Note : Les descriptions sont présentées dans la langue officielle dans laquelle elles ont été soumises.
CA 02220~20 l997-ll-07
W096/36764 PCT~S96/06802
METHOD FOR RECYCLING MIXED WASTEPAPER
USING INK AGGLOMERATION
Field o~ Invention
This invention generally relates to a method to
recycle mixed wastepaper including plastic containing
paper and printed paper. More particularly, it concerns
a process which deinks mixed wastepaper by agglomeration
- 10 of ink particles and the formation of ink/plastic
clusters which are removed by screening procedures to
produce a substantially ink and plastic free pulp medium
used to make recycled paper and board products.
Backqround Art
Separately, both printed office wastepaper and
plastic coated paperboard have been difficult to deink.
Office waste including non-impact (laser and xerox)
toners is not easily purified by conventional deinking
methods such as washing, flotation and dispersion.
Alternatively, agglomeration deinking methods are used
but are expensive procedures due to the high chemical
cost of the agglomeration chemicals used.
Recovery o~ paper fiber from milk cartons and other
types o~ liquid packaging or plastic coated or laminated
paper or paperboard is hampered by plastic contamination
in the recovered pulp. Slotted screens can be used to
remove plastic particles but are not entirely effective.
The liquid packaging often contains a wet strength
additive, which prevents e~ective repulping, and the
resulting flakes of unpulped paperboard tend to seal over
and plug the screen plates. Also, liquid packaging tends
to contain a signi~icant percentage o~ long so~twood
~ibers, which also make screening with ~ine slots more
di~ficult. The thin ~lexible plastic also tends to plug
fine slots, forcing the use o~ larger slots which
compromise the screening efficiency. Therefore, removal
o~ plastic cont~m~n~nts resulting ~rom laminated plastic
CA 02220~20 l997-ll-07
W096/36764 PCT~S96/06802
or plastic coatings remains a problem.
Conventional recycling processes utilize well
characterized and presorted grades of wastepaper. Mixed
wastepaper streams are not readily recycled because of
their non uniform properties and changing chemical
compositions of the constituents.
Separate processes for deinking various types of
printed paper and plastic coated paperboard are known in
the art. Representative of such processes include: U.S.
Patent No. 1,628,931 to Todd which discloses a process
for extracting wax from waste waxed paper by dissolving
in a solution of tri-sodium phosphate and soda ash; U.S.
Patent No. 2,776,209 to O'Flynn which discloses a method
for deinking and dewaxing wastepaper by repulping in a
non-acidic aqueous solution of urea; U.S. Patent No.
3,933,577 to Penque which discloses a method for
recycling municipal solid waste (garbage) by shredding
waste material and passing through an air elutriator to
separate into a heavy stream containing metals and a
light stream containing paper, plastics, etc.; and U.S.
Patent No. 4,332,638 to Mauer which provides a process
and apparatus for sorting long and short fibers from a
mixture of= different types of wastepaper, including
plastic coated paper.
The prior art describes separate methods for
deinking printed wastepaper and plastic coated
paperboard. However, the art has not shown a deinking
process for recycling a combined mixture of printed
wastepaper and plastic coated paperboard to produce clean
pulp. The invention is directed to the provision of such
a process in which simultaneous repulping of a mixture of
plastic coated and printed paper and contact with a
deinking chemical presents a synergy in which separated
plastic components attract and e~ectively adsorb ink
agglomerates to form ink/plastic clusters. These
CA 02220~20 1997-11-07
W096136764 PCT~S96106802
clusters are readily removed from the pulp medium to
produce a high level of pulp cleanliness for creating
recycled paper products. Further advantages of the
invention over prior practices include repulping both
long fibered paperboard pulp with short fibered office
waste paper together which makes the removal steps
easier, particularly the screening stages, and prevents
the screens from becoming overloaded with plastic and
flakes of unpulped paperboard. It further allows the use
of fine slotted screens for complete removal of plastic
from the pulp.
