Note: Descriptions are shown in the official language in which they were submitted.
2035~6~
- 1 -
Supertwist liquid crystal display
The invention relates to supertwist liquid
crystal displays (SLD) having very short switching times
and good steepness and angle dependence, and also to the
novel nematic liquid crystal mixtures used therein.
SLD according to the preamble are known, for
example from EP 0,131,216 B1; DE 3,423,993 A1; EP
0,098,070 A2; M. Schadt and F. Leenhouts, 17th Freiburger
Arbeitstagung Fliissigkristalle (Freiburg Working Meeting
on Liquid Crystals] (8.-10.04.87); K. Kawasaki et al.,
SID 87 Digest 391 (20.6); M. Schadt and F. Leenhouts,
SID
87 Digest 372 (20.1); R. Katoh et al., Japanese Journal
of Applied Physics, volume 26, No. 11, L 1784-L 1786
(1987); F. Leenhouts et al., Appl. Phys. Lett. 50 (21),
1468 (1987); H.A. van Sprang and H.G. Koopman, J. Appl.
Phys. 62 (5), 1734 (1987); T.J. Scheffer and J. Nehring,
Appl. Phys. Lett. 45 (10), 1021 (1984), M. Schadt and
F.
Leenhouts, Appl. Phys. Lett. 50 (5), 236 (1987) and E.P.
Raynes, Mol. Cryst. Liq. Cryst. Letters volume 4 (1),
pages 1-8 (1986). The term SLD here comprises any more
highly twisted display element with an amount of twist
angle between 100 and 600, such as, for example, the
display elements according to Waters et al. (C. M. Waters
( et al., Proc. Soc. Inf. Disp. (New York) (1985) (3rd
Intern. Display Conference, Robe, Japan), the STN-LCD
(German Offenlegungsschrift 3,503,259), SBE-LCD
(T.J. Scheffer and J. Nehring, Appl. Phys. Lett. 45
(1984) 1021), OMI-LCD (M. Schadt and F. Leenhouts, Appl.
Phys. Lett. 50 (1987), 236, DST-LCD (European Published
Application 0,246,842) or BW-STN-LCD (R. Kawasaki et al.,
SID 87 Digest 391 (20.6)).
' Compared with standard twisted nematic displays,
SLD of this type are distinguished by substantially
better steepness of the electro-optical characteristic
and thus associated better contrast values and by a
substantially smaller angle dependence of the contrast.
SLD with very short switching times are here of par-
2U3~8fi?
- 2 -
ticular interest, especially also at relatively low
temperatures. To achieve short switching times, the
viscosities of the liquid crystal mixtures have hitherto
been optimized with the use of, in most cases, monotropic
additives having a relatively high vapour pressure.
However, the switching times achieved were not adequate
for some applications.
To achieve a steep electro-optical characteris
tic, the liquid crystal mixtures should have relatively
high wide (sic) values for K3/K1 and relatively small
values for oE/E1.
Beyond the optimization of the contrast and
switching times, mixtures of this type have to meet
further important demands:
1. a wide d/p window
2. a high chemical fatigue stability
3. a high electrical resistance
4. a low frequency dependence of the threshold voltage.
The parameter combinations achieved are not yet
nearly sufficient, in particular for high-multiplex STN
(1/400). In part, this is to be ascribed to the fact that
the various demands are affected in opposite directions
by material parameters.
There is thus still a great demand for SLD which
have very short switching times coupled with, at the same
n time, a wide range of working temperatures, high steep
ness of the characteristic, good angle dependence of the
contrast and low threshold voltage and which meet the
demands given above.
The invention is based on the object of providing
SLD which show the above-indicated disadvantages only to
a smaller extent or not at all and, at the same time,
have very short switching times.
It has now been found that this object can be
achieved if the nematic liquid crystal mixture
a) is based on component A containing one or more
compounds seleted from group A comprising compounds
of the formulae IIa to IIk~c
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3
R A~ As X B
R A~ CH~C~ A= X
R ~ v Az A~ ;~ ~Ic
R Al Az ~t A~ X
R ~ CFi CHZ Ai C~z A~ X
R A1 CH~fiz A= A3 X
R A~ C=C AI X
R A~ C-C A
R Ai A= C = C A3 X
R al ~~h A= C=C A3 X
R A~ C = C ~ y A~ X
in which R is n-alkyl or n-alkenyl having up to 9 C m oms,
1' Y is cyano, -NCS, F, C1, -CF3, -CHF2, -OCF3, -OCHFz,
-OCFzCF~H or -OC~F;, and the rings Al, A2 and A3 each
independently of one another are 1,4-phenylene~2- or 3-fluoro-
1,4-phenylene or tra-a-1,4-cyclohexylene, or one of the rings
Al, A~ and A3 can also be 1,4-cyclohexenylene, 2,3-difluoro-1,4-
20 phenylene, pyridine-2,5-diyl or pyrimidine-2,5-diyl,
(b) contains 0-40~ by weight of a liquid-crystalline component
B, consisting of one or more compounds having a dielectric
anisotropy of -1.S to *1.5, of the general formula I
CA 02035862 2000-09-29
CA 02035862 2002-07-30
26474-221
4
R1 A1 Z1- ~ - A2 ZZ-~-m A3 R2 I
in which Rl and Rz each independently of one another
are n-alkyl, n-alkoxy, n-oxaalkyl, w-fluoroalkyl or n-alkenyl
having up to 9 C atoms, the rings Al, A2 and A3 each
independently of one another are 1,4-phenylene, 2- or 3-fluoro-
1,4-phenylene, trans-1,4-cyclohexylene or 1,4-cyclohexenylene,
Z1 and Z2 each independently of one another are
-CHZCH2-, -C--_C- or a single bond, and m is 0, 1 or 2,
c) contains 0 to 20% by weight of a liquid-
crystalline component C consisting of one or more compounds
having a dielectric anistropy below -1.5, and
d) contains an optically active component D in such a
quantity that the ratio of cell thickness (spacing of the
plane-parallel carrier plates) to the natural pitch of the
chiral nematic liquid crystal mixture is approximately 0.2 to
1.7 and in particular approximately 0.2 to 1.3,
the nematic liquid crystal mixture has a nematic
phase range of at least 60°C, a viscosity of not more than 35
mPa.s and a dielectric anisotropy of at least +1, the
dielectric anisotropies of the compounds and the parameters
relating to the nematic liquid crystal mixture referring to a
temperature of 20°C.
According to one aspect of the present invention,
there is provided supertwist liquid crystal display with two
plane-parallel carrier plates which, with a frame, form a cell,
a nematic liquid crystal mixture, located in the
cell, having a positive dielecric anisotropy,
CA 02035862 2002-07-30
264?4-221
4a
a tilt angle of about 1 degree to 30 degrees between
the longitudinal axis of the molecules at the surface of the
on the insides of the carrier plates,
carrier plates and the carrier plates, and
a twist angle of the liquid crystal mixture in the
cell from orientation layer to orientation layer of an amount
between 100 and 600°,
IIk:
component A containing one or more compounds selected
from group A consisting of compounds of the formulae IIa to
electrode layers with superposed orientation layers
wherein the nematic liquid crystal mixture comprises:
R A1 Az X IIa
R A1 CHZCH2 AZ X Iib
R A1 A2 A3 X IIc
R A1 AZ CH2CHz A3 X IId
R AZ CH2CH2 AZ CHZCH2 A3 X IIe
R A1 CH2CH2 A2 A3 X IIf
R A1 C=C A2 X IIg
CA 02035862 2002-07-30
26474-221
4b
R A1 C=C A2 A3 X zIh
R A1 AZ C=C A3 X IIi
R A1 CH2CH2 AZ C=C A3 X IIj
R A1 C=C AZ CHZCHZ A3 X zIk
in which R is n-alkyl or n-alkenyl having up to 9 C atoms,
X is F, C1, -CF3, -CHFz, -OCF3, or -OCHF2, and the
rings Al, A2 and A3 each independently of one another are
1,4-phenylene, 2- or 3-fluoro-1,4-phenylene or traps-1,4-
cyclohexylene, or one of the rings Al, A2 and A3 is
1,4-cyclohexenylene, 2,3-difluoro-1,4-phenylene, pyridine-2,5-
diyl or pyrimidine-2,5-diyl, and
an optically active component D in such a quantity
that the ratio of cell thickness (spacing of the plane-parallel
carrier plates) to the natural pitch of the chiral nematic
liquid crystal mixture is about 0.2 to 1.3,
wherein the nematic liquid crystal mixture has a
nematic phase range of at least 60°C, a viscosity of not more
than 35 mPa.s and a dielectric anisotropy of at least +1, the
dielectric anisotropies of the compounds and the parameters
relating to the nematic liquid crystal mixture referring to a
temperature of 20°C.
The invention thus relates to an SLD with
CA 02035862 2002-07-30
26474-221
4c
two plane-parallel carrier plates which, with a
frame, form a cell,
a nematic liquid crystal mixture, located in the
cell, having a positive dielectric anisotropy,
electrode layers with superposed orientation layers
on the insides of the carrier plates,
a tilt angle of about 1 degree to 30 degrees between
the longitudinal axis of the molecules at the
203586?
-5-
surface of the carrier plates and the carrier
plates, and
a twist angle of the liquid crystal mixture in the
cell from orientation layer to orientation layer of
an absolute valve between 100 and 600°, charac
terized in that the nematic liquid crystal mixture
a) is based on component A containing one or more
compounds selected from croup A comprising compounds
of the formulae IIa to IIk:
R-~ A1 A2 -X IIa
R- Al\~ CH2 CH2 -~ -X I I
- b
R- ~ - A2'\ - ~ -X I I
c
R- A1 ~-CH2CH2- A3 -X IId
-
R- A2~- CH2CH2-~ -CH2CH2- A3\ -X IIe
R- Al CH2CH2- A2 - A3 -X IIf
-
R1 - A1 -C=C- A -X IIg
R1 - A1 -C=C- A2 A -X IIh
I.
