Note: Descriptions are shown in the official language in which they were submitted.
I
CATHODIC CORROSION PROTECTION SYSTEM WITH REBAR MOUNTING
ASSEMBLY
This invention relates to a method and/or an anode assembly for
cathodically protecting and/or passivating a metal section in an ionically
conductive
material using an anode assembly a cell or battery of cells to provide a
voltage and
more particularly to a mounting assembly for attachment of the anode assembly
to
the reinforcing bar.
BACKGROUND OF THE INVENTION
Impressed current systems using a battery are known.
Such
impressed current systems can use other types of power supply including common
rectifiers which rectify an AC voltage from a suitable source into a required
DC
voltage for the impressed current between the anode and the steel. It is also
known
to provide solar panels to be used in a system of this type.
In all cases such impressed current systems require regular
maintenance and checking of the status of the power supply to ensure that the
power supply does not fail leading to unexpected and unacceptable corrosion or
overprotection of the steel within the structure to be protected. While such
maintenance can be carried out and the power supply thus ensured, this is a
relatively expensive process.
Alternatively galvanic systems can be used which avoid necessity for
any power supply since the voltage between the steel and the anode is provided
by
selecting a suitable material for the anode which is sufficiently electro-
negative to
Date Recue/Received date 2020-04-13
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ensure that a current is generated to provide corrosion protection. These
systems
have obtained considerable success and are widely used.
There are two primary limitations of ordinary galvanic anodes as used
in steel reinforced concrete. The first relates to the mass of zinc per anode
which,
depending on the required current output, limits the useful life of the anode.
The
second is the actual current output of the anode which may or may not be
sufficient
to halt corrosion of the steel. The current output is limited by the driving
voltage,
which is essentially a fixed property and varies with exposure conditions, age
of the
anode, and build-up of corrosion products over time.
Reference is also made to US patents 8961746 (Sergi) issued
February 24th 2015, 8968549 March 3 2015 (Sergi) and 7264708 (Whitmore) issued
September 4 2007 all issued to the present assignees the disclosures of which
may
be referenced for more relevant information.
SUMMARY OF THE INVENTION
According to one aspect of the invention there is provided an anode
assembly for use in a reinforced structure comprising:
an ionically conductive concrete or mortar material;
a generally cylindrical metal reinforcing bar embedded in the concrete
or mortar material;
an exterior surface of the generally cylindrical metal reinforcing bar
being in direct connection with the concrete or mortar material for flow of
ionic
current therebetween,
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the anode assembly acting to protect and/or passivate the generally
cylindrical metal reinforcing bar and comprising:
an anode at least partly embedded within the concrete or mortar
material and ionically connected to the concrete or mortar material so that a
voltage
difference is generated between the anode and the generally cylindrical metal
reinforcing bar so as to cause a current to flow through the concrete or
mortar
material between the anode and the generally cylindrical metal reinforcing bar
so as
to provide cathodic protection of the generally cylindrical metal reinforcing
bar;
and a mounting assembly fixedly mounting the anode on the
generally cylindrical metal reinforcing bar so as to be supported by the
generally
cylindrical metal reinforcing bar within the concrete or mortar material and
electrically
connected to the generally cylindrical metal reinforcing bar such that the
electrical
current flows from the anode to the generally cylindrical metal reinforcing
bar;
the mounting assembly comprising:
an elongate male threaded rod attached to and extending
forwardly from the anode and having a forward end of the elongate male
threaded
rod forward of the anode, the elongate male threaded rod being electrically
conductive so that the forward end is in electrical connection with a first
surface
portion of the exterior surface of the generally cylindrical metal reinforcing
bar;
a female threaded nut member into which the elongate male
threaded rod engages;
an electrically conductive member extends from the female
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threaded nut portion angularly of the generally cylindrical metal reinforcing
bar at
least to a position on the generally cylindrical metal reinforcing bar
generally
diametrically opposed to said first surface portion to form at a least portion
of the
electrically conductive member in engagement with a second surface portion of
the
generally cylindrical metal reinforcing bar at said position;
the female threaded nut being arranged such that rotation of the
elongate male threaded rod therein acts to draw said at least a portion of the
electrically conductive member in engagement with the second surface portion
toward the forward end of the elongate male threaded rod in engagement with
the
first surface portion for clamping the generally cylindrical metal reinforcing
bar
therebetween;
wherein the electrically conductive member includes at least two
further surface portions each angularly spaced around the generally
cylindrical metal
reinforcing bar to respective sides of said second surface portion;
each said further surface portion being in direct electrical connection
with a respective portion of the exterior surface of the generally cylindrical
metal
reinforcing bar.
In accordance with one important feature of the invention which can be
used with any of the arrangements herein, the anode body is attached to the
elongate rod or first abutment member so that rotation of the anode body
drives
rotation of the forward end of the elongate rod member relative to the first
face of the
bar.
Date Recue/Date Received 2020-07-22
.
,
In this arrangement preferably the forward end of the elongate rod
member includes one or more projections for biting into the bar. This can be
provided by an outer circular edge of the end of the rod or by one or more
projections on the faces itself.
5
In accordance with one important feature of the invention which can be
used with any of the arrangements herein, the elongate rod member is threaded
at
least partly along it length so as to act as a screw to drive a female
threaded portion
of the second abutment member in a direction toward the anode body.
In accordance with one important feature of the invention which can be
used with any of the arrangements herein, the hook member includes a female
threaded portion for engaging the elongate rod member to draw together the
forward
end of the rod member or first abutment and the hook member or second abutment
for clamping the metal reinforcing bar therebetween.
