Note : Les descriptions sont présentées dans la langue officielle dans laquelle elles ont été soumises.
CA 02813001 2013-04-11
METHOD OF CONTROLLING A RECOVERY AND
UPGRADING OPERATION IN A RESERVOIR
CROSS REFERENCE TO RELATED APPLICATION
The present application claims the benefits, under 35 U.S.C. 119(e), of U.S.
Provisional Applications Serial No. 61/026,594 filed February 6, 2008,
entitled "Method of
Controlling a Thermal Recovery and Upgrading Operation in a Reservoir" to Gil
and Serial
No. 61/030,817 filed February 22, 2008, entitled "Method of Controlling a
Thermal
Recovery and Upgrading Operation in a Reservoir" to Gil, both of which are
incorporated
herein by these references.
FIELD
The present invention relates generally to a method and means of generating a
range of petroleum products from bitumen or heavy oil reservoir and
specifically to the in
situ generation of the products from bitumen or heavy oil.
BACKGROUND
Oil is a nonrenewable natural resource having great importance to the
industrialized world. The increased demand for and decreasing supplies of
conventional
oil has led to the development of alternate sources of oil such as deposits of
bitumen and
heavy crude as well as a search for more efficient methods for recovery and
processing
from such hydrocarbon deposits.
There are substantial deposits of oil sands in the world with particularly
large
deposits in Canada and Venezuela. For example, the Athabasca oil sands region
of the
Western Canadian Sedimentary Basin contains an estimated 1.3 trillion bbls of
potentially
recoverable bitumen. An equally large deposit of bitumen may also be found in
the
Carbonates of Alberta. There are lesser, but significant deposits, found in
the U.S. and
other countries. These oil sands and carbonate reservoirs contain a petroleum
substance
called bitumen or heavy oil. Bitumen deposits cannot be economically exploited
by
traditional oil well technology because the bitumen or heavy oil is too
viscous to flow at
natural reservoir temperatures.
When oil sand deposits are near the surface, they can be economically
recovered
by surface mining methods. For example, surface mining of shallower deposits
in the
Alberta oil sands is currently accomplished by large power shovels and trucks
to feed a
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primary bitumen extraction facility, which, in turn, feeds an upgrader
facility where it is
refined and converted into crude oil and other petroleum products.
When oil sand deposits are too far below the surface for economic recovery by
surface mining, bitumen can be economically recovered in many, but not all,
areas by
recently developed in-situ recovery methods, such as Steam Assisted Gravity
Drain
("SAGD") or other variants, and combinations of gravity drain technology, such
as Heat
Assisted Gravity Drain ("HAGD") and VAPEX, which can mobilize the bitumen or
heavy oil. The principal method currently being implemented on a large scale
is Steam
Assisted Gravity Drain ("SAGD"). Typically, SAGD wells or well pairs are
drilled from
the earth's surface down to the bottom of the oil sand deposit and then
horizontally along
the bottom of the deposit. The wells or well pairs are then used to inject
steam and collect
mobilized bitumen.
Horizontal and/or vertical wells may also be installed and operated from an
underground workspace, such as described for example in US Patent Application
Serial
Number 11/441,929, entitled "Method for Underground Recovery of Hydrocarbons",
and
US Patent Application Serial Number 11/737,578, entitled "Method of Drilling
from a
Shaft", which are incorporated herein by reference. These horizontal and/or
vertical wells
may also be operated as HAGD wells, such as described, for example, in US
Patent
Application Serial Number 12/327,547, entitled "Method of Recovering Bitumen
from
Tunnel and Shaft with Electrodes, Heating Elements and Recovery Wells", which
is
incorporated herein by reference.
HAGD is a relatively new process for mobilizing bitumen in the Alberta oil
sands
or carbonates. Electric heater elements are embedded in the reservoir material
and used,
in place of steam, to heat the formation until the bitumen becomes fluid
enough to flow by
gravity drainage. HAGD may require more energy than SAGD but may be used in
reservoirs where SAGD cannot such, as for example, reservoirs with poor steam
caps.
HAGD and SAGD may also be used in combination where HAGD elements are used to
melt the bitumen around the steam injectors, which allows the steam chamber to
form more
quickly. An exemplary means of producing bitumen or heavy oil is described in
US 7,066,254 to Vinegar, et al. entitled "In Situ Thermal Processing of a Tar
Sands
Formation", which is incorporated herein by reference.
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In most thermal recovery operations, 6 to 10 API bitumen is the principal
petroleum product recovered. Typically, this bitumen must be de-sulfurized and
upgraded
to about to about 32 to 36 API to produce a marketable low sulfur crude
comparable to
West Texas intermediate.
Even the most efficient SAGD or HAGD operation requires substantial amounts of
energy to deliver the required amount of steam or heat to the reservoir to
mobilize the
bitumen. If this energy is obtained by burning fossil fuels, there is the
potential to
generate significant amounts of carbon dioxide emissions during recovery
operations. In
an exemplary SAGD operation having an average Steam-Oil-Ratio ("SOR") of 3,
the
energy required to produce high quality steam to recover 1 barrel of heavy oil
or bitumen
oil is equivalent to about 'A of a barrel of oil (the SOR is determined by the
number of
barrels of water required to produce the steam divided by the number of
barrels of oil or
bitumen recovered). Thus, oil produced by thermal recovery methods has the
potential to
generate 25% or more carbon dioxide emissions than oil recovered by pumping
from
conventional oil wells.
In addition, the upgrading process when carried out underground, such as
described
for example in US 7,066,254 or at a surface refmery can generate additional
carbon dioxide
and other unwanted emissions.
Because of global warming concerns, this potential for substantially
increasing
carbon dioxide emissions may outweigh the economic and other advantages of
producing
the enormous reserves of unconventional hydrocarbon deposits available.
