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Patent 1213072 Summary

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Claims and Abstract availability

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(12) Patent: (11) CA 1213072
(21) Application Number: 439317
(54) English Title: PRINTED CIRCUIT BOARD
(54) French Title: CARTE A CIRCUIT IMPRIME
Status: Expired
Bibliographic Data
(52) Canadian Patent Classification (CPC):
  • 356/6
(51) International Patent Classification (IPC):
  • H05K 1/05 (2006.01)
(72) Inventors :
  • BUTT, SHELDON H. (United States of America)
(73) Owners :
  • OLIN CORPORATION (United States of America)
(71) Applicants :
(74) Agent: NORTON ROSE FULBRIGHT CANADA LLP/S.E.N.C.R.L., S.R.L.
(74) Associate agent:
(45) Issued: 1986-10-21
(22) Filed Date: 1983-10-19
Availability of licence: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): No

(30) Application Priority Data: None

Abstracts

English Abstract




ABSTRACT OF THE DISCLOSURE

A composite 24 is characterized by metal or
alloy component 26 having a thin interface layer 28
on a surface 30 thereof. Another metal or alloy
component 32 has a thin interface layer 34 on its
surface 36. A glass 38, having a closely matched
coefficient of thermal expansion to the metal or
alloy components 26 and 32, bonds the thin inter-
face layers 28 and 34 and electrically insulates the
first component from the second component whereby
thermal stress between the metal or alloy compon-
ents and the glass is substantially eliminated.



Claims

Note: Claims are shown in the official language in which they were submitted.



The embodiments of the invention in which an
exclusive property or privilege is claimed are defined
as follows:-

1. A composite 24 adapted to be a printed
circuit board system comprising:
a first metal or alloy component 26;
a second metal or alloy component 32;
a glass or ceramic component 38 disposed
between said first component 26 and said second com-
ponent 32 for bonding the first and second components
to each other,
said glass or ceramic component 38 further
having a coefficient of thermal expansion of at least
about 160 x 10-7 in/in/°C, said coefficient of thermal
expansion being closely matched to the coefficient of
thermal expansion of said first and second components
whereby thermal stress between the first, second and
glass or ceramic components may be substantially
eliminated.

2. The composite as in claim 1 comprising said
first and second metal or alloy components being copper
or a copper alloy.

3. The composite as in claim 2 comprising said
first copper or copper base alloy component being a
first thin foil 50 having a first electrical circuit
pattern thereon.

4. The composite as in claim 3 comprising said
second copper or copper base alloy component being a
second thin foil 52 having a second electrical circuit
pattern thereon.

5. The composite as in claim 4 further compris-
ing conductive means 56 disposed in said glass or
ceramic component and extending between said first
and second components for electrically interconnecting





the first and second electrical circuit patterns.
6. A process of forming a composite 24 adapted
to be a printed circuit board system comprising the
steps of:
providing a first metal or alloy component
26;
providing a second metal or alloy component
32;
disposing a glass or ceramic component 38
between said first and second components, said glass
or ceramic component having a coefficient of thermal
expansion of at least about 160 x 10-7 in/in/°C, said
coefficient of thermal expansion being closely matched
to the coefficient of thermal expansion of said first
and second components whereby thermal stress between
the first, second and glass or ceramic components may
be substantially eliminated; and
bonding said first, second and glass or
ceramic components together.

7. The process as in claim 6 further comprising
the step of disposing one or more conductive devices
56 in said glass or ceramic component for electrically
interconnecting the first and second components.




26

Description

Note: Descriptions are shown in the official language in which they were submitted.


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12086-MB

IMPROVED _RINTED CIRCUIT_BOARD
WhIle the inventlon is sub~ect to a wide range of
appllcations, it is especlal~y suited for use in
pr~nted circuit board appllcatlons and wlll be
part~c~larly described in that connectlon.
The pr~nted circuit industry produces most
prin~ed circuits by adher~ng one or more layers of
copper fo~l to organlc materials such as glass fiber
re~n~orced epoxy, phenolic laminated paper, polyester
1~ fi~ms, polylmide ~ilms, etc. Although widely used,
t~ese ~tructures haYe certain de~icienci es . F ! rstly,
tne~r ma~imum operating tem~erature is restr~cted by
the ma~imum temperature tolerance of the organic
substrate used. Secondly, a substan~al mismatch
15 usually e~ists between the coefflcient of the~al
e~pansion o~ the organic substrate and that of the
copper foil, that o~ the solder compositions normall~
used to attach components to the circui~ry and that of
the components themselves. The coefficient of therm21
20 .expan~ion of the org~nic materials is normally sub-
starlt~ally greater than tha.t of the copper ~oi~ 9 the
solder or the components being attached to the circuit.
This mismatch results in substantial '7thermal stresses"
whenever the finished product is thermally cycled.
These stresses create a Yariety of failure modes, such
as ~enslle failure of the copper foi', failure cf the
solder attachment of components to the circuit and
tensile failure of the ~omponents themselves.
To alleviate some of the problems associated with
3a thermzl stress, the industry uses two distlnct ty~es
of metal core ~oards. One is an epoxy or other organic
insulat~on over the metal core (either steel or
aluminum~, and the other is porcelain enamel ed s~e~l.
The mo~t popular is the metal core-orgznic ~.ype.
35 Typlcally, the metal core, such as . 050" ' h~ck a'~Lmin~,
is drill ed with oYersi zed holes. As ~he core is coated

