Note: Claims are shown in the official language in which they were submitted.
The embodiments of the invention in which an exclusive
property or privilege is claimed are defined as follows:
1. A process of accelerating the setting time of a
quantity of portland cement composition for a particular water-
cement ratio, comprising the steps of:
(a) providing, as a chemical admixture, an .alpha.-hydroxy
carbonyl compound selected from the group consisting
of hydroxyacetic acid and its sodium, potassium
lithium, zinc and triethanolamine salts; sodium 2-
methyllactate; sodium dl-mandelate; and mixtures
thereof; and
(b) admixing with said cement composition an amount
of said .alpha.-hydroxy carbonyl compound sufficient to
accelerate the setting time of the portland cement
composition, at such water-cement ratio, as compared
with its setting time in the absence of any admixture.
2. The process according to claim 1 in which said
chemical admixture, and portland cement are essentially the only
constituents of the composition affecting its setting time.
3. The process according to claim 1 in which said
chemical admixture, portland cement, and water are essentially
the only constituents of the composition affecting its setting
time.
4. The process according to claim 3 in which the
.alpha.-hydroxy carbonyl compound is sodium hydroxyacetate.
5. The process according to claim 4 in which the
concentration of the sodium hydroxyacetate relative to the
cement is in a range whereby the final setting time of the
composition as measured by the Vicat Needle test is less than
one hour.
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6. The process according to claim 5 in which the
portland cement composition includes a quantity of water to
constitute a cement paste and the concentration of the sodium
hydroxyacetate relative to the cement is in the range of from
about 0.5 to about 10 weight percent.
7. The process according to claim 5 in which the
portland cement composition includes quantities of water and
aggregate to constitute a mortar or a concrete and the concen-
tration of the sodium hydroxyacetate relative to the cement
is in the range of from about 1.1 to about 10 weight percent.
8. A process of accelerating the setting time of a
quantity of portland cement composition for a particular water-
cement ratio, comprising the steps of:
(a) providing, as a chemical admixture, an .alpha.-hydroxy
carbonyl compound selected from the group consisting
of hydroxyacetic acid and its sodium, potassium, lithium,
zinc and triethanolamine salts; lactic acid and its
sodium, potassium and calcium salts; sodium 2-methyl-
lactate; sodium dl-mandelate; and mixtures thereof;
and
(b) admixing with said cement composition an amount
of said .alpha.-hydroxy carbonyl compound sufficient to
accelerate the setting time of the portland cement
composition, at such water-cement ratio, as compared
with its setting time in the absence of any admixture;
wherein said chemical admixture, portland cement, and water are
essentially the only constituents of the composition affecting
its setting time.
9. The process according to claim 8 in which the
.alpha.-hydroxy carbonyl compound is sodium lactate.
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10. The process according to claim 8 in which the
concentration of the .alpha.-hydroxy carbonyl compound relative to
the cement is in a range whereby the final setting time of the
composition as measured by the Vicat Needle test is less than one
hour.
11. A process of preparing a quantity of portland
cement composition for shotcreting, comprising the steps of:
(a) providing, as a chemical admixture, an .alpha.-
hydroxy carbonyl compound selected from the group con-
sistingof hydroxyacetic acid and its sodium, potassium,
calcium, lithium, zinc, and triethanolamine salts;
sodium 2-methyllactate; sodium dl-mandelate; and mix-
tures thereof;
(b) mixing portland cement, aggregate, and water to
form a quantity of shotcrete having a particular
water-cement ratio; and
(c) admixing with the portland cement, aggregate, and
water an amount of said .alpha.-hydroxy carbonyl compound
sufficient to accelerate the final setting time as mea-
sured by the Proctor Needle test, at such water-cement
ratio, to a value of less than fifteen minutes, the
setting time of the shotcrete thereby being accelerated
as compared with its setting time in the absence of any
admixture.
12. The process according to claim 11 in which said
chemical admixture, aggregate, water, and portland cement are es-
sentially the only constituents of the composition affecting its
setting time.