There remains, therefore, a need for a method for a controllable recovery
process
that can accomplish a significant amount of in-situ upgrading of bitumen after
it has been
mobilized within the producing reservoir, and this need includes a method that
substantially
reduces or eliminates unwanted emissions, principally carbon dioxide
emissions.
SUMMARY
These and other needs are addressed by the present invention. The various
embodiments and configurations of the present invention are directed generally
to a
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controlled application of reservoir temporal and spatial temperature profiles
not only to
recover hydrocarbons but also to convert in situ hydrocarbons into a number of
desirable
products, such as asphaltenes, jet fuel, diesel fuel, and heavy vacuum gas
oil.
In a first embodiment, a method includes the steps:
(a) providing a plurality of mobilizing wells for mobilizing hydrocarbons and
a
plurality of recovery wells to recover mobilized hydrocarbons, the mobilizing
and recovery
wells defining a portion of an underground deposit, the defmed portion
comprising solid,
liquid and gaseous hydrocarbons, wherein at least some of the mobilizing wells
and/or
recovery wells extend from an underground manned excavation;
(b) for a selected time interval, mobilizing, by the mobilizing wells,
hydrocarbons
from the defined portion while removing hydrocarbons from the defined portion,
wherein,
during mobilization, the defmed portion is at a first temperature of no more
than about
350 C;
(c) after a selected time interval, heating a first zone of the defmed portion
of the
deposit to a temperature above 350 C and sufficient to convert at least a
portion of the
remaining solid and/or liquid hydrocarbons into at least one of asphaltenes,
jet fuel, diesel
fuel, and heavy vacuum gas oil; and
(d) removing the at least one of asphaltenes, jet fuel, diesel fuel, heavy
vacuum gas
oil and gaseous hydrocarbons from the underground deposit.
In a second embodiment, a method includes the steps:
(a) providing a plurality of mobilizing wells comprising at least one of steam
injectors, diluent injectors, and heating elements for mobilizing and
mobilizing
hydrocarbons, a plurality of heating wells to thermally heat and crack
hydrocarbons into
desired products, and a plurality of recovery wells to recover mobilized
hydrocarbons and
products derived therefrom, the mobilizing, heating, and recovery wells being
positioned in
a selected portion of an underground deposit, the selected portion comprising
liquid and
gaseous hydrocarbons, wherein at least some of the mobilizing wells, heating
wells, and/or
recovery wells extend from an underground manned excavation;
(b) for a selected time interval, mobilizing, by the plurality of mobilizing
wells,
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portion, wherein the selected portion is at a first temperature of no more
than about 350 C;
(c) after a selected amount of hydrocarbons are removed from the selected
portion,
heating, by the heating wells, a first zone of the selected portion of the
deposit to a
temperature above 350 C and sufficient to convert at least a portion of the
liquid
hydrocarbons remaining in the selected portion into at least one of
asphaltenes, jet fuel,
diesel fuel, and heavy vacuum gas oil; and
(d) removing the at least one of asphaltenes, jet fuel, diesel fuel, and heavy
vacuum
gas oil from the selected portion of the underground deposit.
In a third embodiment, a system includes:
mobilizing well means for mobilizing, for a selected time interval, a selected
portion of an underground hydrocarbon-containing deposit to a first
temperature of no
more than about 350 C;
recovery well means for removing a selected amount of hydrocarbons from the
selected portion; and
heating well means for heating a first zone of the selected portion of the
deposit to a
temperature above 350 C and sufficient to convert at least a portion of the
liquid
hydrocarbons remaining in the selected portion into asphaltenes, at least one
of jet fuel and
diesel fuel, and heavy vacuum gas oil, wherein the recovery well means removes
the
asphaltenes, at least one of jet fuel and diesel fuel, and heavy vacuum gas
oil from the
selected portion of the underground deposit and wherein at least some of the
mobilizing
well means and/or recovery well means extend from an underground manned
excavation.
The recovery processes of the above embodiments, when operated in a preferred
manner, emit no significant carbon dioxide during thermal recovery and
upgrading phases
of operations. Control is accomplished by installing wells for various
functions from a
combination of surface and underground well-head platforms. Any recovery
process and
system can use a combination of reservoir recovery and heating techniques
based on
various injector and/or heating apparatuses installed by wells into the
reservoir from
underground; product production wells installed from underground or from the
surface;
diluent and/or steam injection wells installed from underground or from the
surface; gas
disposal injection wells installed from underground or from the surface; gas
scavenging
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and collection vacuum wells installed from the surface; carbon dioxide EOR
injection wells
installed from the surface; and water disposal wells installed from
underground or from the
surface. This arrangement of wells installed from the surface and underground
can allow
thermal control of various zones of the reservoir so that various petroleum
products can be
recovered directly from the reservoir. In addition, surface or underground
facilities can be
provided that treat recovered water; prepare and segregate various petroleum
products,
capture emissions especially carbon dioxide; and generate power for heating
elements and
steam generation with excess power being available to be sold. Thus, by
effective use of
surface and underground facilities, a bitumen reservoir may be operated as a
recovery and
partial upgrading facility, thereby substantially reducing energy expenditures
and
eliminating unnecessary emissions, especially carbon dioxide.
In one configuration, suitable for smaller operations, a gas turbine power
plant and
/or a steam power plant are used to generate electrical power and energy. In
another
configuration, suitable for larger operations a nuclear reactor is used to
generate electrical
power and energy.
The following definitions are used herein:
"At least one", "one or more", and "and/or" are open-ended expressions that
are
both conjunctive and disjunctive in operation. For example, each of the
expressions "at
least one of A, B and C", "at least one of A, B, or C", "one or more of A, B,
and C", "one
or more of A, B, or C" and "A, B, and/or C" means A alone, B alone, C alone, A
and B
together, A and C together, B and C together, or A, B and C together.
