the pour volume 100.
A vessel wall 60 extends from the periphery 50 to a rim 90. The vessel wall 60
extends
about the longitudinal axis L of the cap. The vessel wall 60 has an interior
surface 70 and an
5 exterior
surface 80 opposing the interior surface 70. The vessel wall 60 can be a
single layer of
material, such as high density polyethylene or polypropylene, a multilayered
material, a hollow
member, or any other such structure or material having sufficient structural
integrity to be used
as a cap 10 for a container of laundry detergent composition 300. The interior
surface 70 can be
provided with one or more indicia 62 that mark the desired level of detergent
composition 300
10 that
provides for an appropriate unit dose of detergent composition 300. The
indicia 62 can be
an etch, a depression, a raised portion, printing, or any other structure that
is observable by the
consumer. The vessel wall 60 can be a cylindrical segment.
The interior surface 70 and base interior 30 together define a pour volume
100, the base
interior 30 forming a closed end of the pour volume 100. The pour volume 100
can be sized and
15 dimensioned
to provide for a unit dose of a detergent composition 300. The detergent
composition 300 can be a liquid detergent composition 300 such as any of the
liquid detergents
marketed as TIDETm, available from The Procter & Gamble Co., Cincinnati, OH,
USA. In one
embodiment, the interior surface 70 and base interior 30 together form an open
ended, or
partially open ended, cup with the base interior 30 forming the closed end of
the cup. The
20 longitudinal
axis L can extend through the open portion of the open end of the cap 10
defined by
or partially by the rim 90.
The interior surface 70 of the vessel wall 60 can be defined by a surface of
revolution
about the longitudinal axis L. In one embodiment, interior surface 70 of the
vessel wall 60 can
be defined by a portion of the interior surface of a hollow cylinder. Surfaces
of revolutions of
functions not parallel to the longitudinal axis L and surfaces of revolution
of non-linear
functions are contemplated. A cap 10 having an interior surface 70 of vessel
wall 60 that is a
surface of revolution can provide for ease of manufacture of the cap 10 and
engaging the cap 10
with the container 110 after filling the container 110 with detergent
composition 300 during
manufacture and packaging.
The cap 10 can be sealingly engaged to a container 110 containing a detergent
composition 300. By sealingly engaged, it is meant that the cap 10 does not
leak an
unacceptable quantity of detergent composition 300 from the container under
stresses to the cap
10 and container 110 that occur during manufacturing, packaging, shipping,
handling, storage,
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21
and use of the container 110 and detergent composition 300 stored therein. The
cap 10 can be
sealingly engaged to the container by a connector 130 disposed on the cap 10
and a
corresponding receiver 132 disposed on an opening 112 of the container. The
connector 130
and corresponding receiver 132 can be a lug and groove combination, the
combination being
arranged such the lug can be the connector 130 or the receiver 132 and the
groove being
whichever of the connector 130 and receiver 132 that the lug is not. The
connector 130 and
receiver 132 can be interlocking correspondingly disposed threads 134
helically disposed on the
cap 10 and container 110. That is, the connector 130 can be threads and the
receiver 132 can be
corresponding threads. The cap 10 can be sealingly engaged to the container by
threads 134
helically disposed on the cap 10 and corresponding disposed threads 134 on the
opening 112 of
the container 110. The cap 10 can be provided with a connector 130 at any
suitable location
such that the connector 130 can be operatively engaged with the receiver 132
on the container
110. The connector 130 can be disposed on the exterior surface 80 of the
vessel wall 60. The
connector 130 can be disposed on the interior surface 70 of the vessel wall
60. The cap 10 can
be provided with threads 134 in any suitable location such that the threads
134 can be
operatively engaged with the container 110. The threads 134 can be disposed on
the exterior
surface 80 of the vessel wall 60. The threads 134 can be disposed on the
interior surface 70 of
the vessel wall 60, which can provide for cleaner use of the cap 10. The cap
10 can be
releasably attachable to a container 110 by a pressure fitting and detachable
there from.
As shown in FIG. 1, the rim 90 can have a weir 160. A weir 160 can provide for
more
precise delivery of detergent composition 300 to a stain in a fabric by
constricting the flow of
detergent composition 300 from the cap 10 as a small quantity of detergent
composition 300 is
applied to the stain. The weir 160 can be any of the common shapes for weirs
including a V
shape, a semicircular shape, a trapezoidal shape, a multilevel weir having
discontinuous function
describing the hydraulic radius, or any other such shape that can constrict
flow of detergent
composition 300.
The cap 10 can comprise a plurality of first surface irregularities 150 at a
location
selected from the group consisting of on the rim 90, on the exterior surface
80 between the
connector 130 and the rim 90, and combinations thereof. For instance, as shown
in FIG. 1, the
first surface irregularities 150 are illustrated as being on the rim 90 and
between the connector
130 and the rim 90. The first surface irregularities 150 can be on the rim 90.
The first surface
irregularities 150 can be within about 5 mm of the rim 90. The first surface
irregularities 150
can be on or within about 5 mm of the rim 90. The first surface irregularities
150 can be on the
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rim 90 and between the connector 130 disposed on the cap 10 and the rim 90.
When the
consumer grips the cap 10 to execute pouring, once the pour is made, first
surface irregularities
150 located as such are in position to be used to scrub the stain on the
fabric with the first
surface irregularities 150 without requiring the consumer to reposition the
cap in her hand.
Further, by placing the first surface irregularities 150 as such, after using
the cap 10 to pre-treat
and dose the detergent composition 300, the first surface irregularities 150,
which might have a
small amount of detergent composition 300 remaining thereon, can fit back
within the opening
112 of the container 110 to keep any mess inside the container 110.
First surface irregularities 150 can provide a topographically diverse surface
that can be
rubbed against a stained fabric before or after detergent composition 300 is
applied to a stain in
a fabric as part of a stain pretreatment process. A topographically diverse
surface is a surface
that is not smooth. The first surface irregularities 150 when rubbed against a
stain on a fabric
are thought to help dislodge agglomerations of the stain, deform the fibrous
structure of the
fabric allowing the detergent composition 300 to more completely penetrate the
fibrous
structure, and manipulate the fibers of the fabric thereby allowing a greater
surface area of the
fibers to be wetted with the detergent composition 300. Without being bound by
theory, it is
believed that dislodging agglomerations of the stain, more completely
penetrating the stained
fabric with detergent composition 300, and applying detergent composition 300
to a greater
surface area of fibers can improve the efficacy of pre-treatment of stains in
fabrics.
The plurality of first surface irregularities 150 can have a surface
topography that is
distinct from the surface topography of portions of the cap 10 adjacent the
plurality of first
surface irregularities 150. The first surface irregularities 150 can provide
for a surface having a
plurality of peaks and a plurality of low portions that have an amplitude
between adjacent peaks
and low portions greater than about 0.1 mm. The first surface irregularities
150 can provide for
a surface having a plurality of peaks and a plurality of low portions that
have an amplitude
between adjacent peaks and low portions greater than about 0.2 mm. The first
surface
irregularities 150 can provide for a surface having a plurality of peaks and a
plurality of low
portions that have an amplitude between adjacent peaks and low portions
greater than about 0.5
mm. The first surface irregularities 150 can provide for a surface having a
plurality of peaks
and a plurality of low portions that have an amplitude between adjacent peaks
and low portions
greater than about 1 mm. The low portions can be valleys. The plurality of
first surface
irregularities 150 can define a region that has a surface topography that
differs from the surface
topography of portions of the cap 10 adjacent the region. The first surface
irregularities 150 can
CA 02798745 2013-11-19
23
be a series of elevated portions having intermittently disposed recessed
portions. Recessed
portions can be continuous. Elevated portions can be continuous.
The rim 90 can have a weir 160 that is generally aligned with the first
surface
irregularities 150. In such an embodiment, by generally aligned it is meant
that the weir 160 and
first surface irregularities 150 are at least within about 0.257c radians of
one another about the
longitudinal axis L. For instance, as shown in FIG. 1, the weir 160 can be
aligned with the first
surface irregularities 150. Such an embodiment can be practical because as the
user of the cap
dispenses the detergent composition 300 over the weir 160 to pre-treat the
stain, the
consumer will be holding the cap 10 in a position such that the user does not
have to reposition
10 her hand to rub the first surface irregularities 150 against the stain.
