Note: Descriptions are shown in the official language in which they were submitted.
. CA 02847297 2014-02-28
-
Security element with colour-switching effect, use of same and method for
6
producing same
The invention relates to a security element having a colour-tilt effect and
cutouts which
are identifiable in transmitted light, a method for the production thereof and
the use
thereof.
Security elements that have a colour-tilt effect are known. Colour-tilt
effects can be
achieved in various ways, for example by way of thin-film interference such as
in
built-up structures having a layer that reflects electromagnetic waves, a
spacer layer
and a layer formed from metallic clusters. Such security elements are
described in US
2005/042449 A or in EP 1 558 449 A, for example.
Another way to provide a security element with a colour-tilt effect is to use
a coating
made of liquid crystals, either in the form of a pigmented layer or a
polymerized film.
A data storage medium is known from EP 0 435 129 A having a liquid-crystal
security
element, wherein the material is a liquid-crystal polymer that exists as a
solid in
oriented form at room temperature.
')0
Disclosed in WO 00/50249 A is a security element that has an optically
variable
material, which can be for example a liquid-crystal material, and at least one
additional
machine-readable featural material in the same layer.
To optimally recognize the colour-tilt effect, a light-absorbing background,
preferably
a black background, is needed. However, the light-absorbing, preferably black,
background is clearly visible as a dark area on the back of a security
element, such as a
thread or strip embedded at least partially into a valuable document such as a
bank note
or the like. Therefore, this light-absorbing background must be covered to
keep the
security element from being recognizable right away. This covering can be done
through a metallic layer, for example.
Known from EP 1 467 873 A is a method for producing a substrate, comprising
the
following steps: Applying a cover coating onto at least a portion of a metal
layer on a
CA 02847297 201.4-02-28
- 2 -
first side of a transparent polymer film, removing metal from the areas not
covered by
the cover layer to form metal-free sections and applying another layer to
cover the
cover coating and the metal-free sections, wherein the other layer is a layer
of liquid-
crystal polymer material, and the cover coating is dark in colour and masks
the metal
areas beneath the cover coating and leads to a colour-change effect in the
areas
covered by the liquid-crystal polymer material when viewed under reflection
from the
first side, and wherein the contrast between the metalized and the metal-free
areas can
be clearly differentiated.
Known from EP 0 319 157 A is a valuable document for bank notes comprising a
security element that is at least partially embedded and that has a metallic
layer with
cutouts in the metallic layer, wherein the cutouts constitute 10 - 50% of the
metallic
layer.
Known from EP 1 580 297 A is a film material, in particular for security
elements,
which comprises a full-area or partial opaque coating, the opaque coating
being
produced from a single material component by way of a PVD or a CVD process and
having different colour impressions from different sides.
The object of the invention was to provide a security element with a material
that has
an optically variable effect, preferably a colour-tilt effect, and that has
cutouts which
are identifiable in transmitted light, wherein the security element is
designed such that
it allows optimum recognition of the optically variable effect while at the
same time
not being recognizable from the back side through the paper surface in the at
least
partially embedded state in a valuable document when viewed in reflection.
The subject of the invention is therefore a security element comprising a
coating of a
material which has an optically variable effect, in particular a colour-tilt
effect, and
cutouts which are identifiable in transmitted light, wherein the security
element
comprises a carrier substrate and a partial layer having cutouts,
characterized in that
the partial layer is made of an opaque coating having light-absorbing
properties on the
side that faces the coating made of the material having an optically variable
effect and
having a metallic colouration on the side that faces away from the coating
made of the
material having an optically variable effect, wherein the partial opaque
coating consists
CA 02847297 2014-02-28
- 3 -
of a light-absorbing metallic layer and a reflective metallic layer.
When viewed in transmitted light, the cutouts are identifiable as a clear
contrast
compared to the areas that comprise a light-absorbing and a reflective
metallic layer.