There is a need in the art for processes which are
less complex to produce recycled paper. This invention
is directed to the provision of such processes which have
wide range applications in creating recycled paper with
a high level of cleanliness, and using a low dosage of
agglomeration chemical.
Accordingly, it is a broad object of the invention
to provide a deinking process for the recycling of
plastic coated and printed paper.
Another object o~ the invention is to provide a low
cost deinking process that effectively and efficiently
removes ink and plastic particles without using high
concentrations of expensive agglomeration chemicals.
A still further object of the invention is to
provide a recycled paper product having improved strength
and a high level of cleanliness made ~rom recycled
plastic containing paper and printed wastepaper.
Disclosure of Invention
In the present invention, these purposes, as well as
others which will be apparent, are achieved generally by
~ providing a process for recycling a combined mixture of
plastic containing paper and printed paper to produce
clean pulp which is ~ree o~ both ink and plastic
CA 02220~20 1997-11-07
W096/36764 PCT~S96106802
contamination.
The process includes repulping the two types of
wastepaper together in a repulping vessel, preferably a
hydrapulper, to disperse the paper fibers, ink and
plastic components into a pulp medium. The pulp medium
is contacted with a deinking chemical which causes
attraction between the ink components to form larger ink
particles. The repulping and contact with the deinking
chemical may be simultaneous or in separate steps.
Process and reaction conditions are controlled in the
repulping vessel so that e~ective agglomeration of the
ink particles is accomplished. Any deinking chemical
capable o~ causing agglomeration of the ink particles can
be employed. Concentrations of the deinking chemical, as
well as the pH and temperature of the pulp medium are
adjusted to yield maximum agglomeration of the ink
particles. The separated plastic attracts and
effectively scavenges the ink agglomerates in the
hydrapulper to form ink/plastic clusters.
In addition, oxidizing agents such as sodium
hypochlorite and persulfate compounds can be added to the
hydrapulper to assist in breaking down any wet strength
additives that may be present in the liquid packaging
(plastic containing) wastepaper.
Following repulping, screening and cleaning
procedures are used for removal of the ink/plastic
clusters and other rem~;n1ng plastic and ink particles.
At least one screen preferably has a slot width in the
range o~ 0.004" to O.OlO". In addition, after screening,
centri~ugal cleaners may be used ~or ~urther removal o~
ink and plastic particles. The resulting substantially
ink and plastic ~ree pulp medium has a speck removal and
brightness level sufficient to produce recycled paper
products.
Preferred applications of the method of the
CA 02220~20 lss7-ll-07
W096/36764 PCT~S96/06802
invention include use in deinking plastic coated and
printed paper to produce high-grade recycled printing and
writing paper, or other products such as tissue and
towelling, bag grades or board products. Advantageously,
the deinking method of the invention provides a process
for recycling plastic coated and printed paper that is
less complex and expensive than known agglomeration
processes.
The method provides efficient removal of ink by
agglomeration onto the plastic surface reducing the
dosage of agglomeration chemical required. In addition,
since the agglomerated ink is attached to plastic it is
readily thickened for burning or landfilling in contrast
to the ink separated from a flotation deinking system
which is difficult to thicken. The method also provides
efficient removal of plastic cont~m;n~nts by using finer
slotted screens than can be used on the plastic coated
paper when it is processed alone.
Other objects, features and advantages of the
present invention will be apparent when the detailed
description of the preferred embodiments of the invention
are considered in con~unction with the drawings, which
should be construed in an illustrative and not limiting
sense as follows:
Brief Description of the Drawinqs
FIGURE 1 is a diagrammatic view o~ the general
process steps of the invention for deinking of mixed
wastepaper;
FIGURE 2 is a schematic view of the apparatus for
recycling mixed wastepaper in accordance with the process
of the invention;
FIGURE 3 is a graphic illustration o~ the
synergistic effect o~ the formation o~ ink/plastic
clusters on the ink content in deinked pulp; and
CA 02220~20 l997-ll-07
W096/36764 PCT~S96/06802
FIGURE 4 is a graphic illustration of the screening
efficiency of plastic containing wastepaper.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
-With further reference to the drawings, FIG. 1 is a
diagrammatic view of the general process steps for the
deinking of the mixed wastepaper, including plastic
containing and printed paper.
