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Patent 3027826 Summary

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(12) Patent: (11) CA 3027826
(54) English Title: CATHODE
(54) French Title: CATHODE
Status: Granted
Bibliographic Data
(51) International Patent Classification (IPC):
  • C25C 3/08 (2006.01)
  • C25C 3/16 (2006.01)
  • C25C 7/02 (2006.01)
(72) Inventors :
  • OKAMOTO, TATSUYA (Japan)
  • KOYAMA, YASUHIRO (Japan)
(73) Owners :
  • SEC CARBON, LTD. (Japan)
(71) Applicants :
  • SEC CARBON, LTD. (Japan)
(74) Agent: GOWLING WLG (CANADA) LLP
(74) Associate agent:
(45) Issued: 2023-06-27
(86) PCT Filing Date: 2017-05-29
(87) Open to Public Inspection: 2017-12-21
Examination requested: 2022-01-19
Availability of licence: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): Yes
(86) PCT Filing Number: PCT/JP2017/019946
(87) International Publication Number: WO2017/217225
(85) National Entry: 2018-12-14

(30) Application Priority Data:
Application No. Country/Territory Date
2016-120113 Japan 2016-06-16

Abstracts

English Abstract

Provided is a cathode that is easy to install while ensuring electric conductivity. The cathode 10 is a cathode for metal refinery and is provided with a carbon cathode block 11, and at least one carbon collector bar 12, each of which is disposed so as to contact the cathode block 11. The bottom surface of the cathode block 11 is a flat surface. The upper surface of each collector bar 12 is a flat surface. The cathode block 11 is disposed so that the bottom surface of the cathode block 11 contacts the upper surface of each of the collector bars 12.


French Abstract

L'invention concerne une cathode qui est facile à installer tout en assurant une conductivité électrique. La cathode (10) est une cathode destinée à l'affinerie et est équipée d'un bloc cathodique en carbone (11), et d'au moins une barre collectrice de carbone (12), chacune étant disposée de manière à venir en contact avec le bloc cathodique (11). La surface inférieure du bloc cathodique (11) est une surface plate. La surface supérieure de chaque barre collectrice (12) est une surface plate. Le bloc cathodique (11) est disposé de sorte que la surface inférieure du bloc cathodique (11) entre en contact avec la surface supérieure de chacune des barres collectrices (12).

Claims

Note: Claims are shown in the official language in which they were submitted.


CLAIMS
1. A cathode for smelting metal, comprising:
a cathode block made of carbon; and
one or more collector bars made of carbon, each positioned to be in
contact with the cathode block,
wherein the cathode block has a flat bottom surface;
each of the one or more collector bars has a flat top surface; and
the cathode block is positioned such that the bottom surface of the
cathode block is in contact with the top surface of each of the one or more
collector bars.
2. A cathode for smelting metal, comprising:
a cathode block made of carbon; and
one or more collector bars made of carbon, each positioned to be in
contact with the cathode block,
wherein the cathode block has a bottom surface provided with a
groove;
each of the one or more collector bars has a top surface provided with
a groove complementary to the groove of the cathode block; and
the cathode block is positioned such that the bottom surface of the
cathode block is in contact with the top surface of each of the one or more
collector bars.
3. The cathode according to claim 1 or 2, wherein the one or more
collector bars are two collector bars arranged in a longitudinal direction of
the cathode block; and
the two collector bars are spaced apart from each other.
4. The cathode according to any one of claims 1 to 3, wherein a
width of at least part of a portion of the one or more collector bars that
does
not overlap the cathode block as seen in plan view is smaller than a width of
a portion that overlaps the cathode block.
5. A cathode for smelting metal, comprising:
a cathode block made of carbon; and

18

one or more collector bars made of carbon, each positioned to be in
contact with the cathode block,
wherein the cathode further comprises a screw adapted to fasten the
cathode block and the one or more collector bars together.
6. A cathode for smelting metal, comprising:
a cathode block made of carbon; and
one or more collector bars made of carbon, each positioned to be in
contact with the cathode block,
wherein the cathode block includes a male or female thread, or a
protrusion or recess; and
each of the one or more collector bars includes a female or male
thread to be fastened to the male or female thread, or a recess into which the
protrusion is to be fitted or a protrusion to be fitted into the recess.
7. The cathode according to any one of claims 1 to 6, wherein the
one or more collector bars are made of a carbon material with a lower
electrical resistivity than the cathode block.
8. A cathode for smelting metal, comprising:
a cathode block made of carbon; and
one or more collector bars made of carbon, each positioned to be in
contact with the cathode block,
wherein the cathode further comprises a second cathode block; and
at least one of the one or more collector bars is in contact with both
the cathode block and the second cathode block.

19

Description

Note: Descriptions are shown in the official language in which they were submitted.