The security element, when embedded in a valuable document, is not
identifiable, or
barely so, from the back side even by incident light through the paper surface
due to
the reflective metallic layer. However, the cutouts are clearly identifiable
from the
back side in transmitted light. From the front side, the optically variable
effect and the
cutouts are clearly identifiable by incident light.
Possible carrier substrates include carrier films, preferably transparent,
flexible plastic
films, such as those made of PI, PP, MOPP, PE, PPS, PEEK, PEK, PEI, PSU, PAEK,
LCP, PEN, PBT, PET, PA, PC, COC, POM, ABS, PVC, PTFE, ETFE (ethylene
tetrafluoroethylene), PEA (tetrafluoroethylene-perfluoropropylvinylether-
fluorine
copolymer), MFA (tetrafluoromethylene-perfluoropropylvinylether-fluorine
copolymer), PTFE (polytetrafluoroethylene), PVF (polyvinyl fluoride), PVDE
(polyvinylidene fluoride), and EFEP (ethylene-
tetrafluoroethylene-
hexafluoropropylene-fluorine terpolymer).
The carrier films are preferred to have a thickness of 5 - 700 pm, more
preferably
5 - 200 pm, and most preferably 5 - 50 pm.
The material having an optically variable effect can be a printing dye
containing
pigments made of liquid-crystal material. In particular, the pigments consist
of
cholesteric or a mixture of nematic and cholesteric liquid crystals.
Also, optically variable interference pigments (OVI pigments) can be used.
Such
pigments are described in US 2003/0207113, for example.
In another embodiment, iridescent pigments can be used, for example Iriodine
pigments. Iriodinell is based on naturally occurring mineral mica flakes that
are
encased with semitransparent metal oxides.
Furthermore, the material having an optically variable effect can consist of a
liquid-
crystal polymer that is applied as a solution of cholesteric monomers or a
mixture of
cholesteric and nematic monomers, followed by cross-linking. The cross-linking
can
be done thermally or by way of treatment with UV radiation or electron
radiation.
, CA 02847297 2014-02-28
- 4
Preferred light-absorbing metallic layers include non-stoichiometric aluminium
oxide
and stoichiometric or non-stoichiometric copper oxide. The light-absorbing
metallic
layer is preferred to have a dark to black colour. The stronger the background
absorption in the visible spectral range (350 - 800 nm), the stronger the
visible
optically variable effect.
Possible reflective metallic layers include metals such as Al, Sn. Cu, Zn, Pt,
Au, Ag,
Cr, Ti, Mo, Fe, Pd, Ni, Co or alloys thereof, such as Cu/Al.
In one particular embodiment, the light-absorbing metallic layer can consist
of non-
stoichiometric aluminium oxide, preferably with an oxygen content of about 19-
58
at%, and the reflective metallic layer can consist of aluminium.
The cutouts in the light-absorbing metallic layer and the reflective metallic
layer are
completely identical and can be made in the form of characters, letters,
numbers,
images, symbols, lines, guilloches and the like. Combinations of these forms
are also
possible.
The cutouts can also be present in negative form, in other words for example
the area
around a character, letter and the like constitutes the cutout.
The security element according to the invention can also comprise other
security
features that can exist in further layers.
These security features can exhibit specific chemical, physical and even
optical or
optical active properties, for example.
To adjust the magnetic properties of a layer, paramagnetic, diamagnetic and
ferromagnetic materials such as iron, nickel and cobalt or compounds or salts
thereof
can be used (for example oxides or sulphides).
What are particularly suitable are magnetic pigment dyes with pigments based
on iron
oxides, iron. nickel, cobalt and alloys thereof, barium or cobalt ferrites,
hard and soft
magnetic iron and steel types in aqueous or solvent dispersions. Possible
solvents
include i-propanol, ethyl acetate, methyl ethyl ketone, methoxypropanol and
mixtures
CA 02847297 2014-02-28
- 5 -
thereof.