Preferably the female threaded portion is fixed to the hook member so
that rotation of the rod member causes the hook member to move toward the
anode
body. However other arrangements can be used where the female portion
comprises a nut which rotates on the screw relative to the second abutment so
as to
drive the second abutment toward the anode body.
In accordance with one important feature of the invention which can be
used with any of the arrangements herein, the hook member or second abutment
engages the elongate rod member at a position spaced from the anode body to
prevent contact between the surface of the anode body and the metal bar. This
is
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particularly important where the anode is powered by a cell or the power
supply
forming part of the anode body so as to prevent shorting of the power supply
to the
metal bar.
In accordance with one important feature of the invention which can be
used with any of the arrangements herein, the elongate rod member is rigidly
coupled to the anode body to fixedly hold the anode body at a predetermined
distance and orientation relative to the bar. In this way the anode body can
be
located on the bar before pouring of the concrete or other material. Thus the
anode
body is held at a required position relative to the bar and to other adjacent
bars to
better locate an array of anodes relative to the bars. Alternatively the hook
member
may be rigidly coupled to the anode body and a threaded elongate member may be
used to hold the anode body at a predetermined distance and orientation
relative to
the bar.
The arrangements disclosed herein can be used with an anode body
which includes an anode of a material which is less noble than the metal bar
so that
it is sacrificial.
Alternatively in other embodiments the voltage difference is generated
by a storage component of electrical energy with two poles for communicating
electrical current generated by release of the electrical energy and by
electrically
connecting one pole to the metal bar and by electrically connecting the other
pole to
an anode on the anode body.
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The arrangements above this provide a mechanical clamp for the
anode body onto the reinforcing bar. This arrangement can provide the
following
advantages:
The contacts act to bite into reinforcing steel;
The contacts make good connection even if surface of the bar is not
clean such as contaminated with rust or concrete residue.
The clamp is adjustable to different bar sizes/diameters and
sizes/roughness caused by corrosion.
The clamp creates a rigid attachment.
The clamp supports the anode body at a spaced position from
connection point.
The mounting arrangement promotes more uniform current distribution
since the anode is held at a position not very close to one bar and therefore
passes
current more uniformly because of reduced differences in resistance.
The clamp does not easily rotate around steel bar like a wire wrap
connection.
The clamped connection does not loosen as a result of any rotation of
the anode body relative to the bar.
Anode body does not rotate/fall to down position due to gravity
The mechanical clamp allows the installer to position the anode on a
selected bar within the section of concrete/mortar to be cast.
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The connector allows anodes to be manufactured with a standard
threaded rod as the first abutment.
In an arrangement using a power supply, the connection acts to firmly
connect one pole of the supply to the reinforcing steel and ensure the other
pole is
spaced and will not contact the steel as this would cause a short circuit,
drain the
battery and provide no corrosion protection to the steel.
Different connectors can be provided for different size ranges.
Teeth or knife / sharp edges can be provided on an inside opening of a
cavity defined by the hook member to bite into the reinforcing bar.
A concave end and additional teeth on the end of the threaded rod can
act to cut into reinforcing bar.
These features ensure secure rigid, physical and electrical connection.
Also described herein there is provided an anode assembly for use in
cathodically protecting and/or passivating a metal section in an ionically
conductive
material, comprising:
an anode for communication of an ionic current to the metal section in
the ionically conductive material;
a storage component of electrical energy with first and second poles
for communicating electrical current generated by release of the electrical
energy;
a connector for electrically connecting the first pole to the metal
section;
the second pole being connected to the anode;
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the anode being arranged to be mounted in ionic contact with the
ionically conductive material such that the ionic current can flow from the
storage
component through the anode to the metal section;
and an electrical component which limits the current to a maximum
value.
In this arrangement preferably subject to the maximum voltage
available from the storage component the current is allowed to vary by the
electrical
components from the maximum to a lower value dependent on conductivity through
the ionically conductive material so that the components act as a limiter but
not a
regulator. In this way the power draw by the limiter can be kept very low. The
current is not sustained at a higher value than the natural value which will
occur due
to the voltage of the electrical component and the resistivity of the system.
In this way the electrical components act to extend the life of a battery,
or other power supply system, or galvanic anode system as these have limited
capacity and do not function after limited capacity is consumed.
Preferably the electrical components comprise a transistor where a
current through the transistor is limited to the maximum. The transistor can
be a
conventional transistor or a FET. In this arrangement preferably the
electrical
components use a voltage difference between the first and second poles or
between
the anode and the metal section as a reference voltage for the transistor. Of
course
this draws very little current so that the electrical components are arranged
to
consume power of 1pA or less. In this way the circuit can be very simple and
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consist solely of a transistor and a resistor. Other low power limiters can be
used
but typically higher power regulators are not suitable as they draw more
current than
is saved by limiting the current between the anode and the rebar. In addition
in
another arrangement there is provided a second sacrificial anode and the
electrical
components use a voltage difference between two anodes and a resistor to
generate
a reference current for the electrical component.
Typically the current can be limited to the maximum value to within +/-
20%,10%, 5%, 2% depending on the stability of the voltage source, the gain of
the
transistor and the resistance of the resistor.
Preferably the electrical components form part of a combined unit
which includes the anode and a connector for connection to the reinforcing
bar, for
example an arrangement of the type as described above.
Preferably the current limiter described above is associated with and
operates only in respect of a single anode and is not part of a larger system
limiting
or regulating current to a plurality of anodes.
