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Patent 1081919 Summary

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(12) Patent: (11) CA 1081919
(21) Application Number: 276941
(54) English Title: FEED SYSTEM FOR PYROLYSIS REACTORS
(54) French Title: SYSTEME D'ALIMENTATION POUR REACTEURS A PYROLYSE
Status: Expired
Bibliographic Data
(52) Canadian Patent Classification (CPC):
  • 202/40
  • 23/400
(51) International Patent Classification (IPC):
  • C10B 49/16 (2006.01)
  • B01J 8/00 (2006.01)
  • C10B 49/20 (2006.01)
(72) Inventors :
  • LOGAN, FORREST E. (United States of America)
(73) Owners :
  • OCCIDENTAL PETROLEUM CORPORATION (Not Available)
(71) Applicants :
(74) Agent: SMART & BIGGAR
(74) Associate agent:
(45) Issued: 1980-07-22
(22) Filed Date: 1977-04-26
Availability of licence: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): No

(30) Application Priority Data:
Application No. Country/Territory Date
683,301 United States of America 1976-05-05

Abstracts

English Abstract



BE IT KNOWN THAT FORREST EUGENE LOGAN of 1492 Martingale
Place, Santa Ana, California 92705, United States of
America, having made an invention entitled:




"Feed System for Pyrolysis Reactors"


the following disclosure contains a correct and full
description of the invention and of the best mode known
to the inventor of taking advantage of the same.

ABSTRACT
A pyrolysis reactor has a feed system which includes
one or more circularly arcuate feed tubes removably inserted
through the outer wall of the reactor. Each feed tube is
slidably disposed in a corresponding circularly arcuate
external guide sleeve for positioning the discharge end of
each feed tube at a predetermined location and orientation
within the reactor. A hot particulate material normally
suspended in a fluid carrier is red into the reactor. The
inlet end(s) of the feed tube(s) can be connected to a
source of particulate agglomerative carbonaceous material
suspended in a fluid carrier for injection into the reactor,
preferably at a location where the hot particulate material
is uniformly distributed throughout the cross-section of
the reactor. Means can be provided to cool the particulate
agglomerative carbonaceous material during transit through
the feed tube(s) to prevent agglomeration in the feed
tube(s).

- 1 -


Claims

Note: Claims are shown in the official language in which they were submitted.



THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

1. In a pyrolysis system including a pyrolysis
reactor and a system which transports a flow of hot
particulate material suspended in a gaseous carrier through
the reactor, an improved system for feeding particulate
carbonaceous material into the pyrolysis reactor which
comprises:
(a) at least one circularly arcuate feed tube
means, a portion of which is extendible through an opening
in a side wall of the reactor for providing a discharge
end positioned in the reactor;
(b) means for coupling an end opposed to the discharge
end of the feed tube means to a source of particulate
carbonaceous material suspended in a non-deleteriously
reactive carrier gas for injection into the reactor;
(c) at least one circularly arcuate support sleeve
extending outwardly from the external wall of the pyrolysis
reactor about an opening therein, said support sleeve receiving
said circularly arcuate feed tube means in close slidable
relation and preventing rotation of the feed tube means
relative to the internal walls of the reactor to cause
discharge of carbonaceous material from the feed tube means
concurrent to the flow of hot particulate material within
the reactor; and
(d) means on the support sleeve to control the
extension of the feed tube means into the reactor; said
feed tube means at least being circularly arcuate from the
point of said means on the support sleeve for controlling
the extension into the reactor to the discharge end of
said feed tube means in the reactor.

19


2. A pyrolysis system as claimed in Claim 1 which
includes means for maintaining the particulate carbonaceous
material in the feed tube means below a predetermined
temperature

3. A pyrolysis system as claimed in claim 2 in which
the feed tube means includes a circularly arcuate feed tube,
and means to maintain the carbonaceous material in the feed
tube below a predetermined temperature comprising a
circularly arcuate cooling jacket included with the feed
tube which in combination are insertable within the support
sleeve in close slidable relation therewith, and jacket
means to receive a supply of coolant fluid to be circulated
through the cooling jacket.

4. A pyrolysis system as claimed in claim 3 in which
the cooling jacket comprises inner and outer concentric
fluid passages communicating with each other at the discharge
end of the feed tube, and wherein the coolant fluid is
provided from a source connected to the inner passage at
an end of the jacket remote from the discharge end of the
feed tube, the coolant fluid being removable from an exit
connected to the outer passage at the opposed end of the
jacket such that coolant fluid flows from the source
through the inner passage to the discharge end of the feed
tube and from the discharge end of the feed tube through
the outer passage to the exit.



5. A pyrolysis system as claimed in claim 1 in which
the means to control the extension of the feed tube means
comprises abutting flanges respectively on the support
sleeve and the feed tube means and seal means positioned
between the flanges; and in which a supporting beam
extends transversely from the reactor and is secured to
the supporting sleeve; and wherein the supporting sleeve
is secured to the wall of the reactor by an external weld
joint.

6. A pyrolysis system as claimed in claim 3 in which
the coolant fluid is water.
7. A pyrolysis system as claimed in claim 1 in which
the discharge end of the feed tube means is positioned in
the pyrolysis reactor at a point downstream from an inlet
of the reactor which is about 4 to 5 times the width of
the reactor.

8. A pyrolysis system as claimed in claim 1 in which
the ratio of the radius of curvature of the feed tube means
to the width of the reactor is at least about 5 to 1.

9. A pyrolysis system as claimed in claim 7 in which
the ratio of the radius of curvature of the feed tube means
to the width of the reactor is at least about 5 to 1.

21



10. A pyrolysis system as claimed in claim 1 in
which the discharge end of the feed tube means is
substantially normal to the longitudinal axis of the
reactor, and faces in a downstream position to the direction
of flow of the hot particulate material through the reactor.

11. A pyrolysis system as claimed in claim 1 in which
the discharge end of the feed tube means terminates within
the reactor at a point approximately where the hot particulate
material is substantially uniformly distributed throughout
the cross-section of the reactor.

12. A pyrolysis system as claimed in claim 1 including
a plurality of said circularly arcuate feed tube means each
being extendible through a respective opening of the
reactor side wall, the separate feed tube means having
discharge ends for being located at different positions
within the reactor; and each feed tube means having a
circularly arcuate support sleeve and means to control the
extension, location and orientation of the discharge end
of the feed tube means in the reactor.

