Note : Les descriptions sont présentées dans la langue officielle dans laquelle elles ont été soumises.
~- ~ (,/;
2152466
- ~O 94/14910 PCT/EP93/034~8
A neutral self-shine emulsion for the care of floors (IV)
This invention relates to a floor-care formulation
in the form of a dispersion which dries leaving a shine
on the floor. Formulations such as these are also known
as self-shine emulsions.
Nowadays, new previously untreated floors and floors
which have been subjected to thorough cleaning are mainly
treated with self-shine emulsions to protect them against
soiling and damage. These emulsions, which contain wax
and/or film-forming polymers in varying amounts, form
continuous, glossy and soil-repellent films on the floors
after drying. Films with a high percentage wax content
can easily be polished and, when necessary, are also easy
to remove from the surfaces whereas films consisting pre-
dominantly or completely of film-forming polymers are
particularly resistant to mechanical stressing. A prob-
lem affecting all self-shine emulsions, which has not yet
been completely solved, is that the emulsions or disper-
sions have to dry extremely uniformly on the surfaces if
a completely continuous protective film is to be formed.
It is very often found that the initially continuous film
of the aqueous dispersion breaks up on drying and, in
some cases, even contracts to form individual droplets so
that the floor-care film formed is patchy in appearance.
This effect is particularly noticeable in the case of the
dispersions with a substantially neutral pH value which
are preferred today. One of the problems addressed by
the present invention was to provide an improvement in
this regard. Another problem addressed by the invention
was to improve the stability of the dispersions, above
all during storage at low temperatures.
The present invention relates to an aqueous self-
shine emulsion for the care of floors which, in undiluted
2152466
_ Wo 94/14910 2 PCT/EP93/03488
form, has a pH value of 5 to 9 and which contains a natu-
ral or synthetic wax and a monoalkyl diethylene glycol
ether containing 1 to 4 carbon atoms in the alkyl moiety
or a mixture of such ethers. Self-shine emulsions with
a pH value in undiluted form of 6 to 8 are particularly
preferred.
The new self-shine emulsions are distinguished by
high stability in storage, particularly at low tempera-
tures. A particularly noteworthy feature is their
extremely uniform drying behavior characterized by the
virtual absence of cracks in the film, so that uniform
floor-care films of satisfactory appearance are obtained.
Another surprising feature of the formulations according
to the invention is that they are resistant to microbial
contamination so that there is no need for typical pre-
servatives to be added.
Suitable waxes for the self-shine emulsions accord-
ing to the invention are both natural waxes and synthetic
waxes which may be of natural origin or even fully
synthetic. Examples are polyethylene waxes, oxidized
polyethylene waxes, montan ester waxes, paraffin waxes,
candellila wax and carnauba wax. Of these waxes, montan
ester wax, paraffin wax, carnauba wax and polyethylene
wax are preferred in the formulations according to the
invention. Wax mixtures of montan ester wax and polyeth-
ylene wax and of montan ester wax and carnauba wax are
particularly preferred. The wax content in the formula-
tions according to the invention may be from 2 to 50% by
weight and is preferably from 2 and 15% by weight.
Unless predo~ ntly self-emulsifying waxes are
used, the emulsions according to the invention contain
typical wax emulsifiers in quantities of 0.1 to 10% by
weight and preferably in quantities of 0.5 to 3% by
weight. Examples of such emulsifiers are oleyl cetyl
alcohol ethoxylated with 20 moles of ethylene oxide (E0)
2152466
- Wo 94/14910 3 PCT/EP93/03488
and sorbitan monooleate.
The second characteristic component of the self-
shine emulsion according to the invention are monoalkyl
diethylene glycol ethers containing 1 to 4 carbon atoms
in the alkyl moiety which may of course also be used in
admixture with one another. Methyl diglycol, ethyl
diglycol and n-butyl diglycol are preferably used. In
conjunction with the waxes in the aqueous neutral emul-
sion, the ethers appear to be responsible for the unex-
pected properties of the new formulations mentionedabove. Small quantities of the ethers are generally
sufficient. Their percentage content in the formulations
according to the invention is from 0.05 to 11% by weight
and preferably from 3 to 8% by weight.