--
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CATHODE
TECHNICAL FIELD
[0001] The present invention relates to cathodes, and more particularly to
cathodes for smelting metal.
BACKGROUND ART
[0002] Cathodes in electrolytic furnaces for smelting metal, such as
aluminum, typically take the form of cathode blocks made of carbon.
Cathode blocks are positioned in a steel box called "shell" to form the bottom

of the electrolytic furnace. The cathode blocks also function to supply the
electrolytic bath with electrons (see, for example, JP 2012-529567 A and JP
2013-537940 A).
[0003] The cathode blocks are supplied with electric power via steel collector

bars. The connection between the cathode blocks and the collector bars is
established by pouring cast iron into the gaps between them. Specifically,
the bottom surface of each cathode block is provided with a groove, into
which collector bars are fitted, and cast iron that has been heated to about
1300 C to be melted is poured into the gaps between the groove and collector
bars.
[0004] It has been reported that, even in cases where the cathode blocks are
connected to the collector bars through cast iron, gaps may be produced
between a cathode block and cast iron and/or between cast iron and a
collector bar to increase the contact resistance. According to Richard Beeler,

"Bar to Block Contact Resistance in Aluminum Reduction Cell Cathode
Assemblies", Light Metals 2014, pp. 507-510, the proportion of the reduction
in voltage in the cathode blocks and collector bars represented by the contact

resistance is about 25 %, and is equivalent to at least 2 % of the electric
power consumption in aluminum smelting.
[0005] The document cited above teaches that, inter alia, (1) the
solidification behavior of cast iron adjacent to the top of a collector bar is

different from that adjacent to the bottom of the bar; (2) the collector bars
may experience creep deformation; and (3) phase change in steel may cause
discontinuous thermal expansion, thus producing gaps between the cathode
blocks and collector bars.
[0006] To reduce contact resistance, Canadian Patent No. 2846409 teaches
1

AA A A. . A A ^ . = .= = =
-
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using a compression device to compress the collector bars to eliminate the
gaps between the cathode blocks and collector bars. Further, Canadian
Patent No. 2838113 discloses inserting metallic conductors between the
cathode blocks and collector bars to establish electrical connection.
DISCLOSURE OF THE INVENTION
[0007] Approaches in which cast iron is poured in to connect the cathode
blocks to the collector bars, as discussed above, require equipment and
energy to melt cast iron and thus require considerable costs, and, if
conducted manually, may present safety concerns. Further, the resulting
quality is unstable, and variations in contact resistance may occur among
individual blocks/bars.
[0008] An object of the present invention is to provide a cathode that
provides a certain level of electric conductivity and that can be easily
installed.
[0009] One cathode disclosed herein is a cathode for smelting metal,
including: a cathode block made of carbon; and one or more collector bars
made of carbon, each positioned to be in contact with the cathode block. The
cathode block has a flat bottom surface; each of the one or more collector
bars
has a flat top surface; and the cathode block is positioned such that the
bottom surface of the cathode block is in contact with the top surface of each

of the one or more collector bars.
[0010] Another cathode disclosed herein is a cathode for smelting metal,
including: a cathode block made of carbon; and one or more collector bars
made of carbon, each positioned to be in contact with the cathode block. The
cathode block has a bottom surface provided with a groove; each of the one or
more collector bars has a top surface provided with a groove complementary
to the groove of the cathode block; and the cathode block is positioned such
that the bottom surface of the cathode block is in contact with the top
surface
of each of the one or more collector bars.
[0011] Yet another cathode disclosed herein is a cathode for smelting metal,
including: a cathode block made of carbon; and one or more collector bars
made of carbon, each positioned to be in contact with the cathode block. The
cathode further includes a screw adapted to fasten the cathode block and the
one or more collector bars together.
[0012] Still another cathode disclosed herein is a cathode for smelting metal,
2

. ,
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including: a cathode block made of carbon; and one or more collector bars
made of carbon, each positioned to be in contact with the cathode block. The
cathode block includes a male or female thread, or a protrusion or recess; and

each of the one or more collector bars includes a female or male thread to be
fastened to the male or female thread, or a recess into which the protrusion
is to be fitted or a protrusion to be fitted into the recess.
[0013] Yet another cathode disclosed herein is a cathode for smelting metal,
including: a cathode block made of carbon; and one or more collector bars
made of carbon, each positioned to be in contact with the cathode block. The
cathode further includes a second cathode block; and at least one of the one
or more collector bars is in contact with both the cathode block and the
second cathode block.
[0014] In these arrangements, the difference in coefficient of thermal
expansion between the cathode block(s) and collector bars is small, thereby
keeping them in close contact even at high temperatures. This will simplify
the working process for keeping them in close contact. This will provide a
cathode that provides a certain level of electric conductivity and that can be

easily installed.
BRIEF DESCRIPTION OF THE DRAWINGS
[0015] [FIG. 1] FIG. 1 is a schematic cross-sectional view of metal-smelting
equipment.
[FIG. 2] FIG. 2 is a perspective view some components of the
metal-smelting equipment.
[FIG. 31 FIG. 3 shows an example of a manner in which the collector
bars are connected to the bus bars.
[FIG. 41 FIG. 4 is a perspective view of a cathode according to a first
embodiment.
[FIG. 51 FIG. 5 is a perspective view of a conventional common
cathode.
[FIG. 61 FIG. 6 is a cross-sectional view taken along line VI-VI of FIG.
5.
[FIG. 7A] FIG. 7A is a cross-sectional view of a model of a
conventional cathode along a plane perpendicular to the longitudinal
direction thereof.
[FIG. 7B] FIG. 7B is a cross-sectional view of the model of the
3