13. A pyrolysis system as claimed in claim 12 including
means coupling an end opposed to the discharge end of
each feed tube means to a separate source of particulate
agglomerative carbonaceous material suspended in a carrier
gas for injection into the reactor.

14. A pyrolysis system as claimed in claim 12 in which
the plural feed tube means terminate at a common plane
within the reactor.

22



15. A pyrolysis system as claimed in claim 12 in
which the discharge end of each feed tube means is
substantially normal to the longitudinal axis of the
reactor, and faces in a down stream position to the
direction of flow of the hot particles through the reactor.

16. A pyrolysis system comprising:
(a) an elongated pyrolysis reactor;
(b) means for feeding into an inlet of the
reactor a hot particulate material suspended in a carrier
fluid at an elevated temperature;
(c) at least one circularly arcuate feed tube
means having a portion thereof extending through an opening
in a side wall of the reactor and having a discharge end
disposed in the reactor and an inlet end positioned outside
the reactor;
(d) at least one circularly arcuate hollow support
sleeve secured to the pyrolysis reactor for receiving the
circularly arcuate feed tube in close slidable relation
therein to prevent rotation of the feed tube relative to the
interior walls of the reactor so as to position the discharge
end of the feed tube means at a predetermined location and
orientation within the reactor, said feed tube means at
least being arcuate from the point of containment by the
support sleeve to the extremity of said feed tube means in
the reactor;
(e) cooperating means on said feed tube means and
said support sleeve to limit the extension of said feed tube
means into the reactor; and

(f) means for feeding a source of particulate
carbonaceous material suspended in a carrier fluid to the
inlet end of the feed tube means.

23


17. A pyrolysis system as claimed in claim 16 which
includes means for maintaining the temperature of the
carbonaceous material in the feed tube means below a
predetermined temperature.

18. A pyrolysis reactor as claimed in claim 17 in
which the feed tube means includes a circularly arcuate
feed tube, and means for maintaining the temperature of
the carbonaceous material in the feed tube below a
predetermined temperature comprising a circularly arcuate
cooling jacket included with the feed tube, which in
combination are insertable in the circularly arcuate
support sleeve, said combination comprising:
(a) a circularly arcuate annular sleeve
surrounding the feed tube and being spaced therefrom;
(b) an annular plate connecting the annular
sleeve to the discharge end of the feed tube;
(c) a circularly arcuate annular partition
disposed inside said annular sleeve and spaced from said
annular plate, said annular sleeve, and said feed tube to
define a communicating first coolant flow path between said
feed tube and said partition and a second flow path
between said partition and said sleeve; and
(d) a source of coolant fluid coupled to one of
said flow paths near the inlet end of the feed tube and
an exit for the coolant fluid coupled to the other flow
path.

19. A pyrolysis system as claimed in claim 18 in which
the source of coolant fluid is coupled to the first flow
path and exits the second flow path.

24


20. A pyrolysis system as claimed in claim 16 in
which the stop means comprise abutting flanges, one
carried on the feed tube means and the other carried on
the support sleeve.

21. A pyrolysis system as claimed in claim 16 in
which the discharge end of the feed tube means is positioned
in the pyrolysis reactor at a point downstream from an
inlet of the reactor which is about 5 times the width of
the reactor.

22. A pyrolysis system as claimed in claim 16 in which
the ratio of the radius of curvature of the feed tube means
to the width of the reactor is at least about 5 to 1

23. A pyrolysis system as claimed in claim 16 in which
the discharge end of the feed tube means is substantially
normal to the longitudinal axis of the pyrolysis reactor,
and faces in a downstream position to the direction of flow
of the hot particulate material through the reactor.

24. A pyrolysis system as claimed in claim 16 in
which the discharge end of the feed tube means terminates
within the reactor at a location where the hot particulate
material is approximately uniformly distributed throughout
the cross-section of the reactor.


25. A pyrolysis system as claimed in claim 16 in
which the means for feeding the carbonaceous material to
the feed tube means is capable of feeding the carbonaceous
material into the reactor at the same velocity as the
hot particulate material passing through the reactor to
disperse the agglomerative particulate material into the
hot particulate material and carrier fluid.
26. A pyrolysis system as claimed in claim 16 including
a plurality of said circularly arcuate feed tube means
each being extendible through a respective portion of the
reactor side wall, the separate feed tube means having
discharge ends for being located at different positions within
the reactor; and a separate one of said circularly arcuate
support sleeves for controlling the location and orientation
of the discharge end of each feed tube means within
the reactor.

27. A pyrolysis system as claimed in claim 26 including
means coupling the end opposed to the discharge end of
each feed tube means to a separate source of particulate
agglomerative material.

28. A pyrolysis system as claimed in claim 26 in
which the plural feed tube means and their corresponding
support sleeves have different radii of curvature.

29. A pyrolysis system as claimed in claim 26 in which
the discharge end of each feed tube means is substantially
normal to the longitudinal axis of the reactor, and each
feed tube means faces in a downstream position to the
direction of flow of the hot particulate material through
the reactor.

26


30. In a process for the pyrolysis of particulate
agglomerative carbonaceous materials in which the
particulate agglomerative carbonaceous material is
pyrolyzed by combination with a hot particulate material
transported by a carrier gas through an elongated section
of a transport pyrolysis reactor, the improvement which
comprises:
(a) inserting at least one removable circularly
arcuate feed tube through at least one circularly arcuate
sleeve extending outwardly from a side wall of the elongated
section of the reactor about an opening therein to position
the discharge end of the feed tube at a location upstream
of said reactor opening, said arcuate sleeve controlling
the extension of the discharge end of the feed tube into
the reactor and preventing the rotation of the feed tube
relative to the internal walls of the reactor; and
(b) introducing the carbonaceous material as a
suspension in a non-deleteriously reactive carrier gas
through the circularly arcuate feed tube for combined flow
with the hot particulate material through the portion of
the pyrolysis reactor above the discharge end of said feed
tube.

31. A process as claimed in claim 30 in which the flow
of carbonaceous material in the feed tube is sufficient to
maintain the carbonaceous material below a predetermined
temperature.

32. A process as claimed in claim 30 including inserting
a plurality of said circularly arcuate feed tubes through
respective ones of said circularly arcuate sleeves to
position the feed tubes at different preselected locations
within the cross-section of the reactor.

27

33. A process as claimed in claim 32 in which the
flow of the carbonaceous material in the feed tube is
sufficient to maintain the carbonaceous material below a
predetermined temperature.

