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Patent 2968226 Summary

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(12) Patent: (11) CA 2968226
(54) English Title: SYSTEMS AND METHODS FOR MANUFACTURING BULKED CONTINUOUS FILAMENT
(54) French Title: SYSTEMES ET PROCEDES DE FABRICATION DE FILAMENT CONTINU GONFLANT
Status: Granted
Bibliographic Data
(51) International Patent Classification (IPC):
  • B29C 48/08 (2019.01)
  • B29C 48/50 (2019.01)
  • B29B 17/00 (2006.01)
(72) Inventors :
  • CLARK, THOMAS R. (United States of America)
(73) Owners :
  • ALADDIN MANUFACTURING CORPORATION (United States of America)
(71) Applicants :
  • MOHAWK INDUSTRIES, INC. (United States of America)
(74) Agent: SMART & BIGGAR LP
(74) Associate agent:
(45) Issued: 2019-07-30
(86) PCT Filing Date: 2015-11-17
(87) Open to Public Inspection: 2016-05-26
Examination requested: 2018-09-12
Availability of licence: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): Yes
(86) PCT Filing Number: PCT/US2015/061145
(87) International Publication Number: WO2016/081495
(85) National Entry: 2017-05-17

(30) Application Priority Data:
Application No. Country/Territory Date
14/546,819 United States of America 2014-11-18

Abstracts

English Abstract


A method of manufacturing bulked continuous carpet filament which, in various
embodiments, comprises: (A) grinding recycled PET bottles into a group of
flakes; (B) washing
the flakes; (C) identifying and removing impurities, including impure flakes,
from the group of
flakes; (D) passing the group of flakes through an expanded surface area
extruder while
maintaining a pressure within the expanded surface area extruder below about
25 millibars; (E)
passing the resulting polymer melt through at least one filter having a micron
rating of less than
about 50 microns; and (F) forming the recycled polymer into bulked continuous
carpet filament
that consists essentially of recycled PET.


French Abstract

La présente invention concerne un procédé de fabrication de filament de tapis continu gonflant qui, dans divers modes de réalisation, comprend les étapes consistant à : (A) broyer des bouteilles de PET recyclées en un groupe de flocons ; (B) laver les flocons ; (C) identifier et éliminer les impuretés, y compris les flocons impurs, dans le groupe de flocons ; (D) faire passer le groupe de flocons à travers une extrudeuse à zone à surface expansée tout en maintenant une pression à l'intérieur de l'extrudeuse à zone à surface expansée en dessous d'environ 25 millibars ; (E) faire passer le polymère en fusion résultant à travers au moins un filtre ayant une caractéristique nominale inférieure à environ 50 micromètres ; et (F) former le polymère recyclé en filament de tapis continu gonflant qui est constitué essentiellement de PET recyclé.

Claims

Note: Claims are shown in the official language in which they were submitted.


CLAIMS:
1. A
method of manufacturing bulked continuous carpet filament, said method
comprising:
(A) providing a PET crystallizer;
(B) passing a plurality of flakes of recycled PET through said PET
crystallizer to at
least partially dry a surface of said plurality of flakes of recycled PET;
(C) providing a first extruder, said first extruder comprising:
a first extruder inlet and a first extruder outlet;
a first satellite screw extruder, said first satellite screw extruder
comprising a
first satellite screw that is mounted to rotate about a central axis of said
first satellite screw;
a second satellite screw extruder, said second satellite screw extruder
comprising a second satellite screw that is mounted to rotate about a
central axis of said second satellite screw;
a third satellite screw extruder, said third satellite screw extruder
comprising a
third satellite screw that is mounted to rotate about a central axis of said
third satellite screw; and
a fourth satellite screw extruder, said fourth satellite screw extruder
comprising
a fourth satellite screw that is mounted to rotate about a central axis of
said fourth satellite screw, wherein said first satellite screw, said second
satellite screw, said third satellite screw, and said fourth satellite screw
are disposed at least partially within respective extruder barrels;
a satellite screw extruder support system that is adapted to rotate said
first,
second, third, and fourth satellite screws about a main axis while said
22

first, second, third and fourth satellite screws are rotating about their
respective central axes, said main axis being substantially parallel to: (a)
said central axis of said first satellite screw; (b) said central axis of said

second satellite screw; (c) said central axis of said third satellite screw;
and (d) said central axis of said fourth satellite screw; and
a pressure regulation system that is adapted to maintain a pressure within
said
first extruder below about 18 millibars;
(D) using said pressure regulation system to reduce a pressure within said
first
extruder to below about 18 millibars;
(E) after passing said plurality of flakes of recycled PET through said PET
crystallizer, while maintaining said pressure within said first extruder below

about 18 millibars, passing said plurality of flakes of recycled PET through
said first extruder via said first extruder inlet to at least partially melt
said
plurality of flakes into a polymer melt such that: (1) a first portion of said
melt
passes through said first satellite screw extruder, (2) a second portion of
said
melt passes through said second satellite screw extruder, (3) a third portion
of
said melt passes through said third satellite screw extruder, and (4) a fourth

portion of said melt passes through said fourth satellite screw extruder;
(F) providing at least one spinning machine comprising at least one spinning
machine inlet, wherein said at least one spinning machine inlet is
substantially
directly coupled to said first extruder outlet;
(G) after said step of passing said polymer melt through said first extruder,
substantially immediately forming said polymer melt into bulked continuous
carpet filament using said at least one spinning machine.
2. The method of Claim 1, wherein:
23

said pressure regulation system is adapted to maintain said pressure within
said first
extruder below about 5 millibars; and
said method further comprises using said pressure regulation system to reduce
a
pressure within said first extruder to below about 5 millibars.
3. A
method of manufacturing bulked continuous carpet filament, said method
comprising:
(A) providing a PET crystallizer;
(B) passing a plurality of flakes consisting essentially of recycled PET
through said
PET crystallizer to at least partially dry a surface of said plurality of
flakes of
recycled PET;
(C) providing an expanded surface area extruder, wherein said expanded surface
area
extruder defines an expanded surface area extruder inlet and an expanded
surface area extruder outlet and comprises:
a plurality of satellite screws wherein each respective satellite screw of the

plurality of satellite screws is mounted to rotate about its respective
central axis; and
a single screw drum mounted to rotate about its central axis, wherein:
said central axis of said single screw drum is parallel to each respective
central axis of said plurality of satellite screws;
said plurality of satellite screws are arranged within said single screw
drum and at least partially housed within respective extruder
barrels; and
24

each said respective satellite screw is configured to rotate about its said
respective axis while said single screw drum rotates about said
central axis of said single screw drum;
(D) providing a pressure regulation system configured to reduce a pressure
within at
least a portion of said expanded surface area extruder below about 12 mbar;
(E) providing a spinning machine defining a spinning machine inlet, wherein
said
spinning machine inlet is operatively coupled to said expanded surface area
extruder outlet;
(F) using said pressure regulation system to reduce said pressure within said
at least a
portion of said expanded surface area extruder below about 12 mbar;
(G) after passing said plurality of flakes consisting essentially of recycled
PET
through said PET crystallizer, passing said plurality of flakes consisting
essentially of PET flakes through said expanded surface area extruder via said

expanded surface area extruder inlet to at least partially melt said plurality
of
flakes to form a polymer melt such that at least a portion of said polymer
melt
passes through each said respective satellite screw;
(H) substantially immediately after passing said plurality of flakes through
said
expanded surface area extruder, using said spinning machine to form said
polymer melt into bulked continuous carpet filament.
4. The method of Claim 3, wherein:
said pressure regulation system is further configured to reduce said pressure
within
said at least a portion of said expanded surface area extruder below about 6
mbar.
5. A method of manufacturing carpet filament comprising the steps of:
(A) grinding a plurality of recycled PET bottles into a group of polymer
flakes;