R1 - A1 - A2 -C--__C- A'3 -X IIi
Rl - A1 -CH2CH2- A2 -C=C- A3 -X IIj
R1 - A1 -C-C- A2 -CH2CH2- A3 -X IIk
~ in which R is n-alkyl or n-alkenyl having up to 9
C atoms,
X is cyano, -NCS, F, C1, -CF3, -CHF2,
-OCF3, -OCHF2, -OCF2CFZH or -OCZFS, and
the rings Al, A2 .and A3 each independently
of one another are 1,4-phenylene, 2- or
203586?
- 6 -
3-fluoro-1,4-phenylene or traps-1,4
cyclohexylene, or one of the rings A1, A2
and A3 can also be 1,4-cyclohexenylene,
2,3-difluoro-1,4-phenylene, pyridine-2,5
diyl or pyrimidine-2,5-diyl,
b) contains 0-40~ by weight of a liquid-crystalline
component B, consisting of one or more compounds
having a dielectric anisotropy from -1.5 to +1.5, of
the general formula I
R1- .~-Z1_f-<~,~ -Z2-~m-~~ -R2 I
in which Rl and R2 each independently of one another
are n-alkyl, n-alkoxy, n-oxaalkyl,
w-fluoroalkyl or n-alkenyl having up to 9
C atoms , the rings Al, AZ and A3 each
independently of one another are
1,4-phenylene, 2- or 3-fluoro-1,4-pheny-
lene, traps-1,4-cyclohexylene or 1,4-
cyclohexenylene,
Z1 and ZZ each independently of one another
are -CHZCH2-, -C~C- or a single bond, and
m is 0, 1 or 2,
c) contains 0-20% by weight of a liquid-crystalline
component C consisting of one or more compounds
f having a dielectric anisotropy below -1.5, and
d) contains an optically active component D in such a
quantity that the ratio of cell thickness (spacing
of the plane-parallel carrier plates) to the natural
pitch of the chiral nematic liquid crystal mixture
is about 0.2 to 1.7, and in particular 0.2 to 1.3,
and
in that the nematic liquid crystal mixture has a
nematic phase range of at least 60C, a viscosity of
not more than 35 mPa.s and a dielectric anisotropy
of at least +1, the dielectric anisotropies of the
compounds and the parameters relating to the nematic
liquid crystal mixture referring to a temperature
of 20C.
CA 02035862 2002-07-30
26474-221
7
The invention also relates to corresponding liquid
crystal mixtures for use in SLD.
The individual compounds of, for example, the
formulae I and IIa to TIk or also other compounds which can be
used in the SLD according to the invention are either known or
can be prepared analogously to the known compounds.
Preferred liquid crystal mixtures contain
a) at least one component selected from group B4 comprising
compounds of the formulae AI to AVI:
R1 0 CH2CH2 0 R2 AI
R1 0 CHZCH2 RZ All
R1 CHZCHZ 0 RZ AIII
R1 CHZCHZ 0 Rz AIV
R1 0 RZ AV
2o Ri 0 Rz
AVI
in which R1 and R2 each independently of one another
are R and
CA 02035862 2002-07-30
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7a
R is alkyl having 1-12 C atoms, and in which one or
two non-adjacent CH2 groups can also be replaced by -O-,
-CH-CH-, -CO-, -O-CO- or -CO-0-, and wherein the thick dot
indicates that the cyclohexane ring is tran-substituted at that
spot. This is a conventional form of notation and the notation
is used herein consistently with this meaning,
b) and/or at least one component selected from group B1
comprising the compounds of the formulae BI to BIV:
0
R1 ~---Z Z RZ B I
0
0
R1 ZZ ~-R2 BII
0
R1 ZZ RZ BI II
R1 g R2 BIV
203586
_8_
in which R1 and RZ each independently of one another
have the meaning given for R,
ZZ is -CHZCHZ-, -CO-O-, -0-CO- or a single bond, and
is- B ~,_ ~_, _ ~~~._or ~_
and/or at least one component selected from group B2
comprising the compounds of the formulae BV to BVII:
R1- \ H~ '~-Z~- ~ COO-Q BV
Y
R1 H \'~-/ H ~~-CH2CH2- O '>-X BVI
-_
Y
__
R1- ~ H ~y-CH2CH2- H '-- ~~ -X BVI Z
,,
in which R1 has the meaning given for R,
Z° is -CH2CH2- or a single bond and
/Y
Q is -~ -CnH2n+1, ~-R or -~y -X
n being 1 to 9, X being CN or F and Y being H or F,
t and/or at least one component selected from croup B3
compris ing the compounds o f the formulae BVI I I and BIX
N ~
R1-~l-C O ~-R2 BVIII
N --
N
R1-~~-~~-R2 BIX
in which R1 and R2 each independently of one another
have the meaning given for R, and
,, , _~/ _, _
is -~ J -
or
_ ~, _
~035~62
g _
Particularly preferred compounds of the formula
BIII are those of the following partial formulae:
-.,
R1_,~ ~...~ '~R2
R ' CH2CH2-~ ,e..R2
in which
R1 is CH3- ( CH2 ) n-0-, CH3- ( CHZ ) t-, trans-H- ( CH2 ) r
CH=CH- ( CHZCHZ ) g-CH20- or trans-H- ( CH2 ) t )
CH=CH- ( CHzCH2 ) g-,
RZ is CH3- ( CH2 ) t-,
n is 1, 2, 3 or 4,
r is 0, 1, 2 or 3,
' s is 0 or 1 and
t is 1, 2, 3 or 4.
Those compounds of the partial formula
R1- COO-( r-R2
in which R1 and R2 have the meanings given above, are also
preferred.
The proportion of the compounds of the formula
BIII of the above-indicated partial formulae is prefer-
ably about 5% to 45%, especially preferably about 10% to
t 35%. Particularly preferred compounds of the formula BIV
are those-of the following partial formula:
R1_ ~~_~'~R2
in which
R1 i S CH3- ( CH2 ) n-O- Or
trans-H- ( CHZ ) r-CH=CH- ( CHZCH2 ) 5-CH20- and R2 is
CH3- ( CHZ ) t-,
' n being 1, 2, 3 or 4,
r being 0, 1, 2 or 3,
s being 0 or 1 and
t being 1, 2, 3 or 4.
The proportion of these compounds or of the
compounds of the formula BIV is preferably about 5% to
_. ~~3~~~~
- 10 -
40%, especially preferably about 10% to 35%.
Preferably, the mixtures contain compounds of the
formula III, in particular those of the partial formula
R1 ~~ ~/~R2
In a particularly preferred embodiment, the
mixtures simultaneously contain compounds of the formulae
BIII and BIV, the total proportion of components of group
B1 remaining unchanged.
If compounds of the formulae BI and/or BIII are
present, R1 and R2 preferably each independently of one
another are n-alkyl having 1 to 7 C atoms or
(traps)-n-alkenyl having 3 to 7 C atoms. Z2 is preferably
a single bond. BI is particularly preferred.
Those mixtures according to the invention are
also preferred which contain one or more compounds of the
formula BIV, in which
is - ~~ - , - ~> - or - ~~~ - and R1 and RZ have
i ,
one of the preferred meanings given above, especially
preferably n-alkyl having 1 to 7 C atoms.
In any case, the total proportion of components
of group B1 remains unchanged.
The proportion of compounds of group B2 is
preferably about 5% to 45%, especially preferably 5% to
20%. The proportion (preferred ranges) of BV to BVII is
as follows:
BV about 5% to 30%, preferably about 5% to 15%
total of BVI and BVII: about 5% to 25%, preferably about
10% to 20~.
Preferred compounds of group B2 are indicated
below:
a
_ 11 - 20358?
,.
R1- ~ H \~~-.Z~_ ~~~COO- ~~~C H BV1
- n 2a+1
R1-~y-Z~-~~COO- ~~-R BV2
i .~,
Y
R1- H \~Z~- ti tCOO-~> -F BV3
v -/
Y
--,
R1-~ H '~- H CH CH - ~-F BVI1
2 2 ~/
Y
R1 H ~s-CH CH / H \~- O ~ -F BVI I1
~' 2 2 ~_-..
R1 is preferably n-alkyl having 1 to 7 C atoms or
(trans)-n-alkenyl having 3 to 7 C atoms. Z° is preferably
a single bond. R preferably has the preferred meaning
given above for R1 or is fluorine. Y is preferably
fluorine.
Preferably, the mixtures according to the inven-
tion contain one or more compounds selected from the
group comprising BV3, BVI1 and BVII1 in a total
proportion of about 5 to 35$.
In a particularly preferred embodiment, the
mixtures according to the invention contain, in addition
to BV3, BVI1, BVII1 and BV2 (R = A), further terminally
fluorinated compounds selected, for example, from the
group comprising: ~ Y
R1- ( H ~~COO- a O >-F
i
/Y
R1-~-~' )-~~-F
x
and/or polar heterocycles selee~ted from the group com-
prising
20356?
- 12 -
R1- ~/ O N_f'_ .~~ O )_~'- ~ O vYXo
,, N v ;
~. .
- N Y
~1- O ) -\ 0 ) -CH2CH2- 0 ~, _Xo
N '-,
1 ~N ~~Y
t? ~. ~ _ ~~ p , ~~~ _ X o
~- N ~ ~ Y
rZl-.' p ~_,~~,-~,~_Xo
...,. ~ ~/
in which R1 is preferably n-alkyl having 1 to 7 C atoms or
(trans)-n-alkenyl having 3 to 7 C atoms, x is 1 or 2, x°
is F, C1, CF3, -OCF3 or -OCHFZ, y is 0 or 1 and Y is H
or F.