A heating well as used herein is a well containing any type of heating
elements or is
a well capable of steam injection. That is, a heating well is any well used in
thermally
mobilizing an immobile hydrocarbons such, as for example, bitumen or heavy
oil.
Kerogen is a mixture of organic chemical compounds that make up a portion of
the
organic matter in sedimentary rocks such as oil shales. When heated to the
right
temperatures, some types of kerogen release oil or gas.
A mobilized hydrocarbon is a hydrocarbon that has been made flowable by some
means. For example, some heavy oils and bitumen may be mobilized by heating
them
and/or mixing them with a diluent to reduce their viscosities and allow them
to flow under
the prevailing drive pressure. Most liquid hydrocarbons may be mobilized by
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increasing the drive pressure on them, for example by water or gas floods, so
that they can
overcome interfacial and/or surface tensions and begin to flow.
A mobilizing well as used herein is a well whose function is to cause bitumen,
heavy oil or another hydrocarbon which does not readily flow, to be mobilized
and able to
flow to a recovery well. A well containing heating elements is an example of a
mobilizing well. A well from which steam and/or diluent may be injected into a
producing formation is another example of a mobilizing well. A well that can
be used to
operate a combination of heating elements, steam and diluent injection either
simultaneously or at different times is, in general, defmed herein as a
mobilizing well. A
heating well is a mobilizing well. A well for injecting diluent into a
reservoir is no a
heating well but is a mobilizing well since the diluent injection is a cold or
non-thermal
process. A mobilizing well may also be converted to a recovery well.
Primary production or recovery is the first stage of hydrocarbon production,
in
which natural reservoir energy, such as gasdrive, waterdrive or gravity
drainage, displaces
hydrocarbons from the reservoir, into the wellbore and up to surface.
Production using an
artificial lift system, such as a rod pump, an electrical submersible pump or
a gas-lift
installation is considered primary recovery. Secondary production or recovery
methods
frequently involve an artificial-lift system and/or reservoir injection for
pressure
maintenance. The purpose of secondary recovery is to maintain reservoir
pressure and to
displace hydrocarbons toward the wellbore. Tertiary production or recovery is
the third
stage of hydrocarbon production during which sophisticated techniques that
alter the
original properties of the oil are used. Enhanced oil recovery can begin after
a secondary
recovery process or at any time during the productive life of an oil
reservoir. Its purpose is
not only to restore formation pressure, but also to improve oil displacement
or fluid flow in
the reservoir. The three major types of enhanced oil recovery operations are
chemical
flooding, miscible displacement and thermal recovery.
A recovery well is a well from which a mobilized hydrocarbon such, as for
example, bitumen or heavy oil may be recovered.
A shaft is a long approximately vertical underground opening commonly having a
circular cross-section that is large enough for personnel and/or large
equipment. A shaft
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typically connects one underground level with another underground level or the
ground
surface.
A tunnel is a long approximately horizontal underground opening having a
circular,
elliptical or horseshoe-shaped cross-section that is large enough for
personnel and/or
vehicles. A tunnel typically connects one underground location with another.
An underground workspace as used in the present invention is any excavated
opening that is effectively sealed from the formation pressure and/or fluids
and has a
connection to at least one entry point to the ground surface.
A well is a long underground opening commonly having a circular cross-section
that is typically not large enough for personnel and/or vehicles and is
commonly used to
collect and transport liquids, gases or slurries from a ground formation to an
accessible
location and to inject liquids, gases or slurries into a ground formation from
an accessible
location.
Well drilling is the activity of collaring and drilling a well to a desired
length or
depth.
Well completion refers to any activity or operation that is used to place the
drilled
well in condition for production. Well completion, for example, includes the
activities of
open-hole well logging, casing, cementing the casing, cased hole logging,
perforating the
casing, measuring shut-in pressures and production rates, gas or hydraulic
fracturing and
other well and well bore treatments and any other commonly applied techniques
to prepare
a well for production.
It is to be understood that a reference to diluent herein is intended to
include
solvents.
It is to be understood that a reference to oil herein is intended to include
low API
hydrocarbons such as bitumen (API less than 400) and heavy crude oils (API
from 40* to
-20) as well as higher API hydrocarbons such as medium crude oils (API from -
20* to
-35 ) and light crude oils (API higher than -35). A reference to bitumen is
also taken to
mean a reference to low API heavy oils.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 is a schematic of the overall flow process of the present invention
with a
combustion-powered steam plant.
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Figure 2 is a schematic of the overall flow process of the present invention
with a
nuclear-powered steam plant.
Figure 3 is a schematic side view of a possible well placement for the present
invention.
Figure 4 is a schematic end view of a possible well placement and possible
zones of
hydrocarbon recovery for the present invention.
DETAILED DESCRIPTION
Mobilizing hydrocarbons such as bitumen or heavy oil, for example from oil
sands, may be accomplished using steam to heat the bitumen or heavy oil, or by
injecting
diluents to increase the API rating of the bitumen or heavy oil, or by a
combination of
steam and diluents. Other heating methods besides steam may also be used.
These
include, for example:
O electrodes for AC or DC ohmic heating of the reservoir material between
adjacent
electrodes;
0 thermal conduction heaters that heat the surrounding reservoir material
by thermal
conduction;
O electrodes for inductive heating of the surrounding reservoir material;
O high frequency RF, including microwave, heating of the surrounding
reservoir
material in which the heating element is typically called an RF antenna.
Where any of these heating methods (besides steam) may be used, they are
referred
to herein generally as heating elements. When a specific type of heating
method is
intended, it will be referred to by its specific name (ie ohmic electrode,
thermal conduction
heater, induction electrode, RF antenna).
A heating well as used herein is a well containing any of the heating elements
described above or is a well capable of steam injection.
