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Patent 2103082 Summary

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(12) Patent Application: (11) CA 2103082
(54) English Title: SPINNERETTE PLATE FOR THE MANUFACTURE OF A MULTILOBAL FIBER WITH V-SHAPED ENDS
(54) French Title: FILIERE POUR LA FABRICATION D'UNE FIBRE MULTILOBEE A EXTREMITES EN V
Status: Dead
Bibliographic Data
(51) International Patent Classification (IPC):
  • D01D 4/02 (2006.01)
  • D01D 5/253 (2006.01)
(72) Inventors :
  • PORTER, WILLIAM D. (United States of America)
  • HOLLAND, TOMMY T. (United States of America)
(73) Owners :
  • BASF CORPORATION (United States of America)
(71) Applicants :
(74) Agent: ROBIC
(74) Associate agent:
(45) Issued:
(22) Filed Date: 1993-11-15
(41) Open to Public Inspection: 1994-05-17
Availability of licence: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): No

(30) Application Priority Data:
Application No. Country/Territory Date
976,814 United States of America 1992-11-16

Abstracts

English Abstract



Abstract

Described is a spinnerette plate for the manufacture of multilobal
fibers, comprising at least one opening having a plurality of
lobes, each lobe having two ends, one end being connected to the
other lopes, the other end of said lobes being V-shaped and
comprising two arms.

13


Claims

Note: Claims are shown in the official language in which they were submitted.



Claims:

1. A spinnerette plate for the manufacture of multilobal fibers,
comprising at least one opening having a plurality of lobes,
each lobe having two ends, one end being connected to the
other lobes, the other end of said lobes being V-shaped and
comprising two arms.

2. The spinnerette plate according to claim 1, wherein said lobes
radiating outwardly.

3. The spinnerette plate according to claim 1, wherein said
opening has three lobes.

4. The spinnerette plate according to claim 1, wherein said
opening has four lobes.

5. The spinnerette plate according to claim 3, wherein an angle
between said lobes is from about 70 to about 140°.

6. The spinnerette plate according to claim 5, wherein the angle
is from about 110 to about 130°.

7. The spinnerette plate according to claim 6, wherein the angle
is approximately 120°.

8. The spinnerette plate according to claim 4, wherein an angle
between said lobes is from about 70 to about 140°.

9. The spinnerette plate according to claim 8, wherein the angle
is from about 80 to about 100°.

10. The spinnerette plate according to claim 9, wherein the angle
is approximately 90°.

11

11. The spinnerette plate according to claim 1, wherein said lobes
have a length of from about 0.25 to about 1.0 mm, said arms
have a length of from about 0.2 to about 0.8 mm and said lobes
and said arms have a diameter of from about 0.04 to about
0.18 mm.

12. The spinnerette according to claim 11, wherein the length of
the lobes is from about 0.4 to about 0.85 mm, the length of
the arms is from about 0.3 to about 0.7 mm and the diameter of
the lobes and arms is from about 0.08 to about 0.12 mm.

12

Description

Note: Descriptions are shown in the official language in which they were submitted.


--~` 21a3~82
.
IN-4544 ;~

A SPINNER~TTE_~L~ FO~ ~EE_~A~E~CrQ~E OF
A MULTILO~AL FIB~R WITH V-SH~P~D ~NDS

Field of ~he Invention

The present invention is directed to a spinnerette plate for the
manufacture of a multilobal fiber with V-shaped ends for use as
carpet yarns.

Backaround of th~_Invention

Spinnerette plates for the manufacture of multilobal, in particular
trilobal, fibers and filaments are known in the art and have been
widely used, especially for the manufacture of carpet yarns. The -~ -
fibers manufactured by such spinnerette plates show superior - -
properties in bulk and covering power over fibers having round ~;~ ~ ' .~' .. ~"7'. ' ,''~
cross section.

U.S. Pat. No. 3, 19~,002 discloses a multifilament yarn having a
non-regular Y-shaped cross section.

V.S. Pat No. 4,648,830 discloses a spinnerette for producing hollow
trilobal cross-section filaments. ;~

U.S. Pat. No 5,108,838 discloses the trilobal and tetralobal
filaments exhibiting low glitter and high bulko ~he filaments
having substantial convex curves.