The total proportion of all the terminally
fluorinated compounds is preferably about 5% to 65%,
especially about 15% to 40%.
The proportion of the compounds from group B3 is
preferably about 5% to 30%, especially preferably about
10% to 20%. R1 is preferably n-alkyl or n-alkoxy each
having 1 to 9 C atoms. R2 is preferably n-alkyl having 1
to 9 C atoms. However, analogous compounds with alkenyl
or alkenyloxy groups can also be used. Compounds of the
formula BVIII are preferred.
' -~ - is preferably 1,4-phenylene.
The mixtures according to the invention contain
compounds from at least one of groups B1, B2 and B3.
Preferably, they contain one or more compounds from group
B1 and one or more compounds from group B2 and/or B3.
Isothiocyanates, for example of the formula
Sap-29-00 05:36pm From-Sd,B/FaCo, +2328440 T-463 P 06 F-15T
2E~_'14-221
13
y
~NCS in which R1 is n-alkyl having 1 to 7 C
aLOms or n-alkenyl having 3 to 7 C atoms, are also preferred.
In a particularly preferred embodiment, the mixtures
«ccording to the inven:.ion contain preferably about 5~s to 20%
of one or more compounds having a dielectric anisotropy below
-1.5 (component D). Compounds of this type are known, for
example derivatives of 2,3-cicyanohydroquinor~e or cyclohexane
derivatives having the structural element
CN
---~~~~ according to German Of fenlegungssc:~rifc
'y
~.0 3,231,707 or 3,407,013.
Preferably, however, compounds having the structural
element 2,3-difluoro-1,4-phenylene are selected, for example
compounds according ~.o German Offenlegungsschriften 3,807,801,
;,807,861, 3,8C7,863, 3,807,864 or 3,907,908. Particularly
preferred are tolans having the structural element according Lo
ynternational PaLenL Publicac;:on W088/07514, in particular
those of the formu:~ae
F~/F
R ; -~ ~,,%-C ~C -~~ ,i--0 R2
F F
. /
R~ H ~~ Z~ ~ ACC~ ~OR2
,~-- ~ ,,
in which Rl and RZ each independently of one another are
preferably n-alkyl having 1 to 7 C aLOms or n-alkenyl having 3
to 7 C atoms and Z° is -C~:2CH2- or a single bond, and
F"F
phenylpyrimidine of t~:e formul ~a
R~~~~ ~ ~R2
~~ N
corresponding to German. Offenlegungsschrift 3,807,871.
CA 02035862 2000-09-29
Sep-29-00 05:36pm From-S&B/F&Co, +2329440 T-463 P O7 F-157
254'14-221
13a
In a particularly preferred embodiment, the mixtures
contain about 5% to 35%, especially preferably about 10% to
20a, of liquid-crystalline tolan compounds.
CA 02035862 2000-09-29
- 14 - 2~3~~~ s~
As a result, it is possible to use smaller cell thick-
nesses (about 5-6 ~sm), whereby the switching times are
markedly shortened. Particularly preferred tolanes are
shown below:
R1 _( p _C=C-Sz
_ ~~
R1 _ ~~-Z~ _ ~~, _C=C-Q
Rl is preferably n-alkyl or n-alkoxy having 1 to 7
C
atoms,
Z is -CHZCH2- a single nd,
or bo
--. ~ F
-
O
R
Q is -~~ -X or -~ ;-X~ ,
~ i
~'-
'
X being F, C1
or OCF3,
R2 being n-alkyl or n-alkoxy each having 1 to 7 C atoms
or n-alkenyl or n-alkenyloxy each having 3 to 7 C
atoms.
Further particularly preferred embodiments are
given below:
- component A contains compounds of the formulae IIa
to I I f , in which X is cyano , and compounds o f the
formulae IIa to IIf, in which X is -NCS, F, C1, -CF3,
-CHF2, -OCF3, -OCHFZ, -OCF2CF2H or -OC2F5, and the
proportion of the cyano compounds in component A is
0 to 50$ by weight,
- component A contains one or more compounds of the
formulae IIal-IIa3 and IIcl-IIc8
R_/'~_ ~~~-X Ilal
F
R-~ ~- ~ O -X IIa2
F
I I a3
R- ~ - O -X
R-, O -; O _<\'~-X IIcl
.a 2035862
- 15 -
F
i
R ~ ~ ~-( O ~-X
I Ic2
~
i
F
_ ~ IIc3
---_j
R ~~- (~ O /)- ~~-X
F
__
R I I c 4
Ji ~
~
~
X
..
.-- IcS
F
F
_ _, _
R-c, O~'-C O -%. O~-X I
~
/ F ,
,..
~,
.-
F
i-'
R-(/ O\
~
~
-(\ IIc6
- O
-X
~ F F
~
\
R_~ I Ic7
_ O '~- ~
)_X
F --~F ~F
R
~~
~
i
~
-t IIc8
-<
O
-
-X
J , ~~
-
in which R is n-alkyl, n-alkoxy or n-alkenyl having
1-9 C atoms and X is F, C1 or OCF3.
Component A contains at least one compound of the
formulae IIdl-IIdS
F
R- ~-~ -CH2CH2- O -X I Id5
i
~F F .
in which R is CaH~+1 or CnH~,+1 -~. with n = 1-10
and X is F, C1 or OCF3 and very especially F.
- Component A contains no compounds of the formulae
IIa to IIf, in which X is cyano,
- Component A contains one or more compounds of the
formula
R- ~ N-~~ -Z- O-F
N
R - O ,-CH2CH2 O ~-X IIdl
.-.~ ~ F
R- ~-~ -CH2CH2- O~ -X I Id2
R- O ~,-~ -CH2GH2-~~-X IId3
F
R- ~~~ - O -CH2 CH2 - ~ -X I I d4
Sep-29-00 05:36pm From-Sd,B/F~Co, X2328440 T-463 P 08 F-157
26474-221
16
in which
R is n-alkyl, n-alkoxy or n-alkenyl having 1-9 C
atoms,
2 is -CH2CH~- or a single bond and
A j~-- is 1,4-phenylene, 2- or 3-fluoro-1,4-phenylene or
1,4-cyclohexylene.
-X is F, C1, CF3, -OCF3, OCHF~ or CHF2, component B
conr,ains one cr more compounds selected from the group
comprising II1 to II7:
II1
1 o R? ~~ ~(~ RZ
II2
'', ~'
R --rt H ~-C H 2 C H Z ~Or 2 I 3
U
R~ w ~\ ~~ RZ II4
R~~ H \ R2 II5
~W.J '~,
n~
R~~~~r--~ H ~--R2 _ II6
R'---~ H \~ C H 2 C H 2 H \'~ R 2 I I 7
CA 02035862 2000-09-29
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26474-221
17
in which R1 arid R' each independently of one another are n-
alkyl, n-alkoxy, n-oxalkyl, r~-fluoro«lkyl or n-alkenyl having
up to 9 C atoms, the rings A1, Az and A~ each independently oz
one another are 1,4-phenylene, 2- or 3-fluoro-1,4-phenylene,
traps-1,4-cyclohexylene or 1,4-cyclohexenylene, Z1 and ZZ each
independently of one another are -CHICHI-, -C--__C- or a single
bond, and m is 0, 1 or 2.
Component B additionally contains one or mare
compounds selected from the group comprising II8 to II20:
1 Q R, H ~ H 6:=
8 R=
IT10
Ri H ~ R:
D11
R~ 0 0 o RI
al:
a' H a~~,
ass
R' H ~CZi7 ~ Ra
Bts
R' H 8 ~ Ri
ms
R~ H Qt~h H ~ Rz
X16
R' H H Qi~ ~ g~
a17
R H g
CA 02035862 2000-09-29
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26474-221
is
ala
~
R~ x x R
a19
~
Ri rZ ' Rx
8
~0.
R~ H ~ l Ra
'..r J
in which R1 and RZ each independently of one another are n-
alkyl, n-alkoxy, n-oxaalkyl, w-fluoroalkyl or n-alkenyl having
up to 9 C atoms, the rings A1, A2 and A' each independently of
l0 one another are 1,4-phenylene, 2- or 3-fluoro-1,4-phenylene,
traps-1,4-cyclohexylene or 1,4-cyclohexenylene, Z1 and ZZ each
independently of one another are -CHZCH~-, -C=C- or a single
bond, and m iq 0, 1 or 2 and the 1,4-phenylene groups in II8 to
II17 each independently of one another can also be mono- or
poly-substituted by fluoryne.
Component B additionally contains one or more
~ompouncs selected from the group comprising II21 to II25:
R' \ H \~ ,,'~ '' .' O'~~ H ~~ R 2 I I21
s
~/'~ v
R~~~--CH2CH2~~) ~~ '' \~ R2 TI22
y '.
R ~ "~ H ~ H ''' ~~ H R ~
', . II23
i~ ~~ v
R'-- \ H ~r--~\ H C H 2 C H z ,~~ H R 2 I I 2 4
,~ '
CA 02035862 2000-09-29
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19
R'---c,~,y H \ ~ R 2
/ \ 'v ~ II25
in which Rl and R~ have the meanings given in claim 1 and the
1,4-phenylene groups in II21 to II25 each independently of one
another can also be mono- or poly-substituted by fluorine.
Component B contains one or mare compounds selected
from the group cornprising II26 and II27:
C rH2r+~~~\ ,\ H ~CH2-F II26
y
~ rH2r+~-"r H ,\ H ;-CH2CH2-F II27
~.n which CrHar+~ is a straight-chain alkyl group having up to 7 C
atom9.
