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Patent 1041994 Summary

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Claims and Abstract availability

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(12) Patent: (11) CA 1041994
(21) Application Number: 208158
(54) English Title: PREWETTING AIR-ATOMIZED POWDERED POLYELECTROLYTES
(54) French Title: MOUILLAGE PREALABLE DE POLYELECTROLYTES ATOMISES A L'AIR
Status: Expired
Bibliographic Data
(52) Canadian Patent Classification (CPC):
  • 259/1
(51) International Patent Classification (IPC):
  • B01F 3/12 (2006.01)
  • B01F 1/00 (2006.01)
  • B01F 5/00 (2006.01)
  • B01F 5/18 (2006.01)
  • B01F 13/10 (2006.01)
  • B01F 15/02 (2006.01)
  • B01J 4/02 (2006.01)
  • C02F 1/68 (2006.01)
(72) Inventors :
  • RICCIARDI, RONALD J. (Not Available)
(73) Owners :
  • RICCIARDI, RONALD J. (Not Available)
(71) Applicants :
(74) Agent:
(74) Associate agent:
(45) Issued: 1978-11-07
(22) Filed Date:
Availability of licence: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): No

(30) Application Priority Data: None

Abstracts

English Abstract



ABSTRACT


A metering and wetting system for polyelectrolyte,
dry powders or the like, characterized by a volumetric feeder,
a pressurized pneumatic system for atomizing the dry poly-
electrolyte received from the volumetric feeder, a mixing-
wetting chamber for wetting substantially all of the atomi??d
particles of polyelectrolyte, and a mixing tank for agitating
and aging the so-called polyelectrolyte to transfer same into
solution with the aid of mechanical agitation and, according
to one aspect of the invention, a scrubber assembly mounted
on the top of the mixing tank.


Claims

Note: Claims are shown in the official language in which they were submitted.




The embodiments of the invention in which an exclu-
sive property or privilege is claimed are defined as follows:


1. A process for metering and wetting polyelectrolyte,
comprising the steps of metering and conditioning powdered poly-
electrolyte, atomizing said powdered polyelectrolyte with a
controlled quantity of compressed air, conveying said atomized
polyelectrolyte to a mixing-wetting chamber, flooding the
internal surfaces of said mixer-wetting chamber with water and
creating a cyclonic turbulence with the atomized powder poly-
electrolyte entering at the medial portion thereof to wet and
dissolve substantially all of the atomized particles of poly-
electrolyte in the water, passing said wetted dissolved
particles of polyelectrolyte to a mixing tank for aging and
completing the transfer of said wetted polyelectrolyte into
solution in said mixing tank, withdrawing unwetted poly-

electrolyte dust in a scrubber assembly and returning said so
wetted particles to said mixing tank.


2. The process for metering and wetting poly-
electrolyte according to Claim 1, simultaneously providing
a negative air draw through said mixing-wetting chamber and
through the upper portion of said mixing tank.


3. The process for metering and wetting poly-
electrolyte according to Claim 1, wherein said unwetted poly-
electrolyte dust is withdrawn from the upper portion of said
mixing tank, passing said dust through a water blanket at the
bottom of said scrubber assembly, while creating a negative
air draw through said scrubber assembly and through said upper
portion of said mixing tank and through said mixing-wetting
chamber.

12



4. The process for metering and wetting poly-
electrolyte according to Claim 1, wherein said unwetted poly-
electrolyte dust is withdrawn from the upper portion of said
mixing tank, passing said dust through screen means covered
with a water blanket, creating a negative air draw at the upper
end of said scrubber assembly extending through said scrubber
assembly and through said upper portion of said mixing tank
and through said wetting chamber, and subjecting the air flow
between said water blanket and a blower to circuitous flow by
baffle means.


5. The process for metering and wetting poly-
electrolyte according to Claim 1, wherein the metering and
conditioning of the powdered polyelectrolyte is effected in
a volumetric feeder and the controlled quantity of water enters
at an angle of about 90° with respect to the atomized product

inlet in said mixing wetting chamber, passing said so-wetted
particles of polyelectrolyte to a mixing tank, and transferring
said wetted polyelectrolyte into solution in said mixing tank
with the aid of mechanical agitation.