Further, as the consumer
observes the pour, she is likely to see the first surface irregularities 150,
which will provide her
with a visual cue to use the first surface irregularities 150 to scrub the
stain.
Further, with the first surface irregularities 150 positioned as such, the
user is able to see
the first surface irregularities 150 when pouring of a unit dose is initiated.
This can be practical
as a reminder to the consumer to pre-treat stains if she sees the surface
irregularities 150 as she
pours the unit dose into the wash basin prior to pre-treating stains.
In one embodiment, the first surface irregularities 150 can comprise a first
material and
another portion of the cap 10 next to the first material can comprise a second
material, wherein
the first material and the second material differ from one another. In one
embodiment, the first
surface irregularities 150 can comprise a first material and another portion
of the cap 10 next to
the first material can comprise a second material, wherein the first material
and the second
material differ from one another by a property selected from the group
consisting of modulus of
elasticity, chemical composition, Shore A hardness, color, and combinations
thereof. Shore A
Hardness is measured following ASTM D2240 on a material of the same
composition as the
material being evaluated. A cap 10 comprising first surface irregularities 150
comprised of a
first material and another portion of the cap 10 next to the first material
comprising a second
material can be formed by a two shot injection molding process, with the first
material and the
second material delivered to the mold in separate shots. In one embodiment,
the first material
can comprise polypropylene, rubber, neoprene, and/or KRATONTm. In one
embodiment, the
portion of the cap 10 next to the first material can be high density
polyethylene, polypropylene,
polyamide, styro lacrylintrol. The first surface irregularities can be a
elastomeric material.
In one embodiment the first material can have a softer feel to the user than
the second
material, as might be indicated by a lower Shore A hardness or lower modulus
of elasticity. The
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second material can be selected to provide for acceptable overall structural
stability of the cap
during packaging, storing, shipping, and display of the detergent composition
300 and during
use of the cap 10 by the consumer to pre-treat stains. A more readily
deformable first material
might provide for scrubbing surface that is gentler on the fabric being
treated than a scrubbing
surface formed of the second material and may not damage the fabric being
treated. The first
material can have a Shore A hardness between about 20 and about 80. The first
material can
have a Shore A hardness of between about 40 and about 60. The first material
can have a Shore
A hardness that is less than about 80%f the Shore A hardness of a portion of
the cap 10 next to
the first material.
Providing the first material and the second material in two different colors
can help the
consumer quickly identify what part of the cap 10 is engineered to be used for
scrubbing the
stain and might be helpful to vision systems that might be used to position
the cap 10 during
manufacture and/or assembly of the cap and packaging of the detergent
composition 300.
Providing the first material and the second material to have different
chemical composition can
yield a cap 10 for which different parts of the cap 10 are designed to provide
for different
functions, such as one part of the cap being practical and durable for
scrubbing and another part
of the cap 10 providing for structural stability.
To provide for a potentially cleaner stain pretreatment process, the cap 10
can be
provided with a collector 250 that at least partially surrounds the exterior
surface 80 of the
vessel wall 60, an example of which is shown in FIG. 1. The collector 250 can
at least partially
circumscribe or circumscribe the exterior surface of the vessel wall 60. The
collector 250 can
provide for retaining a volume of detergent composition 300 that might drip
from the rim 90 or
aperture when the detergent composition 300 is dispensed from the cap 10. A
portion of the
collector 250 can be spaced apart from the exterior surface 80 of the vessel
wall 60. The
retaining volume defined by the space in the collector 250 and the exterior
surface 80 can be
disposed along the hydraulic pathway of flow for detergent composition 300
between the rim
90, weir 160, or aperture, and the connector 130 disposed on the cap 10. The
collector 250 can
help keep the connector 130 free of detergent composition 300 thereby reducing
the probability
that the consumer may come into physical contact with the detergent
composition 300. The
collector 250 can be sized and dimensioned to fit in the opening 112 of the
container 110 so that
detergent composition 300 caught in the collector drips back into the
container 110 when the cap
10 is reaffixed to the container 110 after use as a pre-treatment device.
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The plurality of first surface irregularities 150 can be structures selected
from the group
consisting of rings, ribs 152, nubs, bristles, fibers, and combinations
thereof. Ribs are a plurality
of elongated elevated portions with inteimittently disposed elongated recessed
portions that are
depressed relative to the elevated portions. Ribs 152 can be, for example, a
plurality of adjacent
5 grooves etched or molded in substrate and can be a plurality of adjacent
ridges. Ribs can be
formed in a substrate, for example, by etching a plurality of adjacent grooves
in the substrate, by
molding the substrate to leave behind a plurality of adjacent grooves, and by
molding the
substrate to leave behind a plurality of adjacent ridges. An example of a
substrate that can form
a portion of cap 10 having first surface irregularities 150 and/or second
surface irregularities
10 having a plurality of ribs 152 is schematically illustrated in FIG. 2.
Ribs 152 can have any
desired cross sectional shape including straight edged and rounded. Ribs 152
can be curved
along their length. Ribs 152 are thought to provide for a bumpy topography
that can effectively
scrub and massage the fabric.
Nubs 154 are generally two-dimensionally symmetric features that are elevated
or
15 depressed relative to adjacent portions, an example schematic of which
is shown in FIG. 3.
Nubs can be, by way of non-limiting examples, elevated portions or depressed
portions having a
shape of a portion of a hemisphere and elevated portions or depressed portions
having a shape of
a cylinder having a height H less than half the diameter D. An example of a
substrate that can
form a portion of cap 10 having first surface irregularities 150 and/or second
surface
20 irregularities 155 having a plurality of nubs 154 is schematically
illustrated in FIG. 3. Nubs 154
are thought to provide for a bumpy topography that can effectively scrub and
massage the
fabric.
An example of a portion of cap 10 having a plurality of bristles 156 is
schematically
illustrated in FIG. 4. Bristles 156 are filaments having an aspect ratio of
height H to diameter D
25 greater than about 0.5. The diameter D is deteimined at the base of the
bristle which is the
location from which the bristle 156 extends from the cap 10. The height H of
the bristle 156 is
measured orthogonal to the surface from which the base of the bristle 156
extends with the
bristle 156 extended orthogonally from the surface from which the base of the
bristle 156
extends. Bristles 156 can have a self sustaining shape when extended from the
surface from
which the base of the bristle 156 extends. For bristles 156 having a non-
cylindrical cross section,
the diameter D is taken to be the diameter of a cylinder having the same cross-
sectional area as
the cross-section area of the bristle 156 at the location from which the
bristle 156 extends from
the cap 10. The filaments can be discrete filaments. Bristles 156 can be
filaments having an
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aspect ratio of height H to diameter D greater than about 1. Bristles 156 can
be filaments having
an aspect ratio of height H to diameter D greater than about 0.5. Bristles 156
can be generally
columnar bristles 156. Bristles 156 are thought to provide for a rough
texture/topography that
can effectively scrub and massage the fabric. Bristles 156 can be hollow.
Bristles 156 can have
a fixed end 256 and a free end 257. Bristles 156 can have a height from about
1 mm to about 10
mm. Bristles 156 can have a height from about 3 mm to about 7 mm. Bristles 156
can have a
height less than about 7 mm.
Rings 158 are closed shapes in which the central portion 159 of the shape is
recessed
relative to a peripheral portion 161 of the shape, schematic examples of which
are shown n FIG.
5. Rings 158 are thought to be practical in that they provide for a bumpy
topography that can
effectively scrub and massage the fabric. Rings can have a height between
about 0.5 mm to
about 3 mm. Rings can have a height less than about 2 mm. Rings can have a
height of about
1.5 mm.
Fibers can be woven, nonwoven, hooked, or looped fibers, for example, and be
provided
for instance by a woven or nonwoven fibrous web being attached to the cap 10
in the desired
location. An inexpensive and easily manufactured embodiment of cap 10 can be
made by using
fibers as the first surface irregularities 150.