In addition to the waxes mentioned above, which make
up the predominant part of the solids in the formulations
according to the invention, the formulations may contain
film-forming polymers in dispersed form. The polymer
component is intended to make the floor-care films more
resistant to mechAn;cal damage. The polymer compounds
present in the self-shine emulsions are those which are
at least partly insoluble in water at a neutral pH value
and which have a minimum film forming temperature in the
range from about 0 to about 70C. The polymer compounds
in question are preferably polymers prepared from ethy-
lenically unsaturated monomers. Examples of such mono-
mers are styrene, acrylates or methacrylates of aliphatic
alcohols containing 1 to 8 carbon atoms, acrylonitrile,
vinyl acetate, acrylic acid and methacrylic acid.
Particularly preferred polymers are poly(meth)acrylates
of two or more of these monomers which may even contain
other monomers in small quantities. Most particularly
preferred polymers contain 1 to 30 parts by weight of
monomers contAining carboxylic acid groups, 30 to 70
parts by weight of monomers which form homopolymers with
2I 52~66
-- WO 9~./14910 4 PCT/EP93/03488
glass temperatures below 20 C, preferably esters of
acrylic acid with Cl8 alcohols and/or methacrylic acid
with C~-8 alcohols, and 30 to 70 parts by weight of
monomers which form homopolymers having glass tempera-
tures above room temperature, preferably methacrylates of
Cl3 alcohols or styrene. Where several different polymer
compounds of the type mentioned above are used in the
form of a mixture, the film forming temperature deter-
mined for the mixture should be in the range from 0 to
70C. The film forming temperatures mentioned apply to
the plasticizer-free system, i.e. to the polymers with no
further additives.
The polymers may be present in the formulations
according to the invention in quantities of up to 30% by
weight and, more particularly, in quantities of 2 to 10%
by weight. These figures apply to the pure polymers.
If the suspensions according to the invention are pro-
ducedd from dispersed polymers of the type often avail-
able on the market, the dispersions in question have to
be used in correspondingly larger quantities in the
production of the formulations according to the inven-
tion.
In addition to the ingredients mentioned above, the
self-shine emulsions according to the invention may con-
tain other active substances and auxiliaries in relative-
ly small quantities providing they do not adversely
affect the positive properties of the formulations.
Examples include plasticizers, wetting agents and flow
control agents, wetting resins, preservatives and perfume
oils.
Plasticizers are intended to modify the consistency
of the film, a distinction being drawn between temporary
plasticizers and permanent plasticizers. Temporary
plasticizers are volatile hydrophilic solvents which
promote the coalescence of the polymer particles during
2152466
Wo 9~/14910 5 PCT/EP93/0~488
film formation. Examples are ethylene glycol, diethylene
glycol and also glycol ethers. Their percentage content
in the formulations according to the invention is gener-
ally not more than 15% by weight and is preferably
between 0.5 and 10% by weight. Permanent plasticizers
are liquids which are not volatile under normal condi-
tions so that the character of the floor-care film can be
lastingly influenced with their assistance. Examples of
such plasticizers are dibutyl phthalate, tributyl phos-
phate, tributoxyethyl phosphate and N-methyl caprolactam.
Permanent plasticizers also are generally present in the
suspensions according to the invention in quantities of
not more than 15% by weight and preferably in a quantity
of 0.5 to 10% by weight.
