Note : Les descriptions sont présentées dans la langue officielle dans laquelle elles ont été soumises.
CA 03148862 2022-01-26
1
DESCRIPTION
FUEL CELL STACK AND OPERATION METHOD FOR FUEL CELL
STACK
Field
[0001]
Embodiments of the present invention relate to a fuel cell
stack and an operation method for a fuel cell stack.
Background
[0002]
A fuel cell stack is an electricity generation device that causes
an electrochemical reaction of a fuel gas such as hydrogen and an
oxidant gas such as air to convert chemical energy of a fuel into
electrical energy. As for fuel cells, there are known several types
different in electrolyte which include a solid oxide type, a molten
carbonate type, a phosphoric acid type, and a solid polymer type,
for example. These different types of fuel cells are used in different
applications due to the difference in operation conditions or the like.
Among them, a solid polymer fuel cell has been widely developed
and put into practical use as a power source for automobiles, home
use, and business use because it has a low operating temperature,
can be easily started and stopped, and can have a high output
density.
[0003]
A solid electrolyte membrane fuel cell using a proton
(hydrogen ion) exchange type electrolyte membrane is currently the
mainstream of the solid polymer fuel cell. In the electrolyte
membrane, it is necessary to hydrate the electrolyte membrane in
order to ensure proton conductivity, and a fuel gas and an oxidant
gas are humidified and operated. Examples of the method for
humidifying a gas include a method in which a humidifier is provided
outside a fuel cell stack (an external humidification method) and a
method in which humidification is performed inside a cell stack (an
internal humidification method). Generally, when the flow rate of a
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
2
gas supplied to a cell stack is high, the humidity at a gas inlet of the
stack decreases and the stack becomes dry. However, it is known
that deterioration of electrolyte membranes constituting a fuel cell
stack is accelerated at a lower humidity and a higher temperature.
[0004]
Meanwhile, the operating temperature of a solid polymer fuel
cell that is widely put into practical use at present is equal to or lower
than the boiling point of water, and reaction product water in an
oxidant electrode and humidifying water that becomes excessive
(supersaturated) with hydrogen consumption in a fuel electrode are
condensed in a cell. In a case where the condensed water is
retained and closes a gas passage, oxygen or hydrogen required for
a reaction becomes insufficient, causing drop of a cell voltage and
an unstable operation. In particular, in a case where hydrogen is
insufficient in the fuel electrode, a carbon corrosion reaction, in
which carbon (a carbon member) constituting a cell member reacts
with water to form carbon dioxide and protons, is promoted. As a
result, the cell member may be worn and the cell may be significantly
deteriorated.
Citation List
Patent Literature
[0005]
Patent Literature 1: Japanese Patent Application Laid-open
No. 2002-25584
Summary
Technical Problem
[0006]
A problem to be solved by the present invention is to provide
a fuel cell stack and an operation method for a fuel cell stack that
can suppress deterioration of an electrolyte membrane caused by
drying and retention of condensed water.
Solution to Problem
[0007]
Date Recue/Date Received 2022-01-26
3
According to the present embodiment, a fuel cell stack
comprises a cell stack having a plurality of unit cells stacked therein,
each of the unit cells including an electrolyte membrane having one
main surface in which a fuel electrode is arranged and the other main
surface that is opposite to the one main surface and in which an
oxidant electrode is arranged, a fuel-electrode porous passage plate
in which a fuel-electrode passage is formed in a main surface on a
side close to the fuel electrode of the electrolyte membrane, and an
oxidant-electrode porous passage plate in which an oxidant-
electrode passage is formed in a main surface on a side close to the
oxidant electrode of the electrolyte membrane, each of the unit cells
having a cooling-water passage formed in a main surface of the fuel-
electrode porous passage plate opposite to the main surface in which
the fuel-electrode passage is arranged or in a main surface of the
fuel-electrode porous passage plate opposite to the main surface in
which the oxidant-electrode passage is arranged, wherein a cooling
water pressure in a cooling-water passage is lower than a fuel gas
in a fuel-electrode passage, a differential pressure between a fuel
gas pressure at an inlet in the fuel-electrode passage and a cooling
water pressure in the cooling-water passage corresponding to the
inlet is smaller than a differential pressure between a fuel gas
pressure at an outlet in the fuel-electrode passage and a cooling
water pressure in the cooling-water passage corresponding to the
outlet, and a large one of a maximum value of a differential pressure
between the cooling water pressure and an oxidant pressure and a
maximum value of a differential pressure between the cooling water
pressure and a fuel electrode pressure is smaller than a capillary
force in a passage plate.
