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Patent 2026470 Summary

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(12) Patent: (11) CA 2026470
(54) English Title: APPARATUS AND METHOD OF MANUFACTURING SYNTHETIC BOARDS INCLUDING FIRE-RETARDANT BOARDS
(54) French Title: DISPOSITIF ET METHODE DE FABRICATION DE PANNEAUX DE MATERIAU SYNTHETIQUE, Y COMPRIS DES PANNEAUX IGNIFUGES
Status: Expired
Bibliographic Data
(51) International Patent Classification (IPC):
  • B27N 3/06 (2006.01)
  • B27K 3/04 (2006.01)
  • B27K 3/06 (2006.01)
  • B27K 3/10 (2006.01)
  • B27K 3/20 (2006.01)
  • B27N 1/02 (2006.01)
  • B27N 3/04 (2006.01)
  • B27N 3/10 (2006.01)
  • B27N 3/12 (2006.01)
  • B27N 3/26 (2006.01)
  • C08K 3/32 (2006.01)
  • C08K 5/17 (2006.01)
  • C09K 21/04 (2006.01)
  • D21J 1/00 (2006.01)
  • D21J 1/08 (2006.01)
  • D21J 1/16 (2006.01)
(72) Inventors :
  • TRELIVING, GORDON (Ireland)
  • KIRWAN, RORY GERARD (Ireland)
  • HARMON, DAVID M. (United States of America)
  • BAUER, TED J. (United States of America)
(73) Owners :
  • WEYERHAEUSER NR COMPANY (United States of America)
(71) Applicants :
(74) Agent: OYEN WIGGS GREEN & MUTALA LLP
(74) Associate agent:
(45) Issued: 1998-12-01
(22) Filed Date: 1990-09-28
(41) Open to Public Inspection: 1991-09-15
Examination requested: 1993-11-19
Availability of licence: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): No

(30) Application Priority Data:
Application No. Country/Territory Date
910/90 Ireland 1990-03-14

Abstracts

English Abstract



APPARATUS AND METHOD OF MANUFACTURING
SYNTHETIC BOARDS INCLUDING FIRE-RETARDANT BOARDS
Abstract of the Disclosure
A method and apparatus for producing a synthetic
board from cellulosic or lignocellulosic fibers is
disclosed wherein a standard isocyanate binder is
emulsified and immediately applied to the fibers before
consolidation into a finished board product. The
apparatus includes an emulsification and application
nozzle comprising a diluent inlet, a binder inlet, a
mixing section for emulsifying the diluent and the binder,
and a spray nozzle for applying the binder/diluent
emulsion to the fibers. The method includes supplying a
binder stream, supplying a diluent stream, emulsifying the
binder with the diluent and immediately applying the
emulsion to the fibers. The method further includes
flushing the binder/diluent emulsion using the diluent at
the end of a binder application run to prevent curing of
the emulsion and clogging of the apparatus. The
binder/diluent emulsion can be applied to the fibers
either in the blowline or downstream of the blowline, such
as in the blender. A method and apparatus are also
disclosed for producing fire-retardant boards in which a
fire-retardant chemical, such as an ammonium
polyphosphate, is applied to the fibers downstream of the
refiner and upstream of the mat-former. Finally, a fire-
retardant board product is disclosed that is made in
accordance with the foregoing described methods and
apparatuses.


French Abstract

MACHINE ET METHODE DE FABRICATION DE PANNEAUX AGGLOMERES, Y COMPRIS DE PANNEAUX IGNIFUGES Cette invention concerne une machine et une méthode de fabrication de panneaux agglomérés à partir de fibres cellulosiques ou lignocellulosiques où un liant d'isocyanate standard est émulsifié et appliqué immédiatement sur les fibres avant leur agglomération en produit fini. La machine comprend une buse d'émulsification et d'application comportant une arrivée de diluant, une arrivée de liant, une chambre de mélange servant à émulsifier le diluant et le liant, et un atomiseur d'émulsion liant/diluant pour l'imprégnation des fibres. La méthode comprend l'alimentation en liant et en diluant, l'émulsification du liant au moyen du diluant et l'application immédiate de l'émulsion sur les fibres. La méthode comprend en outre l'évacuation de l'émulsion diluant/liant résiduelle, sous jet de diluant en fin de cycle, pour éviter le séchage en place de l'émulsion et le colmatage des buses. L'émulsion peut être appliquée sur les fibres dans le tuyau de décharge ou en aval de celui-ci, notamment dans le mélangeur. Cette invention concerne également une méthode de production de panneaux ignifugés selon laquelle un produit chimique d'ignifugation, du polyphosphate d'ammonium par exemple, est appliqué sur les fibres entre le raffineur et la presse d'agglomération. Enfin, l'invention divulgue un panneau ignifugé fabriqué selon les méthodes et par les machines ci-dessus décrites.

Claims

Note: Claims are shown in the official language in which they were submitted.


- 22 -

The embodiments of the invention in which an
exclusive property or privilege is claimed are defined as
follows:
1. An apparatus adapted for mixing a binder
stream and a diluent stream and applying the product
stream to the fibers in the production of synthetic
boards, the apparatus comprising:
binder inlet means for receiving a first stream
containing a binder;
diluent inlet means for receiving a second stream
containing a diluent;
mixing means fluidly connected to the binder
inlet means and the diluent inlet means for mixing the
first stream and the second stream to produce a fourth
stream containing a product stream containing the binder
and the diluent; and
outlet means positioned proximate the mixing
means and fluidly connected to the mixing means for
immediately applying the product stream to the fibers.
2. The apparatus of claim 1 wherein the binder
inlet means comprises binder control valve means for
automatically stopping the flow of the first stream upon a
decrease in application pressure thereof.
3. The apparatus of claim 1 wherein the diluent
inlet means comprises diluent control valve means for
automatically stopping the flow of the second stream upon
a decrease in application pressure thereof.
4. The apparatus of claim 1 wherein the mixing
means emulsifies the binder and the diluent in the fourth
stream.
5. The apparatus of claim 1 wherein the mixing
means comprises a plurality of baffles.
6. The apparatus of claim 1 wherein the outlet
means comprises a spray nozzle.
7. The apparatus of claim 1 and further
comprising flush means for flushing the mixing means with
the second stream after flow of the first stream is
stopped.

