Note: Descriptions are shown in the official language in which they were submitted.
CA 03011260 2018-07-11
= a
WO 2017/124085 PCT/US2017/013748
CONTINUOUS AND RANDOM REINFORCEMENT IN A 3D PRINTED PART
FIELD
[0001] Aspects relate to three dimensional printing.
BACKGROUND
[0002] "Three dimensional printing" as an art includes various methods such as
Stereolithography (SLA) and Fused Filament Fabrication (FFF). SLA produces
high-resolution
parts, typically not durable or UV-stable, and is used for proof-of-concept
work; while FFF
extrudes through a nozzle successive filament beads of ABS or a similar
polymer.
[0003] In the art of "Composite Lay-up", preimpregnated ("prepreg") composite
sheets of fabric
impregnated with a resin binder are layered into a mold, heated, and cured. In
"Composite
Filament Winding" sticky "tows" including multiple thousands of individual
carbon strands are
wound around a custom mandrel to form a rotationally symmetric part.
[0004] There is no commercial or experimental technique for orienting fiber
during additive
manufacturing to =isotropically improve properties of the finished part.
SUMMARY
[0005] According to one aspect of embodiments of the present invention, a
method for
manufacturing a part may include supplying a continuous/random fiber
reinforced composite
filament including a matrix material, a plurality of axial fiber strands
extending substantially
continuously within the matrix material, and a multiplicity of fiber rods
between 0.2-10 mm long
dispersed throughout the matrix material. The continuous/random fiber
reinforced composite
filament is received in a cutter, and may be cut there. The continuous/random
fiber reinforced
composite filament is received in a nozzle. A dragging force is applied from
the part via the axial
fiber strands but not via the dispersed fiber rods. Pressure is applied with
the nozzle to
continuously spread and fuse the continuous/random fiber reinforced composite
filament into the
part, and also to continuously embed a proportion of the short chopped fiber
rods against
previously deposited portions of the part.
[0006] Alternatively, or in addition, the fiber rods at or near the surface of
a previously deposited
layer of the part may be forced to interact with one or more of a fill
material, matrix material,
1
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
axial fiber strands or neighboring fiber rods. Optionally, the
continuous/random fiber reinforced
composite filament is supplied with fiber rods forming a 1-20% volume fraction
of the
continuous/random fiber reinforced composite filament. The continuous/random
fiber reinforced
composite filament may be supplied with axial fiber strands of a different
material from the fiber
rods, and/or with the axial fiber strands formed from glass and the fiber rods
formed from
carbon. The continuous/random fiber reinforced composite filament may be
supplied with the
fiber rods oriented in random directions, and/or with the fiber rods oriented
at least in part non-
randomly. The continuous/random fiber reinforced composite filament may be
supplied with
fiber rods having an aspect ratio from 20:1 ¨ 200:1, and/or with the fiber
rods including fiber
chopped to 0.05-10 mm length (preferably 0.2 to 2 mm length to be managed in a
slightly larger,
e.g., 0.25 to 2.5 mm diameter, nozzle without clogging).
[0007] Further optionally, the deposition head may be driven to force the
second proportion of
the fiber rods to bridge successive layers of continuous/random fiber
reinforced composite
filament.
[0008] In a further aspect of embodiments of the present invention, a
continuous/random fiber
reinforced composite filament may be supplied similarly with a matrix
material, a plurality of
axial fiber strands extending substantially continuously within the matrix
material, and a
multiplicity of fiber rods between 0.2-10 mm long dispersed throughout the
matrix material, at
least some of the dispersed fiber rods being oriented transversely to the
axial fiber strands. A fill
material may be supplied separately from the continuous/random fiber
reinforced composite
filament, including second dispersed fiber rods between 0.2-10 mm long. The
continuous/random fiber reinforced composite filament may be deposited within
a first region
formed in an outward portion of a part that is closer to an outer wall of the
part than to a centroid
of the part, and the fill material may be deposited within a second region
formed in a portion of
the part that is positioned inward from the first region. Heated pressure may
be applied to
continuously melt and spread the core reinforced filament, and/or to
continuously embed a
proportion of the first dispersed fiber rods against a previously deposited
continuous/random
fiber reinforced composite filament, and/or to continuously embed a proportion
of the first
dispersed fiber rods.
[0009] In a still further aspect of embodiments of the present invention, a
three dimensional
printer for additive manufacturing of a part may include a supply of a
continuous/random fiber
2
CA 03011260 2018-07-11
A
WO 2017/124085 PCT/US2017/013748
reinforced composite filament including a matrix material, a plurality of
axial fiber strands
extending substantially continuously within the matrix material, and a
multiplicity of fiber rods
between 0.2-10 mm long dispersed throughout the matrix material. The printer
may further
include a deposition head including a conduit transitioning to an ironing lip,
a deposition head
drive driving the ironing lip, and a filament drive pushing an upstream
portion of the
continuous/random fiber reinforced composite filament to force an unattached
terminal end of
the filament to exit the conduit at the ironing lip. A controller operatively
connected to the
filament drive and the deposition head drive may drive the deposition head to
spread the
continuous/random fiber reinforced composite filament against previously
deposited portions of
the part to (a) flow the matrix material and a first proportion of the fiber
rods interstitially among
the axial fiber strands, and/or (b) force a second proportion of the fiber
rods against previously
deposited portions of the part.
[0010] In a still yet further aspect of embodiments of the present invention,
a method for
manufacturing a part may include supplying a continuous/random fiber
reinforced composite
filament including a matrix material, a plurality of axial fiber strands
extending substantially
continuously within the matrix material, and a multiplicity of fiber rods
between 0.2-10 mm long
dispersed throughout the matrix material. The continuous/random fiber
reinforced composite
filament may be deposited in successive layers. Pressure may be applied to
continuously spread
and fuse the continuous/random fiber reinforced composite filament to
previously deposited
layers and to continuously embed a proportion of the short chopped fiber rods
against previously
deposited layers. A fiber reinforced preform may be formed by the application
of pressure to
successive layers of continuous/random fiber reinforced composite filament,
and may be inserted
in a mold. The fiber reinforced preform may be overmolded into a fiber
reinforced molding.
[0011] In an additional aspect of embodiments of the present invention, a
continuous fiber
reinforced composite filament may be supplied including a matrix material,
with a plurality of
axial fiber strands extending substantially continuously within the matrix
material. The
continuous fiber reinforced composite may be received in a cutter, and cut
there. The continuous
fiber reinforced composite may be received in a nozzle. Pressure may be
applied to continuously
spread and fuse the continuous/random fiber reinforced composite filament into
the part.
Negative contours may be formed in successive layers of the part, and
continuous reinforcing
columns bridging multiple successive layers of the part inserted through the
negative contours.
3
CA 03011260 2018-07-11
WO 2017/124085 PCT/U52017/013748
BRIEF DESCRIPTION OF THE DRAWINGS
[0012] Fig. IA is a schematic view of a continuous core reinforced filament
deposition and fill
material filament extrusion printer.
[0013] Fig. 1B is a cross-sectional and schematic view of a compound extrusion
and fiber
piinthead assembly.
[0014] Fig. 1C is a close-up cross-section of a fiber printhead assembly and a
set of different
possible compression/consolidation shapes.
[0015] Fig. 1D is a block diagram and schematic representation of a three
dimensional printer as
discussed herein, applicable to all embodiments.
[0016] Figs lE through 1G are cross-sections of 3D printed structures that may
be deposited by
the method and printer of the present disclosure, wherein Fig. 1E shows
continuous/random core
fiber reinforced filament deposited together with polymer, ceramic, or metal
fill material,
deposited by a 3D printer (e.g., FDM, SLA, or other technique); Fig. 1F shows
continuous/random core fiber reinforced filament overmolded with a polymer,
ceramic, or
injection or other molding, or continuous (substantially non-layered or micro-
layered) additive
manufacturing; and Fig. 1G shows continuous/random core fiber reinforced
filament deposited
together and interacting with polymer, ceramic, or metal fill material that
includes a proportion
(e.g., 5-20%) of short (e.g., 1/10 to 2 mm length) chopped fiber (e.g.,
carbon, glass, aramid or the
like).
[0017] Figs. 2A through 2C are schematic representations of a three
dimensional printing system
using a continuous core reinforced filament together with stereolithography or
selective laser
sintering in which Figs. 2A and 2B are schematic views of a continuous core
reinforced filament-
SLA/SLS printer and Fig. 2C is a schematic view of a tacking process.
[0018] Fig. 2D is a schematic representation of a three dimensional printing
system being used to
form multiple layers in a printed circuit board, which may be embedded in a
reinforced molding
as disclosed herein.
[0019] Fig. 2E is a schematic representation of a rotatable printing nozzle
including a following
feeding and compression roller.
[0020] Fig. 2F is a schematic representation of a multi-nozzle three-
dimensional printer.
4
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
[0021] Fig. 2G is a schematic representation of a three dimensional printing
system including a
print arm (e.g., a robot arm having 4 or more degrees of freedom) and
selectable printer heads.
[0022] Fig. 2H is a schematic representation of a multi-element printer head
for use in the
printing system.
[0023] Fig. 3 is a flow chart describing the overall operation of the 3D
printer of Fig 3.
[0024] Figs. 4A-4C show exemplary six-axis shell layup in contrasting
directions.
[0025] Figs. 4D-4G show exemplary weighted distributions of 3D printed
composite lay-up
according to the present embodiments, e.g., to form sandwich panel structures,
to increase
effective moment of inertia.
[0026] Figs. 4H-4J show exemplary weighted distributions of 3D printed
composite lay-up
according to the present embodiments, e.g., to form sandwich panel shell and
fiber cellular
interior structures, using both quasi-isotropic sets of shells or layers and
concentrically
reinforced shells or layers, to increase effective moment of inertia about the
entire surface of the
part as well as increase crushing and torsional resistance.
[0027] Figs. 5A-5D show the structures of Figs. 4A-4D in which the internal
structures are
additively deposited as soluble preforms instead of structural resin (although
in Figs. 5A-5J the
internal resin structures may also be deposited in part or in whole as
structural resin, either solid
or partial, e.g., honeycombed,
[0028] Figs. 5E-5G show the structures of Figs. 4E-4G in which the internal
structures are
additively deposited as soluble preforms instead of structural resin.
[0029] Figs. 5H-5J show the structures of Figs. 411-4J in which some internal
structures are
additively deposited as soluble preforms instead of structural resin.
[0030] Figs. 5K-5L show the structures similar to those in Figs. 4A-4J and 5A-
5J in which some
internal structures are additively deposited as sandwich panels.
[0031] Fig. 5M-5N show structures similar to those of Fig. 51 and 5J, in which
continuous
reinforcing columns bridging layers extend through multiple layers.
[0032] Figs. 50-5Q show the structures of Figs. 5B-5D in which the internal
structures are
additively deposited as non-soluble preforms.
[0033] Figs. 6A and 6B show successive steps in a process of multi-component
composite lay-up
to build an exemplary bicycle frame.
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
[0034] Figs. 6C and 6D show successive steps in a process of additive soluble
preform and
additive continuous fiber reinforcement preform to build an exemplary bicycle
frame.
[0035] Fig. 7A shows crossing points or crossing turns of two fiber swaths in
two forms.
[0036] Figs. 7B-7F shows various crossing turns made about a hole (e.g., a
lace aperture or
through hole), in reinforcement formations of composite swath or multi-swath
track approaches
near the center of the hole and departs beside and parallel to its entry;
approached near a tangent
to the hole and departs from the hole opposite to and parallel to its entry;
and in which a bight,
open loop or touching loop may be made away from the reinforced hole from
which the
reinforcement formation of composite swath or multi-swath track returns toward
the hole.
[0037] Figs. 8A-8D show patch fills and concentric fills that may be used to
fill in reinforcement
regions as disclosed herein.
[0038] Fig. 9 depicts a flowchart for configuring 3D printer controller and/or
slicer controller
operations to permit multi-layer rule handling, e.g., setting rules for groups
of layers or regions
and changing the members of the rule groups.
[0039] Fig. 10A-10C shows an exemplary on-screen part rendering and logic
structure for the
rule propagation procedure of Fig. 9.
[0040] Figs. 11A-11B show schematic representations of a printed part
including reinforced
holes formed therein.
[0041] Fig. 11C shows exemplary composite layup via 3D printing of composite
fibers as
disclosed herein in contrasting directions.
[0042] Fig. 12 shows a multi-layer laminate as Fig. 11C deposited successively
in a tubular form.
[0043] Fig. 13 is a schematic representation of a composite part formed using
three-dimensional
printing methods.
[0044] Fig. 14 is a scanning electron microscope image of a reinforcing carbon
fiber and
perpendicularly arranged carbon nanotubes.
[0045] Fig. 15 shows a composite swath 2c of a reinforcement formation in a
layer LAn
continuously deposited end-to-end with an adjacent reinforcement formation
continuing into the
next layer LAn+i, i.e., without cutting the composite swath 2c as the part 14
is indexed to the next
layer.
DETAILED DESCRIPTION
6
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
[0046] This patent application incorporates the following disclosures by
reference in their
entireties: U.S. Patent Application Serial Nos.: 61/804,235; 61/815,531;
61/831,600; 61/847,113;
61/878,029; 61/880,129; 61/881,946; 61/883,440; 61/902,256; 61/907,431;
62/080,890,
62/172,021; 14/222,318; 14/297,437; 14/333,881 and 14/491,439 which may be
referred to
herein as "Composite Filament Fabrication patent applications" or "CFF patent
applications".
DEFINITIONS
[0047] In the present disclosure, "3D printer" is inclusive of both discrete
printers and/or
toolhead accessories to manufacturing machinery which carry out an additive
manufacturing
sub-process within a larger process. With reference to Figs. 1-5, 3D printer
is controlled by a
motion controller 20 which interprets dedicated G-code 1102 and drives various
actuators of the
3D printer in accordance with the G-code 1102.
[0048] As used herein, "extrusion" shall have its conventional meaning, e.g.,
a process in which
a stock material is pressed through a die to take on a specific shape of a
lower cross-sectional
area than the stock material. Fused Filament Fabrication (FFF) is an extrusion
process. Similarly,
"extrusion nozzle" shall have its conventional meaning, e.g., a device
designed to control the
direction or characteristics of an extrusion fluid flow, especially to
increase velocity and/or
restrict cross-sectional area, as the fluid flow exits (or enters) an enclosed
chamber. The present
disclosure shall also use the coined word "conduit nozzle" or "nozzlet" to
describe a terminal
printing head, in which unlike a FFF nozzle, there is no significant back
pressure, or additional
velocity created in the printing material, and the cross sectional area of the
printing material,
including the matrix and the embedded fiber(s), remains substantially similar
throughout the
process (even as deposited in bonded ranks to the part). As used herein,
"deposition head" shall
include extrusion nozzles, conduit nozzles, and/or hybrid nozzles. Also as
used herein, a
reference to a Figure numbers with no following letter suffix shall refer also
to all letter suffixes
of the same Figure number, e.g., a reference to "Fig. 1" refers to all of
Figs. 1A, 1B, IC, ID, 1E,
1F, and 1G (or any other letter suffix).
[0049] Lastly, in the three-dimensional printing art, "filament" typically
refers to the entire
cross-sectional area of a spooled build material, while in the composites art,
"filament" refers to
individual fibers of, for example, carbon fiber (in which, for example, a "1K
tow" will have 1000
individual strands). For the purposes of the present disclosure, "filament"
shall retain the
7
CA 03011260 2018-07-11
WO 2017/124085 PCT/1152017/013748
meaning from three-dimensional printing, and "strand" shall mean individual
fibers that are, for
example, embedded in a matrix, together forming an entire composite
"filament".
3D PRINTING SYSTEM
[0050] The printer(s) of Figs. 1A-1D, with at least two print heads 18, 10
and/or printing
techniques, deposit with one head a fiber reinforced composite filament, and
with a remaining
head apply pure or neat matrix resin 18a (thermoplastic or curing). The fiber
reinforced
composite filament 2 (also referred to herein as continuous core reinforced
filament) may be
substantially void free and include a polymer or resin that coats, permeates
or impregnates an
internal continuous single core or multistrand core. It should be noted that
although the print
head 18 is shown as an extrusion print head, "fill material print head" 18 as
used herein includes
optical or UV curing, heat fusion or sintering, or "polyjet", liquid, colloid,
suspension or powder
jetting devices ¨ not shown - for depositing fill material.
[0051] Although Figs. 1A-1D in general show a Cartesian arrangement for
relatively moving the
print-heads in 3 orthogonal translation directions, other arrangements are
considered within the
scope of, and expressly described by, a drive system or drive or motorized
drive that may
relatively move a print head and a build plate supporting a 3D printed part in
at least three
degrees of freedom (i.e., in four or more degrees of freedom as well). For
example, for three
degrees of freedom, a delta, parallel robot structure may use three
parallelogram arms connected
to universal joints at the base, optionally to maintain an orientation of the
print head (e.g., three
motorized degrees of freedom among the print head and build plate) or to
change the orientation
of the print head (e.g., four or higher degrees of freedom among the print
head and build plate).
As another example, the print head may be mounted on a robotic arm having
three, four, five,
six, or higher degrees of freedom; and/or the build platform may rotate,
translate in three
dimensions, or be spun.
[0052] The fiber reinforced composite filament 2, 2a is fed, dragged, and/or
pulled through a
conduit nozzle 10, 199 optionally heated to a controlled temperature selected
for the matrix
material to maintain a predetermined viscosity, force of adhesion of bonded
ranks, melting
properties, and/or surface finish.
[0053] After the matrix material or polymer 4, 4a is substantially melted, the
continuous core
reinforced filament 2 is applied onto a build platen 16 to build successive
layers 14 to form a
8
CA 03011260 2018-07-11
= WO 2017/124085
PCT/US2017/013748
three dimensional structure. The relative position and/or orientation of the
build platen 16 and
conduit nozzle 10 are controlled by a controller 20 to deposit the continuous
core reinforced
filament 2 in the desired location and direction.
[0054] A cutter 8 controlled by the controller 20 may cut the continuous core
reinforced
filament during the deposition process in order to (i) form separate features
and components on
the structure as well as (ii) control the directionality or anisotropy of the
deposited material
and/or bonded ranks in multiple sections and layers. At least one secondary
print head 18 may
print fill material 18a to form walls, infill, UV resistant and/or scratch
resistant protective
coatings, and/or removable, dissolvable, or soluble support material.
[0055] The supplied filament includes at least one axial fiber strand 6, 6a
extending within a
matrix material 4, 4a of the filament, for example a nylon matrix 4a that
impregnates hundreds or
thousands of continuous carbon, aramid, glass, basalt, or UHMWPE fiber strands
6a. The fiber
strand material has an ultimate tensile strength of greater than 300 MPa.