6. The process for metering and wetting poly-
electrolyte according to Claim 1, wherein said polyelectrolyte
is introduced into a pneumatic conveyor line at an angle of
about 90° with respect to the flow in said line, atomizing
said polyelectrolyte with a controlled quantity of compressed
air, passing said atomized polyelectrolyte through said
conveyor line to a mixing-wetting chamber, passing said wetted
polyelectrolyte to a first mixing tank with aging from about
10 to about 50 minutes to transfer said polyelectrolyte into
solution in said mixing tank with the aid of mechanical agi-
tation, and transferring the completed solution of polyelectro-
lyte to a second holding tank for use.


13



7. A metering and wetting apparatus, comprising:
volumetric feeder means for receiving powdered polyelectrolyte
and conditioning and metering same; means for supplying a con-
trolled quantity of compressed air; means for atomizing said
powdered polyelectrolyte from said feeder means with said com-
pressed air; means for supplying a controlled quantity of
water; a mixing-wetting chamber for receiving said atomized
powdered polyelectrolyte and said controlled quantity of water
and wetting and dissolving substantially all of the atomized
particles of polyelectrolyte in the water; and a mixing tank
for receiving said so wetted polyelectrolyte, said mixing tank
being of sufficient size to age the wetted dissolved poly-
electrolyte from about ten to about fifty minutes, means for
continuously mechanically agitating the wetted polyelectrolyte
solution during said entire aging period, and a scrubber
assembly mounted on the upper portion of said mixing tank for
withdrawing unwetted polyelectrolyte dust from said mixing

tank and returning said particles wetted to said mixing tank.


8. A metering and wetting apparatus according to
Claim 7, wherein said means for atomizing said powdered poly-
electrolyte from said feeder means with said compressed air
comprises a pneumatic conveyor line, means for supplying com-
pressed air to said line, a tee mounted in said line and having
one leg connected to said volumetric feeder, control means for
controlling the compressed air so that the powdered poly-
electrolyte is atomized in said tee and in said conveyor line.


9. A metering and wetting apparatus according to
Claim 7, wherein said mixing-wetting chamber is vertically
disposed, said mixing-wetting chamber having an upper atomized
dry product inlet for receiving said atomized product from said
means for atomizing the powdered material, said mixing-wetting

14


chamber having a water inlet entering at an angle of about 90°
with respect to the atomized product inlet, means for supplying
a controlled quantity of water to said water inlet, said mixing-
wetting chamber having a lower outlet, whereby substantially all
of the dry particles are wetted and dissolved in said mixing-
wetting chamber and dispensed through said lower outlet.

10. A metering and wetting apparatus according to
Claim 9, wherein said mixing-wetting chamber is of upwardly,
outwardly tapered conical configuration and wherein said water
inlet enters tangentially of said chamber.

11. A metering and wetting apparatus according to
Claim 7, wherein said agitating means include a mechanical low
speed mixer mounted in said mixing tank to provide mechanical
agitation; a second holding tank; piping means interconnecting
said mixing tank with said second holding tank, pumping means
connected to said second holding tank for discharging the poly-
electrolyte solution.

12. A metering and wetting apparatus according to
Claim 7, wherein said scrubber assembly further includes a
blower whose draw is toward the upper end of said housing, an
inlet pipe extending from the bottom of said housing down into
the upper portion of said mixing tank, and means for forming
a water blanket towards the lower end of said inlet pipe.

13. A metering and wetting apparatus according to
Claim 7, wherein said scrubber assembly further includes a
blower suction draw on the upper end of said housing, baffle
means mounted in said housing, an inlet pipe extending from the
bottom of said housing down into the upper portion of said
mixing tank, screen means covering the bottom of the inlet




pipe, and at least one tangentially oriented water inlet pipe
mounted above said screen means to form a water blanket on the
screen means.