A mobilizing well as used herein is a well whose function is to cause bitumen,
heavy oil or another hydrocarbon, which does not readily flow, to be mobilized
and able to
flow to a recovery well. A heating well which contains heating elements is an
example of
a mobilizing well. A well from which steam or diluent may be injected into a
producing
formation is another example of a mobilizing well. A well that can be used to
operate a
combination of heating elements, steam and diluent injection either
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simultaneously or at different times is, in general, defmed herein as a
mobilizing well. A
mobilizing well may also be converted to a recovery well.
A recovery well as used herein is a well from which a mobilized hydrocarbon
such,
as for example, bitumen or heavy oil may be recovered.
Figure 1 is a schematic of the overall flow process of the present invention
with a
combustion-powered steam plant. The main production is extracted from
production wells
132 and delivered to a Free Water Knock-Out ("FWKO") unit 101 where most of
the water
is separated from most of the liquid and gaseous hydrocarbons. Water is sent
from the
FWKO 101 to a de-oiling apparatus 102. The liquid hydrocarbon from the FWKO
101 is
sent to oil-treating apparatus 104 where it is prepared for storage in oil
storage tank 105.
The gaseous hydrocarbons from the FWKO 101 are added to other hydrocarbon
gases
collected from the reservoir via gas wells 131 and the combined gases are sent
to a natural
gas refrigeration plant 108. Water from the de-oiling apparatus 102 is
combined with
make-up water from a make-up water source such as for example water well 141
supplying
make-up water to storage apparatus 103. Most of the water from de-oiling
apparatus 102
and make-up water storage 103 is delivered to a Falling Tube Evaporator
apparatus 117.
The Falling Tube Evaporator apparatus 117 removes most of the impurities from
the water
and delivers suitably clean water appropriate for a boiler for Heat Recovery
Steam
Generator ("HRSG") 113. Most of the residual impute water from the Falling
Tube
Evaporator apparatus 117 is sent to a water disposal well 135. It is
understood that
reference to a Falling Tube Evaporator may also mean a Rising Tube Evaporator
since both
a Rising Tube and Falling Tube Evaporator accomplish the same function in
process of the
present invention.
Hydrocarbon and other gases are extracted from gas scavenging wells 131 and
delivered to a vacuum separator unit 106 and then compressed by compressor
107. These
gases are added to other hydrocarbon gases from the FWKO 101 and sent to a Gas
Refrigeration Plant 108. The temperature of Gas Refrigeration Plant 108 is
kept above the
boiling point of hydrogen sulphide so that only the Natural Gas Liquids
("NGLs") remain
as liquids. This process produces NGL products which are stored in a tank 109
for
delivery as products or use in other on-site activities. The NGL products are
typically
propane C3I-18, n-butane Calio and n-pentane C5H12. The Gas Refrigeration
Plant 108
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separates out most of the other gases such as, for example, methane CH4,
ethane C21169
carbon monoxide (CO), carbon dioxide (CO2), hydrogen sulphide (H2S) and
various oxides
of nitrogen ("NOxs") and sends these gases to an Amine Plant 110. The Amine
Plant 110
removes most of the carbon dioxide (CO2) and hydrogen sulphide (H2S) and sends
them to
compressor 111 to be compressed and injected into gas disposal wells 133.
Valuable and
useful gases such as methane CH4 and ethane C2116 are collected via path 153
and used for
other purposes such as fuels for a combustion gas turbine 115. As is well-
known, aqueous
monoethanolamine (MEA), diglycolamine (DGA), diethanolamine (DEA),
diisopropanolamine (DIPA) and methyldiethanolamine (MDEA) are widely used for
removing most of the carbon dioxide (CO2) and hydrogen sulphide (H2S) from
natural gas
streams and refmery process streams. They may also be used to remove most of
the CO2
from combustion gases or flue gases.
Electrical power for the facility is provided by a combustion gas turbine 115
via
path 151 and a steam turbine 114 via path 152. As can be appreciated, these
can be
separate power plants. In Figure 1, they are shown as a Combined Cycle Power
Plant.
The combustion turbine 115 uses fuel and air provided via path 142 where the
fuel may be
from the Amine Plant via path 153 or from an external natural gas source or
from a
combination of both sources. The hot exhaust gases from the combustion turbine
115 are
sent via path 182 to the HRSG 113 to provide some of the heat via an internal
heat
exchange system to generate steam. These gas turbine exhaust gases are then
sent from
the HRSG 113 via path 183 to CO2 capture apparatus 112. Some of the steam
generated
in HRSG 113 is used to provide steam to power steam turbine 114. Most of the
steam
generated in HRSG 113 is sent to steam injection wells 136 where it is used in
mobilizing
bitumen; maintaining desired reservoir temperature; and assisting reservoir
heating
elements (not shown here) to raise reservoir temperature when partial
upgrading is desired.
As described above, carbon dioxide and other combustion products generated in
combustion turbine 115 are sent to a CO2 capture apparatus 112. The CO2
capture
apparatus 112 may use a number of methods for capturing most of the CO2. The
flue
gases may be treated to remove particulate matter, NOxs, capture sulphur and
CO2. An
electrostatic precipitator process may be used to clean-up most of the
particulate matter.
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A catalytic converter process may be used for removing most of the NOxs. Most
of the
sulphur may be removed by injecting, for example, limestone (CaC04) and used
to capture
most of the SO x as gypsum (CaSO4) which is a saleable product. Most of the
carbon
dioxide may be removed and captured from the remaining flue gases by a
membrane
apparatus or other known processes. Some of the CO2 is captured and compressed
by
compressor 116 and may be sent back into the reservoir for Enhanced Oil
Recovery
("EOR") purposes via EOR injector wells 134. Nitrogen is emitted by the CO2
capture
apparatus 112 via path 154. Amine from Amine Plant 110 is also sent via path
171 to the
CO2 capture apparatus 112 where it recovers some CO2. This CO2-rich amine is
then
returned to Amine Plant 110 via path 172 where most of the carbon dioxide, any
hydrogen
sulphide and NOXs are removed and sent to compressor 111 to be compressed and
injected
into gas disposal wells 133.