A cap 10 providing for enhanced restrictive pouring of small volumes of
detergent
composition 300 is also contemplated. For instance, the cap 10 may be provided
with a pouring
ledge 210 having an aperture 220 there through extending from the vessel wall
60 or rim 90, an
example of which is shown in FIG. 6. The aperture 220 can provide for a
discrete and precise
pour.
The aperture 220 can be generally aligned with the first surface
irregularities 150. In
such an embodiment, by generally aligned it is meant that the aperture 220 and
first surface
irregularities are at least within about 0.257c radians of one another about
the longitudinal axis L.
As illustrated in FIG. 6, the pouring ledge 210 can extend from the vessel
wall 60 or rim
90 back towards the longitudinal axis L. When the cap 10 is slightly tipped to
initiate pouring a
small volume of detergent composition 300 onto the stained fabric, the pouring
ledge 210 can
help the consumer limit the amount of detergent composition 300 applied to the
stained fabric
by allowing the detergent composition 300 to be dispensed from the cap 10
through the aperture
220. Once the proper amount of detergent composition 300 is applied to the
stained fabric, the
detergent composition 300 remaining in the cap 10 can be dosed to the washing
machine by
further tipping the cap 10 over the washing machine and allowing the detergent
composition 300
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to be completely poured from the cap 10. For added convenience, the aperture
220 can be
generally aligned with the first surface irregularities 150 so that the user
doses not have to
reposition the cap 10 in her hand to initiate scrubbing of the stained fabric
with the first surface
irregularities 150.
In another alternative arrangement as illustrated in FIG. 7, the pouring ledge
210 can
extend from the vessel wall 60 or rim 90 and an aperture 220 is in the vessel
wall 60 between
the pouring ledge 210 and the base 20 and the aperture 220 is generally
aligned with the first
surface irregularities 150. In such an embodiment, by generally aligned it is
meant that the
aperture 220 and first surface irregularities 150 are at least within about
0.257c radians of one
another about the longitudinal axis L.
The pouring ledge 210 can be sized, dimensioned, and arranged to provide for a
restriction of flow of detergent composition 300 when a small pour of
detergent composition
300 is being made by the consumer. A portion of the pouring ledge 210 can
extend back from
the vessel wall 60 or rim 90 towards the longitudinal axis L and be in a plane
orthogonal to the
longitudinal axis L. A portion of the pouring ledge 210 can extend back from
the vessel wall 60
or rim 90 in a plane within about plus or minus 0.57c radians of being
orthogonal to the
longitudinal axis L. A portion of the pouring ledge 210 may further extend
downwards in the
pour volume 100 towards the base interior 30. Such a design might provide for
improved
control of the quantity of detergent composition 300 delivered to the stain
during pre-treatment.
Embodiments in which the cap comprises a plurality of second surface
irregularities 155
on the outside of the cap 10 such that the connecter 130 is between the rim 90
and the second
surface irregularities 155 are also contemplated, as shown in FIG. 8. The cap
10 can have
second surface irregularities 155 and not have first surface irregularities
150. The scrubbing
surface of the cap can be provided on the outside of the cap such that the
connecter 130 is
between the rim 90 and the second surface irregularities 155 and possibly not
be provided
elsewhere on the cap. The cap 10 can comprise a plurality of second surface
irregularities 155
at a location selected from the group consisting of on a portion of the base
exterior 40, on a
portion of the exterior surface 80, and combinations thereof.
The cap 10 can comprise a plurality of second surface irregularities 155 at a
location
selected from the group consisting of on said base exterior 40 with said
second surface
irregularities 155 being asymmetrically disposed about the longitudinal axis
L, on the exterior
surface 80 with the second surface irregularities 155 being asymmetrically
disposed about the
longitudinal axis L, on the base exterior 40 with the second surface
irregularities 155 comprising
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bristles 156, on the exterior surface 80 with the second surface
irregularities 155 comprising
bristles 156, and combinations thereof. In such embodiments, the second
surface irregularities
155 can be disposed such that the connector 130 is between the rim 90 and the
second surface
irregularities 155. Second surface irregularities 155 can be any of the
structures described above
with respect to first surface irregularities 150. The second surface
irregularities 155 can be
structures selected from the group consisting of rings 158, ribs 152, nubs
154, bristles 156,
fibers, and combinations thereof.
By placing the second surface irregularities 155 as such, the second surface
irregularities
can be located such that after the consumer dispenses a small volume of
detergent composition
300 to pre-treat a stain, the second surface irregularities 155 are located
such the that user does
not have to reposition the cap 10 in her hand or significantly move her hand
to be able to
position the second surface irregularities 155 in an appropriate position to
be rubbed against the
stain.
The second surface irregularities 155 can comprise a first material and
another portion of
the cap 10 next to the first material can comprise a second material, wherein
the first material
and the second material differ from one another by a property selected from
the group consisting
of modulus of elasticity, chemical composition, color, Shore A hardness, and
combinations
thereof. Such an arrangement can be provided in the same manner and for the
same reasons as
described above for a cap 10 in which the first surface irregularities 155 are
formed from a
different material than another portion of the cap 10.
Embodiments in which the second surface irregularities 155 are asymmetrically
disposed
about the longitudinal axis L can help the consumer identify what portion of
the cap 10 is
provided for scrubbing the stain during pre-treatment. By asymmetrically
disposed, it is meant
that such asymmetrically disposed second surface irregularities 155 are
disposed such that the
second surface irregularities 155 on the exterior surface 80 or base exterior
40 are not balanced
about a single location, such as a point on the longitudinal axis L or other
point. The cap can 10
can comprise a plurality of gripping irregularities 260 on the exterior
surface 80 and/or base
exterior 40 and the gripping irregularities 260 can be uniformly distributed
about a location to
provide structures that help the consumer grip the cap when removing the cap
10 from the
container 110. The gripping irregularities 260 may be symmetrically
distributed on the exterior
surface 80 and/or base exterior 40 about a location so as to have one-fold
symmetry, for
example a fold passing through a point on the longitudinal axis L.
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The second surface irregularities 155 can be comprised of a first material and
the
gripping irregularities 260 can be comprised of a second material, wherein the
first material
differs from the second material by a property selected from the group
consisting of modulus of
elasticity, chemical composition, color, Shore A hardness, and combinations
thereof. Such an
arrangement can help the user identify the portion of the cap 10 that is
designed to be used as a
scrubbing implement.
The cap 10 can be a cap 10 wherein a pouring ledge 210 having an aperture 220
there
through extends from the vessel wall 60 or rim 90 and the aperture 220 is
generally aligned with
the second surface irregularities 155 or wherein a pouring ledge 210 extends
from the vessel
wall 60 or rim 90 and an aperture 220 is in the vessel wall 60 between the
pouring ledge 210 and
the base 20 and the aperture 220 is generally aligned with the second surface
irregularities 155.
An illustration of aspects of such an embodiment is shown in FIG. 8.
As shown in FIG. 9, the rim 90 can have a weir 160 and the weir 160 can be
generally
aligned with the second surface irregularities 155. In such an embodiment, by
generally aligned
it is meant that the weir 160 and second surface irregularities 155 are at
least within about 0.257c
radians of one another about the longitudinal axis L. In such an embodiment,
as the user tips the
cap 10 to deliver a small volume of detergent composition 300 to the stain,
the second surface
irregularities 155 will naturally be located proximal the stain and the user
will be able to easily
initiate the scrubbing motion without having to tip the cap 10 further or
reposition the cap 10 in
her hand.
An embodiment in which the second surface irregularities 155 are ribs 152 is
shown in
FIG. 9. As shown in FIG. 9, the ribs 152 are asymmetrically disposed about the
longitudinal
axis L in that the pattern of ribs 152 does not extend all the way around the
exterior surface 80.
The pattern of gripping irregularities 260 is uniformly distributed about the
longitudinal axis L
such that the pattern of gripping irregularities 260 extends all the way
around the exterior
surface 80. As shown in FIG. 9, the second surface irregularities 155 and the
first surface
irregularities 150, if present, can be generally aligned with one another. In
such an embodiment,
by generally aligned it is meant that the first surface irregularities 150 and
second surface
irregularities 155 are at least within about 0.257c radians of one another
about the longitudinal
axis L. Such an embodiment can provide for giving consumers a choice of which
part of the cap
they desire to use for scrubbing. Consumers may rather use the second surface
irregularities 155
if there is some volume of detergent composition 300 left in the cap 10.