[0056] The driven roller set 42, 40 push the unmelted filament 2 along a
clearance fit zone that
prevents buckling of filament 2. In a threading or stitching process, the
melted matrix material 6a
and the axial fiber strands 4a of the filament 2 are pressed into the part 14
and/or into the swaths
below 2d, at times with axial compression. As the build platen 16 and print
head(s) are translated
with respect to one another, the end of the filament 2 contacts the ironing
lip 726 and is
subsequently continually ironed in a transverse pressure zone 3040 to form
bonded ranks or
composite swaths in the part 14.
[0057] Fig. 1B depicts a cross section of a compound (e.g., at least dual)
print head with an
extrusion printhead 1800 (as head 18) and extrusion nozzle 1802 for FFF and a
fiber deposition
printhead 199 (as head 10) and conduit nozzle 708 for continuous fiber
reinforced thermoplastic
deposition. Like numbered features are similar to those described with respect
to Fig. 1A.
[0058] The feed rate (the tangential or linear speed of the drive 42, 40)
and/or printing rate (e.g.,
the relative linear speed of the platen/part and print head) may be monitored
or controlled to
maintain compression, neutral tension, or positive tension within the
unsupported zone as well as
primarily via axial compressive or tensile force within fiber strand(s) 6a
extending along the
filament 2.
[0059] As shown in Figs. 1B and 1C, a transverse pressure zone 3040 includes
an ironing lip 726
that reshapes the filament 2. This ironing lip 726 compacts or presses the
filament 2 into the part
9
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
and may also melt, heat to cross glass transition into a non-glassy state,
and/or liquefy the matrix
material 4a in the transverse pressure zone 3040. Optionally, the ironing lip
726 in the transverse
pressure zone 3040 flattens the melted filament 2 on the "top" side (i.e., the
side opposite the part
14), applying an ironing force to the melted matrix material 4a and the axial
fiber strands 6a as
the filament 2 is deposited in bonded ranks or composite swaths 2c. For
example, the controller
20 maintains the height of the bottom of the ironing lip 726 to the top of the
layer below as less
than the diameter of the filament (e.g., to compress to 1/2 the height of the
filament, at least at 1/2
the filament height; to compress to 1/3 the height of the filament, at least
at 1/3 the filament
height, and so on). The controller 20 may maintain the height at of the bottom
of the ironing lip
726 to the layer below at zero (e.g., in which case the amount of
consolidation/compression and
the fiber swath 2c height may be a function of system stiffness). Another
reshaping force is
applied as a normal reaction force from the platen 16 or part 14 itself, which
flattens the bonded
ranks or composite swaths 2c on at least two sides as the melted matrix
material 4a and the axial
fiber strands 6a are ironed to form laterally and vertically bonded ranks
(i.e., the ironing also
forces the bonded ranks 2c into adjacent ranks).
[0060] As shown in Fig. 1C, if the underlying layer or swaths 2d includes
channels, the normal
reaction force from the part 14 may create T-shapes instead. The pressure and
heat applied by
ironing improves diffusion and fiber penetration into neighboring ranks or
swaths (laterally and
vertically).
[0061] As shown in Fig. 1B, unmelted fiber reinforced filament may be severed
in a gap 62
between a guide tube 72 (having a clearance fit) and the conduit nozzle 708;
or within the
conduit nozzle 708, e.g., upstream of the non-contact zone 3030; and/or at the
clearance fit zone
3010, 3020 or at the ironing lip 726.
[00621 After the matrix material 6a is melted by the ironing lip or tip 726,
the feed and/or
printing rate can be controlled by the controller 20 to maintain neutral to
positive tension in the
composite filament 2 between the ironing lip 726 and the part 14 primarily via
tensile force
within the fiber strands 4a extending along the filament 2. A substantially
constant cross
sectional area of the fiber reinforced composite filament is maintained in the
clearance fit zone,
the unsupported zone, the transverse pressure zone, and also as a bonded rank
is attached to the
workpiece or part 14.
CA 03011260 2018-07-11
' WO 2017/124085 PCT/US2017/013748
[0063] With reference to Fig. 1B, each of the printheads 1800 and 199 may be
mounted on the
same linear guide or different linear guides or actuators such that the X, Y
motorized mechanism
of the printer moves them in unison. As shown, the FFF printhead 1800 includes
an extrusion
nozzle 1802 with melt zone or melt reservoir 1804, a heater 1806, a high
thermal gradient zone
1808 formed by a thermal resistor or spacer 1809 (optionally an air gap), and
a Teflon or PTFE
tube 1811. A 1.75-1.8 mm; 3 mm; or larger or smaller thermoplastic filament is
driven through,
e.g., direct drive or a Bowden tube provides extrusion back pressure in the
melt reservoir 1804.
[0064] The companion continuous fiber embedded filament printhead 199, as
shown, includes
the conduit nozzle 708, the composite ironing tip 728, and the limited contact
cavity 714, in this
example each within a heating block heated by a heater 715. A cold feed zone
712 may be
formed within a receiving tube 64, including a capillary-like receiving tube
of rigid material and
a small diameter (e.g. inner diameter of 32 thou) Teflon/PTFE tube extending
into the nozzle
708. The cold feed zone is surrounded in this case by an insulating block 66a
and a heat sink
66b, but these are fully optional. In operation, an unattached terminal end of
the fiber-embedded
filament may be held in the cold feed zone, e.g., at height Pl. Distance Pl,
as well as cutter-to-tip
distance R1, are retained in a database for permitting the controller 20 to
thread and advance the
fiber-embedded filament as discussed herein. If P1 and R1 are very similar
(e.g., if the cutter
location is near or within the cold feed zone), P1 may be set to be the same
or similar to Rl.
Further as shown, the controller 20 is operatively connected to the cutter 8,
8A, and feed rollers
42 facing idle rollers 40.
[0065] Fig. 1C shows a schematic close-up cross section of the conduit nozzle
708. As shown in
Fig. IC, the inner diameter of the receiving tube 64 (in this case, at a
position where a
Teflon/PTFE inner tube forms the inner diameter) may be approximately 1 1/2 to
2 1/2 times (at,
e.g., 32 thou) the diameter of the filament 2 (at, e.g., 12-15, or 13 thou)
shown therewithin. The
inner diameter or inner width of the terminal cavity 714 (at, e.g., 40 thou)
is from two to six
times the diameter of the filament 2 shown therein. These are preferred
ranges, it is considered
the diameter of the receiving tube may be from 1 1/10 to 3 times the diameter
of the filament,
and the inner diameter of the terminal cavity from two to 12 times the
diameter of the filament.
The terminal cavity is preferably of larger diameter than the receiving tube.
[0066] Fig. 1C is a close-up cross-section of a fiber printhead assembly and a
set of different
possible compression/consolidation shapes, including continuous/random core
reinforced
11
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
filament shapes. That is, in the present disclosure, all descriptions
referring to the continuous
fiber filament 2, 2a or fiber reinforced composite filament 2, 2a may refer to
a fiber reinforced
composite filament 2, 2a including only continuous fibers 6a extending along
the filament and a
matrix material 4, 4a (e.g., polymer, ceramic, or metal) but also to a fiber
reinforced composite
filament 2, 2a including continuous fibers 6a extending along the filament and
embedding a 1-
20% (higher percentages, such as 30% or 40% are possible) volumetric
proportion of short
chopped fibers 6b (referred to as "chopped fiber", "fiber rods", or "short
fiber" herein). The
short chopped fibers 6b may be of the same material as the continuous fiber 6a
or a different
materiel. For example, a filament according to the present disclosure may
include a carbon fiber
continuous tow reinforcement 6a interspersed with short rods 6b of fiberglass,
or a glass fiber
continuous tow reinforcement interspersed with short rods 6b of carbon fiber,
or any such
combination. The short rods 6b may be randomly dispersed and oriented in
random directions,
but processes may also be applied during formation to orient at least a
proportion of the rods
non-randomly. In either case, at least a proportion of the short rods 6b may
extend transverse to
the filament 2, and some rods 6b may stick out or be forced partially out of a
filament to a
neighboring swath of filament 2c or a neighboring bead of fill material 18a or
18b, either during
deposition or during compaction. Some such rods 6b may extend in a direction
with a Z
component (e.g., vertically, or at an angle), or otherwise partially normal to
an external surface
of a deposited swath 2c, and some of these rods 6b may bridge layers in a Z
direction or bridge
neighboring fiber swaths 2c or beads 18a, 18b in X and/or Y directions.
[0067] It should be noted that neither the continuous fiber reinforcement 6a
nor the "rods" are
shown to scale in the drawings herein. A continuous fiber reinforcement may
typically consist of
500, 1000, 2000 or more strands of fiber 6a within the filament 2. The aspect
ratio of a rod (e.g.,
length:diameter may be 20:1 ¨ 200:1, commonly 40-60:1). The rods 6c may be
strands of a fiber
chopped to 0.05-2 mm length (optionally 0.2 mm up to 10 mm in length).
[0068] In addition, as shown in Fig. 1C, the heated composite filament ironing
tip 726 is moved
relative to the part, at a height above the part of less than the filament
diameter and scaled
according to a desired proportion of composite swath, to iron the fiber
reinforced composite
filament 2 as it is deposited to reshape a substantially oval or circular
bundle of inelastic axial
fiber strands 6a within the fiber reinforced composite filament (including any
embedded short or
chopped fiber rods 6b) to a substantially flattened block of inelastic fibers
strands within a
12
CA 03011260 2018-07-11
=
WO 2017/124085 PCT/US2017/013748
bonded rank 2c of the part. Axial compression and/or laterally pressing the
melted matrix
filament 2 into bonded ranks may enhance final part properties by acting on
either the strands 5a
or the rods 6b or both. For example, Fig. 1C shows a composite fiber
reinforced filament 2
applied with a compaction force, axial compression, or lateral pressure 62.
The compaction
pressure from axial compression and flattening from the ironing lip,
compresses or reshapes the
substantially circular cross-section filament 2a into the preceding layer
below and into a second,
substantially rectangular cross-section compacted shape 2c, as well as forcing
rods 6b at or near
the surface of the compacted shape 2c and/or layer below 2d or adjacent ranks
to interact with or
extend into any of fill material 18, matrix 4a, neighboring strands 6a or
neighboring rods 6b..
The entire filament 2a forms a bonded rank 2c (i.e., bonded to the layer below
2d and previous
ranks on the same layer) as it is shaped.
[0069] The filament 2c and/or interior strands 6a of the filament 2c and/or
interior rods 6b
spread and intrude into adjacent bonded ranks 2c or 2d on the same layer and
the matrix material
4a and strands 6a or rods 6b are compressed into the underlying shaped
filament or bonded rank
of material 2d. This pressing, compaction, or diffusion of shaped filaments or
bonded ranks 2c,
2d reduces the distance between reinforcing fibers, and increases the strength
of the resultant part
(and replaces techniques achieved in composite lay-up using post-processing
with pressure plates
or vacuum bagging). Accordingly, in some embodiments or aspect of the
invention discussed
herein, the axial compression of the filament 2 and/or especially the physical
pressing by the
printer head 70, conduit nozzle or ironing lip 726 in zone 3040 may be used to
apply a
compression/compaction/consolidation pressure directly to the deposited
material or bonded
ranks or composite swaths 2c to force them to spread or compact or flatten
into the ranks beside
and/or below. Additionally, the pressure may force rods 6b to interact with or
extend into
neighboring ranks beside or below and any of their components (fill material,
matrix, strands 6a,
rods 6b). Cross-sectional area is substantially or identically maintained.
[0070] Alternatively or in addition, pressure may be applied through a
trailing pressure plate
behind the print head; a full width pressure plate and/or roller 2138 (see,
e.g., Fig. 2E) spanning
the entire part that applies compaction pressure to an entire layer at a time;
and/or heat, pressure,
or vacuum may be applied during printing, after each layer, or to the part as
a whole to reflow
the resin in the layer and achieve the desired amount of compaction (forcing
of walls together
and reduction and elimination of voids) within the final part.
13
= CA 03011260 2018-07-11
=
WO 2017/124085 PCT/US2017/013748
[00711 Figs lE through 1G are cross-sections of 3D printed structures that may
be deposited by
the method and printer of the present disclosure, wherein Fig. lE shows
continuous/random core
fiber reinforced filament deposited together with polymer, ceramic, or metal
fill material,
deposited by a 3D printer (e.g., FDM, SLA, or other technique); Fig. 1F shows
continuous/random core fiber reinforced filament overmolded with a polymer,
ceramic, or
injection or other molding OV10, or continuous (substantially non-layered or
micro-layered)
additive manufacturing; and Fig. 1G shows continuous/random core fiber
reinforced filament
deposited together and interacting with polymer, ceramic, or metal fill
material that includes a
proportion (e.g., 5-20%) of short (e.g., 1/10 to 2 mm length, but potentially
up to 10 mm)
chopped fiber (e.g., carbon, glass, aramid or the like).
[0072] In the example shown in Fig. 1E, the lowest layer shown may be at or
near a floor of a
part and the pattern of Fig. lE may be substantially similar at or near a roof
of a part. As shown
in Fig. 1E, the lowest layer is a layer of 3D printed resin, polymer, ceramic
or metal fill material
18. Two ranks 2c are shown deposited upon the lowest layer, next to one
another. Within each
rank, continuous fiber strands 6a extend along the length of the deposited
core reinforced
filament or swath, and short fiber rods 6b are substantially randomly arranged
within the ranks.
As shown, at least a proportion of the short fiber rods extend, under the
application pressure that
flattens the filament, into neighboring (below or beside) swaths or layers.
The third layer
depicted extends with fiber swaths oriented in a direction substantially 90
degrees turned from
the swaths in the layer below, with ranks of fiber reinforcement in this layer
also including
continuous strands 6a extending substantially along the entire filament (e.g.,
for the lengths of
entire segments of filament as they are deposited and cut) as well as rods 6b
dispersed therein.
This arrangement creates strong reinforcement in each of the directions of the
continuous fiber
strands 6a as well as strong interactions between the swaths and beads of
fiber reinforcement 2
and fill material 18. As noted herein, further layers of fiber reinforcement
may be deposited in
Quasi-isotropic, concentric, or other patterns. Three layers of fill material
18 (in Fig. 1E, the
fourth through sixth layers from the bottom) are deposited above the last
fiber swaths 2c.
[00731 In the example shown in Fig. 1F, as discussed with respect to injection
molding and
overmolding herein, either the fill material 18 or the matrix 4 of Fig. 1E, or
both, would have
been deposited instead as soluble material or in the same material as an
injection molding
material to overmold the Fig. 1E with overmold OV10, treating Fig lE in this
instance as either a
14
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
soluble preform or a fiber reinforcement preform or both. Fig. IF shows the
fiber material, both
fiber strands 6a and short fiber rods 6b, overmolded with overmold OV10 and
embedded in an
overmolded reinforced molding. In this instance, the short fiber rods 6c
bridge between the
continuous fibers 6a and the injection molding material of the overmold OV10.
[0074] In the example shown in Fig. 1G, in contrast to the example shown in
Fig. 1E, the fill
material 18 now includes both a matrix material 18 and short fiber rods 18b.
Accordingly,
continuous reinforced fiber filament is printed together with randomly
reinforced fiber filament.
Additionally, the continuously reinforced fiber filament reinforced with
continuous fibers 6a is
additionally randomly or omnidirectionally reinforced by rods 6b. As shown in
Fig. 1G, the
lowest layer is a layer of 3D printed fill material 18 having a polymer,
ceramic, or metal matrix
18b and a random or omnidirectionally dispersed short chopped fiber 18c.
Again, two ranks 2c
are shown deposited upon the lowest layer, next to one another. Within each
rank, continuous
fiber strands 6a extend along the length of the deposited core reinforced
filament or swath, and
short fiber rods 6b are substantially randomly arranged within the ranks. As
shown, at least a
proportion of the short fiber rods 6b extend, under the application pressure
that flattens the
filament, into neighboring (below or beside) swaths or layers. Distinct from
Fig. 1E, in this case,
the neighboring swaths or layers also include short fiber rods 6b. The third
layer depicted
extends with fiber swaths 6a oriented in a direction substantially 90 degrees
turned from the
swaths 6a in the layer below, with ranks of fiber reinforcement in this layer
also including
continuous strands 6a extending substantially along the entire filament 2
(e.g., for the lengths of
entire segments of filament 2 as they are deposited and cut) as well as rods
6b dispersed therein.
This arrangement creates strong reinforcement in each of the directions of the
continuous fiber
strands 6a as well as strong interactions between the swaths and beads of
fiber reinforcement 2
(and its matrix 4 an strands 6a, 6b) and fill material 18 (and its matrix 18b
and rods 18c). As
noted herein, further layers of fiber reinforcement may be deposited in quasi-
isotropic,
concentric, or other patterns. Three layers of fill material 18 (in Fig. 1E,
the fourth through sixth
layers from the bottom) are deposited above the last fiber swaths 2c.
[0075] In one variation, as shown in Fig, 1F, the chopped rod 18c reinforced
fill material 18 may
be used together with pure polymer, ceramic, or metal fill material 18 (e.g.,
as shown, in the
lowest layer). In another variation, not shown, core reinforced filament 2
without fiber rods 6b
but only with continuous fiber 6a may be deposited together with any of pure
polymer, ceramic,
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
or metal fill material 18, and/or chopped fiber reinforced fill material 18
(with polymer, ceramic,
or metal matrix 18b and chopped fiber rods 18c), and/or core reinforced
filament 2 including
both continuous fiber 6a and dispersed chopped rods 6b. As noted herein, none
of the materials
of the reinforcement need be the same among the reinforcing rods 18c of the
chopped reinforced
fill material 18, the reinforcing continuous strands 6a of the core reinforced
filament, or the
reinforcing chopped short fiber rods 6b of the core reinforced filament;
however, the matrix
material 4 and/or fill material matrix 18c and/or fill material 18 should be
of the same polymer;
of related polymer; of related copolymer; of compatible polymer or copolymer;
or of strongly
adhering polymers.
[0076] As discussed herein, a three dimensional printer 1000 for additive
manufacturing of a part
may include a supply of a combined continuous/random fiber reinforced
composite filament 2
including a plurality of axial fiber strands 6a extending substantially
continuously within a
matrix material 4 of the fiber reinforced composite filament as well as a
multiplicity of short
chopped fiber rods 6c extending at least in part randomly within the same
matrix material 4. A
a deposition head (e.g., 10, 199) including a conduit continuously
transitioning to a substantially
rounded outlet tipped with an ironing lip 726 may be driven by a deposition
head drive hat drives
the ironing lip to flatten the fiber reinforced composite filament 2 against
previously deposited
portions of the part, as the matrix material 4, and a first proportion of the
short chopped fiber
rods 6b, are flowed (e.g., short rods 6b internal to the filament, amongst the
inner strands 6a,
may move with the flow) interstitially among the axial fiber strands 6a spread
by the ironing lip
726, and force a second proportion of the short chopped fiber rods (e.g.,
those near the outer
surface, on the outer surface or extending through the outer surface of the
filament 2) against
previously deposited portions of the part. A filament drive may push an
upstream portion of the
solidified fiber reinforced composite filament (e.g., more force transmitted
along the filament by
the continuous strands 6a than the dispersed rods 6b) to force the unattached
terminal end of the
fiber filament 2 through the conduit to exit the conduit at the ironing lip
726. A controller
operatively connected to the filament drive and the deposition head drive may
direct these
actions.
