Note: Descriptions are shown in the official language in which they were submitted.
y4lAV 1~-Y~.~1~ CA 02345629 2001-03-26
t
Title of Invention
VACUUM FIELD-EFFECT DEVICE AND
FABRICATION PROCESS THEREFOR
Description
Technical Field
This invention relates to microelectronic devices and more particularly to a
vacuum-channel field-effect microelectronic device having a lateral field-
emission
source and preferably having insulated gate(s).
to This application is related to U.S. provisional application Serial No.
60/145,570 filed July 26, 1999, U.S. patent applications Serial Nos.
09/276,198 (now
U.S. Pat. No. 6,004,830), and 09/276,200, both filed March 25, 1999, and U.S.
patent
applications Serial Nos. 09/ 477,788 and 09/ 476,984, both filed December 13,
1999.
Nomenclature And Notations
Throughout this specification and the appended claims, the terms "lateral
emitter" or "lateral field-emission source" are used interchangeably to refer
to a field-
emission source disposed parallel to a substrate. For clarity and simplicity
of
expression, the terms "horizontal" and "vertical" are used herein to mean
parallel and
2o perpendicular to a substrate respectively, without implying any preferred
orientation
in space or any preferred orientation with respect to the earth's surface or
with respect
to the direction of a gravitational force. The acronyms "VFED" and "IGVFED"
are
used, referring to "vacuum field-effect device" and "insulated-gate vacuum
field-
effect device" respectively. The term "insulating," as in "insulating
substrate" or
"insulating layer," is used in its common meaning and particularly for
substances
characterized by a resistivity greater than 108 S2 - cm. The term "conductive"
refers
to substances characterized by a resistivity less than or equal to 108 S2 -
cm., i.e.,
including the resistivity range of both conductive and semiconductive
substances.
y'il H V 1-Yl.l CA 02345629 2001-03-26
r
Background Art
K. R. Shoulders described some vacuum integrated circuits in
"Microelectronics Using Electron-Beam-Activated Machining Techniques," in F.
L.
Alt (Ed.), "Advances in Computers," Vol. 2 (Academic Press, New York, 1961 )
pp.
135 - 197. An article, "Vacuum Integrated Circuits" by R. Greene et al.
(Technical
Digest of 1985 International Electron Devices Meeting [IEDM], IEEE,
Piscataway,
NJ, 1985, pp. 172 - 175), reviewed the physics and fabrication of vacuum
electronic
devices and showed a concept of a FET-like vacuum field emitter triode. The
field-
emission devices described by R. Greene et al. in that article required grid
biases of
to about 100 Volts and anode voltages of about 200 - 500 Volts. An article, "A
Vacuum
Field Effect Transistor Using Silicon Field Emitter Arrays" by Gray et al.
(Technical
Digest of 1986 International Electron Devices Meeting [IEDM], IEEE,
Piscataway,
NJ, 1986, pp. 776 - 779), described a vacuum field-effect transistor-like
device using
silicon field-emitter arrays. Another article by R. Greene et al., "Vacuum
Microelectronics, " (Technical Digest of 1989 International Electron Devices
Meeting
[IEDM], IEEE, Piscataway, NJ, 1989, pp. 89-15 - 89-19), described an
integrally
gridded field emitter array and an interdigitated silicon planar field emitter
array
vacuum FET.
An article by H. H. Busta et al., "Lateral Miniaturized Vacuum Device"
2o (Technical Digest of 1989 International Electron Devices Meeting [IEDM],
IEEE,
Piscataway, NJ, 1989, pp. 89-533 - 89-536), described two types of lateral
field
emitter triodes: one type with triangular shaped metallic emitters, a
collector
electrode, and an extraction electrode, and the other type with a tungsten
filament . v
emitter anchored to the sidewall of a polycrystalline silicon layer, a
collector
electrode, and an extraction electrode.
An article by W. J. Orvis et al., "A Progress Report on the Livermore
Miniature Vacuum Tube Project (Technical Digest of 1989 International Electron
Devices Meeting [IEDM], IEEE, Piscataway, NJ, 1989, pp. 89-529 - 89-531),
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R a
described methods of making miniature vacuum diodes and triodes with Spindt-
type
field emitters. The triodes of Orvis et al. had free-standing anodes and
grids.
An article by J. E. Cronin et al., "Field Emission Triode Integrated-Circuit
Construction Method," IBM Technical Disclosure Bulletin, Vol. 32, No. SB (Oct.