Disadvantage of the ~ilaments of the prior ar~ is that they can
pack together, requiring more fiber use to achieve adequate cover
in a carpet.


Express Mail Certificate TB086597599US datea 11/16/92



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Object of the present invention was to provide a spinneretta plate
with a simple geometry, which is easy to produce and which allows
the manufacture of fibers with a simple cross section, which
exhibits good bulk, uneven surface, high dullness, good soil hiding
properties and improved color.

Summary o~ the Inv~ntion

The object of the present invention could be achieved by a
spinnerette plate for the manufacture of multilobal fibers,
comprising at least one opening having a plurality of lobes, each -
lobe having two ends, one end being connected to the other lobes,
the other end of said lobes being V-shaped and comprising two arms.


Description of the Fi~ures
.: . . ,. :~:
Fig. 1 is a front view of a trilobal spinnerette capillary of the
prior art~

Fig. 1 (a) is a cross-sectional view of a fiber spun by a
spinnerette shown in Fig. 1.

Fig. 2 is a front view of a trilobal spinnerette capillary of the
present invention comprising a V-shaped end at each lobe.

Fig. 2 (a) is a cross-sectional view of a fiber spun by a
spinnerette shown in Fig. 2.

Fig. 3 is a front view of a tetralobal spinnerette capillary of the ~ ;
present invention compxising a V-shaped end at each lobe.; ~;-

Fig. 3 (a) is a cross-sectional view of a fiber spun by a


``~ ' 21~3~82 ``

spinnerette shown in Fig. 3.

Detailed Pescri~tion oP the Invention

The spinnerette plate of the present invention is suitable for the
manufacture of fibers by melt spinning.

Suitable polymers for the production of the fibers of the present
invention are all fiber forming thermoplastic materials especially
polyamides, polyesters, and polyolefins. Suitable polyamides are
nylon 6, nylon 6/6, nylon 6/9, nylon 6/10, nylon 6/12, nylon 11,
nylon 12, copolymers thereof and mixtures thereof. -~

Preferred polyamides are nylon 6 and nylon 6/6. A suitable
polyester is polyethylene terepthalate.

~he polymer is fed into an extruder in form of chips or granules,
melted and directed via DOWTHERM~ (Dow Chemical, Midland, Michigan)
heated polymer distribution lines to the spinning head. The
polymer melt is then metered by a highly efficient gear pump to a
spin pack assembly, and extruded through a spinnerette with
capillaries described below.

The spinnerette plate of the present invention has in general at -~
least one multilobal opening, like tri,~ tetra-, penta- or
hexalobal capillary, preferably tri- and tetralobal capillary.

The capillary of the spinnerette plate of the present invention is
described with reference to Fig. 2 for a trilobal opening:

Lobes (1) (2) and (3) have each two ends, (4), (5); (4), (6) and
(4) (7). On one end (4) the lobes are connected and radiating
outwardly to the second end of each lobe (5), (6) and ~7), ~hich is
V shaped with two arms each (8), (9); (10), (11) and (12) (13).
The angles between the lobes (1), (2) and (3) are from about 100 to


- ~ 2ia3~2 ;~ :
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about 140-, preferably about 120C. Fig. 2 is drawn with round arm
ends, but other shapes like rectangular or triangular may also be
used.

The dimensions of the different parts of the capillary of the
present invention are as follows: The length of the lobes (1)
(2) and (3) from one end (4) to the other end (5) (6) and (7) is
from about 0.25 to about 1.0 mm, preferably from about 0.4 to about
0.85 mm. The length of the arms from one end (5), (6) and (7) to
the other end (8), (9); (10), (11) and (12), (13) is from about 0.2
to about 0.8 mm, preferably from about 0.3 to about 0.7 mm. The
diameter of the lobes (1), (2) and (3) and the arms (8), (9); (lO),
(11) and (12), (13) are from about 0.04 to about 0.18 mm, -~
preferably from about 0.08 to about 0.12 mm.
.: - .. .. .:. - .
The tetralobal opening in the spinnerette plate according to Fig.
3 has four lobes (27), (28), (29) and (30).

On one end (31) the lobes are connected to each other and radiating
outwardly, the other end (32), (33), (34) and (35) of each lobe is
V-shaped with two arms (36) and (37), (38) and (39), (40) and (41)
and (42) and (43).