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w~th epoxy, the holes are ~illed with the epoxy. Copper
foil is then bonded to one or both surfaces o~ the core.
The holes are redr~lled to a desired slze and a liner of
t'le epo~ (or other organic~ ls left in each hole. The
~inished metal core board compares to and may be
processed as a standard plastic board. This may include
electroless depos-ftion of copper ~n the holes to provlde
current paths from top to bottom3 et~. Better heat
disslpat~on is provided by the metal core board as
compared to the glass fiber reinforced epo~y type
boards wi~h rather poor thermal conductlYity.
The second type o~ board, porcelain en~meled steel,
is considered either a metal core board or a metal clad
board depending on the term~nology. Flrst, porcelaln
enamel ~essentially a glas~y material) is ap~lied to a
sheet o-f steel. A circult pat~ern is screen printed on
the surface o~ the porcelain en2mel with one of the
thic~ lllm "conducti~e inks" and the board is refired
to crea~e a ~ontlnuous pattern of metall~c conductiYe
elements. Through-holes cannot be used due to problems
with short c~rcuiting and, therefore, multi-layer
boards are not manufactured fn this manner. The
porcelain (glass) ls rather thick and its thermal
conductivity is relatlYely poor; in fact, it is even
?5 poorer than the therma~ conductiYlty o~ plastics used
in plastic boards o, as a coating in met~l core boards
described abo~e. It follows that the heat dissipation
characteristics of the porcelai~ board are poor.
Conducti~e in~ technology usually requires ~ultiple
applications of the conductive ink to DUi ld a conductor
p~ttern which is thick enough to carry a desired
electr~c current. The multiple sc-eenln~ and firing
operat~ons u~ed ln applying th~ conductiYe ink tend to
be reia~lvely complicated and ex?ensive.

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Pr~sently, ther is an ~ncrease ln the clrcuit
dens~t~ Or printed c$rcu~t boards. This creates
a need for narrower and mor~ closely spaced ~7wires~
or llnes on the printed clrcuit board. The minimum
line wldth generated by the state o~ the art
conductive lnk technology is l~mlted by the printing
process ~or applylng the conductiYe in~. Also, the
final conductiYe ~k CgenerallY elther copper- or
sil~er-) porcelain-steel product ~requently has
problems rela~ing to the metalllzed pattern. The
pattern may ha~e a substantially dlfferent Chigher)
coeff~cient oP therm~l expansion than the steel
sub~trate . Th~ s causes a substant~al shear ~orce at
~e circu~t-porc~lain interface and substantial risk
of ia~lure d~L~ing thermal cycl~ng.
Many of the a~ove-mentioned consldera~io~s
regarding clad metal are described in a paper entitled
~Clad Metal Circuit Board Substrates for Direct
Mounting o~ Ceramic Chip Carriers'~ by Dance and Wallace
and presented at the First Annual Conference of the
I~terna~ional Electronics Packaging Society, Cle~e~and,
Ohio, 1981. Also, an article entitled "Use of Metal
Core Sub trates ~r Leadless Chip Carrler Inter~
~onnection" by Lassen in Electron~c Packaging and
25 Production, March 1981, pages 98-104, dlscusses the
latest technology ~n metal core substrates.
Presently, copper ~oll i5 adhered to an organic
printed circuit substrate by elecl;rodeposition of
~'coral copper:' to the foil sur~ace. The result is a
rough sur~ace ~ith re~entrance cavities to recei~e
the surface layer of the organic substr~te and/or the
orgarlic adhesi~re to form a "locked'l mechanical bond.
Slnce khe surface layer is a conductiYe metal
structure (copper~ embedded in the organic makerial~ 35 considerable care must be exerc~sed to remo~e any
resldual cor21 coooer treatment from the s~aces

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betwPen the flnal pr~nted circuit lines. This avoids
unwanted current passing between llnes, brldging o~
solde~ across the spaces bekween llnes, etc. Xn
pr~ncipal, remo~al o~ residual coral copper treatmenk
~rom are~s requires addltional etching beyond that
required to remo~e the base foll itself. This
e~cessl~e etching leads to add~tional undercut~ing and
partial de~truction of the circuit pattern~ Thus, the
~an~acturer of conventlonal copper ~oil-organlc
circuit boards must strike a balance between enough
etching to reliably remoYe the coral copper treatment
while ~lnlmizing excessive etching to preYent under-
cutting o~ the circult pattern.
The increased complexity o~ circuitry for inter-
connecting various deYices mounted upon a printedcircult board often requires that both surfaces of the
board contain conducti~e patterns. Some of the inter-
connec~ions are provided by the clrcult pattern on the
o~erse face o~ the board Cthe sur~ace to wh~ch the
components zre mounted~ while other interconnections
are provided upon the re~erse side of the board. The
interconnection between the obverse and re~erse sides
o~ the board may be provided by solder ~illed through-
holes. ConYentional two sided copper ~oil-organic
boards o~ th~s general configura~ion ~re widely used.
~owe~e~, in state of the art porcelain enameled steel
substrate boards, two sided boards are not pract cal
since the ~olid ~nd continuous steel substrate creates
a continuous pa~h for elec~rical conduc~ion fr~m one
throuh hole to another.
In certaln applications, the circuit require~ents
include a double sided or multi-layered ~oard- ln which
thermal exposure or other factors pre~ent the use of a
copper ~oil organic board. An alternatiYe is a meta~
35 circuit pat ~ern on both sides of a suit~ble cer2:~ic,
non-condllctiJe substrate with in~,erconnection bet,ween