(B) washing said group of polymer flakes to remove at least a portion of one
or more
contaminants from a surface of said flakes, said group of flakes comprising a
first plurality of flakes that consist essentially of PET and a second
plurality of
flakes that do not consist essentially of PET;
(C) after said step of washing said first plurality of flakes:
(i) scanning said washed group of flakes to identify said second plurality of
flakes,
(ii) separating said second plurality of flakes from said first plurality of
flakes;
(D) providing a PET crystallizer;
(E) passing said first plurality of flakes through said PET crystallizer to at
least
partially dry a surface of said first plurality of flakes;
(F) providing an expanded surface area extruder having an extruder inlet and
an
extruder outlet and comprising:
at least four satellite screws wherein each respective satellite screw of the
at
least four satellite screws is mounted to rotate about its respective
central axis; and
a single screw drum mounted to rotate about its central axis, wherein:
said central axis of said single screw drum is parallel to each respective
central axis of said at least four satellite screws;
said at least four satellite screws are arranged within said single screw
drum and at least partially housed within respective extruder
barrels; and
26

each of said at least four satellite screws is configured to rotate about its
said respective axis while said single screw drum rotates about
said central axis of said single screw drum;
(G) providing a pressure regulation system configured to reduce a pressure
within
said expanded surface area extruder between about 0 mbar and about 5 mbar;
(H) providing a spinning machine having a spinning machine inlet, wherein said

spinning machine inlet is directly coupled to said extruder outlet;
(1) using said pressure regulation system to reduce said pressure within said
expanded surface area extruder between about 0 mbar and about 5 mbar;
(J) while maintaining said pressure within said expanded surface area extruder

between about 0 mbar about 5 mbar, passing said first plurality of flakes
through said expanded surface area extruder via said fist inlet;
(K) melting said first plurality of flakes using said expanded surface area
extruder to
produce a polymer melt so that at least a portion of said polymer melt passes
through each of said at least four satellite screws; and
(L) substantially immediately after passing said second plurality of flakes
through
said expanded surface area extruder, spinning said polymer melt into bulked
continuous carpet filament using said spinning machine.
6. The method of Claim 1, wherein:
said pressure regulation system is adapted to maintain said pressure within
said first
extruder below about 12 millibars; and
said method further comprises using said pressure regulation system to reduce
a
pressure within said first extruder to below about 12 millibars.
27

7. The method of Claim 1, wherein:
said first extruder further comprises:
a fifth satellite screw extruder, said fifth satellite screw extruder
comprising a
fifth satellite screw that is mounted to rotate about a central axis of said
second fifth screw; and
a sixth satellite screw extruder, said sixth satellite screw extruder
comprising a
sixth satellite screw that is mounted to rotate about a central axis of said
sixth screw; and
said satellite screw extruder support system is adapted to rotate said first,
second,
third, fourth, fifth, and sixth satellite screws about a main axis while said
first,
second, third, fourth, fifth, and sixth satellite screws are rotating about
their
respective central axes.
8. The method of Claim 7, wherein:
said first extruder further comprises:
a seventh satellite screw extruder, said seventh satellite screw extruder
comprising a seventh satellite screw that is mounted to rotate about a
central axis of said second seventh screw; and
a eighth satellite screw extruder, said eighth satellite screw extruder
comprising
a eighth satellite screw that is mounted to rotate about a central axis of
said eighth screw; and
said satellite screw extruder support system is adapted to rotate said first,
second,
third, fourth, fifth, sixth, seventh, and eighth satellite screws about a main
axis
while said first, second, third, fourth, fifth, sixth, seventh, and eighth
satellite
screws are rotating about their respective central axes.
28

9. The method of Claim 8, wherein said method comprises manufacturing
bulked
continuous carpet filament from 100% recycled PET substantially immediately
after
extruding said recycled PET.
10. The method of Claim 1, wherein aid PET crystallizer is configured to
reduce a
moisture content of said plurality of flakes of recycled PET to between about
30 and
about 40 parts per million.
11. The method of claim 1, wherein said PET crystallizer comprises:
a hopper screw configured to feed said plurality of flakes of recycled PET
into said
PET crystallizer; and
a blower configured to blow hot air over said plurality of flakes of recycled
PET as
said plurality of flakes of recycled PET pass through said crystallizer.
12. The method of Claim 11, wherein said crystallizer is configured to
maintain a
temperature of between about 140 degrees Celsius and about 230 Celsius within
said
crystallizer.
13. The method of Claim 12, wherein said PET crystallizer causes said
plurality of flakes
of recycled PET to at least partially reduce in size.
14. The method of Claim 3, wherein passing said plurality of flakes
consisting
essentially of PET flakes through said expanded surface area extruder
comprises
passing said plurality of flakes consisting essentially of PET flakes through
said
expanded surface area extruder such that at least a portion of said polymer
melt
passes through each said respective satellite screw while each said respective
satellite
screw is rotating about its said respective axis and said single screw drum is
rotating
about said central axis of said single screw drum.
29

15. The method of Claim 14, wherein said method comprises manufacturing
bulked
continuous carpet filament from 100% recycled PET substantially immediately
after
extruding said recycled PET.
16. The method of Claim 3, wherein said PET crystallizer is configured to
reduce a
moisture content of said plurality of flakes consisting essentially of
recycled PET to
between about 30 and about 40 parts per million.
17. The method of claim 3, wherein said plurality of satellite screws
comprise at least
four satellite screws.
18. The method of Claim 17, wherein said plurality of satellite screws
comprise eight
satellite screws.

Description

Note: Descriptions are shown in the official language in which they were submitted.


1024-02006-PCT PPH
SYSTEMS AND METHODS FOR MANUFACTURING BULKED CONTINUOUS
FILAMENT
BACKGROUND
[001] Because pure virgin PET polymer is more expensive than recycled PET
polymer, and because of
the environmental benefits associated with using recycled polymer, it would be
desirable to be
able to produce bulked continuous carpet filament from 100% recycled PET
polymer (e.g., PET
polymer from post-consumer PET bottles).
SUMMARY
[002] A method of manufacturing bulked continuous carpet filament,
according to various
embodiments, comprises: (A) providing a first extruder comprising a first
extruder inlet, a first
extruder outlet and a pressure regulation system that is adapted to maintain a
pressure within the
first extruder below about 18 millibars; (B) using the pressure regulation
system to reduce a
pressure within the first extruder to below about 18 millibars; (C) while
maintaining the pressure
within the first extruder below about 18 millibars, passing a plurality of
flakes of recycled PET
through the first extruder via the first extruder inlet to at least partially
melt the plurality of flakes
into a polymer melt; (D) providing at least one spinning machine comprising at
least one spinning
machine inlet, wherein the at least one spinning machine inlet is
substantially directly coupled to
the first extruder outlet; (E) after the step of passing the polymer melt
through the first extruder,
substantially immediately forming the polymer melt into bulked continuous
carpet filament using
the at least one spinning machine.
[003] A method of manufacturing bulked continuous carpet filament,
according to various
embodiments: (A) providing an expanded surface area extruder, wherein the
expanded surface
area extruder defines an expanded surface area extruder inlet and an expanded
surface area
extruder outlet; (B) providing a pressure regulation system configured to
reduce a pressure within
at least a portion of the expanded surface area extruder below about 12 mbar;
(C) providing a
spinning machine defining a spinning machine inlet, wherein the spinning
machine inlet is
operatively coupled to the expanded surface area extruder outlet; (D) using
the pressure
regulation system to reduce the pressure within the at least a portion of the
expanded surface area
extruder below about 12 mbar; (E) passing a plurality of flakes consisting
essentially of PET flakes
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through the expanded surface area extruder via the expanded surface area
extruder
inlet to at least partially melt the plurality of flakes to form a polymer
melt; and
(F) substantially immediately after passing the plurality of flakes through
the
expanded surface area extruder, using the spinning machine to form the polymer
melt
into bulked continuous carpet filament.
[004] A method of manufacturing carpet filament, in particular
embodiments,
comprises the steps of: (A) grinding a plurality of recycled PET bottles into
a group
of polymer flakes; (B) washing the group of polymer flakes to remove at least
a
portion of one or more contaminants from a surface of the flakes, the group of
flakes
comprising a first plurality of flakes that consist essentially of PET and a
second
plurality of flakes that do not consist essentially of PET; (C) after the step
of washing
the first plurality of flakes: (i) scanning the washed group of flakes to
identify the
second plurality of flakes, and (ii) separating the second plurality of flakes
from the
first plurality of flakes; (D) providing an expanded surface area extruder
having an
extruder inlet and an extruder outlet; (E) providing a pressure regulation
system
configured to reduce a pressure within the expanded surface area extruder
between
about 0 mbar and about 5 mbar; (F) providing a spinning machine having a
spinning
machine inlet, wherein the spinning machine inlet is directly coupled to the
extruder
outlet; (G) using the pressure regulation system to reduce the pressure within
the
expanded surface area extruder between about 0 mbar and about 5 mbar; (H)
while
maintaining the pressure within the expanded surface area extruder between
about
0 mbar about 5 mbar, passing the second plurality of flakes through the
expanded
surface area extruder via the fist inlet; (I) melting the second plurality of
flakes using
the expanded surface area extruder to produce a polymer melt; and (J)
substantially
immediately after passing the second plurality of flakes through the expanded
surface
area extruder, spinning the polymer melt into bulked continuous carpet
filament using
the spinning machine.
[004a] Another aspect of the present disclosure relates to a method of
manufacturing
bulked continuous carpet filament, said method comprising: (A) providing a PET