[0077] Alternatively, or in addition, a method for manufacturing a part may
include supplying a
core reinforced filament having a solidified matrix material impregnating
reinforcing strands
aligned along the core reinforced filament and impregnating reinforcing
chopped fiber rods in
16
CA 03011260 2018-07-11
=
WO 2017/124085 PCT/US2017/013748
part transverse to the core reinforcing strands. The core reinforced filament
may be received in a
cutter and cut there. The cut core reinforced filament may be received in a
nozzle and heated as it
is displaced out of the nozzle. A dragging force may be applied from the part
via the reinforcing
strands but not via the reinforcing chopped fiber rods (or, the dragging force
may be greater via
the reinforcing strands than via the reinforcing rods). Pressure may be
applied with the nozzle to
continuously compact the core reinforced filament as the core reinforced
filament is fused into
the part, and also to continuously embed a proportion of the short chopped
fiber rods (e.g., those
near the outer surface, on the outer surface or extending through the outer
surface of the filament
2) against previously deposited portions of the part. The compacted core
reinforced filament may
be fused into the part.
[0078] Alternatively, or in addition, a method for manufacturing a part may
include supplying a
core reinforced filament having a matrix material impregnating continuous
reinforcing strands 6a
extending along the entire length of the core reinforced filament and a
proportion of first
chopped fiber rods 6b, at least some of are oriented transversely to the
continuous reinforcing
strands 6a. A fill material 18 may be supplied separately from the core
reinforced filament 2 and
including a second chopped fiber rods 18c. The core reinforced filament 2, as
shown in Figs. 1D-
1F and/or 5A-5N and/or 4A-4J, may be deposited within a first region formed in
an outward
portion of a part that is closer to an outer wall of the part than to a
centroid of the part. Pressure
may be applied with a heated nozzle tip to continuously melt and compact the
core reinforced
filament 2, 2c as the core reinforced filament 2, 2c is fused into the layer
of the part and to
continuously embed a proportion of the first chopped fiber rods 6b against a
previously deposited
core reinforced filament including first chopped fiber rods 6b. Pressure may
also be applied with
the heated nozzle tip to continuously melt and compact the core reinforced
filament 2, 2c as the
core reinforced filament 2, 2c is fused into the layer of the part and to
continuously embed a
proportion of the first chopped fiber rods 6b against a previously deposited
fill material 18
including second chopped fiber rods 18c. The fill material 18õ as shown in
Figs. 1D-1F and/or
5A-5N and/or 4A-4J, may be deposited within a second region formed in a
portion of the part
that is positioned inward from the first region.
[00791 Figs. 2A-2H depict embodiments of a three dimensional printer in
applying a fiber
reinforced composite filament 2 together with DLP-SLA, SLA, SLS, "polyjet" or
other
17
CA 03011260 2018-07-11
õ
WO 2017/124085 Per1CS2017/013748
techniques to build a structure. Like numbered or like appearance features may
be similar to
those described with respect to Fig. 1A.
[0080] Although one embodiment or aspect of the invention uses thermoplastic
matrix, hybrid
systems are possible. A reinforced filament may employ a matrix that is
finished by a curing
cycle, e.g., using heat, light, lasers, and/or radiation. For example,
continuous carbon fibers are
embedded in a partially cured epoxy such that the extruded component sticks
together, but
requires a post-cure to fully harden. Similarly, while one embodiment or
aspect of the invention
use preformed continuous core reinforced filaments, in some embodiments, the
continuous core
reinforced filament may be formed by combining a resin matrix and a solid
continuous core in a
heated extrusion nozzle. The resin matrix and the solid continuous core are
able to be combined
without the formation of voids along the interface due to the ease with which
the resin wets the
continuous perimeter of the solid core as compared to the multiple interfaces
in a multistrand
core. Therefore, such an embodiment may be of particular use where it is
desirable to alter the
properties of the deposited material.
[0081] Figs. 2A and 2B depict a hybrid system employing stereolithography
(and/or selective
laser sintering) to provide the matrix about the embedded fiber, i.e.
processes in which a
continuous resin in liquid or powder form is solidified layer by layer by
sweeping a focused
radiation curing or melting beam (laser, UV) in desired layer configurations.
In order to provide
increased strength as well as the functionalities associated with different
types of continuous core
filaments including both solid and multistrand materials, the
stereolithography process associated
with the deposition of each layer can be modified into a two-step process that
enables
construction of composite components including continuous core filaments in
desired locations
and directions. A continuous core or fiber may be deposited in a desired
location and direction
within a layer to be printed, either completely or partially submerged in the
resin. After the
continuous fiber is deposited in the desired location and direction, the
adjoining resin is cured to
harden around the fiber. This may either be done as the continuous fiber is
deposited, or it may
be done after the continuous fiber has been deposited. In one embodiment, the
entire layer is
printed with a single continuous fiber without the need to cut the continuous
fiber. In other
embodiments, reinforcing fibers may be provided in different sections of the
printed layer with
different orientations. In order to facilitate depositing the continuous fiber
in multiple locations
18
CA 03011260 2018-07-11
. WO 2017/124085 PCT/US2017/013748
and directions, the continuous fiber may be terminated using a cutter as
described herein, or by
the laser that is used to harden the resin.
[0082] Fig. 2B depicts a part 1600 being built on a platen 1602 using
stereolithography or
selective layer sintering. The part 1600 is immersed in a liquid resin
(photopolymer) material or
powder bed1604 contained in a tray 1606. During formation of the part 1600,
the platen 1602 is
moved by a layer thickness to sequentially lower after the formation of each
layer to keep the
part 1600 submerged. During the formation of each layer, a continuous core
filament 1608 is fed
through a conduit nozzle 1610 and deposited onto the part 1600. The conduit
nozzle 1610 is
controlled to deposit the continuous core filament 1608 in a desired location
as well as a desired
direction within the layer being formed. The feed rate of the continuous core
filament 1608 may
be equal to the speed of the conduit nozzle 1610 to avoid disturbing the
already deposited
continuous core filaments. As the continuous core filament 1608 is deposited,
appropriate
electromagnetic radiation (e.g., laser 1612) cures or sinters the resin
surrounding the continuous
core filament 1608 in a location 1614 behind the path of travel of the conduit
nozzle 1610. The
distance between the location 1614 and the conduit nozzle 1610 may be selected
to allow the
continuous core filament to be completely submerged within the liquid resin or
powder prior to
curing. The laser is generated by a source 1616 and is directed by a
controllable mirror 1618.
The three dimensional printer also includes a cutter 1620 to enable the
termination of the
continuous core filament as noted above.
[0083] Optionally, the deposited filament is held in place by one or more
"tacks", which are a
sufficient amount of hardened resin material that holds the continuous core
filament in position
while additional core material is deposited. As depicted in Fig. 2C, the
continuous core filament
1608 is tacked in place at multiple discrete points 1622 by the laser 1612 as
the continuous core
filament is deposited by a nozzle, not depicted. After depositing a portion,
or all, of the
continuous core filament 1608, the laser 1612 is directed along a
predetermined pattern to cure
the liquid resin material 1604 and form the current layer. Similar to the
above system,
appropriate electromagnetic radiation (e.g., laser 1612), is generated by a
source 1616 and
directed by a controllable mirror 1618. The balance of the material can be
cured to maximize
cross linking between adjacent strands is maximized, e.g., when a sufficient
number of strands
has been deposited onto a layer and tacked in place, the resin may be cured in
beads that are
perpendicular to the direction of the deposited strands of continuous core
filament. Curing the
19
CA 03011260 2018-07-11
"
WO 2017/124085 PCT/US2017/013748
resin in a direction perpendicular to the deposited strands may provide
increased bonding
between adjacent strands to improve the part strength in a direction
perpendicular to the direction
of the deposited strands of continuous core filament. If separate portions of
the layer include
strands of continuous core filament oriented in different directions, the cure
pattern may include
lines that are perpendicular or parallel to the direction of the strands of
continuous fibers core
material in each portion of the layer.
[0084] Fig. 2D depicts printing of a multi-layer PCB 1800, on a build platen
16. The PCB 1800
is formed with a conductive core material 1802 and an insulating material 1804
which are
deposited using a printer head including a heated extrusion nozzle 10 and
cutting mechanism 8.
Similar to the multielement printer head, the conductive core material 1802
and insulating
material 1804 may be selectively deposited either individually or together.
Further, in some
embodiments the conductive core material 1802 is solid to minimize the
formation of voids in
the deposited composite material. When the conductive core material 1802 is
printed without the
insulating material 1804 a void 1806 can be formed to enable the subsequent
formation of vias
for use in connecting multiple layers within the PCB 1800. Depending on the
desired
application, the void 1806 may or may not be associated with one or more
traces made from the
conductive core material 1802.
[0085] When desirable, a precision roller set can be used to maintain a
constant thickness along a
relatively wider width of material output from a print head 2102. Such an
embodiment may be
of use when dealing with wider materials such as flat towpregs. Fig. 2E shows
a print head
2102 translating in a first direction. A nozzle 2136 of the print head is
attached to a trailing
compression roller 2138. The roller 2138 imparts a compressive force to the
material deposited
onto print bed 2140. Depending on the embodiment, the trailing roller 2138 can
articulate
around the Z axis using any number of different mechanisms. For example, in
one embodiment,
the print head 2102 is free-rotating on a bearing (e.g., adding a fourth
degree of freedom), such
that the roller always trails the direction of travel of the print head. In
another embodiment, the
entire print head 402 is constructed to rotate (e.g., adding a fourth degree
of freedom).
Alternatively or in addition, the print bed 2140 may be rotated (e.g., as a
fourth or fifth degree of
freedom) to achieve the desired trailing and displacement.
[0086] Fig. 2F shows one embodiment of a high-speed continuous core printer
capable of using
the above described materials. In the depicted embodiment, the printer
includes a print arm 2200
CA 03011260 2018-07-11
,
WO 2017/124085 PCT/US2017/013748
including a plurality of nozzles. The nozzles include a pure resin nozzle 2202
adapted to print
pure resin (e.g., as fill material) 2208. The print arm 2200 also includes a
continuous core
filament nozzle 2204 adapted to print a continuous core filament 2210 for use
in fine detail work.
Additionally, the print arm 2200 includes a tape dispensing head 2206 capable
of printing one or
more printable tapes 2212. The tape dispensing head enables large infill
sections to be printed
quickly using the noted printable tapes. However, fine detail work and gaps
that cannot be filled
in by the tape can be filled by either the pure resin nozzle 2202 or
continuous core filament
nozzle 2204. The above noted method and system using wide tape fills greatly
improves the
speed of a printer, enabling higher throughput, and commensurately lower cost.
[00871 In Fig. 2G, an (e.g., robot arm) print arm 1400 is capable of attaching
to printer head
1402 at a universal connection 1404. A continuous core reinforced filament
1406 may be fed
into the printer head 1402 before or after attachment to the printer 1400. The
print arm 1400
may return the printer head 1402 to an associated holder or turret and then
pick up printer head
1408 or 1410 for printing filament and other consumables different in size,
material, color,
coating, and/or spray; or even a vision system 1412 (e.g., camera,
rangefinder) for part
inspection.
[00881 The continuous core reinforced filament may be formed by adding a resin
matrix or
coating to a solid continuous core or a prepreg in a heated conduit or
extrusion nozzle. Fig. 2H
depicts a multi-element printer head 1500 that selectively combines (in any
feasible
combination) and extrudes material feed options core 1502 (e.g., continuous
copper wire,
continuous fiber, stranded prepreg wire or fiber), matrix 1504 (e.g., binding
resin such as nylon),
and support 1506 (e.g., a dissolvable support material). For example, a core
1502 might be
surrounded by a matrix binder 1504 on the bottom surface and a
dissolvable/soluble support
1506 on the top surface (e.g., section 1508). The multi-element printer head
1500 may also
deposit the core 1502 coated with either the matrix binder 1504 or soluble
support 1506
separately (e.g., sections 1510 and 1514), or e.g., deposit any of the
materials individually (e.g.,
the bare core or copper wire at section 1512).
[00891 As shown in Fig. 2H, multi-element printer head 1500 (or any other
print head
embodiment depicted herein) may include an air nozzle 1508 which enables pre-
heating of the
print area and/or rapid cooling of the extruded material to aid in forming
structures such as flying
leads, gap bridging, and other similar features. For example, a conductive
core material may be
21
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
deposited by the multi-element printer head 1500 with a co-extruded insulating
plastic, to form a
trace in the printed part. The end of the trace may then be terminated as a
flying lead (the multi-
element printer head lifts and deposits the core and jacket), optionally
cooling the insulating
jacket with the air nozzle 1508. The end of the wire could then be printed as
a "stripped wire"
where the conductive core is extruded without the insulating jacket. The
cutting mechanism 8
may then terminate the conductive core. Formation of a flying, uninsulated
lead in the above-
noted manner may be used to eliminate a later stripping step.
[0090] Fig. ID depicts a block diagram and control system of the three
dimensional printer
which controls the mechanisms, sensors, and actuators therein, and executes
instructions to
perform the control profiles depicted in and processes described herein. A
printer is depicted in
schematic form to show possible configurations of e.g., three commanded motors
116, 118, and
120. It should be noted that this printer may include the compound assembly of
printheads 199,
1800 depicted in Fig. 1C.
[00911 As depicted in Fig. 1D, the three-dimensional printer 3001 includes a
controller 20 which
is operatively connected to the fiber head heater 715, the fiber filament
drive 42 and the plurality
of actuators 116, 118, 120, wherein the controller 20 executes instructions
which cause the
filament drive to deposit and/or compress fiber into the part. The
instructions are held in flash
memory and executed in RAM (not shown; may be embedded in the controller 20).
An actuator
114 for applying a spray coat, as discussed herein, may also be connected to
the controller 20. In
addition to the fiber drive 42, a filament feed 1830 be controlled by the
controller to supply the
extrusion printhead 1800. A printhead board 110, optionally mounted on the
compound
printhead 199, 1800 and moving therewith and connected to the main controller
20 via ribbon
cable, breaks out certain inputs and outputs. The temperature of the ironing
tip 726 may be
monitored by the controller 20 by a thermistor or thermocouple 102; and the
temperature of the
heater block holding nozzle 1802 of any companion extrusion printhead 1800 may
be measured
by a thermistor or thermocouple 1832. A heater 715 for heating the ironing tip
726 and a heater
1806 for heating the extrusion nozzle 1802 are controlled by the controller
20. A heat sink fan
106 and a part fan 108, each for cooling, may be shared between the printheads
199, 1800 and
controlled by the controller 20. Rangefinder 15 is also monitored by the
controller 20. The cutter
8 actuator, which may be a servomotor, a solenoid, or equivalent, is also
operatively connected.
A lifter motor for lifting one or either printhead 199, 1800 away from the
part (e.g., to control
22
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
dripping) may also be controlled. Limit switches 112 for detecting when the
actuators 116, 118,
120 have reached the end of their proper travel range are also monitored by
the controller 20.
[0092] As depicted in Fig. 1D, an additional breakout board 122, which may
include a separate
microcontroller, provides user interface and connectivity to the controller
20. An 802.11 Wi-Fi
transceiver connects the controller to a local wireless network and to the
Internet at large and
sends and receives remote inputs, commands, and control parameters. A touch
screen display
panel 128 provides user feedback and accepts inputs, commands, and control
parameters from
the user. Flash memory 126 and RAM 130 store programs and active instructions
for the user
interface microcontroller and the controller 20.
[0093] Fig. 3 depicts a flowchart showing a printing operation of the printers
1000 in Figs. 1-2.
Fig. 3 describes, as a coupled functionality, control routines that may be
carried out to alternately
and in combination use the co-mounted FFF extrusion head 1800 and fiber
reinforced filament
printing head 199 of Fig. 1A-1D.
[0094] In Fig. 3, at the initiation of printing, the controller 20 determines
in step S10 whether
the next segment to be printed is a fiber segment or not, and routes the
process to S12 in the case
of a fiber filament segment to be printed and to step S14 in the case of other
segments, including
e.g., base, fill, or coatings. Step S12 is described in detail with reference
to Figs. 2. After each or
either of routines S12 and S14 have completed a segment, the routine of Fig. 3
checks for slice
completion at step S16, and if segments remain within the slice, increments to
the next planned
segment and continues the determination and printing of fiber segments and/or
non-fiber
segments at step S18. Similarly, after slice completion at step S16, if slices
remain at step S20,
the routine increments at step S22 to the next planned slice and continues the
determination and
printing of fiber segments and/or non-fiber segments. "Segment" as used herein
corresponds to
"toolpath" and "trajectory", and means a linear row, road, or rank having a
beginning and an end,
which may be open or closed, a line, a loop, curved, straight, etc. A segment
begins when a
printhead begins a continuous deposit of material, and terminates when the
printhead stops
depositing. A "slice" is a single layer or lamina to be printed in the 3D
printer, and a slice may
include one segment, many segments, lattice fill of cells, different
materials, and/or a
combination of fiber-embedded filament segments and pure polymer segments. A
"part" includes
a plurality of slices to build up the part. Fig. 3's control routine permits
dual-mode printing with
two different printheads, including the compound printheads 199, 1800 of Fig.
1A-1D.
23
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
[0095] All of the printed structures previously discussed may be embedded
within a molded
article during a molding process, as discussed herein, expressly including
reinforced fiber
structures of any kind, sparse, dense, concentric, quasi-isotropic or
otherwise as well as fill
material or plain resin structures. In addition, in all cases discussed with
respect to embedding in
injection molding, structures printed by fill material head 18 using
thermoplastic extrusion
deposition may be in each case replaced with soluble material (e.g., soluble
thermoplastic or salt)
to form a soluble preform which may form a printing substrate for fiber
reinforcement and then
removed, leaving a continuous fiber reinforced preform. All continuous fiber
structures
discussed herein, e.g., sandwich panels, shells, walls, reinforcement
surrounding holes or
features, etc., may be part of a continuous fiber reinforced preform.