Repulping o~ the plastic containing and printed
paper occurs in a repulping vessel to disperse paper
fibers, ink and plastic components into a pulp medium 1.
During, or after repulping, the pulp medium is contacted
with a deinking chemical. The presence of the deinking
chemical causes the ink components to form larger ink
particles. The separated plastic component attracts the
ink to form ink/plastic clusters. The pulp medium is
passed through one or more steps of screening or
centrifugal cleaning 2, to remove the ink/plastic
clusters and ink and plastic cont~m;n~nts to produce a
substantially ink and plastic free pulp medium 3. The
clean pulp medium can then be made into a recycled paper
product through conventional papermaking techniques.
The mixed wastepaper is selected ~rom the group
consisting of plastic containing paper or paperboard,
non-impact or impact printed paper or paperboard, and
mixtures thereof. The wastepaper includes both wood
containing and wood ~ree grades o~ paper. Various types
of paper or paperboard may be used in this invention
including sorted or unsorted computer printout paper,
writing paper, fine paper, coated and uncoated magazine
paper, newsprint and packaging board. Also, various
types of plastic containing paper and paperboard,
including gable-top milk and juice cartons, aseptic
packaging, polyethylene coated, polyester coated or
CA 02220~20 lss7-ll-07
W096/36764 PCT~S96/06802
complex layered coatings or laminations including
aluminum foil, or scrap from the manufacturing operations
for liquid packaging, may be used in the invention
process. This list is merely representative of the
different types of plastic coated and printed paper and
is not considered to be inclusive of all the possible
types of printed paper which may be used in the
invention.
The mixed wastepaper can generally comprise up to
75~ plastic coated wastepaper, since over 75~ typically
results in screening problems. Figure 4, discussed in
detail later, illustrates the screening efficiency limits
of plastic containing wastepaper Typically, plastic on
the liquid packaging and coated paperboard during its
manufacture has been corona treated or flame treated for
the adherence of printing ink to the plastic surface.
This trea~ment i~ ved t~ increas~ the adherence ~f
the ink particles to the plastic surface during the
process of the invention. The plastic is typically
polyethylene or polyethylene terephthalate (PET). Thus,
this type of plastic would be expected to attract ink
particularly well and act as a substrate for ink
agglomeration to form ink\plastic clusters of a size
which can then be readily removed from the pulp medium.
The repulping action causes ink particles and
plastic components to separate from the wastepaper
fibers. The presence of a deinking agent enhances the
separation of the ink from the fiber surface and in
addition changes the chemistry of the ink particles by
causing them to become more hydrophobic. This results in
formation of ink agglomerates since the ink particles are
more attractive to each other and then in turn are more
attractive to the plastic. As stated the ink present on
the plastic coated wastepaper typically remains on the
plastic during repulping due to the corona or flame
CA 02220~20 l997-ll-07
W096/36764 PCT~S96/06802
treatment during manufacture.
Typically the pH of the aqueous medium during
agglomeration is in the range of 8-13. The pH is
controlled so that there is a balance between the
"dispersion" action of the ink from the fibers and the
"agglomeration" action of the separated ink particles.
If the pH is too high this balance is disrupted and small
ink particles may remain dispersed ln the medium as
opposed to being attracted to each other to form larger
agglomerates. A high pH, i.e. 9-13, is desirable for
helping to break down some types of wet strength
additives present in liquid packaging. A preferred
alkaline pH of 8-12 helps to release ink from the surface
of the printed paper without significant "dispersion"
thereby helping agglomeration.
FIG. 2 is a schematic view of an apparatus,
generally designated 10, for practicing the deinking
process of the invention. As shown in FIG. 2, the mixed
wastepaper is repulped in an aqueous medium at
hydrapulper 12 with an agglomeration deinking chemical to
produce a pulp medium including ink and plastic
components.
Concentrations of the deinking chemical, as well as
the pH and temperature of the pulp medium are adjusted to
yield maximum agglomeration of the ink particles.