In one particularly preferred method, the anode is installed and
connected to the metal section while the ironically conductive material is
unset and
the limitation of the current by the electrical components prevents gas
generation
during curing of the ionically conductive material. The generation of gases
during
setting is a severe problem in that it forms bubbles in the concrete.
The arrangement described herein can be used in a system where the
voltage difference is generated by a storage component of electrical energy
with two
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poles for communicating electrical current generated by release of the
electrical
energy and by electrically connecting one pole to the metal section and by
electrically connecting the other pole to the anode. However the same current
limiting system and the same mechanical connection can be used with
sacrificial or
galvanic anodes and also with combined systems where there is both an
impressed
current anode driven by a power supply and a separate sacrificial anode.
In this arrangement, preferably the anode and the storage component
are both at least partly contained in or buried in the ionically conductive
material,
typically concrete.
In this arrangement preferably the storage component is connected as
a single unit with an impressed current or non-sacrificial anode and/or with a
sacrificial anode.
In this arrangement preferably the storage component is contained
within a closed or sealed canister defining the anode on an exterior surface.
In this
case the anode can be formed of stainless steel.
In this arrangement in some cases in order to provide a longer life
replacement electrical energy can be introduced by re-charging the storage
component or by replacing the storage component.
The storage component can be a cell or battery of cells or can be a
capacitor.
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The arrangement therefore described above provides an arrangement
which acts to limit the current between the anode and the reinforcing bar.
This
arrangement can provide one or more of the following features:
It acts to regulate current from a battery or galvanic anode.
It uses the voltage difference across the poles of the energy storage
device or between the energy storage device and the steel or between the
galvanic
anode and the steel as a reference voltage.
It provides a simple limiting system typically formed of two components
only including a conventional transistor or FET and a resistor which
determines the
regulating voltage of the transistor.
The circuit consumes almost no power and may be as low as 1pA or
less.
This is ideal for battery or galvanic anode systems as these have
limited capacity (limited stored energy) and do not function after limited
capacity is
consumed.
The current can be limited over wide range of circuit resistances from
short circuit to resistance where the available voltage is sufficient to
result in the set
current value.
The current can be regulated to within + 20%, 10%, 5%, 2% depending
on the stability of the voltage source (battery/anode).
The current limiter can be part of a combined unit which includes
battery or capacitor or anode and connector.
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The current limiter allows batteries/high output anodes to be installed
and connected to the steel in fresh concrete/mortar without detrimental
effects of
high current densities discharging through the low resistance fresh material.
Can be
used to prevent gas generation (oxygen and hydrogen) during curing which will
create gas bubbles, voids, reduce bond to the steel and leave
pores/capillaries in the
concrete/mortar. Pores/cavities allow direct path to steel for water and salts
to
penetrate and CO2 to carbonate the concrete. All of which lead to premature
corrosion of the steel.
Where, as stated above the anode is not sacrificial to the metal
section, typically the material is therefore electropositive relative to the
metal section.
However some part of the anode may be sacrificial or the anode may be fully
sacrificial.
The arrangement herein can be used where the anode is in the form of
a plurality of associated anodes all connected to the cell or battery of
cells.
The storage component as defined above can be a cell or battery or
battery of cells / batteries or it can be a capacitor or a supercapacitor or
ultracapacitor which provides a system for storing charge different from
conventional
electrolytic cells or batteries. A supercapacitor is a high-capacity
electrochemical
capacitor with capacitance values much higher than other capacitors. These
capacitors typically have lower voltage limits than standard or conventional
capacitors. They typically store 10 to 100 times more energy per unit volume
or
mass than standard capacitors, can accept and deliver charge much faster than
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batteries, and tolerate many more charge and discharge cycles than
rechargeable
batteries. Supercapacitors do not use the conventional solid dielectric of
standard
capacitors. They use electrostatic double-layer capacitance or electrochemical
pseudo-capacitance or a combination of both instead. Electrostatic double-
layer
capacitors use carbon electrodes or derivatives with much higher electrostatic
double-layer capacitance than electrochemical pseudo-capacitance, achieving
separation of charge in a Helmholtz double layer at the interface between the
surface of a conductive electrode and an electrolyte. The separation of charge
is of
the order of a few angstroms (0.3-0.8 nm), much smaller than in a conventional
capacitor.
Supercapacitors are a great advancement on normal capacitors being
capable of storing a high charge once fully charged. The capacity of a 2.7V
200F
supercapacitor is capable of holding a charge of the order of over 500C (A x
seconds). Typical cathodic protection systems require around 170 to 400C/m2 of
steel per day so such a capacitor is able to provide, when fully charged,
enough
charge to protect 1m2 or more of steel for a day. This represents 2-5mA/m2
current
density. In order for example to double this figure then we need to double the
capacitance to around 400 F. If the capacitor is recharged on a daily basis,
then
logistically a system utilising supercapacitors of this size spaced at
intervals to
provide current for 1m2 or more of steel can be an effective cathodic
protection
system. Daily recharging can easily be provided by solar panels, for example,
but
other means of producing reasonably regular bursts of current could be used as
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charging components for the supercapacitors. An example of such could be
piezoelectric materials which can be incorporated in roads, parking garages,
bridges, runways etc. enabling current to be generated by loading and / or
movement of the structure or vehicles passing over them.
That is, piezoelectric materials could be used to generate electricity to
power an impressed current system directly, or to charge / recharge batteries
or
capacitors / supercapacitors.