An operation in the range of approximately 5,000 to 50,000 barrels per day
("bpd")
of bitumen processing is suitable for such a combustion-powered and steam
plant
embodiment. The power plant would typically be 120 MW for a 10,000 bpd
operation.
In a typical 10,000 bpd bitumen recovery operation with a Gas to Oil Ratio
("GOR") of
2, an estimated 100 thousand standard cubic feet ("Mscf') of gas may be
recovered. This
divides typically into about 80% methane and about 20% carbon dioxide.
Figure 2 is a schematic of the overall flow process of the present invention
with a
nuclear-powered steam plant. The main production is extracted from production
wells 232
and delivered to a Free Water Knock-Out ("FWKO") unit 201 where most of the
water is
separated from most of the liquid and gaseous hydrocarbons. Water is sent from
the
FWKO 201 to a de-oiling apparatus 202. The liquid hydrocarbon from the FWKO
201 is
sent to oil-treating apparatus 204 where it is prepared for storage in oil
storage tank 205.
The gaseous hydrocarbons from the FWKO 201 are added to other hydrocarbon
gases
collected from the reservoir via gas wells 231 and the combined gases are sent
to a natural
gas refrigeration plant 208. Water from the de-oiling apparatus 202 is
combined with
make-up water from a make-up water source such as for example water well 241
supplying
make-up water to storage apparatus 203. The water from de-oiling apparatus 202
and
make-up water storage 203 is delivered to a Falling Tube Evaporator apparatus
217. The
Falling Tube Evaporator apparatus 217 removes most of the impurities from the
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water and delivers suitably clean water appropriate for a boiler for Nuclear
powered steam
generator 213. Most of the residual impure water from the Falling Tube
Evaporator
apparatus 217 is sent to a water disposal well 235.
Hydrocarbon and other gases are extracted from gas scavenging and production
wells 232 and delivered to a vacuum separator unit 206 and then compressed by
compressor 207. These gases are added to other hydrocarbon gases from the FWKO
201
and sent to a Gas Refrigeration Plant 208. The temperature of Gas
Refrigeration Plant
208 is kept above the boiling point of hydrogen sulphide so that only the
Natural Gas
Liquids ("NGLs") remain as liquids. This process produces NGL products which
are
stored in a tank 209 for delivery as products or use in other on-site
activities. The NGL
products are typically propane C3118, n-butane C4H10 and n-pentane C51112. The
Gas
Refrigeration Plant 208 separates out most of the other gases such as, for
example, methane
CH4, ethane C2146, carbon monoxide (CO), carbon dioxide (CO2), hydrogen
sulphide (H2S)
and NOXs and sends these gases to an Amine Plant 210. The Amine Plant 210
removes
most of the carbon dioxide (CO2) and hydrogen sulphide (H2S). Valuable and
useful
gases such as methane CH4 and ethane C2H6 are collected via path 253 and used
for other
purposes such as fuels for auxiliary plant facilities or sold to a pipeline.
Some of the CO2
recovered from Amine Plant 210 is captured and compressed by compressor 216
and may
be sent back into the reservoir for Enhanced Oil Recovery ("EOR") purposes via
EOR
injector wells 234. Most of the remaining carbon dioxide, any hydrogen
sulphide and
NOXs recovered from Amine Plant 210 are removed and sent to compressor 211 to
be
compressed and injected into gas disposal wells 233.
Electrical power for the facility is provided via path 251 by a nuclear power
plant
comprised of a nuclear reactor 216, a heat exchange and steam generation
facility 213 and
a steam turbine 214. Some of the steam generated in heat exchange and steam
generation
facility 213 is used to provide steam to power steam turbine 214. Most of the
steam
generated in heat exchange and steam generation facility 213 is sent to steam
injection
wells 236 where it is used in mobilizing bitumen; maintaining desired
reservoir
temperature; and assisting reservoir heating elements (not shown here) to
raise reservoir
temperature when partial upgrading is desired.
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Cool water in heat exchange and steam generation facility 213 is sent via path
274
to nuclear reactor 216 where it is heated and returned via path 273 to heat
exchange and
steam generation facility 213 where it is used to generate steam for powering
steam turbine
214. Most of the excess heat from this steam is removed by sending the steam
via path
275 to, for example, a cooling tower 215. Most of the cooled steam or water is
then
returned to via path 276 to heat exchange and steam generation facility 213.
An operation in the range of approximately 50,000 to 200,000 barrels per day
("bpd") of bitumen processing is suitable for such a nuclear-powered steam
plant
embodiment. The power plant would typically be 1,200 MW for a 100,000 bpd
operation.
In a typical 100,000 bpd bitumen recovery operation with a Gas to Oil Ratio
("GOR") of 2,
an estimated 1 million standard cubic feet ("Mscf') of gas may be recovered.
This
divides typically into about 80% methane and about 20% carbon dioxide.
Figure 3 is a schematic side view of an example of well placement for the
present
invention. As can be seen from the descriptions of Figures 1 or 2, a complex
hydrocarbon
recovery and partial upgrading facility can involve several different types of
wells. These
are combinations of:
El reservoir heating elements placed into the reservoir from wells
installed from
underground;
0 hydrocarbon production wells installed from underground and/or from the
surface;
CI steam injection wells installed from underground and/or from the
surface;
El gas scavenging and gas production wells installed from the surface;
0 water disposal wells installed from underground and/or from the
surface;
El unwanted-gas disposal wells installed from underground and/or from
the surface;
0 carbon dioxide EOR injection wells installed from the surface.