It is preferable for the pigments to be placed in acrylate-polymer dispersions
with a
molecular weight of 150 000 to 300 000, in nitrocellulose, acrylate-urethane
dispersions, acrylate-styrene or PVC dispersions, or such dispersions
containing
solvents.
The magnetic layer can also comprise a coding. In the process, magnetic
materials of
the same coereivity and/or remanence, as well as different coercivities and/or
remanences can be used to form the coding.
In another embodiment, the reflective metallic layer itself can have magnetic
properties. This is achieved for example by using a magnetic material such as
Fe, Ni,
or Co.
The optical properties of the layer can be influenced using visual dyes and
pigments,
luminescent dyes and pigments that fluoresce or phosphoresce in the visible
range, UV
range or in the IR range, and heat-sensitive dyes and pigments. These can be
used
individually and in all possible combinations.
Optically active features are understood here to mean diffraction structures,
diffraction
gratings, kinegrams, holograms, DID (zero order microstructures in
combination
with thin films).
These optically active features can be produced by way of known UV stamping
methods, for example, such as are described in EP 1 310 381 A, or by way of
hot
stamping methods.
In order to anchor the security element in or on the valuable document, the
element is
usually provided with an adhesive layer on one or both sides. This adhesive
layer can
be produced either in the form of a hot-seal, cold-seal or self-adhesive
layer. The
adhesive can also be pigmented, wherein all known pigments or dyes, such as
Ti02.
ZnS, kaolin, ATO, FTO, aluminium, chromium and silicon oxides, or organic
pigments such as phthalocyanine blue, i-indolide yellow, dioxazine violet and
the like
can he used, for example. Furthermore. luminescent dyes and pigments that
fluoresce
or phosphoresce in the visible range, UV range or in the IR range, and heat-
sensitive
CA 02847297 2014-02-28
- 6 -
dyes and pigments can be added. These can be used in all possible
combinations. In
addition, luminescent pigments can also be used alone or in combination with
other
dyes and/or pigments.
If necessary, the security element can also be protected by one or more
protective
varnish layer(s) that can be pigmented or un-pigmented, or can be further
relined by
way of lamination or the like, for example.
Another subject of the invention is a method for producing a security element
l 0 comprising a
material that causes an optically variable effect, in particular a colour-tilt
effect, and that has cutouts that are identifiable in transmitted light, the
method
comprising the following processing steps:
O Preparing a carrier substrate,
O Applying a colour application that is soluble in a solvent onto the
carrier
substrate in the form of the cutouts,
O Applying a full-area reflective metallic layer,
o Applying a full-area light-absorbing metallic layer.
0 Removing the colour application together with the layers on top thereon by
way of a solvent, if necessary in combination with a mechanical effect,
()Applying a full-area or partial layer comprising a material having an
optically
variable effect.
This achieves absolutely identical cutouts in the light-absorbing and the
reflective
metallic layer. When viewed in transmitted light, the cutouts are identifiable
as a clear
contrast compared to the areas that comprise a light-absorbing and a
reflective metallic
layer. Because of the reflective metallic layer, the security element, when
embedded in
a valuable document, is not identifiable, or barely so, even when viewed with
incident
light from the reflective metallic layer side through the covering paper
surface.
In a first step, a colour application that is soluble in a solvent is applied
to the carrier
substrate in the form of the later cutouts; in a second step, this layer is
treated using an
in-line plasma, corona or flame process, if necessary; and in a third step,
the reflective
and then the light-absorbing metallic coating is applied by way of a PVT) or
CM
, CA 02847297 2014-02-28
- 7 -
process; whereupon in a fourth step the colour application with the layers
disposed
thereon is removed using a solvent, if necessary in combination with a
mechanical
effect.