[0096] That is, the present disclosure contemplates a method of fabricating a
reinforced
molding, where a "molding" is used as a noun and a reinforced molding
comprises a molded,
finished article with a skeletal or dense internal reinforcement formed by a
continuous fiber
structure. Using the 3D printer herein discussed with reference to Figs. 1-3
inclusive, which may
deposit either fill material, soluble material, or continuous fiber, the
reinforcing fiber is
additively deposited in a reinforcement volume to form a continuous fiber
reinforcement
preform. A preform may be a substrate against which further layers of 3D
printing are deposited
(fill material, soluble material, or continuous fiber) or a shape to be
embedded within a molded
article, or both. For example, a continuous fiber reinforcement preform is
located within a mold
of a molding apparatus (such as an injection mold's internal cavity, large
enough and shaped
appropriately to receive the reinforcement preform). The mold is loaded (e.g.,
injected or
otherwise filled) with molten, flowable and/or optionally substantially
isotropic molding material
(e.g., thermoplastic, curable plastic, thermoset, metal, or the like,
optionally including chopped
fibers or dispersed particulates). Injection under heat and pressure of
fluidized thermoplastic is
"loading". The molding material is hardened (e.g., cooled or cured) to
overmold the continuous
fiber reinforcement preform with the molding material, thereby forming a
reinforced molding
surrounding an internal continuous fiber reinforcement preform with a hardened
substantially
isotropic molding material. The reinforcement volume is smaller than a volume
of the entire
reinforced molding.
[0097] For example, a schematic representation of a composite structure is
depicted in Fig. 13
which shows a sandwich panel composite part. This sandwich panel composite
part may form
24
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
part of or the entirety of a continuous fiber reinforcement preform that is
later embedded in a
molded article (reinforced molding). The top section 1900, and bottom section
1902, are printed
using a continuous core reinforced filament to form relatively solid portions.
In contrast, the
middle section 1904 may be printed such that it has different properties than
the top section
1900 and the bottom section 1902. The middle section 1904 may be printed
either as fill material
(to be retained within the reinforced molding), soluble material or a soluble
preform (to be
dissolved away before or during overmolding of the sandwich panel structure
within the mold) or
as fiber honeycomb (again, to be retained within the reinforced molding). For
example, the
middle section 1904 may include multiple layers printed in a honeycomb pattern
using a
continuous core reinforced filament, a pure resin, or even a three
dimensionally printed foaming
material. This enables the production of a composite part including a lower
density core using a
three dimensional printer, and this part may be a skeletal or reinforcement
structure for a
reinforced molding.
[0098] In addition to using the continuous core reinforced filaments to form
various composite
structures with properties in desired directions using the fiber orientation,
each of which may
form part of the reinforcement preform and be embedded in a reinforced
molding, in some
embodiments it is desirable to provide additional strength in directions other
than the fiber
direction. For example, the continuous core reinforced filaments might include
additional
composite materials to enhance the overall strength of the material or a
strength of the material in
a direction other than the direction of the fiber core. For example, Fig. 14
shows a scanning
electron microscope image of a carbon fiber core material 2000 that includes
substantially
perpendicularly loaded carbon nanotubes 2002. Loading substantially
perpendicular small fiber
members on the core increases the shear strength of the composite, and
advantageously increases
the strength of the resulting part in a direction substantially perpendicular
to the fiber direction.
Such an embodiment may help to reduce the propensity of a part to delaminate
along a given
layer.
[0099] Figs. 4A-5P depict various parts formed using the printer head(s)
depicted in Figs. 1A-1D
and/or 2A-2G. Figs. 4A,5A and 50 show a part including a plurality of sections
1322 deposited
as two dimensional layers in the XY plane. These sections 1322 may be
deposited as fill material
18 or as soluble material. If they are deposited as soluble material, they may
form the soluble
preform. Sections 1324 and 1326 are subsequently deposited in the ZY plane to
give the part
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
increased strength in the Z direction. As shown in Fig. 4A and 5A, if sections
1322 are formed as
the soluble preform or as soluble material and are dissolved away or removed
prior to, during, or
after overmolding and/or hardening the molding material to overmold OV1 the
continuous fiber
reinforcement preform, a fiber reinforced molding with an overmold OV1
surrounding an
internal continuous fiber reinforcement preform is formed, the overmold OV1
being a hardened
substantially isotropic molding material. In Figs. 4A and 5A, a box-like or
canister-like
reinforced molding is formed with reinforcement concentrated along outer
walls. Conversely, as
shown in Fig. 50, if the support preform is not soluble and both the support
preform and any
continuous fiber reinforcement preform are overmolded with overmold Oil, a
molding having
both an internal/embedded support preform (which may be, as discussed herein,
reinforced with
rods, chopped, short, long, or particulate reinforcement) and an
internal/embedded fiber
reinforcement preform surrounding the support preform may be formed.
[0100] Figs. 4B, 5B and 5P shows a related method of shell printing, where
layers 1328 and
1330 are formed in the XY plane and are overlaid with shells 1332 and 1334
which extend in
both the XY and ZY planes. As depicted in the figure, the shells 1332 and 1334
may either
completely overlap the underlying core formed from layers 1328 and 1330, see
portion 1336, or
one or more of the shells may only overly a portion of the underlying core.
For example, in
portion 1338 shell 1332 overlies both layers 1328 and 1330. However, shell
1334 does not
completely overlap the layer 1328 and creates a stepped construction as
depicted in the figure.
As shown in Figs. 4B and 5B, if sections 1328 are formed as the soluble
preform or as soluble
material and are dissolved away or removed prior to, during, or after
overmolding and/or
hardening the molding material to overmold 0V2 the continuous fiber
reinforcement preform, a
fiber reinforced molding with an overmold 0V2 surrounding an internal
continuous fiber
reinforcement preform is formed, the overmold 0V2 being a hardened
substantially isotropic
molding material. In Figs. 4A and 5B, a shell-like, cup-like, or open box
reinforced molding is
formed, with reinforcement following the contour of the shell or walls of the
cup or open box.
Again, as shown in Fig. 5P, if the support preform is not soluble and both the
support preform
and any continuous fiber reinforcement preform are overmolded with overmold
0V12, a
molding having both an internal/embedded support preform (which may be, as
discussed herein,
reinforced with rods, chopped, short, long, or particulate reinforcement) and
an
internal/embedded fiber reinforcement preform cupping the support preform may
be formed.
26
CA 03011260 2018-07-11
WO 2017/124085 PCT/U52017/013748
[0101] Figs. 4C and 5C show an alternative embodiment where a support material
1340 is added
to raise the part relative to a build platen, or other supporting surface,
such that the pivoting head
of the three dimensional printer has clearance between the part and the
supporting surface to
enable the deposition of the shell 1342 onto the underlying layers 1344 of the
part core. Again,
as shown in Figs. 4B, 4C and 5B, 5C if sections 1344 and/or 1340 are formed as
the soluble
preform or as soluble material and are dissolved away or removed prior to,
during, or after
overmolding and/or hardening the molding material to overmold 0V3 the
continuous fiber
reinforcement preform, a fiber reinforced molding with an overmold 0V3
surrounding an
internal continuous fiber reinforcement preform is formed, the overmold 0V3
being a hardened
substantially isotropic molding material. In Figs. 4C and 5C, a multi-level
reinforced molding is
formed, with both flat and curved shapes in multiple orientations, and
reinforcement following
the walls. It should be noted that any of the layers or shells of fiber
reinforcement shown in Figs.
4A-4C or 5A-5C may be a multi-layer laminate of differing fiber orientations
(e.g., a quasi-
isotropic pattern or an anisotropic, directional pattern). Again, as shown in
Fig. 5Q, if the support
preform is not soluble and both the support preform and any continuous fiber
reinforcement
preform are overmolded with overmold 0V14, a molding having both an
intemallembedded
support preform (which may be, as discussed herein, reinforced with rods,
chopped, short, long,
or particulate reinforcement) and an internal/embedded fiber reinforcement
preform cupping the
support preform may be formed.
[0102] The above described printer head may also be used to form a part with
discrete
subsections including different orientations of a continuous core reinforced
filament. The
orientation of the continuous core reinforced filament in one subsection may
be substantially in
the XY direction, while the direction in another subsection may be in the XZ
or YZ direction.
[0103] The path planning and printing processes may utilize a fill pattern
that uses high-strength
composite material in selected areas and filler material (e.g., less strong
composite or pure resin
such as nylon) in other locations, see Figs. 4D-4G and 5E-5G, which depict
stacks of layers in
cross section. As discussed with reference to the sandwich panel global or
region rule, in some
cases, reinforcement is conducted by identifying an internal volume or volumes
in the shape of
simplified beams or panel, e.g., an interior prism or volume spanning and
extending beyond
bending load and/or support points. In addition, the part may be oriented
during planning for
deposition such that layers within the volume span the anticipated load and/or
support points.
27
CA 03011260 2018-07-11
,
WO 2017/124085 PCT/US2017/013748
Fiber may be fiber added within the interior prism volume remote from a
centroid of a cross
section of the volume, to increase effective moment of inertia (particularly
for bending or
compression loads). Fibers may be deposited in multiple adjacent bonded ranks
and/or layers, to
increase fiber rank interaction and reinforcement of neighbors (particularly
for compression and
tension loads). Through holes or mounts through which or into which load
members are expected
to be inserted may each be smoothly looped by fiber, optionally directly at
the wall of such
mount (particularly for tension and torsion loads, looping may permit fewer
stress concentrations
and the transmission of tension through smooth paths).
[0104] Especially for beam and panel bending, the strength to weight
performance of a beam is
optimized by placing fiber ranks as far as possible (i.e., at the farthest
position both within the
part and that does not violating any higher priority rules in effect at the
boundary of the part)
from the centroid of a cross-section to increase effective moment of inertia.
A part formed
completely from the fill material or soluble material 1350, and or a complete
soluble preform, is
contemplated.
[0105] In Figs. 4E and 5E, a composite material 1352 is deposited at the
radially outward most
portions of the part and extending inwards for a desired distance to provide a
desired increase in
stiffness and strength. The remaining portion of the part is formed with the
fill material 1350. A
user may extend the use of composite versus filler either more or less from
the various corners of
the part as illustrated by the series of figures Figs. 4D-4G and 5E-5G. For
example, a control
algorithm controlled by controller 20 may use a concentric fill pattern that
traces the outside
corners and wall sections of the part, for a specified number of concentric
infill passes, the
remainder of the part may then be filled using a desired fill material. Fig.
5D shows a dissolved
soluble preform 1340a (as a dotted line). As shown in Figs. 4D-4F and 5D-5F,
if fill material
sections 1350 are instead formed as the soluble preform 1340a or as soluble
material and are
dissolved away or removed prior to, during, or after overmolding and/or
hardening the molding
material to overmold 0V4-0V6 the continuous fiber reinforcement preform, a
fiber reinforced
molding with an overmold 0V4-0V6 embedding an internal continuous fiber
reinforcement
preform is formed, the overmold 0V4-0V6 being a hardened substantially
isotropic molding
material. In Figs. 4E-4G or 5E-5G, a box-like, canister-like, or tube-like
reinforced molding is
formed with reinforcement concentrated as described.
28
CA 03011260 2018-07-11
= WO 2017/124085
PCT/US2017/013748
[0106] Figs. 4H-4J and 5H-5J depict further parts formed using the printer
head(s) depicted in
Figs. 1A-1D and/or 2A-2G.
[0107] Where Figs. 4E through 4G or 5E through 5G do not expressly show outer
walls of the
part formed from fill material 1350 (e.g., the parts in Figs. 4E-4G may have
outer wall(s) of fill
material 1350 or outer walls of composite material 1352), Figs. 4H through 4J
show cross
sections of parts with the outer wall 1350-OW specifically shown.
[0108] As shown by Figs. 5H-5J, in the following description with reference to
Figs. 4H-4J, if
the fill material 1350 is selectively or entirely replaced with soluble
material or considered to
form the soluble preform, the soluble material may be dissolved away prior to,
during, or
following overmolding of any of the fiber reinforcement structures shown in
Figs. 4H-4J and/or
Figs. 5H-5J. As depicted in Fig. 511, following the removal of the material
labeled 1350 as a
soluble preform or as other soluble material, a hollow cored reinforcement
molding is formed
which an overmold 0V7 of hardened isotropic material surrounds outer walls,
floor, and ceiling
of a continuous fiber reinforcement preform formed from the quasi-isotropic
laminates 1352-QI
and concentric laminates 1352-CON. As depicted in Figs. 41 or 51, following
the removal of the
material labeled 1350 as a soluble preform or as other soluble material, a
through-holed but
otherwise solid cored reinforcement molding is formed which an overmold 0V8 of
hardened
isotropic material surrounds inner walls of the through-hole TH-H, outer
walls, floor, ceiling of a
continuous fiber reinforcement preform formed from the quasi-isotropic
laminates 1352-QI and
concentric laminates 1352-CON. As depicted in Figs. 4J or 5J following the
removal of the
material labeled 1350 as a soluble preform or as other soluble material, a
solid cored
reinforcement molding is formed which an overmold OV9 of hardened isotropic
material
surrounds inner walls of the through-hole TH-H, outer walls, floor, ceiling of
a continuous fiber
reinforcement preform formed from multiple quasi-isotropic laminates 1352-QI
and concentric
laminates 1352-CON and bridging laminates 1352-CLW.
[0109] Specifically, in Figs. 411 or 5H, a part is built up from the lowest
layer or down from the
highest layer, depending on the printing type or approach. In Fig. 411, an
outer layer of fill
material 1350 is formed by a floor layer of fill material 1350 (the outer
layer may be 1-3 or more
successive floor layers). As in Figs. 4E-4G, an internal sandwich panel is
built of composite
material 1352, in this case as two quasi-isotropic sets 1352-QI separated by
infill material 1350-
IF. In this case, a quasi-isotropic set 1352-Q1 is formed by four parallel
shells or layers of
29
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
anisotropic fill or composite fiber swaths, in which the dominant direction of
the fiber swaths is
rotated by 45 degrees (in a known manner for quasi-isotropic laminates of four
layers) between
each layer (as noted herein, a quasi-isotropic set of layers or shells tends
be composed of 3 or
more layers, the layers together having a substantially isotropic stiffness
behavior as a laminate).
As discussed, the quasi-isotropic sets 1352-QI are deposited adjacent or
proximate the top and
bottom of the part to provide a higher moment of inertia and bending
stiffness. The quasi-
isotropic sets 1352-QI also provide twisting or torsion stiffness. As shown,
in contrast to Figs.
4E-4G, in Fig. 5H outer walls 1350-OW (including 1-3 or more beads of
isotropic fill material)
optionally surround the sets 1352-QI of quasi-isotropic layers so that the
outer surface of the part
is fill material 1352.
[0110] Further in contrast to Figs. 4E-4G, the middle fill material section
1350-IF is surrounded
by outer concentrically deposited anisotropic composite fiber swaths 1352-CON
(e.g., as shown
in single layer form in Fig. 10A, 10B, or 10C). Each concentric fiber swath
fill section 1352-
CON may be any number of concentric loops, e.g., 1-10 or higher. Again,
optionally, outer walls
1350-OW (including 1-3 or more beads of isotropic fill material) optionally
surround the sets
1352-CON of quasi-isotropic layers and fill material 1352 so that the outer
surface of the part is
fill material 1352. In addition, the upper quasi-isotropic layer set 1352-QI
is additionally covered
by a roof fill of fill material 1350-R (again, 1-3 or more layers of isotropic
fill material 1350). In
this manner, the entire outer surface of the part is optionally sheathed in
fill material 1352, but
immediately adjacent the fill material 1352 outer surfaces and displaced
outwardly from a
centroid of the part, composite material 1352 is deposited to increase
effective moment of inertia
in either anisotropically deposited quasi-isotropic sets 1352-QI, and/or
concentrically deposited
layers 1352-CON. Accordingly, outer contours, perimeters, roofs, and floors of
the 3D
geometry, whether formed from layers or shells of the 3D printing process or
formed from walls,
beads, or swaths within a respective layer or shell of the 3D printing
process, are surrounded by
an inner shell of composite material 1352. It should be further noted that one
exemplary fill
approach for the concentrically deposited outer layers 1352-CON is concentric
loops, spirals, or
offsets starting at an outer region perimeter or contour and spiraling inward
1352-0.CON (outer
concentric fill).
[0111] In a variation of the part of Fig. 411 of a part having a through-hole
TH-H as shown in
Fig. 41, the general approach of Fig. 4H may be followed. In contrast, in Fig.
41, the negative
CA 03011260 2018-07-11
= ' WO 2017/124085
PCT/1JS2017/013748
contours or holes found in each layer having anisotropically deposited and/or
oriented fiber fill,
quasi-isotropic sets of layers 1350-R, and also found in each layer having
anisotropically
deposited and/or oriented fiber fill, outer concentric layers 1352-CON, are
surrounded by these
respective fills as well as isotropic, resin or fill material infill 1350-F.
However, immediately
adjacent the negative contour, a reinforcing column formed from an optional
inner wall of
isotropic, resin or fill material 1350-IW and an inner wall of anisotropically
deposited and/or
oriented fiber fill, inner fill concentric layers 1352-1.CON (e.g., a tube of
concentric fiber and/or
concentric fill material surrounding the through hole TH-H). A non-through,
terminating hole
may be similarly structured (e.g., the sides of the hole being similarly
concentric inner fill of
fiber 1352-I.CON and/or inner wall resin or fill material fill 1350-1W, and
the bottom of the hole
being terminated with, as permitting, a quasi-isotropic set 1352-QI and/or a
roof layer 1350-R).
As shown, the reinforcing column may extend through the infill 1350-IF, the
outer concentrically
reinforced layers 1352-0.CON or 1352-CON, as well as the quasi-isotropic sets
of layers 1352-
QI, such that two or three or more regions, fill patterns, or toolpath
generation approaches are
used in these layers, either in exclusive regions or in overlapping regions
with a set priority
among generation rules. As an example, a layer depicted in Fig. 10B includes
an outer concentric
fiber fill surrounding both of an anisotropically deposited and oriented
infill IF that is one layer
of a quasi-isotropic set, as well as an inner concentric fiber fill
surrounding a negative contour.
The reinforcing column formed from inner wall resin fill 1350-IW and/or inner
concentric fiber
fill 1352-I.CON may surround more than one hole or negative contour in each
layer, e.g., two
holes or three holes, etc., or may be a reinforcing structure distributed
among different layers in a
set or laminate. In this manner, negative contours, through-holes, and similar
structures, whether
formed from layers or shells of the 3D printing process or formed as walls
within a layer or shell
of the 3D printing process, also are surrounded by an inner shell of composite
material.
[01121 It should be noted that the reinforcing columns may be or include or
one or more
continuous fiber columns CRC injected, inserted, drilled, drawn, lain,
stitched, guided, or
otherwise deposited to join layers in the Z-axis direction and resist Z-axis
delamination; and need
not surround a through-hole.