crystallizer: (B) passing a plurality of flakes of recycled PET through said
PET
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crystallizer to at least partially dry a surface of said plurality of flakes
of recycled
PET; (C) providing a first extruder, said first extruder comprising: a first
extruder
inlet and a first extruder outlet; a first satellite screw extruder, said
first satellite screw
extruder comprising a first satellite screw that is mounted to rotate about a
central axis
of said first satellite screw; a second satellite screw extruder, said second
satellite
screw extruder comprising a second satellite screw that is mounted to rotate
about a
central axis of said second satellite screw; a third satellite screw extruder,
said third
satellite screw extruder comprising a third satellite screw that is mounted to
rotate
about a central axis of said third satellite screw; and a fourth satellite
screw extruder,
said fourth satellite screw extruder comprising a fourth satellite screw that
is mounted
to rotate about a central axis of said fourth satellite screw, wherein said
first satellite
screw, said second satellite screw, said third satellite screw, and said
fourth satellite
screw are disposed at least partially within respective extruder barrels; a
satellite
screw extruder support system that is adapted to rotate said first, second,
third, and
fourth satellite screws about a main axis while said first, second, third and
fourth
satellite screws are rotating about their respective central axes, said main
axis being
substantially parallel to: (a) said central axis of said first satellite
screw; (b) said
central axis of said second satellite screw; (c) said central axis of said
third satellite
screw; and (d) said central axis of said fourth satellite screw; and a
pressure regulation
system that is adapted to maintain a pressure within said first extruder below
about
18 millibars; (D) using said pressure regulation system to reduce a pressure
within
said first extruder to below about 18 millibars; (F) after passing said
plurality of
flakes of recycled PET through said PET crystallizer, while maintaining said
pressure
within said first extruder below about 18 millibars, passing said plurality of
flakes of
recycled PET through said first extruder via said first extruder inlet to at
least partially
melt said plurality of flakes into a polymer melt such that: (1) a first
portion of said
melt passes through said first satellite screw extruder, (2) a second portion
of said
melt passes through said second satellite screw extruder, (3) a third portion
of said
melt passes through said third satellite screw extruder, and (4) a fourth
portion of said
melt passes through said fourth satellite screw extruder; (F) providing at
least one
spinning machine comprising at least one spinning machine inlet, wherein said
at
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85104844
least one spinning machine inlet is substantially directly coupled to said
first extruder
outlet; (G) after said step of passing said polymer melt through said first
extruder,
substantially immediately forming said polymer melt into bulked continuous
carpet
filament using said at least one spinning machine.
1004b1 Another aspect of the present disclosure relates to a method of
manufacturing
bulked continuous carpet filament, said method comprising: (A) providing a PET

crystallizer; (B) passing a plurality of flakes consisting essentially of
recycled PET
through said PET crystallizer to at least partially dry a surface of said
plurality of
flakes of recycled PET; (C) providing an expanded surface area extruder,
wherein
said expanded surface area extruder defines an expanded surface area extruder
inlet
and an expanded surface area extruder outlet and comprises: a plurality of
satellite
screws wherein each respective satellite screw of the plurality of satellite
screws is
mounted to rotate about its respective central axis; and a single screw drum
mounted
to rotate about its central axis, wherein: said central axis of said single
screw drum is
parallel to each respective central axis of said plurality of satellite
screws; said
plurality of satellite screws are arranged within said single screw drum and
at least
partially housed within respective extruder barrels; and each said respective
satellite
screw is configured to rotate about its said respective axis while said single
screw
drum rotates about said central axis of said single screw drum; (D) providing
a
pressure regulation system configured to reduce a pressure within at least a
portion of
said expanded surface area extruder below about 12 mbar; (E) providing a
spinning
machine defining a spinning machine inlet, wherein said spinning machine inlet
is
operatively coupled to said expanded surface area extruder outlet; (F) using
said
pressure regulation system to reduce said pressure within said at least a
portion of said
expanded surface area extruder below about 12 mbar; (G) after passing said
plurality
of flakes consisting essentially of recycled PET through said PET
crystallizer, passing
said plurality of flakes consisting essentially of PET flakes through said
expanded
surface area extruder via said expanded surface area extruder inlet to at
least partially
melt said plurality of flakes to form a polymer melt such that at least a
portion of said
polymer melt passes through each said respective satellite screw; (H)
substantially
immediately after passing said plurality of flakes through said expanded
surface area
2b
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extruder, using said spinning machine to form said polymer melt into bulked
continuous carpet filament.
[004c1 Another aspect of the present disclosure relates to a method of
manufacturing
carpet filament comprising the steps of: (A) grinding a plurality of recycled
PET
bottles into a group of polymer flakes; (B) washing said group of polymer
flakes to
remove at least a portion of one or more contaminants from a surface of said
flakes,
said group of flakes comprising a first plurality of flakes that consist
essentially of
PET and a second plurality of flakes that do not consist essentially of PET;
(C) after
said step of washing said first plurality of flakes: (i) scanning said washed
group of
flakes to identify said second plurality of flakes, (ii) separating said
second plurality
of flakes from said first plurality of flakes; (D) providing a PET
crystallizer;
(E) passing said first plurality of flakes through said PET crystallizer to at
least
partially dry a surface of said first plurality of flakes; (F) providing an
expanded
surface area extruder having an extruder inlet and an extruder outlet and
comprising:
at least four satellite screws wherein each respective satellite screw of the
at least four
satellite screws is mounted to rotate about its respective central axis; and a
single
screw drum mounted to rotate about its central axis, wherein: said central
axis of said
single screw drum is parallel to each respective central axis of said at least
four
satellite screws; said at least four satellite screws are arranged within said
single
screw drum and at least partially housed within respective extruder barrels;
and each
of said at least four satellite screws is configured to rotate about its said
respective
axis while said single screw drum rotates about said central axis of said
single screw
drum; (G) providing a pressure regulation system configured to reduce a
pressure
within said expanded surface area extruder between about 0 mbar and about 5
mbar;
(H) providing a spinning machine having a spinning machine inlet, wherein said