34. A process as claimed in claim 30 in which the
particulate agglomerative carbonaceous material exits the
feed tube at a velocity substantially equal to the
velocity of the hot particulate material passing through
the reactor to disperse the agglomerative particulate
carbonaceous material into the hot particulate material and
carrier gas.

35. A process as claimed in claim 30 in which the
discharge end of the feed tube is positioned in the reactor
at a point above the inlet which is about 4 to about 5 times
the width of the reactor.

36. A process as claimed in claim 30 including dis-
charging the particulate material from the feed tube at a
point in the reactor where the hot particulate material is
uniformly distributed across the cross-section of the reactor.

37. A process as claimed in claim 30 in which the
carbonaceous material in the feed tube is maintained below
a predetermined temperature by flow of a coolant fluid
through a circularly arcuate cooling jacket surrounding
the feed tube and contained in the supporting sleeve.

38. A process as claimed in claim 37 in which the
coolant is water.

28


39. In a pyrolysis system including a pyrolysis
reactor and system which transports a hot particulate
material suspended in a gaseous carrier of the reactor, an
improved system for feeding particulate agglomerative
carbonaceous material into the pyrolysis reactor which
comprises:
(a) a circularly arcuate feed tube having a portion
thereof extendible through a side wall of the reactor for
providing a discharge end positioned near the centerline
of the reactor at a point approximately uniformly distributed
across the width of the reactor;
(b) means for coupling an end opposed to the
discharge end of the circularly arcuate feed tube to a
source of particulate agglomerative carbonaceous material
suspended in a carrier gas for injection into the pyrolysis
reactor;
(c) a cooling jacket surrounding the feed tube;
(d) a circularly arcuate support sleeve secured
to the wall of the pyrolysis reactor and surrounding at
least a portion of the cooling jacket and the feed tube
external of the reactor, said sleeve for receiving said
cooling jacket and feed tube in close slidable relation
and for preventing rotation of the cooling jacket and feed
tube relative to the internal walls of the reactor; and
means on the support sleeve to control the extension of
said cooling jacket and feed tube into the reactor, said
circularly arcuate feed tube and cooling jacket at least
being arcuate from the location of said control means to
the extremity of the cooling jacket and feed tube in the
reactor; and
(e) means for circulating a coolant fluid through
said cooling jacket to maintain the temperature of the
particulate agglomerative carbonaceous material.

29

40. A pyrolysis system as claimed in claim 39 in
which the cooling jacket comprises inner and outer concentric
fluid passages communicating with each other at the discharge
end of the feed tube; and wherein the coolant fluid is
provided from a source connected to the inner passage at
the opposed end of the jacket and is removed from an exit
connected to the outer passage at the opposed end of the
jacket such that coolant fluid flows from the source through
the inner passage to the discharge end of the feed tube and
from the discharge end of the feed tube through the outer
passage to the exit.

41. A pyrolysis system as claimed in claim 40 in which
a portion of the cooling jacket and feed tube extend outside
the wall of the pyrolysis reactor through a surrounding
semi-circular support sleeve secured to the wall of the
pyrolysis reactor, said sleeve having securing means to
control the extension of said jacket into the reactor and
to prevent rotation of the cooling jacket and feed tube
relative to the internal walls of the reactor.

42. A pyrolysis system as claimed in claim 41 in which
the securing means comprises abutting flanges, and seal
means positioned between the flanges; and in which a supporting
beam extends transversely from the reactor and is secured
to the sleeve, and wherein the sleeve is secured to the
wall of the reactor by an external weld joint.

43. A pyrolysis system as claimed in claim 40 in
which the coolant fluid is water.



44. A pyrolysis system as claimed in claim 40 in
which the discharge end of the feed tube is positioned in
the pyrolysis reactor at a point above the inlet of the
pyrolysis reactor which is about 4 to 5 times the width of
the pyrolysis reactor.

45. A pyrolysis system as claimed in claim 40 in
which the ratio of the radius of curvature of the feed
tube to the width of the pyrolysis reactor is at least about
5 to 1.

46. A pyrolysis system as claimed in claim 44 in
which the ratio of the radius of curvature of the feed tube
to the width of the pyrolysis reactor is at least about
5 to 1.

47. A pyrolysis system as claimed in claim 40 in
which the end of the feed tube is substantially parallel
to the longitudinal axis of the pyrolysis reactor.

48. A pyrolysis system as claimed in claim 44 in which
the end of the feed tube is substantially parallel to the
longitudinal axis of the pyrolysis reactor.

31

49. A pyrolysis system comprising:
(a) an elongated pyrolysis reactor;
(b) means to feed a hot particulate material
into the inlet of the pyrolysis reactor suspended in a
carrier fluid at an elevated temperature;
(c) a circularly arcuate feed tube having a
portion thereof extending through a side wall of the
reactor and having a discharge end and an inlet end, the
discharge end being disposed in the reactor at approximately
the centerline thereof and at a point where the hot
particulate material is approximately uniformly distributed
across the width of the reactor, the inlet end of the
feed tube being positioned outside the reactor;
(d) a circularly arcuate hollow support sleeve
secured to the pyrolysis reactor, said sleeve being adapted
to receive the circularly arcuate feed tube in close slidable
relation to prevent rotation of the feed tube relative to
the interior walls of the reactor and to position the
discharge end of the feed tube axially with respect to the
centerline thereof;
(e) means on said support sleeve to control the
extension of said feed tube into the reactor, said
circularly arcuate feed tube at least being arcuate from
the location of the control means to the extremity of the
feed tube in the reactor;
(f) means to feed a source of agglomerative
particulate carbonaceous material suspended in a carrier
fluid to the inlet end of the feed tube, said means being
capable of feeding the agglomerative particulate
carbonaceous material into the reactor at the same velocity
as the hot particulate material passing through the reactor
to disperse the agglomerative particulate into the hot
particulate material and carrier fluid; and

32


(g) means for maintaining the temperature of the
feed tube below the agglomerative temperature of the
agglomerative particulate carbonaceous material.

