Note: Descriptions are shown in the official language in which they were submitted.
2014579
1 --
TNK CoMposITIoN
This invention relates to an ink composition
affording white ink images which are erasable, for
5 example, by wiping with a wet cloth impL~I.ated with
water or an organic solvent or by heating. The present
invention is also r~nc~rnc~d with a writing in~LL L
t~ inq the above ink.
Various erasable inks are known and are utilized in
10 the ~ield of, for example, sewing or arts and crafts.
The known erasable inks now on the market, however, are
~r~ ' i nAntly of a type which gives blue or dark color
ink images and, therefore, are not suited for writing on
a dark-colored surface. Known white colored inks
15 generally contain a white pigment or dye and are not
easily erasable.
United States patent No. 4,744,826 issued to
Zenshiro Ii~ ima ~ rlo~P~ an aqueous transparent ink
composition af~ording erasable, white ink images. This
20 composition contains an ammine complex salt of zinc.
Upon use, the ammine complex ~ L to liberate
ammonia and to leave white zinc hydroYide. Thus, this
ink has a problem that odor of ammonia emanates upon use.
The present inventlon has been made to solve the
25 above - i ~n~d problems and ~ _ lates provision of an
ink composition which gives easily erasable, white ink
images .
An aspect of this invention is as follows:
A Dul.DLdllLially colorless, transparent ink
30 composition which turns white upon use, comprising:
(a~ an organic solvent; (b) an organic DuL;~Ldl~Ce selected
from salicylic acid and acetylsalicylic acid which is
dissolved in said organic solvent, the amount of said
organic substance being at least 15~ based on the total
35 weight of said organic solvent and said organic
substance; and (c) a polymer which is dissolved in said
organic solvent and which has a molecular weight of at
least 10, 000.
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The ink composition of the present invention is sub-
stantially colorless and transparent. When applied on a
-
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fabric, paper, leather or the like surface, however, the ink
image becomes white colored as a result of evaporation of the
solvent with the simultaneous deposition of the organic
substance on the applied portion. The resulting white ink
5 images may be easily removed by, for example, wiping with a wet
cLoth impregnated with water or an organic solvent or heating
with an iron.
The present invention will now be described in detail
below .
Any organic solvent may be used for the purpose of the
present invention as long as it can dissolve the organic
substance used as a colorant. Illustrative o suitable solvents
are alcohols, ethers, ketones, esters and halogenated
hydrocarbons. Since it is generally desired to shorten the
period of time through which the applied ink turns white, the
use of a solvent having a low boiling point, especially a
boiling point of 30-150 C is preferred.
Particularly suitable solvents are ketones and
aliphatic monohydric alcohols having a boiling point of 50-100
C. When the polymer which is to be incorporated into the ink
composition of the present invention and which serves as a
penetration inhibiting ingredient is hardly soluble in such an
aliphatic monohydric alcohol, then it is recommendable to use a
halogenated hydrocarbon in con~unction with the monohydric
alcohol. Thus, the solvent is preferably selected from
methanol, ethanol, isopropyl alcohol, isobutyl alcohol,
secondary amyl alcohol, tertiary amyl alcohol, acetone, methyl
ethyl ketone, chloroform, dichloroethane, trichloroethane, - ~
acetonitrile and mixtures thereof.
Any solvent solubLe, relatively low molecular weight
organic substance may be used as a colorant for the ink
composition of the present invention as long as it is by itself
a colorless or white solid at room temperature. Since it is
convenient and desirable that the written ink images be erased
by water-wet cloth, the use of a water-soluble organic substance
is preferable.
