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Patent 2578761 Summary

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(12) Patent Application: (11) CA 2578761
(54) English Title: COLD SHOCK METHOD IMPROVEMENTS
(54) French Title: AMELIORATIONS DE TECHNIQUE DE CHOC THERMIQUE
Status: Dead
Bibliographic Data
(51) International Patent Classification (IPC):
  • A23L 3/375 (2006.01)
  • A23B 4/09 (2006.01)
  • A23L 3/3454 (2006.01)
  • A23L 3/3481 (2006.01)
  • A23L 3/358 (2006.01)
  • A61L 2/00 (2006.01)
  • A61L 2/18 (2006.01)
(72) Inventors :
  • GIACOBBE, FREDERICK W.(DECEASED) (United States of America)
  • YUAN, JAMES T. C. (United States of America)
(73) Owners :
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCED ES GEORGES CLAUDE (France)
(71) Applicants :
  • L'AIR LIQUIDE SOCIETE ANONYME A DIRECTOIRE ET CONSEIL DE SURVEILLANCE PO POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
(74) Agent: LEDGLEY LAW
(74) Associate agent:
(45) Issued:
(86) PCT Filing Date: 2005-07-21
(87) Open to Public Inspection: 2006-03-09
Examination requested: 2007-03-01
Availability of licence: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): Yes
(86) PCT Filing Number: PCT/IB2005/002133
(87) International Publication Number: WO2006/024901
(85) National Entry: 2007-03-01

(30) Application Priority Data:
Application No. Country/Territory Date
10/933,736 United States of America 2004-09-03

Abstracts

English Abstract




The invention is a method of cooling objects by submerging in a fluid to
obtain a desired cooling effect. These objects can be either food or non-food.
The fluid can be liquid nitrogen, liquid argon, liquid oxygen, liquid carbon
dioxide, or any combination thereof. The fluid can include an additive that
helps sanitize the object. This additive can be oxidizing agents such as
ozone, chlorine, chlorine compounds, hydrogen peroxide solutions, ozonia
solutions, or combinations thereof. The submergence can be by way of an
automatic dipping process, or a continuous moving belt process. The regulation
can occur by varying speed or by maintaining a constant speed. The submergence
can be by way of total submergence, or only partial submergence, of the object
in the fluid. The desired effect can be to shock the surface microorganisms to
make them susceptible to concurrent or subsequent treatments.


French Abstract

La présente invention concerne une technique de refroidissement d'objets qui consiste à submerger un objet dans un fluide de façon à obtenir un effet de refroidissement recherché. Ces objets peuvent être alimentaires ou non alimentaires. Le fluide peut-être de l'azote liquide, de l'argon liquide, de l'oxygène liquide, du dioxyde de carbone liquide ou n'importe quelle combinaison de ces éléments. Le fluide peut comprendre un additif qui aide à assainir l'objet. Cet additif peut prendre la forme d'agents oxydants de l'ozone, du chlore, de composés chlorés, de solutions de peroxyde d'hydrogène, de solutions d'ozone ou des combinaisons de ces éléments. La submersion peut être effectuée au moyen d'un processus de trempe automatique ou d'un processus de courroie mobile continue. La régulation peut survenir par variation de la vitesse ou par le maintien d'une vitesse constante. Cette submersion de l'objet dans le fluide peut être effectuée de manière totale ou partielle. L'effet recherché peut consister en un choc pour les micro-organismes de surface, rendant ces derniers sensibles à des traitements simultanés ou subséquents.

Claims

Note: Claims are shown in the official language in which they were submitted.




7


CLAIMS

1. A method of rapidly cooling and sanitizing objects comprising:
a cooling process comprising submerging said objects in a fluid, wherein said
submergence is regulated to obtain a desired cooling effect and a sanitizing
process wherein the objects are exposed to one or more primary sanitizing
additives at one or more times selected from the group consisting of before
the
cooling process, during the cooling process, and after the cooling process.

2. The method of claim 1, wherein said objects are food objects.

3. The method of claim 1, wherein said objects are non-food objects.

4. The method of claim 1, wherein said fluid is selected from the group
consisting of
liquid nitrogen, liquid argon, liquid oxygen, liquid carbon dioxide, and
combinations thereof.

5. The method of claim 4, wherein said fluid further comprises one or more
initial
sanitizing additives.

6. The method of claim 5, wherein said one or more initial sanitizing
additives are
chemically different from said one or more primary sanitizing additives.

7. The method of claim 5, wherein said one or more initial sanitizing
additives are
chemically identical to said one or more primary sanitizing additives.