- 23 -

8. The apparatus of claim 7 wherein the flush
means comprises means for first stopping flow of the first
stream and then stopping flow of the second stream.
9. The apparatus of claim 1 and further
comprising:
supplemental inlet means fluidly connected to the
mixing means for receiving a third stream, wherein the
third stream is mixed with the first stream and the second
stream informing the product stream.
10. The apparatus of claim 1 for producing synthetic
boards from a cellulosic material, including:
refining means for extracting fibers from a
cellulosic material;
conduit means connected to the refiner means for
conveying the fibers along the fiber flow path;
binder application means for mixing a binder and
a diluent to form a binder/diluent mixture and immediately
mixing the binder/diluent mixture with the fibers in the
fiber flow path;
dryer means for partially dewatering the
fiber/binder mixture;
forming means for creating a mat of the dewatered
fiber/binder mixture; and
heated pressing means for compressing the fibers
and curing the binder in the mat for forming a
consolidated board product.
11. The apparatus of claim 10 wherein the binder
application means comprises:
binder inlet means for receiving a first stream
containing a binder;
diluent inlet means for receiving a second stream
containing a diluent;
mixing means fluidly connected to the binder
inlet means and the diluent inlet means for mixing the
binder and the diluent to produce a mixed product stream
thereof; and
outlet means positioned proximate the mixing
means and fluidly connected to the mixing means for

- 24 -

immediately applying the emulsion to the fibers in the
fiber flow path.
12. The apparatus of claim 11 wherein the binder
inlet means comprises binder control valve means for
automatically stopping the flow of the binder stream upon
a decrease in application pressure thereof.
13. The apparatus of claim 11 wherein the
diluent inlet means comprises diluent control valve means
for automatically stopping the flow of the diluent stream
upon a decrease in application pressure thereof.
14. The apparatus of claim 11 wherein the mixing
means comprises an in-line mixer.
15. The apparatus of claim 11 wherein the mixing
means comprises a plurality of baffles.
16. The apparatus of claim 11 wherein the outlet
means comprises a spray nozzle.
17. The apparatus of claim 10 and further
comprising:
flush means for flushing the binder/diluent
mixture from the binder application means at the end of a
production run.
18. The apparatus of claim 17 wherein the flush
means comprises:
means for stopping the flow of binder from the
first stream and then stopping the flow of diluent from
the second stream.
19. The apparatus of claim 10 wherein the
binder/diluent mixture is mixed with the fibers upstream
of the forming means.
20. The apparatus of claim 10 wherein the
conduit means comprises a blender means positioned along
the fiber flow path for receiving and mixing the fibers,
wherein the binder application means is plumbed to the
blender means for applying binder to the fibers therein.
21. The apparatus of claim 10 wherein the
conduit means comprises a blowline means wherein the
binder application means is plumbed to the blowline means
for applying binder to the fibers therein.

- 25 -

22. A method of blending a binder with
cellulosic fibers in the manufacture of synthetic boards
from cellulosic fibers, the method comprising:
conveying cellulosic fibers in a first stream;
conveying a binder in a second stream;
conveying a diluent in a third stream;
merging the second stream and the third stream to
produce a fourth stream; and
immediately thereafter merging the fourth stream
and the first stream to apply the binder and the diluent
to the fibers.
23. The method of claim 22 and further
comprising the step of:
mixing the second stream and the third stream to
produce a binder/diluent mixture in the fourth stream.
24. The method of claim 23 and further
comprising the step of:
emulsifying the binder/diluent mixture
immediately before the fourth stream with the first
stream.
25. The method of claim 24 wherein the
binder/diluent mixture in the fourth stream is emulsified
by forcing said stream through a plurality of baffles.
26. The method of claim 22 and further
comprising the step of:
flushing the second stream at the end of a
production run using the third stream.
27. The method of claim 22 and further
comprising the step of:
conveying a release agent in a fifth stream;
merging the fifth stream with the second and
third streams immediately before merging the fourth stream
and the first stream.
28. The method of claim 22 and further
comprising the step of:
conveying the sizing agent in a fifth stream;

- 26 -

merging the fifth stream with the second and
third streams immediately before merging the fourth stream
and the first stream.
29. The method of claim 22 wherein the binder
comprises a thermosetting binder.
30. The method of claim 22 wherein the binder
comprises a material selected from the group consisting of
monomeric isocyanates, oligomeric isocyanates and mixtures
thereof having a functionality of at least 2.
31. The method of claim 22 wherein the diluent
comprises water.
32. The method of claim 22 wherein the binder
comprises a thermosetting binder and the diluent comprises
water.
33. The method of claim 22 for producing synthetic
boards from a cellulosic material, including the steps of:
extracting hot and wet fibers from a cellulosic
material;
transporting the hot and wet fibers in a first
stream;
transporting separate second and third streams
comprising a binder and a diluent, respectively, generally
toward the first stream;
merging the second and third stream to form a
fourth stream;
emulsifying the binder and the diluent in the
fourth stream;
immediately after emulsifying, applying the
binder/diluent emulsion in the fourth stream to the hot
and wet fibers in the first stream;
partially dewatering the hot and wet fibers;
forming the partially dewatered fibers into a
mat; and
compressing the mat in a heated press to cure the
binder to form a consolidated board product.
34. The method of claim 33 wherein the
emulsifying step comprises:

- 27 -

conveying the merged binder and diluent in the
fourth stream around stationary baffles in the fourth
stream to intermix and emulsify the binder and the
diluent.
35. The method of claim 33 and further
comprising:
flushing the binder/diluent emulsion at the end
of a production run using the third stream.
36. The method of claim 33 wherein the binder
comprises a thermosetting binder.
37. The method of claim 33 wherein the binder
comprises a material selected from the group consisting of
monomeric isocyanates, oligomeric isocyanates and mixtures
thereof having a functionality of at least 2.
38. The method of claim 33 wherein the diluent
comprises water.
39. The method of claim 33 wherein the diluent
comprises a thermosetting binder and the diluent comprises
water.
40. The method of claim 33 wherein the second
stream further comprises a sizing agent.
41. The method of claim 33 wherein the second
stream further comprises a release agent.
42. The method of claim 33 wherein the third
stream further comprises a sizing agent.
43. The method of claim 33 wherein the third
stream further comprises a release agent.
44. The apparatus of claim 1 for producing
synthetic fire-retardant boards from a cellulosic material
including:
refining means for extracting fibers from a
cellulosic material;
conduit means connected to the refiner means for
conveying the fibers along the fiber flow path;
binder application means for mixing a binder and
a diluent to form a binder/diluent mixture and immediately
mixing the binder/diluent mixture with the fibers in the
fiber flow path;