Figure 3 shows a bitumen or heavy oil reservoir 303 overlain by overburden
formations 302 and having a basement formation 304. Many of the wells can be
installed
and facilities built on the surface 301. Many of the wells can also be
installed and other
facilities can also be located underground in tunnels as described in US
Patent Application
Serial No. 11/441,929 filed May 25, 2006, entitled "Method for Underground
Recovery of
Hydrocarbons" which is incorporated herein by this reference,
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CA 02813001 2013-04-11
or shafts as described for example in US Patent Application Serial
No.11/737,578 filed
April 19, 2007 entitled "Method of Drilling from a Shaft" which is also
incorporated herein
by this reference. Some tunnels 311 may be located in the reservoir 303 while
other may
be located in the basement formation 304. Tunnels (not shown) may also be
located
above the reservoir 304 in the overburden 302. Shafts connecting the tunnels
to the
surface 301 are not shown. These may be main shafts for bringing in men,
materials and
machines; ventilation shafts; and utility shafts used as conduits for produced
hydrocarbons,
steam, gas disposal, water disposal and the like. As an example, tunnel 312
may be used
to install horizontal wells 326 that contain heating elements that would be
used to provide
heating of the reservoir, especially the lower half of the reservoir. Examples
of these
might be various heating elements such as described in US Patent Application
Serial
No.12/327,547 filed December 3, 2008 entitled "Method of Recovering Bitumen
from
Tunnel and Shaft with Electrodes, Heating Elements and Recovery Wells" which
is
incorporated herein by this reference. Horizontal wells 326 may be closely
spaced with
service well-heads located in tunnel 312. Tunnel 311 may be used to install
horizontal
wells 323 that may be single wells or well pairs for steam injection into the
reservoir 305
and to install production wells to collect mobilized heavy hydrocarbons from
gravity drain,
especially the lower half of the reservoir. Horizontal wells 323 may also be
closely
spaced with service well-heads located in tunnel 312. As shown in Figure 3,
horizontal
wells 323 and 326 can be interleaved or offset both from the perspective of a
side view as
shown and from the perspective of a plan view (not shown). Horizontal wells
may also be
installed from some of the shafts mentioned previously as described for
example in US
Patent Application Serial No.11/737,578 entitled "Method of Drilling from a
Shaft".
Tunnel 312 could be designed as a manned tunnel as it is isolated from the
heat of
the reservoir. Tunnel 311 may be unmanned after start-up of reservoir heating
because of
the heat of the reservoir but could be accessed under certain conditions when
ventilation
can be used to provide a sufficiently cool working environment for limited
manned entry.
Figure 3 also shows an example of a gas or water disposal well 324 installed
from
underground in tunnel 311 and an example of a gas or water disposal well 325
installed
from the surface 301. Figure 3 also shows an example of horizontal wells 321
and 327
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CA 02813001 2013-04-11
installed from the surface 301. For example, wells such as well 321 can be a
gas
scavenging wells while wells such as well 327 can be steam or heater wells for
heating the
upper portion of the reservoir. As can be appreciated, horizontal wells or
well pairs
installed from the surface can also serve as steam injection and production
wells. Figure 3
shows process facilities 313, such as described in Figures 1 and 2 located on
the surface
301. As can be appreciated some facilities can be located underground in the
tunnels and
shafts. Examples of these might be well-head apparatuses and power sources for
producing steam such as described in US Patent Application Serial
No.11/864,011 filed
September 28, 2007 entitled "Method of Heating Hydrocarbons" which is
incorporated
herein by this reference.
By installing wells both from the surface and from underground, it is possible
to
maximize production, safety and cost effectiveness and, importantly, allow
better control of
hydrocarbon mobilization, recovery and in-situ upgrading. When a large number
of
accurately located horizontal wells is required, it is more effective to
install them from
underground so that cost per installed horizontal well is reduced and well
placement
accuracy improved. This is because the wells will be shorter by a significant
length
because they do not have to be drilled, typically at a 45 degree angle,
through the
overburden. For steam injection wells, energy efficiency is improved by
eliminating heat
losses in the portion of the wells penetrating the overburden. Gas and water
disposal
wells installed from tunnels or shafts can be better serviced from underground
especially if
leakages are detected. Gas and water disposal piping as well as steam and
hydrocarbon
production piping can be routed down utility shafts where they can be serviced
if necessary
when safe for manned entry. Electrical cables for power and control can be
routed down
utility or main access shafts.
Figure 4 is a schematic end view of a possible well placement and possible
zones of
hydrocarbon recovery for the present invention. This figure illustrates a
complex
hydrocarbon recovery operation from another perspective. By controlling the
temperature
history and temperature spatial distributions of various zones within the
reservoir, it is
possible to accomplish recovery of mobilized bitumen in the early phases of
operation and
then to accomplish some upgrading of the remaining bitumen in the middle and
latter
stages of operation. A typical reservoir section is shown in Fig. 4b showing
overburden
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CA 02813001 2013-04-11
402, reservoir zones 403 and basement formation 404. The reservoir 403 is
divided into 5
zones in this example, where the top zone 411 may produce NGLs with molecular
hydrogen to carbon ratios of about 2.2 (H/C =2.2) grading down to a zone 415
of coke
resin (asphaltenes) with molecular hydrogen to carbon ratios of about 135 (H/C
=1.35).
The other zones may produce naphtha (zone 412); jet and diesel (zone 413); and
Heavy
Vacuum Gas Oil ("HVGO") (zone 414). The approximate pyrolysis temperatures
associated with each zone are:
El about 685 C for zone 415, coke resin
El about 550 C for zone 414, HVGO
0 about 360 C for zone 413, jet and diesel
El about 150 C for zone 412, naphtha
El about 60 C for NGLs in their gaseous forms before conversion into
liquid form in
the refrigeration plants described in Figures 1 and 2.