According to an aspect of the present invention there is
provided A fuel cell stack comprising a cell stack having a plurality
of unit cells stacked therein, each of the unit cells including an
electrolyte membrane having one main surface in which a fuel
electrode is arranged and the other main surface that is opposite to
the one main surface and in which an oxidant electrode is arranged,
Date Recue/Date Received 2023-03-23
3a
a conductive fuel-electrode porous passage plate having hydrophilic
micropores in which a fuel-electrode passage is formed in a main
surface on a side close to the fuel electrode of the electrolyte
membrane, and a conductive oxidant-electrode porous passage
plate having hydrophilic micropores in which an oxidant-electrode
passage is formed in a main surface on a side close to the oxidant
electrode of the electrolyte membrane, each of the unit cells having
a cooling-water passage for cooling the cell stack formed in a main
surface of the fuel-electrode porous passage plate opposite to the
main surface in which the fuel-electrode passage is arranged or in a
main surface of the fuel-electrode porous passage plate opposite to
the main surface in which the oxidant-electrode passage is arranged,
wherein
in the cell stack, at least a part of one main surface of the
conductive fuel-electrode porous passage plate is in contact with one
main surface of the conductive oxidant-electrode porous passage
plate, and a capillary force of water contained in the hydrophilic
micropores of the conductive fuel-electrode porous passage plate
and the conductive oxidant-electrode porous passage plate prevents
an oxidant gas in the oxidant-electrode passage and a fuel gas in the
fuel-electrode passage from directly mixing together,
and a cooling water pressure in the cooling-water passage is
lower than the fuel gas pressure, a differential pressure between a
fuel gas pressure at an inlet in the fuel-electrode passage and a
cooling water pressure in the cooling-water passage corresponding
to the inlet is smaller than a differential pressure between a fuel gas
pressure at an outlet in the fuel-electrode passage and a cooling
water pressure in the cooling-water passage corresponding to the
outlet.
According to another aspect of the present invention there is
provided An operation method for a cell stack having a plurality of
unit cells stacked therein, each of the unit cells including an
electrolyte membrane having one main surface in which a fuel
electrode is arranged and the other main surface that is opposite to
Date Recue/Date Received 2023-03-23
3b
the one main surface and in which an oxidant electrode is
arranged, a conductive fuel-electrode porous passage plate having
hydrophilic micropores in which a fuel-electrode passage is formed
in a main surface on a side close to the fuel electrode of the
electrolyte membrane, and a conductive_oxidant-electrode porous
passage plate having hydrophilic micropores in which an oxidant-
electrode passage is formed in a main surface on a side close to
the oxidant electrode of the electrolyte membrane, each of the unit
cells having a cooling-water passage for cooling the cell stack
formed in a main surface of the fuel-electrode porous passage plate
opposite to the main surface in which the fuel-electrode passage is
arranged or in a main surface of the fuel-electrode porous passage
plate opposite to the main surface in which the oxidant-electrode
passage is arranged, wherein
in the cell stack, at least a part of one main surface of the
conductive fuel-electrode porous passage plate is in contact with
one main surface of the conductive oxidant-electrode porous
passage plate,
and the cell stack is operated so that a capillary force of
water contained in the hydrophilic micropores of the conductive
fuel-electrode porous passage plate and the conductive oxidant-
electrode porous passage plate prevents an oxidant gas in the
oxidant-electrode passage and a fuel gas in the fuel-electrode
passage from directly mixing together,
and a cooling water pressure in the cooling-water passage is
lower than the fuel gas pressure, a differential pressure between a
fuel gas pressure at an inlet in the fuel-electrode passage and a
cooling water pressure in the cooling-water passage corresponding
to the inlet is smaller than a differential pressure between a fuel
gas pressure at an outlet in the fuel-electrode passage and a
cooling water pressure in the cooling-water passage corresponding
Date Recue/Date Received 2023-03-23
3c
to the outlet.
Effect of the Invention
[0008]
According to the present invention, it is possible to suppress
deterioration of an electrolyte membrane caused by drying and
retention of condensed water.
Brief Description of Drawings
Date Recue/Date Received 2023-03-23
CA 03148862 2022-01-26
4
[0009]
[FIG. 1] FIG. 1 is a perspective view illustrating a configuration of a
fuel cell stack having its manifold removed therefrom.
[FIG. 2] FIG. 2 is a perspective view illustrating a basic configuration
of a fuel-cell cell.
[FIG. 3] FIG. 3 is a schematic diagram illustrating a shape of a main
surface of a first porous separator on a side close to a fuel electrode
of an electrolyte membrane.
[FIG. 4] FIG. 4 is a schematic diagram illustrating a shape of a main
surface of a second porous separator.
[FIG. 5] FIG. 5 is a schematic diagram illustrating a shape of a main
surface opposite to the main surface of the second porous separator.
[FIG. 6] FIG. 6 is a schematic diagram illustrating a mechanism of
absorbing condensed water in a porous separator.