The liquid crystal mixture additionally contains,
apart from components A, B and C, one or more compounds
selected from the group comprising III and IV:
R'---( H ~~ H '~ p R 2 W I
R \ H ,~~.--CH20R2
~_. / I V
in which R1 and R' each independently of one another are n-
a:.kyl, n-alkoxy, n-oxaalkyl, w-fluoroalkyl or n-alkenyl having
up to 9 C atoms, the rings Al, Az and A~ each independently of
one another are 1,4-phenylene, 2- or 3-fluoro-1,~-phenylene,
traps-1,4-cyclohexylene or 1,4-cyclohexenylene, Z1 and Z~ each
independently of one another are -Ci32CH~-, -C---C- or a single
bond, and m is 0, 1 or 2.
CA 02035862 2000-09-29
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The liquid crystal mixture additionally contains,
apart from components A, B and C, one or more compounds
selected from the group comprising V and VI:
N ~,
R--(~,r-~~ ~-R2 v
~N
R~~ ~ /~ ~R2
~'~-i VI
.n which i~c= and R2 each independently of one another are n-
alkyl, n-alkoxy, n-oxaal?~yl, c~-fluoroalkyl or n-alkenyl having
up to 9 C atoms, the rings Al, A' and A' each independently of
10 one another are 1,4-phenylene, 2- or 3-fluoro-1,4-phenylene,
traps-1,4-cyclohexylene or 1,4-cyclohexenylene, Z1 and 22 each
independently of one another are -CH2CHz-, -C._-C- or a sino_le
bond, and m is 0, 1 or 2. '
Component C contains one or more compounds selected
15 from the group comprising 'till to XI:
F F
VII
~~~-S CN2CH2 ,~R
~/ ~/,
F. F
R? ~~~- S ~~~R2 VIII
F F
2o R-----~:--(CH2CH2)s ~\\~' z
\~ ~ ~~ \~R IX
F F
R~~~CHzCH2~'-.-(CH2CH ~ 2
\~ z )s ,\~ R X
F F
t
CH2CH2 ' ~-(CH2CH2)s H R2
XI
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20a
::n which R1 and R2 each independently of one another are n-
alkyl, n-alkoxy, n-oxaalkyl, c~-fluoroalkyl or n-alltenyl having
up to 9 C atoms, the rings Al, Az and A3 each independently of
one another are 1,4-phenylene, 2- or 3-fluoro-1,4-phenylene,
trans-1,4-cyclohexylene or 1,4-cyclohexenylene, 21 and Z~ each
independently of one another are -CH2CHz-, -C=C- or a single
bond, and m is 0, 1 or 2 and S (sic) is 0 or 1.
Component H contains one or more compounds selected
from the group comprising XI. to XIV;
R~ \(~~C~C ~ R2 XII
R y\,. ~---. 2
\~~C C ~y R XI I I
/~~
R~ H r--CH2CHZ .~~ j--C-C~;--R2 XIV
v \'/
vn which R1 and R~ each independently of one another are n-
alkyl, n-alkoxy, n-oxaal~:yl, ca-fluoroalkyl or n-alkenyl having
up Lo 9 C atoms, the rings A1, A~ and A3 each independently of
one another are 1,4-phenylene, 2- or 3-fluoro-1,4-phenylene,
trans-1,4-cyclohexylene or 1,4-cyclohexenylene, Zl and Zz each
~~ndependently of one another are -CHzCH=-, -C=C- or a single
bend, and m is 0, 1 or 2.
Those mixtures are preferred which exclusively
contain compounds of the formulae IIa to IIh (group A) and
component C, i.e. no compounds of component B.
The preferred mixtures containing terminally
h alogenated compounds of the formulae IIa to IIk (X = F, C1,
-CF3, -CHF2, -OCF3 cr -OCHFz) shows (sic) particularly
advantageous parameter combinations and, at the same time, a
wide d/p window.
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20b
Liguid crystal mixtures according to the invention
whcse component A contains at least one compound of Lhe formula
Y
R~\, C-C ~yX
v
S in which
R i s -CnH~n,,l , -OCnH2n+1 i CnH2n+1
or CnFi2n,.l~~ CH2CH3,
n is an integer of I-15,
Y is H or F and
X is F, C1 or OCF3,
and/or contains a compound of the formulae IId2-IId5,
IIal-IIa3 and/or IIc1-IIcB, have advantageous values of the
threshold voltage vlo~ciao and of the flow viscosity r~ and are
diatinguis_rled by fairly high or high values of the optical
anisotropy. These mixtures are preferred.
For component D, a large number of chiral doping
substances, some of which are commercially obtainable, are
a~Tailable to those skilled in the art. The choice of these is
not critical per se.
The liquid crystal mixtures used in the SLD according
to the inven~l.ion are dielectrically positive with ~F z 1.
Liquid cry9tal mixtures with Ds _> 3 are particularly preferred,
and very particularly those with a~ ? 5.
The liquid crystal mixtures according to the
invention have advantageous values of the threshold
CA 02035862 2000-09-29
.~. zo3~~s~
- 21 -
voltage Vloioiao and of the flow viscosity n. If the value
of the optical path difference den is given, the value
.of the layer thickness d is determined by the optical
anisotropy en. Using i.a. liquid crystal mixtures accord-
s ing to the invention with a relatively high or high value
of the optical anisotropy is preferred, especially in the
case of relatively high or high values of don, since the
value of d can then be selected to be relatively small,
which brings about more advantageous values of the
switching times. However, those liquid crystal displays
according to the invention which contain liquid crystal
mixtures according to the invention having smaller values
of en are also characterized by advantageous values of
the switching times. The liquid crystal mixtures accord-
ing to the invention are characterized further by advan-
tageous values of the steepness of the electro-optical
characteristic and can be operated at high multiplex
rates. Moreover, the liquid crystal mixtures according to
the invention have high stability and advantageous values
of electrical resistance and of frequency dependence of
the threshold voltage. The liquid crystal displays
according to the invention have a wide range of working
temperatures and good angle dependence of the contrast.
The structure of the liquid crystal display
elements according to the invention from polarizers,
,' electrode base plates and electrodes with such a surface
treatment that the preferential orientation (director) of
the adjoining liquid crystal molecules from one electrode
to the other is in each case twisted usually by an amount
of 160 to 360 relative to one another, corresponds to
the type of construction which is conventional for such
display elements . The term co~entional type of construc-
tion is here used in a wide meaning and also comprises
all variations and modifications of the supertwist cell,
and in particular also matrix display elements and the
display elements containing additional magnets according
to German Offenlegungsschrift 2,748,738. The surface tilt
angles at the two carrier plates can be equal or dif-
ferent. Equal tilt angles are preferred.
2035~6a
- 22 -
However, an essential difference between the
display elements according to the invention and the
.hitherto conventional ones on the basis of the twisted
nematic cell resides in the choice of the liquid crystal
components of the liquid crystal layer.
The liquid crystal mixtures which can be used
according to the invention are prepared in a manner
conventional per se.
As a rule, the desired quantity of the components
used in a smaller amount is dissolved in the components
representing the main constituent, advantageously at an
elevated temperature. It is also possible to mix
solutions of the components in an organic solvent, for
example in acetone, chloroform or methanol, and, after
thorough mixing, to remove the solvent again, for example
- by distillation.
The dielectrics can also contain further addi
tives known to those skilled in the art and described in
the literature. For example, 0-15% of pleochroic dyes can
be added.
The examples which follow are intended to explain
the invention, without limiting it.
In the examples:
S-N is the smectic/nematic phase transition
temperature,
c.p. is the clearing point,
visc. is the viscosity (mPa.s),
Ton is the time from switching on until 90% of the
maximum contrast is reached, and
Tuff is the time from switching off until 10% of the
maximum contrast is reached.
The SLD is activated in multiplex operation
(multiplexing ratio 1:100, bias 1:11, operating voltage
18.5 volt).
Above and below, all temperatures are given in
°C. The percentage figures are percent by weight. The
values of the switching times and viscosities refer to
20°C. ~-.
203582
- 23 -
Example 1
An SLD of the STN type having the following
parameters:
twist angle 240°
tilt angle 5°
d/p 0.54
d.en 0.860,
containing a liquid crystal mixture having the following
parameters:
clearing point: 91°
en: 0.1254
eE: +8.1
viscosity (20°C): 16 mPa.s
and consisting of a base mixture of
18% of p-traps-4-propylcyclohexane-benzonitrile,
8% of traps-1-p-methoxyphenyl-4-propylcyclohexane,
5% of 2-p-fluorophenyl-5-propylpyrimidine,
5% of 2-p-trifluoromethoxyphenyl-5-pentylpyrimidine,
5% of 2-p-trifluoromethoxyphenyl-5-heptylpyrintidine,
- 9% of p-[traps-4-(traps-4-propylcyclohexyl)-cyclohexyl]
trifluoromethoxybenzene,
8% of p-[traps-4-(traps-4-pentylcyclohexyl)-cyclo-
hexyl]-trifluoromethoxybenzene,
8% of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethoxyphenyl)-ethane,
(~ 7% of 1-[traps-4-(traps-4-pentylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethoxyphenyl)-ethane,
5% of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(3,4-difluorophenyl)-ethane,
5% of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(p-fluorophenyl)-ethane,
7% of 4-trifluoromethoxy-4'-(traps-4-propylcyclohexyl)-
biphenyl,
3% of 4-(traps-4-propylcyclohexyl)-4'-methoxytolan,
3% of 4-(traps-4-propylcyclohexyl)-4'-ethoxytolan and
4% of 4-(traps-4-propylcyclohexyl)-4'-propoxytolan
and a chiral component (2-octyl p-(p-n-hexylbenzoyloxy)-
benzoate) shows the following switching timess 105 ms
( 1/16 D, 1/5 b) , 198 ms ( 1/240 D, 1/14 . 5 b) , Vla~o~za
203586?