- 28 -

dryer means for partially dewatering the
fiber/binder mixture;
forming means for creating a mat of the dewatered
fiber/binder mixture;
liquid fire-retardant application means for
introducing fire-retardant liquid onto the cellulosic
material located upstream of the forming means; and
heated pressing means for compressing the fibers
and curing the binder in the mat for forming a
consolidated fire-retardant board product.
45. The apparatus of claim 44 wherein the liquid
fire-retardant application means is located along the
fiber flow path.
46. The apparatus of claim 45 wherein the liquid
fire-retardant application means is located along the
fiber/binder mixture flow path.
47. The apparatus of any one of claims 44 to 46
wherein the liquid fire-retardant application means
includes a spray nozzle for introducing the liquid onto
the cellulosic material.
48. The method of claim 22 for producing
fire-retardant synthetic boards from a cellulosic material,
including the steps of:
extracting hot and wet fibers from a cellulosic
material;
transporting the hot and wet fibers in a first
stream;
transporting separate second and third streams
comprising a binder and a diluent, respectively, generally
toward the first stream;
merging the second and third streams to form a
fourth stream;
emulsifying the binder and the diluent in the
fourth stream;
immediately after emulsifying, applying the
binder/diluent emulsion in the fourth stream to the hot
and wet fibers in the first stream;
partially dewatering the hot and wet fibers;


- 29 -
introducing fire-retardant liquid onto the
cellulosic material;
forming the partially dewatered fibers into a
mat; and
compressing the mat in a heated press to cure the
binder to form a consolidated board product.
49. The method of claim 48 wherein the
fire-retardant liquid is introduced to the fibers in the
fiber flow path.
50. The method of claim 49 wherein the
fire-retardant liquid is introduced to the fiber/binder
mixture.
51. The method of claim 48 wherein the
fire-retardant liquid is introduced to the cellulosic
material by means of a spray nozzle.
52. The method of claim 48 wherein the
fire-retardant liquid comprises an aqueous solution of a
fire-retardant compound.
53. The method of claim 52 wherein the
fire-retardant liquid comprises an aqueous solution of
ammonium polyphosphate.
54. The method of claim 48 wherein the
fire-retardant liquid is added in the range of 7 - 15%
solid fire-retardant compound to oven dry weight of wood.
55. The method of claim 48 wherein the
fire-retardant liquid comprises an aqueous solution of
ammonium polyphosphate and the emulsified binder comprises
an emulsified isocyanate.
56. The method of claim 55 wherein the first
stream is a stream of wood fibers and the solution of
ammonium polyphosphate is added to the wood fiber stream
at a rate in the range of 7 - 15% by weight solid ammonium
polyphosphate to oven dry weight to wood.
57. The method of claim 56 wherein the ammonium
polyphosphate is added to the wood fiber stream at a rate
in the range of 7 - 10% by weight of solid ammonium
polyphosphate to oven dry weight of wood.

- 30 -

58. The method of claim 48 for producing a
fire-retardant water-resistant fiberboard product comprising
mixing a stream of hot and wet cellulosic fibers with (1)
an isocyanate binder emulsified with a diluent and (2) an
aqueous solution of ammonium polyphosphate, before forming
the mixture into a mat, then forming the mat into a board
through the application of heat and pressure.
59. The method of claim 58 wherein the weight of
solid ammonium polyphosphate in the mixture comprises 7-15%
of the oven dry weight of cellulosic fibers in the mixture.
60. A synthetic fire-retardant board product
made from a cellulosic material according to claim 48.
61. A synthetic fire-retardant board product
made from a cellulosic material according to claim 58.
62. A synthetic fire-retardant board product
made from a cellulosic material according to the method of
claim 48 including:
extracting hot and wet fibers from a cellulosic
material;
transporting the hot and wet fibers in a first stream;
transporting separate second and third streams
comprising a binder and a diluent, respectively, generally
toward the first stream;
merging the second and third streams to form a
fourth stream;
emulsifying the binder and the diluent in the
fourth stream;
immediately after emulsifying, applying the
binder/diluent emulsion in the fourth stream to the hot and
wet fibers in the first stream;
partially dewatering the hot and wet fibers;
introducing fire-retardant liquid onto the
cellulosic material;
forming the partially dewatered fibers into a
mat; and
compressing the mat in a heated press to cure the
binder to form a consolidated board product.

- 31 -

63. The product of claim 62 wherein the
fire-retardant liquid comprises an aqueous solution of a
fire-retardant compound.
64. The product of claim 63 wherein the
fire-retardant liquid comprises an aqueous solution of ammonium
polyphosphate.
65. The product of claim 62 wherein the
fire-retardant liquid is added in the range of 7 - 15% solid
fire-retardant compound to oven dry weight of wood.
66. The product of claim 62 wherein the
fire-retardant liquid comprises an aqueous solution of ammonium
polyphosphate and the emulsified binder comprises an
emulsified isocyanate.
67. The product of claim 66 wherein the first
stream is a stream of wood fibers and the solution of
ammonium polyphosphate is added to the wood fiber stream at
a rate in the range of 7 - 15% by weight solid ammonium
polyphosphate to oven dry weight to wood.
68. The product of claim 67 wherein the ammonium
polyphosphate is added to the wood fiber stream at a rate
in the range of 7 - 10% by weight of solid ammonium
polyphosphate to oven dry weight of wood.
69. A synthetic fire-retardant water-resistant
board product according to the method of claim 48 made by
mixing a stream of hot and wet cellulosic fibers with (1)
an isocyanate binder emulsified with a diluent and (2) an
aqueous solution of ammonium polyphosphate, before forming
the mixture into a mat, then forming the mat into a board
through the application of heat and pressure.
70. The product of claim 69 wherein the weight
of solid ammonium polyphosphate in the mixture comprises 7
- 15% of the oven dry weight of cellulosic fibers in the
mixture.
71. The method of claim 33 wherein a
fire-retardant liquid is introduced into one of the streams.
72. The method of claim 33 wherein a
fire-retardant liquid is introduced into the first stream.

- 32 -

73. The method of claim 33 wherein a
fire-retardant liquid is introduced into the fourth stream.
74. The method of claim 37 wherein a
fire-retardant liquid is introduced into one of the first and
fourth streams.
75. The method of claim 74 wherein the
fire-retardant liquid comprises an aqueous solution of ammonium
polyphosphate.