[FIG. 7] FIG. 7 is a schematic diagram illustrating a mechanism of
humidifying a gas inlet in a porous separator.
[FIG. 8] FIG. 8 is a diagram illustrating a state where a manifold is
attached to a side surface along a stacking direction of a cell stack.
[FIG. 9] FIG. 9 is a diagram illustrating differential pressures
between a fuel gas pressure and a cooling water pressure.
[FIG. 10] FIG. 10 is a schematic diagram illustrating a differential
pressure between an oxidant gas pressure and a cooling water
pressure.
[FIG. 11] FIG. 11 is a schematic diagram of a conventional fuel cell
stack illustrating a state where a manifold is attached to a side
surface thereof.
[FIG. 12] FIG. 12 is a diagram illustrating differential pressures
between a fuel gas pressure and a cooling water pressure in a
conventional fuel cell stack.
[FIG. 13] FIG. 13 is a schematic diagram illustrating a shape of a
main surface on a side close to an oxidant electrode of a first
electrolyte membrane.
[FIG. 14] FIG. 14 is a schematic diagram illustrating a shape of a
main surface of the second porous separator on a side close to a fuel
electrode.
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
[FIG. 15] FIG. 15 is a diagram illustrating a state where a manifold
is attached to a side surface along a stacking direction of fuel-cell
cells according to a modification.
5 Description of Embodiments
[0010]
Embodiments of the present invention will now be explained
in detail with reference to the accompanying drawings. In the
drawings accompanying this specification, for the conveniences of
illustration and easier understanding, the scales, horizontal and
vertical sizes and the like of constituent elements are illustrated in a
modified or exaggerated manner with regard to actual products.
[0011] (First embodiment)
FIG. 1 is a perspective view illustrating a configuration of a
fuel cell stack 1 having its manifold removed therefrom. As
illustrated in FIG. 1, the fuel cell stack 1 according to one
embodiment is a structure that generates electricity by an
electrochemical reaction in fuel-cell cells. That is, the fuel cell stack
1 is configured to include a cell stack 10, two current collector plates
20, a power terminal 20a, two insulating plates 30, two clamping
plates 100, and a plurality of tie rods 200. The clamping plate 100
includes an end plate 110 and a beam 120. FIG. 1 illustrates the Z-
direction parallel to a stacking direction of the cell stack 10 and the
X and Y-directions that are parallel to each other and perpendicular
to the Z-direction. In a case of installing the fuel cell stack 1
according to the present embodiment on a horizontal plane, the Z-
direction is the horizontal direction and is perpendicular to the
gravity direction. During actual operation of the fuel cell stack 1,
the x-y plane is used as the bottom.
[0012]
The two current collector plates 20 are arranged on both sides
of the cell stack 10 in the stacking direction. The two current
collector plates 20 are plate-shaped conductors and are arranged on
both end surfaces of the cell stack 10. Electrical energy is taken out
from the power terminal 20a provided in the current collector plate
20. The two insulating plates 30 are plate-shaped insulators and
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
6
are arranged between the two current collector plates 20 and the
two clamping plates 100. As described above, the two current
collector plates 20 and the two insulating plates 30 are arranged on
both sides of the cell stack 10 in the stacking direction in turn, and
are clamped as one unit by the two clamping plates 100 from both
sides in the stacking direction, whereby the fuel cell stack 1 is
obtained. The tie rods 200 are arranged to penetrate through
opposed holes provided in the two clamping plates 100. In this
state, nuts are tightened via washers to join the two clamping plates
100.
[0013]
The detailed configuration of a fuel-cell cell 10a according to
the first embodiment is described with reference to FIGS. 2 to 5.
FIG. 2 is a perspective view illustrating a basic configuration of the
fuel-cell cell 10a. As illustrated in FIG. 2, the fuel-cell cell 10a
includes an electrolyte membrane 12, a first porous separator 14,
and a second porous separator 16. In the electrolyte membrane 12,
a fuel electrode including a catalyst layer 31 and a gas diffusion layer
33 is formed on one main surface, and an oxidant electrode including
a catalyst layer 32 and a gas diffusion layer 34 is formed on the other
main surface. The electrolyte membrane 12 is, for example, a
polymer electrolyte membrane. The electrolyte membrane 12, the
catalyst layer 31, and the catalyst 32 may be collectively called
"membrane-electrode complex". A plurality of the fuel-cell cells 10a
are stacked to form the cell stack 10. The fuel-cell cell 10a
according to the present embodiment corresponds to a unit cell.