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conventional cathode along a plane perpendicular to the width direction
thereof.
[FIG. 8A1 FIG. 8A is a cross-sectional view of a model of the cathode
according to the present embodiment along a plane perpendicular to the
longitudinal direction thereof.
[FIG. 8B] FIG. 8B is a cross-sectional view of the model of the
cathode according to the present embodiment along a plane perpendicular to
the width direction thereof.
[FIG. 91 FIG. 9 is a perspective view of a cathode according to a
second embodiment.
[FIG. 10] FIG. 10 is a perspective view of a cathode according to a
third embodiment.
[FIG. 11] FIG. 11 is a perspective view of a cathode according to a
fourth embodiment.
[FIG. 12] FIG. 12 is a perspective view of a cathode according to a
fifth embodiment.
[FIG. 13] FIG. 13 is a perspective view of a cathode according to a
sixth embodiment.
[FIG. 14] FIG. 14 is a perspective view of a cathode according to a
seventh embodiment.
[FIG. 151 FIG. 15 is a perspective view of a cathode according to an
eighth embodiment.
EMBODIMENTS FOR CARRYING OUT THE INVENTION
[0016] Embodiments of the present invention will now be described in detail
with reference to the drawings. In the drawings, the same or corresponding
parts are labeled with the same characters and their description will not be
repeated. For ease of understanding of the description, the drawings, which
will be referred to below, show simplified or schematic constructions, or show

only some of the components. Further, the size ratios between components
shown in the drawings do not necessarily represent the actual size ratios.
[0017] [First Embodiment]
[Overall Construction]
FIG. 1 is a schematic cross-sectional view of metal-smelting
equipment 1000 including cathodes 10 according to a first embodiment of the
present invention. The metal-smelting equipment 1000 includes a plurality
4

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of cells 100. Each of the cells 100 includes a plurality of cathodes 10, a
plurality of anodes 20 and a furnace body 30. The cell 100 is loaded with an
electrolytic bath 33 and a pad 34 made of the metal to be smelted (for
example, aluminum).
[0018] Each cell 100 further includes a raw-material supply device 35. The
raw-material supply device 35 regularly supplies the electrolytic bath 33
with raw material (for example, alumina).
[0019] Each of the cathodes 10 includes a cathode block 11 and two collector
bars 12 electrically connected to the cathode block 11. FIG. 2 is a
perspective view of some components of the cell 100: the cathodes 10 (i.e.
cathode blocks 11 and collector bars 12) and the furnace body 30. As shown
in FIG. 2, the cathodes blocks 11 are placed all over the bottom of the
furnace
body 30. The collector bars 12 are configured to extend to outside of the
furnace body 30 via slots 31a defined in the furnace body 30.
[0020] The cathode blocks 11 and collector bars 12 are preferably made of
materials that can resist high temperatures and have high electric
conductivity. In the present embodiment, both the cathode blocks 11 and
collector bars 12 are made of carbon. Details of the constructions of the
cathode blocks 11 and collector bars 12 will be given further below.
[0021] Each of the anodes 20 (see FIG. 1) includes an anode block 21 and a
connection member 22 electrically connected to the anode block 21. The
anode blocks 21 and connection members 22 are preferably made of
materials that can resist high temperatures and have high electric
conductivity. The anode blocks 21 may be made of carbon, for example.
The connection members 22 may be made of metal, for example.
[0022] The furnace 30 includes a box-shaped shell 31 and a lining 32
positioned within the shell 31. The shell 31 is preferably made of a material
with high toughness to resist thermal expansion of the lining 32. The shell
31 may be made of metal, for example. The lining 32 insulates various
in-furnace components from each other and also prevents the electrolytic
bath 33 from leakage. The lining 32 may be made of fire bricks, for
example.
[0023] The collector bars 12 extending to outside of the furnace body 30 are
electrically connected to the anodes 20 of an adjacent cell 100 via metallic
bus bars 36. This construction results in a plurality of cells 100 being
electrically connected in series.

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[0024] The bus bars 36 are preferably made of a material with low electric
resistivity. The bus bars 36 may be made of aluminum, for example. The
collector bars 12 are connected to the bus bars 36 in areas outside of the
furnace body 30 at relatively low temperatures. As such, the difference in
coefficient of thermal expansion between the collector bars 12 and bus bars
36 poses no problem. The same applies to the connection between the bus
bars 36 and connection members 22.
[0025] The connection between the collector bars 12 and bus bars 36 is not
limited to any particular manner. However, since the collector bars 12 of
the present embodiment are made of carbon, the collector bars 12 and bus
bars 36 cannot be welded. FIG. 3 shows an example of a manner in which
the collector bars 12 are connected to the bus bars 36. In this example, both
sides of each collector bar 12 as determined along the height direction are
sandwiched by a bus bar 36, and bolts 37 and nuts 38 are tightened together
to connect the collector bar 12 to the bus bar 36.
[0026] The cathodes 10 at one end of the series of connected cells 100 (see
FIG. 1) and the anodes 20 at the other end of the cell series are connected to