~ 37~ 12086-MB

the two c~rcu~t~ h~ conductiYe through-hole~. Thls
techn~ue ls used o~ speclalized printed circult boards
and upon substra~es ~or h~rid package~.
As 1ntegra~ed clrcults ~ec~e larger ~more
indi~dual functions on a single sillcon chip), and
there ~s a corresponding increase ln the number of
leads rOr lnterconnec~ion, the princlpal means o~
integrated clrcult interconnection~ the dual-in-llne
CP~P~ package becomes ~mpractical. A DIP lncludes a
lQ lead irame ~ith the leads emerglng ~rom the package and
~ormed ~nto "pinSn. As its n~me indlcates, the DIP
package has two rows of pins, one on either side o~ the
package. The pins ~re inserted and soldered into holes
in a printed c~r~uit board. Characteristically, the
L~ p~ns are spaced apart on .100" centersO A relati~ely
s~ple de~i¢e requiring a 20 lead package, 10 on
side, w~ll b~ approximatel~ 1" long. A 40 lead DIP
pac~age ls abou~ 2Ir long and a 64 lead DTP package,
about the largest now made, is appro~i~nately 3. 2" long.
For reasons relating to geometry, as the pac~ages
become longer with more plns, they become wid2r.
Typically, the width o~ the completed package is
approximately one-third lts length. For both mechan-
ical and electronic re~sons, DIP packages with more
than 64 lead~ are considered impractical to manufac~ure.
X~ever, large-scale integrated clrcuits orten require
~ore lnterconnections than proYided by DIP package~.
E~en with smaller integrated circuits, 'Ghe elrcllits are
spaced together on the printed circu~t board ~ closely
30 as possi.ble~ Ob~iously, th~ package size limi-.s the
closeness of ~he s~acing. Therefore, the semiconductor
in~ustry has a growing interest in "chip carriersi'.
Chip carriers deal with the problems of large-
scale circuits reauiring more interconnection~ khan
35 pro~ided ~y 2 DIP package 2S well as reduction of


, ~

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package size for ~ntermedlate slzed integrated circults
to tncrease component densit~ on the print~d clrcuit
~oard. The term chlp carrier, in lts broadest sense~
relates to packages, both ceramic and plas~ic. The
con~iguratio~ o~ a chip carrier may be essentially
square and leads emerge from withln the package on all
~our sides. Fur~hermore, typical center~to-center
spac~ng of lead~ on a chip carrier is .050". Thusg a
64 lead de~rice ha~ing a 'Y~ootprintn of roughly 3 . 257' x
10 1,1" in a DIP package has a 1'~ootprint" of ap~ro~imately
0. 8" 3: 0 . 8" ln a chip carrler package . More impor-
tarl~ly, the area coYered by the chlp carrier would be
approximately 18% o~ that co~ered by the DIP package.
At thls time g ch~p carrier pac~ages with 128 and more
15 1 eads are be~ng produced.
The principal constraint in establishi~g .100'l as
the normal spacing between le~ds on the DIP package is
the lnsertion o~ the lead pins into holes on the
prlnted circuit board. Allowing ~or the hole, a pad
area around the hole ~or ~older adhesion and spacing
between the holes to e7ectrlc211y isolate them from
each otherJ it becomes dlf~icult to crowd them much
closPr together.
Typically, the coe~flcient of thermal expansion o~
2S ~he DIP package is di~erent from that of the printed
circuit board. The exten~ to which board and package
d~mensions change with ~arying temperature can be
accom~odated by deflection of the leads, i.e. between
the printed circuit board and the package. E~fect-
i~ely, the leads become spri~g members whichaccommodate the differences in coe~ficient of
expansion.
State of the art chip carriers haYing .050" leads
are not normally mounted by insertion of the leads into
35 holes in the printed circuit boarcs. Inst~ad, ;nost
cnip carriers use a surface ..ount ing ~',ecnnlcue in which

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the lead forms a pad mounted flush to the printed
clrcu1 t l~oard and is soldered in place . The metallized
pads on the e~terl or sur~ace of the chip packa~e are
inte~ral with the package and expand and contract wikh
the package~ There is no accommodatlo~ for de~leckion
of leads due to changes in board and package
dimensions, as in the case of DIP packages~ durin~
thermal cycling. As a result, the solder bond between
the pad and the board is sub~ected to sub~tantial
stresse~. The stresses increase as the total package
size becomes larger and/or the board~s operation ls in
an e2panded temperature range. Repeated stressing of
the solder bond leads to ~atigue failureO
As ~ith 9IP packages, chip carr~er packages may
use a plastic package or may require her~etic
package. Wlth the DIP package, essentially the same
external con~i~uration is employed ~or a hermetic
(Ceramic Dual-In~Line ~ackage~ or a plastic package.
In both con~lgurations, the ~le~ible leads accommQdate
for di~erential thermal expansion.
The "sta~dard" glass cloth reinforced epoxy board
material ha~ a coefficient of therm21 expans~on o~ 15.8
x 10~fC. Cer~mic chip carriers usually made ~rom an
aluminum o~ide ceramic have a coeff~cient of ~hermal
e~pansion of 6.4 x 10-6/C. If thermal conducti~ity is
particularly important, they made be made ~rom ber-
yllium ox~d~e also ha~ng a coefficient ol thermal
e~pansio~ o~ 6.4 ~ 10-6~C. In either event~ there is
a substantial mismatch ln co~ffic1ent of thermal
expansion be~ween the board and the ch~p carrier.
Therefore, substantlal stresses ~re imposed on the
solder bond when su~j ected to signif~cant ~hermal
c~c lin~ O
One solution h2s been to sur~ace mount t~.e cn~p
carrier to a metallized pattern on 2n aluminum oxide
cer~mic substrat e . The substrate has the same

. "