1989) pp. 242-243, described a process for fabrication of field-emission
triodes
having field-emission tips self aligned to a control grid.
An article by B. Goodman, "Return of the Vacuum Tube," Discover, March
1990, pp. 55 - 58, described progress and problems in development of vacuum
microelectronics. An article by S. Kanemura et al., "Fabrication and
Characterization
of Lateral Field Emitter Triodes," IEEE Transactions on Electron Devices, Vol.
38,
No. 10, Oct. 1991, pp. 2334 - 2336, described lateral field-emitter triodes
having an
array of 170 field-emitter tips with a 10-micrometer pitch, a columnar gate,
and an
anode.
An article by W. N. Carr et al., "Vacuum Microtriode Characteristics," J. Vac.
Sci. Technol., Vol. A8 (4), July/Aug 1990, pp. 3581 - 3585, described pentode-
like
I-V characteristics simulated for lateral vacuum microelectronic devices with
wedge-
shaped field-emission cathodes.
An article by A. A. G. Driskill-Smith et al., "The 'Nanotriode:' A Nanoscale
Field-Emission Tube," Applied Physics Letters, Vol. 75 No. 18 (Nov. 1, 1999),
pp.
2845 - 2847, described a nanoscale electron tube with a field-emission cathode
(vertical metal "nanopillars" with radii of about one nanometer), an
integrated anode,
and a control gate, all within vertical and horizontal dimensions of about 100
nm. An
article by P. Weiss, "Vacuum Tubes' New Image: Too Small to See," in Science
News, Vol. 156 (Nov. 6, 1999), summarized the vacuum tube development of
Driskill-Smith et al. and reports some comments of others skilled in this
field. An
article, "Vacuum Tubes Attempt a Comeback," in Physics Today, Dec. 1999, p. 9,
summarized some advantages of the vertically oriented devices of the Driskill-
Smith
et al. article and some remaining problems with that device design.
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c
Many prior U.S. patents have described vacuum microelectronic devices
(especially field-emission devices) and their fabrication processes, including
3,753,022 to Fraser, Jr.; 3,755,704 and 3,789,471 to Spindt et al.; 4,163,949
to
Shelton; 4,578,614 to Gray et al.; 4,721,885 to Brodie; 4,827,177 to Lee;
4,983,878
to Lee et al.; 5,007,873 to, Goronkin et al.; 5,012,153 to Atkinson et al.;
5,070,282 to
Epsztein; 5,079,476 to Kane; 5,112,436 to Bol; 5,126,287 to Jones; 5,136,764
to
Vasquez; 5,144,191 to Jones et al.; 5,214,347 to Gray; 5,221,221 to Okaniwa;
5,245,247 and 5,267,884 to Hosogi; 5,268,648 to Calcatera; 5,270,258 and
5,367,181 to Yoshida; 5,394,006 to Liu; 5,493,177 to Muller et al.; and
5,834,790
1o and 5,925,975 to Suzuki.
A number of prior U.S. patents have described microelectronic device
structures with lateral field-emission cathodes and fabrication processes for
such
structures, including Lee 4,827,177; Bol 5,112,436; Jones, et. al. 5,144,191;
Gray
5,214,347; Cronin et al. 5,233,263, 5,308,439, 5,312,777, and 5,530,262; Xie
et al.
5,528,099; Mandelman et al. 5,604,399, 5,629,580, 5,736,810, and 5,751,097;
and
Potter 5,616,061, 5,618,216, 5,628,663, 5,630,741, 5,644,188, 5,644,190,
5,647,998, 5,666,019, 5,669,802, 5,691,599, 5,700,176, 5,703,380, 5,811,929,
5,831,384, 5,850,123, 5,872,421, 5,920,148, 5,965,192, 6,004,830, 6,005,335,
6,015,324, 6,015,326, 6,017,257, 6,037,708, and 6,071,633.
2o There is a continuing need for ultra-high-frequency electronic devices. At
present, many of the needs for ultra-high frequency devices are met by
semiconductor
devices and integrated circuits. Since electron mobilities in semiconductor
devices
are reduced by carrier collisions with atoms of the crystal lattice, the
potentially better
high-frequency performance of miniature vacuum devices is attractive. Such
vacuum
devices, if made small enough and capable of operating at low-enough voltages,
with
sufficiently high and stable currents, will find a wide range of electronics
applications,
both digital and analog.