Preferably the repulping is carried out at temperatures
in the range of 120 to 200~F for 15 to 90 minutes. The
pulp consistency in the hydrapulper is pre~erably 7 to
15~ at an alkaline pH, preferably in the range of 8 to
13. This is in contrast to repulping only plastic coated
paperboard with is optimally repulped at 16 to 20
consistency. These higher consistencies were found to
produce excessive breakdown of the ink agglomerates in
the repulping vessel which is detrimental to ink removal.
Pulp consistency below 7~ produces slow repulping of the
CA 02220~20 lss7-ll-07
W096/36764 PCT~S96/06802
paper and higher chemical usage.
The repulping is preferably done in an alkali
aqueous medium, with sodium hydroxide added to speed the
repulping and to aid in the separation of ink particles
from the pulp fibers. The addition of organic or mineral
solvents are not required for the synergistic effect of
the invention process in which the separated plastic
components attract and effectively adsorb ink
agglomerates to form ink/plastic clusters. However,
small quantities of solvents may be added to improve the
ink agglomeration action. Use of such solvents in the
invention process is generally not desirable because of
environmental problems in using such materials.
Ambient temperature is normally preferred in
conventional deinking processes when using highly
contaminated waste in the hydrapulper since at higher
temperatures cont~m;n~nts, such as stickies, would break
down making them difficult to remove. However, in this
invention the stickies tend to agglomerate with the ink
on the surface of the plastic which protects the stickies
from further breakdown.
Conditions during repulping in the hydrapulper are
controlled so that the ink agglomerates being formed are
not being broken down by the mechanical action of the
hydrapulper. The plastic provides a surface similar to
the surface of a solid ("heterogeneous") catalyst or
"collector" where fine ink particles are attracted to
agglomerate with other ink particles. The rate of
formation of agglomerates then becomes much greater than
the rate of agglomerate breakdown by the attrition in the
hydrapulper.
The pulp medium is then typically passed to a
detrashing device to remove larger pieces of plastic,
wood, metal, paperclips, etc., followed by a liquid
cyclone device to remove heavy debris such as staples and
CA 02220~20 l997-ll-07
W096l36764 PCT~S96/06802
--10--
glass. Coarse screening is done to remove other smaller
cont~;n~nts which might plug or damage the slotted
screen.
The pulp medium is passed through pressurized ~ine
screens 14, having slots of width between 0.004" to
O.OlO". Pre~erably, secondary and tertiary screening
stages are often used for both coarse and fine screening
to reduce the loss of good fiber from the system.
The slotted screens, remove a large percentage of
the stickies from the system, including adhesives from
self-stick envelopes and labels. Removal of the stickies
is critical during the deinking process. High efficiency
stickies removal by the fine screens is achieved in the
system by maintaining the screening temperature at 130~F
or less, so that the stickies do not become softened and
more de~ormable ~or extrusion through the slots into the
pulp accepts stream.
The large ink particles are easily separated into
the centrifugal cleaner rejects, and are removed from the
system for disposal by landfilling or burning or for
other uses. High ef~iciency in the cleaners 16 is
required for fine ink removal which is achieved by using
a smaller diameter cleaner, or using a higher pressure
drop or a lower pulp consistency.
Preferably the deinking chemical is present at a
dosage ranging from between O.l - 2.0~ by weight
calculated on the dry weight of the pulp used. Any
deinking chemical capable of causing agglomeration of ink
particles can be employed. Many of these agents are
surfactants which make the ink hydrophobic and induce a
tendency to agglomerate. For example, deinking agents
such as Sansink PM-201 available from PPG Industries,
Inc., Pittsburg, PA and BRD 2311 available from Buckman
Laboratories, Memphis, Tennessee are suitable for use in
the invention process. Agglomerating agents may also
CA 02220~20 lss7-ll-07
W096/36764 PCT~S96/06802
--11--
comprise polymeric materials which act as collectors to
increase the size of the agglomerates such as the PX-101
by PPG Industries. Any of these agents or other similar
commercially available deinking agents may be used in the
present invention process. The process of agglomeration
of ink particles has also been referred to as
"aggregation", "densification", or "dispersion", and
these terms are used interchangeably to describe the same
process. (See J.K. Borchardt, Proceedings of TAPPI 1993
Pulping Conference, page 839). The agglomeration
chemical may be chosen to be suitable for the type of
wastepaper being used.