Description

Note: Descriptions are shown in the official language in which they were submitted.


CA 02026470 1997-06-20



APPARATUS AND METHOD OF MANUFACTURING
SY~,n~ C BOARDS INCLUDING FIRE-RET~ T BOARDS




The present invention relates to an apparatus and
method of manufacturing synthetic boards and
fire-retardant synthetic boards from cellulosic or
lignocellulosic furnish materials using an organic binder.
The present invention also relates to a fire-retardant
synthetic board product comprising cellulosic or
lignocellulosic furnish materials, an organic binder and
fire-retardant chemicals.
Background of the Invention
Many synthetic board products are manufactured
using a thermosetting binder, heat and pressure to
reconsolidate refined cellulosic and/or lignocellulosic
furnish materials into a unitary finished board product.
Examples of board manufacturing processes are shown in
U.S. Patent No. 2,757,115 to Heritage and U.S. Patent
No. 4,407,771 to Betzner et al. Basically, furnish
material, such as wood, is reduced to fibers of the

desired size by a refiner, mixed with a binder and other
chemicals, such as release and sizing agents, partially
dewatered, formed into mats and compressed between heated
platens in a hot press to form a board product of the



~,~

~2~




desired thickness and density. In many current processes,
the binder is applied to a rapidly moving stream of the
fibers of the fibers as it exits the refiner, in the
so-called "blowline" of the process equipment.
Alternatively, the binder may be added in the blender or
elsewhere downstream of the refiner.
A wide variety of binder systems have been
utilized in the production of synthetic boards, includiny
various thermosetting organic binders, such as
isocyanates, polyisocyanates, urea formaldehydes,
phenolics, melamines and various mixtures thereof.
Isocyanate and polyisocyanate binders have advantages over
urea formaldehyde binders in that boards with greatly
improved weather resistance can be produced. Processing
time can typically be substantially reduced using
isocyanate and polyisocyanate binders, rather than
standard phenolic binders. Although specially formulated
phenolic binders can decrease the processing time, the
cost of these ~pecialty binders makes their use less
attractive. Additionally, urea formaldehyde binders tend
to produce formaldehydes, and phenolic binders tend to
produce both formaldehydes and free phenols around the
press area, which can cause significant health problems.
Heretofore, successful application of isocyanate
binders in fiberboard manufacture has been limited due to
many factors. First, there is often difficulty in
achieving adequate distribution at low dosage rates.
Second, many systems require the use of an expensive




.

r~


release agent-containing binder or must utilize a caul
plate system which allows external release agent
application. These problems usually result in increased
production costs and/or inferior finished board product
quality.
Many of the binder systems used today in board
manufacture include an organic isocyanate binder which is
specially mixed with a variety of diluent/extender agents
to enhance binder distribution. These admixtures must
also have a relatively long pot life to avoid premature
curing, which can clog the binder delivery system.
Unfortunately, even quite stable admixtures tend to
deposit reaction products in process lines during use, and
especially when use is interrupted. Both problems usually
necessitate expensive machine downtime to unclog or
replace components of the binder delivery system.
In systems utilizing isocyanate binders, the
binder is typically formulated into an aqueous emulsion
long before application to the furnish. Since the binder
is highly reactive, the temperature during and after
emulsification must be kept relatively low to avoid
prereaction of the binder before it is applied to the
furnish materials. Water-cooled addition devices, such as
the nozzle described in U.S. Patent No. 4,402,896 to
Betzner et al., have been used, but require a constant
supply of cooling water and are still subject to clogging.
Another problem associated with specialty binders
and their mixing equipment is that if the binder is not


2~2~
~ 4


completely removed from the binder delivery system at the
end of a production run, the binder will usually cure and
clog the system. Therefore, there is a need for a binder
delivery system which assures that all of the binder is
removed therefrom to avoid these problems.
Additionally, release agents are often added to
the binder system to avoid sticking of the board to
platens or caul plates during processing. However, these
specially formulated binders are typically proprietary to
a particular manufacture and are prohibitively expensive
for large-scale fiberboard manufacturing operations.
Accordingly, there is a need for a process and apparatus
which can utilize basic nonproprietar~ isocyanate and
other binder compounds and release agents.
Summary of the Invention
It is, therefore, an object o~ the present
invention to provide a method of producing a synthetic
board from cellulosic or lignocellulosic materials wherein
standard, nonproprietary, inexpensive and readily
available isocyanate, polyisocyanate and similar binders
can be utilized, thus obviating the need for expensive
specialty chemical formulations.
It is also an object of the present invention to
provide an apparatus for producing a synthetic board
wherein standard binders and release agents can be
utilized.
It is a further object of the present invention
to provide a method and apparatus for forming a binder




. . .
'

,
, ~ ' - ' '

~2~7~


emulsion immediately upstream from the point of
application to the wood fibers, thus allowing the use of
isocyanates or polyisocyanates which do not form emulsions
having extended stabilities or pot life.
It is also an object of the present invention to
provide a method and apparatus for binder application
wherein the emulsion is cooled by the diluent.
It is an object of the present invention to
provide a method and apparatus for applying the binder
which would avoid periodic plugging of the process
equipment and the binder system.
It is also an object of the present invention to
provide a method and apparatus for flushing the binder
from the nozzle at the end of a production run so that the
binder does not cure within the nozzle and clog the same.
Another object of the invention is to provide a
method and apparatus as aforesaid which includes a new and
improved method and apparatus for producing a fi.berboard
that is fire-retardant.
Still another object of the invention is to
provide a method and apparatus as aforesaid which produces
a fire-retardant fiberboard having size, strength,
water-resistance and other characteristics comparable to
those of standard fiberboard.
Another object is to provide a method and
apparatus as aforesaid capable of producing an exterior
grade fiberboard that is fire-retardant.