In some embodiments the anode is a sacrificial anode formed of a
material which is less noble than the metal section to be protected. However
in
other cases the anode is not less noble than the metal sections to be
protected so
that it is the same as the metal, typically steel or is more noble than the
steel; so that
it is partially or fully inert during the process. If the anode is formed of a
sufficiently
inert material anode it does not corrode significantly during the flow of the
electrons.
High current output is required from the storage component such as a
battery. As described above, one pole is connected to the metal section to be
protected. Electrons flow from the storage component to the metal section such
that
corrosion of the metal section is reduced. The other pole is connected to an
anode
or if suitable, the casing of the storage component itself can be used as the
anode.
In the case of a zinc-alkaline battery the polarity of the battery is such
that the case
of the battery, if it is made of a suitable material will act as the anode and
will be able
to distribute the necessary current through the ionically conductive material
such as
mortar or concrete. Other batteries, such as most lithium batteries, typically
have
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only a small pole which has the proper polarity which may not be large enough
to
deliver the required current into the ionically conductive material. A
separate anode
can be provided for connection to the appropriate pole. The anode may encase
or
coat the whole storage component such as a battery or capacitor. Anodes can be
made of any inert conductive material such as MMO coated titanium or other
noble
metal or sub-metal, conductive coating, conductive ceramic material etc. and
can be
embedded in an alkaline mortar or an inert material such as sand which may be
dosed with an alkali solution. Stainless steel can also be a suitable current
carrier
when embedded in mortar or compacted sand dosed with alkali such as a
saturated
solution of lithium hydroxide. Anodes may also comprise sacrificial materials
such as
zinc which are less noble than the metal section to be protected.
Preferably in some embodiments the storage component is initially
charged or is subsequently re-charged while in situ that is while in contact
with the
ionically conductive material. The arrangement may include or preferably
includes
automatic switching systems to effect the periodic charging process. For
example
the storage component can be charged by a solar cell or by an outside power
source
such as a second battery or a power supply. Also in some cases there may be
provided a system which operates to subsequently automatically and repeatedly
or
periodically carry out the re-charge.
In another case, the storage component is subsequently re-charged by
a recharging power supply which is an integral unit with the anode and the
storage
component. However the system also may operate as a periodic maintenance
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programme where a power supply is brought into operation periodically as
required
to effect the re-charging of an anode assembly or a set of anode assemblies in
a
structure.
Preferably the storage component is subsequently re-charged by
applying voltage directly between both terminals or between a first connection
to a
terminal of the storage component and a second connection to the metal
section.
In one arrangement the anode comprises sacrificial anode material, or
the anode, which is sacrificial to the metal section, is collated with or in
electrical
contact with a body of sacrificial anode material which gives a boost of
current until
the sacrificial anode material is consumed, following which the current
discharge is
through the anode.
In one arrangement storage component is connected to the metal
section and is charged, in an initial charging step or in a subsequent re-
charging,
after installation by a connection to the one terminal and a second connection
to the
metal section. This method of connection acts to pass extra current to the
metal
section during the charging or re-charging step to passivate the metal section
or
reduce future current requirement to maintain passivity or mitigate corrosion
of the
metal section.
Typically the single unit comprising the storage component and the
anode or anodes is at least partly buried in the ionically conductive
material.
However application to the surface or other modes of mounting where the anode
is
in ionic contact with the material can be used.
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In one particularly preferred arrangement the storage component
comprises a cell with an outer case wherein the case is fully or partially
formed of
the anode material so that the anode is formed by the outer case either by an
outer
surface of the same material or as a coating or layer on the exterior of the
case. In
this case the outer case or at least the outer layer can be formed of a
material which
is more noble than steel. In this arrangement the anode forms directly the
outer
case of the cell where the case contains and houses the cathode material of
the cell
the electrolyte, the anode material and other components of the cell. That is,
in this
embodiment, the anode is defined by a layer or coating on the outer surface of
the
storage component itself or actually as the outer surface of the storage
component
and not as an additional element which is separate from the storage component.
Where the storage component is a cell, the outer case of the cell can directly
carry
the material of the anode or even the outer case of the cell is the anode. The
anode
material may cover the whole surface or may be a partial covering leaving
other
areas exposed.
In another case the case and the anode are formed independently and
the anode forms a separate body which conforms in shape to the outer case of
the
cell. Typically such cells are cylindrical but other shapes can be used. This
arrangement is particularly applicable where the cell is replaceable rather
than
rechargeable to introduce the additional energy after the original cell is
sufficiently
depleted to be no longer effective.
In another case the anode is a separate body which is electrically
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connected to one terminal of the storage component.
The above features can be preferably used for protection of steel
reinforcing or structural members in concrete or mortar material where it is
well
known that corrosion can cause breakdown of the concrete due to the expansive
forces of the corrosion products and due to the reduction to the steel
strength.
However uses in other situations can arise.
The term impressed current anode used herein is intended to
distinguish from the sacrificial anode where the sacrificial anode is formed
of a
material, typically of zinc, which is less noble than the metal section so
that it
.. preferentially corrodes relative to the metal section to be protected. The
impressed
current anode is one which is used in conjunction with an external power
supply and
does not need to be less noble than the metal section. Typically such
impressed
current anodes are formed of titanium, platinum, niobium, carbon and other
noble
metals and oxides which do not corrode readily, or they can be formed of iron
or less
noble materials such as zinc.
For use during a sacrificial or galvanic phase of operation of the above
method, the ionically conductive filler material preferably contains at least
one
activator to ensure continued corrosion of the sacrificial anode. However the
activator can also be located at other positions in the system. Suitable
filler
materials can be in the form of solids, gels or liquids.