[0014]
FIG. 3 is a schematic diagram illustrating a flow of a fuel gas
in a main surface of the first porous separator 14 on a side close to
a fuel electrode of the electrolyte membrane 12. As illustrated in
FIG. 3, the first porous separator 14 is formed by a conductive
porous plate having hydrophilic micropores. A fuel-electrode
passage 140 along the fuel electrode is formed in a main surface 14a
on the side close to the fuel electrode of the electrolyte membrane
12. The fuel-electrode passage 140 includes a first inlet 14b, a first
outlet 14c, a second inlet 14d, and a second outlet 14e. That is, the
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
7
fuel-electrode passage 140 is formed by a first fuel gas passage
connecting the first inlet 14b and the first outlet 14c to each other
and a second fuel gas passage connecting the second inlet 14d and
the second outlet 14e to each other. A fuel gas introduced from the
first inlet 14b flows along the first fuel gas passage of the fuel-
electrode passage 140 and is discharged from the first outlet 14c.
A fuel gas introduced from the second inlet 14d flows along the
second fuel gas passage of the fuel-electrode passage 140 and is
discharged from the second outlet 14e. The hydrophilic micropores
of the first porous separator 14 are hydrated and allow contained
water to migrate through a network of the micropores while
preventing permeation of the fuel gas by a capillary force of the
water in the hydrophilic micropores.
[0015]
FIGS. 4 and 5 are diagrams illustrating a configuration of the
second porous separator 16, where FIG. 4 is a schematic diagram
illustrating a flow of an oxidant gas in a main surface 16a of the
second porous separator 16, and FIG. 5 is a schematic diagram
illustrating a flow of cooling water in a main surface 16b opposite to
the main surface 16a of the second porous separator 16. As
illustrated in FIG. 4, the second porous separator 16 is formed by a
conductive porous plate having hydrophilic micropores. In the
second porous separator 16, an oxidant-electrode passage 160a
along an oxidant electrode is formed in the main surface 16a on a
side close to the oxidant electrode of the electrolyte membrane 12.
The oxidant-electrode passage 160a has a first inlet 16c, a first
outlet 16d, a second inlet 16e, and a second outlet 16f. An oxidant
gas introduced from the first inlet 16c flows along the oxidant-
electrode passage 160a and is discharged from the first outlet 16d.
An oxidant gas introduced from the second inlet 16e flows along the
oxidant-electrode passage 160a and is discharged from the second
outlet 16f. The first porous separator 14 and the second porous
separator 16 according to the present embodiment respectively
correspond to a fuel-electrode porous passage plate and a fuel-
electrode porous passage plate. The hydrophilic micropores in the
second porous separator 16 are also hydrated like those in the first
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
8
porous separator 14 and allow contained water to migrate through a
network of the micropores while preventing permeation of the
oxidant gas by a capillary force of the water in the hydrophilic
micropores.
[0016]
As illustrated in FIG. 5, a cooling-water passage 160b is
formed in the main surface 16b opposite to the oxidant electrode
side. The cooling-water passage 160b has a first inlet 16g and a
first outlet 16h. Cooling water introduced from the first inlet 16g
flows along the cooling-water passage 160b and is discharged from
the first outlet 16h. The pressure of the cooling water flowing in the
cooling-water passage 160b is set to be lower than those of a fuel
gas flowing in the fuel-electrode passage 140 and an oxidant gas
flowing in the oxidant-electrode passage 160a. The cooling water
in the cooling-water passage 160b communicates with water
contained in the hydrophilic micropores in the first porous separator
14 and the hydrophilic micropores in the second porous separator
16. Accordingly, direct mixing of the fuel gas and the oxidant gas
is prevented by a capillary force of the contained water. Also, the
micropore network constitutes a path of humidifying the oxidant gas
and the fuel gas and a path of absorbing water condensed in the
oxidant gas passage and the fuel gas passage. In addition, it is
possible to retain water in the hydrophilic micropores in a stable
manner by maintaining a pressure difference between the pressure
of the oxidant gas and the pressure of the cooling water and a
pressure difference between the pressure of the fuel gas and the
pressure of the cooling water to be lower than the capillary force in
the micropores.
[0017]
FIG. 6 is a schematic diagram illustrating a mechanism of
absorbing condensed water in a porous separator. As illustrated in
FIG. 6, a rate of migration of a fluid mw (a mass flow rate) in a porous
medium such as the first porous separator 14 having hydrophilic
micropores is written by Expression (1) by using a permeability
coefficient k [m2] of porous separator, a water pressure difference
APw [Pa], a water density pw [kg/m3], and a viscosity coefficient of
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
9
water pw [Pa.S]. The water pressure difference APw is a differential
pressure between a gas pressure PG [Pa] and a cooling water
pressure Pw [Pa]. As illustrated in FIG. 6, when the pressure of
condensed water in a gas grove is substantially equal to the gas
pressure PG in a passage and effects of the porosity and the
tortuosity are included in the permeability coefficient K of the porous
separator, a capillary length L is equivalent to the distance from the
cooling-water passage (cooling water groove) 160b to the fuel-
electrode passage (gas groove) 140. Therefore, under a condition
in which the permeability coefficient k, the thickness, and physical
properties of water are constant, the rate of water absorption
becomes higher as the pressure difference between the gas pressure
PG and the water pressure Pw, that is, a differential pressure between
a gas side pressure and a cooling water pressure becomes larger.