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coe~îcient of ther~al e~cpanslorl as the ehlp carrler.
P~ns ~a~ ~e ~raæed to the alumlna substrate and plugged
into holes in the prlnted circu t board. Although this
sork o~ con~lgurat~ on a~oids problems assoclated wlth
~isma.~ch ~ coe~lclent of thermal e~pa.nsion, lt also
has ~e e~fect o~ sacri~icing much o~ ~he space saving
adsrantage of the chlp carr{ erq
A descri~tion o~ the latest technology with
respect to chip carriers ~s pre~ented ln an artlcle
entltled "Chip-Carriers, Pin-Grid Arrays Change the
PC-Board Landscape" by Jerry Lyman, Elec_ronics,
Decem~er 2~, 1981, pages 65 75. AnothQr ar~i~le
entitled 1'Chip Carriers: ~oming Force in Packaging" by-
Er~cksong ~n Electronic Packa in~and Produ tion,
March 1981, pages 64-80 discusses ~he construction and
other deta1 15 concerning chlp carriers.
U.SO Patent No. 3,546,363 to Pryor et al. dls-
closes a composite metal product for use as a seal to
glas es and ceramics which has properties o~ a low
coef~icient of e~panslon, appro~imating that of the
appropriate glasses and ceramics, good thermal
conducti~rit~, and ~lne graln siæe in the annealed
condlt ion .
~.S~ Patent Nos. 3,546,363; 3,618,203; 3,676,292;
3,726,g87; 3,826,627; 3,826,6~9; 3,837,895; 3,852,148;
and 4,149,910 disclose glass or ceramic to metal
composites or seals wherein the glass or ceramic is
bonded ta a base alloy ha~ring a thln ~ilm of re~ractory
02ide on i~s sur~ace . - _ j
.




,

~3~97~2

It is a problem underlying the present inven-
tion to provide a printed circuit board ~Jhich can
accommodate substantial thermal cycling.
It is an advantage of the present invention
to provide a composite and a process which obviate one
or more of the limitations and disadvantages of the
described prior arrangements~
It is a further advantage of the present
invention to provide a composite and a process to
form a printed circuit board which substantially
reduce the formation of stresses between the circuit
and the substrate due to thermal cycling.
It is a still further advan~age of the
present invention to provide a composite and a pro~
cess to make printed circuit boards which are rela-
tively inexpensive to manufacture.
It is a further advantage of the present
invention to provide a composite and a process hav-
ing improved heat dissipationO
In accordance with a particular embodiment
of the invention, there is provided a composite
adapted to be a printed circuit board system com-
prising, a first metal or alloy component and a
second metal or alloy-component. A glass or ceramic
2S component is disposed between the first component
and the second component for bondin~ the first and
second components to each other. The glass or ceramic
component further has a coefficient o~ thermal expan-
sion close to the coefficient of thermal expansion
of the first and second components whereby thermal
stress ~etween the first, second and glass or ceramic
components may be substantially eliminated.
In accordance with a further embodiment of
the invention there is provided a composite adapted to
be a printed circuit board system comprising, a first
metal or alloy component and a second metal or alloy

3~7Z
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component. Means are disposed between the first and
second components for bonding the components to each
other and for electrically insulating the components
from each other. Grid means are embedded in the
bonding and insulating means for stiffening the
composite.
From a different aspect, and in accordance
with the invention there is provided a process of
forming a composite adapted to be a printed circuit
board system. The process includes the steps of
providing a first metal or alloy component and
providing a secona metal or alloy component. A
glass or ceramic component is disposed between the
first and second components, the glass or ceramic
component having a coefficient of thermal expansion
close to the coefficient of thermal expansion of the
first and second components whereby thermal stress
between the first, second and glass or ceramic com-
ponents may be substantially eliminated. Then,
bonding the first, second and glass or ceramic
components together.
In accordance wit~ a further embodiment,
there is provided a process of forming a composite
adapted to be a circuit board system. The process
includes the steps of providing a first metal or
alloy component and providing a second metal or alloy
component. A bonding and insulating component is
disposed between the first and second components,
and the first and second bonding components are
bonded together. A grid component is embedded in
the bonding and insulating component for stiffening
the circuit board system.

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between each o~ the thin refractory oxide layers of two
metal base alloy components to provide rlgidity to the
mult i-layer c ompo s lt e ..
The lnventlon and ~urther deYelopments o~ the
invention are now el~1cidated by means Or preferred
~mbodiments shown in ~he drawings:
Figure 1 is a cross section of a prior art printed
clrcuit board;
~ gure 2 is a cross section o~ a metal core prior
art pr~nted cirruit board;
Figure 3 is a cross section of a printPd circuit
board haYing a glass c~mponent bonded between the
coating of two copper alloys in accordarlce with
the present invention;
Figure 4 is a printed circuit board haYing high
thermal conducti~ity su~strates bonded to copper alloy
com~onents;
Figure 5 is a cross-sec~ional view of a printed
circuit board with a ~used interfaced layer between
two substrates,
Flgure 6 is a prin~ed circuit board ha~ing
clrcuits on opposite surfaces and lnterconnections
there~etween;
~ igure 7 1~ a cross-sectional view o~ a printed
circu~t board hav~ng circuits on o~oosite surfaces and
a metal grid therebetween;
Figure 8 is a top view of a metal grid used ~or.
reinforcement o~ a printed circuit board;
Figure 9 i5 a view through 9-9 of F1gure 8;
30 Figure 10 is a side ~e~ o~ ~ mult~-12yer printed
circu~t board in accord~nce with the present inventlon;
~igure 11 1~ a slde Yiew of a leadless chip
carrier in accordance with ~he present in~ention;
~igure 12 i5 a ~lew through ~1-ll o~ ~igure 10;
and

