Note: Descriptions are shown in the official language in which they were submitted.
CA 02561033 2006-09-22
WO 2005/100689 PCT/FI2005/050118
1
Paper manufacturing process
The present invention relates to a method for manufacturing a web
comprising wood-based fibres and man-made fibres.
To improve the strength and/or dimensional stability of webs made of
wood-based fibres, it is possible to admix man-made fibres, i_e. syn-
thetic fibres or regenerated fibres, with wood-based fibres. W hile the
wood-based fibres used have an average fibre length of 1.2 mm, the
fibre length of man-made fibres used is usually in the order of 5 mm. In
the manufacture of the fibre, problems are caused by different fibre
lengths and also various other fibre properties. One problem is the
flocculation of the fibres in the headbox, resulting in poor form ation of
the web. Long fibres adhere to each other, and they also captu re short
fibres in the fibre bundles of the long fibres.
The flocculation tendency can be alleviated by reducing the consis-
tency of the pulp, but the production parameters may thus become
such that the production is not possible with conventional machinery
and/or the machine speeds must be dropped so low that the production
is not profitable. Attempts have also been made to manufacture multi-
layered paper, wherein diluted pulps can be run at a relatively high
speed. Furthermore, paper qualities of similar types have been shifted
to be manufactured by wet web formation with machinery for non-
woven fabrics. To sum up, it has been problematic to run webs com-
prising man-made fibres in paper machines, and attempts have been
made to solve this problem for about 30 years.
The method according to the invention is characterized in that a poly-
mer is added to a fibre suspension comprising wood-based fibres and
man-made fibres, to improve the web formation and to slow down the
removal of water in the wire section of the paper machine.
The above-mentioned problems can be reduced or eliminated by using
a polymer mixed in the pulp to improve the web formation and to slow
down the removal of water in the wire section of the paper rr~ achine.
The web can be manufactured by utilizing a normal paper machine
CA 02561033 2006-09-22
WO 2005/100689 PCT/FI2005/050118
2
construction, because there is no need to lower the consistency of the
pulp, and thus the size of the slice is sufficient for dosing the pulp onto
the wire. Typically, the consistency is about 1 % and the normal run-
ning speed is 800 m/min.
The improvement in the web formation is manifested by the smooth-
ness of the web. As the polymer slows down the exit of water,
mechanical means can be used to have an effect on the placement of
the fibres in the web. The mechanical means include, for example, the
intrinsic improvement in the web formation during dewatering, due to
the nature of the dewatering, because the fibres tend to move to loca-
tions with lower flow resistance and shear forces due to the speed dif-
ference between the headbox discharge and the wire. Other possible
improving mechanisms include shearing forces generated by shaking
of the wire and/or oscillation of the surface of the pulp layer. Further
mechanical means include the effect of suction boxes underneath the
forming wire, or it is possible to use a roll on the upper surface of the
forming wire to prevent the formation of fibre bundles.
The polymer to be used in the method according to the invention has a
high molecular weight and is relatively unbranched. The polymer is
preferably anionic.
Suitable polymers to be used include, for example, anionic polyacryl-
amide, CMC, guargum, or compounds of these. An anionic polyacryl-
amide suitable for the purpose has a molecular weight of at least
10,000,000 g/mol and an electric charge density of about 30 %, and it
is dosed 0.2 to 2 kg per ton of fibre. CMC has a molecular weight of at
least 750,000 g/mol, and it is dosed 2 to 8 kg per ton of fibre. During
the process, the dosage of the polymer can be reduced, because the
polymer hardly adheres to the fibre and is thus returned to use.
The pH value, at which the method works, is neutral or alkaline. The
pH of the fibre suspension is adjusted to at least 6.5, for the polymer to
function in the process. On the other hand, the polymer does not
function at too high a pH value either. The polymer is added either into
CA 02561033 2006-09-22
WO 2005/100689 PCT/FI2005/050118
3
the pulp mixing tank, before the machine screen, or after the machine
screen.
The method according to the invention is used primarily in the manu-
facture of wallpaper, particularly in connection with so-called paste-the-
wall wallpapers (the adhesive agent is applied onto the wall to be
papered and the dry wallpaper is placed onto the adhesive). In wall-
paper, the content of man-made fibres with a typical fibre length of
5 mm is often 10 weight-%, but in a wallpaper made by the method
according to the invention, the content may be 15 to 50 weight-%.
Normally, the rnan-made fibre to be used is polyester, because it has a
density suitable for manufacturing with pulp fibres. In the manufacture
of wallpaper, the method is cost-efficient, as the paper can be made
according to the conventional paper machine concept.
In addition to wallpaper, the method according to the invention can be
applied in products which are presently made by the wet web formation
technique, such as filter papers, dust bags for vacuum cleaners, wet-
strength towels, bed sheets and linen papers.
In the following, the invention will be described with reference to an
example and a figure. The figure illustrates the formation (Ambertec
formation) as a function of the consistency in the headbox.
An experiment was made to find out the effect of polyacrylamide and
CMC on the formation at different consistencies. The reference was a
sample to which no polymer had been added to improve the formation
and to slow down the dewatering.
The dosage of anionic polyacrylamide was 1 to 2 kg per ton of fibre.
The dosage of CMC was 5 to 10 kg per ton of fibre. The pH of the fibre
suspension in connection with acrylamide was from 7 to 8. The pH of
the fibre suspension in connection with CMC was from 7 to 8.
The invention is not restricted to the description above, but it may vary
within the scope of the claims.