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Disclosure of Invention
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S o
An ultra-high-frequency vacuum-channel field-effect microelectronic device
(VFED or IGVFED) has a lateral field-emission source, a drain, and one or more
insulated gates. The insulated gates) is preferably disposed to extend in
overlapping
alignment with the emitting edge of the lateral field-emission source and with
a
portion of the vacuum channel region. If the gates) is omitted, the device
performs as
an ultra-high-speed diode. A preferred fabrication process for the device uses
a
sacrificial material temporarily deposited in a trench for the vacuum channel
region,
which is covered with an insulating layer cover. An access hole in the cover
allows
io removal of the sacrificial material. As part of a preferred fabrication
process, the
drain preferably acts also as a sealing plug, plugging the access hole and
sealing the
vacuum-channel region after the vacuum-channel region is evacuated.
Brief Description of Drawings
FIG. 1 is a partially cut-away perspective view of an insulated-gate vacuum
field-effect device made in accordance with the invention.
FIGS. 2a - 2 j are side-elevation cross-sectional views of the device in
various
stages of a preferred fabrication process.
FIG. 3 is a flowchart illustrating the steps of a preferred fabrication
process
performed in accordance with the invention.
2o Modes for Carrying Out the Invention
Disclosed herein is a new ultra-high-switching-speed vacuum field-effect
device (VFED). The charge carrier source for the VFED is an electron emitter
source
operable via Fowler-Nordheim emission. The channel region is a vacuum. Since
there is no material in the channel region to scatter the electrons and the
channel
length is short, the electron transit time is very short. There is no vacuum
path
between the source and gate or between the drain and gate. Therefore, a
relatively
high drain potential can be maintained without causing electron emission from
the
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gate. The high drain potential together with the short vacuum channel leads to
an
electron transit time on the order of sub-picoseconds. Furthermore, taking
into
account the very small parasitic capacitance terms (sub-
femtofarads/micrometer) of
the new VFED, in-depth calculations predict switching speeds up to 10
terahertz for a
0.5 micrometer vacuum channel length. For a 0.1 micrometer vacuum channel
length,
the calculated speed of the device is nearly 30 terahertz.
For applications where it is desirable to minimize the output impedance,
(rp = 8Vd/8Id @ Vg = constant), a very short vacuum channel length will allow
a
significant change in drain current due to the drain's potential influence on
the source
1o field. Here, Vd is the drain voltage, Id is the drain current, and Vg is
the gate voltage.
Furthermore, a number of individual devices arranged to be electrically in
parallel will
reduce the effective output impedance without diminishing switching speed. The
transconductance, (gm = 8Id/8Vg @ Vd = constant), can be high due to the
effective
close proximity of the gate to the source. The use of high dielectric-constant
insulators can aid the gate influence; however, the consideration of
increasing the gate
to source parasitic capacitance should be taken into account. The electric
permittivity
preferably has a value greater than two. The gain parameter, ( ~t = ~ 8Vd/8Vg
( @ Id
= constant), can be large due to the strong influence of the gate on the
channel current
with a vacuum channel length in the range of about equal to or greater than
0.5
micrometer.
FIG. 1 (not to scale) is a partially cut-away perspective view of an insulated-
gate vacuum-channel field-effect device 10 made in accordance with the
invention.
Device 10 is made on an insulating substrate 20. Source layer 60 (a lateral
field-
emission cold cathode with emitting tip 85) is parallel to substrate 20. While
FIG. 1
and the cross-section drawings 2f - 2 j show emitting tip 85 schematically as
having a
rectangular shape, the actual shape of the emitting tip 85 can be a very sharp
edge ,
i.e., an extremely small radius, as is known in the art of field-emission
cathodes. A
drain 150 collects electrons emitted from emitting tip 85 of source 60 when a
suitable
bias voltage is applied to source 60 and drain 150. Drain 150 is spaced apart
laterally
from emitting tip 85 of the source 60 by a spacing preferably between about
one
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nanometer and about one millimeter. Gates, preferably bottom gate 40 and top
gate
160, are disposed in at least partial alignment with emitting edge 85 of
source 60 and
extend to overlap a portion of a vacuum-channel region 120. A conductive
bottom-
gate contact 155 extends down and makes ohmic electrical contact with bottom
gate
40. Contact 155 is also connected to top gate 160 in the embodiment shown in
FIG.