.
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3~2
12~6-~B

~ igure 13 ls a side ~iew of a leadless chlp
ca~rier mounted upon a printed clrcuit board ln
accordance with the present invention~
As shown ~n ~gure 1, pr~or art printe~ c~rcults
10 are produced by adhering one or more layers o~ copper
foil 12 to organlc material 14 such as glass flber
re~nforced epo~y, phenolic laminated paper, etc. These
structures have se~eral deficiencies ~ncluding
~estricted maximum operating temperature due to the
or~anic su~strate and substantial mlsmatc~ between the
coefficient o~ thermal expanslon of the organic sub~
strate and that o~ the copper foil, the solder
composltions to attach components to the circuitry and
the components themselves~ Substantlal thermal
stresses, resulting ~rom the mismatch, create failure
modes such as tensile ~ailure of the copper foil,
~ailure o~ the solder attachment of components to the
clrcuit and tensile ~ailure o~ the components them-
~elves.
There is some use o~ metal core boards 16 fo~ld in
F~gure 2. Typically, these include a metal core 18, a
copper foll 22 and an epox~ insulating layer 20 bonded
to both layer 20 and foil 22. Thls type o~ board
pro~ides better heat dlssipatlon than the normal glass
~iber r~in~orced epoxy boards but still has the
restricted ma~imum operating temperature related to the
organic substra~e. Also, substantial mlsmatch between
t~e coef~icient o~ ~hermal e~pans~on o~ the organic
substrate and the copper ~oil causes the types of
problems associated wi~h conventional printed circults
as shown ln Flgure 1~
The present invention overcomes these problems
by providing a composite or printed circuit board
24 as shown in Figure 3. The composite may include
a first metal or metal base alloy component 26 having
a thin interface layer 28 on at least a ~irst

, .

~ 3~

- 12 -
surface 30 ther~of and a second thin interface layer
34 on at least surface 36 of a metal or metal base
alloy component 32. A glass component 38 is bonded
to the ~irst and second thin interface layers 28
and 34 to insulate the component 26 from the second
component 32.
The preferred alloy for use in the embodi-
ments of the present invention is a copper base alloy
containing from 2 to 12% aluminum and the balance
copper. Preferably, the alloy contains from 2 to 10%
aluminum, 0.001 to 3% silicon, and if desired, a
grain refining element selected from the group con-
sistiny of iron up to 4.5%, chromium up to 1%,
zirconium up to 0.5%, cobalt up to 1% and mixtures
o~ these grain refining elements and ~he balance
copper. In particular, CDA alloy C6381 containing
2.5 to 3.1% aluminum, 1.5 to 2.1% silicon, and the
balance copper is useful as a substrate for this
invention. Impurities may be present which do not
prevent bonding in a desired environment.
The 3110ys useful with this invention and,
especially alloy C6381 are described in U. S.
Patent Nos. 3,341,369 and 3,475,227 to Caule et al.
which disclose copper base alloys and processes for
2~ preparing them.

7~
13 -

The present invention is not restricted to
applications of alloy C6381 but includes the broad
field of metal or alloys which have the ability to
form continuous interface layers on their surface.
Several examples of other metal alloys such as
nickel base and iron base alloys are dlsclosed in
U. S. Patent Nos. 3,698,964, 3,730,779 and 3,810,754.
The present invention uses any suitable glass
or ceramic component 38, such as cited in the patents
above, preferably with a coefficient of thermal ex-
pansion which closely matches the metal components.
The glass is bonded to the thin inter~ace layers
28 and 34 and functions to adhere the metal com-
ponents together and electrically insulate them
from each other. Since the glass and the copper
alloy substrates preferably have the same or
closely matched coefficients of thermal expansion,
thermal stresses in the system may be essentiàlly
eliminated and the problems associated with thermal
stress in the finished product alleviated.
Table I lists ~arious exemplary glasses and
ceramics which are adapted for US2 in accor~ance with
this invention.


-14~ 1208~-M~

TABLE I
Coeff~clen~ Or Thermal
Gla~s or ~eramlc Type E
Ferro Corp~l No. RN 3066-H 167 x 10-7
Ferro Corp.l No. RN-3066-S 160 ~ 10-7

lPropr~etary composit~on manufactured by Ferro Corpora-
tion, CleYeland, Ohio.
Re~erring again to the embodiment as lllustrated
in ~g~re 3, a ~oll layer 32 is bonded to a th~cker
suppor~ive layer Z6 by means of glass 38. The foll 32
may be subsequentlally treated with a l'resist" pattern
and etched to produce a prlnted circuit. The result ~s
a wrought copper al~oy circuit attern bonded to and
insulated from a wrought copper alloy supportive
substrate 26 by a layer o~ glass 38 which serves as
both an adhesiYe and an insulating materlal. This
configuration has a number of advantages o~er the prior
technique Or printing circuitry upon the sur~ace of
porcelaln with conductiYe ink. Firstly, in the prior
20 conducti~e ~nk technology, multiple lay~rs of the
conductlYe ~n~ are applled to provide an adeauate
conductive pattern for the required electric current.
Xowe~er, the circuit foil 32 may be of any desired
thickness and rPplaces the multiple screening and
~5 ~ring operations by a single firing operation and a
single etch~ng operation. Secondly~ recent increases
in circuit density of prlnted circ~lit ~oards create a
need ~or narrower and more closely spaced printed
"wires" or lines. The prior conducti~e in~ technology
~s limited to the minimum line width ~enerated ~y the
printing process. The present invention, howeYer,
e~ches copper foil and provides narrow lines and spaces
25` in conYentional etched copper ~o~ 1, org~nic sub
strate circuits. Thirdly, the .~etalli~ed ~attern
35 formed on the conductiYe ~ nk-po-cel2~ n-steel ci~cult