spinning machine inlet is directly coupled to said extruder outlet; (I) using
said
pressure regulation system to reduce said pressure within said expanded
surface area
extruder between about 0 mbar and about 5 mbar; (J) while maintaining said
pressure
within said expanded surface area extruder between about 0 mbar about 5 mbar,
passing said first plurality of flakes through said expanded surface area
extruder via
said fist inlet; (K) melting said first plurality of flakes using said
expanded surface
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area extruder to produce a polymer melt so that at least a portion of said
polymer melt
passes through each of said at least four satellite screws; and (L)
substantially
immediately after passing said second plurality of flakes through said
expanded
surface area extruder, spinning said polymer melt into bulked continuous
carpet
filament using said spinning machine.
BRIEF DESCRIPTION OF THE DRAWINGS
[005] Having described various embodiments in general terms, reference will
now
be made to the accompanying drawings, which are not necessarily drawn to
scale, and
wherein:
[006] FIG. 1 depicts a process flow, according to a particular embodiment,
for
manufacturing bulked continuous carpet filament.
[007] FIG. 2 is a perspective view of an MRS extruder that is suitable for
use in the
process of FIG. 1.
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1024-02006-PCT PPH
[008] FIG. 3 is a cross-sectional view of an exemplary MRS section of the
MRS extruder of FIG.
2.
[009] FIG. 4 depicts a process flow depicting the flow of polymer through
an MRS extruder and
filtration system according to a particular embodiment.
[0010] FIG. 5 is a high-level flow chart of a method, according to
various embodiments, of
manufacturing bulked continuous carpet filament.
DETAILED DESCRIPTION OF VARIOUS EMBODIMENTS
[0011] Various embodiments will now be described in greater detail. It
should be understood that
the invention may be embodied in many different forms and should not be
construed as limited to
the embodiments set forth herein. Rather, these embodiments are provided so
that this disclosure
will be thorough and complete, and will fully convey the scope of the
invention to those skilled in
the art. Like numbers refer to like elements throughout.
I. Overview
[0012] New processes for making fiber from recycled polymer (e.g.,
recycled PET polymer) are
described below. In various embodiments, this new process: (1) is more
effective than earlier
processes in removing contaminates and water from the recycled polymer; and/or
(2) does not
require the polymer to be melted and cooled as many times as in earlier
processes. In at least one
embodiment, the improved process results in a recycled PET polymer having a
polymer quality
that is high enough that the PET polymer may be used in producing bulked
continuous carpet
filament from 100% recycled PET content (e.g., 100% from PET obtained from
previously used
PET bottles). In particular embodiments, the recycled PET polymer has an
intrinsic viscosity of
at least about 0.79 dL/g (e.g., of between about 0.79 dL/g and about 1.00
dL/g).
II. More Detailed Discussion
[00131 A BCF (bulked continuous filament) manufacturing process,
according to a particular
embodiment, may generally be broken down into three steps: (1) preparing
flakes of PET polymer
from post-consumer bottles for use in the process; (2) passing the flakes
through an extruder that
melts the flakes and purifies the resulting PET polymer; and (3) feeding the
purified polymer into
a spinning machine that turns the polymer into filament for use in
manufacturing carpets. These
three steps are described in greater detail below.
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1024-02006-PCT PPH
STEP 1: Preparing Flakes of PET Polymer from Post-Consumer Bottles
[0014] In a
particular embodiment, the step of preparing flakes of PET polymer from post-
consumer bottles comprises: (A) sorting post-consumer PET bottles and grinding
the bottles into
flakes; (B) washing the flakes; and (C) identifying and removing any
impurities or impure flakes.
A. Sorting Post-Consumer PET bottles and Grinding the Bottles into Flakes
[0015] In particular embodiments, bales of clear and mixed colored
recycled post-consumer (e.g.,
"curbside") PET bottles (or other containers) obtained from various recycling
facilities make-up
the post-consumer PET containers for use in the process. In other embodiments,
the source of the
post-consumer PET containers may be returned 'deposit' bottles (e.g., PET
bottles whose price
includes a deposit that is returned to a customer when the customer returns
the bottle after
consuming the bottle's contents). The curbside or returned "post-consumer" or
"recycled"
containers may contain a small level of non-PET contaminates. The contaminants
in the containers
may include, for example, non-PET polymeric contaminants (e.g., PVC, PLA, PP,
PE, PS, PA,
etc.), metal (e.g., ferrous and non-ferrous metal), paper, cardboard, sand,
glass or other unwanted
materials that may find their way into the collection of recycled PET. The non-
PET contaminants
may be removed from the desired PET components, for example, through one or
more of the
various processes described below.
[0016] In particular embodiments, smaller components and debris (e.g.,
components and debris
greater than 2 inches in size) are removed from the whole bottles via a
rotating trammel. Various
metal removal magnets and eddy current systems may be incorporated into the
process to remove
any metal contaminants. Near Infra-Red optical sorting equipment such as the
NRT Multi Sort IR
machine from Bulk Handling Systems Company of Eugene, Oregon, or the Spyder IR
machine
from National Recovery Technologies of Nashville, Tennessee, may be utilized
to remove any
loose polymeric contaminants that may be mixed in with the PET flakes (e.g.,
PVC, PLA, PP, PE,
PS, and PA). Additionally, automated X-ray sorting equipment such as a
VINYLCYCLE machine
from National Recovery Technologies of Nashville, Tennessee may be utilized to
remove
remaining PVC contaminants.
[0017] In particular embodiments, a binary segregation of the clear
materials from the colored
materials is achieved using automated color sorting equipment equipped with a
camera detection
system (e.g., an Multisort ES machine from National Recovery Technologies of
Nashville,
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Tennessee). In various embodiments, manual sorters are stationed at various
points on the line to
remove contaminants not removed by the sorter and any colored bottles. In
particular
embodiments, the sorted material is taken through a granulation step (e.g.,
using a 50B Granulator
machine from Cumberland Engineering Corporation of New Berlin, Wisconsin) to
size reduce
(e.g., grind) the bottles down to a size of less than one half of an inch. In
various embodiments,
the bottle labels are removed from the resultant "dirty flake" (e.g., the PET
flakes formed during
the granulation step) via an air separation system prior to entering the wash
process.
B. Washing the Flakes
[0018] In particular embodiments, the "dirty flake" is then mixed into
a series of wash tanks. As
part of the wash process, in various embodiments, an aqueous density
separation is utilized to
separate the olefin bottle caps (which may, for example, be present in the
"dirty flake" as remnants
from recycled PET bottles) from the higher specific gravity PET flakes. In
particular
embodiments, the flakes are washed in a heated caustic bath to about 190
degrees Fahrenheit. In
particular embodiments, the caustic bath is maintained at a concentration of
between about 0.6%
and about 1.2% sodium hydroxide. In various embodiments, soap surfactants as
well as defoaming
agents are added to the caustic bath, for example, to further increase the
separation and cleaning
of the flakes. A double rinse system then washes the caustic from the flakes.
[0019] In various embodiments, the flake is centrifugally dewatered and
then dried with hot air to
at least substantially remove any surface moisture. The resultant "clean
flake" is then processed
through an electrostatic separation system (e.g., an electrostatic separator
from Carpco, Inc. of
Jacksonville, Florida) and a flake metal detection system (e.g., an MSS Metal
Sorting System) to
further remove any metal contaminants that remain in the flake. In particular
embodiments, an air
separation step removes any remaining label from the clean flake. In various
embodiments, the
flake is then taken through a flake color sorting step (e.g., using an OPTIMIX
machine from TSM
Control Systems of Dundalk, Ireland) to remove any remaining color
contaminants remaining in
the flake. In various embodiments, an electro-optical flake sorter based at
least in part on Raman
technology (e.g., a Powersort 200 from Unisensor Sensorsysteme GmbH of
Karlsruhe, Germany)
performs the final polymer separation to remove any non-PET polymers remaining
in the flake.
This step may also further remove any remaining metal contaminants and color
contaminants.
[0020] In various embodiments, the combination of these steps delivers
substantially clean (e.g.,
clean) PET bottle flake comprising less than about 50 parts per million PVC
(e.g., 25 ppm PVC)
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and less than about 15 parts per million metals for use in the downstream
extrusion process
described below.
C. Identifying and Removing Impurities and Impure Flakes
[0021] In particular embodiments, after the flakes are washed, they are
fed down a conveyor and
scanned with a high-speed laser system 300. In various embodiments, particular
lasers that make
up the high-speed laser system 300 are configured to detect the presence of
particular contaminates
(e.g., PVC or Aluminum). Flakes that are identified as not consisting
essentially of PET may be
blown from the main stream of flakes with air jets. In various embodiments,
the resulting level of
non-PET flakes is less than 25 ppm.
[0022] In various embodiments, the system is adapted to ensure that the
PET polymer being
processed into filament is substantially free of water (e.g., entirely free of
water). In a particular
embodiment, the flakes are placed into a pre-conditioner for between about 20
and about 40
minutes (e.g., about 30 minutes) during which the pre-conditioner blows the
surface water off of
the flakes. In particular embodiments, interstitial water remains within the
flakes. In various
embodiments, these "wet" flakes (e.g., flakes comprising interstitial water)
may then be fed into
an extruder (e.g., as described in Step 2 below), which includes a vacuum
setup designed to remove
- among other things - the interstitial water that remains present in the
flakes following the quick-
drying process described above.
STEP 2: Using an Extrusion System to Melt and Purify PET Flakes
[0023] In particular embodiments, an extruder is used to turn the wet
flakes described above into
a molten recycled PET polymer and to perform a number of purification
processes to prepare the
polymer to be turned into BCF for carpet. As noted above, in various
embodiments, after STEP 1
is complete, the recycled PET polymer flakes are wet (e.g., surface water is
substantially removed
(e.g., fully removed) from the flakes, but interstitial water remains in the
flakes). In particular
embodiments, these wet flakes are fed into a Multiple Rotating Screw ("MRS")
extruder 400. In
other embodiments, the wet flakes are fed into any other suitable extruder
(e.g., a twin screw
extruder, a multiple screw extruder, a planetary extruder, or any other
suitable extrusion system).
An exemplary MRS Extruder 400 is shown in Figures 2 and 3. A particular
example of such an
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MRS extruder is described in U.S. Published Patent Application 2005/0047267,
entitled "Extruder
for Producing Molten Plastic Materials", which was published on March 3, 2005.
[0024] As may be understood from this figure, in particular
embodiments, the MRS extruder
includes a first single-screw extruder section 410 for feeding material into
an MRS section 420
and a second single-screw extruder section 440 for transporting material away
from the MRS
section.
[0025] In various embodiments, the wet flakes are fed directly into the
MRS extruder 400
substantially immediately (e.g., immediately) following the washing step
described above (e.g.,
without drying the flakes or allowing the flakes to dry). In particular
embodiments, a system that
feeds the wet flakes directly into the MRS Extruder 400 substantially
immediately (e.g.,
immediately) following the washing step described above may consume about 20%
less energy
than a system that substantially fully pre-dries the flakes before extrusion