2 ~ 7~


Another object is to provide a cellulosic or
lignocelluslosi.c Eiberboard product that is fire-retardant
and yet has size, strength, water-resistance and other
characteristics comparable to those of standard
fiberboard.
According to one aspect of the present invention,
there is provided an apparatus adapted for mixing a binder
stream and a diluent stream and applying the product
stream to the fibers in the production of synthetic boards
from cellulosic fibers, the apparatus comprising:
binder inlet means for receiving a first stream
containing a binder;
diluent inlet means for receiving a second steam
containing a diluent;
mixing means fluidly connected to the binder
inlet means and the diluent inlet means for mixing the
first stream and the second stream to produce a fourth
stream containing a product stream containing the binder
and the diluent; and
outlet means positioned proximate the mixing
means and fluidly connected to the mixing means for
immediately applying the product stream to the fibers.
According to another aspect of the present
invention, there is provided an apparatus for producing
synthetic boards from a cellulosic material, comprising:
refining means for extracting fibers from a
cellulosic material;




. ' .

r 7 ~

-- 7 --


conduit means connected to the refiner means for
conveying the fibers along the fiber flow path;
binder application means for mixing a binder and
a diluent to form a binder/diluent mi~ture and immediately
mixing the binder/diluent mixture with the fibers in the
fiber flow path;
dryer means for partially dewatering the
fiber/binder mixture;
forming means for creating a mat of the dewatered
fiber/binder mixture; and
heated pressing means for compressing the fibers
and curing the binder in the mat for forming a
consolidated board product.
According to yet another aspect of the present
invention, there is provided a method of blending a binder
with cellulosic fibers in the manufacture of synthetic
boards from cellulosic fibers, the method comprising:
conveying cellulosic fibers in a first stream;
conveying a binder in a second stream;
conveying a diluent in a third stream;
merging the second stream and the third stream to
produce a fourth stream; and
immediately thereafter merging the fourth stream
and the first stream to apply the binder and the diluent
to the fibers.
According to a further aspect of the present
invention, there is provided a method of producing


~2~ 7~
-- 8


synthetic boards from a cellulosic material, comprising

the ste s o~-
P
extracting hot and wet fibers from a cellulosic
material;
transporting the hot and wet fibers in a first
stream;
transporting separate second and third streams
comprising a binder and a diluent, respectively, generally
toward the first stream;
merging the second and third stream to form a
fourth stream;
emulsifying the binder and the diluent in the
fourth stream;
immediately after emulsifying, applying the
binder/diluent emulsion in the fourth stream to the hot
and wet fibers in the first stream;
partially dewatering the hot and wet fibers;
forming the partially dewatered fibers into a
mat; and
compressing the mat in a heated press to cure the
binder to form a consolidated board product.
The present invention further relates to an
apparatus and method for the production of fire-retardant
fiberboard. Such boards have traditionally been
manufactured by a post-production impregnation treatment
of the boards with a suitable fire-retardant chemical. In
order to achieve a board which conforms to the British

Standard Class 1 (as set out in BS476: Part 7: 1987) by


2 ~ 7 ,'~
_ 9 _


this method, it is necessary to vacuum/pressure impregnate
the boards. Fire-retardant boards produced by such
post-production treatments suffer from the disad~antage
that since the treatments are aqueous, thickness swell of
the boards of up to 10% is common. Furthermore,
substantial reduction in internal bond strength results
from these processes. Thus, the boards produced by
post-manufacturing treatments are of inferior ~uality, as
compared to an otherwise compa:rable, but nonfire-retardant
board.
U.S. Patent No. 3,874,990 to Surdyk discloses a
method for producing a flame retardant particle-board or
chip-board in which the flame ratardant chemicals are
added during production of the particle board, prior to
mat-forming, and comprise alkaline borate chemicals and
flame retardant phosphoric acid-dicyandiamide-formaldehyde
resin. The alkaline borate chemicals are added to the
wood chips as a dry powder. Such a method does not lend
itself to applications in the field of fiberboard
production as it wou].d be extremely difficult to achieve a
good dispersion of a powder with the fine fiber used.
Therefore, there is a need for an apparatus and method for
producing a fire-retardant fiberboard in which the
fire-retardant compound is incorporated into the board
during its production and the product board has the
desirable physical characteristics of standard fiberboard,
as well as excellent fire-retardant characteristics.


-- 10 --

According to a further aspect, there is provided
an apparatus for producing synthetic fire-retardant boards
from a cellulosic material comprising:
refining means for extracting fibers from a
cellulosic material;
conduit means connected to the refiner means for
conveying the fibers along the fiber flow path;
binder application means for mixing a binder and
a diluent to form a binder/diluent mixture and immediately
mixing the binder/diluent mixture with the fibers in the
fiber flow path;
dryer means for partially dewatering the
fiber/binder mixture;
forming means for creating a mat of the dewatered
fiber/binder mixture;
liquid fire-retardant application means for
introducing fire-retardant liquid onto the cellulosic
material located upstream of the forming means; and
heated pressing means for compressing the fibers
and curing the binder in the mat for forming a
consolidated fire-retardant board product.
According to yet a further aspect, there is
provided a method of producing fire-retardant synthetic
boards from a cellulosic material, comprising the steps
of:
extracting hot and wet fibers from a cellulosic
material;


- 11 - 2~ '3

transporting the hot and wet fibers in a first
stream;
transporting separa-te second and third streams
comprising a binder and a diluent, respectively, generally
toward the first stream;
merging the second and third streams to form a
fourth stream;
emulsifying the binde:r and the diluent in the
fourth stream;
immediately after emulsifying, applying the
binder/diluent emulsion in the fourth stream to the hot
and wet fibers in the first stream;
partially dewatering the hot and wet fibers;
introducing fire-retardant liquid onto the
cellulosic material;
forming the partially dewatered fibers into a
mat; and
compressing the mat in a heated press -to cure the
binder to form a consolidated board product.
The present invention is a method and apparatus
for producing a synthetic board from cellulosic or
lignocellulosic fibers, preferably wood fibers, wherein a
standard thermosetting binder, preferably an isocyanate or
polyisocyanate binder, is emulsified and immediately
applied to the fibers before consolidation of the fibers
into a mat or finished board product. The apparatus
includes a binder emulsification and application nozzle
comprising a diluent inlet, a binder inlet, a mixing


- 12 -


section for emulsifying the diluent and the binder, and a
spray nozzle ~or applying the binder/diluent emulsion to
the fibers in a fiber stream upstream of the forming mat
in the board forming process. The method includes
supplying a binder stream, supplying a diluent stream,
merging the two streams, emulsifying the binder with the
diluent and immediately thereaEter applying the emulsion
to the fiber stream. The method further includes flushing
the nozzle with the diluent stream at the end of a
production run to remove the binder from the nozzle to
prevent curing of the binder emulsion and clogging of the
nozzle. In the apparatus of the present invention, the
nozzle can be used to apply the emulsi~ied binder to the
fiber stream either in the refiner, the blowline or
downstream of the blowline, such as in the blender, of the
board forming apparatus.
The method may also include introducing a
fire-retardant liquid into the fiber stream as part of the
board forming process. The apparatus may also include
means for applying a fire-retardant liquid to the fiber
stream.
Description of Drawinqs
The invention will now be described more
particularly with reference to the accompanying drawings.
In the drawings:
FIG. 1 is a schematic diagram showing the process
and apparatus in accordance with the present invention.


r~ ~3
- 13 -


FIG. 2 is a side view of a nozzle in accordance
with the present invention mounted on a blowline of a
fiberboard manufacturing process.
FIG. 3 is a schematic view of the nozzle in
accordance with the present invention.
FIG. 4 is a schematic drawing showing the
positions of entry of binder, diluent, and other agents to
the fiber flow path.