16

Description

Note: Descriptions are shown in the official language in which they were submitted.


lQ~9~4

This invention relates to metering and wetting
systems, for dry powders and is particularly adapted, inter
alia, for wetting polyelectrolytes, or the like, which are
basically coagulation aids used in such processes as waste
water treatment, for example. The polyelectrolyte is actually
a polymer which has recently been introduced as an extremely
effective means of coagulation. It replaces certain other
chemicals which have been used for many years, such as alum,
for example. The main advantage of polyelectrolytes is that an
extremely small quantity of this polymer will accomplish what
used to take many hundreds of times the quantity of other
chemicals used for coagulation.
A particular problem occurs in the handling of poly-
electrolyte, which is due to its inherent hygroscopic nature
and the difficulties involved in properly wetting the polymer
and bringing it into solution. Such polymers vary from about
10 to about 50 minutes to "age" after it has been properly
wetted, to transfer into solution. It would appear as though a
very simple method of wetting the polyelectrolyte would be to
meter the polymer directly into a tank and mix it with a mixer.
However, the problem involved with wetting a polyelectrolyte,
or the like, is one created by its extremely hygroscopic
nature. If, for example, one took a handful of polyelectrolyte
and dumped it into a bucket of water, the outer portion of this
clump would wet instantaneously upon contact with the water,
preventing the center core of the lump from being wetted. The
wetted outer area then becomes a viscous shell and will actu-
ally isolate the still dry encapsulated powder. In fact, it
is very difficult to penetrate the outer wetted shell in an
effort to try and wet the dry powder encapsulated therein.
These unwetted particles or globules are generally known, in



-

1~4~994

the trade, as "fish-eyes". Mechanical mixers are also em-
ployed, but have difficulty in breaking down these lumps, par-
ticularly within the allocated period of time required for the
aging process or within allocated process time requirements.
Thus, it is essential that every grain of poly-
electrolyte be wetted in order for a metering/wetting polymer
system to be completely functional.
~n addition, once unwetted particles are created and
exist, the fact that they are very difficult to dissolve and
break up is only part of the problem. Another serious problem
resides in the extremely adhesive nature of improperly wetted
polymer. The unwetted or partially wetted polyelectrolyte
globules will adhere to practically any surface to which it
comes in contact. Therefore, it is easy to realize that in
transporting a polyelectrolyte solution which contains unwetted
or partially wetted particles, there is a tendency for these
particles to agglomerate and adhere to themselves and to the
inside of the pipes, which creates a serious problem. Thus,
in operation, if a polyelectrolyte solution containing these
unwetted particles is permitted to pass through pipe lines,
pumps, etc., clogging will undoubtedly result in a very short
period of time, rendering the system useless. On the other
hand, a properly wetted polyelectrolyte solution does not cause
any handling problems per se.
Applicant has discovered a novel combination of
elements combined in such a way as to afford a very economical,
efficient and practical solution of the difficulties and the
problems above discussed, as will become apparent as the
description proceeds.
Briefly, my invention contemplates the provision of a
new and improved metering and wetting system characterized by a



, . .~

~0419~4 `

volumetric feeder for receiving powdered polyelectrolyte and
supplying metered, conditioned polyelectrolyte to apparatus for
atomizing the polyelectrolyte. The so atomized polyelectrolyte
is passed to a mixing-wetting chamber wherein substantially all
of the atomized particles of polyelectrolyte are wetted and
thence transferred to a mixing tank for aging. After aging the
solution of polyelectrolyte is then ready for use in industry.
In accordance with one aspect of the invention, the
apparatus for atomizing the polyelectrolyte is in the form of a
"tee" which is mounted in a pneumatic conveying line. One
branch of the tee receives the powdered polyelectrolyte from
the outlet of the volumetric feeder and another leg of the tee
receives a controlled quantity of compressed air which inter-
mixes with the powdered polyelectrolyte in the tee and in the
pneumatic line extending from the third leg of the tee to
thereby completely atomize the polyelectrolyte and convey it to
the mixing-wetting chamber.
According to another aspect of my invention, the
mixing-wetting chamber is conical in shape and vertically
mounted with the so atomized polyelectrolyte entering at the
top thereof and a controlled quantity of water entering tan-
gentially through an inlet disposed at about 90 with respect
to the atomized powder inlet. The top of the wetting chamber
is open. The flow of water is carefully controlled and a
selected volume of air is employed to create a positive turbu-
lent wetting action as the water and air combine whereby the
atomized polyelectrolyte particles are completely wetted and
passed through with the water to a lower outlet of the mixing-
wetting chamber. The mixing-wetting chamber is so constructed
that all internal surfaces are flooded with water to limit any
possibility of polymer adhesion and to provide the optimum