a power source, not shown. Electric power from the power source applies a
voltage between the cathodes 10 and anodes 20 of each cell 100. This causes
raw material in the electrolytic bath 33 to be reduced and deposited on the
pad 34.
[0027] Thus, the metal-smelting equipment 1000 is capable of
manufacturing metal in a continuous manner. The metal-smelting
equipment 1000 is particularly suitable for smelting aluminum.
[0028] [Construction of Cathodes]
FIG. 4 is a perspective view of a cathode 10 according to the first
embodiment of the present invention. As discussed above, the cathode 10
includes a cathode block 11 and two collector bars 12. The cathode block 11
and two collector bars 12 have the shape of rectangular parallelepipeds.
The cathode block 11 is located on the top surfaces of the two collector bars
12. The bottom surface of the cathode block 11 is in contact with the top
surfaces of the two collector bars 12 to establish electrical connection
between the cathode block 11 and the two collector bars 12.
[0029] For ease of explanation, the longitudinal direction of the cathode 10
(i.e. x-direction) will be referred to as longitudinal direction, while the
vertical direction (i.e. z-direction) will be referred to as height direction.
6

õ., = = = = ===.===el=
4.,Y0=.=,lnr.KW ¾=V= =y..0 =
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The direction perpendicular to both the longitudinal direction and vertical
direction (i.e. y-direction) will be referred to as width direction. The
dimensions of a part as measured in the longitudinal direction, height
direction and width direction will be referred to as length, height and width,

respectively.
[0030] The larger the width w of the collector bar 12, the better. The larger
the width w, the larger the contact area between the bar and the cathode
block 11. Further, the larger the width w, the larger the cross-sectional area

of the collector bar 12, which means lower electrical resistance of the
collector bar 12. More preferably, the width w of the collector bar 12 is
equal to the width W of the cathode block 11. Further, the larger the height
h of the collector bar 12, the better.
[0031] The two collector bars 12 are arranged in the longitudinal direction of

the cathode block 11. The two collector bars 12 are separated by a distance
sp. The distance sp may be in the range of 15 to 50 cm, for example.
[0032] In the present embodiment, both the cathode block 11 and collector
bars 12 are made of carbon. Preferably, the cathode block 11 and collector
bars 12 are made of materials with low electrical resistivities. The cathode
block 11 and collector bars 12 are preferably made of graphite. Further, the
collector bars 12 are preferably made of a material with a lower electrical
resistivity than the cathode block 11.
[0033] [Effects of Cathode 10]
To help demonstrate the effects of the cathode 10, the construction of
a conventional common cathode 90 will be described. FIG. 5 is a perspective
view of the cathode 90. FIG. 6 is a cross-sectional view taken along line
VI-VI of FIG. 5.
[0034] The cathode 90 includes a cathode block 91 and four collector bars 92.
The cathode block 91 is made of carbon, typically graphite. The collector
bars 92 are made of metal, typically steel.
[0035] Steel usually has a lower electrical resistivity (specific resistance)
than carbon. Accordingly, with the collector bars 92 made of steel, it is
easier to achieve low electrical resistance. On the other hand, the collector
bars 92 made of steel have a coefficient of thermal expansion different from
that of the cathode block 91, which is made of carbon, making it difficult to
keep them in close contact with the cathode block 91 at high temperatures,
and thus the contact resistance tends to be high. The contact resistance
7

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between the cathode block 91 and collector bars 92 must be reduced in one
way or the other.
[0036] As shown in FIG. 6, the bottom surface of the cathode block 91 is
provided with grooves, into which the collector bars 92 are fitted. Further,
cast iron 93 is poured into the gaps between the cathode block 91 and
collector bars 92.
[0037] Creating this construction requires working time and costs.
Particularly, the step of pouring cast iron 93 represents a heavy load and, if

conducted manually, presents safety concerns. Further, the resulting
quality is unstable, and variations in contact resistance may occur among
individual blocks/bars.
[0038] The cross-sectional area of the collector bars 92 significantly affects

the electrical resistance. To reduce the electrical resistance, it is
preferable
to increase the cross-sectional area of the collector bars 92. However, if the

cross-sectional area of the collector bars 92 is to be increased, the grooves
in
the cathode block 91 must be increased accordingly. If the grooves are too
large, the strength of the cathode block 91 may be insufficient and thermal
stress caused by cast iron 93 being poured and other factors may produce a
crack 91a, called wing crack.
[0039] Instead of cast iron 93, paste may be used that is mainly composed of
coke and coal-tar pitch. However, such paste has a high electrical
resistance, which means a high energy loss.
[0040] If cast iron 93 is used, as discussed in the background section, (1)
the
solidification behavior of cast iron adjacent to the top of a collector bar is

different from that adjacent to the bottom of the bar; (2) the collector bars
may experience creep deformation; and (3) phase transition in iron may
cause discontinuous thermal expansion, thus producing gaps between the
cathode block 91 and collector bars 92. This increases the contact
resistance between the cathode block 91 and collector bars 92.
[0041] In the construction of the cathode 10 according to the present
embodiment, both the cathode block 11 and collector bars 12 are made of
carbon, which means that there is no difference in coefficient of thermal
expansion between them. This makes it possible to keep the cathode block
11 and collector bars 12 in close contact even at high temperatures.
[0042] This eliminates the necessity to provide grooves on the bottom
surface of the cathode block 11 or to pour cast iron into the gaps between the
8

