Note : Les descriptions sont présentées dans la langue officielle dans laquelle elles ont été soumises.
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DEPRESSANTS FOR MINERAL ORE FLOTATION
CROSS-REFERENCE TO RELATED APPLICATION
[0001] The present disclosure claims priority to U.S. Provisional Application
No.
61/708,222, filed October 1, 2012.
FIELD OF THE ART
[0001] The present disclosure generally relates to depressants for use in
mineral
ore flotation processes.
BACKGROUND
[0002] In the processing of mineral-containing ores, it is necessary to
separate
undesirable minerals known as gangue (e.g. A1203, 5i02 and Ti02) from the
desired
minerals in ore (e.g. iron ore). One method of accomplishing this goal is to
depress the
flotation of a particular mineral during the normal flotation process. In
mineral flotation
systems, it is common to depress the gangue materials while floating the
desirable mineral
or minerals. In differential or reverse flotation systems, it is common to
depress the
desired mineral or minerals while floating the gangue. Depression is
conventionally
accomplished by the use of one or more depressing agents (also known as
depressants)
during the flotation step. The depressant, when added to the flotation system,
exerts a
specific action on the material to be depressed thereby preventing it from
floating. The
ability of the depressant to facilitate such separation is referred to as its
selectivity, i.e. a
more selective depressant achieves better separation of the gangue from the
desired
minerals.
[0003] In a typical ore flotation scheme, the ore is ground to a size
sufficiently
small to liberate the desired mineral or minerals from the gangue. An
additional step in the
flotation process involves the removal of the ultra-fine particles by
desliming. Ultra-fine
particles are generally defined as those less than 5 to 10 microns in
diameter. The
desliming process may be accompanied by or followed by a flocculation step or
some
other type of settling step such as the use of a cyclone separating device.
This step is
followed by a flotation step wherein gangue materials are separated from the
desired
mineral or minerals in the presence of collectors and/or frothers.
[0004] It has been conventional in many flotation systems to use naturally
derived
substances such as starches, dextrins and gums as depressants. In some
countries, there is a
prohibition against using substances such as starch which have food value in
this type of
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commercial application.
[0005] Starch, or causticized starch, is commonly used as a depressant in
reverse
iron ore flotation processes. Native starch is typically digested with sodium
hydroxide or
boiling water before use in such applications, see for example Tang et al.
"The Acidity of
Caustic Digested Starch and Its Role in Starch Adsorption on Mineral Surfaces"
International Journal of Mineral Processing (2012), doi: 10.1016/j .minpro
.2012.06.001.
Starch produces relatively small but robust flocs which can be further
upgraded by
washing.
[0006] Large quantities of starch are consumed as a result of its use as a
depressant
in flotation processes. For example, Brazilian iron ore pellet feed production
in 2010 was
approximately 73,000,000 Tons, which consumed approximately 50,000 Tons of
starch as
the depressant. Depressant consumption is expected to increase at least 4-fold
by 2017.
BRIEF SUMMARY
[0007] Depressants comprising one or more types of polysaccharides comprising
one or more types of pentosan units, and compositions comprising the
depressants and a
solvent, are provided. Also disclosed herein are processes for enriching a
desired mineral
from an ore comprising the desired mineral and gangue, wherein the process
comprises
carrying out a flotation process in the presence of one or more collecting
agents and one or
more of the depressants.
[0008] The disclosure may be understood more readily by reference to the
following detailed description of the various features of the disclosure and
the examples
included therein.
BRIEF DESCRIPTION OF FIGURES
[0009] Figure 1 is graph of the iron and silicate content in the fraction
concentrate
for processes using an exemplary depressant (KEMXMC) and starch.
[0010] Figure 2 is a graph of which shows the correlation of iron and silicate
in the
fraction concentrate.
[0011] Figure 3 shows the effect of the depressant amount on the metallurgic
recovery for KEMXMC and starch.
[0012] Figure 4 shows the effect of the collector amount on the metallurgic
recovery for KEMXMC and starch.
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DETAILED DESCRIPTION
[0013] According to the various exemplary embodiments described herein,
depressants and related compositions and processes may be used to process
mineral-
containing ore to separate gangue from desired minerals. Exemplary depressants
comprise
one or more types of polysaccharides comprising one or more types of pentosan
units. The
depressants, compositions and processes may provide improved selectivity
compared to
other depressants such as starch or causticized starch. In particular, the
depressants may
provide increased flotation process selectivity, decreased collector
consumption, decreased
sodium hydroxide consumption, and/or decreased landfill, as compared to starch-
based
depressants. The exemplary depressants also offer an advantage over starch-
based
depressants because they do not have food value. In exemplary embodiments, the
depressants may be provided in a form which renders them easier to dilute
and/or directly
apply, for example in gel form.