- 24 -
2.31 volt, Vg0/0/20 2.51 volt and a o d/p (d/p window) of
0.21.
.Example 2
An SLD of the STN type having the following
parameters:
twist 240
angle
tilt _;~
angle 5
d/p 0.56
d.nn 0.85,
containing
a liquid
crystal
mixture
having
the
following
parameters:
clearing
point:
87
on; 0.1222
AE:
+8.5
viscosity
{20C):
16
mPa.s
' and
consisting
of
a base
mixture
of
18% of p-traps-4-prooylcyclohexane-benzonitrile,
8% of traps-1-p-methoxyphenyl-4-propylcyclohexane,
5% of 2-p-fluorophenyl-5-propylpyrimidine,
5% of 2-p-trifluoromethoxyphenyl-5-pentylpyrimidine,
5% of 2-p-trifluoromethoxyphenyl-5-heptylpyrimidine,
9% of p-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-trifluoromethoxybenzene,
8% of p-[traps-4-(traps-4-pentylcyclohexyl)-cyclo-
hexyl]-trifluoromethoxybenzene,
8% of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethoxyphenyl)-ethane,
7% of 1-[traps-4-(traps-4-pentylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethoxyphenyl)-ethane,
5% of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(3,4-difluorophenyl)-ethane,
5% of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(p-fluorophenyl)-ethane,
7% of 4-trifluoromethoxy-4'-(traps-4-propylcyclohexyl)-
biphenyl,
5% of 4-(traps-4-propylcyclohexyl)-2',3'-difluoro-4'-
ethoxytolan and
5$ of 4-(traps-4-pentylcyloh~xyl)-2',3'-difluoro-4'-
ethoxytolan
203~~62
- 25 -
and a chiral component (2-octyl p-(p-n-hexylbenzoyloxy)-
benz oate) shows the following switching times:
114 ms (1/16 D, 1/5 b), 236 ms (1/240 D, 1/14.5 b), v10/o/20
2.35 volt, V9o~oizo 2.53 volt and a a d/p (d/p window)
of
0.20 .
Example
3
An SLD of the STN type containing a liquid
crys tal mixture having the following parameters:
clea ring point: 106
en: 0.1322
eE: +6.9
and consisting of a base mixture of
18% of p-traps-4-propylcyclohexane-benzonitrile,
8% of traps-1-p-methoxyphenyl-4-propylcyclohexane,
9% of p-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-trifluoromethoxybenzene,
8% of p-[traps-4-(traps-4-pentylcyclohexyl)-cyclo-
hexyl]-trifluoromethoxybenzene,
8% of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethoxyphenyl)-ethane,
7% of 1-[traps-4-(traps-4-pentylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethoxyphenyl)-ethane,
7% of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(3,4-difluorophenyl)-ethane,
6% of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(p-fluorophenyl)-ethane,
7% of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethylphenyl)-ethane,
7% of 4-trifluoromethoxy-4'-(traps-4-propylcyclohexyl)-
biphenyl,
2% of 4-(traps-4-propylcyclohexyl)-4'-methoxytolan,
2% of 4-(traps-4-propylcyclohexyl)-4'-ethoxytolan,
3% of 4-(traps-4-propylcyclohexyl)-4'-propoxytolan,
4% of 4-methyl-4'-ethoxytolan and
4% of 4-ethyl-4'-methoxytolan
and a chiral component (2-octyl p-(p-n-hexylbenzoyloxy)-
benzoate)
shows
short
switching
times.
Example
4
An SLD of the STN type containing a liquid
- 26 - 203586
crystal mixture having the following parameters:
clearing point: 81°
on: 0.1130
0E: +6.5
and consisting of a base mixture of
20% of p-traps-4-propylcyclohexane-benzonitrile,
10% of traps-1-p-methoxyphenyl-4-propylcyclohexane,
5.6%of traps-1-p-trifluoromethoxyphenyl-4-propylcyclo-
hexane,
5.6%of traps-1-p-trifluoromethoxyphenyl-4-butylcyclo-
hexane,
5.6%of traps-1-p-trifluoromethoxyphenyl-4-pentylcyclo-
hexane,
7% of p-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-trifluoromethoxybenzene,
6.3%of p-[traps-4-(traps-4-pentylcyclohexyl)-cyclo-
hexyl]-trifluoromethoxybenzene,
6.3%of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethoxyphenyl)-ethane,
5.6%of 1-[traps-4-(traps-4-pentylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethoxyphenyl)-ethane,
5.6%of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(3,4-difluorophenyl)-ethane,
5.6%of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethyl)-ethane,
7% of 4-trifluoromethoxy-4'-(traps-4-propylcyclohexyl)-
biphenyl,
3.5%of 4-(traps-4-propylcyclohexyl)-4'-methoxytolan,
2.8%of 4-(traps-4-propylcyclohexyl)-4'-ethoxytolan and
3.5%of 4-(traps-4-propylcyclohexyl)-4'-propoxytolan
and a chiral component (2-octyl p-(p-n-hexylbenzoyloxy)-
benzoate) shows short switching times.
Example 5
An SLD of the STN type, containing a liquid crystal
mixture having the following parameters:
clearing point: 73°
on; 0.1252
nE: ,. +8.7
and consisting of a base mixture of
.,. - 27 - ~03~~~~
20$ of p-traps-4-propylcyclohexane-benzonitrile,
10~ of traps-1-p-methoxyphenyl-4-propylcyclohexane,
5.6~of 2-p-fluorophenyl-5-propylpyrimidine,
5.6~of 2-p-fluorophenyl-5-pentylpyrimidine,
5.6$of 2-p-trifluoromethoxyphenyl-5-pentylpyrimidine,
5.6~of 2-p-trifluoromethoxyphenyl-5-heptylpyrimidine,
7$ of p-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-trifluoromethoxybenzene,
6.3~of p-[traps-4-(traps-4-pentylcyclohexyl)-cyclo-
hexyl]-trifluoromethoxybenzene,
6.3~of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethoxyphenyl)-ethane,
5.6$of 1-[traps-4-(traps-4-pentylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethoxyphenyl)-ethane,
5.6~ of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(3,4-difluorophenyl)-ethane,
5.6~of 1-[traps-4-(traps-4-propylcyclohexyl)-cyclo-
hexyl]-2-(p-trifluoromethyl)-ethane,
3.5~of 4-(traps-4-propylcyclohexyl)-4'-methoxytolan,
3.5~af 4-(traps-4-propylcyclohexyl)-4'-ethoxytolan and
4.2~of 4-(traps-4-propylcyclohexyl)-4'-propoxytolan
and a chiral component (2-octyl p-(p-n-hexylbenzoyloxy)-
benzoate) shows short switching times.
In the following table, physical data of further
mixtures M1 to M41 according to the invention are given,
the composition of which is to be found after the table:
c . p . Vlo~o~zo on D a
89-263 M1 120 5.1 0.1267 1.09
89-220 M2 89 3.0 0.1173
89-172 M3 110 3.3 0.0905 2.3
89-83 M4 93 2.1 0.1049 5.0
89-70 M5 97 0.1057
89-25 M6 90 3.7 0.1159 1.6
89-15 M7 80 3.5 0.0922 1.7
89-470 M8 90
ZLI-4582 M9 98 2.5 0.1008 3.2
ZLI-4581 M10 94 2.2 ., 0.1006 4.1
ZLI-4580 M11 95 2.0 0.1050 5.2
v. 2035862
- 28 -
c ' p' Vio~oizoon
'89-438 M12 92 0.1044 5.7
89-374 M13 92 4.7 0.1132 1.2
89-348 M14 93 0.0704
89-337 M15 79 0.1174 1.6
89-425 M16 107 0.1213 5.0
89-254 M17 92
2.5
89-796 M18 91.2 .153 6.2
89-1081 M19 94 0.1242 8.0
90-205 M20 87 0.1250 6.4
90-442 M21 87 0.1435 g,6
89/1018 M22 85 2 0.1480
89/1020 M23 84 1.82 0.1458
I 89/1034 M24 86 1.94 0.1531
89/1036 M25 96 2.24 0.1645
89/1037 M26 95 2.18 0.1648
89-733 M27 80
89-789 0.1255 5
M28
90-81 M29 90 2.06 0.1403
11.1
90-499 M30 82 1.93 0.1427
90-502 M31 84 2.01 0.1401 10.3
90-515 M32 83 1.77 0.1405 12.3
90-602 M33 86 1.8 0.14
90-604 M34 81 2.0 0.137
90-605 M35 94 1.9 0.15
90-606 M36 80 1.8 0.14
90-607 M37 87 1.8 0.14
90-608 M38 80 1.8 0.14
ZLI-4720-100 M39 91 2.3 0.1299 6
90-609 M40 85 2.2 0.125
90/2008 M41 76 2.15 0.1115
90/370 M42 76 1.63 0.1345
90/371 M43 70
1.44 0.1065
90/373 M44 2.12 0.1678
90/409 M45 8 1.42 0.1306
90/414 M46 74 1.44 0.1136
90/416 M47 63 I:66 0.1617
90/411 M48 72 1.89 0.1306
2035862
- 29 -
W o~o~zo on
90/415 M49 78 2.07 0.1193
90/417 M50 g0
186 0.1609
90/2014 M51 71 1.70 0.1401 10.