104199~
percentage of air to water to polymer relationship without
flooding, clogging, or improper wetting.
According to another aspect of the invention, there
is provided a scrubber assembly mounted on top of the mixing
tank, which is characterized by a cylindrical housing having a
blower mounted on the upper periphery thereof and a plurality
of staggered baffle plates mounted on the internal walls. An
inlet pipe extends from the middle of the bottom of the housing
a short distance down into the mixing tank. A screen covers
the bottom of the inlet pipe and a pair of tangentially
oriented water inlet pipes are mounted above the screen to form
a water blanket on the screen, thereby providing a negative air
draw through the wetting chamber to eliminate dust at this
point, assisting in the inward draw of polymer and water into
the mixing tank and preventing polymer dust from adhering to
the internal areas of the mixing tank.
According to still another aspect of my invention,
the mixing tank which receives the so wetted polyelectrolyte
particles from the mixing-wetting chamber is provided with a
mechanical mixer for mechanically agitating the polyelectrolyte
and to assist with the complete transfer of same into solution.
The foregoing process cycle may operate continuously for as
long as required.
There has thus been outlined rather broadly the more
important features of the invention in order that the detailed
description thereof that follows may be better understood, and
in order that the present contribution to the art better
appreciated. There are, of course, additional features of the
invention that will be described more fully hereinafter. Those
skilled in the art will appreciate that the conception on which
this disclosure is based can readily be utilized as the basis



- . . . . ~ ., .

~04~994

for the designing of other structures for carrying out the
several purposes of the invention. It is important, therefore,
that this disclosure be regarded as including such equivalent
constructions as do not depart from the spirit and scope of the
invention.
Several embodiments of the invention have been chosen
for purposes of illustration and description, and are shown in
the accompanying drawings, forming a part of the specification,
wherein:
Fig. 1 is a side elevation, partially in section, of
a system for metering and wetting polyelectrolyte, constructed
according to the concepts of my invention;
Fig. 2 is a plan view of the system of Fig. l;
Fig. 3 is an enlarged, medial, vertical, sectional
view of a mixing and wetting chamber of the system;
Fig. 4 is a greatly enlarged view showing particles
of polyelectrolyte prior to being wetted and is located on the
sheet showing Figure l;
Fig. 5 is a view similar to Fig. 4, but showing the
particles after being wetted, and is also located on the sheet
showing Figure l;
Fig. 6 is a side elevation, partially in section, of
a system for metering and wetting polyelectrolyte including an
air scrubber, constructed according to the concepts of my
invention;
Fig. 7 is an enlarged sectional view taken along the
line indicated at 7-7 in Fig. 6; and
Fig. 8 is an enlarged, medial sectional view of the
lower portion of the air scrubber shown in Fig. 6.
In the embodiment of the invention illustrated in
Figs.l to 5, the system for metering and wetting polyelectro-



. .

~(~41994

lytes comprises a volumetric feeder indicated generally at 10,
such as the one described in my U.S. Patent No. 3,1$6,602, for
example,issued June 1, 1965 which includes a gin 12 for
- receiving powdered polyelectrolyte or the like to be processed,
and which feeds into a conditioning chamber 14 containing a
pair of concentric augers 16 and 18, Fig. 2, which condition
and meter a predetermined volume of material out through a dis-
charge conduit 20. An electric motor 22 serves to drive the
augers through a variable speed or constant speed drive 24.
The discharge of the volumetric feeder meters the
polymer into a "tee" 26, Fig. 2, which is located in a pneu-
matic conveying line 28. Either compressed air or a blower
unit 30 moves air through the line to atomize the powdered
polyelectrolyte and convey it to a mixing-wetting chamber 32.
A valve 33 serves to control the flow of air, as will be
described more fully hereinafter.
; As best seen in Figs. 1 and 3, the mixing-wetting
chamber is mounted vertically, and is of conical configuration,
with a water inlet 34 entering tangentially at about 90 with
respect to an atomized product nozzle-like inlet 36. As the
air carrying the polymer is forced into the mixing-wetting
chamber 32 under a few pounds of pressure, a cyclonic turbu-
lence is created as the air comes into contact with the flowing
water and the tapered portion of the mixing-wetting portion.
This turbulence generates through mixing action. Water is
supplied through an inlet pipe 38 containing a valve 40, flow
meter 42 and a second valve 44 for accurately controlling the
flow therethrough. Thus, as seen in Fig. 3, atomized product
46 vertically enters the mixing-wetting chamber while water 48
enters the chamber horizontally. Within this cyclonic mixing-
wetting chamber, as indicated at 50, basically each and every