[0014] Definitions
[0015] As used herein, a "depressant" refers to an agent that depresses the
flotation
of the desired minerals in preference to depressing the flotation of the
associated gangue.
[0016] As used herein, the "desired minerals" refers to minerals which have
value
and may be extracted from ore which contains the desired mineral and gangue.
Examples
of desired minerals include iron powder, hematite, magnetite, pyrite,
chromite, goethite,
marcasite, limonite, pyrrohotite or any other iron-containing minerals.
[0017] As used herein, "gangue" refers to the undesirable minerals in a
material
that contains both undesirable and desired minerals, for example an ore
deposit. Such
undesirable minerals may include oxides of aluminum, silica (e.g. quartz),
titanium, sulfur
and alkaline earth metals. In certain embodiments, the gangue includes oxides
of silica,
silicates or siliceous materials.
[0018] As used herein, the term "polysaccharide" refers to carbohydrate
molecules
of repeated monomer (monosaccharide) units joined together by glycosidic
bonds. The
polysaccharide may vary in structure, for example, may be linear or branched.
The
molecules may contain slight modifications of the repeating unit.
Monosaccharides are
generally aldehydes or ketones with two or more hydroxyl groups. A
polysaccharide
containing a single type of monosaccharide unit is referred to as a
homopolysaccharide,
while a polysaccharide containing more than one type of monosaccharide unit is
referred
to as a heteropolysaccharide. Polysaccharides are generally considered to
contain ten or
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more monosaccharide units, while the term "oligosaccharide" is generally used
to refer to
the polymers containing a small number, e.g. two to ten, of monosaccharide
units.
[0019] As used herein, the term "starch" refers to a carbohydrate consisting
of a
large number of glucose units joined by glycosidic bonds. It is well
established that starch
polymer consists mainly of two fractions, amylose and amylopectin, which vary
with the
source of starch. The amylose having a low molecular weight contains one end
group per
200 - 300 anhydroglucose units. Amylopectin is of higher molecular weight and
consists
of more, than 5,000 anhydroglucose units with one end group for every 20 - 30
glucose
units. While amylose is a linear polymer having a 1¨>4 carbon linkage,
amylopectin is a
highly branched polymer with a 1¨>4 and a 1¨>6 carbon linkages at the branch
points.
[0020] As used herein, "ore" refers to rocks and deposits from which the
desired
minerals can be extracted. Other sources of the desired minerals may be
included in the
definition of "ore" depending on the identity of the desired mineral. The ore
may contain
undesirable minerals or materials, also referred to herein as gangue.
[0021] As used herein, "iron ore" refers to rocks, minerals and other sources
of
iron from which metallic iron can be extracted. The ores are usually rich in
iron oxides and
vary in color from dark grey, bright yellow, deep purple, to rusty red. The
iron itself is
usually found in the form of magnetite (Fe304), hematite (Fe203), goethite
(Fe0(OH)),
limonite (Fe0(OH).n(H20)), siderite (FeCO3) or pyrite (FeS2). Taconite is an
iron-bearing
sedimentary rock in which the iron minerals are interlayered with quartz,
chert, or
carbonate. Itabirite, also known as banded-quartz hematite and hematite
schist, is an iron
and quartz formation in which the iron is present as thin layers of hematite,
magnetite, or
martite. Any of these types of iron are suitable for use in processes
described herein. In
exemplary embodiments, the iron ore is substantially magnetite, hematite,
taconite or
itabirite. In exemplary embodiments, the iron ore is substantially pyrite. In
exemplary
embodiments, the iron ore is contaminated with gangue materials, for example
oxides of
aluminum, silica or titanium. In exemplary embodiments, the iron ore is
contaminated
with clay.
[0022] Depressants
[0023] The exemplary embodiments include a depressant having one or more
types of polysaccharides comprising one or more types of pentosan units.
Exemplary
pentosan units are monosaccharides having five carbon atoms, including, for
example,
xylose, ribose, arabinose, and lyxose. In exemplary embodiments, the pentosan
unit may
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be an aldopentose, which has an aldehyde functional group at position 1, such
as, for
example, the D- or L- forms of arabinose, ribose, xylose and lyxose. Exemplary
polysaccharides include, for example, xylan, hemicellulose, and gum arabic.
Exemplary
hemicellulose is derived from biomass, for example grasses and wood, such as
hardwood.
In exemplary embodiments, the hemicellulose may contain mixtures of xylose,
arabinose,
mannose and galactose. Exemplary gum arabic may contain arabinose and ribose.