The angles between the lobes (27), (28), (29) and (30) are from
about 80 to 100, preferably about 90. The angles between the
arms (36) and (37), (38) and (39), (~0) and (41) and (42) and (43)
are from about 100 to about 140, preferably about 120~. Fig. 2 is
drawn with arm ends to roun~, but other shapes like rectangular or
triangular may also be used.

The dimensions of the different parts of the capillary are
:: - . ~
approximately the same as described for the trilobal opening. The ~ --
arm ends may be round, rectangular or triangular as described fox
the trilobal opening.

2 1 0 3 ~ 8 2

The disclosed dimensions are dependent for example on polymer type,
spinning temperature, melt-viscosity of the polymer and quench
medium temperature.
` '

The desired "modification ratio" for the resulting filaments is
also an important factor. By the term "modification ratio" (MR),
it is meant the ratio o~ the radius of a circle which circumscribes
the filament cross-section to the radius of the largest circle
which can be inscribed within the filament cross-section.

The two circles are shown as dotted lines in Fig. 2a. The
dimensions in the capillaries of the spinnerette plate are chosen,
that the MR for the cross-section of the resulting fiber is from
about 2 to about 5, preferably from about 3 to about 4.

The respective polymer is extruded through the capillary of the
spinnerette plate described in Fig. 2 or Fig. 3 to form a fiber
having a cross-section described in Fig. 2a or Fig. 3a.

The trilobal cross-section of the fiber according to Fig. 2a has
three lobes (14), (15) and (16) with two ends (17) and (18), (19)
and (20). On one end (17) the three lobes are connected to each
other and radiating outwardly to the other end of each lobe (18),
(19) and (20), which is V-shaped with two arms (21) and (22), (23)
and (24) and (25) and (26). ~ach of the V-shaped arms ideally are
shaped, like the filament of Fig. 2a. Fig. 2a is drawn with round
arm ends, but other shapes like rectangular or triangular may be
used.

The tetralobal cross-section of the ~iber according to Fig. 3(a)
has four lobes (44), (45), (46) and (47) with two ends (4~) and
(49), (50) (51) and (52). On one end (48) the lobes are connected
to each other and radiating outwardly to the other end of each lobe
(49), (50), (51) and (52), which is V-shaped with two arms (53) and
(54), (55) and (56) (57) and (58) and (59) and (60).


-- 2~3a82

The modification ratio (MR) for the trilobal cross-section is from
about 2 to about 5, preferably from about 3 to about 4

The MR for the tetralobal cross section is from about 2 to about 5,
preferably from about 3 to about 4.
.. ~ '
The spinnerette plate of the present invention has from about 30 to
about 300 openings in form of the capillaries, described above,
preferably from about 50 to about 200. In case of the manufacture
of staple fibers the spinnerette plate has from 30 to 500 openings,
preferably from about 100 to about 300.

The extruded fibers or filaments are quenched for example with air
in order to solidify the filaments. The filaments are then treated
with a finish comprising a lubricating oil or mixture of oils and
antistatic and antisailing agents. The filaments are then combined
to form a yarn bundle which is then wound onto a suitable package.

In a subsequent step, the yarn is drawn and texturized to form a
bulked continuous filament (BCF) yarn suitable for tufting into
carpets. A more preferred technique involves combining the
extruded or as-spun filaments into a yarn, then drawing,
texturizing and winding a package, all in a single step. This one~
step method of making 8CF is referred to in the trade as spin-draw-
texturing. The manufacture of staple fibers is also included in
the scope of the present invention.

Nylon filaments for the purpose of carpet manufacturing have
deniers (denier = weight in grams of 9000 meters of yarn) in the
range of about 3 to 75 denier/filament (dpf). A more preferred
range for carpet fibers is from about 15 to 25 dpf.
. ~ . .
From here, the BCF yarns can go through various processing steps
well known to those skilled in the art. ~he fibers of this
invention are particularly useful in the manufacture of carpets for


--` 21~3~82 i i
. .
floor covering applications.