8. The method of claim 5, wherein said additive participates in a preliminary
sanitation process.

9. The method of claim 8, wherein said preliminary sanitation process occurs
before
the cooling of the object.



8


10. The method of claim 8, wherein said preliminary sanitation process occurs
during the cooling of the object.

11. The method of claim 5, wherein said initial sanitizing additive is
selected from the
group consisting of ozone, chlorine, chlorine compounds, hydrogen peroxide
solutions, oxonia solutions, and combinations thereof.

12. The method of claim 5, wherein said initial sanitizing additive is
selected from the
group consisting of organic substances, inorganic substances, a combination of

two or more organic substances, a combination of two or more inorganic
substances, and a combination of one or more organic substance and one or
more inorganic substance.

13. The method of claim 1, wherein said submergence is by way of an automatic
dipping process, or a continuous moving belt process.

14.The method of claim 1, wherein said regulation occurs by varying speed.

15. The method of claim 1, wherein said regulation occurs by maintaining a
constant
speed.

16. The method of claim 1, wherein said submergence comprises totally
submerging
said object in the fluid.

17. The method of claim 1, wherein said submergence comprises partially
submerging said object in the fluid.

18. The method of claim 1, wherein said desired cooling effect is to shock
surface
microorganisms to make them susceptible to a concurrent treatment.

19. The method of claim 1, wherein said desired cooling effect is to shock
surface
microorganisms to make them susceptible to a subsequent treatment.



9


20.The method of claim 1, wherein said desired cooling effect is to promote
the
destruction and inactivation of surface microorganisms without freezing the
object
throughout.

21. The method of claim 1, wherein said desired cooling effect is to promote
the
destruction and inactivation of surface microorganisms without cooling the
object
throughout.

22. The method of claim 1, wherein said desired cooling effect is to promote
the
destruction and inactivation of surface microorganisms and freeze the object
throughout.

23. The method of claim 1, wherein said desired cooling effect is to promote
the
destruction and inactivation of surface microorganisms and cool the object
throughout.

24. The method of claim 1, wherein the cooling process and the sanitizing
process
occur simultaneously.

25. The method of claim 1, wherein said primary sanitizing additive is
selected from
the group consisting of ozone, chlorine, chlorine compounds, hydrogen peroxide

solutions, oxonia solutions, and combinations thereof.

26.The method of claim 5, wherein said primary sanitizing additive is selected
from
the group consisting of organic substances, inorganic substances, a
combination
of two or more organic substances, a combination of two or more inorganic
substances, and a combination of one or more organic substance and one or
more inorganic substance.

Description

Note: Descriptions are shown in the official language in which they were submitted.



CA 02578761 2007-03-01
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COLD SHOCK METHOD IMPROVEMENTS
BACKGROUND
It is well known that chilling food products reduces bacterial growth and
retards the onset of spoilage, thereby increasing shelf life. However, in the
past 20
years, it has become known that some microorganisms have been able to adapt to
a
period of such chilled, low growth temperature. In response to this ability to
adapt,
recent investigations into the cold shock responses of various microorganisms
have
been conducted. It has been found that cold shocking can introduce stresses
affecting biological structures, which can fatally injure the microorganism,
or weaken
the microorganism and make it more susceptible to antibacterial or
disinfecting
agents. Various difficulties have been associated with the attempts that have
been
made so far to try to rapidly cool food and thereby effectively introduce such
a cold
shock procedure into food processing.

One attempt at using cryogenic liquids for cold shocking a food product is
described in U.S. Pat. No. 4,325,221, where animal carcasses are sprayed with
liquid nitrogen. This disclosure teaches that the surface membranes of the
carcass
are to be rapidly frozen in order to seal in the loss of moisture from the
carcass. The
principle desired effect is to reduce moisture loss from the product.

Another attempt is described in U.S. Pat. No. 4,367,630, where carcasses are
immersed into a tank of cryogenic fluid to crust-freeze the exterior. Again,
the
desired effect is to reduce valuable weight loss of the carcass.

Yet another attempt is described in U.S. Pat. No. 4,940,599, where the
surface of fresh meat is subjected to a cryogenic liquid just long enough to
form a
layer of ice, but not long enough to freeze the outermost, and innermost,
layers of
flesh on the carcass. The desired effect is to reduce spoilage in the
appearance of
the outermost layer of the flesh.

CONFIRMATION COPY


CA 02578761 2007-03-01
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2
Another attempt is described in U.S. Pat. No. 5,471,846, where a mass of
food product is introduced into a storage compartment, then into which an
amount of
cryogenic liquid is introduced, as a function of the weight of the food
product present.
The desired effect is to increase the overall efficiency of the chilling
process using
cryogenic liquids.