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cathode block 11 and collector bars 12. This reduces working time and
costs.
[0043] The collector bars 12 made of carbon have a lower thermal
conductivity than the collector bars 92 made of steel. This prevents heat in
the cell 100 from dissipation.
[0044] The cathode block 11 or 91 may wear down due to friction with the
pad 34 (see FIG. 1) and other factors. In the case of the cathode 90, when
the cathode block 91 has worn down to a level with the collector bars 92 that
are fitted in, the collector bars 92 made of steel come in contact with the
content of the electrolytic bath 33 (see FIG. 1), potentially contaminating
the
content of the electrolytic bath 33; to prevent this, the cathode block 91 is
not
used anymore. That is, the portions of the volume of the cathode block 91
that are at the same levels as the fit-in collector bars 92 do not contribute
to
the life of the cathode 90. In contrast, in the construction of the cathode
10,
the entire volume of the cathode block 11 contributes to the life of the
cathode 10. Thus, from a given volume of raw material, a cathode with a
longer life can be produced.
[0045] In the construction of the cathode 10, the collector bars 12 do not
need to be fixed to the cathode block 11, and the cathode block 11 may be
simply put on the collector bars 12. The interface between the cathode
block 11 and collector bars 12 receives a certain level of pressure from the
weights of the cathode block 11, electrolytic bath 33 and pad 34. Further,
the lining 32 and other elements can thermally expand, thus applying a
compression stress on the cathode block 11 and collector bars 12. This
further facilitates keeping the cathode block 11 and collector bars 12 in
close
contact even at high temperatures.
[0046] [Example Calculations]
Model calculations were conducted to verify that collector bars made
of carbon can provide electric conductivity levels substantially equal to
those
of collector bars made of steel. The model calculations were conducted in
accordance with the method described in Richard Beeler, "An Analytical
Model for Cathode Voltage Drop in Aluminum Reduction Cells", Light Metals
2003, pp. 241-245.
[0047] Table 1 shows the parameters used for the calculations and the
calculation results.
[0048]
9

_
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[Table 1]
TABLE 1
Comp. Ex. Inv. Ex.
0.505 m 0.505 m
0.480 m 0.480 m
1.750 m 1.750 m
0.210 m 0.505 m
0.130 m 0.150 m
L' 0.500 m 0.500 m
32 32
pn 1.2 pgrn 4.0 pgm
p's 0.6 pm 4.0 pQm
pc 9.1 pm 9.1 pm
10.0 pQm2 1.0 pQm2
H* 0.39 m 0.36 m
R'B 10.99 pg2 26.40 pg
RB 76.92 pg 92.41 pg
RC 3.97 pg 3.69 pg
Rj 12.16 lig 1.13 pg
a 2.18 4.38
Rcen 1.473 pg 1.484 pg
[0049] FIGS. 7A to 8B illustrate the models used for the calculations. FIG.
7A is a cross-sectional view of a model of a conventional cathode 95
(comparative example) along a plane perpendicular to the longitudinal
direction thereof. FIG. 7B is a cross-sectional view of the same model along
a plane perpendicular to the width direction thereof. FIG. 8A is a
cross-sectional view of a model of the cathode 10 according to the present
embodiment (inventive example) along a plane perpendicular to the
longitudinal direction thereof. FIG. 8B is a cross-sectional view of the same
model along a plane perpendicular to the width direction thereof.
[0050] As shown in FIGS. 7A to 8B, W, H and L indicate the width, height
and length, respectively, of the cathode block 96 or 11. w and h indicate the
width and height, respectively, of the collector bars 97 or 12. L' indicates
the
length of the portions of a collector bar 12 or 97 that protrude from the
cathode block 96 or 11. As shown in Table 1, the cross-sectional area of the
collector bars 96 was 21 cm x 13 cm, and the cross-sectional area of the
collector bars 12 was 50.5 cm x 15 cm.

