PROCEDE DE PRODUCTION DE METHANOL DANS UN REACTEUR PRESENTANT UNE DERIVATION

A METHOD FOR PRODUCING METHANOL IN A REACTOR WITH BYPASS

Abrégé français

La présente invention concerne un procédé de production de méthanol qui comprend les étapes consistant à faire passer un flux d'alimentation de gaz de synthèse de méthanol à travers un réacteur de méthanol principal contenant un catalyseur de synthèse de méthanol, pour former un gaz mixte contenant du méthanol, refroidir le gaz mélangé contenant du méthanol, séparer le méthanol du gaz mélangé et chauffer le gaz mélangé. Le procédé selon l'invention consiste également à faire passer le flux de gaz mélangé chauffé à travers un réacteur de méthanol supplémentaire contenant un catalyseur de synthèse de méthanol, et mélanger l'effluent provenant du réacteur de méthanol supplémentaire avec le flux d'alimentation du gaz de synthèse de méthanol et le faire passer à travers le réacteur de méthanol principal.

Abrégé anglais

A method for producing methanol comprises the steps of passing a feed stream of methanol synthesis gas through a main methanol reactor containing a methanol synthesis catalyst, to form a mixed gas containing methanol, cooling the mixed gas containing methanol, separating methanol from the mixed gas and heating the mixed gas. The stream of heated mixed gas is passed through an additional methanol reactor containing a methanol synthesis catalyst, and the effluent from the additional methanol reactor is mixed with the feed stream of methanol synthesis gas and passed through the main methanol reactor.

Revendications

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Claims:
1. A method for producing methanol, comprising the steps
of
(a) passing a feed stream of methanol synthesis gas through
a main methanol reactor containing a methanol synthesis
catalyst, to form a mixed gas containing methanol,
(b) cooling the mixed gas containing methanol,
(c) separating methanol from the mixed gas and
(d) heating the mixed gas,
wherein
- the stream of heated mixed gas from step (d) is passed
through an additional methanol reactor containing a metha-
nol synthesis catalyst, and
- the effluent from the additional methanol reactor is
mixed with the feed stream of methanol synthesis gas and
passed through the main methanol reactor.
2. Method according to claim 1, wherein the main methanol
reactor is a boiling water reactor (BWR).

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3. Method according to claim 2, wherein an adiabatic cat-
alyst layer is placed on top of the tube sheet to reduce
the size of the boiling water reactor.

Description

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A method for producing methanol in a reactor with bypass
The present invention relates to a method for producing
methanol in a reactor provided with a bypass in the form of
an additional methanol reactor.
In a traditional methanol loop, feed gas is compressed and
mixed with recycled unreacted gas before being sent to the
methanol reactor, in which methanol is produced from syn-
thesis gas (syngas) via equilibrium reactions proceeding at
elevated temperature under elevated pressure. The synthesis
reactions are:
CO + H20 <¨> CH3OH + heat
(1)
CO2 + 3H2 <-> CH3OH + H20 + heat (2)
CO + H20 <¨> CO2 + H2 + heat
(3)
Because the reactions are exothermal, the methanol reactor
has to be equipped with a lot of cooling tubes to control
the temperature.
In order to reduce the size of the traditional methanol re-
actor (or to boost the production), it is advantageous to
install a catalyst layer in an additional reactor upstream
the traditional reactor. This additional reactor may be a
less complicated or less cooled (alternatively adiabatic)

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reactor. However, if the new additional reactor is an adia-
batic reactor (alternatively less cooled), the temperature
profile will vary with capacity, gas composition and cata-
lyst activity, and there is a risk of too high temperatures
at the outlet of the catalyst bed. High temperatures in the
catalyst bed will lead to an increased formation of by-
products and to catalyst sintering.
US 8.536.235 discloses a process for the synthesis of meth-
anol comprising (a) passing a synthesis gas mixture of a
loop gas and a make-up gas through a first synthesis reac-
tor cooled by boiling water under pressure and containing a
methanol synthesis catalyst, to form a mixed gas containing
methanol, (b) cooling said mixed gas, (c) passing said
mixed gas through a second synthesis reactor containing a
methanol synthesis catalyst, where further methanol is syn-
thesized to form a product gas stream, (d) cooling said
product gas stream to condense methanol, and (e) recovering
the methanol and returning unreacted gas as the loop gas to
the first synthesis reactor. The mixed gas containing meth-
anol from the first synthesis reactor is cooled in heat ex-
change with either the loop gas or the make-up gas.
CN 107382665 A discloses a technology for synthesizing
methanol, comprising generating methanol from a synthesis
gas containing fresh gas through a first reactor, exchang-
ing the heat of the mixed gas containing the synthesis gas
and methanol steam with the heat of the synthesis gas con-
taining fresh gas to be fed into the first reactor and then
generating methanol through a second reactor, cooling the
synthesis gas of higher methanol concentration after the
reaction, and then guiding it into a methanol separator and