1. The use of a recess in substrate 20 for bottom gate 40 allows for
planarization of
gate 40 and therefore provides for precise control and uniformity of the
thickness of
insulating layer 50 deposited over gate 40 in a preferred fabrication process,
described
in detail below. However, in other embodiments, gate 40 may be disposed on the
top
surface of substrate 20, without a recess.
An insulating layer between each gate and the vacuum channel region prevents
any electrons emitted by the source from reaching either gate, each gate being
completely separated from the vacuum channel region by its respective
insulating
layer (50 or combination of 70 with 100). Each of these insulating layers also
prevents any vacuum path between its corresponding gate and the drain 150, so
there
is no possibility of electron current flowing through the vacuum between
either gate
and the drain (for example, secondary electron current). It will be understood
that this
is also true for an IGVFED having only one gate instead of the two-gate
preferred
embodiment described and illustrated herein. In the embodiment of FIG. 1,
which has
2o two gates, the conductive contact 155 that interconnects them is also fully
insulated
from vacuum-channel region 120 by the insulators 50, 70, and 100. As shown in
FIG.
1, the dimensions of vacuum-channel region 120 are designed to prevent vacuum-
.
channel region 120 from extending back to the region of conductive contact
155.
A conventional passivation layer (not shown) may be deposited over device 10
to protect the device and to prevent surface leakage currents. Conventional
via-
openings may be formed and conventional terminal metallurgy (not shown) may be
deposited to contact the conductive elements shown in FIG. 1.
Thus, one aspect of the invention is a vacuum field-effect device 10 having a
source 60 comprising a lateral field-emitter with an emitting tip 85 for
emitting
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electrons, having a conductive drain 150 spaced apart laterally from the
emitting tip,
having a vacuum channel region 120 extending at least between the emitting tip
85 of
the source and the drain 150, having at least one gate 40 or 160, completely
separated
from the vacuum channel region by an insulating layer 50, 70, or 100 disposed
between the gate and the vacuum channel region 120 to prevent any electrons
emitted
by the source from reaching the gate, and having terminals (e.g., 140) for
applying a
bias voltage between the drain and source and for applying a control signal to
the gate.
The terminals may be integral with their respective electrodes, such as 150
and 160 in
FIG. 1. The device preferably has two electrically common gates 40 and 160,
which
to may be connected by an integrated conductive gate contact 155. The device
is
constructed on an insulating substrate Z0, which may consist of an insulating
film on a
conductive or semiconductive substrate.
Fabrication Process
The new terahertz vacuum field-effect device (VFED) is much simpler to
fabricate than compound semiconductor or heterojunction semiconductor devices.
No
semiconductor materials are used in the preferred embodiment. The structure
fabrication is, however, compatible with standard IC metallization,
passivation, and
interconnecting processing. Furthermore, the new device can be integrated with
either
variations of the preferred embodiment fabrication process or with other
integrated-
2o circuit fabrication processes.
An overall process for fabricating the vacuum field-effect device includes the
steps of providing a suitably flat insulating substrate, forming a source by
disposing a
lateral field emitter parallel to the substrate, forming an emitting tip on
the lateral field
emitter of the source, providing a conductive drain spaced apart laterally
from the
emitting tip for receiving electrons, forming a first opening for a vacuum
channel
region at least between the emitting tip and the drain, disposing at least one
gate in at
least partial alignment with respect to the emitting tip and in at least
partially
overlapping alignment with the first opening, substantially covering the first
opening
to form a closed vacuum channel chamber, removing any gases from the first
opening
3o to provide a vacuum, and sealing the vacuum channel chamber. The overall
process
_g_
941AVT-PCT ~ 02345629 2001-03-26
s ,
may also include the step of disposing an insulating layer between the gate
and the
vacuum channel region to prevent any of the electrons emitted by the source
from
reaching the gate, the gate being completely separated from the vacuum channel
region by the insulating layer. Terminals are added for applying a bias
voltage
between the source and drain and for applying a control signal to the gate.
The step of providing an insulating substrate may be accomplished by first
providing a base substrate, where the base substrate may have any degree of
conductivity or semiconductivity, and then depositing an insulating surface
layer on
the base substrate. Thus the base substrate may be a conductor, a
semiconductor, or
to any substance characterized by a resistivity of less than about 108 S2-cm.,
or an
insulator differing in composition from the insulating layer deposited on it.