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[0051] N is the number of cathode blocks in a cell multiplied by 2. This
parameter is used to calculate the resistance Rcell per cell.
[0052] ps and p's indicate the electric resistivities (volume resistivities)
of
the collector bars at 1000 C and 500 C, respectively. The electric
resistivity of the collector bars of the comparative example is represented by

the value for steel. The electric resistivity of the collector bars of the
inventive example is represented by the value for a nipple material for
artificial graphite electrodes, which is a carbon material with a particularly

low electric resistivity.
[0053] pc indicates the electric resistivity of the cathode block at 1000 C.
It is represented by the same value for graphite for the inventive and
comparative examples.
[0054] a indicates the contact resistance per unit contact area at the
interfaces between the cathode block and collector bars. The larger the
contact area, the smaller the contact resistance becomes. a in the
comparative example was calculated backward from a measured value of
Rcell. It is assumed that a in the inventive example can be reduced to 1.0
ilS2m2, since no problem arises due to the difference in coefficient of
thermal
expansion, which would be the case in collector bars made of steel.
[0055] H* indicates the effective height and expressed by the following
equation:
H*=H¨h(h+w)/(2h+w)
[0056] R's indicates the resistance of the portions of a collector bar that
protrude from the cathode block as measured along the longitudinal
direction thereof. R's is expressed by the equation provided below. In
reality, a temperature distribution exists in the collector bar and electric
resistivity may vary depending on location; however, for the sake of
simplicity, the electric resistivity at the median temperature, i.e. 500 C,
was
used for calculation.
R's=p'sL7wh
[0051 RB indicates the resistance of the portions of a collector bar that
overlap the cathode block as seen in plan view, as measured along the
longitudinal direction of the collector bar. Rs is expressed by the equation
provided below. For the purpose of calculation, the temperature of these
portions was 1000 C.
Rs=psL/wh
11

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[0058] Rc indicates the resistance of the cathode block as measured along
the height direction. Rc is expressed by the equation provided below. For
the purpose of calculation, the temperature of these portions was 1000 C.
Rc=pcH*/WL
[0059] RJ indicates the resistance of the connection between the cathode
block and a collector bar, and is expressed by the following equations:
RJ=o/(2h+w)L (for FIGS. 7A and 7B)
RJ=a/wL (for FIGS. 8A and 8B)
[0060] a indicates the ratio of the resistance as measured along the
longitudinal direction to the resistance as measured along the height
direction, and is expressed by the following equation:
a2=RB/(Rc+RJ)
[0061] The resistance Rcell of a cell can be calculated by the following
equation:
[Math 1]
1B
a tanh (ct ))
[0062] Table 2 demonstrates that the use of collector bars made of carbon
also provides a level of electrical conductivity that is substantially equal
to
those of collector bars made of metal.
[0063] The construction and effects of the cathode 10 according to the first
embodiment of the present invention have been described. According to the
present embodiment, both the cathode block 11 and collector bars 12 are
made of carbon. In this construction, the difference in coefficient of thermal
expansion between the cathode block 11 and collector bars 12 is small,
making it possible to keep them in close contact even at high temperatures.
This simplifies the work for keeping them in close contact. This provides a
cathode that provides a certain electrical conductivity and can be easily
installed.
[0064] According to the present embodiment, the bottom surface of the
cathode block 11 is flat, and the top surfaces of the collector bars 12 are
flat.
The cathode block 11 is positioned such that the bottom surface of the
cathode block 11 is in contact with the top surfaces of the collector bars 12.

This construction makes it particularly easy to machine the cathodes.
[0065] In FIG. 4, both the cathode block 11 and collector bars 12 have the
12

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shape of rectangular parallelepipeds. Alternatively, in the cathode block 11,
only the bottom surface is required to be flat and the other surfaces may take

any shapes. Similarly, in each of the collector bars 12, only the top surface
is required to be flat and the other surfaces may take any shapes. The
bottom surface of the cathode block 11 and the top surfaces of the collector
bars 12 preferably have high smoothness. The higher the smoothness of
these surfaces, the larger the contact area between them becomes, which
means smaller contact resistance.
[0066] The present embodiment illustrates an implementation where two
collector bars 12 are provided for each cathode block 11. Alternatively, only
one collector bar may be provided or more than two collector bars may be
provided for each cathode block 11.
[0067] Preferably, in the cathode 10, two or more collector bars 12 are
provided for each cathode block 11. With this construction, even when one
collector bar 12 is physically broken, the other collector bar(s) 12 will
provide
electrical connection.
[0068] According to the present embodiment, for each cathode block 11, two
collector bars 12 are arranged in the longitudinal direction of the block, the

two collector bars 12 being separated by the distance sp. In this
construction, when a collector bar 12 thermally expands, stresses in the
collector bar 12 in the longitudinal direction is allowed to escape. This
prevents the collector bar 12 from deforming.
[0069] Preferably, the collector bars 12 are made of a carbon material with a
lower electrical resistivity than the cathode block 11. For the cathode block
11, other properties than electric resistivity are required, such as
reactivity
with the content of the electrolytic bath 33 (see FIG. 1); accordingly, the
selection of materials is limited to some degree. The collector bars 12 have
no such limits and, as such, can be made of carbon materials with lower
electric resistivities. This improves the electric conductivity of the cathode

10.
[0070] According to the present embodiment, the bus bars 36 (see FIG. 1)
made of metal may be connected to the collector bars 12. The collector bars
12 and bus bars 36 need not be connected within the furnace at high
temperatures. Thus, the difference in coefficient of thermal expansion
between them does not pose a problem. Using bus bars 36 made of metal
for connection reduces the overall electric resistance of the equipment.
13