In
exemplary embodiments, the one or more types of pentosan units comprises xylan
units
and one or more of hemicellulose and aldopentoses. In exemplary embodiments,
the one
or more types of polysaccharides are derived from plant cell walls, for
example sugar-
cane- or corn-plant cell walls, or algae. In exemplary embodiments, the one or
more types
of polysaccharides are derived from sugar cane, fiber cane, or corn. In
exemplary
embodiments, the one or more types of polysaccharides are derived from sugar
cane
bagasse. In exemplary embodiments, the one or more types of polysaccharides
are derived
from corn fiber residue. In exemplary embodiments, the depressant may be a
blend or a
mixture of polysaccharides having one or more types of pentosan units. In
certain
embodiments, the depressant may consist essentially of polysaccharides
comprising one
type of pentosan unit, for example xylan. In certain embodiments, the one or
more types of
pentosan units comprise xylan. In exemplary embodiments, a depressant is
provided that
includes one or more types of polysaccharides comprising xylan units.
[0024] In exemplary embodiments, a polysaccharide comprising xylan may be
extracted from plant material or from algae with dilute alkaline solutions. In
exemplary
embodiments, the polysaccharide comprising xylan may be extracted from sugar
cane
bagasse or corn fiber residue with dilute alkaline solutions.
[0025] Xylan is an oligosaccharide which could be extracted in the form of 5
to
200 anhydroxylose units consisting of D-xylose units with 113¨>4 linkages.
H OH H OH
H /_10)-0 OF1 H H 0-11')LOH H H
OH H 0 OH H
O-
H H H 0
0
H OH H OH
Xylan oligosaccharide with 5 to 200 anhydroxylose units consisting of D-xylose
units with
113¨>4 linkages
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[0026] In exemplary embodiments, the polysaccharides comprising one or more
types of pentosan unit may be extracted from the pulping black liquors, from
the cold
caustic extraction (CCE) filtrates, and/or from acid pre-hydrolyzes or auto-
hydrolyzes
process in order to achieve dissolve pulp grades. Such extractions are
described in, for
example, Jayapal et al. Industrial Crops and Products 2012, v. 42, pp. 14-24;
Muguet et
al. Holzforschung 2011, v. 65, pp. 605-612; and Gehmayer et al.
Biomacromolecules
2012, v. 13, pp. 645-651.
[0027] In exemplary embodiments, the depressants are not substantially
digestible
or are not suitable for human consumption. In certain embodiments, the
depressants do not
comprise substantial amounts of arabinose or ribose or sources thereof.
[0028] In exemplary embodiments, the depressant may have any molecular weight
so long as the depressant has the effect of depressing the flotation of the
desired minerals
in preference to depressing the flotation of the associated gangue. In
exemplary
embodiments, the depressant possesses essentially no flocculating properties.
In
exemplary embodiments, the molecular weight of the depressant is about 700 to
about
50,000; about 700 to about 25,000; or about 700 to about 8000 Daltons. In
exemplary
embodiments, the molecular weight of the depressant is about 5 to about 300,
about 5 to
about 150, or about 5 to about 50 aldopentose units, for example xylose units.
[0029] According to the various exemplary embodiments, the amount of
depressant to be used is that which will depress the flotation of the desired
mineral ore or
ores to a necessary or desired extent. The amount of depressant needed will
depend, at
least in part, on a number of factors such as the desired mineral and gangue
to be separated
and the conditions of the flotation process. In exemplary embodiments, the
amount of
depressant used in the flotation process is about 0.01 to about 1.5 kilogram,
or about 0.2 to
about 0.7 kg of depressant per metric ton of ore to be floated. In exemplary
embodiments,
the specific consumption of depressant in the processes is about 0.01 to about
1.5
kilogram, or about 0.2 to about 0.7 kg of depressant per metric ton of ore to
be floated.
[0030] According to the exemplary embodiments, the depressants may be used
alone, or may be used in a flotation process with other depressants. Other
depressants
which may be used in combination with the exemplary depressants include but
are not
limited to: starch; starch activated by treatment with alkali; cellulose
esters, such as
carboxymethylcellulose and sulphomethylcellulose; cellulose ethers, such as
methyl
cellulose, hydroxyethylcellulose and ethyl hydroxyethylcellulose; hydrophilic
gums, such
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as gum arabic, gum karaya, gum tragacanth and gum ghatti, alginates; starch
derivatives,
such as carboxymethyl starch and phosphate starch; and combinations thereof.