DETAILED DESCRIPTION OF PREFERRED EMBODI~ENTS

Embodiments Producinq Boards Having
Optimum Water Resistance

The present invention is intended for use in the
production of reconstituted products made from cellulosic
or lignocellulosic materials, and in particular, the
production of fiberboard from wood fibers. The invention
is also intended for use in the production of fiberboard
having ~ire-retardant characteristics.
As shown in FIG. 1, pieces of wood, such as
chips, are fed into a plug feeder 10 for delivery to a
digester 12, where they are subjected to steam and high
pressure to soften the chips and break down the lignin
therein. The cooked chips are transferred to a refiner 14
where they are separated into their constituent fibers,
such as between uni- or bi-directional rotating discs.
The hot and wet fibers exit refiner 14 with steam
in a rapidly moving continuous stream which is transported
through a so-called "blowline" 16, where the binder and
other desired compounds, such as rel~ase and sizing
agents, are typically added. The binder is preferably a
material selected from the group consisting of monomeric
isocyanates, oligomeric isocyanates t and mixtures thereof
having a functionality of at least 2. In addition, other
conventional thermosetting binders may be used.




'
'

2~2~47~

Aqueous emulsions of the, binder and other
additives are well-suited to blowline injection for
several reasons. First, a large portion of the heat
energy available in the blowline is absorbed in raising
the temperature of the applied emulsions since the
specific heat of water is higher than many of the other
substances being added. Second, the water-to-water
solvent compatibility between the wood fibers and the
additive emulsion is excellent and helps assure good flow
and distribution of the binder. Third, deposits of the
additive emulsion on the wall of the blowline are
minimized due to the presence of a continuous ~ilm of
water condensate, with which the additive emulsions are
also compatible. Fourth, the great turbulence within the
blowline results in a scouring action which tends to keep
the blowline wall clean, providing those adhering
substances are also water compatible. Lastly, the
residence time in the blowline is so short that most
chemical reactions, such as curing of the binder, have
insufficient time and energy to move very far toward
reaction products.
A binder emulsion and application nozzle assembly
18 in accordance with the present invention is connected
to blowline 16 for emulsifying the isocyanate binder with
a diluent and applying the resulting emulsion to the
fibers as they pass through blowline 16. Conventional
nozzles 20 and 22 are also plumbed to blowline 16 for
applying release and sizing agents to the fibers.
Alternatively, the isocyanate binder, release agent and
siziny agents may be added at other locations in the
process, as will be described below.
Upon entering blowline 16, the steam and the
fibers undergo a rapid drop in pressure and temperature,
but travel therethrough in less than about 1 second. The
velocity of the fibers through a typical blowline has been
reported to be approximately 325 feet per second. There
is extreme turbulence in blowline 16, which provides




' ' '

~2~7~
- 15 -

excellent mixing of additives, such as the binder, with
the fibers.
After exiting blowline 16, the fibers enter a
dryer 24 where they are partially dewatered. A first
cyclone 26 and an air lock 28 are provided to separate the
fiber from the dryer airstream. The fibers next pass to a
blender 30 wherein the isocyanate binder, siziny, release
agents or other desired materials can be mixed with the
fibers, if desired. If all desired compounds have already
been added, the fibers can be directed through a bypass
chute 32 and go directly to a second cyclone 34 with an
air lock 36 and then into a fiber storage bin 38. ~iber
storage bin 38 provides fibers to one or more forming head
apparatuses 40 which are used to dispense a forming mat of
15 fibers 41 onto a forming belt 42. Forming mat 41 is
deaerated by one or more prepressees 44 and then
compressed to the final pressed thickness by a hot
press 46 wherein the binder is cured to form the desired
board product.
In general, the binder can be added to the fibers
in any suitable location in the board forming apparakus
upstream of forming mat 41. Alternative locations where
the binder can be added to the fibers are designated by
dashed arrows 17a-d in FIG. 1. For example, the binder
may be added using the nozzle assembly of the present
invention in any of the following locations: refiner 14;
blender 30; bypass chute 32 or forming head
apparatuses 40. Similarly, the sizing and release agents
can be added, separately or together, in the various
locations in the board forming apparatuses, including:
plug feeder 10, digester 12, refiner 14, blowline 16,
blender 30 or bypass chute 32.
Referring to FIGS. 2 and 3, nozzle assembly 13
comprises a diluent inlet 52, a binder inlet 54, a mix
section 56 for emulsifying diluent and binder and a spray
nozzle 58 adapted for connection to a blowline 16 for
spraying the emulsion on the fibers. A stream of water or
other diluent is introduced through diluent inlet 52, and

2 ~ 7 ~
- 16 -

a stream of a binder, which can be isocyanate,
polyisocyanate or other suitable thermosetting binder, is
introduced through binder inlet 54.
Diluent inlet 52 includes a coupling 62, such as
a quick disconnect coupling shown, for connection to a
diluent supply line 64 with an appropriate coupling 66
through which water or other suitable diluent is delivered
to nozzle assembly 18. A pressure relief check valve 68
for diluent inlet 52 is operated by a control spring 70
and is threadedly connected to coupling 62. Diluent check
valve 68 prevents backflow from mix section 56 into
diluent supply line 64. In addition, diluent check
valve 68 will only open to allow diluent into mix
section 56 when the pressure of the water stream is above
a certain minimum pressure, for example, 15 psi. This
assures that there will be no admixing of water and binder
until the water stream has achieved proper operating
pressure, such as by the use of an appropriate metering
pump (not shown). It also assures that the flow of
diluent into nozzle assembly 18 will stop ;mr~-~;ately upon
stopping the flow of the diluent stream or upon a drop in
the pressure of the stream. Suitabls check valves are
available from the NuPro Company of Willoughby, Ohio.
Although alternative diluents, such as propylene
carbonate or furfural, can be used under various
conditions, water has long been used to reduce the
viscosity of binders and thus improve distribution. The
water also serves as a thermal buffer of the binder. This
is particularly significant for those applications
utilizing blowline addition of isocyanates. Since there
is a constant flow of relatively cool (less than ambient
temperature) diluent water through nozzle assembly 18, the
temperature to which the binder is subjected during
emulsification is also less than ambient, which prevents
precuring. No additional cooling of the emulsion, such as
provided by a cooling water jacket, is required.
Binder inlet 54 similarly includes a coupling 72
for connection to a bindsr supply line 74 with a




., : ' ~ ' .