-
.
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[0071] [Second Embodiment]
FIG. 9 is a perspective view of a cathode 15 according to a second
embodiment of the present invention. The cathode 15 includes a cathode
block 16 and two collector bars 17. According to the present embodiment,
too, both the cathode block 16 and collector bars 17 are made of carbon.
[0072] The cathode block 16 is positioned on the top surface of the two
collector bars 17. The bottom surface of the cathode block 16 is in contact
with the top surfaces of the two collector bars 17 to establish electrical
connection between the cathode block 16 and two collector bars 17.
[0073] In the cathode 10 (see FIG. 4) according to the first embodiment, the
bottom surface of the cathode block 11 and the top surfaces of the collector
bars 12 are flat. In contrast, in the cathode 15 according to the present
embodiment, the bottom surface of the cathode block 16 is provided with
grooves 16a, while the top surfaces of the collector bars 17 are provided with

grooves 17a complementary to the grooves 16a.
[0074] According to the present embodiment, the contact area between the
cathode block 16 and collector bars 17 is increased. Further, when the
cathode block 16 is placed on the collector bars 17, the block can easily be
aligned with the bars. Furthermore, during operation, the cathode block 16
and collector bars are prevented from being displaced.
[0075] Since the cathode 15 requires formation of the grooves 16a and
grooves 17a, it requires more work steps than the cathode 10 (see FIG. 4).
Still, compared with the cathode 90 (see FIG. 5), the process is simplified
since cast iron need not be poured in, for example.
[0076] In FIG. 9, the cathode block 16 and collector bars 17 include V-shaped
grooves. Alternatively, any number of grooves may be provided and the
groove(s) may take any shape. The groove(s) may be saw-shaped or curved.
[0077] [Third Embodiment]
FIG. 10 is a perspective view of a cathode 40 according to a third
embodiment of the present invention. In the cathode 40, the collector bars
12 of the cathode 10 (see FIG. 4) are replaced by collector bars 42.
[0078] As with the collector bars 12, the collector bars 42 are made of
carbon.
The collector bars 42 have a planar shape different from that of the collector

bars 12. The width of some of the portions of the collector bars 42 that do
not overlap the cathode block 11 as seen in plan view is smaller than the
width of the bar portions that overlap the cathode block 11. Specifically, the
14

,
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portions of the collector bars 42 that do not overlap the cathode block 11 as
seen in plan view include terminal portions 42a that have smaller widths
than the bar portions that overlap the cathode block 11.
[0079] According to the present embodiment, the collector bars 42 can be
configured to extend to outside of the furnace body 30 (see FIG. 2) even in
implementations where the slots 31a of the furnace body 30 have small
openings. Specifically, a furnace body 30 that has been constructed
presupposing the shape of the collector bars 92 of the cathode 90 (see FIG. 5)

can be used without a design modification.
[0080] On the other hand, maintaining a large width of the bar portions that
overlap the cathode block 11 maintains a large contact area between the bars
and the cathode block 11, thereby providing a low contact resistance.
Further, a large cross-sectional area as measured in a plane perpendicular to
the longitudinal direction provides a low resistance along the longitudinal
direction.
[0081] [Fourth Embodiment]
FIG. 11 is a perspective view of a cathode 45 according to a fourth
embodiment of the present invention. The cathode 45 includes a cathode
block 46 and two collector bars 47. According to the present embodiment,
too, both the cathode block 46 and collector bars 47 are made of carbon.
[0082] According to the present embodiment, the cathode block 46 and
collector bars 47 are fastened together by screws 48. Female threads 46a
are formed in the cathode block 46 to be used to fasten the screws 48, while
through-holes 47a are formed in the collector bars 47 through which the
screws 48 can be inserted.
[0083] As discussed above, even with the cathode block 46 simply put on the
collector bars 47, thermal expansion of the lining 32 (see FIG. 1) and other
factors cause pressure on the interface between the cathode block 46 and
collector bars 47. However, for some constructions of the furnace, sufficient
pressure may not be applied. Further, in some cases, greater pressure may
be desired. Fastening the block and bars using screws 48, as in the present
embodiment, enables adjusting the contact area pressure between the
cathode block 46 and collector bars 47.
[0084] [Fifth Embodiment]
FIG. 12 is a perspective view of a cathode 50 according to a fifth
embodiment of the present invention. The cathode 50 includes a cathode