The colour application is done either in the form of characters, letters,
numbers,
images, symbols, lines, guilloches or a point or line pattern, or a semitone
pattern and
the like, or such that the colour application forms the outlines of the
characters, letters,
numbers, images, symbols, lines, guilloches or a point or line pattern, or a
semitone
pattern and the like. In the first case, the cutouts are identifiable in the
final structure in
transmitted light in the form of characters, letters, numbers, images,
symbols, lines,
guilloches and the like; in the second case, the characters, letters, numbers,
images,
symbols, lines, guilloches and the like are dark in transmitted light, and the
areas
around these characters, letters, numbers, images, symbols, lines, guilloches
and the
like form the cutouts that arc identifiable in transmitted light.
Application of the colour application can be done using any desired method,
for
example through intaglio printing, flexographic printing, screen printing,
digital
printing and the like. The dye or coloured varnish used is soluble in a
solvent,
preferably water, but a dye which is soluble in any desired solvent, such as
in alcohol,
esters and the like, can be used. The dye or coloured varnish can be common
compositions based on natural or synthetic macromolecules. The soluble dye can
be
pigmented or tin-pigmented. All known pigments can be used as pigments. What
are
particularly suitable are Ti02. ZnS, kaolin and the like.
Then, if necessary, there is a pretreatment step for the carrier substrate
provided with
the colour application prior to the application of the metallic layers. The
pretreatment
can involve an in-line plasma (low pressure or atmospheric plasma), corona or
flame
process. This pretreatment improves the adhesion of the metallic layer. At the
same
time, the surface is activated. In the process, terminal polar groups are
produced on the
surface.
If necessary, a thin metal or metal oxide layer can be applied simultaneously
with the
application of the plasma or corona or flame treatment as an adhesion
promoter, for
example by way of sputtering or vapour deposition. What are particularly
suitable here
CA 02847297 2014-02-28
- 8 -
are Cr, Ti, Ti02, Si oxides or chromium oxides. This adhesion promoter layer
generally has a thickness of 0.1 nm - 5 nm. preferably 0.2 nm - 2 nm, more
preferably
0.2 to I nm.
Then, the reflective metallic layer is applied by way of PVD or CVD processes,
such
as thermal evaporation, sputtering or electron beam evaporation.
In a PVD process, the coating is deposited onto the carrier substrate under a
vacuum
(up to 1042 mbar, preferably 10-2 to 104 mbar) at a temperature that depends
on the
vapour pressure and the thickness of the coating to be applied, such as
through thermal
evaporation, arc evaporation or electron beam evaporation.
Another option is to apply the coating by way of AC or DC sputtering, wherein
the
process is selected depending on the thickness of the layer to be applied and
on the
material used accordingly.
In a CVD process, the materials to be applied are introduced to a vacuum
coating
system in the form of gaseous (e.g. organometallic) precursors by way of an
inert
carrier gas (such as NI), argon). Here, the materials are broken up through
the input of
energy and caused to react. A portion of the reaction products condenses onto
the
substrate and forms the desired layer there, whereas the remaining reaction
products
are removed using a vacuum system. Gaseous precursors can include CO, CO2.
oxygen, silanes, methane, ammonia, fermcene, trimethyl aluminium or the like,
for
example.
The input of energy can be accomplished by way of an ion or electron beam, a
plasma
or an elevated temperature, for example.
in the following step. a light-absorbing metallic layer is deposited similarly
by way of
PVD or CVD processes, such as through thermal evaporation, sputtering or
electron
beam evaporation.
For the application of the light-absorbing metallic layer, the coating is
oxidized
through a correspondingly metered amount of oxygen feed to form non-
stoichiometric
oxides. This changes the appearance as well. Non-stoichiometrie aluminium
oxide or
CA 02847297 2014-02-28
- 9 -
stoichiornetric or non-stoiehiometric copper oxide thus appears black and
forms a
light-absorbing metallic layer this way.
Then, the colour layer is removed by way of a suitable solvent, matched to the
composition of the colour layer. It is preferable for the colour application
to be water-
soluble. If necessary, dissolution can he supported by mechanical effects.