FIG. 6 illustrates a typical one fine pore for simplification. An actual
separator has a complicated configuration in which a large number
of fine pores are connected to form a network. Here, the
permeability coefficient K can be defined as the cross-sectional area
of a typical passing in the whole group of fine pores forming the
network.
[Expression 1]
K APw
mAt [ketn2fricc Ptof ¨
4. (1 )
[0018]
FIG. 7 is a schematic diagram illustrating a mechanism of
humidifying a gas inlet in a porous separator. As illustrated in FIG.
7, a rate of humidification my in a surface of the first porous
separator 14 is the rate of evaporation of water from a gas-liquid
interface formed at an end of a fine pore near the fuel-electrode
passage 140 to a gas side. The upper limit of the evaporation rate
of water is defined by a rate of transport of water by a capillary force
from the cooling-water passage 160b to near the fuel-electrode
passage 140. The transport rate of water follows Expression (1)
also in FIG. 7, but FIG. 7 is different from FIG. 6 in that a driving
pressure difference AP is a pressure difference between a pressure
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
Pws in a capillary on the water side of the gas-liquid interface near
a surface of a gas passage and the pressure Pw in the cooling-water
passage 160b. This Pws has a relation of Expression (3) with the
gas pressure PG. Further, since a typical pore radius rc in
5 Expression (3) has a relation of Expression (4) with the permeability
coefficient K of the separator, a relation of Expression (2) is
established. Here, pw is the water density [kg/m3], pw is a viscosity
coefficient [Pa=s], pw is a viscosity coefficient [Pa.s], 0 is an angle
[rad] of contact of water with an inner wall of a fine pore in a porous
10 separator, rc is a typical radius [m] of a fine pore in the porous
separator, E is a porosity [-] of the porous separator, K is the
permeability coefficient [m2] of the porous separator, and L is the
distance [m] from a gas passage to a cooling water passage.
[Expression 2]
tavola < mor (40 Av 21
Pw A,
a PAL [ K p12r o ri .7:67 p wawa
õ, (2)
[Expression 3]
-x-cr 2y cove
Pws'
rc (3)
[Expression 4]
re --zilch;
(4)
[0019]
In Expression (2), a main driving force of water transport is
a capillary pressure, and PG-Pw represents a reduction of the driving
force. Therefore, it is desirable that PG-Pw, that is, a differential
pressure between the fuel-electrode passage 140 and the cooling-
water passage 160b is as small as possible.
[0020]
Similarly to FIG. 6, FIG. 7 also illustrates a typical one pore.
Although an actual separator has a complicated configuration in
which a large number of fine pores are connected to form a network,
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
11
Expression (3) can be applied by defining the permeability coefficient
as the cross-sectional area of a typical passing in the whole group of
fine pores forming the network and defining the typical pore radius
as the capillary characteristics. A relation between the fuel-
electrode passage 140 and the cooling-water passage 160b have
been described in the above description. An identical phenomenon
occurs also regarding the oxidant-electrode passage 160a and the
cooling-water passage 160b.
[0021]
Since the fuel-cell cells 10a are stacked, the second porous
separator 16 of the next fuel-cell cell 10a is stacked in the Z-direction
of the first porous separator 14. Therefore, the first porous
separator 14 can be cooled by cooling water in at least any one of
the cooling-water passages 160b in the Z-direction. Furthermore,
humidification of a fuel gas in the fuel-electrode passage 140 is
affected by the cooling water pressure in the cooling-water passage
160b at the closest position. That is, humidification of the fuel gas
progresses more as a differential pressure between the fuel gas
pressure in the fuel-electrode passage 140 and the cooling water
pressure in the cooling-water passage 160b at the closest position
becomes smaller. On the contrary, as the differential pressure
becomes larger, absorption of condensed water in the fuel-electrode
passage 140 is promoted, and retention of the condensed water is
suppressed.
[0022]
Similarly, humidification of an oxidant gas in the oxidant-
electrode passage 160a is affected by the cooling water pressure in
the cooling-water passage 160b at the closest position. That is,
humidification of the oxidant gas progresses more as a differential
pressure between an oxidant gas pressure in the oxidant-electrode
passage 160a and the cooling water pressure in the cooling-water
passage 160b at the closest position becomes smaller. On the
contrary, as the differential pressure becomes larger, absorption of
condensed water in the oxidant-electrode passage 160a is promoted,
and retention of the condensed water is suppressed.