[0031] The exemplary depressants are generally useful as depressants in
mineral
flotation. In particular, the exemplary depressants are effective in
selectively depressing
the flotation of desired mineral(s) as compared to gangue. In certain
embodiments, the
exemplary depressants are used to enhance the separation of iron-containing
minerals,
such as iron oxides or iron powder, from silicate gangue by differentially
depressing the
flotation of the iron-containing minerals relative to that of the silicate
gangue. One of the
problems associated with the separation of iron-containing minerals from
silicate gangue
is that the iron-containing minerals and silicates both tend to float under
certain processing
conditions. The exemplary depressants may be used to change the flotation
characteristics
of the iron-containing minerals relative to silicate gangue, to improve the
separation
process.
[0032] According to the various embodiments, the amount of depression may be
quantified. For example, a percent of depression may be calculated by
measuring the
weight percent of the particular mineral or gangue floated in the absence of
any depressant
and measuring the weight percent of the same mineral or gangue floated in the
presence of
a depressant. The latter value is subtracted from the former; the difference
is divided by
the weight percent floated without any depressant; and this value is
multiplied by 100 to
obtain the percent of depression. In exemplary embodiments, the percent of
depression
may be any amount that will provide a necessary or desired amount of
separation to enable
separation of the desirable minerals from gangue. In exemplary embodiments,
use of the
exemplary depressant causes the flotation of desirable minerals to be
depressed by at least
about 5%, about 10%, or about 12%. In exemplary embodiments, use of the
depressant
causes the flotation of the gangue to be depressed by less than about 7.5% or
about 5%.
[0033] Compositions
[0034] In exemplary embodiments, a composition comprises a depressant and a
solvent, wherein the depressant comprises one or more types of polysaccharides
comprising one or more types of pentosan units. Exemplary depressants may be
any
depressant according to the embodiments described herein. In exemplary
embodiments,
the solvent is water.
[0035] In exemplary embodiments, the composition is a gel, for example a
polysaccharide gel. In exemplary embodiments, the gel is water-soluble.
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[0036] An exemplary composition may be formulated to provide a sufficient
amount of depressant to a flotation process, i.e., an amount sufficient to
produce a desired
result.
[0037] In an exemplary embodiment, the composition may include one or more
other depressants. In an exemplary embodiment, the composition may include one
or
more agents or modifiers. Examples of such agents or modifiers include, but
are not
limited to, frothers, activators, collecting agents, depressants, dispersants,
acidic or basic
addition agents, or any other agent known in the art.
[0038] Processes
[0039] According to exemplary embodiments, a flotation process may use the
exemplary depressants described herein. As discussed above, flotation is a
commonly
used process for separating or concentrating desirable minerals from ore, for
example iron
from taconite. Flotation processes take advantage of the differences between
the
hydrophobicity of the desired minerals and that of the gangue to achieve
separation of
these materials. Such differences can be increased with the use of surfactants
and flotation
agents, including but not limited to collecting agents and depressants (also
called
depressing agents).
[0040] Generally, a flotation process may include the steps of grinding
crushed
ore, classifying the ground ore in water, treating the classified ore by
flotation to
concentrate one or more minerals in the froth while the remainder of the
minerals of the
ore remain in the water pulp, and collecting the minerals in the froth and/or
pulp. Some of
these steps are described in more detail below.
[0041] In exemplary embodiments, a flotation process comprises separating the
gangue from the desirable mineral concentrate by floating the gangue in the
froth and
recovering the desirable mineral concentrate as the underflow. In other
exemplary
embodiments, a flotation process comprises separating the gangue from the
desirable
mineral concentrate by inducing the gangue to sink to the bottom of the cell
(as
underflow) and recovering the desirable mineral concentrate as the overflow
(froth). In
exemplary embodiments, the flotation process comprises separating iron
concentrates
from silica and other silaceous materials by flotation of the silica and
recovering the iron
concentrate as underflow.
[0042] In exemplary embodiments, a process for enriching a desired mineral
from
an ore having the desired mineral and gangue includes carrying out a flotation
process in
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the presence of one or more collecting agents and one or more depressants. In
exemplary
embodiments, at least one of the one or more depressants comprises one or more
types of
polysaccharides comprising one or more types of pentosan units. In exemplary
embodiments, at least one of the one or more depressants comprises one or more
types of
polysaccharides comprising xylan units.
[0043] In exemplary embodiments, the desired mineral is an iron-containing
mineral, such as iron oxides or iron powder.
[0044] In exemplary embodiments, a process for enriching an iron-containing
mineral from an ore having the iron-containing material and silicate-
containing gangue,
includes carrying out a flotation process in the presence of one or more
collecting agents
and one or more depressants. In exemplary embodiments at least one of the one
or more
depressants comprises one or more types of polysaccharides comprising one or
more types
of pentosan units. In exemplary embodiments, at least one of the one or more
depressants
comprises one or more types of polysaccharides comprising xylan units.