Gels can include carbomethyl cellulose, starches and their derivatives,
fumed silica or polymer gel electrolytes, e.g. acrylic acid in a potassium
hydroxide
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solution or polyvinyl chloride/acetate-KOH composites with additions of
bentonite,
propylene carbonate and or alumina. The alkali hydroxide in these gels acts as
a
suitable activator.
Suitable activators include alkali hydroxides, humectants, catalytic
materials and other materials which are corrosive to the sacrificial anode
metal.
Activators may be used alone or in combination.
For use during a sacrificial or galvanic phase of operation of the above
method, the ionically conductive filler material preferably has a pH
sufficiently high
for corrosion of the sacrificial anode to occur and for passive film formation
on the
sacrificial anode to be avoided. Alternatively, the filler may have a lower pH
and / or
contain other activators for corrosion of the sacrificial anode to occur and
for passive
film formation on the sacrificial anode to be avoided.
The anode and methods herein are preferably designed for use where
the metal section is steel and the ionically conductive material is concrete
or mortar.
The anode apparatus including the impressed current and sacrificial
components is typically buried in the concrete or other solid material so that
it is fully
encased by the concrete or a filler material, but this is not essential and
the anode
may be only partially buried or in direct or indirect physical or ionic
contact with the
concrete.
The anode apparatus including the impressed current and sacrificial
components may be surrounded by an encapsulating material or ionically
conducting
filler material which may be a porous material or porous mortar material.
Suitable
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encapsulating materials can be inorganic or organic and may be any ionically
conductive cementitious, polymer or non-cementitious material or mortar
including
geopolymers or modified Portland cements. The encapsulating material may be
solid, gel or liquid and may be deformable.
The power supply may include a solar panel which drives the
impressed current anode and rechargeable galvanic anode so as to provide long
term protection when the solar power is on and off.
The construction and methods proposed herein are designed
particularly where the metal section is steel and the ionically conductive
material is
concrete or mortar. However the same arrangements may be used in other
corrosion protection systems such as for pipes or other constructions in soil,
and in
many other systems where such anodes can be used.
Preferably the assembly includes a reinforcing layer, such as disclosed
in US Patent 7,226,532 issued June 5 2007 to Whitmore, the disclosure of which
may be referenced for further details not disclosed herein, to restrain and
resist
forces such as expansion, contraction and deformation forces which may be
caused
by corrosion of the anodes, deposition of sacrificial anode ions and other
physical /
environmental forces such as freezing, thawing, wetting, drying and thermal
expansion / contraction.
The invention as defined and described herein can also be provided as
an assembly, as opposed to a method for cathodically protecting and/or
passivating
a metal section in an ionically conductive material. Thus the following
definitions of
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the invention presented herein are included herein. Each of these independent
definitions can be used in conjunction with any one of or all of the
subsidiary
features as defined above.
BRIEF DESCRIPTION OF THE DRAWINGS
Embodiments of the invention will now be described in conjunction with
the accompanying drawings in which:
Figure 1 is a cross-sectional view of an anode assembly for use in the
present invention.
Figure 2 is an enlarged view of the current limiting circuit for use with a
cell and the mounting of the first abutment on the anode body.
Figure 2A is a schematic illustration of the current limiting circuit for
use with a galvanic anode which uses a battery voltage to generate the
reference
current.
Figure 2B is a schematic illustration of the current limiting circuit for
use with a galvanic anode which uses two anodes where the second anode is used
to generate the reference current.
Figure 2C is a schematic illustration of the current limiting circuit for
use with a system in which both an impressed current anode with the battery
supply
and a galvanic anode are used and wherein the voltage across the resistor is
used
to control the FET.
Figure 3 is a front elevational view of an anode assembly similar to that
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of Figure 1 where the anode body uses a sacrificial anode.
Figure 4 is an isometric view of the anode assembly of Figure 3.
Figure 5 is a top plan view of an anode assembly similar to that of
Figure 1 laid in a patch repair in a concrete assembly ready for the addition
of fresh
unset concrete to be applied to the patch.
In the drawings like characters of reference indicate corresponding
parts in the different figures.
DETAILED DESCRIPTION
In the example shown in Figure 1 there is provided a cell which may be
rechargeable, as shown in prior co-pending Application 15/341532 filed
November 2
2016, the disclosure of which may be referenced, or may be a simple non-
rechargeable cell. The cell may form part of the anode structure or the anode
and
the cell may be physically separated. As shown in Figure 1, an anode body 10
is
defined by a typical alkaline manganese dioxide-zinc rechargeable cell
comprises
the following main units: a steel can 12 defining a cylindrical inner space, a
manganese dioxide cathode 14 formed by a plurality of hollow cylindrical
pellets 16
pressed in the can, a zinc anode 18 made of an anode gel and arranged in the
hollow interior of the cathode 14, and a cylindrical separator 20 separating
the anode
18 from the cathode 14. The ionic conductivity (electrolyte) between the anode
and
the cathode is provided by the presence of potassium hydroxide, KOH,
electrolyte
added into the cell in a predetermined quantity. Other types of rechargeable
cells
comprise similar main components (can, cathode, anode, separator and
electrolyte)
Date Recue/Received date 2020-04-13
24
but the composition of the components may differ. Some of the types of cell
may
however be of a different construction such as lead/acid cells or lithium
cells.