Illustrative of suitable organic substances are
~ 3 ~ 201~5~9
aminoquinoline, benzoic acid, 3-oxy-1 ,4-pyrone, quinazoline,
chlorofumaric acid, tolylenediamine, salicylic acid, 2,4,6-
trioxynaphthalene, o-phenylenediamine homocatechol, phtalic
acid, acetylsalicylic acid, dichlorobenzene, acetonaphalide,
ael~tr~x;m~-, aminobenzyl alcohol, isosaccharic aicd, isovanillic
acid, teraconic acid, indazole, ethylurea, ethylmalonic acid,
hydroxy-p-toluic acid, oxy-2-naphthoic acid, oxyhydroquinone,
2-hydroxypyridine, m-hdroxyphenylacetic acid, hydroxybenzyl-
alcohol, -hydroxybutylic acid, orcinol, ethyl carbamate,
valeramide, quinonechloroimine, glyoxime, glutaconic acidr
chlorobenzoic acid, colchiclne, diethylurea, dihydroxy-
naphthiqlon~-lihydroxyphthalic acid, diglycolic acid, cyclohexane
dicarboxylic acid, dichloroacetamide, dichlorophthalic acid,
dihydroresorcin, dibromosuccinic acid, dimethylnitroamine,
dimethylurea, dimethylpyrone, dimethylphosphinic acid,
dimethylresorcin, sulfamoylbenzoic acid, sulfobenzoic acid,
thioacetamide, desoxalic acid, tetrahydroxybenzene, tetrolic
acid, tri;~min~h~nzene~ trihydroxyanthracene, trihydroxy-
naphthalene, trichlorolactic acid, tribromoacetic acid,
trimethylfluoroglycine, naphthalene sulfonic acid, nitrophthalic
acid, hydrocoumalic acid, hydrotoluquinone, bipyridine,
pyrazole, pyridinecarboxylic acid, o-phenylenediamine,
fulminuric acid, bromopropionic acid, bromomaleic acid,
hexahydrosalicylic acid, hyxahydroterephthalic acid,
pentaglycerine, homochatecol, formylbenzoic acid, methyl-
hydantoin, cr~sorcinol, malic acid and leucic acid.
Above all, the use of water-soluble substances, such
as salicylic acid, acetylsalicylic acid and benzoic acid, are
especially preferably used because they give clear white ima~es
which are ~asily erased when wiped with a wet cloth impregnated
with water. The use of sublimable substances is also preferred
since the resulting ink images vanish when heated with a heater
such as an iron or when allowed to stand for a suitable period
of t ime .
In order to obtain clear ink images, the organic
substance serving as a colorant should be used in an amount of
at least 10 ~6 by weight, preferably 15 % by weight based on the
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total weight of the organic solvent and the orqanic substance.
The upper limit is a concentration providing the saturated
solution. Since a saturated solution is apt to foFm solids due
to the evaporation of the solvent, it is desired that the upper
5 limit of the content of the organic substance be maintained
slightly below the saturation concentration, preferably 95 96 of
the saturation concentration. Preferred content of the organic
substance is 70-95 56 of the saturation concentration.
The ink composition additionally contains a polymer
10 ~ having a molecular weight of at least 10,000. The polymer is
used in an amount sufficient to prevent the organic substance
from being absorbed quickly in a paper or cloth on which an ink
¦ pattern is to be formed. Any polymer may be used for
controlling the penetrability of the ink composition as long as
it is soluble in the solvent used. Illustrative of suitable
polymers are poly(ethylene oxide), poly(vinylpyrroIidone),
poly(vinyl butyral), polyacrylate, poly(vinyl acetate), phenol
resins, shellac, rosin, dammar and copal. The polymer serves to
prevent the occurrence of blurs of the ink images. Polyethylene
oxide having an average molecular weight of about 105 to 5x1 o6
is especially suitable for the purpose of the present invention.
The amount of polymer used varies with its moleculaF weight but
is generally 0.001-10 g per 100 g of the total weight of the
solvent and the organic substance.
The ink composition accsrding to the present invention
is suitably used for a writing instrument having a porous or
fibrous tip, such as a felt-tip pen. The ink is contained in an
ink tank which is in fluid communication with the tip.
The letters or patterns written with such a writing
instrument are initially illegible. After a period of, for
example, 2-1 5 seconds, the ink image turns white as a result of
evaporation of the solvent. The ink image may be erased by
wiping with an organic solvent-impregnated cloth. When the
organic substance used as a colorant is soluble in water, the
ink image may also be erased with a water-impregnated cloth.
The ink image may be vanished when heated at a temperature above
the boiling point of the organic substance. When a sublimable
~ ~ 5 201~79
compound is used as the organic substance, the resulting ink
image vanishes with time.