- ~04199~

particle of the polymer is thoroughly wetted and thence dis-
pensed through an outlet pipe 52 extending a short distance,
such as about six inches for example, down into a mixing or
aging tank 54 mounted thereunder. As shown in Fig. 4, the
. .
particles of polymer 56 arrive at the mixing-wetting chamber
inlet as an atomized product 46 and when they leave the chamber
each particle of the polymer is thoroughly wetted by the water
48, as shown in Fig. 5. It will be appreciated that the
mixing-wetting chamber 32 is so constructed that all internal
surfaces are flodded with water to eliminate any possibility of
polymer adhesion and to provide the optimum percentage of air
to water to polymer relationship without flooding, clogging or
improper wetting. The volume of air is so controlled, by valve
33 that it passes through without back pressure, thus providing
a wetting action whereby the atomized polyelectrolyte particles
are completely wetted in a cyclonic fashion and passed through
with the water to the mixing tank 54 therebelow.
As best seen in Fig. 1, the mixing tank 54 is pro-
vided with a mechanical mixer 57 powered by an electric motor
58. The purpose of the mixing tank is to provide mechanical
assistance through positive mechanical agitation and to provide
, sufficient ti~e for the aging process, which may take from
about ten to about fifty minutes, usually about 15 to about 20
minutes, depending on the particular polyelectrolyte to com-
pletely transfer into solution. However, it is important that,
as the material enters this mixing or aging tank, the solution
is continuously mechanically agitated during this aging period.
`~ Once this has been completed, the material may remain in the
tank for a number of hours without any difficulty,such as up to
about 48 hours, for example. The mixing tank is provided with
an outlet pipe 60 and an outlet valve 62. A second similar or
-- 7


.. . .


104199~
holding tank 64 may be mounted adjacent to or underneath said
mixing tank and is provided for receiving all of the contents
of the first mixing tank 54 after the polymer has gone into
solution. A pump 66 is utilized to draw the polyelectrolyte
solution from the second mixing tank 64 and introduce it into
the process wherein the polyelectrolyte is being used as a
coagulate. The foregoing process cycle is continuous for as
long as required. Since the system operates basically on a
batch basis, the solution is normally only prepared on demand,
the demand being the amount used in the water purification
process. Accordingly, a second or holding tank is employed so
that, after the polyelectrolyte solution is complete, it is
automatically discharged into the holding tank, once the level
in the holding tank is low enough to permit the entire contents
.
: 15 of the mixing tank to be dumped. The polyelectrolyte solution
is then pumped into the process from the holding tank. As will
be appreciated, the mixing or aging tank is the preparation
tank for the solution, and the frequency of this cycle is based
on the process usage of the solution, as drawn off from the
~ 20 holding tank. For example, if the usage is very small, it may
; be necessary to prepare only one solution per day, or perhaps
even longer.
In order to provide for the complete wetting of all
polymers, if a small percentage thereof does happen to escape
the initial wetting process, and to further eliminate the
escape of loose unwetted particles of polymer into the mixing
` tank, which would adhere to the internal surfaces thereof, the
~` system as illustrated in Figs. 6 and 8 is equipped with a
scrubber assembly, as indicated generally at 68, which draws
the majority of its air supply through the wetting chamber.
This scrubber assembly serves multiple purposes;
.. ' .
~ - - 8 -
'
,.. ~ . ...