50. A pyrolysis system as claimed in claim 49 in which
the means for controlling temperature in the feed tube is
a cooling jacket surrounding the feed tube, a portion of which
is contained in the circularly arcuate support sleeve and
which comprises:
(a) a circularly arcuate annular sleeve surrounding
the feed tube and spaced therefrom;
(b) an annular plate connecting the annular sleeve
to the discharge end of the feed tube;
(c) a circularly arcuate annular partition disposed
inside said sleeve and spaced from said annular plate, said
sleeve, and said feed tube to define a communicating first
coolant flow path between said feed tube and said partition
and a second flow path between said partition and said
sleeve; and
(d) a source of coolant fluid coupled to one of
said flow paths near the inlet end of the feed tube and an
exit for the coolant fluid coupled to the other flow path.

51. A pyrolysis system as claimed in claim 50 in
which the source of coolant fluid is coupled to the inner
flow path and exits the outer flow path.

52. A pyrolysis system as claimed in claim 50 in
which the cooling fluid is water.
53. A pyrolysis system as claimed in claim 51 in which
the cooling fluid is water.

33

54. A pyrolysis system as claimed in claim 50 in
which the circularly arcuate supporting sleeve surrounds
the portion of the cooling jacket and feed tube outside
the pyrolysis reactor, said supporting sleeve being
connected to the outer wall of the pyrolysis reactor by an
external weld joint; and wherein said supporting sleeve
provides means for limiting the extension of said feed tube
and cooling jacket into the reactor.

55. A pyrolysis system as claimed in claim 51 in
which the said means for limiting the extension of said
feed tube and cooling jacket into the pyrolysis reactor
comprises abutting flanges and seal means between the flanges.

56. A pyrolysis system as claimed in claim 49 in
which the discharge end of the feed tube is positioned in
the pyrolysis reactor at a point above the inlet of the
pyrolysis reactor which is about 4 to 5 times the width of
the pyrolysis reactor.

57. A pyrolysis system as claimed in claim 49 in
which the ratio of the radius of curvature of the feed tube
to the width of the pyrolysis reactor is at least about
5 to 1.

58. A pyrolysis system as claimed in claim 56 in
which the ratio of the radius of curvature of the feed tube
to the width of the pyrolysis reactor is at least about
5 to 1.

34


59. A pyrolysis system as claimed in claim 49 in
which the discharge end of the feed tube is substantially
parallel to the longitudinal axis of the pyrolysis reactor.

60. A pyrolysis system as claimed in claim 50 in which
the discharge end of the feed tube is substantially parallel
to the longitudinal axis of the pyrolysis reactor.

61. A pyrolysis system as claimed in claim 56 in
which the discharge end of the feed tube is substantially
parallel to the longitudinal axis of the pyrolysis reactor.


62. In a process for the pyrolysis of particulate
agglomerative carbonaceous materials in which the particulate
agglomerative carbonaceous material is pryolyzed by combination
with a hot particulate material transported through an
elongated section of a transport pyrolysis reactor by a carrier
gas, the improvement which comprises:
(a) inserting through a circularly arcuate sleeve
secured to a side wall of the elongated section of the
pyrolysis reactor about an opening therein a closely fitting,
removable, circularly arcuate feed tube and circularly
arcuate surrounding cooling jacket to position the discharge
end of the feed tube at approximately the center of the
reactor in a plane approximately normal to the axis of the
reactor, the position of the discharge end being upstream of
said opening and at a point where the hot particulate
material is uniformly distributed across the reactor, said
sleeve controlling the extension of the discharge end of the
feed tube into the reactor and preventing rotation of the
cooling jacket and feed tube relative to the internal walls
of the reactor;
(b) passing a coolant fluid through the coolant
jacket to maintain the interior of the feed tube below the
agglomeration temperature at the carbonaceous material while
introducing the carbonaceous material as a suspension in
an inert carrier gas through the circularly arcuate feed tube
for combined flow with the hot particulate material through
the portion of the pyrolysis reactor above the discharge end
of said feed tube.

36



63. A process as claimed in claim 62 in which the particulate
agglomerative carbonaceous material exits the feed tube at a velocity
substantially equal to the velocity of the hot particulate material
passing through the reactor to disperse the agglomerative particulate
carbonaceous material into the hot particulate material and carrier gas.

64. A process as claimed in claim 62 in which the cooling fluid is
water.

65. A process as claimed in claim 63 in which the discharge end of the
feed tube is positioned in the pyrolysis reactor at a point above the inlet
which is about 4 to about 5 times the width of the pyrolysis reactor.

37

Description

Note: Descriptions are shown in the official language in which they were submitted.


L9

This invcntion re]ates to the feeding of particulate
pyrolysable materials, e.g. carbonaceous materials such as
agglomerative coal particles, into a pyrolysis reactor.
In a typical process for coal conversion by pyrolysis,
coal particles are fed through a fesd tube into a pyrolysis
reactor. The coal particles -typically are suspended in a
non-deleteriously reactive fluid carrier, such as nitrogen
gas, and are mixed in the reactor with hot char particles
at a temperature of about 600 ~`. (31~C.) or more. The
hotjchar particles are normally also suspended in a non-
deleteriously reactive carrier fluid, such as nitrogen gas,
at about the same temperaturè. When the coal particles are
agglomerative, the fluid carrier in which they are suspended
must be ~ept relativeiy cool prior to injection of the coal
particles into the hot stream of char particles, in order to
prevent agglomerative plugging of the feed tube.
In the past, agglomerative coal particles have been fed
into the hot stream of char particles by connecting the feed
tube to the side wall of a curved conduit carrying the stream
Or char particles to the reactor, the feed being connected
along the outside of a bend of that conduit. Excess heating
of the coal particles in the feed tube has been avoided
because the feed tube terminates at the side wall of the
conduit, the feed tube not extending into the reactor.
However, the char particles ~lowing in the conduit tend to
concentrate aroun~ the outside of the bend in the conduit,
owing to centrifugal force. ~s a consequence, some of the
coa] particles reach the wall of the reactor before they have
been sufficiently heated to have passed through their
agglomerative state. This causes an agglomerative mass to




- 2 ~
, . .. _, ... ... .