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block 51 and two collector bars 52. According to the present embodiment,
too, both the cathode block 51 and collector bars 52 are made of carbon.
[0085] Female threads 51a are formed on sides of the cathode block 51. A
male thread 52a is formed on one end of each collector bar 52 as determined
along the longitudinal direction to be used to fasten the male thread to the
female threads 51a. According to the present embodiment, fastening the
male threads 52a and female threads 51a connects the cathode block 51 to
the collector bars 52.
[0086] This embodiment, too, simplifies the process compared with
implementations using the cathode 90 (see FIG. 5).
[0087] In FIG. 12, female threads 51a are formed in the cathode block 51,
while male threads 52a are formed on the collector bars 52. Alternatively,
male threads may be formed on the cathode block 51 and female threads may
be formed on the collector bars 52.
[0088] [Sixth Embodiment]
FIG. 13 is a perspective view of a cathode 55 according to a sixth
embodiment of the present invention. The cathode 55 includes a cathode
block 56 and two collector bars 57. According to the present embodiment,
too, both the cathode block 56 and collector bars 57 are made of carbon.
[0089] Recesses 56a are formed on sides of the cathode block 56. A
protrusion 57a is formed on one end of each collector bar 57 as determined
along the longitudinal direction to be fitted into the associated recess 56a.
According to the present embodiment, fitting the protrusions 57a into the
recesses 56a connects the cathode block 56 and collector bars 57.
[0090] This embodiment, too, simplifies the process compared with
implementations using the cathode 90 (see FIG. 5).
[0091] In FIG. 13, recesses 56a are formed in the cathode block 56, while
protrusions 57a are formed on the collector bars 57. Alternatively,
protrusions may be formed on the cathode block 56 and recesses may be
formed in the collector bars 57.
[0092] [Seventh Embodiment]
FIG. 14 is a perspective view of a cathode 60 according to a seventh
embodiment of the present invention. According to the present embodiment,
a cathode block 61 and collector bars 62 are integrally formed. That is, the
cathode block 61 and collector bars 62 are fabricated by machining a single
raw material. The cathode 60, composed of a cathode block 61 and collector
16

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bars 62 that are integrally formed, is made of carbon.
[0093] According to the present embodiment, the cathode block 61 and
collector bar 62 are integrally formed, which means that there is no
interface.
As such, contact resistance is zero.
[0094] [Eighth Embodiment]
FIG. 15 is a perspective view of a cathode 65 according to an eighth
embodiment of the present invention. The cathode 65 includes a plurality
of cathode blocks 11 and two collector bars 67. According to the present
embodiment, too, the cathode blocks 11 and collector bars 67 are made of
carbon.
[0095] According to the present embodiment, each of the two collector bars
67 is in contact with the plurality of cathode blocks 11. This construction
achieves a large cross-sectional area of the collector bars 67, thereby
reducing electrical resistance.
[0096] In FIG. 15, two collector bars 67 are both in contact with seven
cathode blocks. Meanwhile, the above-described effects can be obtained if
at least one collector bar 67 is in contact with a plurality of cathode
blocks.
The number of cathode blocks is only required to be not smaller than 2.
That is, the cathode 65 is only required to include at least two cathode
blocks
(cathode block and second cathode block) and one or more collector bars,
where at least one of the collector bars is in contact with at least two
cathode
blocks.
[0097] Although embodiments of the present invention have been described,
the present invention is not limited to the above-illustrated embodiments
and various modifications are possible within the scope of the invention.
17

Representative Drawing
A single figure which represents the drawing illustrating the invention.
Administrative Status

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Administrative Status

Title Date
Forecasted Issue Date 2023-06-27
(86) PCT Filing Date 2017-05-29
(87) PCT Publication Date 2017-12-21
(85) National Entry 2018-12-14
Examination Requested 2022-01-19
(45) Issued 2023-06-27

Abandonment History

There is no abandonment history.

Maintenance Fee

Last Payment of $277.00 was received on 2024-05-13


 Upcoming maintenance fee amounts

Description Date Amount
Next Payment if standard fee 2025-05-29 $277.00
Next Payment if small entity fee 2025-05-29 $100.00

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Please refer to the CIPO Patent Fees web page to see all current fee amounts.

Payment History

Fee Type Anniversary Year Due Date Amount Paid Paid Date
Application Fee $400.00 2018-12-14
Maintenance Fee - Application - New Act 2 2019-05-29 $100.00 2019-03-27
Maintenance Fee - Application - New Act 3 2020-05-29 $100.00 2020-05-12
Maintenance Fee - Application - New Act 4 2021-05-31 $100.00 2021-04-26
Request for Examination 2022-05-30 $814.37 2022-01-19
Maintenance Fee - Application - New Act 5 2022-05-30 $203.59 2022-04-20
Final Fee $306.00 2023-04-28
Maintenance Fee - Application - New Act 6 2023-05-29 $210.51 2023-05-24
Maintenance Fee - Patent - New Act 7 2024-05-29 $277.00 2024-05-13
Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
SEC CARBON, LTD.
Past Owners on Record
None
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
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Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Request for Examination 2022-01-19 3 76
Examiner Requisition 2022-12-02 4 163
Amendment 2023-02-15 6 135
Final Fee 2023-04-28 3 82
Representative Drawing 2023-06-02 1 5
Cover Page 2023-06-02 1 36
Abstract 2018-12-14 1 17
Claims 2018-12-14 2 78
Drawings 2018-12-14 7 135
Description 2018-12-14 17 972
Representative Drawing 2018-12-14 1 5
Patent Cooperation Treaty (PCT) 2018-12-14 2 43
International Search Report 2018-12-14 2 66
Amendment - Abstract 2018-12-14 2 71
National Entry Request 2018-12-14 3 85
Cover Page 2018-12-24 1 33
Electronic Grant Certificate 2023-06-27 1 2,527