[0045] In exemplary embodiments, the flotation process is a reverse or
inverted
flotation process, for example a reverse cationic flotation process. In such
processes, the
flotation of the desired mineral is selectively depressed when compared to the
flotation of
the gangue so as to facilitate separation and recovery of the desired mineral.
[0046] In exemplary embodiments, the flotation process is a direct flotation
process, for example a cationic or anionic flotation process.
[0047] In certain exemplary embodiments, the one or more depressants are added
in the form of a composition comprising the depressant and a solvent.
[0048] In exemplary embodiments, the one or more depressants may be added at
any stage of the process prior to the flotation step. In certain embodiments,
the one or
more depressants are added before or with the addition of the collecting
agents.
[0049] In an exemplary process, various agents and modifiers may be added to
the
ore that is dispersed in water (flotation pulp), and air is introduced into
the pulp to form a
froth. The resulting froth contains those materials which are not wetted and
have an
affinity for air bubbles. Examples of such agents and modifiers include but
are not limited
to frothers, activators, collecting agents, depressants, dispersants, acidic
or basic addition
agents, or any other agent known in the art.
[0050] In exemplary embodiments, a collecting agent or collector may be added
to
the flotation pulp. Generally, collecting agents may form a hydrophobic layer
on a given
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mineral surface in the flotation pulp, which facilitates attachment of the
hydrophobic
particles to air bubbles and recovery of such particles in the froth product.
Any collecting
agent may be used in the exemplary processes. The choice of collector will
depend, at
least in part, on the particular ore to be processed and on the type of gangue
to be
removed. Suitable collecting agents will be known to those skilled in the art.
In exemplary
embodiments, the collecting agents may be compounds comprising anionic groups,
cationic groups or non-ionic groups. In certain embodiments, the collecting
agents are
surfactants, i.e. substances containing hydrophilic and hydrophobic groups
linked together.
Certain characteristics of the collecting agent may be selected to provide a
selectivity and
performance, including solubility, critical micelle concentration and length
of carbonic
chain.
[0051] Exemplary collecting agents include compounds containing oxygen and
nitrogen, for example compounds with amine groups. In exemplary embodiments,
the
collecting agents may be selected from the group consisting of: ether amines,
for example
primary ether monoamines, and primary ether polyamine; aliphatic C8-C20 amines
for
example aliphatic amines derived from various petroleum, animal and vegetable
oils, octyl
amine, decyl amine, dodecyl amine, tetradecyl amine, hexadecyl amine,
octadecyl amine,
octadecenyl amine and octadecadienyl amine; quaternary amines for example
dodecyl
trimethyl ammonium chloride, coco trimethyl ammonium chloride, and tallow
trimethyl
ammonium sulfate; diamines or mixed amines for example tallow amine,
hydrogenated
tallow amine, coconut oil or cocoamine, soybean oil or soya-amine, tall oil
amine, rosin
amine, tallow diamine, coco diamine, soya diamine or tall oil diamines and the
like, and
quaternary ammonium compounds derived from these amines; amido amines and
imidazolines such as those derived from the reaction of an amine and a fatty
acid; and
combinations or mixtures thereof In an exemplary embodiment, the collecting
agent is an
ether amine or mixture of ether amines.
[0052] Exemplary collecting agents may be partially or wholly neutralized by a
mineral or organic acid such as hydrochloric acid or acetic acid. Such
neutralization
facilitates dispersibility in water. In the alternative, the amine may be used
as a free base
amine by dissolving it in a larger volume of a suitable organic solvent such
as kerosene,
pine oil, alcohol, and the like before use. These solvents sometimes have
undesirable
effects in flotation such as reducing flotation selectivity or producing
uncontrollable
frothing. Although these collecting agents differ in structure, they are
similar in that they
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ionize in solution to give a positively charged organic ion.
[0053] According to the exemplary embodiments, the quantity of collecting
agent
may vary over a wide range. The amount of collecting agent may depend, at
least in part,
upon the gangue content of the ore being processed. For example, ores having
higher silica
content may require greater quantities of collecting agents. In exemplary
embodiments,
about 0.01 to about 2 lbs., or about 0.1 to about 0.35 lbs., of collecting
agent per ton of ore
is used in the process.
[0054] In exemplary embodiments, one type of collecting agent is used in the
process. In exemplary embodiments, two or more collecting agents are used in
the
process.