Alternatively, the cutouts can also be produced through a known etching
process. In
the process, the reflective and light-absorbing metallic layer are first
applied to the
carrier substrate and then an etching resist is applied which leaves exposed
the later
cutouts. In another step, the areas of the two layers not covered by the
etching resist
are removed through etching. If necessary, the etching resist can then be
removed.
In another step, a full-area or partial layer of a material having an
optically variable
effect is applied. The application can be carried out through any desired
method, such
as intaglio printing, flexographic printing, screen printing, digital
printing, co-
rotational or counter-rotational roller application methods, curtain coating,
spin coating
and the like.
In another embodiment, the method for producing the security element can be
carried
out as follows:
O Preparing a first carrier substrate,
o Applying a -Full-area or partial layer of a material having an optically
variable
effect,
o Preparing a second carrier substrate,
O Applying a colour application that is soluble in a solvent in the form of
cutouts onto the second carrier substrate,
o Applying a full-area reflective metallic layer
O Applying a full-area light-absorbing metallic layer,
o Removing the colour application together with the layers on top thereon by
way of a solvent, if n.ecessary in combination with a mechanical effect,
O Laminating the layers on the second carrier substrate against the layers
on the
first carrier substrate,
CA 02847297 2014-02-28
- I 0
0 If necessary, removing the first carrier substrate.
In the process, the layers that comprise the cutouts which are identifiable in
transmitted
light are constructed on a second carrier substrate, whereas the layer
comprising a
material having an optically variable effect is applied to the first carrier
substrate.
This embodiment is particularly preferred when using liquid-crystal polymers
as the
layer with an optically variable effect, the polymers being applied in
solution in the
form of their monomers, whereupon cross-linking is done. The molecule chains
can
orient themselves onto the carrier substrate in this process.
Then, the layers applied to the second carrier substrate are laminated against
the layers
present on the first carrier substrate, and depending on the intended use of
the security
element the first carrier substrate can be removed if necessary.
If necessary, further security features having optical, optically active,
electrically
conductive or magnetic properties can be applied to the first and/or second
carrier
substrate or onto the layers present thereon, or can already be applied
thereon.
The security element so produced can then be provided with one or more
protective
varnish layer(s) and/or an adhesive layer on one or both sides.
Another subject of the invention is a method for producing a transferable
security
element comprising a material that causes an optically variable effect, in
particular a
colour-tilt effect, and that has cutouts that are identifiable in transmitted
light, the
method comprising the following processing steps:
o Preparing a first carrier substrate,
o Applying a full-area or partial layer comprising a material having an
optically
variable effect,
0 Applying a colour application that is soluble in a solvent in the Corm of
the
cutouts
0 Applying a full-area light-absorbing metallic layer,
0 Applying a full-area reflective metallic layer,
0 Removing the colour application together with the layers on top thereon by
way of a solvent, if necessary in combination with a mechanical effect,
CA 02847297 2014-02-28
- 1 -
Applying a hot-seal, cold-seal. or self-adhesive layer.
In the process, the entirety of the construction of the layer is on the first
carrier
substrate, wherein all process steps listed occur analogous to the method
described
above.
If necessary, a release layer can be applied to the carrier substrate prior to
applying the
layer of a material haying an optically variable effect, the adhesion of the
release layer
to the carrier substrate being less than the adhesion to the layers applied
thereon.
Possible advantageous release layers include UV varnish layers, but other
known
poorly adhering varnish compositions, such as compositions based on
methacrylate or
oil layers, polyamide, polyethylene or fluoropotymer wax layers, can be used
as well.
The application of a release layer is not required if the layer made of a
material having
an optically variable effect is itself releasable.
The security element so produced can be applied to a substrate with the
adhesive layer,
wherein the first carrier substrate is optionally removed after application.
Shown in Figures 1 to 5 are security elements according to the invention. In
these
figures
1 is an adhesive layer (for example a hot-seal varnish layer)
2 is the layer comprising a material that causes an optically variable effect
3 is a laminated adhesive layer
4 is a light-absorbing metallic layer
5 is a reflective metallic layer
6 is a protective varnish layer
7 is a partial layer with magnetic properties
8 is a carrier substrate
9 is another carrier substrate
10 are the cutouts in the light-absorbing and reflective metallic layer
II is another reflective metallic layer
12 is the substrate of a valuable document, for example paper.