For decreasing lightweight cont~m'n~nts, including
hot melts, stickies, wax, latex, adhesives, styrofoam and
lightweight plastics, the deinking process of the
invention can include a number of additional steps. The
use of reverse cleaners, through-flow cleaners, rotary
cleaners or combination cleaners which remove both heavy
and light debris can be effective.
Flotation deinking can be used ~or additional ink
removal, but this step should not be necessary. Also, to
achieve a brightness increase in the final ink and
plastic free pulp medium dissolved air flotation or
clarification can be used on the grey water from the
final pulp thickener.
In yet another alternative embodiment, additional
sets of forward cleaners can be added for further
improvement in the cleanliness of the pulp.
In addition, oxidizing agents such as persulfate
compounds or sodium hypochlorite can be used for
enhancing the breakdown of the wet strength additives
present in the paperboard, thus reducing the batch time,
bleaching the pulp and controlling odor and
mlcroorganlsms.
The substantially ink and plastic free pulp medium
CA 02220~20 l997-ll-07
W096/36764 PCT~S96/06802
is made into a paper or paperboard product by
conventional papermaking techniques. These recycled
paper products have improved strength as compared to
recycled paper products produced solely from recycled
printed o~ice waste. O~ice wastepaper contains ~illers
such as calcium carbonate and has lower strength
properties than plastic coated paper or paperboard. The
plastic coated paper or board generally has no ~illers
and has a higher pulp strength due to a higher so~twood
(long ~iber) content and low ash content. Thus a
recycled product made ~rom the pulp medium produced in
accordance with the invention will have a higher strength
and lower ash content than paper made ~rom o~ice waste
alone.
Table I below illustrates the higher so~twood
content and lower ash content o~ pulp recovered ~rom
plastic containing wastepaper, i.e. milk cartons.
Samples #1 to 4 represent commercially available deinked
pulps produced ~rom o~ice waste and other grades o~
wastepaper, not including any plastic containing
wastepaper. The ash content was measured a~ter
combustion in a mu~le ~urnace at 500 ~C.
TABLE I
MILK SAMPLE SAMPLE SAMPLE SAMPLE
CARTON #1 #2 #3 #4
PULP
FIBER ANALYSIS
~ SOFTWOOD79 35 26 28 27
~ HARDWOOD 21 59 71 70 66
~ GROUNDWOOD 0 6 3 2 7
ASH C~N1'~N'I' _ 0.3 3.1 3.5 3-6 1-8
The following examples illustrate advantages o~ the
process ~or deinking mixed wastepaper over known
practices. Example I is a control in which only printed
wastepaper was repulped with a deinking chemical. In
CA 02220~20 lss7-ll-07
W096l36764 PCT~S96/06802
-13-
Example II, the same reaction conditions as Example I
were used except that plastic containing paperboard was
included in the repulping vessel in addition to the
printed wastepaper and deinking chemical.
These examples are merely representative and are not
inclusive of all the possible embodiments o~ the
invention.
EXAMPLE I
Three hundred pounds (300 lb) of white office
wastepaper, containing approximately equal amounts of
impact and non-impact printed paper, was repulped for 60
minutes in a 5' diameter hydrapulper equipped with a
turbine type rotor at 11~ pulp consistency, 160 ~F and a
pH of lO. A dosage of 0.8~ agglomeration deinking
chemical which is a mixture of alcohols and nonionic
surfactants was used, calculated on oven dry waste paper.
The pulp was then extracted through 3/8" holes in the
bedplate of the pulper and screened using a pressure
screen equipped with 0.050" holes. The screen did not
remove a substantial amount of the agglomerated ink and
the screened pulp had a TAPPI speck count of 1899 ppm
(TAPPI Method T-213).