(e.g., a system that pre-
dries the flakes by passing hot air over the wet flakes for a prolonged period
of time). In various
embodiments, a system that feeds the wet flakes directly into the MRS Extruder
400 substantially
immediately (e.g., immediately) following the washing step described above
avoids the need to
wait a period of time (e.g., up to eight hours) generally required to fully
dry the flakes (e.g., remove
all of the surface and interstitial water from the flakes).
[0026] Figure 4 depicts a process flow that illustrates the various
processes performed by the MRS
Extruder 400 in a particular embodiment. In the embodiment shown in this
figure, the wet flakes
are first fed through the MRS extruder's first single-screw extruder section
410, which may, for
example, generate sufficient heat (e.g., via shearing) to at least
substantially melt (e.g., melt) the
wet flakes.
[0027] The resultant polymer melt (e.g., comprising the melted flakes),
in various embodiments,
is then fed into the extruder's MRS section 420, in which the extruder
separates the melt flow into
a plurality of different streams (e.g., 4, 6, 8, or more streams) through a
plurality of open chambers.
Figure 3 shows a detailed cutaway view of an MRS Section 420 according to a
particular
embodiment. In particular embodiments, such as the embodiment shown in this
figure, the MRS
Section 420 separates the melt flow into eight different streams, which are
subsequently fed
through eight satellite screws 425A-H. As may be understood from Figure 2, in
particular
embodiments, these satellite screws are substantially parallel (e.g.,
parallel) to one other and to a
primary screw axis of the MRS Machine 400.
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[0028] In
the MRS section 420, in various embodiments, the satellite screws 425A-II may,
for
example, rotate faster than (e.g., about four times faster than) in previous
systems. As shown in
Figure 3, in particular embodiments: (1) the satellite screws 425A-H are
arranged within a single
screw drum 428 that is mounted to rotate about its central axis; and (2) the
satellite screws 425A-
H are configured to rotate in a direction that is opposite to the direction in
which the single screw
drum rotates 428. In various other embodiments, the satellite screws 425A-H
and the single screw
drum 428 rotate in the same direction. In particular embodiments, the rotation
of the satellite
screws 425A-J1 is driven by a ring gear. Also, in various embodiments, the
single screw drum 428
rotates about four times faster than each individual satellite screw 425A-H.
In certain
embodiments, the satellite screws 425A-H rotate at substantially similar
(e.g., the same) speeds.
[0029] In various embodiments, as may be understood from Figure 4, the
satellite screws 425A-
H are housed within respective extruder barrels, which may, for example be
about 30% open to
the outer chamber of the MRS section 420. In particular embodiments, the
rotation of the satellite
screws 425A-H and single screw drum 428 increases the surface exchange of the
polymer melt
(e.g., exposes more surface area of the melted polymer to the open chamber
than in previous
systems). In various embodiments, the MRS section 420 creates a melt surface
area that is, for
example, between about twenty and about thirty times greater than the melt
surface area created
by a co-rotating twin screw extruder. In a particular embodiment, the MRS
section 420 creates a
melt surface area that is, for example, about twenty five times greater than
the melt surface area
created by a co-rotating twin screw extruder
[0030] In various embodiments, the MRS extruder's MRS Section 420 is
fitted with a Vacuum
Pump 430 that is attached to a vacuum attachment portion 422 of the MRS
section 420 so that the
Vacuum Pump 430 is in communication with the interior of the MRS section via a
suitable opening
424 in the MRS section's housing. In still other embodiments, the MRS Section
420 is fitted with
a series of Vacuum Pumps. In particular embodiments, the Vacuum Pump 430 is
configured to
reduce the pressure within the interior of the MRS Section 420 to a pressure
that is between about
0.5 millibars and about 5 millibars. In particular embodiments, the Vacuum
Pump 430 is
configured to reduce the pressure in the MRS Section 420 to less than about
1.5 millibars (e.g.,
about 1 millibar or less). The low-pressure vacuum created by the Vacuum Pump
430 in the MRS
Section 420 may remove, for example: (1) volatile organics present in the
melted polymer as the
melted polymer passes through the MRS Section 420; and/or (2) at least a
portion of any interstitial
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water that was present in the wet flakes when the wet flakes entered the MRS
Extruder 400. In
various embodiments, the low-pressure vacuum removes substantially all (e.g.,
all) of the water
and contaminants from the polymer stream.
[0031] In a particular example, the Vacuum Pump 430 comprises three
mechanical lobe vacuum
pumps (e.g., arranged in series) to reduce the pressure in the chamber to a
suitable level (e.g., to a
pressure of about 1.0 millibar). In other embodiments, rather than the three
mechanical lobe
vacuum pump arrangement discussed above, the Vacuum Pump 430 includes a jet
vacuum pump
fit to the MRS extruder. In various embodiments, the jet vacuum pump is
configured to achieve
about 1 millibar of pressure in the interior of the MRS section 420 and about
the same results
described above regarding a resulting intrinsic viscosity of the polymer melt.
In various
embodiments, using a jet vacuum pump can be advantageous because jet vacuum
pumps are steam
powered and therefore substantially self-cleaning (e.g., self-cleaning),
thereby reducing the
maintenance required in comparison to mechanical lobe pumps (which may, for
example, require
repeated cleaning due to volatiles coming off and condensing on the lobes of
the pump). In a
particular embodiment, the Vacuum Pump 430 is a jet vacuum pump is made by
Arpuma GmbH
of Bergheim, Germany.
[0032] In particular embodiments, after the molten polymer is run the
through the multi-stream
MRS Section 420, the streams of molten polymer are recombined and flow into
the MRS
extruder's second single screw section 440. In various embodiments, the single
stream of molten
polymer is next run through a filtration system 450 that includes at least one
filter. In a particular
embodiment, the filtration system 450 includes two levels of filtration (e.g.,
a 40 micron screen
filter followed by a 25 micron screen filter). Although, in various
embodiments, water and volatile
organic impurities are removed during the vacuum process as discussed above,
particulate
contaminates such as, for example, aluminum particles, sand, dirt, and other
contaminants may
remain in the polymer melt. Thus, this filtration step may be advantageous in
removing particulate
contaminates (e.g., particulate contaminates that were not removed in the MRS
Section 420).
[0033] In particular embodiments, a viscosity sensor 460 (see Figure 4)
is used to sense the melt
viscosity of the molten polymer stream following its passage through the
filtration system 450. In
various embodiments, the viscosity sensor 460, measures the melt viscosity of
the stream, for
example, by measuring the stream's pressure drop across a known area. In
particular
embodiments, in response to measuring an intrinsic viscosity of the stream
that is below a
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predetermined level (e.g., below about 0.8 g/dL), the system may: (1) discard
the portion of the
stream with low intrinsic viscosity; and/or (2) lower the pressure in the MRS
Section 420 in order
to achieve a higher intrinsic viscosity in the polymer melt. In particular
embodiments, decreasing
the pressure in the MRS Section 420 is executed in a substantially automated
manner (e.g.,
automatically) using the viscosity sensor in a computer-controlled feedback
control loop with the
vacuum section 430.
100341 In particular embodiments, removing the water and contaminates
from the polymer
improves the intrinsic viscosity of the recycled PET polymer by allowing
polymer chains in the
polymer to reconnect and extend the chain length. In particular embodiments,
following its
passage through the MRS Section 420 with its attached Vacuum Pump 430, the
recycled polymer
melt has an intrinsic viscosity of at least about 0.79 dL/g (e.g., of between
about 0.79 dL/g and
about 1.00 dL/g). In particular embodiments, passage through the low pressure
MRS Section 420
purifies the recycled polymer melt (e.g., by removing the contaminants and
interstitial water) and
makes the recycled polymer substantially structurally similar to (e.g.,
structurally the same as) pure
virgin PET polymer. In particular embodiments, the water removed by the vacuum
includes both
water from the wash water used to clean the recycled PET bottles as described
above, as well as
from unreacted water generated by the melting of the PET polymer in the single
screw heater 410
(e.g., interstitial water). In particular embodiments, the majority of water
present in the polymer
is wash water, but some percentage may be unreacted water.
100351 In particular embodiments, the resulting polymer is a recycled
PET polymer (e.g., obtained
100% from post-consumer PET products, such as PET bottles or containers)
having a polymer
quality that is suitable for use in producing PET carpet filament using
substantially only (e.g.,
only) PET from recycled PET products.
Step 3: Purified PET Polymer Fed into Spinning Machine to be Turned into
Carpet Yarn
[00361 In particular embodiments, after the recycled PET polymer has
been extruded and purified
by the above-described extrusion process, the resulting molten recycled PET
polymer is fed
directly into a BCF (or "spinning") machine 500 that is configured to turn the
molten polymer into
bulked continuous filament. For example, in various embodiments, the output of
the MRS extruder
400 is connected substantially directly (e.g., directly) to the input of the
spinning machine 500 so
that molten polymer from the extruder is fed directly into the spinning
machine 500. This process
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may be advantageous because molten polymer may, in certain embodiments, not
need to be cooled
into pellets after extrusion (as it would need to be if the recycled polymer
were being mixed with
virgin PET polymer). In particular embodiments, not cooling the recycled
molten polymer into
pellets serves to avoid potential chain scission in the polymer that might
lower the polymer's
intrinsic viscosity.
[0037] In particular embodiments, the spinning machine 500 extrudes
molten polymer through
small holes in a spinneret in order to produce carpet yarn filament from the
polymer. In particular
embodiments, the molten recycled PET polymer cools after leaving the
spinneret. The carpet yarn
is then taken up by rollers and ultimately turned into filaments that are used
to produce carpet. In
various embodiments, the carpet yarn produced by the spinning machine 500 may
have a tenacity
between about 3 gram-force per unit denier (gf/den) and about 9 gf/den. In
particular
embodiments, the resulting carpet yarn has a tenacity of at least about 3
gf/den.
[0038] In particular embodiments, the spinning machine 500 used in the
process described above
is the Sytec One spinning machine manufactured by Oerlika Neumag of
Neumuenster, Germany.
The Sytec One machine may be especially adapted for hard-to-run fibers, such
as nylon or solution-
dyed fibers, where the filaments are prone to breakage during processing. In
various embodiments,
the Sytec One machine keeps the runs downstream of the spinneret as straight
as possible, uses
only one threadline, and is designed to be quick to rethread when there are
filament breaks.
[0039] Although the example described above describes using the Sytec
One spinning machine to
produce carpet yarn filament from the polymer, it should be understood that
any other suitable
spinning machine may be used. Such spinning machines may include, for example,
any suitable
one-threadline or three-threadline spinning machine made by Oerlika Neumag of
Neumuenster,
Germany or any other company.
[0040] In various embodiments, the improved strength of the recycled
PET polymer generated
using the process above allows it to be run at higher speeds through the
spinning machine 500 than
would be possible using pure virgin PET polymer. This may allow for higher
processing speeds
than are possible when using virgin PET polymer.
Summary of Exemplary Process
[0041] Figure 5 provides a high-level summary of the method of
manufacturing bulked continuous
filament described above. As shown in the figure, the method begins at Step