The can 12 is closed at the bottom, and it has a central circular pip 22
serving as the positive terminal. The upper end of the can 12 is hermetically
sealed
by a cell closure assembly which comprises a negative cap 24 formed by a thin
metal sheet, a current collector nail 26 attached to the negative cap 24 and
penetrating deeply into the anode gel to provide electrical contact with the
anode,
and a plastic top 28 electrically insulating the negative cap 24 from the can
12 and
separating gas spaces formed beyond the cathode and anode structures,
respectively.
The material of separator 20 consists of two different materials, i.e.: a
first material 30 made of fibrous sheet material wettable by the electrolyte,
and a
second material 32 being impermeable to small particles but retaining ionic
permeability. An expedient material for the first layer is a sheet material of
non-
woven polyamide fiber, which is absorbent and serves as a reservoir for
electrolyte.
The macro-porous structure of the absorbent layer cannot prevent internal
shorting
by zinc dendrites or deposits during discharge/charge cycling.
Shorting is prevented by the second 32 material which may be a layer
or layers of micro-porous or non-porous material which may be laminated to or
coated onto the fibrous sheet material. One suitable material is one or more
cellophane membranes laminated to the non-woven polyamide sheet. Another is
one or more coatings of regenerated cellulose or viscose coated onto and
partially
Date Recue/Received date 2020-04-13
25
impregnating the non-woven polyamide sheet, resulting in a composite material.
Other types of rechargeable cells may be used. In the present
arrangement, the type described above is used in a method for cathodically
protecting and / or passivating a metal section such as steel reinforcing bar
40 in an
ion ically conductive material such as concrete 41. The cell therefore
includes a first
terminal 42 and a second terminal 43 defined by the outer casing 12. The first
terminal 42 is connected to the pin or nail 26 which is engaged into the anode
material 18. The terminal 42 connects to a connecting wire 42A which extends
from
the terminal 42 for eventual connection to the steel reinforcing bar 40 as
shown in
figure 1 through the mounting assembly generally indicated at 50 which
mechanically and electrically attaches the anode body to the bar 40.
In figure 1, an anode 44 is applied as a coating onto the casing 12 of
the cell. In this embodiment the anode 44 is of an inert material so that it
is more
noble than steel. Examples of such materials are well known. Thus the anode
material 44 does not corrode or significantly corrode during the cathodic
protection
process.
In this arrangement the application of the anode 44 onto the outside
surface of the casing 12 provides the structure as a common single unit where
the
anode is directly connected to the cell and forms an integral element with the
cell.
Anode 44 may comprise one or more layers and may include a mixed metal oxide
(MMO), catalytic or sub-oxide layer.
In this embodiment, as the anode 44 is formed of an inert material
Date Recue/Received date 2020-04-13
26
which does not corrode in the protection process, the anode and the cell
contained
therein can be directly incorporated or buried in the concrete or other
ionically
conductive material without the necessity for an intervening encapsulating
material
such as a porous mortar matrix. As there are no corrosion products there is no
requirement to absorb such products or the expansive forces generated thereby.
As
the process does not depend uponT continued corrosion of a sacrificial anode,
there
is no necessity for activators at the surface of the anode. As the chemical
reaction at
the surface of any inert anode during operation generates acid (or consumes
alkali)
it is beneficial for the anode to be buried in an alkaline material such as
concrete or
high alkalinity mortar to prevent material near the anode from becoming
acidic. If
desired, additional alkali may be added to the concrete or other material the
anode is
in contact with.
The apparatus shown herein includes an anode body generally
indicated at 10 which is connected to the reinforcing bar 40 by the mounting
assembly generally indicated at 50. In addition, the anode body includes a
current
limiting system generally indicated at 51 which limits the flow of current
from the
anode body to the bar 40.
As previously described, the anode body can be defined by a power
supply typically in the form of a cell with the anode 44 on the outside
surface of the
cell and with the other terminal of the cell provided at the end of the cell
for
connection to the bar 40.
Date Recue/Received date 2020-04-13
27
In other embodiments described hereinafter the cell can be omitted in
which case the anode body comprises a sacrificial material which is less noble
than
the steel rebar, such as zinc where a voltage between the anode and the bar
comprises the galvanic voltage between the two metal components.
In yet another embodiment, the anode body can comprise a
combination of both an impressed current anode and a sacrificial anode.
In this way the anode body is constructed and arranged so that when
the anode is ionically connected to the concrete, a voltage difference is
generated
between the anode 44 and the bar 40 so as to cause a current to flow through
the
concrete between the anode and the bar 40 so to provide cathodic protection
and/or
passivation of the reinforcing bar in the concrete.
In the embodiment shown in figure 1, 3 and 4, the mounting assembly
50 comprises a first abutment 52 in the form of a threaded rod 53 which is
attached
at one end to the anode body 10. An opposed end 54 of the threaded rod forms a
front face for engaging one side face of the bar 40. As shown in figures 2 and
4, the
end face 54 of the threaded rod 53 includes a peripheral circular edge 55 and
intervening projections 56 which are arranged to bite into the surface of the
bar 40
when in compressed contact therewith.
The mounting assembly 50 further comprises a second abutment 57
for engaging generally the opposed the face of the bar 40 at a surface 58. In
general
the second abutment forms a hook member which contacts the opposite or rear
surface of the bar 40 at least at two positions 59 and 60 on either side of a
diameter
Date Recue/Received date 2020-04-13
28
61 extending through the bar 40 from the face 54. In this way the bar 40 is
contacted
by three points 54, 59 and 60 which are spaced around the axis 62 of the bar
system
to provide a stable engagement.