Wetting agents and flow control agents are intended
to improve the wetting of the treated surface during
application of the self-shine emulsion. In addition,
they make the emulsion easier to dilute with water, for
example for application to wet floors. Suitable wetting
and flow control agents are any of the usual surfactants,
more particularly nonionic and anionic surfactants, for
example ethoxylates of long-chain alcohols or alkyl
benzene sulfonates and fatty alcohol sulfates. Fluorine
surfactants are also used in many cases and produce a
particularly mar~ed reduction in surface tension. The
content of wetting and flow control agents is generally
not more than 5% by weight, based on the total weight of
the self-shine emulsion, and is preferably between 0.1
and 2% by weight. Surface wetting during application can
also be improved with wetting resins. Wetting resins are
preferably styrene/maleate resins or clear polyacrylates.
Their content in the formulations is generally not more
than 5% by weight and is preferably from 0.1 to 2% by
weight.
The formulations may be prepared by standard suspen-
2152466
~0 94/14910 6 PCT/EP93/03488
ding processes. For example, they may be prepared by the
water-in-wax method or by the wax-in-water method. If
nece~c~ry, the pH of the formulation is adjusted to the
required value in the neutral range (pH 5 to pH g) by
addition of alkalis or acids.~
The self-shine emulsions according to the invention
are generally applied in undiluted form. The emulsions
are applied to the surface and uniformly distributed
thereon in the required quantity using a soft object, for
example a sponge or a cloth. After evaporation of the
water, an extremely uniform, glossy film is left on the
surface in this floor-care process.
Examples
A wax-in-water dispersion was first prepared from
the waxes and emulsifiers listed in the Table and then
mixed with the other components to form the final formu-
lations. Unless otherwise indicated, the figures in the
Table are percentages by weight, based on the pure active
substances. The self-shine emulsions thus prepared were
then tested for their stability during storage at low
temperatures and for their flow control properties.
To evaluate stability at low temperatures, the
samples were stored for 12 weeks at O to 3C. Over this
period, the samples were removed weekly from the freezer
and visually evaluated on reaching room temperature.
Visible signs of instability were flocculation, sediment,
deposits and changes in viscosity. Evaluation was~based
on the following scale:
O uniform, homogeneous sample
1 slight deposits or sediment after 12 weeks
2 slight deposits or sediment after 3 weeks
3 medium deposits or sediment after 3 weeks
4 heavy deposits or sediment after 3 weeks
2152466
- Wo 94/14910 7 PCT/EP93/03488
very heavy deposits or sediment after 3 weeks
The flow control properties were determined by
application to black untreated PVC sheets under condi-
tions which meet practical requirements. To this end, 10ml of the suspension to be tested were uniformly applied
by hand applicator to a 30 x 60 cm PVC tile in each test.
The applicator consisted of an upholstery velvet stretch-
ed over a frame with an effective surface area of 20 x
5.5 cm. After drying, the appearance of the surface was
visually evaluated on the following scale:
0 streak-free
1 faintly visible uniform streaks
2 distinctly visible streaks
3 distinct, uneven streaks
4 heavy uneven residues.
2 1 5 2 ~ 6 6
-_ Wo 94/14910 8 PCT/EP93/03488
Tabl~ 1
Example 1 2
Isothiazoline 0.02
Montan wax, dropping point 3.5 3.5
82 C
Ester wax, solidification 3.5 3.5
point 85C
Oleyl cetyl alcohol + 23 E0 0.5 0.5
Isotridecyl alcohol + 8 E0 1.0 1.0
Styrene acrylate MFT 45CC* 4.5 4.5
Zonyl FSJ (fluorine surfactant) 0.02 0.02
Diethyl ethanolamine 0.3 0.3
Perfume 0.2 0.2
Diethylene glycol mono-n- - 10.0
butyl ether
Water ad 100 ad 100
pH value 8.4 8.4
Stability in storage at 0-3C 3 0
Flow control properties 4
*MFT = minimum film forming temperature
The test results clearly reflect the advantageous
properties of self-shine emulsion 2 according to the
invention in relation to comparison formulation 1.