372
_}5_ 12o86~

board has a substantiall~ hi~her coef~tcient of thermal
e~pans~on than the steel substrate. Thermal cycling
de~elops su~tantial shear forces at the clrcult~
porcela~n inter~ace creating subs'cantial rlsk of'
~ailure. The em~odlment of ~igure 3 su~stantially
ellminates these shear forces because the coef.icient
of thermal expansion of the circuit foil and the metal
s~strate may be substantially ~he same.
Where greater conductivity than that ~nherent in
the metal or alloys producing bondable alumlna and
sllica fi~ms is desired, a composite copper alloy ~o~l
incorpora~ing a hi~her conductivity layer, as shown in
Figure 4, may replace the solid alloy 32 as in the
previous embodlment.
The embodiment o~ Figure 4 includes bondable
copper alloy substrate 40 and circuit foil ~6
having inter~ace layers 41 and 43, respectively. A
~lass or cer~mlc 44 is bonded betwee~ ~he interface layer
43 on c~rcuit foil 46 and the interface layer 41 on the
copper base alloy 40. Substrate 40 ls bond~d, as a
composite, to a copper or high conductivity cop~er
alloy thicker component 42. l~e latter provldes for
super~or ther~al dissipation rom the board as compared
to both conventional copper foil organic boards and
25 porcelain on steel boards. Also, foil 4~ may be bonded
as a composite to a copper or high conductivity copper
alloy component 47 for superior electrlcal or therma
conducti~ity. It is also withln the scope o the
present invention to pro~ide only one of the components
- 30 42 or 4~ a~ required. It is also within the scope of
the present inYen~ion to modi~y any Or the descr~bed
embodiments by bonding the component, 2s a comDosite,
to a metal layer having desired ~hysic~l properties.
The embodiment as sho~m in ~i~ur_ 5 pro~Jides
co~pe~ alloy substrates 48 and 49 e2ch .or~in~ an
inter-face layer. These interface layers are
,

~2~ 72
-16 12086-~B

fused together inta layer 50 and dispense wlth the
pro~slon Or ~la~s. The un~ied interface layer
50 ~ot~ adheres the metal substrates 48 and ~9 and
insulates them from each other. It ls within the scope
of the lnvention to substitute the glass ln the embod-
iments of the present invention with fused interface
laye~s as desired.
~ he c~ple~ity of the circuitry for intercon-
necting the various devices mounted upon a printed
10. c~rcu~.t board a~ten req~ire~ that both surfaces of the
board contain conductiYe patterns. Details of prior
art tw~ sided circuit boards are described in the back-
ground o~ the ~nventlon.
A two sided circ~t board on~iguration 5~, as
sho~n in Figure 6, has two relatively thick layers of
copper ~ase alloy co~onents 50 and 52, each having
a thin interface layer 51 and 53, respectively,.
on at least one surface. The components are bonded
together and insulated ~ro:~ one another by a glass or
ceramic 54 which ls ~used to the interface layers 51 and
53. A circuit pattern is formed on each of the
c~mponents 50 and ~2 ~y a conYentional technique. The
t~lckness of each metal component ls estab~ ished in
accordance with the desired stlf~ness o~ the ~inished
boardO The circuit patterns on each side of the board
55 must be carefully designed to provide reasonable
sti~ness and to avoid plane~ of weaknes~. Such planes
might de~elop if an area o~ considerable size without
any clrcuitr~ on one side o~ the board coincides with
30 a similar area on the reverse side of the ~ond.
Through-holes 56 may be provided in the circuit board
by any conven~iorial technique such as drilling or
punching. The through-holes may be ~ormed into z
conductlve path by ~ny sul~able mearls such as electro_
3~ less deposition o, co~er on thei~ w~lls. I~ desired,

`` ~2~ 3~72

17 --
the through-holes can then ~e fillec3 with a conductive
material such as solder.
Another embodiment of a two sided metal y:Lass
printed cîrcuit board 57, as shown in Figure 7, includes
two copper alloy substra-tes 58 and 60, each having a
thin interface layer 62 and 64, respectively, bonded on
at least one surface. A glass component 65 is fused to
the layers 62 and 64. A grid 66, preferably metal, is
bonded in the glass 65 and insulated from the alloy
substrates 58 and 60. The recesses 68 of the grid may
be filled with glass 65 or any other suitable inorganic
filler~ q~hrough-holes 69 are formed in the board as
described above. The iresult is a board with the same
_ . .
aesign flexibility as conventional foil-organic boards
but with the advantage of substantial elimination of
thermal stresses. The metal grid both stiffens the
board 57 and permits a plurality of through-holes 69-to
i } pass through openings,~ of t:he grid. 'rhe through-holes
must not contact the metal grid to avoid short circuits.
~he metal grid is preferably made of a copper
alloy having a thin interface layer on both surfaces.
It is, however, within the scope of the present invention
to use any desired material to construct the grid. ~he
grid may be formed with any desired con~iguration, and
a typical one is shown in Figure 8. A series of recesses
68 are stamped in a metal sheet 67~ Subsequently, the
bottom ~ of the recesses are pierced leaving a pattern
o~ interlocking "V" bars, as shown in Figure 8, E~or
. ~ .
reinfc~rcement.
The need for still greater circuit complexity
than provided by a t~to sided circuit boara leads to
multi-layer circuit boards with three or more layers o
copper foil. Using the concepts ~escribed hereinabove,
a multi layer board composed of alternate layers of
copper alloy foil having a thin interface layer

-18~ 2 12086-i~

on each surface ~n contact ~ith the glass insulator ls
descrlbed. As shown in Figure 10, copper foil com-
ponents 70, 71 and 72 have their interface
l~yers 73, 74 and 75~ respectively, bonded to glass 76.
5 The foll components may each be proYlded wlth circuitry
as in khe em~odiments described above. Also, the
components may be bonded as composites to other metals
wit~ desired physical properties 2S described aboYe.
It is ~hought that the thicker multi-layer boards will
10 be suf~iciently r~gid. Where addltional rigidity ls
required, grid relnforcement as descriDed and illu-
strated in Fi~e 7 may be added. Also, throu~h-holes
77~78 and 79 between the circuits9 as described above~
may be provi~ed as necessary. Note that the throu~-
holes may be between any number o~ circuits.
Since the power consumption o~ most board mounted~lectronic components is qulte modest, the heat
generated during their operatlon is comparably small.
However, as packaging denslty becomes greater, more
elaborate means for cooling must be provided. The
present invention proYides for cooling of the multi-
layer printed circult boards, as shown in Figure 10,
by bonding high thermal condu~ti~ity layers of copper
2110y tO the circuit ~oil, as in Figure 4. This lzyer
25 Q~ copper alloy ~unctions to condurt heat ~rom the
board. It ls within the scope of the invention to
pro~de one or more layers of conducti~e material 80
with~n ~he multi-layer boardO Material 80 may be a
solid strip o~ hlgh thermal conducti~lty material such
as copper or copper alloy. Xt ~aY be desirable to use
a copper alloy hav~ng an interface layer for
i~pro~ed ~ondin~ to the glass 76. Naturally, an~
through-holes may reau~re insul~tion rrom the strip 80.
The con~uc~i~e materlal 80 may comprise one or ~ore
tubular members e~bedded ln ~he glass ~o Dro~ide
cool2nt passages. Again, lt is prefer2ble tha~ the