The hook member defined by the surfaces 59 and 60 forms a part of a
C-shaped structure 63 with a bottom crossmember 64 and a top crossmember 65
carrying the surfaces at 59 and 60. These cross members are interconnected by
an
outwardly extending leg 66 which extends parallel to the threaded rod 53. The
crossmember 64 includes a flange 67 at right angles to the threaded rod 53
with a
threaded hole 68 through the flange which acts as a nut on the threaded rod so
the
rotation on the threaded rod causes the nut to be driven toward the anode body
to
pull the surfaces 59 and 60 toward the surface 54 to clamp the bar 40
therebetween.
The surfaces 59 and 60 can also be formed with teeth or other
projections 59A or a sharp cutting edge 59B which bite into the surface of the
bar 40
and cooperate with the teeth 55 and 56 of the face 54. In this way a strong
physical
connection is provided between the first and second abutment and the bar 40
and
also a strong electrical connection is provided between the rod 53 and the bar
40.
These teeth or sharp cutting edges on some or all contacting surfaces can bite
into
any contaminant such as corrosion or concrete residue on the surface of the
rebar to
ensure an effective engagement and electrical contact with the metal of the
rebar.
That is each of the first and second abutment members includes components for
cutting into a surface of the reinforcing bar thus avoiding the necessity to
clean the
surface of the bar.
Date Recue/Received date 2020-04-13
29
In accordance with another independent feature of the invention, in
order to ensure that the projections and cutting edges provide the necessary
engagement with the metal of the rebar, a sensor can be provided which
measures
the effectiveness of the connection. This can be done for example by measuring
the
resistance across the connection by bridging the rebar and a point on the
connection
to ensure that the resistance of the connection meets the necessary low level
of
resistance. This output is provided to an indicator to output to the installer
an
indication for example visually or audibly as to whether the connection
properly
meets the set standard.
The hook member can comprise a single body on one side of the rod
53. However as best shown in figure 4, typically the hook member is formed by
two
separate hook portions 68 and 69 connected by a backplate 70. In this way the
rod
53 is contained between the portions of 68 and 69 and in front of the
backplate 70.
The hook portions of 68 and 69 each include surfaces 59 and 60 which engage
the
rear surface of the bar 40. Thus the forces pulling the second abutment member
toward the anode body pull on both hook portions and on both surfaces 59 and
60
providing four points of engagement which cooperate with the single point of
engagement from the surface 54 of the rod 53.
In this embodiment the female threaded portion is provided by a
threaded hole through the flange 67. A screw action pulling the second
abutment
member toward the anode body is therefore provided by rotating the rod 53.
This
can most effectively be done by grasping manually the anode body and using it
as a
Date Recue/Received date 2020-04-13
30
handle to turn the rod 53. Of course this requires a strong connection between
the
bottom end of the rod 53 and the anode body. In the arrangement shown in
figure 2,
this connection is provided by a base plate 71 attached onto the bottom end of
the
rod 53 and engaged firmly into the upper end of the anode body. In an
arrangement
using a solid anode 74 of a sacrificial material, the rod 53 can be cast into
the
interior of the anode body to provide the necessary structural and electrical
connection. In figure 3, the solid anode body 74 includes a conventional
covering of
a mortar material 75 for purposes of retaining corrosion products and of
carrying
conventional activating materials described herein before.
In another arrangement (not shown) the female threaded portion
engaged on the rod 53 can be formed by a separate nut which itself can rotate
relative to the second abutment member on the flange and 67. In this
embodiment
rather than rotate the rod, the nut can be rotated to drive the flange 67
toward the
anode body. Other arrangements of threaded connection are also possible to
drive
the second abutment member toward the anode body. In another example, the
hook is part of the anode body and the screw is turned to press the rebar
against the
hook.
A sensor 401 is provided which measures the effectiveness of the
connection for example by measuring the resistance across the connection by
terminals 403, 404 bridging the rebar and a point on the connection to ensure
that
the resistance of the connection meets the necessary low level of resistance.
This
output is provided to an indicator 402 to output to the installer an
indication for
Date Recue/Received date 2020-04-13
31
example visually or audibly as to whether the connection properly meets the
set
standard.
Turning now to figure 2, there is shown in more detail the connection
between the terminal 42 of the cell and the rod 53 which is electrically
connected to
the bar 40 as described above.
The terminal 42 is connected to a wire 42A which in turn is connected
to a transistor 78. An output wire 79 of the transistor 78 is connected to the
base
plate 71 connected to the rod 53.
The transistor 78 can be a conventional transistor in which case a base
of the transistor 78 has a control current provided by a wire 80 connected
through a
resistor 81 in turn connected through a wire 82 to the positive terminal of
the battery
connected to the anode 44.
The transistor 78 can also be an FET in which case the wire 80
controls a gate of the FET through the resistor 81.
As the transistor 78 is connected to the steel bar 40 and the wire 82 is
connected to the anode 44, the control current to the transistor 78 is
determined by
the voltage across the cell and the resistance of resistor 81. As this voltage
is
typically relatively constant at least until the cell is in its later stages
of life, this
constant control current controls the amount of current flowing through the
transistor
from the cell to the bar 40. As is well known the resistor 81 can be selected
to
provide a control base current to the transistor which sets the current flow
through
the transistor to a maximum value. This maximum value is retained regardless
of the
Date Recue/Received date 2020-04-13
32
conductivity between the anode 44 and the bar 40 through the concrete. As the
conductivity through the concrete is very high, for example during an initial
installation, the current is maintained at the maximum value. As the
conductivity
through the concrete falls to a lower level, the current is maintained at the
desired
level until the maximum voltage of the cell is reached. If the conductivity
falls to a
yet lower level, the current through the transistor also falls dependent upon
the
conductivity and is not maintained by the action of the transistor. The simple
circuit
therefore provided by the resistor and the transistor does not act as a
regulator but
instead merely acts as a current limiter.