[01131 Fig. 5M-5N show structures similar to those of Fig. 51 and 5J, in which
continuous
reinforcing columns bridging layers extend through multiple layers. These
continuous
reinforcing columns may be orthogonal/vertical/perpendicular to one or more 2D
layers LAõ, at
31
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
an angle to one or more layers, or curving through one or more layers, or take
paths joining
orthogonal, angled, or curved paths. For example, the reinforcing columns
labeled may include
either concentric fiber surround, concentric fiber surround combined with
continuous reinforcing
column(s), or just continuous reinforcing columns extending parallel to the
through hole. As
shown in Fig. 5M, a continuous reinforcing column CRC bridging layers may
extend along the
internal surface of a through-hole; may be embedded in injection overmolding
as in Figs. 5H-5J,
or may extend at an angle through multiple layers but not the entire part
(e.g., having been placed
during the successive deposition of multiple layers). As shown in Fig. 5N, a
continuous
reinforcing column CRC may extend at an angle through many layers or the part,
may extend
through reinforcing columns in intermediate layers; or between or through or
into sandwich
panel laminate layer groups forming quasi-isotropic laminates and forming
sandwich panel
internal structures, or may be arranged to overlap, spanning only 2-10 layers
each but each layer
being "connected" by offset or staggered continuous reinforcing columns CRC.
[0114] In a further variation of the part of Fig. 41-1 of a part having an
internally dense fiber infill
pattern, as shown in Fig. 4J, the general approach of Fig. 4H may again be
followed. In contrast,
in Fig. 4J, a matrix or cellular arrangement of concentrically filled
anisotropic material walls (of
anisotropically deposited and oriented fiber material) 1352-CLW is arranged
within the part to
provide increasing fiber density and/or stiffness and/or crushing resistance.
The pattern of cell
walls 1352-CLW may be a honeycomb formed from reinforcement formations.
Further, the
pattern of cell walls of anisotropically deposited and oriented fiber material
1352-CLW may be
formed by crossing or non-crossing outer concentric or inner concentric fills
1352-0.CON or
1352-I.CON. The pattern of cell walls of anisotropically deposited and
oriented fiber material
1352-CLW may be a mirroring, repeating, orthogonally varying, or complementary
arrangement.
The cells are filled with infill material 1350-IF, in a dense or sparse
arrangement. Additionally in
contrast, in Fig. 4J, one or more intervening sets of quasi-isotropic fill
1352-QI (of
anisotropically deposited and oriented fiber material) may be formed as an
inner wafer other than
at the top and bottom regions remote from the centroid. As shown in Fig. 4J,
in contrast to Fig.
4H, the one or more intervening sets of quasi-isotropic fill 1352-QI (of
anisotropically deposited
and oriented fiber material) may be further surrounded by an outer concentric
fill 1352-0.CON
(in order to provide a consistent outer shell) or may instead fill a layer to
an outer wall of resin
material 1350-OW (as with the upper and lower sets of quasi-isotropic fill
1352-QI.
32
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
[0115] It should be further noted that the structures of Figs. 41 and 4J may
be combined by
using exclusive regions or regions having a priority among them, e.g., through-
holes TH-H may
penetrate through or partially through a matrix or cellular arrangement of
fiber fills 1352-CLW
and/or 1352-QI combined with fill material 1350-IF and be nonetheless
surrounded by wall-
reinforcing tubes of fiber and/or fill material, e.g., as shown in Fig. 10B.
[0116] As shown in each of Figs. 4H-4J, at least one (e.g., 1-3 or more) roof
layer of resin or
isotropic material or infill material 1350-R, solid, filled or densely filled
in ox-row or other
packed fashion, may be printed above a set of resin or fill material infill
1350-IF. The infill
1350-IF may in some cases be a sparse honeycomb pattern, and the solid, filled
or densely filled
roof layer(s) 1350-R provide a complete shell or layer surface upon which the
anisotropic fiber
swaths may be compressed and fused.
[0117] As shown in Figs. 4A-4J, the three-dimensional geometry of the parts
shown in Figs. 4A-
4J may be sliced into shells or layers as described herein. For each of a set
of shells or layers
defining a portion of a 3D printed part, first isotropic fill tool paths such
as 1322, 1328, 1330,
1344, 1350, 1350-R, 1350-0W, and/or 1350-IW may be generated for controlling
an isotropic
solidifying head (e.g., head 18 or 1800 or 1616) to solidify, along the
isotropic fill tool paths, a
substantially isotropic fill material such (e.g., material 18a or 1604). For
each of an anisotropic
fill subset of the set of shells or layers defining the portion of the 3D
printed part (e.g., the
different fiber fills throughout a part), first anisotropic fill tool paths
(e.g., 1352-QI or 1352-
0.CON or 1352 I.CON) may be generated for controlling an anisotropic
solidifying head to
solidify, along the anisotropic tool paths, a substantially anisotropic fill
material having an
anisotropic characteristic oriented relative to a trajectory of the
anisotropic fill tool path. As
shown with reference to Figs. 10A-10C, from among the set of shells or layers
defining the
portion of the 3D printed part, a selection of an editing subset of shells or
layers may be received,
the editing subset including at least part of the anisotropic fill subset. For
each shell or layer of
the editing subset, one of second isotropic fill toolpaths different from the
first isotropic fill
toolpaths and second anisotropic fill toolpaths different from the first
anisotropic fill toolpaths
may be regenerated.
[0118] Similarly, a printer for additive manufacturing of a part may include
an anisotropic
solidifying head (e.g., head 10, or 199) that solidifies, along anisotropic
fill toolpaths, fiber
swaths from a supply of anisotropic fiber reinforced material including a
plurality of fiber strands
33
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
extending continuously within a matrix material, the fiber swaths having an
anisotropic
characteristic oriented relative to a trajectory of the anisotropic fill tool
paths. An isotropic
solidifying head (e.g., head 18 or 1800 or 1616) may solidify, along isotropic
fill toolpaths, a
substantially isotropic material from a supply of solidifiable isotropic
material. A motorized
drive as shown in Figs. 1A-1D and 2A-2H may relatively move at least the
anisotropic
deposition head and a build plate supporting a 3D printed part in three or
more degrees of
freedom. A controller 20 may be operatively connected to and configured to
control the
motorized drive, the anisotropic solidifying head and the isotropic
solidifying head, and may
control these to build the 3D printed part by solidifying the isotropic
material along the isotropic
fill tool paths, and/or solidifying the anisotropic fill material in fiber
swaths tracking a non-
concentric set (e.g., quasi-isotropic set 1352-QI, or any of the non-
concentric complementary
sets in Figs. 12-14, all suffixes inclusive) of the of anisotropic fill tool
paths for at least a first
sequence of parallel shells. Further, the controller may control these
elements to solidify the
anisotropic fill material in fiber swaths tracking an outer concentric set
(e.g., 1352-CON, or any
of the concentric layer types shown herein) of anisotropic fill tool paths for
at least a second
sequence of parallel shells. Each of the non-concentric set and the outer
concentric set of
anisotropic tool paths may be located at least partially radially outward from
the centroid of the
3D printed part, as shown in Figs. 4H-4J.
[0119] With respect to the described structures, including all of those
discussed with respect to
Figs. 4A-4J and 5A-5J, the reinforcement volume may include a combined volume
of
reinforcement fiber and a resin matrix within which the reinforcement fiber is
additively
deposited, and the reinforcement volume is less than 20 percent of the entire
reinforced molding.
With reference to embodiments shown herein, the continuous reinforcing fiber
may be additively
deposited simultaneously by a plurality of deposition heads (i.e., in parallel
or substantially in
parallel).
[0120] As discussed with reference to Figs. 4A-4J and 5A-5J, the method of
fabricating a
continuous fiber reinforced injection molding, may include forming a first
shape in a support
material to form a support preform, e.g., using the structures of Figs. 1A-1D,
2A-2H, and 3. As
shown in Fig. 6B, the printer may additively deposit continuous reinforcing
fiber in a second
shape following a contour of the support preform to form a continuous fiber
reinforcement
preform. Further as shown in Fig. 6B, the continuous fiber reinforcement
preform may be
34
CA 03011260 2018-07-11
=
0
WO 2017/124085 PCT/US2017/013748
located within a mold of a molding apparatus. The mold may be loaded with
flowable and
substantially isotropic molding material, and the mold material may be
hardened the molding
material to overmold the continuous fiber reinforcement preform. As a result,
a fiber reinforced
molding or molded article is formed, in which an internal continuous fiber
reinforcement
preform is surrounded by a hardened substantially isotropic molding material.
[0121] The support preform may be formed from, and/or the support material may
include, a
soluble material (e.g., a polymer and/or salt soluble in a solvent), and
further comprising
dissolving the preform. The support preform may be dissolved before locating
the continuous
reinforcement fiber shell within the mold. The support preform may also be
dissolved by the
mold loading, where the support preform material is displaced, melted, or
dissolved by the mold
loading. The support preform may also be dissolved after the mold material is
hardened (in
which case at least one part of the preform shape may extend to be contiguous
with a surface of
the fiber reinforced molding). The support preform may be dissolved in a
combination of these
steps (e.g., partly or in one part before location in the mold, and partly or
in a second part after
the reinforced molding is hardened).
[0122] The support preform may be formed in a rotationally symmetric shape or
mandrel for
winding the continuous fiber reinforcement preform. Alternatively, the support
preform is
formed in a non-looped shape permitting winding the continuous fiber
reinforcement preform
upon the support preform. In this case, a robot arm supporting the fiber
deposition printhead may
reach concave areas of the support preform to deposit or wind the continuous
fiber reinforcement
preform.
[0123] The support preform may be injection molded. The support preform may be
injection
molded as a honeycombed structure, with a contiguous outer surface shell
suitable as a winding
substrate (alternatively, without the contiguous outer surface shell). The
support preform and
continuous fiber reinforcement preform may be formed in successive additive
and injection
molded stages. For example, a honeycomb structure I-NW may be additively
formed from either
a substantially isotropic material additive deposition or by fiber deposition,
followed by insertion
of the honeycomb I-HW into an injection mold for overmolding a substantially
isotropic material
contiguous outer surface shell of the support preform, followed by winding or
surface-following
raster/coverage continuous fiber deposition to cover the contiguous outer
surface shell of the
preform as the continuous fiber reinforcement preform, followed by one of
additive or molding
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
deposition of a final outer shell of substantially isotropic hardened material
of the reinforced
molding. Winding may use at least two translational and one rotational
relative degrees of
freedom between a continuous reinforcement fiber deposition head and the
support preform,
and/or or surface-following coverage additive deposition may use at least
three translational and
one rotational relative degrees of freedom between a continuous reinforcement
fiber deposition
head and the support preform.
[0124] The second shape and/or the continuous fiber reinforcement preform may
embed at least
one sandwich panel structure E-SP1 (e.g., a first laminate of fiber
reinforcement L-CFL, an
intermediate honeycomb I-HW or solid material either of fill material or fiber
reinforcement, and
a second laminate of fiber reinforcement U-CFL substantially parallel to the
first laminate but
spaced therefrom). As shown in Figs. 5K and 5L, the sandwich panel structure E-
SP1 may be a
foldable structure, e.g., with the second laminate U-CFL being continuous and
the first laminate
L-CFL and the intermediate material I-HW having linear gaps formed therein
opposite fold
line(s) in the second laminate to form hinges LH1 (e.g., living hinges if the
fiber reinforcement is
readily bent, or separation/snapping guides if the fiber reinforcement is more
brittle). Optionally
the preform itself embeds at least one sandwich panel structure E-SP1.
[0125] The support preform may be relatively moved in at least one rotational
degree of
freedom with respect to a deposition head that additively deposits the
continuous reinforcing
fiber in the second shape following the contour of the preform to form the
continuous fiber
reinforcement preform.
[0126] The overmolding and/or molding may be performed at a molding material
pressure which
removes air voids within the fiber reinforcement matrix material. The
continuous fiber
reinforcement preform may be bent or deformed from its formation shape to a
deformed shape
within the mold. Two or more continuous fiber reinforcement preforms may be
bonded to one
another before location within the mold. The support preform may be bent or
deformed from its
formation shape to a deformed shape for depositing the fiber reinforcement to
form the
continuous fiber reinforcement preform.
[0127] The mold may be an injection mold, and pack pressure of the injection
molded material
during molding compresses and/or consolidates the fiber reinforcement preform
into a final
shape and/or removes voids within the fiber reinforcement preform. At least in
the case where
36
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
the mold is an injection mold, heat from the injected mold material remelts a
matrix material of
the fiber reinforcement preform.
[0128] The fiber deposition or winding of the continuous fiber reinforcement
preform may be
additively deposited thermoplastic continuous fiber reinforced prepreg tape or
prepreg tow
having a width at least three times its height.
[0129] The described techniques may further include arranging a wide prepreg
sheet against or
on the soluble preform before additively depositing continuous fiber tow or
tape thermoplastic
prepreg.
[0130] The described techniques may further include applying a vacuum during
formation of the
continuous fiber reinforcement preform and/or the molding to remove voids. The
vacuum may
be applied at the part perimeter and if the molding material is injected or
pressurized into the
middle of the part. The continuous fiber reinforcement preform may include
ribs or air channels
to help air escape.
[0131] In a variation, in a method of fabricating a continuous fiber
reinforced injection molding,
continuous reinforcing fiber is additively deposited by the devices of Figs. I
A- ID, 2A-2H and 3
in a second shape following a contour to form a first continuous fiber
reinforcement preform as a
flat or curved "A" panel. The first continuous fiber reinforcement preform may
be located within
a mold of a molding apparatus along a first mold plate, and a second mold
plate formed with a
honeycombed cavity may be located opposite the first continuous fiber
reinforcement preform.
The mold may be loaded with a flowable and substantially isotropic molding
material. The
molding material may be hardened to overmold a honeycomb of the substantially
isotropic
molding material against the continuous fiber reinforcement preform, thereby
forming a fiber
reinforced molding including a hardened substantially isotropic molding
material honeycomb
integrated with the continuous fiber reinforcement preform (optionally the
continuous fiber
reinforcement preform is further enclosed within the molding material).
Subsequently, a
complementary "B" side reinforced fiber panel may be deposited by continuous
fiber deposition
against the honeycomb. Alternatively, a "B" side may be formed as a mirror
process (e.g., first a
continuous fiber reinforced preform, then a honeycomb overmold) then joined or
overmolded
honeycomb-to-honeycomb (preferably with other locating or indexing or
interlocking features).
Further alternatively, the honeycomb mold cavity may be formed in as a soluble
preform upon
which the fiber reinforced preform is deposited, simplifying the second mold
plate to the match
37
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
contours of the honeycomb soluble preform shape. The soluble material is
removed before the A
and B sides are joined.
TUBULAR FRAMEWORK EXAMPLE
[01321 As shown in Figs. 6A and 6B, in composite lay-up of a bicycle frame, in
step CL2
mandrels SMAN-N may be prepared for one or more (N) junctions of tubes (e.g.,
head tube
joining the top tube and down tube; bottom bracket joining the seat tube, down
tube, and chain
stay; or seat post joining the top tube, seat tube, and seat stay; or rear
dropout joining the seat
stay and chain stay). Often, as in step CIA, seven (N=1...7) parts are laid up
and compression
molded about mandrels SMAN-N or other defining shapes as in steps CL6 and CL8
into molded
components COMP-C and finally as in step CL 10 bonded into a unitary frame FRM
(left and
right dropouts, bottom bracket assembly, seat post assembly, head tube
assembly, and v-shaped
chain stay frame, and v-shaped seat stay frame).
[0133] As shown in Figs. 6C and 6D, in an example of contrasting in-mold
assembly of a
reinforced molding RM2 formed by resin overmolding OV3a a fiber reinforced
preform 1342a,
in the present embodiments, an additively deposited soluble preform 1340a may
be printed as in
step AP2 to take the place of a steel mandrel that defines the shape and
surfaces of a frame
component formed as a reinforced molding RM2, and steps may take place in a
different order or
different form.
[0134] For example, each component (e.g., head tube junction component) may
have a soluble
mandrel (soluble preform 1340a) additively deposited (3D printed) by the
printer 1000 as in step
AP2. Pressurizable nylon bladders or heat-activated foam inserts may be
integrated at this time,
or may have been printed over (or printed in an appropriate material). In a
second stage as in step
AP4, a printhead 1402 deposits and/or winds and/or wraps continuous fiber over
the soluble
preform(s) 1340a including bladders or heat-activated foam inserts as
appropriate, including
printing inner or outer guard layers of plastic about the continuous fiber.
During overmolding,
bladders or heat-activated foam may help pressurize the continuously wound
fiber, optionally
against a mold wall, to eliminate internal voids.
[0135] At this stage, as shown in Figs. 6C and 6D, a component assembly
includes a fiber
reinforcement preform 1342a wrapped about a soluble preform, optionally with
the pressure-
increasing features integrated. The soluble preform 1340a, in weight-sensitive
applications, may
38
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
be dissolved away as in step AP6. In other cases the role of the soluble
preform 1340a to allow
winding of the reinforcement preform 1342a is instead taken by a honeycomb,
foam, or low-
density preform that will remain in the final assembly (in addition to any
heat-activated mold
cores). The pressure-increasing features may be left in place.
[0136] As in step AP8, a component including at least the fiber reinforcement
preform 1342a
may be placed inside a mold MLD-2 substantially in the shape of the final
reinforced molding
RM2 (absent molding features such as sprues, runners, etc.). As in step AP8,
the mold MLD-2 is
closed, and any bladders may be connected to pressurized air fittings. As in
step Ap8, the mold
MLD-2 is filled with molding material and pressurized or heated as appropriate
for the molding
technique (e.g., injection molding). Pressure is increased by the bladders
and/or reacting heat-
activated foam cores. If necessary, curing is performed on the reinforced
molding RM2.
[0137] In an alternative, before or instead of overmolding the fiber
reinforced preform 1342a, a
heat-shrinking tape may be printed or wound about the fiber reinforcement
preform 1342a. In
this case, the soluble preform 1340a may be left to provide internal
resistance versus pressure
created by heating and/or curing the heat-shrinking tape. If the component
1342a is not to be
overmolded, once cured, the tape may be removed and the hardened part may be
sanded to its
final diameter and shape (additional layers may be additively printed before
sanding and/or
additively sprayed after sanding). As in step AP10, the components may be
bonded into a whole
(e.g., frame FRM).
[0138] In this framework example, as with any frame or truss example, the
junction components,
whether they have long arms extending from them or short, are distinct from
the entire frame in
that they can be wound or externally traced or printed without a weaving
operation, i.e., the
external surface does not connect with itself in a loop or ring (although the
internal surface may
be a hollow tube or a junction of hollow tubes).
[0139] It should be noted with this example, as with any frame or truss
example, that the
overmolding may be performed on each junction component, and then the
reinforced moldings
RM2 or 1342a joined (e.g., by nesting tubes or shapes, smaller diameter within
larger diameter,
and adhesive or fastener bonding). In an alternative, the fiber reinforcement
preforms RM2 or
1342a may be first joined to one another (again by nesting tubes or shapes,
smaller diameter
within larger diameter or otherwise interlocking, and adhesive or fastener
bonding), and then the
joined assembly overmolded in an entire assembly mold (not shown).