~19~

form on the walls of the curved conduit leading to the reactor near or at the
attachment of the feed tube to the curved conduit. Thus, the coal particles
eventually plug the mouth oE tlle feed tube.
According to one aspect of the present invention, there is provided
in a pyrolysis system including a pyrolysis reactor and a system which trans-
ports a flow of hot particulate material suspended in a gaseous carrier
through the reactor, an improved system for feeding particulate carbonaceous
material into the pyrolysis reactor which comprises:
(a) at least one circularly arcuate feed tube means, a portion of
which is extendible through an opening in a side wall of the reactor for
providing a discharge end positioned in the reactor;
(b) means for coupling an end opposed to the discharge end o the
feed tube means to a source of particulate carbonaceous material suspended in
a non-deleteriously reactive carrier gas for injection into the reactor;
~ c) at least one circularly arcuate support sleeve extending out-
wardly from the external wall of the pyrolysis reactor about an opening
therein, said support sleeve receiving said circularly arcuate feed tube means
in close slidable relation and preventing rotation of the feed tube means
relative to the internal walls of the reactor to cause discharge of carbon-

aceous material from the feed tube means concurrent to the flow of hotparticulate material within the reactor; and
(d) means on the support sleeve to control the extension of the
feed tube means into the reactor; said feed tube means at least being
circularly arcuate from the point of said means on the support sleeve for
controlling the ex*ension into the reactor to the discharge end of said feed
tube means in the reactor.
Although the pyrolysis system of the invention has generally
applicability to the pyrolysis of pyrolysable materials it is, of course,
especially appropriate to the pyrolysis of particulate carbonaceous material
and accordingly, in another aspect, the invention also provides a pyrolysis




~ - 3 -



.

`~

system comprising an elon~ated pyrolysis reactor; means for feeding into
an inlet of the reactor a hot particulate material suspended in a carrier
Eluid at an elevated temperature; at




- 3a -


~'~

~19~ 9
least one feed tube mcans having a portion thereof extending
through an opening in a s:ide wall of the reactor and having
a discharge end ~lsposed in the reactor and an inlet end
positioned outside the reactor; at least one circularly
arcuate hollow suFport sleeve secured to the pyrolysis
reactor for rece~ving the feed tube means in close slidable
relation therein to prevent rotation of the feed tube means
relative to the interior walls of the reactor so as to
position the discharge end of the feed tube means at a
predetermined location and orientation within the reactor~
said-feed tube means being arcuate at least from the point of ~ ~ -
containment by the support sleeve to the extremity of said
feed tube means in the reactor; cooperating means on said feed
tube means and said support sleeve to limit the extension of
said feed tube means into the reactor; and means for feeding a
source of particulate carbonaceous material suspended in a
carrier fluid to the inlet end of the feed tube means.
~or the pyrolysis of agglomerative carbonaceous materials,
means are preferably provided to maintain the temperature of
the particulate agglomerative material in the feed tube below
a predetermin~d temperature such as the agglomeration
temperature of the material. Another reason for providing
such means is to avoid pyrolysis or reaction before the
material enters the reactor.
In one form of the invention, a plurality of the feed
tube means extend through respective portions of the reactor
side wall, the separate feed tube means being slidably
disposed in corresponding circularly arcuate support sleeves
for controlling the location and orientation of the discharge
end of each feed tube within the reactor. This structure
'~ .




....... , .~ . . , ....... ...... .... _ .. , ... _ .. _ . , __ . _ _ . .. _ _ ,,_ _. _ _._.,, ,,, _,, _,.. .. . .

9~
provides high throughput of, e.g. carbonaceous materials
and consisten-tly ensures that the particles will be mixed with
the hot (e.g. char) particles flowing in the reactor so that
uniPorm pyrolysis occurs in the xeactor.
The invention further provides a process forthe pyrolysis
oP particulate agglomerative carbonaceous materials in which
the particula-te agglomerative carbonaceous material is pyro-
ly~ed by combination with a hot particulate material trans-

ported by a carrier gas through an elongated section of a `
transport pyrolysis reactor, characterised by introducing
the carbonaceous material as a suspension in a non-deleteriously
reactive carrier gas into the reactor through at least one
removable circularly arcuate feed tube extending through at
least one ~ircularly arcuate sleeve extending outwardly from
a side wall oP the elongated section of the reactor about an
opening therein to position the discharge end of the feed tube
at a location upstream of said reactor opening, said arcua-te
sleeve controlling the extension of the discharge end-of the
Peed tube into the reactor and preventing rotation of the feed ;
tube relative to the internal walls of the reactor.
The invention is further described and explained with
reference to the accompanying drawings in which:
FIGURE 1 is a Pragmenta~y top plan view showing a pyrolysis
reactor having a feed system according to the invention;
FIGURE 2 is a Pragmentary front elevation view, partly
in cross-section~ taken on li~e 2-2 oP Figure l;
FIGURE 3 is a Pragmentary, partly schematic, top plan
view, partly in cross-sectiont showi~gan alternate ernbodiment
of the pyrolysis reactor and Peed system of Figures 1 and 2;
FIGURE ~ is a fragmentary, partly schematic, Pront



r


elevation -vie~, partly in cross-section, taken on line 4_L~ of
~lgure 3;
FIGURE 5 is a cross-sectional view taken on line 5-5 of
Figure 3;
FIGURE 6 is a fragmentary top plan view, partly in cross-
section, showing a rnultiple feed system for a pyrolysis
reactor;
FIGURE 7 is a fragmentary front elevation vi0w taken on
line 7-7 of Figure 6;
iFIGURE 8 is a fragmentary top plan view, partly in cross-
sectjion, showing an alternate embodiment of a multiple feed
system for a pyrolysis reactor; and
FIGURE 9 is a fragmentary front elevation view taken on
line 9-9 of Figure 8.
Referring -to the drawings, hot particulate material, typ-
ically char in a hot stream of non-deleteriously reactive carrier
gas at about 600F. (315 C) or more, is fed into a generally
upright pyrolysis reactor 10. A source of particulate carbon-
aceous material, such as bituminous coal suspended in a non-
deleteriously reactive carrier gas, such as nitrogen, is also
- fed into the pyrolysis reactor 10.
By a "carbonaceous material" there is meant a solid material
such as coal or solid organic residue, eOg. solid waste oil
shale, tar sands and the like. "Coal" includes anthracite,
agglomerativ~ bituminous coal, sub-bituminous coal, lignite and
peat. By the term "non-deleteriously reactive carrier gas" ;
there is mean~ a gas tha-t is substantially free of free oxygen,
although the constituents of the gas may react with pyrolysis
products to upgrade their value. To be avoided are constituents
which degrade pyrolysis products. Figure 1 and 2 illustrate a