3~
., ~

-- 19 --
copper tubing have a thin interface layer on its surface
to bond to the glass.
Another important aspect of the present invention
resides in the provision of a leadless ceramic chip
carrier which can be directly mounted to the surface of
a printed circuit board. This chip carrier substantially
eliminates excessive stressing of the solder bond to the
circui-t board which generally occurs during thermal
cycling of the chip carrier-printed circuit board
systems as described hereinabove. Referring to Figures
11 and 12, there is illustrated a leadless chip carrier
90 wherein a copper alloy 92 with a thin interface layer
93, such as A1203, provided on one surface thereof is
substituted for the prior art alumina or beryllia
ceramic. A glass 94 may be fused onto the interface
layer as described above. It is, however, within the
scope of the invention to use only the interface layer.
As can be seen in Figure 11, the copper alloy 92 may
be shaped with a slight indentation 96, exaggerated
in the drawing to better clarify the concept. It is
within the scope of the present-invention to form the
indentation in any desired configuration. A metal foil
98, which may be formed of thè same material as 92,
having an interface layer 99, is bonded to the glass
94 or interface layer 93 and etched in any conventional
manner to provide electrical leads 100. A chip 102 is
preferably attached to the glass 94 by any conventional
technique and lead wires connected between the circuitry
on the chip and the leads 1009
~30 The chip may be sealed within the indentation
96 by several techniques. Preferably, the sealing device
97 may be a cover plate 104 comprising a copper or
copper base alloy having a thin interface layer
thereon. Glass 95 is fused onto at least the edges
of the cover 97~ This glass can be bonded to either

-20- 120a6-~B

the interface layer 99 on the comp~nent 98 or to the
glass 94 as required. The result i~ to hermetically
seal t~e c~ip 102 in the leadless chip carrier gO.
~nother em~odimenk provides the se~l by ~illing the
lndentatlon 96 with an epoxy. The epo~y will bond to
the leads and the glass and provide an adequate but not
necessar~ly hermetic seal.
~ eferrlng to Figure 13, the leadless chip carrler
90 is affi~ed to a typical printed circuit board 110.
This board has copper foil 112 and 114 separated by
glass clo~h reinforced epo~y 116. A c~rcuit ls
proY~ded on the foil 11~. ~ne leadless chip carrier
may ~e applied direct~ onto the ~ircuitry of strip 112
~y solder pads 118 between the lead 100 and the foil
112 i~ a co~Yentional manner.
Alloy C6381, the preferred material of alloy
com~onents 92 and 98 Or the chlp carrier9 has ~
coe~ficient of thermal expansion of 17.1 ~ 10 ~C.
This is only 8 . 2% dlfferent from the coe~ficient o~
-20 thermal e2pansion o~ convent~onal glass cloth rein-
forced epo~y which is 15.8 x 10 6/oC. This is a vast
- improvement o~er chip carrier~ formed of alum~na
cer~mic which ha~e a coef~icient o therm~l expanslon
o~ 6.4 ~ 10-6fC~ i.e. aporoximztely 144p greater than
25 the thermal expansion o~ the zlumina ceramic. The
result is a significant decre2se in the ~ormation of
stress bet~een the solder, leads and circutt board due
to thermal cyc ling .
As the number of individual Lunctions incorporated
upon a slngle sil~con chip becomes larger, the amoun~
of heat generated requir~ng dissipation increzses
accord~ngt~ Also, as the nu~.ber o~ ~unc~ions become
-eater9 they are packed more closely`toether on ~he
chip which ~urthe~ ma~nifies the D~oblem of heat
- 35 dissipation. It ls 2 furth~r adYanta~e of the prosent
inYention that the ther~al co~ductiv~ty of alloy C6381 is


-21- 120~6-~

24 Btu~ft2J~t~hr/F. Thls is 131d greater than the
thermal con~uctivlty of alumina o~ide (typlcally used
for chip carrier~) which is 10.4 Btu~t2~ft/hr/F.
Also, the thermal resistance imposed between the chip
and the e~ter$or means of heat dissipation is reduced
because of the khinner sect~ons of the tou~her ~aterlal
such as 6381 which are aDle to replace the thlcker, more
fragile and brittle materials such as alumlna cer2mics~
It should ~e noted that in certain applicatlons,
beryllla with a the~al conducti~ity of 100 Btu~ft2~ft/
hr/F is used as a substrate ~or better heat dissi-
pation despite lts e~tremely high cost,
Referring again to Figure 11, the copper alloy
romponent ~2 with an interface layer may be clad
upon copper or any high conductivity alloy~
Assuming that the composlte metal is appro~imately 10%
alloy C6381 clad upon gaz alloy C151~ the oYerall
thermal conducti~ity is 196 Btu/ft2/~t/hr/F. This is
18~8% better than ~he thermal conductiYity of alumina
ana 63~ better than that pro~ided by beryllia. In addl-
tlon, there ls the additlonal ad~antage o~ a thinner chip-
less carrier as comp~red to a thicker. alumina carrier~
~ e sllr~ace mounted hermetic chip carrier as
described above an~ illustrated in Figure 12 will
resolYe most of the normal problems associated wi~h the
effect of thermal cycling on a chip ~arrier that is
surface mounted to a conYent~ onal glass cloth reinforced
epo:cy prin~ed circuit board. ~iowe~rer in some cases, 2
closer match of coef~icient of the~al ex~ansion may be
required and/or greater heat`dissipation ca?ability may
be necessary. In t~ese cases, a metal board confi~-
uration Or the types descr~ bed hereinabove and
~llustrated iIl Flgures 2-~1 and 10 may be su~stituted for
~he conYent;ional printed circuit board.
In one embod~.T.ent, reduced ml smatch of ther~21
e~parlsion and ~. eal;er heat dissi~ation can be zchie~ed