.

- 17 -

coupling 76 through which binder is de:Livered to nozz]e
assembly 18. In the preferred embodiment, the binder is
standard technical grade isocyanate or polyisocyanate. A
pressure relief check valve 78 for binder inlet 54
includes a control spring 80 and is threadedly connected
to coupling 72. Binder check valve 78 operates as above
to prevent backflow from mix section 56 into binder supply
line 74. Binder check valve 78 also prevents the admixing
of water and binder before the binder stream has achieved
its proper operating pressure, or if the flow of the
binder stream has been stopped or if the pressure of the
binder stream drops below a proper operating pressure.
Additional compounds, such as release agents,
sizing agents, etc., may be applied to the fibers, if
desired. Referring to FIG. 4, release agents and sizing
agents may be added, separately or together, to diluent
stream 81a, binder stream 81b, combined binder/diluent
stream 81c or directly to fiber stream 81d, as shown by
dashed lines 82a - 82d, respectively. If the additional
compounds are to be added to combined binder/diluent
stream 81c, a third inlet 83 (shown by dashed lines in
FIG. 2) can be plumbed to mix section 56 of nozzle
assembly 18 for introducing such compounds into mix
section 56. In this way, the additional compounds will be
merged with the binder/diluent immediately before
application to the fibers.
Mix section 56 includes an intersection tee 84
which is threadedly attached to the outlets of diluent
check valve 68 and hinder check valve 78 for receiving the
binder stream and the ~iluent stream. Tee 84 is also
threadedly connected to an in-line mix section 85 equipped
with a plurality of interior baffles 86 which cause mixing
and emulsion of the binder with the diluent. The exact
number and configuration of baffles 86 has not been found
to be critical, as long as sufficient mixing results.
plastic baffled-style motionless mixer insert sized for
insertion into in-line mix section 85 and sold by TAH

- 18 -

Industries of Imalyston, New Jersey, under the name
Kinetic Mixer, has been found to give good results.
Spray nozzle 58 is threadedly attached to in-line
mix section 85 for applying the diluent/binder emulsion to
the fibers passing through blowline 16. Spray nozzle 58
is provided with external threads 90 for attachment to
mating internal threads 92 in wall 94 of blowline 16.
Spray nozzle 58 is mounted so that only a small tip
portion 96 of the nozzle 90 extends into blowline 16 and
is subjected to the abrasive atmosphere therein. Due to
the abrasive atmosphere of blowline 16 and to avoid any
possible interaction with the emulsion, it has been
determined that spray nozzle 58 should be constructed out
of stainless steel or other suitable material.
It has also been determined that a spray nozzle
obtained from Spraying Systems Company of Wheaton,
Illinois, and sold under the trademark FULLJET gives good
results. This nozzle tip includes an integral interior
spiral vane mixer which produces a full cone spray pattern
for good distribution of the emulsion on the fibers. It
has also been determined that a nozzle I.D. of 0.245
inches is preferred to maintain proper backpressure in
nozzle assembly 18. Nozzle assembly 18 is typically
operated at an emulsion flow rate of approximately
5 gallons per minute and a pressure of between 80 and
125 psi, although some applications may require other
application rates and parameters.
In a working embodiment, blowline 16 has an
interior diameter of about 6 inches. Thus, the distance
between the point of emulsification of the binder and the
point of application to the fibers in blowline 16 is very
small, approximately 4 inches. This relatively short
distances helps assure that tha binder emulsion does not
cure before application to the fibers.
In accordance with the present invention, a
method of and means for flushing binder and emulsion out
of nozzle assembly 18 is also provided. This flushing is
necessary to avoid leaving the emulsion in mix section 56

2 ~

-- 19 --

or spray nozzle 58 where it could quickly cure and plug
nozzle assembly 18. To flush nozzle assembly 18 at the
end of a production run, the binder pump should be turned
off to stop the flow of binder. This causes binder check
valve 78 to close. The water stream is allowed to
continue to flow for a few seconds (3-5 seconds) to flush
out any residual emulsion. Pr,eferably, the binder stream
should be shut off before fiber stream flow past spray
nozzle 58 has ended to avoid buildup of binder in
blowline 16.
Application of the aqueous emulsions o~ standard
isocyanate and polyisocyanate through nozzle assembly 18
into blowline 16 results in a practical and economical
means of producing a superior fiberboard product,
especially a medium density, water-resistant fiberboard
suitable for exterior use. The ready availability of the
binders are of great significance to a commercial
fiberboard production facility.
Embodiments Producinq Boards Havinq
OPtimum Fire Retardance
Fire-retardant fiberboard is advantageously
produced by the above-described method and apparatus, with
the introduction of an additional step whereby a
fire-retardant chemical in aqueous solution is added to
the wood or other cellulosic or lignocellulosic material.
Ammonium polyphosphate has been found to be a suitable
compound for this purpose when used with an isocyanate
binder. Ammonium polyphosphate is known as a
fire-retardant for the treatment by spraying, dipping,
etc. of fabrics. However, it has not, to Applicants'
knowledge, been used successfully as a fire-retardant in
fiberboard. Attempts have been made by the Applicants to
produce a fire-retardant fiberboard using urea
formaldehyde as the binder system, together with ammonium
polyphosphate as the fire-retardant compound. The product
was found to have poor internal bonding, probably due to
chemical reaction between the binder and fire-retardant,
resulting in inferior fire-retardancy, water resistance,