5
90/2015 M52 76 1.91 0.1152 8.6
90/487 M53 g7 1.90 0.1401 11.4
.:.r"
w 203~~62
- 30 -
89-263 (M1) 89-220 (M2)
G-50CF2 30 % PYP-50CF3 18
PCH-53 11 % PYP-70CF3 18
I32 16 % PCH-301 13 o
I35 10 % CCH-303 13
BCH-32 9 % CH-35 4
CBC-33 4 % CH-43 4
CBC-53 4 % CH-45 4
CBC-55 4 % CBC-33 4
CBC-33F 4 % CBC-53 5
CBC-53F 5 % CBC-55 4
CBC-55F 3 % CBC-33F 4
CBC-53F 5
CBC-55F 4
89-172 (M3) 89-83 (M4)
CCP-30CF3 20 % PCH-3 14
CCP-50CF3 20 % PCH-SF 10
PCH-301 15 % PCH-7F 10
PCH-302 10 % PCH-50CF2 20
CCH-303 10 % ECCP-3F 6
O CCH-501 9 % ECCP-5F 6
CBC-33 3 % ECCP-33 5
CBC-53 4 % CBC-33 5
CBC-33F 3 % CBC-53 5
CBC-53F 3 % CBCt55 4
CBC-55F 3 % CBC-33F 5
CBC-53F 5
CBC-55F 5
m 203586 2
- 31 -
89-70 (MS) 89-25 (M6)
PCH-3 14 % PCH-5F 14 ,a
PCH-5F 14 % PCH-6F 13 ,,o
PCH-7F 14 % PCH-7F 14 a
PCH-SOCF2 10 % I32 16
ECCP-3F 6 % I35 10
ECCP-5F 6 % BCH-32 9
ECCP-33 5 % CBC-33 4
CBC-33 5 % CBC-53 4
CBC-53 5 % CBC-55 4
CBC-55 5 % CBC-33F 4
CBC-33F 5 % CBC-53F 5
CBC-53F 6 % CBC-55F 3
CBC-55F 5
89-15 (M7) 89-470 (M8)
PCH-30CF2 20 % PCH-3 18
PCH-50CF2 10 % PCH-5F 12
CCH-303 13 % PCH-6F 12
CCH-502 13 % PCH-7F 10
ECCP-31 4 % ECCP-3F.F 7
( ECCP-32 4 % ECCP-SF.F 7
ECCP-33 4 % ECCP-33 5
ECCP-35 4 % CBC-33 5
BCH-32 9 % CBC-53 5
BCH-52 9 % CBC-55 4
CBC-33F 4 % CBC-33F 5
CBC-53F 3 % CBC-53F 5
CBC-55F 3 % CBC-55F 5
203862
- 32 -
ZLI-4582 (M9) ZLI-4581 (M10)
PCH-3 7 o PCH-3 10
PCH-5F 12 o PCH-5F 18
PCH-6F 12 % PCH-6F 14
0
PCH-7F 10 % PCH-7F 10
ECCP-3F 7 % ECCP-3F 9
ECCP-5F 7 % ECCP-5F 7
PCH-53 8 % ECCP-33
ECCP-33 5 % CBC-33 5
CBC-33 5 % CBC-53 6
CBC-53 6 % CBC-55 5
CBC-55 5 % CBC-33F 5
'CBC-33F 5 % CBC-53F 6
CBC-53F 6 % CBC-55F 5
CBC-55F 5
LLI-4580 (M11) 89-438 (M12)
PCH-3 18 % PCH-3 18
PCH-5F 12 % PCH-5F 12
PCH-6F 12 % PCH-6F 12
PCH-7F 10 % PCH-7F 10
ECCP-3F 7 % ECCP-3CF3 7
ECCP-5F 7 % ECCP-5CF3 7
ECCP-33 5 % ECCP-33 5
CBC-33 5 % CBC-33 5
CBC-53 5 % CBC-53 5
CBC-55 4 % CBC-55 4
CBC-33F 5 % CBC-33F 5
CBC-53F 5 % CBC-53F 5
CBC-55F 5 % CBC-55F 5
203586
- 33 -
89-374 (M13) 89-348 (M14)
PCH-5F 15 % PCH-5F 10
PCH-7F 15 % PCH-6F 5
PCH-53 20 % PCH-7F 10
BCH-32 14 % ECCP-3CF3 10
BCH-52 11 % ECCP-5CF3 10
CBC-33 3 % CCP-30CF3 10
CBC-53 4 % CCP-30CF3 10
CBC-55 4 % CCP-50CF3 10
CBC-33F S % ECCP-30CF3 10
CBC-53F 6 % ECCP-50CF3 10
CBC-55F 3 % CBC-53F 5
89-227 (M15) 89-425 (M16)
EPCH-20CF3 20 % PCH-3 15
EPCF~-30CF3 5 % PCH-5F 12
EPCH-50CF3 5 % PCH-6F 12
PCH-53 11 % PCH-7F 10
I32 16 % ECCP-3F 6
I35 10 % ECCP-5F 6
BCH-32 9 % CPTP-301 3
CBC-33 4 % CPTP-302 3
CBC-53 4 % CPTP-303 3
CBC-55 4 % CBC-33 5
CBC-33F 4 % CBC-53 5
CBC-53F 5 % CBC-55 4
CBC-55F 3 % CBC-33F 5
CBC-53F 5
CBC-55F 5
2o3~ssz
- 34 -
3,9-254 (M1?) 89-796 (M18)
PCH-3 6 o PCH-3 15
PCH-Y 4 % PCH-4 10
0
CCP-30CF3 7.5 % PCH-301 16
CCP-50CF3 2.5 % PCH-302 10
PCH-302 15 % PTP-40F 23
0
PCH-304 13 % CBC-33F 4
0
PCH-402 8 % CBC-53F 5
PCH-501 9 % CBC-55F 4
PCH-502 5 % CBC-33 4
CP-33 5 % CBC-53 5
CP-35 5 % CBC-55 4
CP-43 5
CP-45 5
CBC-33 3
0
CBC-53 5
CBC-55 2
89-1081 (M19) 90-205 (M20)
PCH-3 16 % PCH-3 16
- PTP-40F 9 % PTP-40F 9
PTP-50F 10 % PTP-50F 10
ECCP-3F 5 % CCP-20CF3 7
ECCP-5F 7 % CCP-30CF3 7
CCP-20CF3 7 % CCP-40CF3 7
CCP-30CF3 7 % CCP-50CF3 7
CCP-40CF3 7 % ECCP-30CF3 4
CCP-50CF3 7 % ECCP-50CF3 4
ECCP-30CF3 6 % ECCP-3F.F 5
~ECCP-50CF3 6 % ECCP-SF.F 4
ECCP-3F.F 8 % D-302FF 7
ECCP-SF.F 7 % D-502FF 6
CP-302FF 7
203586,
- 35 -
90-442 (M21) 89/1018 (M22)
PCH-2 4 % PCH-3 22
PCH-3 17 % PCH-4 18
PCH-4 12 % PTP-70F 6
PCH-5 11 % PTP-102 5
CCP-30CF3 7 % PTP-201 7
CCP-50CF3 6 % CP-3F 10
ECCP-31 4 % CP-5F 8
ECCP-32 4 % ECCP-3F 4
ECCP-3F 6 % BCH-32 10
ECCP-5F 6 % BCH-5.F2 10
CPTP-301 5
CPTP-302 5
PTP-40F 7
PTP-SOF 6
89/1020 (M23) 89/1034 (M24)
PCH-3 22 % PCH-3 22
PCH-4 17 % PCH-4 16
K6 9 % K6 2
K9 3 % PTP-40F 8
PTP-70F 6 % PTP-102 4
CP-3F 10 % PTP-201 5
CP-5F 9 % CP-3F 10
ECCP-3F 9 % CP-5F 8
CPTP-301 5 % ECCP-3F 5
CPTP-302 4 % BCH-32 8
BCH-5.F2 10
CPTP-301 2
20358~~
- 36 -
8G;~1036 (M25) 89/1037 (M26)
PCH-3 21 % PCH-3 15
K6 6 % K6 6
PTP-40F 8 % K9 6
PTP-102 6 % PTP-40F 8
PTP-201 7 % PTP-102 4
CP-3F 10 % PTP-201 6
CP-5F 10 % PCH-302 3
ECCP-3F 11 % CP-3F 10
BCH-32 10 % CP-5F 10
BCH-5.F2 11 % ECCP-3F 11
BCH-32 10
BCH-5.F2 11
89-733 (M27) 89-789 (M28)
PCH-3 21 % PCH-3 18
K6 6 % PCH-5F 12
PTP-40F 8 % PCH-6F 12
PTP-35 7 % PCH-7F 10
PTP-201 7 % PTP-40F 14
CP-3F 10 % ECCP-33 5
CP-5F 8 % CBC-33 5
ECCP-3F 12 % CBC-53 5
BCH-32 10 % CBC-55 4
BCH-5.F2 11 % CBC-55 4
CBC-33F 5
CBC-53F 5
CBC-55F 5
203~86~
- 37 -
9081 (M29) 90-499 (M30)
PCH-2 7 % PCH-3 18
PCH-3 18 % PCH-4 8
PCH-4 14 % PCH-S 10
PCH-5 15 % PCH-301 13
PCH-7 7 % ME2N.F 3
BCH-32 10 % ME3N.F 3
CPTP-301 4 % PTP-102 3
CPTP-302 3 % PTP-201 4
CPTP-303 3 % CPTP-301 4
ECCP-3 7 % CPTP-302 4
ECCP-3F 6 % CPTP-303 4
ECCP-5F 6 % ECCP-3F 6
ECCP-SF 6
ECCP-31 3
ECCP-32 2
CCP-30CF3 5
CCP-SOFF3 4
C
203~~6 2
- 38 -
90502 (M31) 90-515 (M32)
PCH-3 18 % PCH-3 18
PCH-4 8 % PCH-4 8
PCH-5 10 % PCH-5 10
PCH-301 11 % PCH-301 8
rlE2N.F 3 % ME2N.F 3
ME3N.F 3 % ME3N.F 3
PTP-102 4 % MESN.F 5
PTP-201 3 % PTP-102 5
CPTP-301 3 % CPTP-301 3
CPTP-302 4 % CPTP-302 4
CPTP-303 3 % CPTP-303 3
ECCP-3F 6 % ECCP-3F 6
ECCP-5F 6 % ECPP-5F 6
ECCP-31 5 % ECCP-31 5
ECCP-32 4 % ECCP-32 4
CCP-30CF3 5 % CCP-30CF3 5
CCP-50CF3 4 % CCP-50CF3 4
90-602 (M33) 90-604 (M34)
PCH-2 5 % PCH-2 5
PCH-3 15 % PCH-3 15
PCH-4 11 % PCH-4 11
PCH-5 21 % PCH-5 21
PCH-7 11 % PCH-32 5
PCH-32 5 % FET-3F I4
CFET-3F 12 % FET-5F 11
CFET-5F 10 % CBC-33 6
CBC-33 4 % CBC-53 6
CBC-53 6 % CBC-55 6
~03~$~~
- 39 -
90-605 (:~I35 ) 90-606 (M36 )
PCH-3 15 % PCH-3 15
PCH-4 11 % PCH-4 11
PCH-5 21 % PCH-5 21
PCH-7 11 % PCH-7 11
CFET-3F 12 % PCH-32 5
CFET-5F 10 % CFET-3F 8
FET-3F 5 % CFET-5F 6
FET-5F 5 % FET-3F 7
CBC-33 4 % FET-5F 7
0
CBC-53 6 % CBC-33 4
0
CBC-53 5
90-607 (M37) 90-608 (M38)
PCH-2 5 % PCH-2 5
PCH-3 15 % PCH-3 15
PCH-4 11 % PCH-4 11
PCH-5 21 % PCH-5 21
PCH-7 11 % PCH-7 11
PCH-32 5 % PCH-32 5
CFET-3F 12 % CPTP-30CF3 12
CFET-3F.F 10 % CPTP-50CF3 10.