Consumers might
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choose between first surface irregularities 150 and second surface
irregularities 155 based on
efficacy for different types of stains.
If the cap 10 has both first surface irregularities 150 and second surface
irregularities
155, the second surface irregularities 155 can be substantially identical in
physical structure to
5 the first surface irregularities 150. In such an embodiment, by
substantially identical it is meant
that the first surface irregularities 150 and second surface irregularities
155 have the same
geometric characteristics or differ, if at all, only in scale or dimension.
For instance, if the
second surface irregularities 155 are nubs 154 then the first surface
irregularities can also be
nubs 154. The nubs 154 in each location may have the same geometric
characteristics or differ
10 only in scale or dimension of the nubs 154. In one embodiment, the
second surface
irregularities 155 can be ribs 152 and the first surface irregularities 150
can also be ribs 152.
Such embodiments might provide for designs in which the first surface
irregularities 150 are
obscured from view when the cap 10 is engaged with the container 110 when the
container 110
is on display at a retailer. Since the second surface irregularities 155 are
visible to the consumer
15 in this condition, the second surface irregularities 155 can provide an
indicator to the consumer
of what the obscured first surface irregularities 150 look like without the
consumer having to
open the package. This can be important when the container 110 is on display
at a retailer
because consumers might desire to open the container 110 prior to purchase to
see if the cap 10
is provided with the first surface irregularities 150. Embodiments in which
the second surface
20 irregularities 155 can be selected from the group consisting of rings
158, ribs 152, nubs 154,
bristles 156, fibers, and combinations thereof, are contemplated.
For second surface irregularities 155 that are bristles 156, bristles 156 can
be formed
such that the bristles are generally aligned parallel to the longitudinal
axis, as for instance shown
in FIG. 8, or generally aligned orthogonal to the longitudinal axis L. In such
an arrangement,
25 when the second surface irregularities 155 are scrubbed against the
stained fabric, the cap 10 is
likely to be tilted. Thus, as the user scrubs with the cap, a combination of
normal forces and
shear forces can be delivered to the stained fabric and the bristles 156 may
tend to bend thereby
creating an effective brushing movement of the individual bristles 156.
The bristles 156, if present as second surface irregularities 155, can be set
such that the
30 bristles 156 are nested with the maximum radial extent of the exterior
surface 80 of the cap 10
from the longitudinal axis L. Such an arrangement can protect the bristles 156
from damage
during transport, storage, and use. For a similar benefit, the bristles 156
can be set such that the
bristles 156 are nested within the maximum axial extent along the longitudinal
axis L.
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An example of a cap 10 in which the rim 90 has the shape of a spout 92 is
illustrated in
FIG. 10. A cap 10 in which the rim 90 has the shape of a spout 92 can be
practical for providing
for a precise pour of a small volume of detergent composition 300 to a stained
fabric and to help
keep a large volume of detergent composition 300 from being accidentally
dispensed during pre-
treatment of a stain. A variety of spout 92 geometries can be practical,
particularly those
geometries which tend to tightly channel liquid flow.
A plurality of first surface irregularities 150 can be provided at the tip of
the spout 92.
First surface irregularities 150 can be advantageously placed as such so that
once the small
volume of detergent composition 300 is poured onto the stain, the cap 10 is
positioned in the
usef s hand such that the first surface irregularities 150 can be conveniently
rubbed against the
stain. Further, if the user only places a small volume of detergent
composition 300 in the pour
volume 100 and tips the cap 10 nearly completely over when she pre-treats the
stain, the spout
92 can still be visible to the user and she will be able to see the first
surface irregularities 150
and observe her scrubbing of the stain. Without a spout 92, the portion of the
rim 90 located
opposite of the side from which the detergent composition 300 is dispensed
might obstruct her
view of the first surface irregularities 150 and her scrubbing of the stain.
Further, since the
consumer may tend to pour from the cap 10 such that the flow emanates from a
location on the
rim 90 between her index finger and thumb as she rotates her wrist, the first
surface
irregularities 150 can be located such that these features might be
conveniently and
ergonomically located for the consumer to exploit these features. For
instance, the cap 10 can
comprise a plurality of first surface irregularities 150 at a location
selected from the group
consisting of on the rim 90, between the connecter 130 disposed on the cap 10
and the rim 90,
and combinations thereof.
One example design for a practical spout 92 can be a cylindric section, as
illustrated in
FIG. 11. A spout 92 having the shape of a cylindric segment can be
structurally stable so that an
unacceptable amount of deformation of the rim 90 does not occur during
scrubbing of the stain.
Further, after filling the pour volume 100 of the cap 10 with detergent
composition 300, the user
may tend to try to keep the phreatic surface of the detergent composition 300
level with the
ground. When the phreatic surface of the detergent composition 300 in the pour
volume 100 is
kept level, the profile view of the cap 10 will present an angled rim 90 to
the viewer. The
consumer expectation for dosing devices, such as caps or cups, might be that
the rim 90 of the
cap should be level with the ground, for instance as might be the case for
caps that have a
cylindrical pour volume 100. Thus, when applying the detergent composition 300
to pre-treat a
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stain, the consumer might naturally and intuitively attempt to level the rim
90 of the cap as she
pours out the detergent composition 300 from the cap 10. A consumer may tend
to pour from
the cap 10 such that the flow emanates from a location between her index
finger and thumb as
she rotates her wrist. With these insights, designers might be able to have a
significant influence
on what portion of the rim 90 that a consumer will choose to pour from. By
driving the
consumer to pour from a certain portion of the rim 90, designers can
coordinate the location of
other features on the cap, for example first surface irregularities 150,
second surface
irregularities 155, aperture 220, pouring ledge 210, weir 160, and collector
250, such that these
features might be conveniently and ergonomically located to allow the user to
exploit these
features without having to reposition the cap 10 in her hand.
In one example embodiment, the rim 90 can be parallel to a plane oriented at
an angle 13
more than about five degrees out of plane with respect to the base exterior
40. In one example
embodiment, the rim 90 can be parallel to a plane oriented at an angle 13 more
than about ten
degrees out of plane with respect to the base exterior 40. In one example
embodiment, the rim
90 can be parallel to a plane oriented at an angle 13 more than about fifteen
degrees out of plane
with respect to the base exterior 40.
The rim 90 can have an apex 94, which is the highest portion of the rim 90
when the cap
10 positioned on a flat surface such that detergent composition 300 can be
poured into the pour
volume 100. The rim 90 can be provided with a weir 160. In one embodiment, the
rim 90 can
be parallel to a plane oriented at an angle 13 more than about five degrees
out of plane with
respect to the base exterior 40 and the rim can have an apex 94 relative to
the base exterior 40
and the cap 10 can comprise a plurality of first surface irregularities 150 on
the rim 90.
A cap 10 having a spout 92 can have a plurality of second surface
irregularities 155 on a
portion of the base exterior 40 or a portion of the exterior surface 80, an
example of which is
shown in FIG. 12. In one example embodiment, the apex 94 and the second
surface
irregularities 155 are generally aligned with one another. In such an
embodiment, by generally
aligned, it is meant that the apex 94 and the second surface irregularities
155 are at least within
about 0.257c radians of one another about the longitudinal axis L. In one
embodiment, the rim
90 can have a weir 160 at the apex 94 and the apex 94 and the second surface
irregularities 155
can be generally aligned with one another. In such embodiments, by generally
aligned, it is
meant that the apex 94 and the second surface irregularities 155 are at least
within about 0.257c
radians of one another about the longitudinal axis L. In embodiments having
such second
surface irregularities 155, by coordinating the location of the second surface
irregularities 155
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with the apex 94, and weir 160 if present, when the consumer finishes pouring
the detergent
composition 300 to pre-treat the stain, the second surface irregularities 155
can be in the proper
position for the consumer to scrub the stain with the second surface
irregularities 155 without
her having to reposition the cap 10 in her hand. After pouring, she will
likely be holding the cap
10 in an upright position with the second surface irregularities 155 located
proximal to the
stained fabric.