602, where recycled
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PET bottles are ground into a group of flakes. Next, at Step 604, the group of
flakes is washed to
remove contaminants from the flakes' respective outer surfaces.. Next, at Step
606, the group of
flakes is scanned (e.g., using one or more of the methods discussed above) to
identify impurities,
including impure flakes. These impurities, and impure flakes, are then removed
from the group of
flakes.
[0042] Next, at Step 608, the group of flakes is passed through an MRS
extruder while maintaining
the pressure within an MRS portion of the extruder below about 1.5 millibars.
At Step 610, the
resulting polymer melt is passed through at least one filter having a micron
rating of less than about
50 microns. Finally, at Step 612, the recycled polymer is formed into bulked
continuous carpet
filament, which may be used in producing carpet. The method then ends at Step
614.
Alternative Embodiments
[0043] In particular embodiments, the system may comprise alternative
components or perform
alternative processes in order to produce substantially continuous BCF from
100% recycled PET,
or other recycled polymer. Exemplary alternatives are discussed below.
Non-MRS Extrusion System
[0044] In particular embodiments, the process may utilize a polymer
flow extrusion system other
than the MRS Extruder described above. The alternative extrusion system may
include for
example, a twin screw extruder, a multiple screw extruder, a planetary
extruder, or any other
suitable extrusion system. In a particular embodiment, the process may include
a plurality of any
combination of any suitable conical screw extruders (e.g., four twin screw
extruders, three multiple
screw extruders, etc.).
Making Carpet Yarn from 100% Recycled Carpet
[0045] In particular embodiments, the process described above may be
adapted for processing and
preparing old carpet (or any other suitable post-consumer product) to produce
new carpet yarn
comprising 100% recycled carpet. In such embodiments, the process would begin
by grinding and
washing recycled carpet rather than recycled PET bottles. In various
embodiments where old
carpet is converted into new carpet yarn comprising 100% recycled carpet, the
process may
comprise additional steps to remove additional materials or impurities that
may be present in
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recycled carpet that may not be present in recycled PET bottles (e.g., carpet
backing, adhesive,
etc.).
Other Sources of Recycled PET
[0046] In various embodiments, the process described above is adapted
for processing recycled
PET from any suitable source (e.g., sources other than recycled bottles or
carpet) to produce new
carpet yarn comprising 100% recycled PET.
The Use of a Crystallizer as Part of BCF Process
[0047] In various embodiments, the process for producing recycled BCF
may further include a
crystallizing step that utilizes one or more PET crystallizers. In particular
embodiments, the
system is configured to perform the crystallization step on the ground flakes
prior to running the
flakes through the one or more extruders (e.g., single screw extruder, MRS
extruder, etc.). In
particular embodiments, the PET crystallizer comprises a housing, a hopper
screw (e.g., an auger)
disposed at least partially within the housing, a stirring apparatus, one or
more heating elements,
and one or more blowers.
Hopper Screw
[0048] In particular embodiments, the hopper screw comprises any
suitable screw conveyor (e.g.,
such as an Archimedes' screw) for moving liquid or granular materials (e.g.,
such as PET flakes).
In various embodiments, the hopper screw comprises a substantially cylindrical
shaft and a helical
screw blade disposed along at least a portion of the cylindrical shaft. In
particular embodiments,
the substantially cylindrical shaft is configured to rotate the screw blade,
causing that hopper screw
to move material (e.g., the PET flakes) along the cylindrical shaft and into
the crystallizer housing.
In other embodiments, the hopper screw comprises any other suitable screw
conveyer such as, for
example, a shaftless spiral. In embodiments in which the hopper screw
comprises a shaftless spiral,
the shaftless spiral may be substantially fixed at one end and free at the
other end and configured
to be driven at the fixed end. In various embodiments, the hopper screw is
disposed at least
partially within the crystallizer housing.
[0049] In various embodiments, the hopper screw is configured to feed
PET flakes into the
crystallizer. In various embodiments, the PET crystallizer is configured to
feed the PET flakes
into the crystallizer using the hopper screw relatively slowly.
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One or More Heating Elements
[0050] In various embodiments, the crystallizer comprises one or more
heating elements for
raising a temperature within the crystallizer. In particular embodiments, the
one or more heating
elements comprise one or more electric heating elements, one or more gas-fired
heating elements,
or any other suitable heating elements. In some embodiments, the one or more
heating elements
may be substantially electrically powered. In various embodiments, the one or
more heating
elements comprise one or more infra-red heating elements. In other
embodiments, the one or more
heating elements may utilize natural gas such, for example, propane. In
particular embodiments,
the one or more heating elements are configured to raise a temperature within
the crystallizer to
between about 100 degrees Fahrenheit and about 180 degrees Fahrenheit. In
still other
embodiments, the one or more heating elements are configured to raise a
temperature within the
crystallizer to between about 100 degrees Celsius and 180 degrees Celsius. In
some embodiments,
the one or more heating elements are configured to maintain a temperature
within the crystallizer
that is substantially about a maximum crystallization temperature of PET. In
particular
embodiments, the maximum crystallization temperature of PET is between about
140 degrees
Celsius and about 230 degrees Celsius.
One or More Blowers
[0051] In various embodiments, the crystallizer further comprises one
or more blowers configured
to blow air over the flakes as the flakes passes through the crystallizer. In
particular embodiments,
the one or more blowers comprise any suitable blowers for moving air
substantially across a
surface area of the flakes as the flakes pass through the crystallizer. For
example, in some
embodiments, the one or more blowers comprise one or more suitable fans or
other suitable
mechanisms for moving air. In various embodiments, the one or more blowers are
configured to
blow air that has been at least partially heated by the one or more heating
elements. In particular
embodiments, the one or more blowers are configured to blow air having a
temperature of at least
about 140 degree Fahrenheit. In another particular embodiments, the one or
more blowers are
configured to blow air having a temperature of at least about 140 degree
Celsius. In other
embodiments, the one or more blowers are configured to maintain the
temperature in the
crystallizer between about 140 degrees Fahrenheit and about 180 degrees
Fahrenheit. In some
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embodiments, the one or more blowers are configured to blow hot air from a
bottom portion of the
crystallizer and draw air from an upper portion of the crystallizer.
Stirring Apparatus
[0052] In various embodiments, the crystallizer comprises a stirring
apparatus that comprises any
suitable apparatus for stirring the PET flakes while the PET flakes are
passing through the
crystallizer. In various embodiments, the stirring apparatus may be operated,
for example, by any
suitable gear motor. In a particular embodiment, the stirring apparatus
comprises a suitable rod or
other suitable mechanism mounted to rotate, or otherwise stir the PET flakes
as the PET flakes are
passing through the crystallizer. In other embodiments, the stirring apparatus
may comprise any
suitable tumbler, which may, for example, comprise a drum mounted to rotate
via the gear mother
such that the PET flakes are at least partially stirred and/or agitated while
the PET flakes are within
the drum. In still other embodiments, the stirring apparatus comprises one or
more screws and/or
augers configured to rotate and stir the PET flakes. In particular
embodiments, the stirring
apparatus comprises the hopper screw.
[0053] As may be understood from this disclosure, the stirring
apparatus is configured to agitate
or stir the PET flakes as the one or more blowers blow air heated by the one
or more heating
elements across the PET flakes. In particular embodiments, the stirring
apparatus is configured to
at least partially reduce agglomeration (e.g., sticking or clumping of the
flake) while the flake is
at least partially crystallizing in the crystallizer.
100541 In particular embodiments, the crystallizer at least partially
dries the surface of the PET
flakes. In various embodiments, the PET crystallizer is configured to reduce a
moisture content
of the PET flakes to about 50 ppm. In other embodiments the PET crystallizer
is configured to
reduce a moisture content of the PET flakes to between about 30 and about 50
ppm.
100551 In various embodiments, the use of drier flakes may enable the
system to run the flakes
through the MRS extruder more slowly, which may allow for higher pressure
within the MRS
extruder during extrusion (e.g., may enable the system to maintain a higher
pressure within the
MRS extruder, rather than very low pressure). In various embodiments of the
process, the pressure
regulation system may be configured to maintain a pressure within the MRS
extruder of between
about 0 millibars and about 25 millibars. In particular embodiments, such as
embodiments in
which the PET flakes have been run through a crystallizer before being
extruded in the MRS
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extruder, the pressure regulation system may be configured to maintain a
pressure within the MRS
extruder of between about 0 and about 18 millibars. In other embodiments, the
pressure regulation
system may be configured to maintain a pressure within the MRS extruder
between about 0 and
about 12 millibars. In still other embodiments, the pressure regulation system
may be configured
to maintain a pressure within the MRS extruder between about 0 and about 8
millibars. In still
other embodiments, the pressure regulation system may be configured to
maintain a pressure
within the MRS extruder between about 5 millibars and about 10 millibars. In
particular
embodiments, the pressure regulation system may be configured to maintain a
pressure within the
MRS extruder at about 5 millibars, about 6 millibars, about 7 millibars, about
8 millibars, about 9
millibars, or about any suitable pressure between about 0 millibars and about
25 millibars.
[00561 In particular embodiments, the crystallizer causes the flakes to
at least partially reduce in
size, which may, for example, reduce a potential for the flakes to stick
together. In particular
embodiments, the crystallizer may particularly reduce stickiness of larger
flakes, which may, for
example, include flakes comprising portions of the ground PET bottles which
may be thicker than
other portions of the PET bottles (e.g., flakes ground from a threaded portion
of the PET bottle on
which a cap would typically be screwed).
Use of Curbside Recycling v. Deposit Bottles in Process
[0057] In various embodiments, the system is configured to utilize
recycled PET of varying quality
in the process described above. For example, in various embodiments, the
system is configured
to produce bulked continuous carpet filament from PET derived from PET bottles
sourced from
curbside recycling sources (e.g., PET bottles that were collected as part of a
general bulk recycling
program or other recycling source) as well as deposit PET bottles (e.g.,
bottles returned as part of
a deposit program). In various embodiments, Curbside recycled bottles may
require more
thorough processing in order to produce bulked continuous filament, as
curbside recycled PET
bottles may be mixed in with and otherwise include contaminants such as, for
example: other
recyclable goods (e.g., paper, other plastics, etc.), garbage, and other non-
PET bottle items due to
imperfect sorting of recycled goods or for any other reason. Deposit PET
bottles may include PET
bottles with fewer unwanted contaminants due in part because deposit PET
bottles may be
collected separately from other recyclable or disposable goods.
16
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[0058] In