CBC-33 4 % CBC-33 4
CBC-53 6 % CBC-53 6
203862
- 40 -
ZLI-4720-100 (M 39) 90609 (M 40)
PCH-3 18 % PCH-3 18
PCH-4 14 % PCH-4 14
PCH-5 12 % PCH-5 12
PCH-7 8 % PCH-7 8
PTP-102 3 % PTP-20F 3
PTP-201 3 % PTP-40F 3
CPTP-302 3 % CPTP-30CF3 3
ECCP-31 4 % ECCP-31 4
ECCP-32 5 % ECCP-32 5
ECCP-33 5 % ECCP-33 5
ECC1~-35 4 % ECCP-35 4
ECCP-3 7 % ECCP-3 7
ECCP-3F 7 % ECCP-3F 7
ECCP-5F 7 % ECCP-5F 7
90/2008 (M 41) 90/370 (M 42)
PCH-3 10 % PYP-3F 7
PYP-3F 10 % PCH-3 11
PYP-5F 9 % PCH-5 10
', PCH-5F 9 % PCH-7 10
PCH-7F 9 % PTP-35 16
ECCP-3F 13 % CPTP-303 4
ECCP-SF 12 % CCP-20CF3 15
CP-3F 9 % CCP-30CF3 21
CP-5F 9 % CCP-50CF3 6
CPTP-301 5
CPTP-303 5
i
- 41 - 2035862
90/371 (a'1 43) 90/373 (M 44)
PYP-3F 7 % PYP-3F 7
PCH-3 11 % PCH-3 9
PCH-5 10 % PCH-5 10
PCH-7 10 % PCH-7 9
PCH-301 16 % PTt'-35 15
CPTP-303 4 % PTP-45 19
CCP-20CF3 15 % CPTP-303 4
CCP-30CF3 21 % BCH-32 14
CCP-50CF3 6 % BCH-52F 13
90/409 (M 45) 90/414 (M 46)
PYP-3 F 7 % PYP-3 F 7
PCH-3 21 % PCH-3 11
:CH-5 10 % PCH-5 10
PCH-7 10 % PCH-7 10
PCH-301 10 % PCH-301 13
PTP-102 4 % CPTP-303 4
PTP-201 4 % PTP-102 3
CPTP-303 6 % CCP-20CF3 10
CCP-20CF3 8
CCP-30CF3 11
CCP-30CF3 8 % CCP-40CF3 10
CCP-40CF3 6 % CCP-50CF3 11
CCP-50CF3 6
a
- 42 - 203~~6?
90,'4'15 ( M 47 ) 90/411 ( M 48 )
?YP-3F 10 % PYP-3F 7
T~6 10 % PCH-3 21
PCH-3 11 % PCH-5 10
PCH-5 10 % PCH-7 10
PCH-7 10 % PCH-301 10
PCH-301 12 % PTP-102 4
PTP-35 5 % PTP-201 3
PTP-102 5 % CPTP-303 6
CPTP-302 5 % CCP-30CF3 10
CPTP-303 5 % CCP-50CF3 10
BCH-32 8 % ECCP-32 4
BCH-52F 9 % ECCP-33 5
90/415 (M 49) 90/417 (M 50)
PYP-3F 6 % PYP-3F 4
PCH-3 14 % PCH-3 22
PCH-5 10 % PCH-5 11
PCH-7 10 % PCH-7 13
PCH-301 13 % PCH-301 11
CPTP-303 4 % PTP-102 5
PTP-102 4
PTP-201 4
CCP-30CF3 11 % CPTP-301 4
CCP-50CF3 11 % CPTP-302 3
ECCP-32 9 % CPTP-303 5
ECCP-33 8 % BCH-32 10
BCH-52F 8
203586
- 43 -
90/2014 (M51) 90/2015 (M52)
K5 7.0 PCH-3 21,0
PCH-3 28.0 PCH-5 10.0
PCH-5 13,0 PCH-7F 15,0
PCH-301 11,0 CCP-20CF3 12.0
CCP-20CF3 8.0 CCP-30CF3 13.0
CCP-30CF3 8,0 CCP-40CF3 10,0
CCP-40CF3 5,0 CCP-50CF3 8.0
CCP-50CF3 6,0 PTP-102 . 7,0
PTP-102 3.0 CPTP-301 4.0
CPTP-301 6,,0
90/487 (M53)
PCH-3 18,0
PCH-4 14,0
PCH-5 11,0
ME2N.F 3,0
ME3N.F 4,0
0-302 5,0
D-402 5,0
PTP-102 4,0
CPTP-301 4,0
CPTP-302 4,0
CPTP-303 3,0
ECCP-3F ~ 6,0
ECCP-5F 6,0
ECCP-31 6,0
ECCP-32 7,0
_. . 203~8~;
- 44 -
PCH-53: traps-1-p-propylphenyl-4-pentylcyclohexane
I-32: 1-(traps-4-propylcyclohexyl)-2-(4'-ethyl
2'-fluorobiphenyl-4-yl)-ethane
I-35: 1-(traps-4-propylcyclohexyl)-2-(4'-pentyl-
2'-fluorobiphenyl-4-yl)-ethane
BCH-32: 4-ethyl-4'-(traps-4-propylcyclohexyl)-
biphenyl
BCH-52: 4-ethyl-4'-(traps-4-pentylcylcohexyl)-
biphenyl (sic)
CCH-303: traps,traps-4-propoxy-4'-propylcyclohexyl-
cyclohexane
CCH-501: traps,traps-4-methoxy-4'-pentylcyclohexyl-
cyclohexane
C
CH-35: traps-4-pentylcyclohexyl trans,trans-4-
propylcyclohexylcyclohexanecarboxylate
CH-43: traps-4-propylcyclohexyl trans,trans-4-
butylcyclohexylcyclohexanecarboxylate
CH-45: traps-4-pentylcyclohexyl trans,trans-4-
butylcyclohexylcyclohexanecarboxylate
PCH-302: traps-1-p-ethoxyphenyl-4-propylcyclohexane
PCH:303: traps-1-p-propoxyphenyl-4-propylcyclo-
hexane
PCH-304: traps-1-p-butoxyphenyl-4-propylcyclohexane
CCH-502: traps,traps-4-ethoxy-4'-pentylcyclohexyl-
cyclohexane
ECCP-32: 1-[traps-4-(traps-4-propylcyclohexyl)-
cyclohexyl]-2-(p-ethylphenyl)-ethane
ECCP-31: 1-[traps-4-(traps-4-propylcyclohexyl)-
cyclohexyl]-2-(p-methylphenyl)-ethane
ECCP-35: 1-[traps-4-(traps-4-propylcyclohexyl)-
cyclohexyl]-2-(p-pentylphenyl)-ethane
PCH-501: traps-1-p-methoxyphenyl-4-pentylcyclo-
hexane
PCH-502: traps-1-p-ethoxyphenyl-4-pentylcyclohexane
CP-33: p-propylphenyl trans,trans-4-propylcyclo
hexylcyclohexanecarboxylate
CP-35: p-pentylphenyl trans,trans-4-propylcyclo-
hexylcyclohexanecarboxylate
2o3~~sz
- 45 -
CP-43: p-propylphenyl trans,trans-4-butylcyclo-
hexylcyclohexanecarboxylate
,CP-45: p-pentylphenyl trans,trans-4-butylcyclo-
hexylcyclohexanecarboxylate
PTP-40F: 4-butoxy-4'-fluorotolan
PTP-50F: 4-pentoxy-4'-fluorotolan
PTP-70F: 4-heptoxy-4'-fluorotolan
PCH-301: traps-1-p-methoxyphenyl-4-propylcyclo-
hexane
CCH-301: traps,traps-4-methoxy-4'-propylcyclohexyl-
cyclohexane
CBC-33F: 4,4'-bis-(traps-4-propylcyclohexyl)-2-
fluorobiphenyl
CBE-55F: 4,4'-bis-(traps-4-pentylcyclohexyl)-2-
fluorobiphenyl
CBC-53F: 4-(traps-4-pentylcyclohexyl)-4'-(traps-4-
propylcyclcohexyl)-2-fluorobiphenyl (sic)
CBC-33: 4,4'-bis-(traps-4-propylcyclohexyl)-
biphenyl
CBC-55: 4,4'-bis-(traps-4-pentylcyclohexyl)-
biphenyl
CBC-53: 4-(traps-4-pentylcyclohexyl)-4'-(traps-4
propylcyclohexyl)-biphenyl
ECCP-33: 1-[traps-4-(traps-4-propylcyclohexyl)
cyclohexyl~-2-(p-propylphenyl)-ethane
CCH-51F: traps,traps-4-fluoromethyl-4'-pentyl-
cyclohexylcyclohexane
CCH-31F: traps,traps-4-fluoromethyl-4'-propyl-
cyclohexylcyclohexane
PTP-102: 4-methyl-4'-ethoxy-tolan
PTP-201: 4-methoxy-4'-ethyl-tolan
CPTP-301: 4-(traps-4-propylcyclohexyl)-4'-methoxy-
tolan
CPTP-302: 4-(traps-4-propylcyclohexyl)-4'-ethoxy-
tolan
CPTP-303: 4-(traps-4-propylcyclohexyl)-4'-propoxy-
tolan
PCH-5F: traps-1-p-fluorophenyl-4-pentylcyclohexane
PCH-6F: traps-1-p-fluorophenyl-4-hexylcyclohexane
203586?