An example embodiment in which a pouring ledge 210 having an aperture 220
there
through extends from the rim 90, the rim 90 having an apex 94 relative to the
base exterior 40
and the aperture 220 is generally aligned with the apex 94 is shown in FIG.
13. As disclosed
above, the pouring ledge 210 can extend from, for example, the vessel wall 60
or rim 90.
Further, as disclosed above, the aperture 220 can be in the vessel wall 60
between the pouring
ledge 210 and the base 20, the aperture 220 being closer to the pouring ledge
210 than the base
20. In these embodiments, by generally aligned, it is meant that the aperture
220 and the apex
94 are at least within about 0.257c radians of one another about the
longitudinal axis L. Various
combinations of these features can provide the desired benefit and can be
described as a cap 10
wherein a pouring ledge 210 having an aperture 220 there through extends from
the vessel wall
60 or rim 90 and the rim 90 has an apex 94 relative to the base exterior 40
and the aperture 220
is generally aligned with the apex 94 or, in an another embodiment, wherein a
pouring ledge 210
extends from the vessel wall 60 or rim 90 and an aperture 220 is in the vessel
wall 60 between
the pouring ledge 210 and the base 20 and the aperture 220 is closer to the
pouring ledge 210
than the base 20.
A cap 10 having various combinations of the features disclosed herein can
provide an
effective stain pre-treatment device. A cap 10 can be provided with first
surface irregularities
150 at any of the locations or combinations of locations described above. A
cap 10 can be
provided with second surface irregularities 155 at any of the locations or
combinations of
locations described above. A cap 10 can be provided with first surface
irregularities 150 and
second surface irregularities 155, each of which are located at the locations
or combinations of
locations for second surface irregularities 155 described above. Various
embodiments can be
provided with a pouring spout 92 as described above to provide for more
precise pouring. Such
pouring spout 92 can be a cylindric section. Each of the embodiments
contemplated herein can
be provided with a pouring ledge 210 having an aperture 220 there through, as
described above.
Each of the embodiments contemplated herein can be provided with a collector
250.
Embodiments contemplated herein can be provided with a weir 160 in the rim 90
to provide for
CA 02798745 2013-11-19
34
precise pouring. The features of the cap 10 can be located relative to one
another as described
for the embodiments above.
A cap 10 may be used in a method of pre-treating a clothing article having a
stained
portion. The method can comprise the steps of removing a cap 10 from a
container containing a
detergent; pouring or dispensing a volume of the detergent composition 300
from the container
110 into the cap 10; applying at least a portion of the volume of the
detergent composition 300
to a stained portion of the stained clothing article; scrubbing the stained
portion with a portion of
the cap 10; reengaging the cap 10 with the container 110 containing the
detergent composition
300. The step of scrubbing the stained portion with a portion of the cap 10
can be performed
with a portion of the cap 10 selected from the group consisting of the rim 90
of the cap 10, a
portion of the cap 10 between the rim 90 and the connector 130, the exterior
surface 80, the base
exterior 40 of the cap 10, and combinations thereof. The cap 10 used in the
method can be any
of the various embodiments and combinations of embodiments of the cap 10
contemplated
herein. The cap 10 can be removed from a container 110 by unscrewing the cap
10 to disengage
threads 134 on the cap 10 from corresponding threads 134 located on the
container 110. The
cap 10 can be reengaged with the container 110 by screwing the cap 10 to
engage threads 134
on the cap 10 with threads 134 located on the container 110. The cap 10 can
have a spout 92.
The spout 92 can be a cylindric section. The volume detergent composition 300
poured into the
cap 10 can be a unit dose of the detergent composition 300. The method can
comprise a step of
placing the cap 10 in the drum of a washing machine. In such an approach,
detergent
composition 300 remaining in the cap 10 after pre-treatment of a stain can be
delivered to the
wash.
The color of the first material and second material are measured by the
reflectance
spectrophotometer according to the colors L*, a, and h* values.
75 The color difference is calculated using the L*, a*, and b* values by
the formula AE=
[(L*x.¨L*y)2 + (a*x.¨a*y)2 + (b*x¨b*y)21112. Herein, the 'X in the equation
represents the first
material and 'Y represents the second material, X and Y cannot be the same two
points of
measurement at the same time. For any particular comparison of the difference
in color, the
location of X the location of Y.
Reflectance color is measured using the Hunter Lab LabScanTM XE reflectance
spectrophotometer obtained from I lunter Associates Laboratory of Reston, Va.
A cap 10 is
tested at an ambient temperature between 65 F and 75 F and a relative
humidity between 50%
and 80%.
CA 02798745 2013-11-19
The spectrophotometer is set to the CIELabTM color scale and with a D65
illumination. The
Observer is set at 100 and the Mode is set at 45/00. Area View is set to
0.125' and Port Size is set
to 0.20'. The spectrophotometer is calibrated prior to sample analysis
utilizing the black glass and
white reference tiles supplied from the vendor with the instrument.
Calibration is done according
5 to the manufacturer's instructions as set forth in LabScan XE User's
Manual, Manual Version 1.1,
August 2001, A60-1010-862. If cleaning is required of the reference tiles or
samples, only
tissues that do not contain embossing, lotion, or brighteners should be used
(e.g. PUFFSTM tissue).
Any sample point on the cap containing the color to be analyzed can be
selected.
The cap 10 is placed over the sample port of the spectrophotometer with a
white clamp
10 disk placed behind the cap 10.
The cap 10 is removed and repositioned so that a minimum of six readings of
color of the
cap 10 are conducted. If possible (e.g., the size of the imparted color on the
element in question
does not limit the ability to have six discretely different, non-overlapping
sample points), each of
the readings is to be performed at a substantially different region on the
externally visible surface
15 so that no two sample points overlap. If the size of the portion of the
cap comprising the first
material or second material requires overlapping of sample points, only six
samples should be
taken with the sample points selected to minimize overlap between any two
sample points. The
readings are averaged to yield the reported L*, a*, and b* values for a
specified color on an
externally visible surface of an element.
20 The first material and second material are considered to have different
colors if AE is
greater than about 1.
An embodiment in which the cap 10 comprises two regions of surface
irregularities on the
base exterior 40 is shown in FIG. 14. The base exterior 40 can have a first
region 400 and a
second region 410 disposed thereon. The second region 410 can be adjacent to
the first region
25 400. The first region 400 can comprise a plurality of first surface
irregularities 150 and the
second region 410 can comprise a plurality of second surface irregularities
155. Each region of
surface irregularity can provide for a different benefit. For instance, the
first surface
irregularities 150 can provide for a scrubber that can be used to scrub a
stain on a fabric or article
of clothing. Second surface irregularities 155 can provide for a spreader that
can spread a
30 detergent composition 300 over such a stain or provide for a roughened
surface to disrupt the
boundary layer of detergent composition 300 that might develop when scrubbing
the stain with
first surface irregularities 150.
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WO 2011/163457 PCT/US2011/041596
36
For a cap 10 that has only first surface irregularities 150 on the base
exterior 40 or on the
vessel wall 60 proximal the base exterior 40, it is possible that some
consumers might use a cap
as disclosed herein by choosing to scrub the stain with the base exterior 40
facing the stain
such that the first surface irregularities 150 and the remainder of the base
exterior 40 face the
5 stain. That is, the cap 10 may be in position that is essentially the
same as the position a
consumer puts the cap 10 in when she is filling the pour volume 100 with a
unit dose of detergent
composition 300. If the portion of the base exterior 40 that does not comprise
first surface
irregularities 150 is generally smooth, that portion of the base exterior 40
may glide over the
detergent composition 300 much like a person glides on a thin layer of water
when they slide
10 down a recreational waterslide or slip on a smooth wet floor. Such a
result may not be desirable
if the thin layer of detergent 300 that forms the boundary layer between the
fabric being treated
and the cap 10 is thick enough to maintain separation or reduce contact (no
direct contact)
between the first surface irregularities 150 and the fabric being treated.