109~1994

firstly, it provides a negative air draw through the wetting
chamber thereby eliminating dust at this point; secondly, the
scrubber aids in the effectiveness of the mixing function in
the wetting chamber by providing inward draw of polymer and
5 water; and thirdly, the scrubber maintains a slight negative
- draw in the mixing tank thereby eliminating the possibility of
unwetted polymer dust blowing about and/or adhering to the
internal areas. In operation, the scrubber assembly draws
unwetted particles of polymer therethrough which, in turn,
10 results in the complete wetting of any remaining particles of
powder.
The scrubber assembly, as seen in Fig. 6, comprises a
` housing 70 having blower suction on the upper periphery there-
of, as at 74, and a plurality of staggered baffle plates 76 are
15 mounted on the internal walls. An inlet pipe 78 extends from
the bottom of the housing 70 downwardly through a cover 79, and
thence a short distance, of the order of about six inches,
s downwardly into the mixing tank 54. As seen in Fig. 8, the
screen 80, having a 20 mesh size, completely covers the bottom
-: 20 of the scrubber inlet pipe 78. Water, under pressure, supplied
from any convenient source, enters the scrubber assembly
through a pair of tangentially oriented inlet pipes 82 located
a short distance above the screen 80 with a generally centrifu-
~ gal motion, as indicated by the arrows 84 in Fig. 7. The
; 25 screen serves to form a water blanket 86 thereabove, as best
seen in Fig. 8. It is noted that the pipes 52 and 78 terminate
in an upper portion 88 above the surface of the solution of
. polyelectrolyte in the mixing tank 54.
In operation, the blower 72 draws air and any un-
30 wetted polymer contained therein from the wetting chamber,
through the pipe 52 and from the upper portion 88 of the mixing

g


.. . . . ...


9~4
tank 54. This air is drawn up through the water covered screen
80 and any unwetted particles of polymer are effectively
- trapped, wetted, and dropped into the mixing tank. The air is
then drawn up through the cylindrical housing 70 through the
-5 baffle arrangement 76, where the moisture contained therein is
removed, and then out through the blower 72 and discharged from
the outlet 92 into the atmosphere. Thus, the discharge from
the blower is only clean air.
Tests indicate that when processing certain types of
polyelectrolyte, the quantity of unwetted polymer passing
through the wetting chamber may vary up to a maximum of about
1.5%. This percentage is completely dependent upon the mesh or
~; particle size of the polymer, which is reflected in its ability
to atomize. The larger the particle size, the higher the
wetting percentage and the lower the amount of unwetted
polymer. The scrubber, however, does provide for 100% wetting
by trapping and wetting any remaining polymer material which
escapes the initial wetting process. Thus, the scrubber serves
to draw air through the system thereby restricting the escape
of dust contained therein and preventing buildup of particles
of polymer on the bottom of the cover 79 and on the walls of
- the upper portion 88 of the mixing tank 54.
It will thus be seen that the present invention does
indeed provide an improved metering and wetting system which is
superior in simplicity, operability, reliability and efficiency
as compared to prior art such devices. The combination of the
feeder-atomizing portion, the wetting chamber portion and the
scrubber portion cooperate to provide a complete self-cleaning
and very effective polymer metering and wetting system.
Although particular embodiments of the invention are
herein disclosed for purposes of explanation, various modifi-
: .,
- 1 0 -


. .

1041994
. - cations thereof, after study of the specification will be
apparent to those skilled in the art to which the invention
pertains.




.

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Representative Drawing

Sorry, the representative drawing for patent document number 1041994 was not found.

Administrative Status

For a clearer understanding of the status of the application/patent presented on this page, the site Disclaimer , as well as the definitions for Patent , Administrative Status , Maintenance Fee  and Payment History  should be consulted.

Administrative Status

Title Date
Forecasted Issue Date 1978-11-07
(45) Issued 1978-11-07
Expired 1995-11-07

Abandonment History

There is no abandonment history.

Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
RICCIARDI, RONALD J.
Past Owners on Record
None
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Drawings 1994-05-24 3 78
Claims 1994-05-24 5 158
Abstract 1994-05-24 1 15
Cover Page 1994-05-24 1 13
Description 1994-05-24 11 388