various embodiments, curbside recycled PET bottles acquired during particular
times of
year may include more impurities and other contaminants than at other times of
the year. For
example, curbside recycled PET bottles collected during summer months may
comprise a higher
percentage of clear PET bottles (e.g., water bottles) at least in part due to
additional water
consumption during summer months.
[0059] In various embodiments, the system described above may be
configured to adjust particular
components of the process based at least in part on the source of recycled PET
being used to
produce the bulked continuous carpet filament. For example, because deposit
PET bottles include
fewer impurities that need to be removed during the initial cleaning and
sorting phases of the
process, the pressure regulation system may be configured to maintain a
pressure within the MRS
extruder that is higher than a pressure that it would be configured to
maintain for PET flake derived
from curbside recycled PET bottles. In a particular embodiment, the pressure
regulation system
may be configured to maintain a pressure within the MRS extruder of between
about 0 millibars
and about 12 millibars when flakes derived from deposit PET bottles are
passing through the MRS
extruder. In still other embodiments, the pressure regulation system may be
configured to maintain
a pressure within the MRS extruder of between about 5 millibars and about 10
millibars in such
instances.
[0060] In various embodiments, the system is configured to determine a
suitable pressure at which
to maintain the pressure within the MRS extruder based at least in part on the
source of the recycled
PET. in other embodiments, the system is configured to omit one or more of the
steps above or
include one or more additional steps to the steps described above based at
least in part on the source
of the recycled PET.
Direct Coupling of Various Process Components
Direct Coupling of MRS Extruder to Spinning Machine
[0061] In particular embodiments, the output of the MRS machine may be
substantially directly
coupled (e.g., directly coupled) to a spinning machine for forming the
resulting molten polymer
into bulked continuous filament. In such embodiments, after the recycled PET
polymer has been
extruded and purified by the above-described extrusion process, the resulting
molten recycled PET
polymer is fed substantially directly (e.g., directly) into the spinning
machine. This process may
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1024-02006-PCT PPH
be advantageous because molten polymer may, in certain embodiments, not need
to be cooled into
pellets after extrusion (as it would need to be if the recycled polymer were
being mixed with virgin
PET polymer) prior to spinning the molten polymer into filament. In particular
embodiments, not
cooling the recycled molten polymer into pellets serves to avoid potential
chain scission in the
polymer that might lower the polymer's intrinsic viscosity.
Direct Coupling of Non-MRS Extruder to Spinning Machine
[0062] In various embodiments of the process for recycling PET (e.g.,
or other polymers) into
BCF, the recycled PET flakes are passed through an extruder other than an MRS
extruder (e.g., a
"first extruder") prior to spinning the resultant molten polymer into BCF. In
particular
embodiments, the first extruder is substantially directly coupled (e.g.,
directly coupled) to the
spinning machine (e.g., an outlet of the first extruder is substantially
directly coupled to an inlet of
the spinning machine). For example, in various embodiments, an outlet of the
first extruder is
substantially directly coupled (e.g., via a suitable pipe, connector, etc.) to
one or more inlets of one
or more spinning machines. In particular embodiments, the first extruder may
include any suitable
expanded surface area extruder. In various embodiments, the first extruder may
include, for
example, a twin screw extruder, a multiple screw extruder, a planetary
extruder, or any other
suitable extrusion system (e.g., any other suitable expanded surface area
extruder). In various
embodiments, the first extruder is any suitable extruder for increasing an
amount of surface area
of a polymer melt being extruded by the first extruder that is exposed to a
low pressure within the
first extruder (e.g., a low pressure caused by a pressure regulation system,
such as any suitable
pressure regulation system described above). In a particular embodiment, the
first extruder is an
MAS extruder manufactured by Maschinen und Anlagenbau Schulz GmbH of Pucking,
Austria.
[0063] In various embodiments, the first extruder is a conical co-
rotating twin screw extruder. In
such embodiments, the first extruder comprises an extruder housing in which
two, co-rotating
conical screws are disposed (e.g., a first conical screw and a second conical
screw). In various
embodiments, each conical screw is substantially conical (e.g., conical) such
that the screw
narrows from a first diameter at a base end of each respective conical screw
to a second diameter
at a vertex end of each respective conical screw that is less than the first
diameter. In various
embodiments, each particular conical screw may have any suitable thread or
threading. In some
embodiments, each conical screw has a substantially uniform (e.g., uniform)
thread pitch and
18
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1024-02006-PCT PPH
thread crest along at least a portion of the conical screw. In other
embodiments, thread pitch and
crest may at least partially vary along a length of the particular conical
screw. In still other
embodiments, a difference between a major and minor diameter of the conical
screw may vary
along a length of the conical screw (e.g., the screw thread may be larger or
smaller along particular
portions of the conical screw). In a particular embodiment, the pitch of
thread of a particular
conical screw may decrease along the conical screw from the base portion to
the vertex portion.
In particular embodiments, the first and second conical screws are
substantially structurally
identical (e.g., structurally identical).
[0064] In particular embodiments, the two conical screws are oriented
within the conical twin
screw extruder such that the base portion of each screw is disposed adjacent
an intake (e.g., inlet)
of the conical twin screw extruder, and the vertex portion of each screw is
disposed adjacent an
outlet of the conical twin extruder. In particular embodiments, a central axis
of the first conical
screw forms an acute angle with the central axis of the second conical screw.
In various
embodiments, the first and second conical screws are disposed such that at
least a portion of the
thread of the first conical screw at least partially mates with (e.g., mates
with) at least a portion of
the thread of the second conical screw. In other embodiments, at least a
portion of the thread of
the first conical screw at least partially engages with (e.g., engages with)
at least a portion of the
thread of the second conical screw
10065] In particular embodiments, the conical twin screw extruder may
be configured to at least
partially melt the plurality of flakes into a polymer melt. In such
embodiments, the conical twin
screw extruder may, for example, generate sufficient heat (e.g., via shearing)
to at least
substantially melt (e.g., melt) the flakes. In particular embodiments, the
first extruder is configured
to increase a surface area of the polymer melt. In various embodiments, the
conical design of the
conical twin screw extruder may result in an intake volume that is
substantially greater (e.g.,
greater) than a discharge volume of the conical twin screw extruder. This
higher intake volume,
in various embodiments, may result in a high volume throughput per revolution
of the twin conical
screws. In various embodiments, the first extruder is configured to receive a
plurality of polymer
flakes (e.g., PET flakes) via a first extruder inlet, melt the plurality of
flakes into a polymer melt
while extruding the plurality of flakes, and pass the resulting polymer melt
though an extruder
outlet.
19
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1024-02006-PCT PPH
[0066] In
various embodiments, the first extruder comprises a pressure regulation system
configured to reduce a pressure within the first extruder. In a particular
embodiment, the first
extruder is fitted with a suitable vacuum pump such that the vacuum pump is in
communication
with an interior of the first extruder's housing via a suitable opening in the
first extruder's housing.
In still other embodiments, the first extruder is fitted with a series of
vacuum pumps. In particular
embodiments, the vacuum pump is configured to reduce the pressure within the
interior of the first
extruder to a pressure that is between about Omillibars and about 25
millibars. In other
embodiments, the vacuum pump is configured to reduce a pressure within the
first extruder to
between about 5 millibars and about 18 millibars. In still other embodiments,
the vacuum pump
is configured to reduce a pressure within the first extruder to any particular
suitable pressure
between about 0 millibars and about 25 millibars. In various embodiments, the
low-pressure
vacuum created by the vacuum pump in the first extruder may remove, for
example: (1) volatile
organics present in the melted polymer as the melted polymer passes through
the first extruder;
and/or (2) at least a portion of any interstitial water that was present in
the wet flakes when the wet
flakes entered the first extruder. In various embodiments, the low-pressure
vacuum removes
substantially all (e.g., all) of the water and contaminants from the polymer
stream. In various
embodiments, the vacuum pump may include any suitable vacuum pump, such as any
vacuum
pump described above or any other suitable vacuum pump.
[0067] In embodiments in which the system includes a first extruder
directly coupled to the
spinning machine, the process may include passing the plurality of flakes
(e.g., a plurality of wet
flakes after a washing step) through the first extruder to at least partially
melt the plurality of flakes
into a polymer melt and remove at least a portion of the impurities from the
polymer melt. The
polymer melt is then fed substantially directly (e.g., directly) into the
spinning machine for
spinning into bulked continuous carpet filament.
Conclusion
[0068] Many modifications and other embodiments of the invention will
come to mind to one
skilled in the art to which this invention pertains having the benefit of the
teachings presented in
the foregoing descriptions and the associated drawings. For example, although
the vacuum system
discussed above is described as being configured to maintain the pressure in
the open chambers of
the MRS extruder to about 1 mbar, in other embodiments, the vacuum system may
be adapted to
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1024-02006-PCT PPH
maintain the pressure in the open chambers of the MRS extruder at pressures
greater than, or less
than, 1 mbar. For example, the vacuum system may be adapted to maintain this
pressure at
between about 0.5 mbar and about 12 mbar.
[0069] Similarly, although various embodiments of the systems described
above may be adapted
to produce carpet filament from substantially only recycled PET (so the
resulting carpet filament
would comprise, consist of, and/or consist essentially of recycled PET), in
other embodiments, the
system may be adapted to produce carpet filament from a combination of
recycled PET and virgin
PET. The resulting carpet filament may, for example, comprise, consist of,
and/or consist
essentially of between about 80% and about 100% recycled PET, and between
about 0% and about
20% virgin PET.
[0070] Also, while various embodiments are discussed above in regard to
producing carpet
filament from PET, similar techniques may be used to produce carpet filament
from other
polymers. Similarly, while various embodiments are discussed above in regard
to producing carpet
filament from PET, similar techniques may be used to produce other products
from PET or other
polymers.
[0071] In addition, it should be understood that various embodiments
may omit any of the steps
described above or add additional steps.
[0072] In light of the above, it is to be understood that the invention
is not to be limited to the
specific embodiments disclosed and that modifications and other embodiments
are intended to be
included within the scope of the appended claims. Although specific terms are
employed herein,
they are used in a generic and descriptive sense only and not for the purposes
of limitation.
21
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Representative Drawing
A single figure which represents the drawing illustrating the invention.
Administrative Status