For
example, the base substrate may be a metal, silicon, germanium, III-V
compounds
(GaAs, AIGaAs, InP, GaN, etc.), conducting oxides (e.g., indium tin oxide,
indium
oxide, tin oxide, copper oxide, or zinc oxide), transition metal nitrides, or
transition
metal carbides.
Within the framework of this overall fabrication process, many variations of
particular materials and specific process methods and their sequence may be
made.
The following description, read in conjunction with FIGS. 2a - 2 j and 3,
gives details
of a particularly preferred fabrication process. FIGS. 2a - 2 j are not drawn
to scale.
This description includes steps for providing two gates, but it will be
recognized that a
VFED device may be made with one or more gates and that the gates may be
omitted
to make a high-speed diode.
FIGS. 2a - 2j show a series of side-elevation cross-sectional views showing
the results of specific steps of the preferred process. FIG. 3 shows a flow
chart
representing the preferred fabrication process, in which steps are designated
by
reference numerals Sl, ..., S21. For each of these steps, the act performed is
listed in
Table I (following page). '
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941AVT-PCT ~ 02345629 2001-03-26
r
S1 Provide substrate
S2 Form a first trench
S3 Fill first trench with conducting layer and planarize
S4 Deposit first insulating layer
SS Deposit conductive material and pattern source
S6 Deposit second insulating layer
S7 Form second trench to define vacuum channel region ,
S8 Fill second trench with sacrificial material and planarize
1o S9 Deposit third insulating layer
S10 Form access hole through third insulating layer
S11 Form source via and bottom gate via openings
S12 Remove sacrificial material
S13 Provide vacuum environment
S14 Deposit and pattern conductive source contact
S15 Deposit and pattern conductive top gate
S16 Deposit and pattern conductive bottom gate contact
S17 Deposit and pattern conductive drain
S18 Seal vacuum-channel region
2o S19 (Combination of steps S14 through S18 performed together
simultaneously)
S20 If desired, deposit passivation
S21 If desired, form via holes and tenminal metallurgy
TABLE I. Process steps of FIG. 3
In step S1, a suitably flat insulating substrate 20 is provided. Insulating
substrate 20 may comprise any suitable insulating material such as glass,
ceramic,
glass ceramic, diamond, quartz, aluminum oxide, sapphire, silicon oxide,
silicon
nitride, aluminum nitride, nickel oxide, plastic, polymer, polyimide,
parylene,
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941AVT-PCT ~ 02345629 2001-03-26
polyethylene terephthalate, and mixtures and combinations thereof. As
mentioned
above, the flat insulating substrate 20 provided in step S1 may be made by
first
providing a conductive base substrate, such as a silicon semiconductor wafer,
and
depositing a surface layer of a suitable insulating material on the conductive
base
substrate to form an insulating surface. The insulating layer may be any of
the
insulating materials listed above, for example.
In step S2, a trench 30 is formed in the surface of the insulating substrate
(FIG.
2a). In step S3, trench 30 is filled with a conducting layer 40 and planarized
(FIG. 2b)
to form a first gate. The planarization may be done by chemical-mechanical
polishing
to (CMP). Some suitable materials for conducting layer 40 are aluminum,
copper, silver,
gold, platinum, palladium, bismuth, conducting oxides, conducting nitrides,
the
refractory transition metals (titanium, vanadium, chromium, zirconium,
niobium,
molybdenum, hafnium, tantalum, and tungsten), the refractory transition metal
carbides, the refractory transition metal nitrides, boron carbide, doped boron
nitride,
transition metal silicides, carbon in any of its conductive forms (e.g., doped
diamond,
graphite, amorphous carbon, fullerenes, nanotubes, or nanocoralline), silicon
(N - type
or P - type, polycrystalline, amorphous, or single-crystal), germanium, and
mixtures,
alloys, and combinations thereof. The conductive material is chosen to be
compatible
in processing with the other materials of the device.
Step S4 consists of depositing a first insulating layer 50 over the planarized
surface (FIG. 2c). First insulating layer 50 may comprise any suitable
insulator, such
as glass, glass ceramic, quartz, aluminum oxide, sapphire, silicon oxide,
silicon
nitride, barium strontium titanate, titanium oxide, samarium oxide, yttrium
oxide,
tantalum oxide, barium titanium oxide, barium tantalum oxide, lead titanium
oxide,
strontium titanium oxide, strontium (zirconium, titanium) oxide, aluminum
nitride,
polyimide, parylene, or mixtures and combinations thereof. The electric
permittivity E
of first insulating layer 50 preferably has a value greater than two.