13. The process according to claim 12 in which the
.alpha.-hydroxy carbonyl compound is calcium hydroxyacetate.
14. The process according to claim 12 in which the
concentration of the .alpha.-hydroxy carbonyl compound relative to the
cement is in the range of from about 1.1 to about 10 weight
percent.
15. A process of preparing a quantity of portland
cement composition for shotcreting, comprising the steps of:
(a) providing, as a chemical admixture, an .alpha.-hydroxy
carbonyl compound selected from the group consisting of
hydroxyacetic acid and its sodium, potassium, lithium,
zinc, and triethanolamine salts; sodium 2-methyllactate;
sodium dl-mandelate; and mixtures thereof;
(b) mixing portland cement, aggregate, and water to
form a quantity of shotcrete having a particular water-
cement ratio; and
(c) admixing with the portland cement, aggregate,
and water an amount of said .alpha.-hydroxy carbonyl compound
sufficient to accelerate the final setting time as
measured by the proctor Needle test, at such water-
cement ratio, to a value of less than fifteen minutes,
the setting time of the shotcrete thereby being acceler-
ated as compared with its setting time in the absence of
any admixture.
16. The process according to claim 15 in which said
chemical admixture, aggregate, water, and portland cement are
essentially the only constituents of the composition affecting
its setting time.
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17. The process according to claim 16 in which the
concentration of the .alpha.-hydroxy carbonyl compound relative to the
cement is in the range of from about 1.1 to about 10 weight
percent.
18. A process of preparing a quantity of portland
cement composition for shotcreting, comprising the steps of:
(a) providing, as a chemical admixture, an a-
hydroxy carbonyl compound selected from the group con-
sisting of hydroxyacetic acid and its sodium, potassium,
calcium, lithium, zinc, and triethanolamine salts; lac-
tic acid and its sodium, potassium, and calcium salts;
sodium 2-methyllactate; sodium dl-mandelate; and mix-
tures thereof;
(b) mixing portland cement, aggregate, and water
to form a quantity of shotcrete having a particular
water-cement ratio; and
(c) admixing with the portland cement, aggregate, and
water an amount of said .alpha.-hydroxy carbonyl compound
sufficient to accelerate the final setting time as meas-
ured by the Proctor Needle test, at such water-cement
ratio, to a value of less than fifteen minutes, the
setting time of the shotcrete thereby being accelerated
as compared with its setting time in the absence of
any admixture;
wherein said chemical admixture, aggregate, water, and portland
cement are essentially the only constituents of the composition
affecting its setting time.
19. The process according to claim 18 in which the
concentration of the .alpha.-hydroxy carbonyl compound relative to the
cement is in the range of from about 1.1 to about 10 weight per-
cent.
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20. A portland cement concrete patching compound mixable
with water to a selected water-cement ratio and comprising
portland cement, aggregate, and, as a chemcial admixture, an
.alpha.-hydroxy carbonyl compound selected from the group consisting of
hydroxyacetic acid and its sodium, potassium, lithium, zinc, and
triethanolamine salts; sodium 2-methyllactate; sodium dl-mandelate;
and mixtures thereof; the concentration of the .alpha.-hydroxy carbonyl
compound relative to the cement being sufficient to accelerate
the final setting time, as measured by the Vicat Needle test at
such water-cement ratio, to a value of less than one hour, the
setting time of the concrete patching compound thereby being
accelerated as compared with its setting time in the absence of
any admixture.
21. The portland cement concrete patching compound
according to claim 20 in which said chemical admixture, aggregate,
and portland cement are essentially the only constituents of the
composition affecting its setting time.