Another attempt is described in U.S. Pat. No. 5,577,392, where a cryogenic
chiller is disclosed that uses a vortical flow pattern. The desired effect is
to sweep
any liquid or solid cryogen from the bottom surface of the tunnel and
recirculate it
around the food product.

There is also a need to disinfect and sanitize non-food objects, such as
surgical, dental or laboratory instruments, prosthetic joints, dentures and
similar
objects. Traditional processes for sanitizing such objects have utilized
steam,
ethylene oxide, ionizing radiation, formaldehyde, and hot air. Within the past
decade, new processes have been introduced that include peracetic acid,
chlorine
dioxide, plasmas, and ultva-violet light.

Each of these references suffers from the disadvantage that either the germs
on the very surface, or just below the surface, of the object are not actually
cold
shocked. There is no control of the application of the fluid to obtain the
desired
effect of cold shocking the surface pathogens. There is no additive introduced
into
the fluid-.

For the foregoing reasons, there is a need for a method for cold shocking food
that allows control of the submerging of objects into a fluid to obtain a
desired
cooling effect. It would be an advance in the art of disinfection to couple
this
resulting cold shock effect with either the prior, concurrent, or subsequent
application
of an additive within the cryogenic fluid. There is a need in the industry for
such an
additive to further assist in the sanitation process.


CA 02578761 2007-03-01
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3
SUMMARY
The present invention is directed to a method that satisfies the need in
society
in general for a method for cold shocking food, or non-food objects, that
allows
control of the submerging of objects into a fiuid, wherein this fluid has an
additive, to
obtain a desired cooling effect. The present invention is also directed to a
method
that satisfies the need to combine this resulting cold shock effect with
either the prior,
concurrent, or subsequent application of an additive within the fluid, wherein
this
additive is preferably an aid to sanitation.

This method comprises a method of cooling objects by submerging the
objects in a fluid, where the fluid has an additive, and where the submergence
is
regulated to obtain desired cooling and sanitizing effects. These objects may
be
either food or non-food objects. The fluid may be liquid nitrogen, liquid
argon, liquid
oxygen, liquid carbon dioxide, or any combination thereof.
This additive may be something that participates in the desired sanitation
process of the object. The objects may be exposed to the disinfecting additive
prior
to, coincident with, or subsequent to the actual cooling treatment. The object
may
be exposed to the same, or different, additive before the cooling process,
then may
be exposed again during or after the cooling process. This additive may be an
ozidizing agent such as ozone, chlorine, chlorine compounds, hydrogen peroxide
solutions, oxonia solutions, or combinations thereof.

Oxonia is known to one skilled in the art to be a solution composed of either
hydrogen peroxide and peristaltic acid, or hydrogen peroxide and peroxyacetic
acid.
The submergence may be by way of an automatic dipping process, or a
continuous moving belt process. The regulation may occur by varying speed or
maintaining a constant speed. The submergence may be by way of total
submergence, or only partial submergence, of the object in the cryogenic
liquid.


CA 02578761 2007-03-01
WO 2006/024901 PCT/IB2005/002133
4
The desired cooling effect may be to shock the surface microorganisms to
make them susceptible to concurrent or subsequent treatments. The desired
cooling
effect may be to promote the destruction and/or the inactivation of the
surface
microorganisms without cooling or freezing the object throughout. The desired
cooling effect may be to promote the destruction and/or the inactivation of
the
surface microorganisms while cooling or freezing the object throughout.

These and other features, aspects, and advantages of the present invention
will become better understood with reference to the following description and
appended claims.
DESCRIPTION
Illustrative embodiments of the invention are described below. While the
invention is susceptible to various modifications and alternative forms,
specific
embodiments thereof are herein described in detail. It should be understood,
however, that the description herein of specific embodiments is not intended
to limit
the invention to the particular forms disclosed, but on the contrary, the
intention is to
cover all modifications, equivalents, and alternatives falling within the
spirit and
scope of the invention as defined by the appended claims.
It will of course be appreciated that in the development of any such actual
embodiment, numerous implementation-specific decisions must be made to achieve
the developer's specific goals, such as compliance with system-related and
business-related constraints, which will vary from one implementation to
another.
Moreover, it will be appreciated that such a development effort might be
complex
and time-consuming, but would nevertheless be a routine undertaking for those
of
ordinary skill in the art having the benefit of this disclosure.