[0055] In exemplary embodiments, one or more frothing agents are used in the
process. Exemplary frothing agents are heteropolar organic compounds which
reduce
surface tension by being absorbed at air-water interfaces and thus facilitate
formation of
bubbles and froth. Examples of frothing agents are methylisobutyl carbinol;
alcohols
having 6-12 carbon atoms which optionally are alkoxylated with ethylene oxide
and/or
propylene oxide; pine oil; cresylic acid; various alcohols and soaps. In
exemplary
embodiments, about 0.001 to 0.2 lb. of frothing agent per ton of ore are
provided.
[0056] According to an exemplary embodiment, after completion of the
flotation, a
gangue-enriched flotate (froth), for example a silicate-enriched flotate, and
a bottom
fraction rich in the desired mineral (tailings, underflow), for example iron,
are produced.
[0057] According to the embodiments, one or more steps may be done prior to
the
flotation step to prepare the ore for flotation. For example, in one step of
the process, the
ore can be ground, together with water, to the desired particle size, for
example a particle
size between about 5 and about 200 lam. Optionally, conditioning agents such
as sodium
hydroxide and/or sodium silicate may be added to the grinding mill prior to
grinding the
crude ore. In exemplary embodiment, sufficient water is added to the grinding
mill to
provide a slurry containing approximately 70% solids.
[0058] In exemplary processes, the ground ore may be deslimed. For example,
the
ground ore may be suspended in water, and fine material maybe deslimed, for
instance, by
filtration, settling, siphoning or centrifuging. In exemplary embodiments, the
desliming
step may be repeated one or more times.
[0059] In exemplary processes, an ore-water slurry may be prepared from the
deslimed ore, and one or more depressants according to the embodiments may be
added to
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the slurry. In exemplary embodiments, the one or more depressants are added in
an
amount of about 10 to about 1500 g per ton of ore. In exemplary embodiments,
the ore-
water slurry to transferred to a flotation cell and the one or more
depressants are added to
the ore water slurry in the flotation cell.
[0060] In exemplary embodiments, base or alkali may be added to adjust the pH
of
the slurry. For example, the slurry may be adjusted to a pH in the range of
about 8 to
about 11, or about 9 to about 11, or about 10 to about 11. In certain
embodiments, the pH
is adjusted to about 10.5. In exemplary embodiments, the pH of the slurry in
the flotation
cell is maintained at between about 8 and about 11 for optimum iron
recoveries.
[0061] According to the embodiments, in one step of the flotation process, one
or
more collecting agents may be added, for example after the addition of the one
or more
depressants and any other process agents.
[0062] In exemplary embodiments, once all of the processing agents have been
added, the mixture is further conditioned or agitated for a period of time
before the froth
flotation is carried out. If desired, a froth-regulating means can be added on
a convenient
occasion before the froth flotation.
[0063] In exemplary embodiments, the flotation process may be performed in a
plurality of flotation processing steps. For example, the flotation process
may be
performed in flotation units containing a plurality of communicating cells in
series, with
the first cell(s) being generally used for the rougher flotation, and
subsequent cell(s) being
used for the cleaner flotation. In exemplary embodiments, each flotation cell
may be any
flotation equipment, including, for example, the Denver laboratory flotation
machine
and/or the Wemco Fagergren laboratory flotation machine, in which the slurry
mixture is
agitated and air is injected near the bottom of the cell as desired.
[0064] In exemplary embodiments, before flotation treatment the ore-water
slurry
comprises about 20 to about 40% by weight solids. The duration of the
flotation process
depends upon the desired result. In exemplary embodiments, the time of
flotation
treatment may be from about 1 to 10 minutes for each circuit. The time of the
flotation
process may depend at least in part upon the gangue content, the grain size of
the ore
being treated and the number of flotation cells involved.
[0065] According to the embodiments, in the rougher flotation treatment, the
gangue may be selectively separated from the ore and removed with the
flotation froth.
The desired mineral concentrate from the flotation treatment is removed as the
underflow
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and isolated as the rougher concentrate. In exemplary embodiments, the
concentrate of the
desirable mineral in the rougher concentrate is found to contain a
sufficiently low quantity
of gangue to be suitable for almost any desired use.
[0066] In exemplary embodiments, the flotation froth, the rougher concentrate,
or
both may be further processed. For example, in exemplary embodiments, the
overflow or
froth from the rougher flotation may be advanced to a first cleaner flotation
cell where a
second flotation treatment is performed. The underflow from this first
cleaning flotation
cell is an mineral concentrate identified as the first cleaner middlings which
generally will
contain more gangue than the rougher concentrate but significantly less gangue
than the
original crude ore. The overflow frothing from the first cleaning cell may be
advanced to a
second cleaning flotation cell where the flotation procedure is repeated and
another
mineral concentrate is obtained which is identified as the second cleaner
middlings. In
exemplary embodiments, the froth flotation cleaning is repeated one or more
times. Any or
all of the cleaner middlings may be combined with a rougher concentrate to
provide an
upgraded mineral ore concentrate. The extent to which the rougher concentrate
is
combined with the various middling fractions will depend upon the desired
mineral
content of the final product derived from the procedure. As an alternative
embodiment, the
cleaner middlings may be returned and recycled through the rougher flotation
cell to
further upgrade these cleaner middlings.