-- 6 --

319~L9

single feed system for the pyrolysis reactor 10 whereas Figures
3 to 5 illustrate the same basic feed system in combination
with a system for cooling, where necessary, the par-ticulate
carbonaceous material prior to its injection into -the pyrolysis
reactor 10.
The stream of hot particulate mat0rial, such as char,
enters a curved conduit section 12 from which it passes through
a diffusion section 13 and into an elongated~section of the
pyrolysis reactor lO. The pyrolysis reactor 10 is generally
typical of those used for the pyrolysis of coal in the presence
of hot particulate char or other inert particulate material.
A course~of the particulate carbonaceous material suspended
in a non-deleteriously reactive carrier gas is represented by a
block 14 in Figure 3. The carbonaceous particles from the
source 14 are fed through an elongated feed tube 16 into the
interior of thereactor lO. The carrier gas for the carbonaceous
particles is kept at a substantially lower temperature than the
hot particulate material-bearing carrier stream in the conduit
12~ to prevent premature pyrolysis and/Gr agglomeration of the
particles in the feed tube 16. The carrier gas for the carbon-
aceous particles also is maintained at a sufficient pressure to
continuously carry the carbonaceous particles into the reactor 10.
The carbonaceous particles may be of a nature that at some
temperature below the pyrolysis temperature they will begin to
swell and secrete tarry constituents which causes closely spaced
particles to stick together and agglomerate and to adhere to
the walls of the reactor 10, in which case the feed tube 16 may
require a cooling s~stem as shown in Figures 3 to 5. An alter-
native is to lnject the material at a flow rate sufficient to
prevent the material from reaching the agglorneration temperature

9::19
before it exits tho fe0d tube.
The feed tube 16 has a circularly arcuate end sec-tion which
extends from a location substantially external o-f the reactor
side wall, through the reactor side wall, and into the interior
of -the reactor 10. This circularly arcuate section of the feed
tube 16 has a discharge end 18 preferably located at a point
within the reactor 10 which is spaced sufficiently from the
entrance to the reactor for the hot particles to be approximately
uniformly distributed in their carrier gas across the cross-

section of the reactor. In the single feed system shown in
~igures 1 to 5, the discharge end 18 preferably is located near
the centerline reactor 10~ and is also located downstream from
the inlet of the reactor by a distance equal to four or five times
the width ~r diameter of the reactor. The discharge end 18 of
the ~eed tube 16 also ~aces downstream away from the entrance to
the reactor 10~ and preferablyinjects coal particles into the
reactor in a direction substantially parallel to the flow path
through the reactor 10~ i.e. substantially parallel to the long-
itudinal axis o~ the reactor 10. Since the feed tube extends a
major distanc~ into the reactor 10~ the disturbance o~ the fluid
flow caused by the feed tube is minimized. To achieve this, th~
ratio of the radius of the circularly arcuate section of the
feed tube 16 to the inside diameter of the reactor 10 should be
at least about ~
In contr~st wlth the present invention, prior feed tubes
have been connected to the fluid system along the outside of the
bend of the conduit 12, as represented by phantom lines at 12a
in Figure 4, to prevent heating of the particulate coal above its
agglomeration temperature prior to injection into the hot char
stream. However, the concentration of char par-ticles along the




- 8 -

.

19

outside of the bond caused by centrifugal force rapldly heats the
coal particles at the mouth o~ the feed tube before they can pass
through the agglomerative temperature range~ thereby causing $he
coal particles to agglomerate and eventually plug the mouth of
the tube and curveld conduit 12.
The coal p~lr-ticles are kept relatively cool as they are fed
to the gas stream containing the hot char in the reactor 10. A
variety of alternative systems or methods may be used to cool the
~oal particles prior to injectio~ into the reactor. In the feed
system shown in Figures 1 and 2, for example, the coal particles
may be fed through the feed tube 16 at such a velocity that the
particles are discharged into the reactor 10 before they have time
to reach the pyrolysis or agglomeration temperature whichever be ~:
the requirement, within the feed tube 16. If the in-troduction...
velocity of agglomerative material, for example, is so low that
agglomeration can occur in the feed tube, -then external means can
be used to cool the particles traveling in the feed tube 16 of
~igures l-and 2 prior to injection into the reactor. For example,
the carrier gas for the coal particles may be cooled, or an
isolated coolant fluid such as water, Dowtherm the fluid known
under the Trade Mark DOWTHERM, refrigerated air and the like can be ~;
discharged over the portion of the feed tube which extends from
the coal source 14 to the reactor 10.
Figures 3 to 5 show a jacketed system for cooling the
coal particles traveling in the feed tube 16. The feed tube
16 has an end 20 connected to the particulate coal source 14
by a pipe 22. A cooling jacket for the feed tùbe 16 includes
an outer annular sleeve 24 and an elongated inner annular
partition 26 concentrically disposed about the feed tube 16. ~.
At the discharge end 18 of the feed tube 16, an annular


_ g _

91~
plate 28 closes the conduit 24, while leaving the end of
the feed tube 16 open The ins:ide diameter o~ the partition
26 is lQrger than the outside diameter o~ the feed tube 16.
Weld beads 30 support the partition 26 in a position space~
from the feed tube 16 to form an inner flow passage. The
ins:ide diameter o~ the s:Leeve 24 is larger -than the outside
diameter of the partition 26. Weld beads 32 support the
sleeve 24 in a position spaced from the partition 26 to
define an outer ~low passage. The partition 26 is spaced
from the end plate 28 to permit fluid communication between
the inner and outer flow passages at the discharge end 18
of the feed tube 16.
An elongated, circularly arcuate supporting sleeve 34
is secured Ito the outer wall o~ the reactor 10. The supporting . ;
sleeve 34 extends away ~rom the reactor and surrounds the
circularly arcuate portions o~ the feed tube 16, the partition ~;
26, and the sleeve 24 immediately adjacent the reactor outer
wall. The supporting sleeve 34 has a mounting flange 36 at
the end of the sleeve remote ~rom the point o~ attachment of
t~e sleeve to the reactor wall. The sleeve 34 is attached
to the reactor 10 by a supporting beam 38 which, as shown,
has a T--shaped cross-section that extends transversely from
the reactor 10 to a point spaced from the reactor outer wall
and located near the flange 36. An external weld joint 40
- is formed between the sleeve 34 and the outer wall of the
reactor 10 at the point where the feed tube 16 enters the
reactor. The weld joint 40 secures the sleeve 36 to the
reactor 10 and seals the point of entry of the sleeve 24 into
the reactor.. A flange 42 on the conduit 24 is secured to
the flange 36 by fasteners 44. An 0-ring seal 46 is sandwiched
. _ 10 -