The average size of the ink agglomerates in the ~eed
to the pressure screen was 0.3 sq.mm and very ~ew o~
these particles were large enough to be removed by the
pressure screen.
EXAMPLE II
The conditions in Example I were repeated using a
2:1 ratio o~ o~ice waste to post-consumer milk cartons.
The plastic coating separated from the milk cartons, and
the agglomerated ink was adsorped onto the plastic to
form ink/plastic clusters. A majority o~ the ink/plastic
clusters were large enough to be removed by the
pressurized screen. The smallest of the ink/plastic
clusters in the feed to the screen was about 1.5 sq.mm in
CA 02220~20 l997-ll-07
W096l36764 PCT~S96106802
-14-
size but most were much larger and were of irregular
shape. The majority of the ink was then removed with the
plastic in the screening stage using a screen having
0.050" perforations and the dirt count on the screened
pulp was reduced to 611 ppm.
With reference to Figure 3, wastepaper containing
lOO~ plastic coated paper produces a pulp with a low
speck count, because of its low initial ink content.
Office wastepaper has an extremely high ink content and
therefore makes dirty deinked pulp. In combining the
wastepaper streams the synergistic effect lowers the
speck content of the office wastepaper to that closer to
the plastic coated paper. In Figure 3 line A illustrates
the synergistic effect which results from the formation
of the ink/plastic clusters and line B is a theoretical
line which would occur if no ink/plastic clusters were
formed.
Deinked office wastepaper has a very low plastic
content due to very fine slotted screens which are used.
Wastepaper containing 75-lOO~ plastic containing material
cannot be screened with very fine slots because of
plugging problems caused by the plastic, by the longer
so~twood fibers and by unpulped flakes of ~iber. In
Figure 4 a graphic illustration shows that along line A
high efficiency screens with very fine slots are
effective ~or plastic removal. Along line B this
efficiency ~;m;n;shes because less efficient screens with
lower plastic removal must be used.
Unexpectedly, the present invention process provides
a method for recycling a combined mixture of plastic
containing and printed paper to produce clean pulp which
is free_of both ink and plastic contamination. As
illustrated in the examples the dif~erent properties and
compositions of the different wastepaper streams provide
formation of ink/plastic clusters which are easily
CA 02220~20 1997-11-07
W096/36764 PCT~S96106802
removed by further processing through slotted screens and
centrifugal cleaners to produce a substantially ink and
plastic free pulp medium. This recycled pulp has speck
removal and brightness levels sufficient to produce high-
grade recycled paper through conventional papermakingproce-sses.
The simplicity of the equipment used and the high
amount of ink and plastic removal without dependence on
a particular deinking chemical formulation make the
deinking process of the invention advantageous over prior
art practice.
Advantageously, the method of this invention for
deinking printed paper is less complex than conventional
deinking processes involving washing and flotation
procedures. Further advantage of the process of the
invention is in the utilization of low quality and low
cost wastepaper, i.e. office waste and milk cartons that
are polyethylene coated, which is difficult to recycle.
It will be recognized by those skilled in the art
that the invention has wide application in recycling a
variety of plastic coated and printed paper to produce a
high quality pulp.
Numerous modi~ications are possible in light of the
above disclosure such as application o~ alternative
agglomeration deinking chemicals chosen according to the
wastepaper treated. In addition, alternative process
parameters may be employed in the invention, which
include using the deinking agent with no pH ad~ustment to
the wastepaper; using the deinking agent in an alkali pH
range; or using the deinking agent in the presence o~
other chemicals suitably employed in a deinking and/or
papermaking process such as oxidizing agents, bleaching
agents, defoamers, sizing agents, brighteners, and water
quality processing agents among others.
Therefore, although the invention has been described
CA 02220~20 l997-ll-07
W096/36764 PCT~S96/06802
-16-
with re~erence to certain pre~erred embodiments, it will
be appreciated that other composite structures and
processes ~or their ~abrication may be devised, which are
nevertheless within the scope and spirit o~ the invention
as de~ined in the claims appended hereto.