[0067] The depressants, compositions and processes of the exemplary
embodiments can be used to provide higher selectivity and desired mineral
recoveries as
compared to other depressants when used in cationic flotation processes. In
exemplary
embodiments, the mineral concentrate, e.g. hematite concentrate, that is
obtained by the
exemplary processes meets the specifications for the steel industry. In
exemplary
embodiments, the depressants, compositions and processes can be used to
maximize the
iron recovery to increase production of metallic charge per unit ore fed,
which may
provide increases in production and profitability.
[0068] The following examples are presented for illustrative purposes only,
and
are not intended to be limiting.
EXAMPLES
[0069] General Protocol for Flotation Tests
[0070] Flotation tests described herein were generally performed with iron
pulp
samples according to the following procedure:
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[0071] 1) The pulp is filtered using a vacuum pump and filtration kit
(Kitazato
flask, Buchner funnel and filter paper white ribbon).
[0072] 2) The volume of liquid filtered is measured and recorded.
[0073] 3) The filtered liquid is transferred to a bottle suitable for further
analysis of
iron by wet chemistry and the silicate was determinate as the mass of
insoluble in 3:1
HC1:H2NO3.
[0074] 4) The solid is weighed in trays and subsequently dried at 105 C for 24
hours.
[0075] 5) After cooling, the weight of the solid is recorded.
[0076] 6) The final solid is put in a bottle suitable for further ICP analysis
of iron,
alumina, phosphorous and silicate and particle size distribution. It is then
separated for
making the pulp to be used in the flotation test.
[0077] Using a calibrated pH meter, a make-up water (to keep the level of the
recipient of the flotation cell constant) is prepared by adjusting its pH (for
example to pH
10.5 with NaOH 5% or acetic acid 10%) to a desired value.
[0078] The collector solution of amine, for example an ether amine
(concentration
is, for example, 1 wt %), is prepared as well as the depressant solution
(concentration is,
for example, 1 wt %). Preparation of the depressant solution must take into
account its
moisture and organic content.
[0079] The flotation cell (2L) is weighed and the required amount of pulp for
flotation is added as follows: a dry mass of pulp is added, up to its half,
completing the
other half with the required quantities of collector and depressant solutions
and with
"water" (liquid) filtered from the sample of the pulp received. (Note: the
capacity of the
flotation cell is measured up to the height of the blades.) The addition of
these materials is
made as follows:
[0080] 1) The "water" volume needed for sample homogenization is added.
[0081] 2) The extractor is downloaded up to the limit, switching on the
rotation
(950 rpm). The initial pH is measured and recorded.
[0082] 3) The mass of depressant solution is added in and conditioned and/or
agitated for a period of time, for example 5 minutes, observing the pH. If the
pH stabilizes
at a desired value (for example 10.5), no adjustment is needed. Otherwise, pH
modifiers
(for example 5% NaOH and/or acetic acid solution 10%) may be added to adjust
the pH to
the desired value.
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[0083] After the conditioning and/or agitation and if necessary, pH
adjustment, the
mass of amine collector solution is added to the recipient vessel and the
remaining volume
of the tank is completed with remaining calculated "water" from the sample,
for a given
pulp solids %. This mixture is conditioned or agitated for a period of time,
for example 1
minute. Collection trays are weighed and their weighs recorded.
[0084] With the flotation cell and the collection trays put together, maximum
aeration and collecting shovels are switched on, starting to count the timing
of flotation
(chosen according to each test). The level of recipient is kept constant by
the use of make-
up water, already prepared previously with a desired pH, for example a pH of
10.5.
[0085] At the end of the test, the flotation cell is cleaned taking the
necessary care
for no contamination of the materials floated and sunk.
[0086] The floated (gangue) and sunk (concentrate) materials are collected in
the
weighed trays during the time chosen for collection. The samples are
subsequently dried at
105 C.
[0087] The trays containing the float and sunk materials are weighed and
recorded.
A quantity of each material is sent for analysis of iron, silica, alumina and
phosphorus.
[0088] Example 1: Flotation Test with High Grade Iron Ore and Exemplary
Depressant Comprising Xylan
[0089] In this example, flotation tests were conducted on a laboratory scale
and the
objective of these tests were to separate the mineral of interest (hematite)
from gangue.