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separating methanol, mixing the synthesis gas after sepa-
rating methanol with fresh gas, thereby acquiring the syn-
thesis gas containing fresh gas, guiding the synthesis gas
containing fresh gas into the first reactor again, utiliz-
ing a valve A to directly guide a part of fresh gas into
the second reactor and controlling the hot-spot temperature
of a catalyst bed of the second reactor to around 250 C,
keeping a part of synthesis gas containing fresh gas free
from heat exchange and directly introducing it into the
first reactor by a valve B and controlling the gas inlet
temperature of the second reactor at 200-240 C. This way,
the use ratio of the catalyst is increased and the quality
of the methanol product is improved.
In US 2011/0065966, the synthesis gas containing hydrogen
and carbon oxides for the production of methanol is passed
through a first, preferably water-cooled reactor, in which
a part of the carbon oxides is catalytically converted to
methanol. The resulting mixture containing synthesis gas
and methanol vapour is fed to a second, preferably gas-
cooled reactor, in which a further part of the carbon ox-
ides is converted to methanol. To achieve a maximum metha-
nol yield, even with an aged catalyst, a partial stream of
the synthesis gas is guided past the first reactor and in-
troduced directly into the second reactor.
To increase the capacity of a cooling medium reactor, the
catalyst will in some cases be loaded not only into the re-
action tubes, but also further up above the upper tube
sheet wherein the reaction tubes are mounted. As regards
exothermal reactions, this will increase the reaction gas
temperature even before the reactant reaches the reaction

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tubes which are in thermal contact with the cooling medium.
Thus there is a risk that the temperature of the tube sheet
gets too high, with the consequent risk of damage to the
tube sheet or damage to the top of the reaction tubes and
the upper tube sheet. This problem is solved by Applicant's
WO 2017/186538, which discloses a cooling medium reactor
for an exothermal reaction. The reactor comprises reaction
tube inserts to provide for an adiabatic catalyst layer on
top of the upper tube sheet inserts arranged on top of the
upper tube sheet and a guide means of the inserts which
thermally insulates the upper tube sheet from the exother-
mal reaction within the inserts.
The object of the present invention is to add an extra re-
actor and to arrange a feed gas bypass around the first (or
more) reactor(s) in order to control the temperature at the
reactor outlet. The feed gas that is bypassed has a lower
temperature, and it is mixed with the hot gas at the outlet
of the reactor to control the temperature at the desired
level. The gas bypass is taken from the feed gas, allowing
the full flow of recycled gas to pass through the first re-
actor and reducing the amount of fresh feed gas to the adi-
abatic (or less cooled) reactor, as shown in the appended
figure.
So the present invention relates to a method for producing
methanol, comprising the steps of
(a) passing a feed stream of methanol synthesis gas through
a main methanol reactor containing a methanol synthesis
catalyst, to form a mixed gas containing methanol,

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(b) cooling the mixed gas containing methanol,
(c) separating methanol from the mixed gas and
5 (d) heating the mixed gas,
wherein
- the stream of heated mixed gas from step (d) is passed
through an additional methanol reactor containing a metha-
nol synthesis catalyst, and
- the effluent from the additional methanol reactor is
mixed with the feed stream of methanol synthesis gas and
passed through the main methanol reactor.
To reduce the size of the boiling water reactor (BWR) in
the methanol loop (or alternatively boost the production of
an existing BWR), an adiabatic catalyst layer can be placed
on top of the tube sheet. For large units, it could be an
advantage to place the adiabatic bed in a separate reactor.
The major difference between this idea and the adiabatic
top layer (catalyst inserts) described in WO 2017/186538
is the ability to control outside the cooled reactor, which
makes it possible to operate the loop in a different way.
If the catalyst bed is placed in a separate reactor, then
it is possible to add an extra control to limit the temper-
ature in low load or transient cases.
As the fresh gas to the new reactor is reduced, the gas at
the inlet of the additional reactor is less reactive, which

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leads to a lower peak temperature in the catalyst bed and a
lower by-product formation.
The idea of utilizing an additional reactor upstream the
existing methanol reactor and controlling the outlet tem-
perature (the existing reactor inlet temperature) by gas
bypass is illustrated in the appended figure:
The stream of methanol synthesis feed gas f is split into
two streams, one of which is sent to the main methanol re-
actor A via a throttle valve v, while the other is sent to
the additional methanol reactor B after passing a feed/ef-
fluent heat exchanger Hex.
Thus, the main methanol reactor A is fed with a mixture of
fresh methanol synthesis feed gas f and the effluent e2
from the additional methanol reactor B.
The effluent e/ from the main methanol reactor A is cooled
in a loop air cooler lac and a loop water cooler lwc and
then fed to a separator S. where liquid methanol product
(Me0H) is separated from the gas phase, the latter being
mixed with fresh feed gas and passed to the additional
methanol reactor B.