22. A portland cement quick-setting-mortar compound
mixable with water to a selected water-cement ratio and comprising
portland cement, aggregate, and, as a chemical admixture, an .alpha.-
hydroxy carbonyl compound selected from the group consisting of
hydroxyacetic acid and its sodium, potassium, calcium, lithium,
zinc, and triethanolamine salts; sodium 2-methyllactate; sodium
dl-mandelate; and mixtures thereof; the concentration of the
.alpha.-hydroxy carbonyl compound relative to the cement being
sufficient to accelerate the final setting time, as measured by
the Vicat Needle test, at such water-cement ratio, to a value of
less than thirty minutes, the setting time of the quick-setting-
mortar compound thereby being accelerated as compared with its
setting time in the absence of any admixture.
23
23. The portland cement quick-setting-mortar compound
according to claim 22 in which said chemical admixture, aggregate,
and portland cement are essentially the only constituents of the
composition affecting its setting time.
24. A portland cement plugging compound mixable with
water to a selected water-cement ratio and comprising portland
cement, aggregate, and, as a chemical admixture, and .alpha.-hydroxy
carbonyl compound selected from the group consisting of hydroxy-
acetic acid and its sodium, potassium, calcium, lithium, zinc,
and triethanolamine salts; sodium 2-methyllactate; sodium dl-
madelate; and mixtures thereof; the concentration of the .alpha.-hydroxy
carbonyl compound relative to the cement being sufficient to
accelerate the final setting time, as measured by the Vicat Needle
test, at such water-cement ratio, to a value of less than fifteen
minutes, the setting time of the plugging compound thereby being
accelerated as compared with its setting time in the absence of
any admixture.
25. The portland cement plugging compound according to
claim 24 in which said chemical admixture, aggregate, and port-
land cement are essentially the only constituents of the com-
position affecting its setting time.
26. A portland cement concrete patching compound mixable
with water to a selected water-cement ratio and consisting
of portland cement, aggregate, and, as a chemical admixture,
an .alpha.-hydroxy carbonyl compound selected from the group consisting
of hydroxyacetic acid and its sodium, potassium, lithium, zinc,
and triethanolamine salts; lactic acid and its sodium, potassium,
and calcium salts; sodium 2-methyllactate; sodium dl-mandelate;
and mixtures thereof; the concentration of the a-hydroxy
carbonyl compound relative to the cement being sufficient to accel-
24
erate the final setting time, as measured by the Vicat Needle
test at such water-cement ratio, to a value of less than one
hour, the setting time of the concrete patching compound thereby
being accelerated as compared with its setting time in the absence
of any admixture.
27. A portland cement quick-setting-mortar compound
mixable with water to a selected water-cement ratio and consis-
ting of portland cement, aggregate, and, as a chemical admixture,
an .alpha.-hydroxy carbonyl compound selected from the group consisting
of hydroxyacetic acid and its sodium, potassium, calcium, lithium,
zinc, and triethanolamine salts; lactic acid and its sodium,
potassium, and calcium salts; sodium 2-methyllactate; sodium
dl-mandelate; and mixtures thereof; the concentration of the
.alpha.-hydroxy carbonyl compound relative to the cement being
sufficient to accelerate the final setting time, as measured by
the Vicat Needle test, at such water-cement ratio, to a value of
less than thirty minutes, the setting time of the quick-setting-
mortar compound thereby being accelerated as compared with its
setting time in the absence of any admixture.
28. A portland cement plugging compound mixable with
water to a selected water-cement ratio and consisting of portland
cement, aggregate, and, as a chemical admixture, an .alpha.-hydroxy
carbonyl compound selected from the group consisting of hydroxy-
acetic acid and its sodium, potassium, calcium, lithium, zinc,
and triethanomlaine salts; lactic acid and its sodium, potassium,
and calcium salts; sodium 2-methyllactate; sodium dl-mandelate;
and mixtures thereof; the concentration of the .alpha.-hydroxy carbonyl
compound relative to the cement being sufficient to accelerate the
final setting time, as measured by the Vicat Needle test, at
such water-cement ratio, to a value of less than fifteen minutes,
the setting time of the plugging compound thereby being
accelerated as compared with its setting time in the absence
of any admixture.