~2~f~
- 20 -

strength and other characteristics. Applicants have now
found, surprisingly, that use of the same fire-retardant
chemical with an isocyanate binder system gives a product
board having superior physical characteristics and with
water resistance and strength similar to comparable
nonfire-retardant boards. It has been found that the
fire-retardant compound may be added in the range of
7 - 15% solid ammonium polyphosphate to oven dry weight of
wood where an isocyanate is used as the binder. Addition
of higher amounts of the fire-retardant compound, when
used with an isocyanate binder, has been found to result
in a finished fiberboard whose tensile strength is
unacceptably lowered. The preferred range is 7 - 10%
solid ammonium polyphosphate to oven dry weight of wood.
The fire-retardant chemical may be added to the
wood chips or fibers at any suitable location in the board
forming apparatus upstream of forming mat 41 (FIG. 1).
Suitable points are: plug feeder 10; digester 12;
refiner 14, blowline 16 or blender 30. Introduction of
the chemical is via a standard spray nozzle, for example,
a 1 inch FULLJET (trademark) nozzle. The fire-retardant
liquid may be added to the fiber stream either before or
after addition of the isocyanate binder emulsion to the
fiber stream. If desired, one of auxiliary nozzles 20, 22
may be used for this purpose. Alternatively, a stream of
the fire-retardant liquid may be merged with the stream of
emulsified isocyanate binder in nozzle assembly 18, for
example, by using inlet 83 to nozzle mix section 85. The
fire-retardant liquid may also be added to either the
diluent in inlet passage 64 or the binder in inlet
passage 74 to the nozzle assembly 18.
The fire-retardant fiberboard meets the same
technical specifications, including size, strength,
density and water-resistance characteristics, as the
nonfire-retardant fiberboard produced by the method and
apparatus according to the invention. With respect to its
fire-retardant properties, the fire-retardant fiberboard
described herein is certified to Class 1 surface spread of

~2~7~
- 21 -

flame in accordance with the class definitions given in
British Skandard 476: Part 7: 1987. The test assesses
ignition characteristics and the extent to which the
product surface spreads flames laterally. Materials are
classified according to performance as Classes 1 to 4 in
descending order of performance. The fire-retardant
fiberboard is suitable for use, but is not limited to use,
in any of the following applications: ceilings, wall
linings, partitioning in build:ing and shopfitting, display
panels for the shopfitting and exhibitions industry,
shipbuilding applications, general purpose building panels
where greater fire integrity is specified or required
whilst still retaining a surface suitable for finishing.
Although preferred embodiments of the present
invention have been shown, it is obvious that many
modifications and variations of the present invention are
possible in the light of the above teachings. It is,
therefore, to be understood that the present invention
may be practiced otherwise than as specifically described.

Representative Drawing
A single figure which represents the drawing illustrating the invention.
Administrative Status

For a clearer understanding of the status of the application/patent presented on this page, the site Disclaimer , as well as the definitions for Patent , Administrative Status , Maintenance Fee  and Payment History  should be consulted.

Administrative Status

Title Date
Forecasted Issue Date 1998-12-01
(22) Filed 1990-09-28
(41) Open to Public Inspection 1991-09-15
Examination Requested 1993-11-19
(45) Issued 1998-12-01
Expired 2010-09-28

Abandonment History

There is no abandonment history.

Payment History

Fee Type Anniversary Year Due Date Amount Paid Paid Date
Application Fee $0.00 1990-09-28
Maintenance Fee - Application - New Act 2 1992-09-28 $100.00 1992-08-28
Registration of a document - section 124 $0.00 1993-04-08
Registration of a document - section 124 $0.00 1993-04-08
Maintenance Fee - Application - New Act 3 1993-09-28 $100.00 1993-08-20
Request for Examination $400.00 1993-11-19
Maintenance Fee - Application - New Act 4 1994-09-28 $100.00 1994-08-12
Registration of a document - section 124 $0.00 1994-12-30
Maintenance Fee - Application - New Act 5 1995-09-28 $150.00 1995-08-23
Maintenance Fee - Application - New Act 6 1996-09-30 $150.00 1996-08-30
Maintenance Fee - Application - New Act 7 1997-09-29 $150.00 1997-08-27
Registration of a document - section 124 $50.00 1998-06-05
Final Fee $300.00 1998-06-17
Maintenance Fee - Application - New Act 8 1998-09-28 $150.00 1998-08-26
Maintenance Fee - Patent - New Act 9 1999-09-28 $350.00 2000-05-19
Maintenance Fee - Patent - New Act 10 2000-09-28 $200.00 2000-05-19
Maintenance Fee - Patent - New Act 11 2001-09-28 $200.00 2001-08-27
Maintenance Fee - Patent - New Act 12 2002-09-30 $200.00 2002-08-16
Maintenance Fee - Patent - New Act 13 2003-09-29 $200.00 2003-09-15
Maintenance Fee - Patent - New Act 14 2004-09-28 $250.00 2004-08-09
Maintenance Fee - Patent - New Act 15 2005-09-28 $450.00 2005-08-08
Registration of a document - section 124 $100.00 2006-03-07
Maintenance Fee - Patent - New Act 16 2006-09-28 $450.00 2006-08-08
Maintenance Fee - Patent - New Act 17 2007-09-28 $450.00 2007-08-06
Maintenance Fee - Patent - New Act 18 2008-09-29 $450.00 2008-08-11
Maintenance Fee - Patent - New Act 19 2009-09-28 $450.00 2009-08-07
Registration of a document - section 124 $100.00 2009-11-17
Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
WEYERHAEUSER NR COMPANY
Past Owners on Record
BAUER, TED J.
HARMON, DAVID M.
KIRWAN, RORY GERARD
MEDITE CORPORATION
MEDITE OF EUROPE LIMITED
TRELIVING, GORDON
WEYERHAEUSER COMPANY
WILLAMETTE INDUSTRIES, INC.
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Representative Drawing 1998-11-18 1 7
Description 1997-06-20 21 866
Cover Page 1993-12-11 1 18
Abstract 1993-12-11 1 39
Claims 1993-12-11 11 436
Drawings 1993-12-11 2 41
Description 1993-12-11 21 872
Claims 1997-06-20 11 434
Cover Page 1998-11-18 2 83
Assignment 1990-09-28 29 1,319
Assignment 1998-06-05 3 100
Correspondence 1998-06-17 1 52
Prosecution-Amendment 1993-11-19 5 191
Prosecution-Amendment 1996-12-20 2 74
Prosecution-Amendment 1997-06-20 11 395
Assignment 2009-11-17 13 584
Assignment 2006-03-07 5 218
Fees 1996-08-30 1 47
Fees 1995-08-23 1 43
Fees 1994-08-12 1 50
Fees 1993-08-20 1 37
Fees 1992-08-28 1 36