Figures 2A and 2B show applications of the current limiting device in
use with a galvanic anode.
Figure 2A shows galvanic anode 86 connected to transistor 78. A
separate battery 87 is connected to resistor 81 and is connected to transistor
78 to
provide the control current to the transistor such that the transistor
controls the
maximum current flowing to the bar 40.
Figure 2B shows a galvanic anode 88 connected to transistor 78. In
this case the control current to the transistor is provided by a second
galvanic anode
89 and resistor 81. As in the example described above, the control current
controls
the maximum current flowing to the bar 40.
Figure 2C shows a current limiting circuit for use with a system in
which both an impressed current anode 10 with the battery supply and a
galvanic
anode 90 are used and wherein the voltage across the resistor 81 is used to
control
Date Recue/Received date 2020-04-13
33
the FET 78. The output from the anode 10 and the anode 90 is added downstream
of the FET and the current from the anode 10 generated by the battery is
limited
using the current limiting circuit. In this way the current from the impressed
current
anode is used to "top up" the current from the galvanic anode to maintain a
current
which is adequate to provide the required protection. As is known the current
from
the anode 90 can vary due to changing conditions in the concrete so that the
top up
from the battery is used only when required. As the current taken from the
battery is
now limited, the system can be designed such that the life of the battery can
match
the life of the anode 90.
If the electrical circuit includes a normally closed FET, the FET can
allow current to flow unimpeded from the galvanic anode 86 to the bar 40 after
the
separate battery or separate galvanic anode described above ceases to
function.
This limitation of the current to a maximum value set during
manufacture by the selection of the resistor 81 can ensure that the current
remains
during the life of the system at a relatively low level so as to dramatically
increase
the lifetime of the cell from a typical value in the absence of the current
limiter which
could be of the order of one year up to a more suitable lifetime of 10 years
for
example. In this way the current is maintained at a value which is suitable
for
cathodic protection but at no time is there any excess current over and beyond
this
desirable value which may damage the concrete or deplete the cell prematurely
such that corrosion protection is not provided for the desired timeframe.
This arrangement is particularly valuable in relation to an arrangement
Date Recue/Received date 2020-04-13
34
which uses a non-sacrificial impressed current anode and a cell as the power
supply
for generating the required voltage. In such an arrangement the current
generated
between the anode 44 and the bar 40 can in some circumstances significantly
exceed the desirable value. In addition the mechanical mounting of the anode
body
on the reinforcing bar provides an effective electrical connection.
Furthermore the
strong physical connection between the anode body and the bar ensures that the
anode body can be located at a required orientation relative to gravity such
as where
the anode body is to one side of the bar or above the bar as required.
In order to connect the terminal 42 to the rod 53, there is provided an
insulating or protective collar 83 surrounding the transistor 78 and the
resistor 81.
The bottom end of the collar is attached to the top end of the cell and the
top end of
the collar receives the base plate 71 in a suitable receptacle portion. The
collar 83 is
attached to the cell 44 by a surrounding insulating layer 84 of a suitable
plastic
material. Inside the collar 83 is provided a conventional potting material 85
which
surrounds the electrical components and wires to maintain connection and to
prevent damage from moisture penetration. The structure is thus sufficiently
strong
to ensure that the base plate 711s attached to the cell in a manner which
allows the
cell to be grasped manually and rotated as an operating handle to rotate the
rod 53.
As shown in figure 5, and anode body generally indicated at 90 is
mounted within a patch repair 91 in a concrete material 92. The anode body
includes
a mounting assembly 50 as previously described including a rod 53 and a hook
portion 57. In this embodiment the anode body 90 is formed of a cell 93 and
portion
Date Recue/Received date 2020-04-13
35
94 of a sacrificial material. The cell 93 has an outer surface 95 which acts
as an
impressed current anode. The cell has a terminal 96 which is attached by a
wire 97
including a diode 98 which transmits voltage from the terminal 96 to the rod
53.
During an initial operating period, therefore, the system operates primarily
as an
impressed current system where the cell generates a majority of the flowing
current
between the anode at 95 and the bar 40. However when the cell is depleted, the
cathodic protection is taken over by the sacrificial anode 94 which is
directly
connected to the rod 53. In this arrangement the diode 98 prevents the reverse
flow
of current through the cell 93 which could act to reverse the sacrificial
process and
instead more actively corrode the steel The cell 93 and the anode 94 are
suitably
connected by a structural mounting element 99 shown only schematically which
physically attaches the cell to the anode 94 sufficiently to prevent the cell
from
breaking away from the anode during installation.
As shown in figure 5, the anode body 90 stands outwardly to one side
of the bar 40 horizontally within the patch. In this way the anode body is
supported at
a spaced position from the bar 40 defined by the length of the rod 53 and the
mechanical connection of the clamping assembly. The mechanical connection of
the clamping assembly ensures that the anode body remains in its horizontally
extending orientation during the filling of the patch 91 with additional
concrete.
During the setting of the additional concrete, the current limiting system
described
above prevents the generation of gases at the surfaces of the anode and the
rebar
which can enter the setting concrete and cause significant damage to the
concrete.
Date Recue/Received date 2020-04-13