Shown in Fig. 1 is a security element that is suitable for at least partial
embedding and
application. The layers are constructed on a carrier substrate 8, In the
process. the
, CA 02847297 2014-02-28
- 1 2
partial reflective metallic layer 5 and the partial light-absorbing metallic
layer 4 with
the cutouts 10 are applied first, followed by a full-area layer 2 comprising a
material
having an optically variable effect.
Fig. la shows the security element illustrated in Figure 1 as viewed in
incident light
from the side of layer 2 with an optically variable effect. The optically
variable effect
can be a colour-tilt effect, for example. A strong colour is identifiable in
the areas in
which layer 2 lies over the light-absorbing metallic layer 6 and the
reflective metallic
layer 5. When the security element is tilted such that the angle of viewing
changes, a
colour envelope is visible, particularly in the areas in which layers 2, 4 and
5 lie one
above the other. The areas in which layer 2 comes to lie over cutouts 10 show
no or
only weakly identifiable colour impression in incident light. In transmitted
light, the
area in which layers 2, 4 and 5 lie superimposed on one another appears
opaque. The
cutouts 10 are identifiable in transmitted light as a bright area with a
strong contrast to
the surrounding dark areas.
Shown in Fig. 2 is a security element according to the invention in which the
layer is
constructed on two carrier substrates (8, 9). The material 2 with an optically
variable
effect is applied to the first carrier substrate 9, and the reflective
metallic layer 5 and
the light-absorbing metallic layer 4 with the cutouts 10 are constructed on
the second
carrier substrate 8. The two carrier substrates with the layers applied
thereon are
connected together by way of a laminated adhesive layer 3 such that the layer
having
an optically variable effect comes to lie on the side of the light-absorbing
metallic
layer. If the security element is now observed through carrier substrate 10a,
a colour
impression is seen which depends on the angle of observation in a manner
similar to
that described in the case of Fig. I.
The security element according to the invention is shown in Figures 3 and 4 as
a
transfer element. Such a transfer element is preferred to be used when the
security
element is not embedded in a valuable document, but rather is applied to the
surface of
a valuable document, In the process, the structure (Fig. 3) is constructed on
a carrier
substrate 8, wherein the first layer to be applied is the layer comprising a
material 2
with an optically variable effect and then the light-absorbing metallic layer
4 and the
= CA 02847297 2014-02-28
- 13 -
reflective metallic layer 5 with the cutouts 10 are applied. The security
element is
provided with a protective varnish layer 6 and an adhesive layer 1, preferably
a hot-
seal adhesive layer.
The adhesion of layers 2 to layer 8 is weaker than the adhesion of layers 2,
4, 5, 6, 1
Shown in Fig. 4 is the transfer element applied to a substrate of a valuable
document,
for example a paper bank note. The transfer element is applied to the valuable
document 12 substrate by way of the hot-seal adhesive layer I, and then the
carrier
Shown in Fig. 5 is a security element according to the invention, the
structure of which
The security elements according to the invention are suitable as security
features in
data storage media, in particular valuable documents such as IDs, cards, bank
notes or
labels, seals and the like, if necessary after corresponding tailoring, but
also as packing
For the application as security features, the substrates and film materials
are preferably
cut into strips, threads or patches, wherein the width of the strips or
threads can
30 preferably be 0.5 - 20 mm and the patches are preferred to have average
widths and
lengths of 0.3 - 20 mm.
For the application in or on packages, the film material is preferred to be
cut into
. CA 02847297 2014-02-28
- 14
strips, bands, threads or patches, wherein the width of the threads, strips or
bands is
preferred to be 0.5 - 50 mm and the patches are preferred to have average
widths and
lengths of 2-30 mm.