29. The portland cement concrete patching compound
according to claim 20 in which the concentration of the .alpha.-hydroxy
carbonyl compound relative to the cement is in the range of
from about 1.1 to about 10 weight percent.
30. The portland cement quick-setting-mortar compound
according to claim 22 in which the concentration of the .alpha.-hydroxy
carbonyl compound relative to the cement is in the range of from
about 1.1 to about 10 weight percent.
31. The portland cement plugging compound according to
claim 24 in which the concentration of the .alpha.-hydroxy carbonyl
compound relative to the cement is in the range of from about 1.1
to about 10 weight percent.
32. The portland cement concrete patching compound
according to claim 26 in which the concentration of the .alpha.-hydroxy
carbonyl compound relative to the cement is in the range of from
about 1.1 to about 10 weight percent.
33. The portland cement quick-setting-mortar compound
according to claim 27 in which the concentration of the .alpha.-hydroxy
carbonyl compound relative to the cement is in the range of from
about 1.1 to about 10 weight percent.
34. The portland cement plugging compound according to
claim 28 in which the concentration of the .alpha.-hydroxy carbonyl
compound relative to the cement is in the range of from about 1.1
to about 10 weight percent.
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35. A portland cement concrete patching compound mixable
with water to a selected water-cement ratio and consisting
essentially of portland cement, aggregate, and, as a chemical
admixture, an .alpha.-hydroxy carbonyl compound selected from the group
consisting of hydroxyacetic acid and its sodium, potassium,
lithium, zinc and triethanolamine salts; lactic acid and its
sodium, potassium, and calcium salts; sodium 2-methyllactate;
sodium dl-mandelate; and mixtures thereof; the concentration of
the .alpha.-hydroxy carbonyl compound relative to the cement being
sufficient to accelerate the final setting time, as measured by
the Vicat Needle test at such water-cement ratio, to a value of
less than one hour, the setting time of the concrete patching
compound thereby being accelerated as compared with its setting
time in the absence of any admixture, the portland cement and
the .alpha.-hydroxy carbonyl compound being the only constituents
of the concrete patching compound influencing its setting time.
36. A portland cement quick-setting-mortar compound
mixable with water to a selected water-cement ratio and consisting
essentially of portland cement, aggregate, and, as a chemical
admixture, an .alpha.-hydroxy carbonyl compound selected from the
group consisting of hydroxyacetic acid and its sodium, potassium,
calcium, lithium, zinc, and triethanolamine salts; lactic acid and
its sodium, potassium, and calcium salts; sodium 2-methyllactate;
sodium dl-mandelate; and mixtures thereof; the concentration of
the .alpha.-hydroxy carbonyl compound relative to the cement being
sufficient to accelerate the final setting time, as measured by
the Vicat Needle test, at such water-cement ratio, to a value of
less than thirty minutes, the setting time of the quick-setting-
mortar compound thereby being accelerated as compared with its
setting time in the absence of any admixture, the portland
cement and the .alpha.-hydroxy carbonyl compound being the only constitu-
ents of the quick-setting-mortar compound influencing its
27
setting time.
37. A portland cement plugging compound mixable with
water to a selected water-cement ratio and consisting essentially
of portland cement, aggregate, and, as a chemical admixture,
an .alpha.-hydroxy carbonyl compound selected from the group consisting
of hydroxyacetic acid and its sodium, potassium, calcium, lithium,
zinc, and triethanolamine salts; lactic acid and its sodium,
potassium, and calcium salts; sodium 2-methyllactate; sodium
dl-mandelate; and mixtures thereof; the concentration of the
.alpha.-hydroxy carbonyl compound relative to the cement being
sufficient to accelerate the final setting time, as measured by
the Vicat Needle test, at such water-cement ratio, to a value of
less than fifteen minutes, the setting time of the plugging
compound thereby being accelerated as compared with its setting
time in the absence of any admixture, the portland cement and the
.alpha.-hydroxy carbonyl compound being the only constituents of the
plugging compound influencing its setting time.
28