[0023]
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
12
Each of the fuel-cell cells 10a generates electricity by a
reaction represented by Chemical formula 1. In more detail, the
fuel gas is, for example, a hydrogen-containing gas. The fuel gas
flows along the fuel-electrode passage 140 of the first porous
separator 14 to cause a fuel electrode reaction. The oxidant gas is,
for example, an oxygen-containing gas. The oxidant gas flows
along the oxidant-electrode passage 160a of the second porous
separator 16 to cause an oxidant electrode reaction. The fuel cell
stack 1 uses these electrochemical reactions to take out electrical
energy from the power terminal 20a provided in the current collector
plate 20 (FIG. 1).
[0024] (Chemical formula 1)
Fuel electrode reaction: 2H2-- 4H++4e-
Oxidant electrode reaction: 4H++02+4e---- 2H20
[0025]
FIG. 8 is a diagram illustrating a state where a manifold is
attached to a side surface along the stacking direction of the cell
stack 10 of the fuel-cell cell stack 1. As illustrated in FIG. 8, the
fuel-cell cell stack 1 includes a fuel-electrode manifold 42, a fuel-
electrode facing manifold 44, a cooling-water manifold 46, and a
cooling-water facing manifold 48.
[0026]
The fuel-electrode manifold 42 is arranged on a first side
surface along the stacking direction of the fuel-cell cell stack 1. The
fuel-electrode manifold 42 is a manifold in which a supply space 42b
and a discharge space 42a are divided by a divider. The supply
space 42b supplies a fuel gas supplied from a fuel gas supply device
to the fuel-electrode passage 140 in the fuel-cell cell 10a by the first
inlet 14b. The discharge space 42a is for further discharging the
fuel gas discharged from the second outlet 14e.
[0027]
The fuel-electrode facing manifold 44 is arranged on a third
surface corresponding to the first side surface. The fuel-electrode
facing manifold 44 is a manifold that supplies a fuel gas discharged
from the first outlet 14c of the fuel-electrode passage 140 to the
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
13
fuel-electrode passage 140 in the fuel-cell cell 10a from the second
inlet 14d.
[0028]
The cooling-water manifold 46 includes a first cooling-water
manifold 46a, a first oxidant-electrode manifold 46b, and a second
oxidant-electrode manifold 46c. The cooling-water manifold 46 is
arranged on a second side surface that is adjacent to the first side
surface and is along the stacking direction of the fuel-cell cell stack
1. The first cooling-water manifold 46a is a manifold that supplies
cooling water to the cooling-water passage 160b in the fuel-cell cell
10a through the first inlet 16g.
[0029]
The first oxidant-electrode manifold 46b supplies an oxidant
gas supplied from an oxidant gas supply device to the oxidant-
electrode passage 160a in the fuel-cell cell 10a by the first inlet 16c.
The second oxidant-electrode manifold 46c further discharges the
fuel gas discharged from the second outlet 16f. The first oxidant-
electrode manifold 46b and the second oxidant-electrode manifold
46c are divided by a divider.
[0030]
The cooling-water facing manifold 48 includes a first cooling-
water facing manifold 48a and an oxidant electrode facing manifold
48b. The cooling-water facing manifold 48 is arranged on a fourth
side surface that is opposed to the second side surface and is along
the stacking direction of the fuel-cell cells 10a.
[0031]
The first cooling-water facing manifold 48a is a manifold
having a discharge space for further discharging cooling water
discharged from the first outlet 16h. The oxidant electrode facing
manifold 48b is a manifold that supplies an oxygen-containing gas
discharged from the first outlet 16d to the oxidant-electrode passage
160a in the fuel-cell cell 10a from the second inlet 16e.
[0032]
As illustrated in FIG. 8, a first fuel gas passage connecting
the first inlet 14b and the first outlet 14c to each other is arranged
vertically above an upstream region in the cooling-water passage
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
14
160b, and a second fuel gas passage connecting the second inlet 14d
and the second outlet 14e to each other is arranged vertically above
a downstream region in the cooling-water passage 160b. The
cooling water pressure in the cooling-water passage 160b decreases
toward the downstream side. Similarly, the fuel gas in the fuel-
electrode passage 140 is reduced toward the downstream side.
Further, in general, a differential pressure between the inlet 16g and
the outlet 16h of the cooling-water passage 160b is larger than a
differential pressure between the first inlet 14b and the first outlet
14c of the fuel-electrode passage 140.