.. ..... .. . . .. ..... ... . . ... .. . . . . . .

be-tween the fLanges 36 and 42. The cooling jacke-t and the
feed tube -I 6 are slidable -together as a unit axially relative
to the fixed support:ing sleeve 34.
< To install the feed tube 16 in the reactor 10, the
cooling jacket and feed tube 16 are slid lengthwise as a
unit through the sleeve 3LI until the flange 42 abuts against
the flange 36 . The stop provided by the abutting fl~nges
determines the extent of penetration of the feed tube 16 into
the interior of the reactor 10 and ensures the correct, i.e.,
location and orientation, of the discharge end 18 within the
reactpr 10. The feed tube 16, its associated cooling jacket,
and the sleeve 3L~ are of matching circularly arcuate
configuration, The feed tube and cooling jacket are
circularly arcuate in length at least between the cooling
jacket and the feed tube 16 within the reactor. This
prevents the discharge end 18 of the feed tube 16 from being
rotated away from its correct position in the reactor 10.
Thus, the sleeve 3L~, the external weld joint 40, and the
support beam 38 provide for the feed tube 16 and its
cooling jacket a means of support and attachment to the
reactor 10 that presents no obstructions to the flow path
within the reactor 10; and they provide means for positioning
the discharge end 18 of the feed tube 16 in a predetermined
location and orienta-tion inside -the reactor 10 without the feed
tube or water jacket being movable lengthwise or rotatable
from this preselected posi-tion. However, other stop means
for properly locating the end of the feed tube withln the
reactor can be used,
The positioning of the feed tube 16 shown in ~igures 1
and 2 is substantially identical -to that described for

9~19

Figures 3 to 5, except that the feed tube shown in
Figures 1 and 2 carries the flange 42 and can be connected
directly to the source 14 rather -than via the separate
conduits 22 and 26 shown in Figures 3 to 5.
Referring again to the cooling system shown in Figures
3 to ~, a coolan~, fiuch as water, the said DOWTHEnM fluid,
refrigerated air and the like is fecl to -the jacket by a
pump ~8 (represented-in block form in Figure 3). The
pump 48 is connected to -the portion of the partition 26
which extends outside -the reactor 10. The coolant is
forced by the pump 48 through the inner flow passage of
the cooling jacket to the end 18 of the feed tube 16 and
from the end of the feed tube through the outer flow passage
of the cooling jacket -to an exit 50 (shown in Figure 3). In
this manner, the coal particles passing through the feed
tube 16 are kept relatively cool as they are fed to the gas
stream containing hot char in reactor 10. The temperature of
the coolant is suitably lower than the hot char in the
carrier stream in the reactor 10. Moreover, the flow rate
of the coolant is sufficien-tly high to maintain the temperature
within the feed tube 16 below the agglomeration temperature
of the coal par-ticles. By connecting the inner flow passagé
of the cooling jacket to the source of coolan-t fluid, more
effective cooling of the feed tube 16 occurs because the
cooler upstre~m portion of the fluid flowing through the
cooling jacket is closer to the feed tube 16, and the down-
stream portion thereof insulates the upstream portion from
the hot en~ironment within the reactor 10, which is typically
at a temperature of about 600 ~. (315 C.) or more.
If desired, the coolant can be circulated in a closed


_ 12 -

11 9~L9
system. In this lnstance, a cooler 52 is connected to the
exit 50 to return the coolant to its original temperature.
The cooler 52 is coupled to the pump ~8 by a pi.pe represented
schematically as a line at 54 in Figure 3.
The source 14 is designed to inJeCt particulate coal
and a carrier gas into the feed tube 16 as a dense mass so
that the coal and carrier gas travel through the feed tube
at approximately the same velocity as the hot carrier
stream traveling through the reactor 10. Consequently, the
coal particles exit from the discharge end 18 generally at
the same velocity as the hot carrier stream traveling through :the reactor 10; and the coal particles pass through the
agglomerative temperature range before reaching the
walls of the reactor.
Two factors minimize agglomeration of coal particles
prior to contact with the hot carrier stream in the reactior 10.
First, the coal particles are maintained below the agglomeration
temperature as they exit from the discharge end 18 by virtue
of the cooling jacket shown in Figures 3 to 5, or any other
desired means for cooling the coal particles; and, secondlyg
the coal particles are quickly heated in the hot stream in
the reactor 10 to a temperature above the agglomeration
temperature before coming into contact with the walls of the
reactor 10.
If desired, the pressure of the source 14 can be auto-
matically adjusted to compensate for changes in conditions
in the reactor 10. For example, the pressure of the source
14 can be adjusted by a servo system (not shown) responsive
to a mass flowmeter (not shown) located in the reactor 10
and a mass flo1~meter (not shown) located in the feed tube 16.
13 -


When the velocity o~ the hot char-bearing stream trav0ling
through the reactor 10 incroases~ the velocity of the coal-

bearing s-tream traveling through the fced tube 16 also :
increases, and vice versa. Further, if desired, the flow
rate of the coolant forced through -the cooling jackot by
the pump 48 can be automatically adjus-ted to compensate for
changes in the temperature in the reactor 10, For example,
the pump 48 can be adjusted by a servo system responsive to
a temperature sensor (not shown) located in the reactor 10
and a temperature sensor (not shown) located in the feed tube
16. When the temperature of the hot carrier stream increases,
the flow rate of the water flowing through the cooling jacket
also increases, and vice versa. Similar control systems also
may be used for other means for cooling the coal particles
prior -to injection into the reactor 10.
As will be appreciated, the feed tube 16 and its
surrounding cooling conduit 24 can be readily removed from
the reactor 10 by virtue of the guide means provided by
sleeve 34. This can be accomplished without disturbing any
insulation or covering surrounding the sleeve 34 or the
reactor 10. In addition, withdrawal of -the feed tube 16
and the cooling conduit 24 has been found to have on].y a
slight or minimal effect on the flow within the reactor 10. ~;
Howev0rt should greater control over flow through the
reactor 10 be dcsired, a plug (no-t shown) conforming to
the sleeve 34, and having an end which conforms to the
interior contour of the reactor 10 "nay be inser-ted in
place of the feed tube 16 and its surrounding cooling .
conduit This permi-ts the use of the reactor 10 for other
purposes, such as pyrolysis of non-agglomerative carbonaceous