- 46 -
PCH-7F: traps-1-p-fluorophenyl-4-heptylcyclohexane
EPCH-20CF3: 1-(traps-4-ethylcyclohexyl)-2-(p-tri-
fluoromethoxyphenyl)-ethane
EPCH-30CF3: 1-(traps-4-propylcyclohexyl)-2-(p-tri-
fluoromethoxyphenyl)-ethane
EPCH-50CF3: 1-(traps-4-pentylcyclohexyl)-2-(p-tri-
fluoromethoxyphenyl)-ethane
EPCH-70CF3: 1-(traps-4-heptylcyclohexyl)-2-(p-tri-
fluoromethoxyphenylj-ethane
PCH-30CF3: traps-1-p-trifluoromethoxyphenyl-4-propyl-
cyclohexane
PCH-50CF3: traps-1-p-trifluoromethoxyphenyl-4-pentyl-
cyclohexane
ECCP-30CF3: 1-[traps-4-(traps-4-propylcyclohexyl)-
cyclohexyl]-2-(p-trifluoromethoxyphenyl)-
ethane
ECCP-50CF3: 1-[traps-4-(traps-4-pentylcyclohexyl)-
cyclohexyl]-2-(p-trifluoromethoxyphenyl)-
ethane
CCP-20CF3: p-[traps-4-(traps-4-ethylcyclohexyl)-
cyclohexyl]-trifluoromethoxybenzene
CCP-30CF3: p-[traps-4-(traps-4-propylcyclohexyl)-
cyclohexyl]-trifluoromethoxybenzene
CCP-40CF3: p-[traps-4-(traps-4-butylcyclohexyl)-
cyclohexyl]-trifluoromethoxybenzene
CCP-50CF3: p-[traps-4-(traps-4-pentylcyclohexyl)-
cyclohexyl]-trifluoromethoxybenzene
BCH-30CF3: 4-trif luoromethoxy-4'-(traps-4-propyl-
cyclohexyl)-biphenyl
ECCP-3F. F: 1-[traps-4-(traps-4-propylcyclohexyl)-
cyclohexyl]-2-(3,4-difluorophenyl)-ethane
ECCP-5F. F: 1-[traps-4-(traps-4-pentylcyclohexyl)-
cyclohexyl]-2-(3,4-difluorophenyl)-ethane
CCP-3F. F: 4-[traps-4-(traps-4-propylcyclohexyl)-
cyclohexyl]-1,2-difluorobenzene
CCP-5F. F: 4-[traps-4-(traps-4-pentylcyclohexyl)-
cyclohexyl]-1,2-difluorobenzene
D-302FF: 2,3-difluoro-4-,~sthoxyphenyl traps-4-
propylcyclohexylcarboxylate
203586'
- 47 -
D-502FF: 2,3-difluoro-4-ethoxyphenyl traps-4-
pentylcyclohexylcarboxylate
CCP-3F: 4-[traps-4-(traps-4-propylcyclohexyl)-
cyclohexyl]-fluorobenzene
ECCP-3F: 1-[traps-4-(traps-4-propylcyclohexyl)-
cyclohexyl]-2-(p-fluorophenyl)-ethane
ECCP-5F: 1-[traps-4-(traps-4-pentylcyclohexyl)-
cyclohexyl]-2-(p-fluorophenyl)-ethane
CP-3F: p-fluorophenyl traps-4-(traps-4-propyl-
cyclohexyl)-cyclohexanecarboxylate
CP-5F: p-fluorophenyl traps-4-(traps-4-pentyl-
cyclohexyl)-cyclohexanecarboxylate
PYP-5F: 2-p-fluorophenyl-5-pentylpyrimidine
- PYP-6F: 2-p-fluorophenyl-5-hexylpyrimidine
PYP-7F: 2-p-fluorophenyl-5-heptylpyrimidine
PYP-30CF3: 2-p-trifluoromethoxyphenyl-5-propyl-
pyrimidine
PYP-50CF3: 2-p-trifluoromethoxyphenyl-5-pentyl-
pyrimidine
PYP-70CF3: 2-p-trifluoromethoxyphenyl-5-heptyl-
pyrimidine
PCH-3: p-traps-4-propylcyclohexyl-benzonitrile
PCH-4: p-traps-4-butylcyclohexyl-benzonitrile
PCH-5: p-traps-4-pentylcyclohexyl-benzonitrile
ECCP-3: 1-[traps-4-(traps-4-propylcyclohexyl)-
cyclohexyl]-2-(p-cyanophenyl)-ethane
ECCP-3CF3: 1-[traps-4-(traps-4-propylcyclohexyl)-
cyclohexyl]-2-(p-trifluoromethylphenyl)-
ethane
ECCP-5CF3: 1-[traps-4-(traps-4-pentylcyclohexyl)-
cyclohexyl]-2-(p-trifluoromethylphenyl)-
ethane
PYP-SN.F: 2-(3-fluoro-4-cyanophenyl)-5-pentyl-
pyrimidine
PYP-7N. F: 2-(3-fluoro-4-cyanophenyl)-5-heptyl-
pyrimidine
PCH-30CF2: traps-1-p-difluoromethoxyphenyl-4-propyl-
cyclohexane ,
203586?
- 48 -
PCH-50CFz: traps-1-p-difluoromethoxyphenyl-4-pentyl-
cyclohexane
PCH-3-OCFZ: traps-1-p-difluoromethoxyphenyl-4-propyl-
cyclohexane
BCH-5.F2: 4-(traps-4-pentylcyclohexyl)-2'-fluoro-4'-
ethylbiphenyl
K6: 4-ethyl-4'-cyanobiphenyl
K9: 4-propyl-4'-cyanobiphenyl
PTP-35: 4-propyl-4'-pentyltolane
ME2N.F: 3-fluoro-4-cyanophenyl 4-ethylbenzoate
ME3N.F: 3-fluoro-4-cyanophenyl 4-propylbenzoate
MESN.~': 3-fluoro-4-cyanophenyl 4-pentylbenzoate
PCH-2: p-traps-4-ethylcyclohexylbenzonitrile
PCH-7: p-traps-4-heptylcyclohexylbenzonitrile
PCH-32: traps-1-p-ethylphenyl-4-propylcyclohexane
CFET-3F: 1-(4-(traps-4-propylcyclohexyl)-2-fluoro-
4'-yl-biphenyl)-2-(4-fluorophenyl)-ethane
CFET-5F: 1-(4-(traps-4-pentylcyclohexyl)-2-fluoro-
4'-yl-biphenyl)-2-(4-fluorophenyl)-ethane
FET-3F: 1-(2-fluoro-4-propyl-4'-yl-biphenyl)-2-(4-
fluorophenyl)-ethane
FET-5F: 1-(2-fluoro-4-pentyl-4'-yl-biphenyl)-2-(4-
fluorophenyl)-ethane
CPTP-30CF3: 4-(traps-4-propylcylcohexyl)-4'-trifluoro-
methoxy-ethane (sic)
CPTP-50CF3: 4-(traps-4-pentylcylcohexyl)-4'-trifluoro-
methoxy-ethane (sic)
PTP-20F: 4-ethoxy-4'-fluorotolane
PYP-3F: 2-(4-fluorophenyl)-5-propylpyrimidine
PTP35: 4-propyl-4'-pentyltolane
PTP45: 4-butyl-4'-pentyltolane
BCH-52F: 4-(traps-4-pentylcyclohexyl)-2-fluoro-4'-
ethylbiphenyl
CP-302FF: 2,3-difluoro-4-ethoxyphenyl traps-4-
(traps-4-propylcyclohexyl)-cyclohexane-
carboxylate
PCH-301: traps-1-p-methoxyphenyl-4-propylcyclo-
hexane .
PCH-401: traps-1-p-methoxyphenyl-4-butylcyclohexane
20358 2
- 49 -
D-302: 4-ethoxyphenyl traps-4-propylcyclohexyl-
carboxylate
D-402: 4-ethoxyphenyl traps-4-butylcyclohexyl-
carboxylate