In step S5, a conductive material is deposited and patterned to define a
source
layer 60 (FIG. 2d). In step S6, a second insulating layer 70 is deposited,
covering the
source layer 60 (FIG. 2e). Second insulating layer 70 may comprise any
suitable
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CA 02345629 2001-03-26
insulator, such as any of the materials used for first insulating layer 50
(glass, glass
ceramic, quartz, aluminum oxide, sapphire, silicon oxide, silicon nitride,
barium
strontium titanate, titanium oxide, samarium oxide, yttrium oxide, tantalum
oxide,
barium titanium oxide, barium tantalum oxide, lead titanium oxide, strontium
titanium
oxide, strontium (zirconiu;n, titanium) oxide, aluminum nitride, polyimide,
parylene,
or mixtures and combinations thereof). However, it is preferable that
insulating layers
50 and 70 consist of the same insulating material. The electric permittivity s
of
second insulating layer 70 preferably has a value greater than two.
A second trench 80 for a vacuum channel region is formed (step S7, FIG. 2f)
by etching at least through second insulating layer 70 and source layer 60,
but not
down as far as first gate layer 40. Trench 80 may be formed by directional
reactive
ion etching. Forming this trench also etches source layer 60 to form emitting
tip 85.
If necessary, further etching, such as an isotropic wet etch or plasma etch
may be used
to further etch emitting tip 85. As is known in the art of field-emission
cathodes, it is
desirable to form emitting edge 85 with an extremely small radius, to have a
very
sharp knife-edge shape. This is accomplished by depositing a very thin source
layer
60 in step S5, and then by etching the thin layer's edge in step S7. Suitable
conductive materials for source layer 60 are aluminum, copper, silver, gold,
platinum,
palladium, bismuth, conducting oxides, conducting nitrides, the refractory
transition
2o metals (titanium, vanadium, chromium, zirconium, niobium, molybdenum,
hafnium,
tantalum, and tungsten), the refractory transition metal carbides, the
refractory
transition metal nitrides, boron carbide, doped boron nitride, transition
metal silicides,
carbon in any of its conductive forms (e.g., doped diamond, graphite,
amorphous
carbon, fullerenes, nanotubes, or nanocoralline), silicon (N - type or P -
type,
polycrystalline, amorphous, or single-crystal), germanium, and mixtures,
alloys, and
combinations thereof. As is well known in the art, it is preferable to use a
material of
low work function, at least at emitting edge 85 of source layer 60.
In step S8, second trench 80 is filled with a sacrificial material 90 and
planarized (FIG. 2g). Sacrificial material 90 may be an inorganic material or
an
organic material such as parylene. A third insulating layer 100 is deposited
(step S9,
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941AVT-PCT ~ 02345629 2001-03-26
FIG. 2h). Third insulating layer 100 may comprise any suitable insulator, such
as any
of the materials used for first insulating layer 50 and second insulating
layer 70.
Insulating layer 100 preferably consists of the same insulating material as
insulating
layers 50 and 70 and preferably has an electric permittivity s of greater than
two.
In step S10, an access hole I10 is opened through third insulating layer 100
down at least into sacrificial material 90 (FIG. 2i). Access hole 110 is
preferably
made at or near the edge of trench 80 that is spaced farthest from emitting
tip 85. In
step S11, source via-opening 130 and a via-opening (not shown) for bottom gate
40
are formed. The bottom gate contact 155 (shown in FIG. 1) uses this bottom
gate via-
opening, which is out of the plane of the cross-sections of FIGS. 2a - 2j.
Optionally,
steps S10 and S11 may be combined and performed simultaneously, as indicated
in
FIG. 3 by a bracket joining these two steps. In step S12, sacrificial material
90 is
removed through access hole 110, e.g., by dissolving sacrificial material 90
with a
suitable solvent and removing the solution through access hole 110. For
example, if
the sacrificial material 90 is photoresist or wax, the solvent may be acetone.
If the
sacrificial material 90 is silicon dioxide, it may be removed by wet chemical
etching,
e.g., with HF. For many sacrificial materials, the removal process may be done
by
oxygen plasma etching. Removing the sacrificial material leaves an empty
vacuum
channel region 120. The next few steps may be performed in a vacuum
environment,
with a vacuum pressure preferably less than or equal to about one tort,
provided in
step S13.