39
CA 03011260 2018-07-11
=
WO 2017/124085 PCT/US2017/013748
[0140] As discussed herein with reference to the continuous fiber
reinforcement preform, in the
case of one, two, or more holes, airflow holes, negative contours, embedded
contours, or
overmolded contours in any reinforced molding component, in many cases
different kinds of
reinforcement will be possible. For example:
(1) Reinforcement of inner walls and hole walls may closely follow the walls,
with or without
layers of fill material shielding the innermost wall to prevent print-through
of fiber. "Holes"
include negative contours and embedded (e.g., overmolded) contours.
(2) Reinforcement of outer walls may closely follow the walls, with or without
layers of fill
material shielding the innermost wall to prevent print-through of fiber, e.g.,
"outer"
reinforcement formations.
(3) Reinforcement may extend along load lines or stress lines, e.g., outer
reinforcement
formation.
(4) Reinforcement for tension load purposes may include multiple straight
composite swaths
between the sites at which the tension load is supported.
(5) Reinforcement for torsion, torque, or pressure load purposes may include
multiple circular
composite swaths along directions of hoop stresses.
(6) Reinforcement for compression load purposes may include multiple
neighboring composite
swaths to provide low aspect ratio cross sections and/or squat structures,
and/or anchors at 1/2, 1/3
fractional, e.g. harmonic lengths to guard vs. buckling; and/or e.g., more
composite swaths for
compression struts than for tension struts.
(7) Reinforcement for twisting may include angular cross bracing in triangle
or X shapes.
(8) Reinforcement for bending or combination load purposes may include
embedded high
moment of inertia (cross section) structures such as sandwich panels, tubes,
boxes, I-beams,
and/or trusses formed from embedded composite swaths. These may be made in
layers spaced
from the centroid of the component cross section, or in outer toolpaths spaced
from the centroid
of the component cross section, depending on the load and the orientation of
the reinforced
molding during printing.
[0141] In general, it is preferable to apply strategies in which compression
and/or layer height
interference of an overlapping or crossing layer (e.g., which may correspond
in part to layer
height) may be set to deposit two highly compressed layers of composite swaths
2c-2, 2c-1, and
to square up corresponding fill material 18a at a height of close to twice the
highly compressed
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
composite swath height. It may also be preferable to permit or create
crossings of toolpaths of
composite swaths 2c-1, 2c-2, and to square up corresponding fill material 18a
at a height of close
to twice the highly compressed composite swath height. Crossings of highly
compressed
composite swaths with one another, and/or crossings of highly compressed
composite swaths
with lightly compressed composite swaths may be used. As shown in the CFF
patent
applications, toolpaths for deposition of core reinforced fiber may be
generated within contours
and sub-contours, and in order to maintain parallel paths, and often follow
offsets of the contours
and sub-contours.
[0142] It should be noted that only some toolpaths, composite swaths 2c,
and/or multi-swath
fiber tracks form "loops", closed "loops", or "crossing turns" as continuously
deposited in a
single layer of an additive manufacturing process. Fig. 7A shows crossing
points or crossing
turns of two fiber swaths in two forms. Any of these loops, crossing points,
closed loops, or
crossing turns may form a portion of a continuous fiber reinforcement preform
as discussed
herein, and may be printed together with fill material and/or onto soluble
material or a soluble
preform.
[0143] Figs. 7A-7F show three examples of crossing turns, i.e., loops or
crossed loops that are
made about internal geometry, such as a hole within a layer (a hole
represented as a negative
contour); and Figs. 7B-7C show two examples that may be crossing turns but
could also be
distributed between two layers. Each represented crossing turn may depict
either a single
composite swath, or a multi-swath track of parallel composite swaths. "Track"
in this context
means closely arranged (often touching), and often parallel swaths, which may
be printed
concentrically, spirally, or in parallel. A track need not have all swaths
parallel throughout its
entire length. The followed hole HO is in each case circular, but may be any
shape having a
perimeter that can be followed by a toolpath (e.g., hexagonal or square). In
Figs. 7A-7F, single
layer or double layer overlaps (i.e., locations where a swath or multi-swath
track is directly over
an underlying swath or multi-swath track within the same printing layer) are
depicted as darker
shade and single swaths or multi-swath tracks as comparatively lighter
shade/transparency). In
several cases, parallel or neighboring entering and exiting swaths or multi-
swath tracks are
depicted as cleanly separated and cleanly on either side of the center line,
but may overlap and/or
cross a center line.
41
CA 03011260 2018-07-11
4
WO 2017/124085 PCT/US2017/013748
[0144] Crossing points made in a same layer, which may be one continuous
composite swath or
different composite swaths, may be referred to as "intra-layer" crossing
points. Crossing points
made between two layers, which in most cases may be different continuous
composite swaths are
referred to as "inter-layer" crossing points. It should be noted that a raster
pattern crossed with
another raster pattern on another layer produces a dense array of inter-layer
crossing points, but
these crossing points do not particularly reinforce any neighboring feature or
contour. As such, a
single inter-layer crossing point (e.g., such as that in Figs. 7E or 7F) or a
small group of inter-
layer crossing points are herein discussed as "isolated crossing points". As
discussed herein,
intra-layer crossing points tend to create protrusions at the crossing point
layers in the case of
composite swaths, less so in the case of extruded fill material alone; while
inter-layer crossing
points do not create such protrusions unless otherwise described.
[0145] Fig. 7B shows a crossing turn made about a hole HO ¨ such as a lace
aperture, airflow
aperture, mesh gap, through-hole, in upper, insole, sole, or orthotic - in
which (i) the swath or
multi-swath track approaches the hole HO approximately parallel to an
(imaginary) line through
its center, axis or centroid, (ii) crosses the line to an opposing side of the
hole, (iii) closely
follows the perimeter of the hole HO, (iv) crosses itself and the line, and
(v) departs from the hole
HO approximately parallel to itself and the line. A diamond-shaped overlap
PR13 is formed,
which may extend above the height of a single swath 2c. A buffer-zone BF15 may
be created or
marked about the overlap. This type of crossing turn closely follows and
reinforces a hole wall
for greater than 300 degrees of arc, and may be the end loop of a larger
pattern. It should be
noted that the entering and exiting swaths 2c or multi-swath tracks are
depicted as cleanly
separated and cleanly on either side of the center line, but may overlap
and/or cross the center
line.
[0146] Fig. 7C shows a crossing turn made about a hole HO ¨ such as an airflow
aperture, mesh
gap, or through-hole - in which (i) the swath 2c or multi-swath track
approaches the hole HO
approximately parallel to an (imaginary) line parallel to a tangent to a
perimeter of the hole HO,
(ii) crosses the line to follow a perimeter of the hole HO, (iii) closely
follows the perimeter of the
hole HO, (iv) crosses itself and (v) departs from the hole HO approximately
along the same line
from which it approached, continuing the entry toolpath. A C-shaped overlap
BF16 is formed,
which may extend above the height of a single swath 2c. A buffer-zone BF16 may
be created or
marked about the overlap. This type of crossing turn closely follows and
reinforces a hole wall
42
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
for greater than 360 degrees of arc, and may be a middle loop in a larger
pattern. It should be
noted that the entering and exiting swaths 2c or multi-swath tracks are
depicted as along the
same line, but may be offset or exit at an angle to the approaching swath 2c
or track. Fig. 7D
shows a crossing turn similar to Fig. 7C, except that (i) the approaching
swath 2c or multi-swath
track is more offset from the (imaginary) tangent to the hole, and so turns
slightly in an S-shape
to approach the tangent at an angle, and similarly (v) departs from the hole
HO in a manner
mirroring the entry. The C-shaped overlap PR15 and buffer zone BF17 may be of
different or
more concave shape.
[0147] Fig. 7E and 7F show overlaps or crossing points adjacent a hole ¨ such
as an airflow
aperture, mesh gap, or through-hole - in which a bight, open loop or touching
loop may be made
away from the reinforced hole HO from which the swath 2c or multi-swath track
returns toward
the hole HO. A different swath 2c or multi-swath track within the same layer
may also form the
return path. In the case of Fig. 7E, (i) the swath 2c or multi-swath track
approaches the hole HO
approximately parallel to an (imaginary) line through its center, axis or
centroid, separated by
approximately a track width, (ii) follows the perimeter of the hole HO, then
(iii) crosses the line
to an opposing side of the hole HO, and (iv) departs from the hole HO
approximately parallel to
itself and the line. Upon returning from the pattern away from the hole HO,
the swath 2c or multi-
swath track (v) crosses itself and the line to an opposing side of the hole
HO, (vi) closely follows
the perimeter of the hole HO, and (vii) departs from the hole HO approximately
parallel to itself
and the line, again separated by a swath or track width. A diamond-shaped
overlap PR16, PR17
is formed, which may extend above the height of a single swath. A buffer-zone
BF18, BF19 may
be created or marked about the overlap PR16, PR17. This type of crossing point
closely follows
and reinforces a hole wall for 240 degrees of arc, and may be the end loop of
a larger pattern. A
crossing point may be complemented by a vertically mirrored version of itself
in a
complementary layer without stacking overlaps or buffer zones. A crossing
point may, in
contrast, approaches the hole closer to the center line and crosses itself at
both sides of the hole.
[0148] At least the following strategies are available for accommodating the
protrusion PR in a
reinforced molding 14 where successive layers are nominally of a consistent
height ¨ for
example, 0.1 mm height. These strategies would in many cases be applied during
slicing and
toolpath or reinforcement formation planning for the reinforced molding 14, in
part so that inter-
layer accommodations may be made. Where the protrusion PR scale (e.g., height
and/or width)
43
CA 03011260 2018-07-11
=
WO 2017/124085 PCT/US2017/013748
is modeled/predicted/empirically known and stored as an absolute or relative
value or a function
of system variables, the overlap PR or a buffer zone BF larger than the
overlap PR may be
marked or planned in the current layer LAS. The protrusion or protrusions may
be one or more
continuous transverse or fiber columns injected, inserted, drilled, drawn,
lain, stitched, guided, or
otherwise deposited to join layers in the Z-axis direction and resist Z-axis
delamination. These
transverse columns may be orthogonal/vertical/perpendicular to one or more 2D
layers LAõ, at
an angle to one or more layers , or curving through one or more layers, or
take paths joining
orthogonal, angled, or curved paths.
(1) Subsequent path planning in the same layer (layer LAõ) may:
(a) avoid crossing the overlap within the same layer (e.g., layer LAõ by
planning toolpaths which
do not cross the overlap, although the new toolpaths may form a crossing
point, jump, crossed
loop or crossing turn forming a new overlap).
(b) plan new toolpaths within the same layer (layer LA,,) separated by more
than the buffer zone.
[0149] Subsequent or integrated path planning for a new, adjacent layer
(LAn+i) adjacent to the
layer in which protrusions are formed (layer LAõ) may:
(c) increase the previous layer height (of layer LAõ) in the overall slicing
approach, and/or
decrease the current layer height (of layer LAn+i). This is most applicable
when no composite
swaths, or composite swaths which do not cross and create protrusions, will be
formed in the
current layer.
(d) path plan composite swaths to avoid overlaps and/or buffer zones in the
layer below (layer
LA,,);
(e) path plan a complementary or partner patterns in the current layer
(LAn.,i) which provide
complementary functionality to a pattern in an adjacent or previous layer
(layer LA.).
[0150] Figs. 8A-8D show patch fills and concentric fills that may be used to
fill in reinforcement
regions as disclosed herein. Any of these patch fills or concentric fills may
form a portion of a
continuous fiber reinforcement preform as discussed herein, and may be printed
together with fill
material and/or onto soluble material or a soluble preform.
[0151] Fig. 8A shows a variation of Fig. 8B in which the toolpath, composite
swath pattern, or
reinforcement formation 99E is of offset approach, with crossovers 0F02 at the
opposite side of
the reinforced molding from the spiral start and end of the spiral strategy
toolpath of Fig. 8B.
44
CA 03011260 2018-07-11
k
=
WO 2017/124085 PCT/US2017/013748
Fig. 8B shows a toolpath, composite swath strategy or reinforcement formation
99F, as a spiral
strategy, excepting that Fig. 8B shows a paired square hole H2 and circular
hole H5.
[0152] Fig. 8C shows a single layer of a densely filled square plate of four
long side members,
with an aperture, space for a stretchable substrate, hole or negative contour
in the middle. In Fig.
8C, as shown, a lengthwise raster fill reinforcement formation 99X surrounds
the contour or
region in the middle. There are many turns in the raster pattern, and two gaps
GAP1 and GAP2
(which may also be stress concentrations, starts, or stops are formed. GAP1 is
formed where the
pattern changes regional groups, and GAP 2 is formed at the end of the
composite swath 2c.
These gaps may also occur if the composite swath 2c length is not perfectly
predicted or
measured. Within the layer, the gaps may be filled with (i) fill material 18a,
(ii) lengths of
composite swath 2c which do not continue the raster fill (e.g., gap filling
patterns, which may be
concentric, wall or region following), (iii) and/or with overlapping composite
swath 2c or
protrusion PR. E.g. in order to fill the GAP1 or GAP2 with overlapping
composite swath 2c,
each raster pattern would be widened to overlap (e.g., wherein the gaps are
closed with
protrusions PR, which may be varied in position among layers as discussed
herein). In Fig. 6D,
two superimposed reinforcement formations 99X, 99X layers are shown, where the
reinforcement formation 99X is rotated by 90 degrees, optionally in the
subsequent layer. The
reinforcement formation 99X may be rotated at 90 degrees, then again, in an
additional two
layers to continue to change the position of the gap, stress concentration,
starts, or stops.
Optionally, the pattern is rotated by 45 degrees in some intervening layers.
[0153] Fig. 9 depicts a flowchart for configuring 3D printer controller and/or
slicer controller
operations to permit multi-layer rule handling, i.e., setting rules for groups
of layers or regions
and changing the members of the rule groups. This routine may be used in
preparing a
continuous fiber reinforcement preform. In step S7602, updating or re-slicing
of toolpaths from
any toolpath, region, or layer setting change is carried out. In step S7604,
as necessary, any
changes in the currently displayed graphical representation resulting from an
updated toolpath
(e.g., change of a layer, group of layers, or volume) are processed and
displayed. In step S7606,
as shown in Figs. 10A-10C, graphical representations of rule groups and end
points of the rule
groups are rendered as orthogonal bar(s) parallel to an edge of a display. In
step S7610, the
display area of the orthogonal bar is monitored for a pointer P01 action
selecting, an entire
CA 03011260 2018-07-11
WO 2017/124085 PCT/IJS2017/013748
group, an endpoint of a group, or a new range within and/or adjacent an
existing group, and the
input handled according to the particular case.
[0154] When an entire group is selected and retaining focus, in step S7613,
one or more interface
elements (e.g., a drop down menu, slider, text or number box, radio button,
check box) are
monitored for input reflecting a change in the rule applied to the selected
entire group, and the
rule change is captured from the input. When an endpoint of a group (e.g., a
group will have at
least two endpoints, but may have any number for non-contiguous groups) is
selected per step
S7614 and retains focus, in step S7618 one or more interface elements (e.g., a
drop down menu,
slider, text or number box, radio button, check box) are monitored for input
reflecting a change
in the position of the endpoint, and therefore a change in the members in the
set of layers or
regions of the group, and the rule change is captured from the input. When a
new range is
formed or is selected per step S7612 and retains focus, in step S7616 one or
more interface
elements (e.g., a drop down menu, slider, text or number box, radio button,
check box) are
monitored for input reflecting a change in the rule applied to the selected
entire group, and the
rule change is captured from the input and the new group created in step
S7620. If the new group
is within a previously existing group, three new groups may be created (e.g.,
the new group
selected as well as one or two fractional remainder groups reflecting that
part of the previously
existing group which was not changed). In each case, in step S7622, the rule
change is applied
and the process proceeds back to step S7602 to update the toolpaths per the
rule change or range
change, as well as the graphical representation (7604) and representation on
the orthogonal bar
(S7606).
[0155] Fig. 10A and 10B show an embodiment of the orthogonal layer topography
bar OB 1.2a
¨ OB 1.2c. This interface may be used in preparing a continuous fiber
reinforcement preform. As
shown and described, like elements throughout the figures are often like
numbered, but some
numbers may be omitted in these views. The description of elements of
substantially identical
appearance in other drawings generally applies to Figs. 10A and 10B, including
the described
associations among displays, processes, and databases. The orthogonal layer
topography bar OB
1.1 is described in the context of exclusive rule sections RS1-RS4 (although
it may be used with
non-exclusive rule sections), Figs. 10A and 10B are described in a context of
rule sections RS7-
RS9 which may overlap. As shown in Figs. 10A and 10B, the orthogonal layer
topography bar
OB1.2 is formed as a set of independent orthogonal subbars OB1.2a/RS7 through
OB1.2c/RS9,
46
CA 03011260 2018-07-11
= s
=
WO 2017/124085 PCT/US2017/013748
each subbar OB1.2a through 1.2c or rule section RS7 through RS9 being
associated with
adjustment handles at each end of each section.
[0156] As shown in Fig. 10A, extending across a lower part of the display
1002, the volume fill
graph section VFG-B display element is a topography representation of
approximately 150
layers. As shown by the position of the thumb TH1, the currently displayed
layer is layer 6
within rule section RS9, within which layers 4-44 and 107-147 include
approximately 25% fiber
fill as shown by the volume fill graph section VFG4, VFG5. As shown, rule
section RS9 is non-
contiguous in two parts, i.e., the display, interface, and database may record
and apply
customized or default rules (toolpath, region, or layer) to non-contiguous but
associated ranges
of toolpaths, regions, or layers. Rule section RS9 is selected via pointer
P01, and is highlighted
between rule adjustment handles HA9 and HA10, and again between handles HA 11
and HAl2,
with annotation AN2 indicating that the common ranges of the rule of the
selected rule section is
layers 4-44 and 107-147, and annotation AN3 indicating that the rule
selectable for an associated
"Volume 1" (e.g., a volume formed by the height of the layers 4-44 and 107-147
and either an
entire layer or a region within a layer) is a "CONCENTRIC FILL" rule (from
among fiber fill
types, with the selectable rule itself being changed, e.g., via the selection
panel 1004). Reflecting
the current index layer, the depicted model shows concentric fill of about 25
percent fiber
content in layer 6 within the rule ranges.
[0157] Fig. 10B shows a set of changes from the state of Fig. 10A of the
display state as well as
corresponding processes and databases. In particular, Fig. 10B shows the
addition of two
additional rule sections RS8 and RS7 to the displays, processes, and
databases. Rule set RS8, for
example, is a rule applicable from layer 3 to 150, in this case, for example,
a rule prescribing the
concentric, inner negative contour following hole wall reinforcement pattern
HR, surrounding
the through-hole W04 which passes through the part in each layer. Rule set
RS7, for example, is
a rule applicable in layers 35 through 70 and 100 through 125, in which
isotropic fill is
prescribed for a particular defined region or volume, or for example for any
area which is not
otherwise subject to a higher priority rule (not that the priority of the
rules could be adjusted,
e.g., by restacking (rearranging) the rule layers RS7, RS8, RS9 such that the
priority order is the
order of the stack). As shown in Fig. 10B, the position of the thumb TH1 is
shifted to layer 61.