Thick high density
liquids such as modern liquid detergent formulations that have high viscosity
may form an
appreciable boundary layer when vigorously sheared, as might occur during
scrubbing. If such a
fluid dynamic occurs, the first surface irregularities 150 may not contact the
stain being treated
and the cap 10 may glide around the stained fabric and the stained fabric may
offer little
frictional resistance. A user can mitigate this concern if the cap 10 is
slightly tipped such that
only, or mostly only, first surface irregularities 150 contact the stain being
treated or tipping the
cap 10 enough such that a boundary layer of fluid does not develop upon which
the cap 10 can
glide.
The first surface irregularities 150 can differ in shape from the second
surface
irregularities 155. The shape may be different so as to provide for a
different benefit in that one
shape provides for scrubbing and the other provides for disrupting development
of a boundary
layer of detergent composition 300. Such a difference in shape can also be
helpful to drive the
consumer to recognize that different regions of the base exterior 40 of the
cap may be present to
provide for different functions and to select the proper region to scrub the
stain with.
The first surface irregularities 150 can differ in shape from the second
surface
irregularities 155 by properties including, but not limited to, height,
diameter, aspect ratio,
curvature of various surfaces. For instance, first surface irregularities 150
can be generally
columnar shaped and second surface irregularities can be a disordered
roughened texture.
The apexes 420 of a plurality of first surface irregularities 150 can be in
plane with the
apexes 420 of a plurality of second surface irregularities 155. Such an
arrangement might be
CA 02798745 2013-11-19
37
practical for providing a cap 10 that can be stably set on a surface such that
detergent
composition 300 can be poured into the pour volume 100. The pour volume 100
can have a
phreatic surface when filled with detergent composition 300 wherein the apexes
420 of the
plurality of first surface irregularities 150 and the apexes of the plurality
of second surface
surface is the free surface of the detergent composition 300 when poured into
the pour volume
100.
For high density liquid detergent compositions 300, the pour volume 100 can be
sized and
dimensioned to provide for a pour volume 100 that is between about 10 mL and
about 200 mL.
The first surface irregularities 150 can comprise a thermoplastic elastomer.
The second
surface irregularities 155 can comprises a thermoplastic elastomer. The first
surface
irregularities 150 and second surface irregularities 155 can comprise a
thermoplastic elastomer.
25 The first surface irregularities 150, the second surface irregularities
155, and both the first
surface irregularities 150 and the second surface irregularities 155 can be
acrylonitrile butadiene
styrene. The vessel wall 60 and/or the base 20 may be comprised of a thermoset
material in the
embodiments described herein. The vessel wall 60 and/or base 20 may be
comprised of
acrylonitrile butadiene styrene. The vessel wall 60 and/or base 20 may be
comprised of
CA 02798745 2013-11-19
38
If the vessel wall 60 and/or base 20 is polypropylene and a thermoplastic
elastomer is
used for either or both of the first surface irregularities 150 and/or the
second surface
irregularities 155, the thermoplastic elastomer can be selected such that it
is of the type that is
compatible with polypropylene. In one embodiment in which a thermoplastic
elastomer is
employed, the thermoplastic elastomer used for surface irregularities selected
from the group
consisting of first surface irregularities 150, second surface irregularities,
and combinations
thereof, the thermoplastic elastomer can be VERSAFLEXTM 9500, available from
GLS
Thermoplastic Elastomers, McIIenry, Illinois, U.S.A.
It can be practical to a have a cap 10 wherein the first surface
irregularities 150 and the
vessel wall 60 comprise materials having different chemical compositions from
one another so as
to provide different benefits with different portions of the cap 10 and/or to
cost-optimize
manufacture of the cap 10. Similarly, it can be practical to have the first
surface irregularities
150 and second surface irregularities 155 comprise materials having different
chemical
composition from one another so as so as to provide different benefits with
different portions of
the cap 10 and/or to cost-optimize manufacture of the cap 10. For instance the
first surface
irregularities 155 can be thermoplastic elastomer that provides for a pliable
scrubbing surface and
second surface irregularities 155 can be a thermoset material that provides
for a rugged and rigid
topographic profile for disrupting a boundary layer of detergent composition
300 and that is
durable.
The vessel wall 60 can comprise a material that has a Shore A hardness greater
than that of
the first surface irregularities 150 to provide for a rigid vessel wall that
is stiff when the
consumer grips the cap 10 to remove the cap 10 from the container 110, is
stiff enough to
withstand installation with the container 110 during production of consumer
product, and is stiff
enough to withstand shipping and storage.
The base exterior 40 may be non-planar, as shown in FIG. 14. If apexes of the
plurality
of first surface irregularities 150 are in plane with apexes of a plurality of
second surface
irregularities 155 and the base exterior 40 is planar, providing for diversity
of height of first
surface irregularities 150 and/or second surface irregularities 155 can be
challenging. Providing
for a diversity of height H of first surface irregularities 150 and/or second
surface irregularities
155 can be desirable as the diversity in height H can provide for a visual cue
to the consumer of
what part of the cap 10 might be most effective for pretreating a stain. For
instance, as shown in
FIG. 14, the first surface irregularities 155 have the greatest height I-I
proximal the location
where the base 20 joins with the vessel wall 60. Since higher first surface
irregularities 150
CA 02798745 2012-11-06
WO 2011/163457 PCT/US2011/041596
39
might be perceived by the consumer as being more effective than lower first
surface
irregularities, the consumer may understand the cap 10 might be designed such
that the most
effective scrubbing surface is at the edge of the first region 400 proximal
where the base 20 joins
with the vessel wall 60 and a cap 10 used in such a manner might provide for
ergonomic use.
The first surface irregularities 150 can vary in height H. The second surface
irregularities 155
can vary in height H. The first surface irregularities 150 and the second
surface irregularities 155
can vary in height H. First surface irregularities 150 can be bristles 156.
First surface
irregularities 150 can be bristles 156 that vary in height wherein the height
of the bristles
increases as a function of distance from the longitudinal axis L. As such the
bristles proximal the
periphery 50 have a greater height than bristles 156 further from the
periphery 50. In such an
embodiment, the base exterior 40 can be non-planar (contoured) such that the
apexes 420 of the
first surface irregularities can be in plane with one another. For bristles
156 having the same
cross section as a function of distance from the apex 420, the deformation of
each bristle 156
under an applied load increases as a function of height. Thus, longer bristles
156 can be
perceived by the consumer as being more flexible, and gentler on the fabric,
than shorter bristles
156. Surface irregularities selected from the group consisting of said first
surface irregularities,
said second surface irregularities, and combinations thereof can vary in
height.
The base exterior 40 has a base exterior surface area 41, which is the area of
the surface
of the base exterior 40. To provide for a cap 10 having a large enough first
region 400 to be
effective for pretreating stains, the first region 400 can comprise between
about 10% to about
90% of the bases exterior surface area 41. To provide for a cap 10 having a
large enough second
region 410 to be effective for disrupting the formation of a boundary layer of
detergent
composition 300 between the base exterior 40 and the fabric being pretreated,
the second region
410 can comprise between about 10% and about 90% of the base exterior surface
area 41 The
second region 410 can comprise more than 50% of the base exterior surface area
41.
The first region 400 can comprise less than 50% of the base exterior surface
area 41. By
having such arrangement, the consumer might be able to better identify that
the first region 400
has some unique property and/or capability as compared to other regions or
portions of the base
exterior 40 because first region 400 contrasts visually with the remainder of
the base 20 of the
cap. To provide for ergonomic use, the first region 400 can be generally
aligned with a portion
of the rim 90 having the shape of a spout 92. When the consumer pours a small
amount of
detergent composition 300 onto a stain via the spout 92, the first region 400
that can be used to
CA 02798745 2012-11-06
WO 2011/163457 PCT/US2011/041596
pretreat the stain by scrubbing is already in the proper position to be used
by the consumer
without the consumer having to rotate the cap 10 or change the position of her
wrist.
The first region 400 can comprise between about 10% and about 40% of the base
exterior
surface area 41. The second region can comprise between about 60% and about
90% of the base
5 exterior surface area 41.
One challenge in introducing new product forms to consumers is helping
consumers
adopt new habits, particularly those habits that can enhance consumer
satisfaction with a product.