[0033]
FIG. 9 is a diagram illustrating differential pressures between
fuel gases in the fuel-electrode passage 140 and cooling water
pressures in a cooling-water passage at positions corresponding to
the fuel-electrode passage 140. The vertical axis represents a
pressure. A line 70 indicates fuel gas pressures at positions along
the fuel-electrode passage 140 from the first inlet 14b to the second
outlet 14e of the fuel-electrode passage 140. A line 72 indicates
cooling water pressures in the cooling-water passage 160b
corresponding to the positions along the fuel-electrode passage 140.
That is, the cooling water pressures in the cooling-water passage
160b corresponding to the positions along the fuel-electrode passage
140 are cooling water pressures at positions in the cooling-water
passage 160b each of which is located at the shortest distance from
a corresponding one of the positions along the fuel-electrode
passage 140. More specifically, the line 72 indicates the cooling
water pressures in the cooling-water passage 160b at positions
vertically below or above the respective positions.
[0034]
As illustrated in FIG. 9, a differential pressure between the
fuel gas pressure and the cooling water pressure can be made larger
from the upstream side to the downstream side in the fuel-electrode
passage 140. Therefore, a differential pressure between the fuel
gas pressure at the first inlet 14b in the fuel-electrode passage 140
and the cooling water pressure in the cooling-water passage 160b at
a position vertically below or above the first inlet 14b becomes
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
smaller than a differential pressure between the fuel gas pressure at
the second outlet 14e in the fuel-electrode passage 140 and the
cooling water pressure in the cooling-water passage 160b at a
position vertically below or above the second outlet 14e. In a case
5 where the
cooling-water passage 160b is not present at the position
directly below or above, the differential water is obtained by using
the cooling water pressure in the cooling-water passage 160b near
that position.
[0035]
10 As described
above, each of the first porous separator 14 and
the second porous separator 16 is formed by a conductive porous
plate having micropores. Therefore, as the differential pressure
between the fuel gas pressure and the cooling water pressure
becomes smaller, the moisture infiltrating the second porous
15 separator 16 and the moisture infiltrating the first porous separator
14 through the electrolyte membrane 12 are increased. Accordingly,
the fuel gas can be humidified more easily at the first inlet 14b in
the fuel-electrode passage 140 than at the second outlet 14e.
Therefore, it is possible to suppress drying of the electrolyte
membrane 12 and temperature increase in the electrolyte
membrane 12.
[0036]
Meanwhile, as described above, as the differential pressure
between the fuel gas pressure and the cooling water pressure
becomes larger, condensed water retained in the fuel-electrode
passage 140 can be absorbed more easily. Therefore, the
condensed water generated in the fuel-electrode passage 140 can
be absorbed more easily at the second outlet 14e than at the first
inlet 14b. That is, since the differential pressure becomes larger
toward the downstream side in the fuel-electrode passage 140,
carbon corrosion and deterioration of characteristics caused by a
puddle in the fuel-electrode passage 140 can be more suppressed
toward the downstream side. As described above, by making the
differential pressure between the fuel gas pressure and the cooling
water pressure larger from the upstream side to the downstream
side in the fuel-electrode passage 140, an effect that humidification
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
16
of the fuel gas more progresses at the first inlet 14b and absorption
of the condensed water more progresses at the second outlet 14e is
obtained. Accordingly, the effect that humidification of the fuel gas
more progresses at the first inlet 14b and absorption of the
condensed water more progresses at the second outlet 14e is
obtained.
[0037]
FIG. 10 is a schematic diagram illustrating a differential
pressure between an oxidant gas at the first inlet 16c in the oxidant-
electrode passage 160a and a cooling water pressure and a
differential pressure between the oxidant gas at the second outlet
16f and the cooling water pressure. The vertical axis represents a
pressure. The first inlet 16c is arranged on the upstream side of the
second outlet 16f in the cooling-water passage 160b. Accordingly,
a differential pressure between an oxidant gas pressure at the first
inlet 16c and a cooling water pressure in the cooling-water passage
160b at a position vertically below the first inlet 16c becomes smaller
than a differential pressure between the oxidant gas pressure at the
second outlet 16f and the cooling water pressure in the cooling-water
passage 160b at a position vertically below the second outlet 16f.
[0038]
Since the first porous separator 14 is formed by a conductive
porous plate having micropores as described above, the moisture
infiltrating the first porous separator 14 is increased as the
differential pressure between the oxidant gas pressure and the
cooling water pressure becomes smaller. Accordingly, the oxidant
gas can be humidified more easily at the first inlet 16c in the oxidant-
electrode passage 160 than at the second outlet 16f. Therefore, it
is possible to suppress drying of the electrolyte membrane 12 and
temperature increase in the electrolyte membrane 12.