The currently displayed layer is layer 50 spanning rule sections RS7, RS8, and
RS9, within
which the displayed layers includes the 25% volume outer perimeter following
concentric fill of
47
CA 03011260 2018-07-11
0
WO 2017/124085 PCT/US2017/013748
rule RS9, the 10% volume circular negative contour perimeter following
concentric fill of rule
RS8, and the 75%+ volume isotropic fill IF, at this level a 45 degree
boustrophedon fill, of rule
RS7. As noted, an isotropic fill IF will have a different angle depending on
the level (e.g.,
rotating among 0, +45, -45, and 90 degrees to form repeating quasi-isotropic
wafers). As shown
by the volume fill graph section VFG6, the 10%, 25%, and 75% volume fill are
additive on
layers where rules overlap, indicating the simultaneous operation of the
rules. Interface element
1E1 is selected via pointer P01, and is shown in a configuration in which the
layers indicated by
annotation AN2, i.e., layers 35-70 and 100-125, may have a common rule
selected for them, in
this case isotropic fill. Similarly to the Fig. 10B, annotation AN2 indicates
that the rule is
selectable for an associated "Volume 3" (e.g., a volume formed by the height
of the layers 35-70
and 100-125, and either an entire layer or a region within a layer) is an
"ISOTROPIC FILL" rule
(from among fiber fill types, with the selectable rule itself being changed,
e.g., via the selection
panel 1004).
[0158] In the case where rules may "overlap" per layer, this may occur in at
least two forms.
First, within a layer, different regions may have independent rules (e.g., as
shown in Fig. 10B,
each of three regions - outer perimeter of three fiber rings, hole
reinforcement of three fiber
rings, and boustrophedon fill of the remainder ¨ may be defined by region).
Second, for any path,
region, layer, or volume, rules may take precedence by a predetermined
priority. One possible
priority for rule category precedence is toolpath rules being of highest
priority, followed by
region rules, then layer rules, then volume or global rules. Within each
category, user
customizations are of higher priority than default rules, other than safety or
minimum
functionality defaults.
[0159] Fig. 10C shows an alternative display approach to that of Fig. 10A-10B.
This display
may be used in preparing a continuous fiber reinforcement preform. The bottom
portion of the
display 1002 is similar to that of Fig. 10A, with the volume fill graph
section VFG-B display
element as a topography representation of approximately 150 layers, the same
as or similar to the
volume fill graphs of Figs. 10A-10B. As shown by the position of the thumb
TH1, the currently
displayed layer is layer 38 within rule section RS9, within which layers 4-44
and 107-147
include approximately 25% fiber fill as shown by the volume fill graph section
VFG4, VFG5. A
3D rendering of the accumulated layers of the part is shown instead of a 2D
layer plan view.
Optionally, the 3D rendering is more transparent with respect to fill
material, walls; and
48
CA 03011260 2018-07-11
WO 2017/124085 PCT/1JS2017/013748
comparatively less transparent for fiber material; optionally with additional
luminance for
highlighted sections of fiber material. As shown, section RS9 is selected via
pointer P01, and a
fiber highlight FHL corresponding to the fiber tracks of rule section RS9 is
arranged and/or
highlighted within the 3D rendering of the part.
[01601 Accordingly, a machine implemented method for displaying 3D printable
model shells on
a display 1002 may include displaying a multidimensional shell of a sliced
model (such as the
2D additive manufacturing layer representations of Figs. 10A through 10C, or
the 3D rendered
additive manufacturing model, mesh, or accumulation of layers representation
of Fig. 10C) on
the display. An orthogonal bar OB1.1, OB1.2 is displayed together with the
displayed shell(s)
parallel to an edge of the display. A first proportional grouping bar RS1¨RS9
is displayed
relative to a first range, similarly/respectively RS1¨RS9 of the orthogonal
bar OB1.1, 0B1.2, the
first proportional grouping bar RS 1¨RS9 representative of a first toolpath
rule (e.g., no fiber,
concentric, isotropic) common to a first range of shells at index positions
within the range. A
movement of a pointer P01 in a direction relative to the display and/or an
actuation of the
pointer is detected (e.g., a mouse click; a touchscreen tap; a button press
associated with pointer).
In response to detecting the movement and/or the actuation of the pointer P01,
one or both of the
toolpath rule or the range is changed. For example, in response, the printer
or its slicer
processing may be configured to change the first toolpath rule common to the
first range of shells
to a different, second toolpath rule common to the first range of shells. In
the alternative or in
addition, the printer or its slicer processing may be configured to change the
first range of shells
to a different, second range of shells having the first toolpath rule common
thereto. Subsequently
or simultaneously, the printer or its slicer processing may be configured to
change the displayed
multidimensional shell of the sliced model so that the change of the toolpath
rule and/or the
change of the range of shells is one of highlighted or displayed.
[0161] Fiber reinforcement strategies, which may in some cases be used in
combination and
which may have sub-strategies, include Concentric Inward, Boustrophedon (ox
rows, also known
as raster, or as isotropic, or quasi isotropic when the direction of rows is
rotated or alternated in
adjacent layers), Concentric Outward, or Sandwich Panel.
[0162] Concentric fill is performed within a layer by first obtaining 80-105%
(preferably 85-
99%) fiber-width offsets from an outer perimeter of a region of the layer.
That is, the offsets
form concentric paths that are 80-105% (preferably 85-99%) of the fiber-width
as laid. One
49
CA 03011260 2018-07-11
W02017/124085 PCT/US2017/013748
advantageous globally set region is the non-wall region adjacent a shell or
wall thickness region
(e.g., 1-3 bonded ranks thick). Fiber is deposited by controlling the
deposition head to stroke the
center of the concentric fiber fill offsets. When the offset has been looped,
an S-shaped, L-
shaped or U-shaped crossover or bend lays fiber into the neighboring offset.
Concentric fill is
suitable for bending and tension loads in particular, and is efficient (fewer
turns) as well as
inherently strong (no fiber separation permits more force to be transmitted
and distributed along
the fiber length). As a global setting, concentric fiber fill may be set to be
adjacent a floor and or
a roof, and/or at a set number of layers from the top and/or bottom of the
part. In the alternative,
spiral or concentric fill may have no particular orientation, as its direction
depends on the
perimeter of the part. Optionally, the concentric fill algorithm may be used
for other strategies
(e.g., for surrounding holes or hole splines for reinforcement). As noted,
other settings can be
used in combination to, e.g., migrate the crossover or bend between layers,
locate crossovers in a
particular place, or repeat or vary concentric fill patterns.
[0163] Ox-row fill or Raster fill is performed in back and forth rows. U.S.
Patent 6,934,600,
herein incorporated by reference in its entirety, discloses various
implementations of raster fill
for nanotube impregnated three dimensional printing. Ox-row fill is performed
by specifying an
orientation of rows (e.g., lengthwise, widthwise, or at a specified angle) and
a region. One
advantageous globally set region is again a non-wall region adjacent a shell
or wall thickness
region. Parallel straight rows, offset by 80-105% (preferably 85-99%) of the
fiber width as laid,
are calculated side by side traversing the region. If a cutter is available
sufficiently close to the
tip of the deposition head, the fibers may be cut at each turn, alternating
turns, every 3 turns,
according to a desired fiber length, and so on. However, a boustrophedon path
is optional.
Boustrophedon paths can be connected at end rows by 180 degree curved fiber
paths of the same
diameter as the offset, and/or by folded paths of two right angles (these may
alternate). Fiber is
again deposited by controlling the deposition head to stroke the center of the
concentric fiber fill
offsets. When the offset has been looped, an S-shaped crossover lays fiber
into the neighboring
offset. As a global setting, ox-row fiber fill may be set to be adjacent a
floor and or a roof, and/or
at a set number of layers from the top and/or bottom of the part. Ox-row fill
may be set to
substantially repeat a direction of fill (for increased cumulative strength in
that direction, or to
provide arbitrary or predetermined patterns of two, three, four or more
varying directions to
increase multi-directional strength (e.g., 90-90 would represent two adjacent
90 degree
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
perpendicular layers; 60-60-60 three adjacent layers each rotated 60 degrees,
45-45-45-45 or 90-
45-90-45 four layers following a repeating pattern of reinforcing
crisscrossing layers).
[0164] In this regard, successive layers of composite may, like traditional
lay-up, be laid down at
00, 45 , 90 , and other desired angles to provide part strength in multiple
directions and to
increase the strength-to-weight ratio. The controller 20 may be controlled to
deposit the
reinforcing fibers with an axial alignment in one or more particular
directions and locations. The
axial alignment of the reinforcing fibers may be selected for one or more
individual sections
within a layer, and may also be selected for individual layers. For example,
as depicted in Figs.
11C and 12 a first layer 1200 may have a first reinforcing fiber orientation
and a second layer
1202 may have a second reinforcing fiber orientation (as may further layers
1204..1206).
Additionally, a first section 1204 within the first layer 1200, or any other
desired layer, may have
a fiber orientation that is different than a second section 1206, or any
number of other sections,
within the same layer.
[0165] Concentric fiber outward fill is distinct in from concentric fill in
that (i) the fiber loops
are offset from an inner perimeter formed by an envelope about features or
parts to be spanned,
rather than outside in. Otherwise, the description with respect to concentric
fill applies as would
be understood by one of ordinary skill in the art. Fill is performed within a
layer by first
determining an interior region to be surrounded, e.g., first obtaining an
envelope about two
features to be circled. Offsets are generated at 80-105% (preferably 85-99%)
fiber-width from an
outer perimeter of the envelope. Fiber is deposited by controlling the
deposition head to stroke
the center of the concentric fiber fill offsets. Any S-shaped, L-shaped or U-
shaped crossovers
may be concentrated on the lengthwise ends, i.e., the curves, of the loops.
Alternatively, as with
concentric, a "spiral" offset of linearly increasing offset distance may be
used to avoid cross-
overs, but a spiral offset typically does not fully wrap features such as
holes. Optionally, the
envelope generation and inner perimeter start may be used for other
strategies. Through-hole fill,
as an example, may treat each hole as an envelope, and extend the fill from
top to bottom of the
part, lining a hole along greater than 80 percent of its top-to-bottom length.
As noted, other
settings can be used in combination to, e.g., migrate the crossover between
layers, locate
crossovers in a particular place, or repeat or vary concentric fill patterns.
[0166] As an example, the embodiment of a part rendered and processed include,
but are not
limited to, the operation of the following rules:
51
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
(i) concentric fiber fill in the region R08 between the outermost wall region
R06 and the
neighboring region R10;
(ii) pure polymer, fill material, or fiber triangular infill in the region
R10, which may be a
remainder region (set after the other regions are defined) extending between
the limits of the
fiber fill region R08 and the negative contour W02, W04 outlining wall regions
R02, R04.
(iii) a sandwich panel, outer shell, inner shell, outer/inner shell, or
cellular rule as
discussed below; and
(iv) a rule to outline or reinforce holes as discussed below, among other
rules.
[01671 In some embodiments, a core reinforced filament 1854 is used to form a
hole (or surround
a protrusion, including a Z-axis direction continuous fiber column orthogonal
to, angled with
respect to, or curving through a layer) directly in a part, soluble preform,
or continuous fiber
reinforcement preform, see Figs. 11A and 11B. More specifically, the core
reinforced filament
1854 comes up to the hole (or protrusion or continuous fiber column), runs
around it, then exits
from the direction it came, though embodiments in which the filament exits in
another direction
are also contemplated. A benefit associated with this formation method is that
the hole is
reinforced in the hoop direction by the core in the core reinforced filament.
As illustrated in Fig.
11A, the core reinforced filament 1854 enters the circular pattern
tangentially. Entering
tangentially is good for screws that will be torqued in. In another version
illustrated in Fig. 11B,
the core reinforced filament 1854 enter the circular pattern at the center of
the circle. Of course,
it should be understood that other points of entering the pattern are also
possible. In one
embodiment, the entrance angle may be staggered in each successive layer. For
example, if there
are two layers, the entering angle of the first layer may be at 0 degrees
while the entering angle
for the second layer may be at 180 degrees. This prevents the buildup of a
seam in the part. If
there are 10 layers, the entering angle may be every 36 degrees (e.g.,
staggering the entering
angle by 360 degrees/10 layers) or any other desired pattern or arrangement.
[01681 Still further alternative or additionally, with reference to Fig. 15,
the controller 20 of the
printer 1000 may control the actuators and heaters such that depositing the
first consolidated
composite swath 2c and the second consolidated composite swath 2c as a
continuous composite
swath 2c spanning (e.g., via inter-layer continuous traverse SP30-A, SF30-B)
two shells LAõ,
LAn+i of an additive manufacturing process. That is, the fiber is not cut but
is continuous
52
CA 03011260 2018-07-11
WO 2d17/124085 PCT/US2017/013748
between two additive fill material layers. This technique may be used in
preparing a continuous
fiber reinforcement preform.
[0169] Still further alternative or additionally, the controller 20 of the
printer 1000 may control
the actuators and heaters such that the first consolidated composite swath 2c
is deposited in a
first reinforcement formation 99A-99Z that has a higher strength in tension
between a first
negative contour (or hole Ha) and a second negative contour (or hole Hb) than
the second
reinforcement formation 99A-99Z.
[0170] The secondary print head 18 prints fill material or soluble material to
form walls, infill,
protective coatings, and/or support material on each layer, and as described
herein, to smooth
over protrusions into neighboring layers, and/or to form a soluble preform.
CONSOLIDATION, COMPRESSION AND/OR FLATTENING OF COMPOSITE SWATHS
[0171] A preferred technique for depositing a core-reinforced filament to
become a fused
composite swath includes compressing a core reinforced filament exiting a
conduit nozzle to
form a flattened shape (as discussed in the CFF patent applications).
[0172] The flattened shape is of variable height-to-width proportion, e.g., in
cross-section from
1:2 through about 1:12 proportion. Preferably, the height of a compressed
composite swath 2c
substantially corresponds to the fill material layer height in the same layer
LAI , so that
neighboring composite swaths 2c in the vertical direction can be tightly
packed, yet be built up
as part of the same or adjacent layers as the surrounding, complementary
and/or interstitial fill
material 18a.
[0173] Inter-layer interaction among composite swaths 2c and fill material 18a
may be more
involved than interlayer interaction among layers of fill material 18a. In
most cases, an optional
requirement for adjacent layers of fill material 18a is that they are
satisfactorily fused in the
vertical direction to avoid delamination, and in many cases the fill material
18a is fused (melted,
or cured) under ambient or room pressure.
[0174] A core-reinforced multi-strand composite filament 2 may be supplied,
for example, as a
circular to oval cross section, and/or of approximately 1/3 mm in diameter
and/or "13 thou"
diameter.
53
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
[0175] As shown in Table 1 below, a circular cross-section filament 2
compressed during
deposition becomes a progressively wider composite swath 2c. The table uses an
example
dimensionless diameter of 3 units for "round numbers".
[0176] As shown in the table, for any size of substantially circular cross
section core reinforced
filament 2, flattening to about 1/3 of its diameter becomes about 2.2 ¨ 2.5
times as wide as its
original diameter, and if flattened to about 1/2 its diameter becomes about
1.4 ¨ 1.7 times its
original diameter.
54
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
TABLE 1
Example Diameter (Circle): 3 units
Rectangle Compression
2/3 D height ¨ 2 ¨ 3 1/2
1/2 D height ¨ 1 1/2 ¨ 4 1/2
1/3 D height ¨1 ¨7
1/4 D height ¨ 3/4 ¨ 9 1/2
[0177] For example, to complement an additive manufacturing layer height of
0.1 mm, a 1/3 mm
diameter core reinforced filament 2 may be flattened to a composite swath 2c
of roughly
rectangular shape of proportion 1:6 through 1:12 (herein "highly compressed"),
e.g., about 0.7 ¨
1.1 mm wide by about 0.07-0.12 mm high. One preferred ratio is roughly 1:9.
Even higher
compression may be possible, e.g., 1:12 to 1:20, but may demand significant
system stiffness in
the printer 100.
[0178] In contrast, to complement an additive manufacturing layer height of
0.2 mm, a 1/3 mm
diameter core reinforced filament 2 may be flattened to a composite swath 2c
of roughly
rectangular shape of proportion 1:1.5 to 1:4 (herein "lightly compressed"),
e.g., about a roughly
rectangular shape of about 0.4 - 0.6 mm wide by about 0.2 mm high.
[0179] However, a fiber-embedded rectangular cross section of 1:1.5 to 1:3 is
not as compressed
or consolidated as one of 1:6 to 1.12 proportion, and in many cases, an
relatively higher amount
of consolidation is preferable to reduce voids and improve mingling of fibers
in adjacent ranks
2c-2c or 2c-2d.
[0180] It should be noted that a supplied fiber reinforced filament 2 may have
a constant cross-
sectional area as supplied and as deposited (unless coextruded or
supplemented); while a
supplied FFF filament 18a has both a very different cross-sectional area as
supplied and as
deposited (having a much larger diameter as supplied), as well as variable
cross-sectional area as
deposited (having a bead size depending on extrusion rate). Given that a
highly compressed
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
composite swath is preferable to a lightly compressed one, combining a larger
FFF extrusion rate
layer height (e.g., 0.3 mm) with a highly compressed composite swath (e.g.,
1:9 ratio) may be
challenging. Accordingly, when a fill material height is such that the amount
of compression is
unacceptably reduced, more than one layer of fiber may be arranged per layer
of fill material
(e.g., 2 or 3 1:9 sublayers of 0.1 mm composite swath 2c per one respective
0.2 or 0.3 mm layer
of fill material 118a). In this case, most or all fill material 18a is
deposited after the composite
swaths 2c; although in an alternative mode self-collision detection may be
used to avoid
contacting the nozzles to the part and the order of deposition thereby varied.
In addition, in a
modification of this process, the fill material height and compression amount
may be selected to
match stacks of 1:6-1:12 "highly compressed" composite swaths 2c (e.g., for a
fiber of 1/3 mm
diameter, the matching fill material 18a layer height capped at approximately
0.24 mm, because
the highest acceptable "highly compressed" stack of two fibers is 1:6 ratio x
2, or 0.12 mm x 2).
[0181] It should be noted that the cross-sectional representation of
reinforcing strands 4a within
filament 2a and deposited swaths 2c are schematic only. In most cases, the
reinforcing strands
are in the hundreds to thousands of parallel strands within the filament 2a or
swaths 2c.
EXTRUSION TOOLPATHS AND/OR EXTRUDATES
[0182] In general, in the "FFF' or "FDM" extrusion method of additive
manufacturing,
extrusion beads in adjacent layers LAõ, LA.,' may be arranged to run either
parallel or
transverse to one another, without crossing while within a layer. A "retract"
may be performed in
the filament feed path to stop nozzle flow and move from one isolated area to
another to restart
extrusion, but the active printing beads tend to remain uncrossed. This is
reasonable, because
continuing to extrude while crossing a previously printed bead may cause
extrudate to jet out
horizontally and unpredictably as the nozzle is partially blocked.