~3~'~2
-22 1208~ l~B

b~ mounting a chlp carrier Or t~e type illustrated in
~lgures 11 and 12 o~ a prlor art printed circu~t board
as shown ln Figure 2 where t~e core is copper or a hlgh
conductl~ity copper alloy. An alloy may be desirable
~ greater stren~th is req~ired than may be provided
w~th pure copper. A suitable plastic lnsulating layer
20 ls appropriately ~onded to the copper or copper
alloy core and in turn, the prlnted c.ircult ~oil 22 is
bonded to the lnsulating layer. The plastic must. be
suitable ~or bonding with adhesi~es~ ha~e suikable
dielectr~c .ch~racter~stics and the ahility to withstand
processlng temperatures such as soldering. The
thermally conductive plastics may be particularly
usefu~ for the plastic layer. T~ese plastics typically
1~ eontatn metal powders to ~mproYe thelr thermal conduc-
ti~lty while maintainlng dielectric properties since
the metal powders are not in a contlnuous phase. Since
the plastic is only thick enough to pro~ide the
necessary dielectric properties, resistance to heat
trans~er from the chip carrler to the high conductiYity
copper or copper alloy core is minimized. Xt can be
appreciated that the coefficient of thermal expansion
of the metal board is essenti211y the same as that Or
the glass coated chlp carrier and, thererore, stresses
lnduced by thermal cycling of the system are substanr
tially eliminated, This con~iguratlon is limited by
the temperature capability o~ the plastic or plastics
and th@ temperature resistance of the adhesi~es whlch
are used in con~unction with the pl2stics.
To improve the m~ximum te.~per2ture c2~ability o~
the leadless chip carrier and pr~ntea circuit board
combinakion, a printed circuit boa.d as illustrated in
Figure 3 may be used in con~unction with the leadless
chip carrier 90 shown in Figure 11. In thls config-
uration, the metal core consists oi copper or a hi~h
conductiYity copper alloy 26 to whicn is clad ~lloy

2~L3q~2
-23- 12086-MB

C6381 or an alternat~2 glass bondable copper alloy.
In turn, a printed circuit foll 32 consisting of a
glass ~ondable copper alloy such as C6381 is bonded to
the glass 38~ The alloy bonded to the C6381 may be
selected from copper or high conductivity copper alloys
so as to improve the electrical conductivity in the
c1rcult or to provide optimum solderabillty character-
istics. The system is completely inorganlc and will
withstand temperatures much higher than systems with
organic materials and further avoids va.rious modes of
degradation to which organic materlals are susceptible.
An additi~re circuit may be substituted for photo-
etched fc~l 48 in Figure 5O The circuit may be
generated upon a glass coating applied to the
interface layer on alloy C6381 or other glass
bondable alloy core material 49 using con~entional
techniques employed in generating addit~ve circuits.
~or exampleg the additi~e circui~ may be a pattern
printed upon the surface o~ ~he glass with conductiYe
ink and ~ired lnto pl~ce. It is also within the scope
of t~e present invention for the alumina film which may
be ~ormed by heating th~ alloy to be used as the
d~electr~c layer separat~ng the metal core from the
additiYe circuit~
Whereas an interface layer has been described as being
~ormed by separately heating the metal or alloy, it may
be ~ormed in any manner such as during the process of
bonding the me~al or alloy ~o the glass, ceramic or
another ~e layer~
Whereas the chip carrier has been descrlbed as
leadless~ lt is ~lso within the scope of the present
invention to substitute a chip carrler with leads.

., ~

3~

- 24 -
Although the disclosure has thus far described
embodiments using interface layers, it will be apparent
to one skilled in the art that such layers are not
necessary to meet the objectives of the invention.
For example, a preferred embodiment of the invention
does not have any interface layer between the glass
component and each of the metal or alloy component.
Another preferred embodiment of the invention com-
prises at least one such interface layer made of a
material other than refractory oxide, e.g. made of
any oxide such as copper oxide..
It is apparent that there has been provided in
accordance with this invention a composite, a chip
carrier and a system of mounting the chip carrier with
1~ the composite which satisfies the objects, means,
and advantages set forth hereinabove. While the
invention has been described in combination with the
embodiments thereof, it is evident that man~ alterna-
tives, modifications, and variations will be apparent
to those skilled in the art in light of the foregoing
description. Accordingly, it is intended to embrace
all such alternatives, modifications, and variations
as fall within the spirit and broad scope of the
appended claims.

Representative Drawing

Sorry, the representative drawing for patent document number 1213072 was not found.

Administrative Status

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Administrative Status

Title Date
Forecasted Issue Date 1986-10-21
(22) Filed 1983-10-19
(45) Issued 1986-10-21
Expired 2003-10-21

Abandonment History

There is no abandonment history.

Payment History

Fee Type Anniversary Year Due Date Amount Paid Paid Date
Application Fee $0.00 1983-10-19
Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
OLIN CORPORATION
Past Owners on Record
None
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Drawings 1993-07-15 2 84
Claims 1993-07-15 2 74
Description 1993-07-15 25 1,300
Abstract 1993-07-15 1 17
Cover Page 1993-07-15 1 15