For a thermal recovery process, the formation must be heated to the
approximate
range of about 200 C to about 350 C to mobilize and recover bitumen. Then,
when the
desired amount of bitumen is recovered, the lower zone of the formation can be
heated to
about 685 C to pyrolize and crack the remaining bitumen. The less dense
hydrocarbon
fractions will rise and segregate by API gravity as illustrated for example in
Fig. 4b,
eventually leaving the lowest zone (zone 415) comprised primarily of pyrolized
asphaltenes
and resins such as coke. In order to achieve first bitumen recovery and then
partial
upgrading of remaining bitumen and finally recovery of the partially refined
products, it is
necessary to have excellent control of the temperature histories, levels and
profiles in the
reservoir by having available an appropriate array of installed wells. This
can be best
achieved by being able to install a dense network of horizontal well types
which can be
used for the various purposes described above. It can be shown that for a
large number of
wells, it is most economical and better well placement accuracy is achieved
when the
horizontal wells are installed from underground within or in close proximity
to the
reservoir deposit.
An example of a sectional end view is presented in Fig. 4a showing surface
401,
overburden zone 402, reservoir zone 403, basement formation 404 and several
horizontal
wells. For example, well types 421 and 422 could be installed from underground
with
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CA 02813001 2013-04-11
well types 421 being heater wells and well types 422 being producing wells or
SAGD
injector/collector well pairs. Well types 423 and 424 could be installed from
underground
or from the surface with well types 423 being heater wells and well types 424
being steam
injection wells. Well types 425 could be, for example, installed from
underground or
from the surface and could be production wells for some of the less dense
hydrocarbon
fractions such as HVGO, jet and diesel and naphtha. Finally, well types 426
could be, for
example, installed from the surface and could be scavenging wells for gases
liberated
during bitumen mobilization and subsequently could be production wells for
gases
produced by the pyrolysis or for recovering the NGLs.
The bitumen or heavy oil reservoir may be viewed as a combined in-situ
recovery
and upgrading operation. Initially, the hydrocarbon-bearing formation is
typically heated
by various means (heating elements, steam injection, steam with diluent
injection or some
combination of all of these) to mobilize the bitumen or heavy oil. This
preferably
involves heating the lower portion of the formation to no more than about 300
C to about
350 C and the upper portion of the formation to no more than about 200 C. As
can be
appreciated the vertical temperature profile is graduated from the higher
temperature of the
lower portion of the reservoir to the lower temperature of the upper portion
of the reservoir.
During this phase of the operation, the bitumen or heavy oil is mobilized and
recovery of
mobilized hydrocarbon begins. The maximum temperature of about 350 C for the
reservoir during initial recovery is set such that the temperature is not high
enough to
initiate coking which would tend to diminish or shut off the flow of
hydrocarbons. Once
the reservoir is approximately about 60% to about 80% drained of hydrocarbons
(the exact
percentage being determined by factors such as geology, depth and the like),
the
temperature profile may be ramped up so as to begin transformation and
production of
other hydrocarbons. For example, beginning at the top of the reservoir, Nas
grading
down to naphtha , jet and diesel, Heavy Vacuum Gas Oil ("HVGO") and finally to
coke
resin (asphaltenes) as described above. Once the reservoir is approximately
about 80% to
about 90% drained of hydrocarbons, the temperature profile may be further
ramped up so
that a maximum temperature of about 685 C to about 800 C is reached in the
lower
portion of the reservoir grading to about 350 C in the upper portion of the
reservoir.
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CA 02813001 2013-04-11
Near the end of the process, oxygen may be injected into the bottom of the
formation to
increase recovery.
A configuration of an in situ process for recovering bitumen or heavy oil and
various thermally generated products and byproducts is now described.
In a first stage, a specific well grid system is determined based on a
combination of
past experience, laboratory and core testing and reservoir simulation. The
tighter the grid
for heater element and steam injection wells, the greater the recovery.
In a second stage, the well grid system is established to subdivide the
underground
hydrocarbon deposit into a plurality of portions. Underground shaft and tunnel
complexes
are developed for installation of various types of mobilizing wells and lower
recovery or
production wells. Other production wells, gas scavenging vacuum wells, and gas
disposal
injection wells may be drilled from the surface. The thermal recovery process
uses the
combination of heating element wells installed into the reservoir from
underground;
product production wells installed from underground or from the surface; steam
injection
wells (or steam injection wells with entrained diluents and catalysts)
installed from
underground or from the surface; gas and water injection disposal wells
installed from
underground or from the surface; and vacuum gas scavenging wells installed
from the
surface. Thus, by effective use of surface and underground facilities, the
bitumen
reservoir is operated as a recovery and partial upgrading facility, thereby
substantially
reducing energy expenditures and eliminating unnecessary emissions, especially
carbon
dioxide.
All wells are instrumented with temperature and pressure sensors and automated
to
duplicate a thermal soaker or coking process.
In a next stage, power and steam is generated by gas turbine co-generation
(operations up to about 50,000 bpd) or nuclear plant (operations from about
50,000 bpd to
several hundred bpd).
As an example, in a start-up stage, mobilizing wells are brought up to a range
of
from about 200 to about 250 C through steam injection and electrical heater
wells, then a
reservoir temperature profile is applied for mobilizing and recovery of
bitumen. Vacuum
wells pull -0.5 psig or other optimized value on the top of the reservoir to
facilitate the in-
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CA 02813001 2013-04-11
situ movement of gases to the top of the reservoir. When the defined portion
of the
reservoir is up to the selected temperature, a desired amount of bitumen is
produced.
In a next stage, the desired amount of bitumen is removed from the defined
portion
of the underground deposit and the temperature in the lower wells is increased
up to a
range of about 550 to about 1,000 C, with a temperature of about 800 C being
preferred.