To help consumers understand the functionality of a cap 10 and a method of
using cap 10, as
disclosed herein, it can be practical to provide usage instruction 430 for the
cap 10 that appear on
10 the cap in text form or graphical form. Usage instructions 430 can be
advantageously placed on
the base 20 so that the consumer sees the usage instruction as she opens the
container 110 as she
commences to use the product. A text form of a usage instruction can
be"Pretreat With X', where
X is the brand of detergent composition 300 contained within the container
110. Other usage
instructions are contemplated, such usage instruction needing only to inform
the consumer of the
15 functionality of the cap 10. A graphical form of a usage instruction can
be a pictorial
representation of how the cap 10 can be used, such as a human hand gripping
the cap 10 in the
desired manner and arrows or other indicia to indicate movement.
A profile view of the cap 10 shown in FIG. 14 is shown in FIG. 15, with a
portion of the
cap 10 cutaway. As shown in FIG. 15, a plurality of apexes 420 of the first
surface irregularities
20 150 are in plane with apexes 420 of a plurality of second surface
irregularities 155 such that the
cap 10 can be rested flat. Also shown in FIG. 15 is a phreatic surface 440 of
a detergent
composition 300 after detergent composition 300 has been poured into the pour
volume 100.
III. Methods
25 Hydrophilic Index
The "Hydrophilic IndeK' or 'HI' for a system of mixed surfactants can be
calculated as
follows:
(1) HIc = Ey (weight % of surfactant y in the surfactant system) x (HIS for
surfactant y).
HIS is calculated for each of the individual surfactants in the mixture as
follows:
30 (2) HIS = 20 x (the molecular weight of the head group) / (the molecular
weight the surfactant).
In the case of ionic surfactants, the HIs in equation (2) are calculated for
the surfactant ions and
the weight percents in equation (1) are for the corresponding surfactant ions.
CA 02798745 2013-11-19
41
Measurement of the Stain Removal Index
The Stain Removal Index (SRI) is measured using a modified version of the
"Standard
Guide for Evaluating Stain Removal Performance in Home Laundering' (ASTM D4265-
98). The
modifications include the following. At least 4 external replicates and at
least 2 internal
replicates are tested. The stain is applied by placing the fabric on a flat
surface and applying the
stain using a pipette for liquids or a brush for solids with a predetermined
amount each time.
Modified artificial sebum and air filter dirt are not tested. The stains
tested are supplied by EMC
Empirical Manufacturing Company.
Pretreat Procedure
According to the pretreat (PT) procedure used herein, stains are laid out on a
flat level
surface and, using a ManostatTM Syringe (or a similar tool), each stain is
covered with 1 mL of
detergent composition. To simulate pretreat executions without the benefit of
the pretreat cap,
the detergent composition is spread lightly to cover the entire stain and
allowed to sit for five
minutes, then the pretreated stained fabric is introduced into the wash cycle.
To simulate pretreat
executions with the benefit of the pretreat cap, the detergent composition is
rubbed into the stain
using the pretreat cap of the invention with 5 strokes in the same direction
and allowed to sit for
five minutes, then the pretreated stained fabric is introduced into the wash
cycle.
IV. Examples
Exemplary Liquid Detergent Compositions: Liquid detergent compositions may be
prepared
by mixing together the ingredients listed in the proportions shown:
CA 02798745 2013-11-19
42
Ingredient A
Wt% Wt% Wt% Wt% Wt% Wt%
C12-15 alkyl polyethoxylate
(1.8) sulfate 17.29% 14.78% 16.40%
17.29% 14.72% 16.40%
C 11.8 linear alkylbenzene
sulfonic acid 7.73% 7.67% 9.02% 7.73% 4.34%
9.02%
C 16-17 branched alkyl sulfate 3.30% 0.00% 0.00% 3.30% 1.75%
0.00%
C 24 alkyl 9-ethoxylate 1.46% 1.16% 1.30% 1.46% 1.00%
1.30%
C12-14 alkyl dimethyl amine
oxide 1.03% 0.77%
0.97% 1.03% 0.60% 0.97%
subtotal surf. 30.82% 24.38% 27.69%
30.82% 22.41% 27.69%
citric acid 0.67% 0.63% 0.63% 0.00% 3.50%
1.06%
C12-18 fatty acid 1.52% 0.90% 0.90% 1.52% 1.52%
1.29%
protease active enzyme protein
(GenencorTM) 0.06% 0.07%
0.07% 0.06% 0.07% 0.07%
amylase active enzyme protein
(NatalaseTM) 0.01% 0.01%
0.01% 0.01% 0.01% 0.01%
mannanase active enzyme
protein (MannawayTm) 0.00% 0.00% 0.00% 0.00% 0.00%
0.00%
xyloglucanase active enzyme
protein (WhitezymeTM) 0.00% 0.00% 0.00% 0.00% 0.00%
0.00%
pectate lyase active enzyme
protein (PectawashTM) 0.00% 0.00% 0.00% 0.01% 0.00%
0.00%
lipase active enzyme protein
(LipolexTM) 0.00% 0.00%
0.00% 0.03% 0.00% 0.00%
Borax 2.53% 2.40%
2.40% 2.53% 2.46% 2.40%
Ca Formate 0.09% 0.09% 0.09% 0.09% 0.09%
0.09%
Soil suspension polymer
(alkoxylated polyalkylene
imine) 1.44% 1.42%
1.42% 1.44% 1.51% 1.51%
Grease cleaning alkoxylated
polyalkylene imine) 1.93% 1.84% 1.84% 1.93% 1.28%
1.93%
D'I'PA 0.34% 0.34%
0.34% 0.34% 0.34% 0.63%
TironTM 0.19% 0.19%
0.19% 0.19% 0.00% 0.00%
Flourescent whitening agent 0.29% 0.27% 0.29% 0.29% 0.20%
0.29%
hydrogenated castor oil 0.12% 0.10% 0.12% 0.00% 0.00%
0.12%
Mica, titanium dioxide coated 0.10% 0.02% 0.03% 0.00% 0.00%
0.00% -
Silicone 0.00% 0.10%
0.10% 0.00% 0.00% 0.10%
hueing dye 0.05% 0.02% 0.02% 0.05% 3.20%
0.02%
Water, perfumes, dyes, buffers,
neutralizers, stabilizers, suds
suppressors, solvents, and other to to to to
optional components 100% 100% 100% to 100% 100%
to 100%
CA 02798745 2013-11-19
43
Ingredient G H I J
Wt% Wt% Wt % Wt %
C12-15 alkyl polyethoxylate (3.0) sulfate 8.5 - 4 5
C11.8 linear alkylbenzene sulfonc acid 11.4 11 12 13
C14-15 alkyl 7-ethoxylate 7 2
_ 3
C12-14 alkyl 7-ethoxylate 7.6 1 0.5 0.5
C12-14 alkyl dimethyl amine oxide - 0.4
1,2 Propane diol 6.0 5 5 3
Ethanol 1 1 1.5
Di Ethylene Glycol 4.0 - 0.7
Na Cumene Sulfonate 1 1 1
C12-18 Fatty Acid 9.5 2.7 0.8 0.9
Citric acid 2.8 3.3 2.3 1.9
Protease (40.6mg/g/)1 1.0 0.5 0.5 0.5
Natalase 200L (29.26mg/g)2 - 0.1 0.1 0.1
TermamylTm Ultra (25.1 mg/g)2 0.7 0.05 0.05 0.05
Mannaway 251, (25 mg/g)2 0.1 0.05 0.05 -
Whitezyme (20mg/g)2 0.7 0.05 0.05 0.05
Fluorescent Whitening Agent 0.2 0.1 0.1 0.05
Diethylene Triatnine Penta Acetic acid -
Diethylene Triamine Perna Methylene 0.5 0.4 0.30 0.30
Phosphonic acid
' Hydroxy Ethylidene 1,1 Di Phosphonic- 0.7 - 0.2
acid
1,2-diydroxybenzene-3,5-disulfonic acid 0.5 0.15 0.15
Soil Suspending Alkoxylated- 0.1 -
Polyalkylenimine Polymer3
Zwitterionic ethoxylated quaternized 7.1 0.7 0.7 1.6
sulfated hexamethylene diamine4
Grease Cleaning Alkoxylated 0.1
Polyalkylenimine Polymer
CA 02798745 2013-11-19
44
PEG-PVAc Polymer6 0.9 0.8 0.8 1.3
hydrogenated castor oil7 0.8 0.4 0.4 0.4
MEA Borate 0.7
Ca C12 0.05 0.05 0.05
Sodium formate 0.7 0.2
Violet DD 0.03 0.03 0.03
Mica 0.1 0.05
Water, perfumes, dyes, buffers, to 100% To 100% To 100%
to 100%
neutralizers, stabilizers, suds suppressors pH 8.0-8.2 pH 8.0- pH 8.0-
pH 8.0-
and other optional components 8.2 8.2 8.2
Available from Genencor International, South San Francisco, CA.