The general protocol for flotation tests as described above was used for these
experiments.
The depressant used for these experiments was a blend of polysaccharides
present in plant
cell walls comprising mainly xylan (labeled KEMXMC) or starch (for example
corn or
tapioca starch). In this raw iron ore sample, the values of iron and silicate
were 59.7%
(59.61% and 59.88%) and 13.0% (13.43% and 12.66%) respectively.
[0090] It was observed that the KEMXMC depressant, when used in the flotation
tests, performed comparably or better than starch. At depressant
concentrations of less
than 200 g/T, KEMXMC increased iron concentration in the final sample compared
to
processes with similar amounts of starch (see Figure 1). Smaller amounts of
silicate were
also observed in the samples which were produced by processes utilizing KEMXMC
compared to starch (see Figures 1 and 2). It was also observed that
metallurgic recovery
was increased (see Figure 3), and the amount of collector needed was decreased
(see
Figure 4) when KEMXMC was used in place of starch in the flotation test.
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[0091] Example 2: Flotation Test with High Grade Iron Ore and Exemplary
Depressant Comprising Xylan from Sugar Can Bagasse or Corn Fiber Residue
[0092] In this example, flotation tests were conducted on a laboratory scale
and the
objective of these tests were to separate the mineral of interest (hematite)
from gangue.
The depressant used for these experiments was a blend of polysaccharides
present in plant
cell walls comprising mainly xylan (labeled KEMXMC) or starch (for example
corn or
tapioca starch). The source of the xylan was sugar cane bagasse (ca. 20% over
dry base) or
corn fiber residue (ca. 20-30% over dry base). Chemical analysis of the iron
ore sample
was by X-ray fluorescence and the results are provided in Table 1.
[0093] Table 1. Chemical Analysis of High Grade Iron Ore
Substance Weight %
Fe 65.1
Si02 5.24
A1203 0.87
P 0.03
Mn 0.18
TiO2 0.14
CaO <0.10
MgO <0.10
[0094] The general protocol for flotation tests as described above was used
for
these experiments. The specific parameters for the experiments are provided in
Table 2.
[0095] Table 2. Flotation Test Parameters for High Grade Iron Ore and
Exemplary
Depressants or Starch
Depressant Type Starch KEMXMC
Depressant Amount 700 700
(g/ton)
Collector Amount (g/ton) 28 3
pH 10.5 9.5
Time (min) 5 5
Agitation (rpm) 1100 1100
Fe in Concentrate (wt %) 68.2 68.2
5i02 in Concentrate (wt %) 2.53 2.64
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Fe Recovery (%) 97.33 99.96
[0001] Example 3: Flotation Test with Low Grade Iron Ore and Exemplary
Depressant Comprising Xylan from Sugar Can Bagasse or Corn Fiber Residue
[0002] In this example, flotation tests were conducted on a laboratory scale
and the
objective of these tests were to separate the mineral of interest (hematite)
from gangue.
The depressant used for these experiments was a blend of polysaccharides
present in plant
cell walls comprising mainly xylan (labeled KEMXMC1 or KEMXMC2) or starch (for
example corn or tapioca starch). The source of the xylan was sugar cane
bagasse (ca. 20%
over dry base) or corn fiber residue (ca. 20-30% over dry base). Chemical
analysis of the
iron ore sample was by X-ray fluorescence and the results are provided in
Table 3.
[0003] Table 3. Chemical Analysis of High Grade Iron Ore
Substance Weight %
Fe 50.9
Si02 24.8
A1203 0.14
P 0.07
Mn 0.10
TiO2 <0.10
CaO <0.10
MgO <0.10
[0004] The general protocol for flotation tests as described above was used
for
these experiments. The specific parameters for the experiments are provided in
Table 4.
[0005] Table 4. Flotation Test Parameters for Low Grade Iron Ore and Exemplary
Depressants or Starch
Depressant Type Starch KEMXMC 1 KEMXMC2
Depressant Amount 1200 2000 600
(g/ton)
Collector Amount (g/ton) 32 32 32
pH 10.5 10.5 10.5
Time (min) 3 3 3
Agitation (rpm) 950 950 950
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Fe in Concentrate (wt %) 67.77 67.93 61.60
Si02 in Concentrate (wt %) 1.23 1.26 10.41
Fe Recovery in Concentrate (%) 79.18 92.11 98.22
Fe in Gangue (wt%) 23.88 13.27 8.17
[0006] In the preceding procedures, various steps have been described. It
will,
however, be evident that various modifications and changes may be made
thereto, and
additional procedures may be implemented, without departing from the broader
scope of
the exemplary procedures as set forth in the claims that follow.
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