In step S 14, a conductive source contact 140 is deposited and patterned. In
step S15, a conductive top gate 160 is deposited and patterned. In step S16, a
conductive bottom gate contact 155 (shown in FIG. 1) is deposited and
patterned. In
step S17, a conductive drain 150 is deposited and patterned. Suitable
conductive
materials for conductive top gate 160, conductive bottom gate contact 155, and
conductive drain 150 are aluminum, copper, silver, gold, platinum, palladium,
bismuth, conducting oxides, conducting nitrides, the refractory transition
metals
(titanium, vanadium, chromium, zirconium, niobium, molybdenum, hafnium,
tantalum, and tungsten), the refractory transition metal carbides, the
refractory
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941AVT-PCT ~ 02345629 2001-03-26
transition metal nitrides, boron carbide, doped boron nitride, transition
metal silicides,
carbon in any of its conductive forms (e.g., doped diamond, graphite,
amorphous
carbon, fullerenes, nanotubes, or nanocoralline), silicon (N - type or P -
type,
polycrystalline, amorphous, or single-crystal), germanium, and mixtures,
alloys, and
combinations thereof.
In step S18, access hole 110 is filled to seal the vacuum channel region 120.
This step S18 is preferably performed at a vacuum pressure of less than or
equal to
about one torr. When the vacuum channel region 120 is sealed, the channel
region
will be at vacuum. Steps S14 - S18 are preferably all performed together
simultaneously as a step S19, as indicated in Fig. 3 by a bracket. In this
preferred
process, access hole 110 also defines the pattern for the lower part of drain
150 (inside
vacuum chamber channel region 120). The resultant device after performing
steps
S14 - S18 or the combined step S19 is shown in the cross-sectional view of
FIG. 2j
and in the partially cut-away perspective view of FIG. 1. Alternatively to
this process,
forming conductive drain 150 and sealing vacuum channel region 120 may be
accomplished by the methods of U.S. Pat. No. 5,700,176 to Potter, the entire
disclosure of which is incorporated herein by reference. If desired, a
passivation layer
may be deposited (step S20) and via-openings formed and terminal metallurgy
deposited (step S21).
2o A person skilled in the art will recognize that simply by omitting those
process
steps for incorporating control gate elements 40 and 160, an ultra-high
frequency
diode structure is realized. If one of the control gate elements 40 and 160 is
omitted,
and the other included, the device will still operate as a triode.
The vacuum field-effect device of this invention may be made with very wide
ranges of dimensions and of material characteristics such as electric
permittivity of
insulators. For example, depending on the application, the vacuum channel
length
may be made between about one nanometer and about one millimeter. There are
wide
ranges of electric permittivities s, drain voltage values, tradeoffs with
coupling
capacitance, and enhancement vs. retardation mode of operation. The
thicknesses of
the insulating layers 50 and combination of 70 and 100 (i.e., the spacing of
the gates
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941AVT-PCT CA 02345629 2001-03-26
from source layer 60) is preferably chosen to be between about one nanometer
and
about 1000 nanometers when the electric permittivity of the insulating layer
is less
than or equal to 20, and the spacing is preferably chosen to be between about
10
nanometers and about 5000 nanometers when the electric permittivity of the
insulating layer is greater than 20.
Industrial Applicability
The device disclosed herein is particularly useful for high bandwidth
communication requirements. Such uses of the device include transmitting and
receiving data at the chip level, and thus, the device is suitable for short-
range intra-
LAN communication, wired or wireless. The device also inherently has high
thermal
tolerance and radiation resistance. It is therefore desirable for applications
in harsh
environments. These applications include sensor applications for fission or
fusion
reactors, borehole sensors, accelerator sensors and instrumentation,
applications in
satellites, deep space and extraterrestrial exploration vehicles, and many
other similar
applications.
Other embodiments of the invention to adapt it for various uses and conditions
will be apparent to those skilled in the art from a consideration of this
specification or
from practice of the invention disclosed herein. For example, additional gate
electrodes may be incorporated into the structures. For another example, the
device
2o may be fabricated on an insulating substrate comprising a suitable plastic
or other
polymer, which may be flexible and/or transparent, or conductive elements may
be
made of conductive polymers. Also, the order of the various fabrication
process steps ,
may be varied for some purposes, and some process steps may be omitted for
fabrication of the simpler structures. It is intended that the specification
and examples
be considered as exemplary only, with the true scope and spirit of the
invention being
defined by the following claims.
What is claimed is:
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