!The following examples will further illustrate the
present invention.
Example 1
Ben~oic acid (36 g) was dissolved in 100 g of
isopropyl alcohol to obtain a f irst solution and 0 . 5 g of
poly(ethylene oxide) having a molecular weight of 1.7 x 106 to
2 . 2xl o6 was dissoLved in 50 g of methylene chloride to obtain a
second solution. The first solution (100 g) was then mixed with
10 g of the second solution to obtain a colorless, transparent
ink composition. This composition was charged in an ink tank of
a felt-tip pen. A pattern was drawn on a black fabric with the
pen. A clear, white image was obtained after 5 seconds from the
drawing. This image was able to be erased by wiping with a
water-impregnated wet cloth. By ironing the fabric, the ink
image also vanished. The felt-tip pen was also able to write
easily on a leather.
Example 2
Benzoic acid (3~ g) was dissolved in 100 g of a mixed
soLvent consisting of 80 g of isopropyl alcohol and Z0 g of
methylene chloride, in which 0.6 g of poly(ethylene oxide)
having a molecular weight of 1 .7 x 106 to 2.2 X106 was further
dissolved, thereby to obtain a colorless, transparent ink
composition. This composition was charged in an ink tank of a
felt-tip pen. A pattern was drawn on a black fabric with the
pen. A clear, white image was obtained after 3 seconds from the
drawing. This image was able to be erased by wiping with a
water-impregnated wet cloth. By ironing the fabric, the ink
image also vanished. The felt-tip pen was also able to write
easi ly on a leather .
Example 3
Salicylic acid (35 g) was dissolved in 100 g of a
mixed solvent consisting of 80 g of isopropyl alcohol and 20 g
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of ethanol to obtain a first solution and 2.5 g of poly(ethylene
oxide) having a molecular weight of 6 x 105 to 1 .1 x1 o6 was
dissolved in 50 g of ethylene dichloride to obtain a second
solution. The first solution (150 g) was then mixed with 5 g of
5 the second solution to obtain a ct~lorless, transparent ink
composition. This composition was charged in an ink tank of a
felt-tip pen. A pattern was drawn on a black fabric with the
pen. A clear, white image was obtained after 3 seconds from the
drawing. This image was able to be erased by wiping with a
10 water-impregnated wet cloth. By ironing the fabric, the ink
image also vanished. The felt-tip pen was also able to write
easily on a leather.
Example 4
~;alicylic acid (36 g) was dissolved in 100 g of a
mixed solvent consisting of 80 g of isopropyl alcohol and 20 g
of ethylene dichloride, in which 0.5 g of poly(ethylene oxide)
having a molecular weight of 6 x 105 to 1.1 x 106 was further
dissolved, thereby to obtain a colorless, transparent ink
composition. This composition was charged in an ink tank of a
felt-tip pen. A pattern was drawn on a black fabric with the
pen. A clear, white image was obtained after 3 seconds from the
drawing. This image was able to be erased by wiping with a
water-impregnated wet cloth. By ironing the fabric, the ink
image also vanished. The felt-tip pen was also able to write =~
easily on a leather.
Example 5
Acetylsalicylic acid (23 g) was dissolved in 100 g of
a mixed solvent consisting of 80 g of isopropyl alcohol and 20 g
of ethylene dichloride, in which 0.2 g of poly(ethylene oxide)
having a molecular weight of 3.3 x 106 to 3.8 x106 was further
dissolved, thereby to obtain a colorless, transparent ink
composition. This composition was charged in an ink tank of a
felt-tip pen. A pattern was drawn on a black fabric with the
pen. ~ clear, white image was obtained after 3 seconds from the
drawing. This image was able to be erased by wiping with a
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water-impregnated wet cloth. By ironing the fabric, the ink
image also vanished. The felt-tip pen was also able to write
easily on a leather.
The invention may be embodied in other specific forms
5 without departing from the spirit or essential characteristics
thereof. The present embodiments are therefore to be considered
in all respects as illustrative and not restrictive, the scope
of the invention being indicated by the appended claims rather
than by the foregoing description, and all the changes which
10 come within the meaning and range of equivalency of the claims
are therefore intended to be embraced therein.