2
Available from NovozymesõDenmark.
3
600 g/mol molecular weight polyethylenimine core with 20 ethoxylate groups per
-NH.
Available from BASF (Ludwigshafen, Germany)
4 Described in WO 01/05874 and available from BASF (Ludwigshafen, Germany)
600 g/mol molecular weight polyethylenimine core with 24 ethoxylate groups per
-NH and 16
propoxylate groups per -NH. Available from BASF (Ludwigshafen, Germany).
6 PEG-PVA graft copolymer is a polyvinyl acetate grafted polyethylene oxide
copolymer having
a polyethylene oxide backbone and multiple polyvinyl acetate side chains. The
molecular
weight of the polyethylene oxide backbone is about 6000 and the weight ratio
of the
polyethylene oxide to polyvinyl acetate is about 40 to 60 and no more than 1
grafting point per
50 ethylene oxide units. Available from BASF (Ludwigshafen, Germany).
7 Available under the trade mark ThixinR from Elementis Specialties,
Highstown, NJ.
V. Data -
A series of tests are run in order to demonstrate the stain removal
performance of the
present invention (composition + cap) on grease stains, grass stains, and
beverage stains, as well
as overall stain removal performance in comparison to the stain removal
performance of a
comparative product, which contains a hydrophilic surfactant system and has a
Hydrophilic
Index of greater than 10 (composition + cap), on grease stains, grass stains,
and beverage stains,
as well as overall stain removal performance.
Table I provides a summary of the comparative data illustrating the greasy
stain removal
of the detergent compositions of the present invention, which have a
Hydrophilic Index of 7.8
CA 02798745 2012-11-06
WO 2011/163457 PCT/US2011/041596
and 7.9, in comparison to the greasy stain removal of a comparative detergent
composition
having a Hydrophilic Index of 10.5
Table I - low HI detergent
compositions (A and B)
vs. high HI detergent
composition (C)
FORMULA A B C
HI 7.8 7.9 10.5
Pre-treated Y Y Y
Pre-treat cap used Y Y Y
Total Surfactant c'/0 30.7 27.7 30.6
AES WT % 17.3 16.4 9.7
LAS WT% 7.7 9.0 6.2
HSAS WT% 3.3 0.0 0.0
NI 24-9 VVT% 1.3 1.3 14.8
Amine Oxide WT% 1.0 1.0 0.0 C vs A C vs. B
SRI SRI SRI dSRI dSRI
Overall Average 77.23 76.29 74.92 -2.31 -1.37
Grass 89.55 89.08 88.79 -0.76 -0.29
Grease Average 87.78 86.57 79.92 -7.86 -6.66
Grease burnt butter 96.71 96.16 96.34 -0.37 0.18
Grease bacon 95.68 95.54 90.40 -5.29 -5.14
Grease Taco 81.33 76.45 66.31 -15.02 -10.14
Grease Hamburger 73.67 72.91 60.22 -13.45 -12.69
Margarine 91.49 91.81 86.32 -5.17 -5.49
Beverage Average 64.13 61.85 64.09 -0.04 2.24
Coffee (instant) 67.60 66.14 68.99 1.39 2.85
Tea 45.86 41.83 43.90 -1.96 2.07
Wine burgundy 63.02 60.60 62.38 -0.64 1.78
Grape Juice 72.04 70.46 72.78 0.74 2.32
Fruit blueberry 72.11 70.21 72.39 0.28 2.18
Particulate Average 60.35 59.43 59.07 -1.27 -0.36
Clay (U.S.) 60.35 59.43 59.07 -1.27 -0.36
Make-up replenish 77.07 77.22 74.36 -2.71 -2.86
The data in Table I demonstrates that detergent compositions according to the
present
5 invention, A and B above, which have HIs of 7.8 and 7.9, respectively,
have grease average SRIs
of 87.78 and 86.57, respectively, whereas a comparative composition, C, which
has an HI of
10.5, has a grease average SRI of only 79.92, a difference of 7.86 and 6.66
SRI units,
respectively.
Table II provides a summary of the comparative data illustrating the
particulate stain
10 removal achieved with the cap of the present invention in comparison to
the particulate stain
removal achieved without the use of the cap of the present invention.
CA 02 7 987 45 2 0 1 3-1 1-1 9
46
Table II - low HI detergent compositions (A
and B) with cap vs. low HI detergent
compositions (A and B) without cap
FORMULA A A B B
HI 7.8 7.8 7.9 7.9
Pre-treated Y Y Y Y
Pre-treat cap used N V N Y
Total Surfactant % 30.7 30.7 27.7 27.7
AES WT % 17.3 17.3 16.4 16.4
LAS WT% 7.7 7.7 9.0 9.0
HSAS WT% 3.3 3.3 0.0 0.0
NI 24-9 WT% 1.3 1.3 1.3 1.3
cap
Amine Oxide WT% 1.0 1.0 vs. no 1.0 1.0 cap vs.
cap no cap
SRI SRI dSRI SRI SRI dSRI
Overall Average 72.94 77.23 4.29 71.98 76.29
4.31
Grass 88.20 89.55 1.35 87.85 89.08
1.23
Grease Average 84.89 87.78 2.89 83.94 86.57 2.63
Grease burnt butter 95.77 96.71 0.94 95.03 96.16 1.13
Grease bacon 95.30 95.68 0.38 95.70 95.54
-0.16
_
Grease Taco 71.41 81.33 9.92 69.27 76.45
7.18
,
Grease Hamburger 71.20 73.67 2.46 68.65 72.91 4.26
Margarine 90.75 91.49 0.74 91.07 91.81
0.74
Beverage Average 61.83 64.13 2.30 59.62 61.85 2.23
._
Coffee (instant) 65.67 67.60 1.93 63.70 66.14
2.44
Tea 42.19 45.86 3.67 38.43 41.83
3.40
Wine burgundy 61.43 63.02 1.59 58.98 60.60
1.62
Grape Juice 69.98 72.04 2.06 67.96 70.46
2.50
Fruit blueberry , 69.87 72.11 2.24 69.05 70.21
1.16
Particulate Average 49.55 68.71 19.16 47.37 68.33 20.96
Clay (U.S.) 48.25 60.35 12.09 47.46 59.43
11.97
Make-up replenish 50.84 77.07 26.23 47.27 77.22 29.95
The data in Table II demonstrates that the cap of the present invention
provides an
increase in particulate average SRI of 19.16 units and 20.96 units, for
formulas A and B
respectively.
The dimensions and values disclosed herein are not to be understood as being
strictly
limited to the exact numerical values recited. Instead, unless otherwise
specified. each such
dimension is intended to mean both the recited value and a functionally
equivalent range
surrounding that value. For example, a dimension disclosed as"40 mill' is
intended to mean"about
40 innf
CA 02798745 2013-11-19
47
The citation of any document is not an admission that it is prior art with
respect to
any invention disclosed or claimed herein or that it alone, or in any
combination with any
other reference or references, teaches, suggests or discloses any such
invention. Further, to
the extent that any meaning or definition of a term in this document conflicts
with any
meaning or definition of the same term in a document referenced herein, the
meaning or
definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated
and
described, the claims should not be restricted to the particular embodiments
set forth. The
claims should be given the broadest interpretation consistent with the
description as a whole.