To produce carpets for floor covering applications, the BCF yarns
are generally tufted into a pliable primary backing. Primary
backing materials are generally selected from the group comprising
conventional woven jute, woven polypropylene, cellulosic nonwovens,
and nonwovens of nylon, polyester, and polypropylene. The primary
backing is then coated with a suitable latex material such as a
conventional styrene-butadiene latex, vinylidene chloride polymer,
or vinyl chloride-vinylidene chloride copolymers. It is common
practice to use fillers such as calcium carbonate to reduce latex
costs. The final step is to apply a secondary backing, generally
a woven jute or woven synthetic such as polypropylene.

Fibers with a cross section according to the invention have
greater cover or lower bulk density, because they cannot be packed
more tightly together than the trilobal fibers of the prior art.
The less-packing geometry of the new cross sections also offer more
void space, thus more shadows and decreased luster of the carpet
fibers. Light entering the fixed voids defined by the geometric
shape has more difficulty reflecting to the observer without
striking one of the filament arms which are rigidly held in
position in the cross section.

Example 1~

Nylon 6 (relative viscosity R.V. = 2.68) bulked continuous filament
yarns were produced using conditions shown in Table 1 and a
spinnerette having a cross section shown in Fig. 2 with the
following dimensions:

Length of the lobes (1), (2) and (3): 0.5 mm
Length of the arms (8), (9), (10), (11), (12) and (13): 0.41 mm




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Diameter of the lobes and arms: 0.12 mm
Angle between the lobes: 120-
The molten polymer was extruded, solidified in a quench zone and
the undrawn yarn wound onto a package. The undrawn yarn was then
drawbulked. The yarn was drawn between two rolls (second roll-
heated). A heated draw pin was used between the two rolls. After
drawing, the yarns were bulked (textured ) with a steam jet and
wound on a package.

A control yarn (2.9 MR symmetric trilobal) was processed in a
similar manner. Tufted, heatset carpets (Superba) made from yarn
having the sectiol~ of the present invention exhibited higher bulk,
less luster and improved uniformity when compared to the control
yarn (Table 2).



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- ~-` 21~3~82

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Table 1
~xample 1 Control

Polymer RV (96% 2.68 2.68
Sulfuric acid) `

Spinning Temp~, C 270 270
~lowbox Air Volume, 240 160
CFM
Spinning Speed, 500 500
meters/min.
Polymer Output, 156 156 `
g~mln.
Finish on yarn, % -1.5 -1.5
Drawbulking Speed, 1500 1500
m/min.
Draw Ratio 3.1:1 3.1:1
Hot Pin Temp., C 90 90 ~;
Steam Jet Temp., C 210 210
Steam Jet Press., 75 75
psig -

t
2 ~ a 3 0 8 2
able.2
E~mple 1 Control

Denier (filaments) 1146 (6.8) 1135 (68) . -.
Tenacity, gms/den. 2.45 2.38 .
% Elongation 49.6 55.2 .
% Wet 8ulk 11.9 11.7
% 80iling Water 3.4 3-9 .
Shrinkage
Modification Ratio 3.37 2.9
Cylinder Bulk 4.87 4.69
cc./gm.

Carpet Evaluation
Example 1 Control ~. :.:.~.. :

Luster (1 = 6 5 . --~
brightest; 10 =
dullest)
Bulk (1 = least; 10 7.0 6.5 -~
= most)
Uniformity (1 = 7.0 5 5 .
least: 10 = best)

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Representative Drawing

Sorry, the representative drawing for patent document number 2103082 was not found.

Administrative Status

For a clearer understanding of the status of the application/patent presented on this page, the site Disclaimer , as well as the definitions for Patent , Administrative Status , Maintenance Fee  and Payment History  should be consulted.

Administrative Status

Title Date
Forecasted Issue Date Unavailable
(22) Filed 1993-11-15
(41) Open to Public Inspection 1994-05-17
Dead Application 1996-05-15

Abandonment History

There is no abandonment history.

Payment History

Fee Type Anniversary Year Due Date Amount Paid Paid Date
Application Fee $0.00 1993-11-15
Registration of a document - section 124 $0.00 1994-05-25
Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
BASF CORPORATION
Past Owners on Record
HOLLAND, TOMMY T.
PORTER, WILLIAM D.
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Description 1994-05-17 10 611
Drawings 1994-05-17 1 53
Claims 1994-05-17 2 102
Abstract 1994-05-17 1 44
Cover Page 1994-05-17 1 92