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Administrative Status

Title Date
Forecasted Issue Date 2019-07-30
(86) PCT Filing Date 2015-11-17
(87) PCT Publication Date 2016-05-26
(85) National Entry 2017-05-17
Examination Requested 2018-09-12
(45) Issued 2019-07-30

Abandonment History

There is no abandonment history.

Maintenance Fee

Last Payment of $210.51 was received on 2023-11-10


 Upcoming maintenance fee amounts

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Payment History

Fee Type Anniversary Year Due Date Amount Paid Paid Date
Application Fee $400.00 2017-05-17
Maintenance Fee - Application - New Act 2 2017-11-17 $100.00 2017-11-01
Request for Examination $800.00 2018-09-12
Maintenance Fee - Application - New Act 3 2018-11-19 $100.00 2018-11-14
Registration of a document - section 124 $100.00 2019-05-02
Final Fee $300.00 2019-06-17
Maintenance Fee - Patent - New Act 4 2019-11-18 $100.00 2019-11-08
Maintenance Fee - Patent - New Act 5 2020-11-17 $200.00 2020-11-13
Maintenance Fee - Patent - New Act 6 2021-11-17 $204.00 2021-11-12
Maintenance Fee - Patent - New Act 7 2022-11-17 $203.59 2022-11-11
Maintenance Fee - Patent - New Act 8 2023-11-17 $210.51 2023-11-10
Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
ALADDIN MANUFACTURING CORPORATION
Past Owners on Record
MOHAWK INDUSTRIES, INC.
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Abstract 2017-05-17 1 56
Claims 2017-05-17 6 203
Drawings 2017-05-17 5 93
Description 2017-05-17 21 1,017
Representative Drawing 2017-05-17 1 4
Patent Cooperation Treaty (PCT) 2017-05-17 1 51
International Search Report 2017-05-17 7 355
Amendment - Abstract 2017-05-17 1 16
National Entry Request 2017-05-17 5 132
Cover Page 2017-07-17 1 36
Abstract 2017-05-18 1 16
Description 2018-09-12 21 1,141
Claims 2018-09-12 8 276
PPH OEE 2018-09-12 74 8,269
PPH Request 2018-09-12 37 1,668
Examiner Requisition 2018-09-20 5 274
Refund 2018-12-21 2 55
Office Letter 2019-01-14 1 46
Amendment 2019-03-19 19 795
Description 2019-03-19 25 1,337
Claims 2019-03-19 9 299
Abstract 2019-04-08 1 16
Final Fee 2019-06-17 2 60
Cover Page 2019-07-04 1 36