The temperature depends on the selected reservoir coking mechanism. A
temperature
profile over a selected dimension of the production zone is generated to allow
for gravity
segregation, with ashphaltenes segregating in the (cooler) lower portions of
the zone and
NGLs in the hotter (upper) portions of the zone or vice versa.
Wells are placed in a fashion that allows production of high API fluid and
natural
separation based on gravity and temperature. High API products from thermal
conversion
of bitumen and heavy oil include Heavy Vacuum Gas Oil ("HVGO"), jet, diesel
and
naphtha.
To assist in cracking of the bitumen and heavy oil, a Fluidized Cracking
Catalyst
("FCC") may be injected into the production zone. For example, very small
particles of
aluminum oxide and silica can be added to steam injected into the formation.
These
particles will be entrained by the steam and distributed into the formation
where they will
help catalyze cracking activities in the various temperature zones.
Controlled amounts of steam and or air may be injected into the various levels
as a
way to add heat.
Produced gases and flue gases, especially CO2, may be injected into the
various
levels of the reservoir to aid in and act as solvents.
CO2 can be captured and re-injected into the production zone to act as both a
solvent in the upgraded portions of the production zone and as a micro-bubble
generator for
the non-upgraded portions of the production zone.
At later recovery stages, air is injected for partial in-situ combustion.
On the surface, a natural gas refrigeration plant recovers C3 + liquids from
the
produced gas, and C2- fluids are blown into the Vapor Recovery Unit ("VRU")
and
combined with H2S/CO2 for re-injection.
An amine plant sweetens the fuel gas from the Turbine Heat Recovery Steam
Generator ("HRSG"). Sour gas (fuel gas from processes such as catalytic
cracking and
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CA 02813001 2013-04-11
hydrotreating, which contains hydrogen sulphide and carbon dioxide) is mated
before it
can be used as refmery fuel. Amine plants in petroleum refming remove acid
contaminants
from sour gas and hydrocarbon streams. In amine plants, gas and liquid
hydrocarbon
streams containing carbon dioxide and/or hydrogen sulfide are charged to a gas
absorption
tower or liquid contactor where the acid contaminants are absorbed by
counterflowing
amine solutions. The stripped gas or liquid is removed overhead, and the amine
is sent to a
regenerator. In the regenerator, the acidic components are stripped by heat
and reboiling
action and disposed of, and the amine is recycled.
The Falling Tube Evaporator (FTE) treats water and condensate from the
produced
fluids and make-up water for steam generation for power and some injection.
Standard techniques are used to treat oil.
Brine water concentrate is disposed into the appropriate geologic layer.
A number of variations and modifications of the invention can be used. As will
be
appreciated, it would be possible to provide for some features of the
invention without
providing others. For example, the use of horizontal heating elements could be
combined
with other extraction technologies advanced from the tunnel or shaft. For
example, the
heating elements could be used as a formation pre-heater, then the formation
could be
steamed, solvent injected or other method advanced from the underground
workings or the
ground surface.
Another method that is covered by the present invention utilizes a cold
recovery
process such as diluent or solvent injection to mobilize the bitumen or heavy
oil for the first
phase of the recovery operation. This approach minimizes the amount of energy
used and
CO2 generated during initial recovery operations (typically, the initial phase
of recovery is
about 50% to about 60% of total recovery). Thereupon, heating wells are
activated to
heat the reservoir, continue the mobilization and recovery operations and
gradually phase
in increased heating to initiate the partial upgrading phase of the operation.
This approach
may result in minimizing energy requirements and CO2 generation for the
overall
operation. New diluent and solvent stocks are one of the potential products
resulting from
in-situ partial upgrading and/or surface refining operations and so may
provide a make-up
supply of diluents lost in the overall operation.
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CA 02813001 2013-04-11
The methods described herein can be applied to oil sands formations such as
the
Athabasca oil sands in Alberta, Canada. These methods can also be applied to
bitumen or
heavy oil deposits in carbonate reservoirs such as the Grosmont Carbonates,
also in
Alberta, Canada. These methods can also be applied to oil shales such as occur
extensively in Colorado and Utah in the United States.
The present invention, in various embodiments, includes components,
methods, processes, systems and/or apparatus substantially as depicted and
described
herein, including various embodiments, sub-combinations, and subsets thereof.
Those of
skill in the art will understand how to make and use the present invention
after
understanding the present disclosure. The present invention, in various
embodiments,
includes providing devices and processes in the absence of items not depicted
and/or
described herein or in various embodiments hereof, including in the absence of
such items
as may have been used in previous devices or processes, for example for
improving
performance, achieving ease and\or reducing cost of implementation.
The foregoing discussion of the invention has been presented for purposes
of illustration and description. The foregoing is not intended to limit the
invention to the
form or forms disclosed herein. In the foregoing Detailed Description for
example,
various features of the invention are grouped together in one or more
embodiments for the
purpose of streamlining the disclosure. This method of disclosure is not to be
interpreted
as reflecting an intention that the claimed invention requires more features
than are
expressly recited in each claim. Rather, as the following claims reflect,
inventive aspects
lie in less than all features of a single foregoing disclosed embodiment.
Thus, the
following claims are hereby incorporated into this Detailed Description, with
each claim
standing on its own as a separate preferred embodiment of the invention.
Moreover though the description of the invention has included description
of one or more embodiments and certain variations and modifications, other
variations and
modifications are within the scope of the invention, e.g., as may be within
the skill and
knowledge of those in the art, after understanding the present disclosure. It
is intended to
obtain rights which include alternative embodiments to the extent permitted,
including
alternate, interchangeable and/or equivalent structures, functions, ranges or
steps to those
claimed, whether or not such alternate, interchangeable and/or equivalent
structures,
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CA 02813001 2013-04-11
functions, ranges or steps are disclosed herein, and without intending to
publicly dedicate
,
any patentable subject matter.
¨23¨