- 14 -


materials.
~ igures 6 and 7 show an alternative form of the :inven-tion
in which a pyrolysis reactor 110 has a multiple feed system
for the carbonaceous material and carrier gas. The reactor
110 :includes a s~ries of circularly arcuate supporting
sleeves 134 exte~ding radially away from the outer wall
of the r0actor llo. The structure of each supporting sleeve
13l~ is identical to that of the sleeve 34 described above.
That is~ each sleeve is attached to a corresponding portion
of the reactor outer wall by a respective weld joint 1~0.
Each sleeve also may be supported by a corresponding
supporting beam (not shown) similar to that of beam 38
described above, or a different supporting arrangemen-t may
be used if desired. The end of each supporting sleeve 134
remote from the poin-t of at-tachment of this sleeve to the
reactor carries a separate flange 136 similar to the flange 36
described above.
A separate circularly arcuate feed tube 116 is slid
lengthwise into each sleeve 134 until the flange 142
carried on each feed tube abuts a corresponding flange 136.
This positions the discharge ends 118 of the feed tubes 116
at predetermined locations an~ orienta-tions within the reactor
110~ As shown best in Eigure 6, the discharge ends 118 of the
feed tubes 116 are circumferentially spaced apart around
the longitudina:L axis of the reactor 110. The mul-tiple
feed systems couple the reactor to one or more sources
of carbonaceous material in any of a variety of configurations.
The multiple feed sys-tem provides means for substantially
increasing the rate of throughput in the reactor relative
to a single feed sys-tem. The multiple feed system also

- 15 -


319

prov:ides means for efficiently mixing the carbonaceousmaterials with the stream of hot char particles. To produce
desired mixing within the cross-sec-tion of the reactor,
the ends of the feed tubes 116 may be uniformly oriented
with:in the cross-section of the reactor, as shown in
~igure 7; or other orientat:ions may be used, such as that
Shown in the alternate multiple feed sys-tem illustrated in
~igures 8 and 9.
In the system shown in ~igures 8 and 9, a pyrolysis
reactor 210 includes a first set of circularly arcuate
supporting sleeves 234a ex-tending radially away from opposite
sides of the reactor 210; a second set of circularly arcuate
sleeves 234b secured to the reactor below the sleeves 234a
and extending radially away from opposite sides of the
reactor along the same radial extent as the sleeves 234a; and
a third set of a circularly arcuate sleeves 234c secured to
the reactor at the same elevation as the sleeves 234b but
extending radially away from the reactor at right angles to the
radial ex-tent of the sleeves 23~a and 234b. The ends of the
sleeves 234a~ 234b and 234c remo-te from their points of
connection to the reactor carry corresponding flanges 236a,
236b and 236c, respectively, Each set of sleeves has a
different radius of curvature. Separate circularly arcuate
feed tubes 216a, 216b and 216c are extended lengthwise into
corresponding ones of the sleeves 234a, 234b, and 23L~C,
respectively. ~ach feed tube carries a flange which abuts
the flange on the corresponding sleeve for the feed tube to
control the extent and orientation of the feed tubes in the
interior of the reac-tor 210.
The feed system shown in Figures 8 and 9 illustrates
~ ~ .
- 16 - ~

that ~he dischargQ ends 218cl, 218b, and 218c of the respect-
ive feed tubes can terminate at different locations within
the cross-sectional area of the reactor 210. Moreover~
tho dlscharge ends of the feed tubes ca.n terminate at
different locations axially within the reactor 210. ~lthough
the feed tubes s~own in ~igures 6 to 9 are illustrated
as being circular :in cross-section, feed tubes having
other cross-sectional configurations also may be used.
Moreover, the cross-sectional shape of the pyrolysis reactors
also is sho~n as being circular, but other cross-sectional
configurations may be used. The multiple feed systems shown
in ~igures 6 to 9 also may be used with any of a variety of
means for cooling the carbonaceous material injected into
the reactor through the feed tubes.
In summary, the invention provides a feed system for
a transport pyrolysis reactor which positions the discharge
end(s) of the feed tube(s) at predetermined location(s) within
the reactor. This feed system ensures that carbonaceous
materials to undergo pyrolysis are introduced into the reactor
so that pyrolysis occurs at a desired location and under
desired conditions within the reactor.
The feed system can assure, for example9 that the
carbonaceous materials be introduced into the reactor a-t a
point where the ho-t char par-ticles are uniformly dis-tributed
across the width of the reactor in a manner which minimizes
the disturbance of flow of the ho-t char particles through
the réactor and precl.udes impingement upon -the side walls
of the reactor, as well as preventing pyrolysis or agglomeration
in the feed tube(s). This avoids serious plugging problems.
By making the feed tube circularly arcuate and providing

g~9

the guide means and stop means to control the extension of
the feed tube into the reactor, the discharge end of the
feed tube can be automatically positloned "blind" at the
pr0cise location and orientation. Since the circularly
arcuate sleeve c:Losely fits the feed tube or its surround-
ing cooling jacket, the arcuate construction prevents
rota-tion of the feed tube in the reactor relative to
the .side walls of the reactor. This can ensure that the
discharge end of the feed tube will always be aligned in a
predetermined position. Normally this is along the axis
of the reactor to avoid ejecting carbonaceous materials
toward the side walls of the reactor, The feed system
thus precludcs the need for internal inspection and control
always to ble assured that the feed tube is accurately positioned
within the reactor. The feed system also enables the removal
of the feed tube from the reactor for repair, cleaning and/or
inspection, or the like with positive assurance of correct
and quick repositioning in the reactor.




,~

, :


- 18

Representative Drawing

Sorry, the representative drawing for patent document number 1081919 was not found.

Administrative Status

For a clearer understanding of the status of the application/patent presented on this page, the site Disclaimer , as well as the definitions for Patent , Administrative Status , Maintenance Fee  and Payment History  should be consulted.

Administrative Status

Title Date
Forecasted Issue Date 1980-07-22
(22) Filed 1977-04-26
(45) Issued 1980-07-22
Expired 1997-07-22

Abandonment History

There is no abandonment history.

Payment History

Fee Type Anniversary Year Due Date Amount Paid Paid Date
Application Fee $0.00 1977-04-26
Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
OCCIDENTAL PETROLEUM CORPORATION
Past Owners on Record
None
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Drawings 1994-04-08 4 164
Claims 1994-04-08 19 671
Abstract 1994-04-08 1 36
Cover Page 1994-04-08 1 14
Description 1994-04-08 18 748