The present invention relates to a cryogenic rapid chilling and sanitation
process in which a mixture of fluid and an additive is used to cold shock an
object.
In one embodiment of the invention the object is subjected to a cooling
process
wherein the object is submerged in the fluid for a time which is regulated to
obtain a


CA 02578761 2007-03-01
WO 2006/024901 PCT/IB2005/002133
desired cooling effect, an is subjected to a sanitizing process wherein the
objects are
exposed to one or more primary sanitizing additives either before, during or
after the
cooing process (or any combination thereof). In one embodiment of the
invention,
the liquid cryogen and additive are mixed prior to use in the chilling
process. In this
5 way, both the liquid cryogen and the additive may be directed to the object
simultaneously.

In another embodiment the object may be either food or non-food objects. In
another embodiment of the invention, the additive may be oxidizing agents such
as
ozone, chlorine, chlorine compounds, hydrogen peroxide solutions, oxonia
solutions,
or combinations thereof.

Oxonia is known to one skilled in the art to be a solution composed of either
hydrogen peroxide and peristaltic acid, or hydrogen peroxide and peroxyacetic
acid.
In another embodiment of the invention, the additive may be an organic
substance, an inorganic substance, a combination of two (or more) organic
substances, a combination of two (or more) inorganic substances, or a
combination
of one (or more) organic and one (or more) inorganic substance.
In another embodiment of the invention, the additive may be directed to the
object at a combination of prior to, simultaneous with, or subsequent to the
chilling
process, as desired by the operator. In another embodiment of the invention,
different additives may be directed to the object at differing times in the
chilling
process.

In another embodiment the object may be submerged into the additives one
or more times that are additive prior to, simultaneous with, and/or subsequent
to the
chilling process. In another embodiment of the invention, the object may be
submerged in different additives at different times during the chilling
process.


CA 02578761 2007-03-01
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6
In another embodiment of the invention, the rate that the objects are
submerged, and /or the duration of the submergence, in the additive may vary
with
time as a function of the progress of the chilling, or cold shock process.

In another embodiment of the invention, the rate that the objects are
submerged, and /or the duration of the submergence, in the additive may vary
with
discrete locations on the object to be chilled.

In one embodiment of the invention, the regulation of the rate that the
objects
are submerged, and/or the duration of this submergence, may be accomplished by
way of sensors, or weighing devices, or other techniques commonly known in the
industry.

In one embodiment of this invention, the regulation of the rate that the
objects
are submerged, and/or the duration of this submergence, may be accomplished by
way of sensors located on, or within the body of, the object to be cooled.

In another embodiment, the object to be chilled is subsequently introduced to
a chilling room, or a freezing room.
The invention is not limited to the preferred embodiments described above,
but rather defined by the claims set forth below.

Representative Drawing

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Administrative Status

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Administrative Status

Title Date
Forecasted Issue Date Unavailable
(86) PCT Filing Date 2005-07-21
(87) PCT Publication Date 2006-03-09
(85) National Entry 2007-03-01
Examination Requested 2007-03-01
Dead Application 2010-07-21

Abandonment History

Abandonment Date Reason Reinstatement Date
2009-07-21 FAILURE TO PAY APPLICATION MAINTENANCE FEE
2009-08-27 R30(2) - Failure to Respond
2009-08-27 R29 - Failure to Respond

Payment History

Fee Type Anniversary Year Due Date Amount Paid Paid Date
Request for Examination $800.00 2007-03-01
Registration of a document - section 124 $100.00 2007-03-01
Registration of a document - section 124 $100.00 2007-03-01
Application Fee $400.00 2007-03-01
Maintenance Fee - Application - New Act 2 2007-07-23 $100.00 2007-07-10
Registration of a document - section 124 $100.00 2007-11-20
Maintenance Fee - Application - New Act 3 2008-07-21 $100.00 2008-06-17
Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCED ES GEORGES CLAUDE
Past Owners on Record
AMERICAN AIR LIQUIDE, INC.
GIACOBBE, FREDERICK W.(DECEASED)
L'AIR LIQUIDE SOCIETE ANONYME A DIRECTOIRE ET CONSEIL DE SURVEILLANCE PO POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
YUAN, JAMES T. C.
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Claims 2007-03-01 3 109
Abstract 2007-03-01 1 66
Description 2007-03-01 6 273
Cover Page 2007-05-14 1 40
PCT 2007-03-01 4 135
Assignment 2007-03-01 10 315
Correspondence 2007-05-18 1 48
Assignment 2007-11-20 11 338
Prosecution-Amendment 2009-02-27 4 139