Additionally, any time spent
extruding with a blocked nozzle reduces the amount of active deposition of
extrusion. Slicing
software generally avoids creating extrusion toolpaths which cross one
another.
[0183] However, in the FFF printer discussed herein, extrusion toolpaths may
cross one another
in the same manner as described with respect to core reinforced fiber
toolpaths, partially enabled
by a fast-response clutching in the filament supply for the extrusion head 18,
e.g., a low motor
current or other slippable drive. This is also the case when the fill material
or fiber will form part
of a continuous fiber reinforcement preform. In such a case, crossing
extrusion toolpaths should
56
CA 03011260 2018-07-11
==
= WO 2017/124085
PCT/US2017/013748
cross at a high angle (e.g., from 45-90 degrees) and/or limited to short
periods of time or narrow
existing beads (e.g., for 1/10 to 1/100 of a second, e.g., for a printing
extrusion speed of 300
mnVs, crossing no more than 1 mm of previously solidified extrudate, and
preferably 1/4 to 1/2 mm
of solidified extrudate). This is particularly advantageous in the case of
honeycomb fills of
patterned lines (e.g., triangular tessellation, e.g., of 60-60-60 degree
crossing straight paths,
either with all paths intersecting (e.g., triangular honeycomb or two paths
intersecting with one
path offset (e.g., Star of David network or honeycomb).
[0184] Generally, even the fast-response buffered crossing of a newly extruded
bead or road of
fill material 18a across a previously printed extrusion bead or toolpath may
not change the layer
height of the current layer LAn either on top of the solidified bead crossed
or in the currently
deposited row, i.e., neat plastic does not generally vertically accumulate as
beads are crossed.
Rather, fluidized fill material 18a tends to find a least resistance direction
to escape horizontally
or downward when the extrusion nozzle 18 is blocked by a previously deposited
bead[0185] As
discussed herein, metal and ceramic matrices are also possible, for example as
a matrix with
either the chopped fiber rods, short fiber, long fiber, or continuous
reinforcing fiber, in
approximately 0.1-25% (preferably approx. 5-15%) volume fraction of carbon
fiber strands, each
fiber strand coated with a metal that does not react with carbon at, e.g.,
sintering temperatures or
below (e.g., nickel, titanium boride). In the case of a 3D printing deposition
that is sintered while
or after printing, the ceramic or metal material of the matrix holds the fiber
filler. Carbon fiber is
not the only reinforcing material, e.g., a chopped fiber rods, short fiber,
long fiber, or continuous
reinforcing fiber having approximately 2-10 times the elastic modulus of the
metal or ceramic
matrix material is beneficial. In addition or as an alternative to the chopped
fiber rods, short
fiber, long fiber, or continuous reinforcing fiber, other reinforcing
particles (e.g., particles,
whiskers, nanostructures, spheres or irregular dispersed material) of a
material having
approximately 2-10 times the elastic modulus of the metal or ceramic matrix
material may also
be beneficial.
57
CA 03011260 2018-07-11
=
WO 2017/124085 PCT/US2017/013748
[0186] A comparison of elastic modulus may be found in the following table, of
matrix vs.
reinforcement:
Matrix Elastic Modulus Fill/Fiber Elastic Modulus
09 Arim2, GPa) (1(/ N/m2, GPa)
Steel 180-200 Carbon Fiber 200-600
Aluminum 69 Graphite Fiber 200-600
Copper 117 Boron Nitride 100-400
Titanium 110 Boron Carbide 450
Alumina 215 Silicon Carbide 450
Cobalt 209 Alumina 215
Bronze 96-120 Diamond 1220
Tungsten Carbide 450-650
Graphene 1000
Carbon Nanotube 1000+
[0187] Some candidate matrix-filler combinations that may be deposited by a 3D
printer include
cobalt or bronze matrix with tungsten carbide coated graphite (carbon) fibers;
aluminum matrix
with graphite (carbon) fibers; steel matrix with boron nitride fibers;
aluminum matrix with boron
carbide fibers; aluminum matrix with nickel coated carbon fibers; alumina
matrix with carbon
fibers; titanium matrix with silicon carbide fibers; copper matrix with
aluminum oxide particles
(and carbon fibers); copper-silver alloy matrix with diamond particles. Those
fibers that may be
printed via the techniques of the present application and the CFF Patent
Applications may also
be embedded as continuous fibers. Carbon forms for particles or fibers include
carbon
nanotubes, carbon blacks, short/medium/long carbon fibers, graphite flakes,
platelets, graphene,
carbon onions, astralenes, etc.
[0188] As discussed herein, the 3D printer may additively deposit one or more
of the continuous
reinforcing fiber, soluble preform, or non-soluble support preform in a
reinforcement volume to
form a continuous fiber reinforcement preform. The soluble preform may be
dissolved before
any overmolding. As an additively manufactured body, the preform may be far
more complex
than simply a sheet, panel, or curved panel, the preform may be a "complex
solid", i.e., produced
58
CA 03011260 2018-07-11
,
WO 2017/124085 PCT/US2017/013748
by combining and/or removing parts of three dimensional shapes including at
least some of
cuboids, cylinders, prisms, pyramids, spheres, and cones. The continuous fiber
reinforcement
preform (optionally with a non-soluble support preform) may be located within
a mold of a
molding apparatus, and the mold loaded with molten molding material. The
molding material is
hardened to overmold the continuous fiber reinforcement preform (optionally
with a non-soluble
support preform), thereby forming a reinforced molding surrounding an internal
continuous fiber
reinforcement preform (optionally with a non-soluble support preform) with a
hardened molding
material, wherein the reinforcement volume is smaller than a volume of the
entire reinforced
molding. The continuous fiber reinforcement volume may include a
continuous/random fiber
reinforced composite filament including (a) a plurality of axial fiber strands
extending
substantially continuously within a matrix material of the fiber reinforced
composite filament (b)
a multiplicity of chopped fiber, fiber rods, short fiber, and/or particulates
dispersed throughout
the matrix material. The non-soluble support preform may include the matrix
material and a
multiplicity of chopped fiber, fiber rods, short fiber, and/or particulates
dispersed throughout the
matrix material. The matrix may be plastic, resin, or polymer (e.g., of 1-5
GPa elastic modulus),
metal or ceramic.
[0189] The continuous fiber reinforcement volume may include the
continuous/random fiber
reinforced composite filament and a matrix that may be heated to a liquid
state (e.g., a crystalline
material having a melting temperature, an amorphous material having a glass
transition
temperature, or a semi-crystalline material having both) within which the
continuous/random
fiber reinforced composite filament is additively deposited, and the
reinforcement volume is less
than 20 percent of the entire reinforced molding volume.
[0190] Alternatively, or in addition, the molding is performed at a molding
material pressure
which removes air voids within the fiber reinforcement matrix material.
Further, the continuous
fiber reinforcement preform including the continuous/random fiber reinforced
composite
filament may be bent or deformed from its formation shape to a deformed shape
within the mold.
Further optionally, two or more continuous fiber reinforcement preforms may be
bonded to one
another before location within the mold.
[0191] In some embodiments, the mold is an injection mold, and pack pressure
of the injection
molded material during molding consolidates the fiber reinforcement preform
into a final shape
and removes voids within the fiber reinforcement preform. If the mold is an
injection mold, and
59
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
heat from injected molding material may remelt a matrix material of the fiber
reinforcement
preform. In some examples, the fiber deposition is an additively deposited
thermoplastic
continuous fiber reinforced prepreg tape having a width at least three times
its height, which may
also include the multiplicity of chopped fiber, fiber rods, short fiber,
and/or particulates dispersed
throughout the matrix material. Optionally, vacuum may be applied during at
least one of
formation of the continuous fiber reinforcement preform and the molding to
remove voids.
[0192] In one optional approach, a support material is formed in a first shape
as a support
preform, and the continuous reinforcing fiber is additively deposited in the
reinforcement volume
in a second shape following a contour of the removable support preform to form
a continuous
fiber reinforcement preform. Optionally, at least one part of the support
preform extends to be
contiguous with a surface of the reinforced molding. In another example, the
support preform is
formed in a non-looped shape for permitting additively depositing the
continuous fiber
reinforcement preform by winding about the support preform. The support
preform may itself be
injection molded, and may be injection molded as a honeycombed structure, with
a contiguous
outer surface suitable as a winding substrate. The support preform and
continuous fiber
reinforcement preform may be formed in alternating successive additive and
injection molded
stages. The support preform may be formed from an additively deposited or
injection molded
matrix material, such as plastic, resin, or polymer (e.g., of 1-5 GPa elastic
modulus), metal or
ceramic, and including the multiplicity of chopped fiber, fiber rods, short
fiber, and/or
particulates dispersed throughout the matrix material.
[0193] Optionally, the support preform is formed in a substantially
rotationally symmetric shape
or mandrel for permitting additively depositing the continuous fiber
reinforcement preform by
winding about the support preform. In one embodiment, the support preform is
relatively moved
in at least one rotational degree of freedom with respect to a deposition head
that additively
deposits the continuous and/or continuous/random reinforcing fiber in the
second shape
following the contour of the preform to form the continuous fiber
reinforcement preform.
[0194] A continuous fiber reinforcement preform may embed at least one
sandwich panel
structure. The sandwich panel structure is optionally a foldable structure,
having a linear gap
formed therein opposite a fold line to form a hinge.
[0195] Further optionally, the support preform is formed including a soluble
material, and further
comprising dissolving the preform. The support preform may be dissolved before
locating the
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
continuous reinforcement fiber preform (optionally including the
continuous/random
reinforcement fiber material) within the mold, and/or the support preform may
be one of
displaced, melted, or dissolved by the mold loading. Alternatively, or in
addition, the support
preform may be dissolved after the mold material is hardened. The support
preform may be
dissolved at least in part before location in the mold, and at least in part
after the reinforced
molding is hardened. The support preform may be bent or deformed from its
formation shape to
a deformed ,shape for depositing the fiber reinforcement to form the
continuous fiber
reinforcement preform. In one embodiment, a wide prepreg sheet is arranged
against the support
preform before additively depositing continuous fiber tape prepreg.
[0196] Optionally, the continuous reinforcement preform is located in the
reinforcement volume
following a contour to form the continuous fiber reinforcement preform as a
first reinforced
panel. In this case, a further step or act may be locating a honeycombed panel
of molding
material alongside the first reinforced panel, wherein the molding material is
hardened to
overmold the honeycombed panel against the first reinforced panel, thereby
forming a fiber
reinforced molding including a molding material honeycomb and a continuous
fiber
reinforcement. Optionally, a second reinforced panel is additively continuous
fiber deposited
upon the honeycombed panel. The second reinforced panel may be formed having a
joining
surface mirroring a surface of the first reinforced panel. A honeycomb
structure may be formed
as a support preform upon which the second fiber reinforced preform is
deposited.
[0197] In each case, the molding material may be substantially isotropic in
tensile strength (e.g.,
a resin, metal, or ceramic, including some reinforced with additives), and the
continuous
reinforcing fiber as well as the continuous/random reinforcing fiber are
substantially anisotropic
in tensile strength (e.g., carbon, glass, aramid, basalt, UHMWPE, or other
continuous and/or
long fibers).
[0198] Section headings used herein are dependent upon following content which
they describe,
and can only broaden the content described.
TERMINOLOGY
[0199] A "composite swath" or "composite swath" may refer to a deposited fiber-
reinforced
composite filament, having been compressed, consolidated and widened by
ironing during
61
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
deposition. Extending within the composite swath are a plurality of individual
fibers, from 50-
5000, preferably 100-2000, within a matrix material.
[0200] A "multi-swath track" may refer to a set of parallel swaths that
generally follow parallel
paths, although individual swaths may deviate to avoid obstacles or achieve
reinforcement goals.
[0201] A "fold" may refer to a composite swath which folds, twists, or bunches
over itself along
a curved segment of composite swath (such as a corner). A "fold" is not
limited to sheet-like or
tape-like folds, but includes path changes in which different fibers within
the composite swath
may cleanly switch sides of a swath, but may also cross, twist, or bunch along
the curved or
angled segment (such as a corner).
[0202] A "continuous fiber column" generally means a continuous fiber element
(two, tape,
prepreg, or strands) extending between two or more 3d printed layers
(orthogonal, at any angle,
transverse, or curved), with at least part of the continuous fiber strands
having a Z direction
component bridging two or more layers.
[0203] "Fill material" includes material that may be deposited in
substantially homogenous form
as extrudate, fluid, or powder material, and is solidified, e.g., by
hardening, crystallizing,
transition to glass, or curing, as opposed to the core reinforced filament
discussed herein that is
deposited as embedded and fused composite swaths, which is deposited in a
highly anisotropic,
continuous form. "Substantially homogenous" includes powders, fluids, blends,
dispersions,
colloids, suspensions and mixtures, as well as chopped fiber reinforced
materials. In any case
herein where "fill material" may be replaced with some soluble material or
form a soluble
preform, this disclosure so contemplates. In such a case, as discussed herein,
once the soluble
material is removed, a continuous fiber reinforcement preform remains formed
from continuous
fiber deposition patterns. It should be noted that a coating, wall, shell,
roof, ceiling or other
buffer of non-soluble fill material may remain or be deposited even when the
fill material
discussed is partially or largely substituted with soluble material.
[0204] "Honeycomb" includes any regular or repeatable tessellation for sparse
fill of an area
(and thereby of a volume as layers are stacked), including three-sided, six-
sided, four-sided,
complementary shape (e.g., hexagons combined with triangles) interlocking
shape, or cellular.
[0205] A "Negative contour" and "hole" are used herein interchangeably.
However, either word
may also mean an embedded contour (e.g., an embedded material or object) or a
moldover
contour (e.g., a second object with surfaces intruding into the layer).
62
CA 03011260 2018-07-11
,
WO 2017/124085 PCT/US2017/013748
[0206] "Outwardly spiraling" or "outwardly offsetting" meaning includes that a
progressive
tracing, outlining, or encircling is determined with reference to an
innermost, generally negative
or reference contour, not necessarily that the composite swath mush begin next
to that contour
and be built toward an outer perimeter. Once the toolpath is determined, it
may be laid in either
direction. Similarly, "inwardly spiraling" or "inwardly offsetting" means that
the progressive
tracing is determined with reference to an outer, generally positive contour.
[0207] "3D printer" meaning includes discrete printers and/or toolhead
accessories to
manufacturing machinery which carry out an additive manufacturing sub-process
within a larger
process. A 3D printer is controlled by a motion controller 20 which interprets
dedicated G-code
(toolpath instructions) and drives various actuators of the 3D printer in
accordance with the G-
code.
[0208] "Extrusion" may mean a process in which a stock material is pressed
through a die to take
on a specific shape of a lower cross-sectional area than the stock material.
Fused Filament
Fabrication ("FFF"), sometimes called Fused Deposition Manufacturing ("FDM"),
is an
extrusion process. Similarly, "extrusion nozzle" shall mean a device designed
to control the
direction or characteristics of an extrusion fluid flow, especially to
increase velocity and/or
restrict cross-sectional area, as the fluid flow exits (or enters) an enclosed
chamber.
[0209] A "conduit nozzle" may mean a terminal printing head, in which unlike a
FFF nozzle,
there is no significant back pressure, or additional velocity created in the
printing material, and
the cross sectional area of the printing material, including the matrix and
the embedded fiber(s),
remains substantially similar throughout the process (even as deposited in
bonded ranks to the
part).
[0210] "Deposition head" may include extrusion nozzles, conduit nozzles,
and/or hybrid nozzles.
"Solidifying head" may include the same, as well as laser melting and
solidifying, laser curing,
energy curing. A material need not be liquefied to be solidified, it may be
cured, sintered, or the
like.
[0211] "Filament" generally may refer to the entire cross-sectional area of an
(e.g., spooled)
build material, and "strand" shall mean individual fibers that are, for
example, embedded in a
matrix, together forming an entire composite "filament".
[0212] "Alternating", with respect to reinforcement regions, generally means
in any regular,
random, or semi-random strategy, unless the pattern is described, specified,
or required by
63
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
circumstances, for distributing different formations within or among layers.
E.g., simple
alternation (ABABAB), repeating alternation (AABBAABB), pattern alternation
(ABCD ¨
ABCD), randomized repeating groups (ABCD-CBDA-CDAB), true random selection
(ACBADBCABDCD), etc.
[0213] "Shell" and "layer" are used in many cases interchangeably, a "layer"
being one or both
of a subset of a "shell" (e.g., a layer is an 2.5D limited version of a shell,
a lamina extending in
any direction in 3D space) or superset of a "shell" (e.g., a shell is a layer
wrapped around a 3D
surface). Shells or layers may be nested (within each other) and/or parallel
(offset from one
another) or both. Shells or layers are deposited as 2.5D successive surfaces
with 3 degrees of
freedom (which may be Cartesian, polar, or expressed "delta"); and as 3D
successive surfaces
with 4-6 or more degrees of freedom. Layer adjacency may be designated using
descriptive
notations "LAI ", "LA2" or LA0, LA0.,.1", etc., without necessarily specifying
unique or non-
unique layers. "LAI "may indicate the view shows a single layer, "LA2"
indicating a second
layer, and "LAi, LA2" indicating two layers superimposed or with contents of
each layer visible.
For example, in a top down view, either of "LAI , LA2 , LA3" or "LAn, LAn+i,
LA0+2" may
indicate that three layers or shells are shown superimposed. "LAI, LA2... LA."
may indicate an
arbitrary number of adjacent layers (e.g., m may be 2, 10, 100, 1000, or 10000
layers).
64
CA 03011260 2018-07-11
WO 2017/124085 PCT/US2017/013748
[0214] Some representative Ultimate/Tensile Strength and Tensile/Young's
Modulus values for
reinforcing fibers, core reinforced fiber matrix materials, fill materials,
and comparative
materials are as follows:
Ultimate Strength
Young/Tensile Modulus
MATERIAL MPa GPa
reinforcing strands - UHMWPE- Dyneema, Spectra 2300-3500 0.7
reinforcing strands - Aratnid or Aramid Fiber - Kevlar,
Nomex, Twaron 2000-2500 70.5-
112.4, 130-179
reinforcing strands - Carbon Fiber 4000-4500 300-400
reinforcing strands - Glass Fiber (E, R, S) 3500-4800 70-90
reinforcing strands - Basalt fiber 1300-1500 90-110
Carbon Fiber reinforced plastic (70/30 fiber/matrix,
unidirectional, along grain) 1600 170-200
Glass-reinforced plastic (70/30 by weight fiber/matrix,
unidirectional, along grain) 900 40-50
Steel & alloys ASTM A36 350-450 200
Aluminum & alloys 250-500 65-80
matrix, fill material, solidifiable material- Epoxy 12-30 3.5
matrix, fill material, solidifiable material - Nylon 70-90 2-4