[0039]
On the other hand, condensed water retained in the oxidant-
electrode passage 160 can be absorbed more easily as the
differential pressure between the oxidant gas pressure and the
cooling water pressure becomes larger. Therefore, the condensed
water retained in the oxidant-electrode passage 160 can be
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
17
absorbed more easily at the second outlet 16f than at the first inlet
16c. Accordingly, deterioration of characteristics caused by a
puddle in the oxidant-electrode passage 160 can be suppressed. As
described above, by making the differential pressure between the
oxidant gas pressure at the first inlet 16c and the cooling water
pressure smaller than the differential pressure between the oxidant
gas pressure at the second outlet 16f and the cooling water pressure,
an effect that humidification of the oxidant gas more progresses at
the first inlet 16c and absorption of the condensed water more
progresses at the second outlet 16f is obtained.
[0040]
(Comparative example)
FIG. 11 is a schematic diagram of a conventional fuel cell
stack illustrating a state where a manifold is attached to a side
surface along the stacking direction of fuel-cell cells of the fuel-cell
cell stack 1. As illustrated in FIG. 11, in a conventional fuel cell
stack 4, positions of the first inlet 14b and the second outlet 14e of
the fuel-electrode passage 140 are opposite to those in the fuel cell
stack 1 according to the present embodiment. Further, positions of
the first inlet 16c and the second outlet 16f of the oxidant-electrode
passage 160a in the conventional fuel cell stack 4 are opposite to
those in the fuel cell stack 1 according to the present embodiment.
[0041]
FIG. 12 is a diagram illustrating differential pressures
between fuel gas pressures in the fuel-electrode passage 140 and
cooling water pressures in a cooling-water passage at positions
corresponding to the fuel-electrode passage 140 in a conventional
fuel cell stack. The vertical axis represents a pressure. A line 74
indicates fuel gas pressures at positions along the fuel-electrode
passage 140 from the first inlet 14b to the second outlet 14e of the
fuel-electrode passage 140. The line 72 indicates cooling water
pressures in the cooling-water passage 160b at positions vertically
below the positions along the fuel-electrode passage 140.
[0042]
In the conventional fuel cell stack 4, the positions of the first
inlet 14d and the second outlet 14e of the fuel-electrode passage
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
18
140 are opposite to those in the fuel cell stack 1 according to the
present embodiment. Therefore, a differential pressure between
the fuel gas pressure at the first inlet 14b and the cooling water
pressure in the cooling-water passage 160b at a position vertically
below or above the first inlet 14b becomes larger than a differential
pressure between the fuel gas pressure at the second outlet 14e in
the fuel-electrode passage 140 and the cooling water pressure in the
cooling-water passage 160b at a position vertically below or above
the second outlet 14e. Accordingly, drying at the first inlet 14b
progresses more than at the second outlet 14e. Further, absorption
of condensed water at the second outlet 14e is suppressed more
than at the first inlet 14b.
[0043]
Similarly, positions of the first inlet 16c and the second outlet
16f of the oxidant-electrode passage 160a in the conventional fuel
cell stack 4 are opposite to those in the fuel cell stack 1 according to
the present embodiment. Therefore, a differential pressure
between an oxidant gas pressure at the first inlet 16c and the cooling
water pressure in the cooling-water passage 160b at a position
vertically below the first inlet 16c becomes larger than a differential
pressure between the oxidant gas pressure at the second outlet 16f
and the cooling water pressure in the cooling-water passage 160b at
a position vertically below the second outlet 16f. Accordingly,
drying at the first inlet 16c progresses more than at the second outlet
16f. Further, absorption of the condensed water at the second
outlet 16f is suppressed more than at the first inlet 16c. Accordingly,
the effect obtained in the conventional fuel cell stack 4 is opposite to
the effect obtained in the fuel cell stack 1 according to the present
application.
[0044]
As described above, according to the present embodiment, a
differential pressure between a fuel gas pressure at the first inlet
14b in the fuel-electrode passage 140 and a cooling water pressure
in the cooling-water passage 160b corresponding to the first inlet
14b is made smaller than a differential pressure between the fuel
gas pressure at the second outlet 14e in the fuel-electrode passage
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
19
140 and the cooling water pressure in the cooling-water passage
160b corresponding to the second outlet 14e. This configuration
provides an effect that humidification of the fuel gas progresses
more at the first inlet 14b and absorption of the condensed water
progresses more at the second outlet 14e. Since the fuel gas can
be more humidified at the first inlet 14b as described above,
deterioration of the electrolyte membrane 12 due to drying is
suppressed. Further, since the differential pressure becomes larger
toward the second outlet 14e, retention of the condensed water can
be suppressed more.
[0045]
Furthermore, the first fuel gas passage connecting the first
inlet 14b and the first outlet 14c to each other is arranged vertically
above or below an upstream region in the cooling-water passage
160b, and the second fuel gas passage connecting the second inlet
14d and the second outlet 14e to each other is arranged vertically
above or below a downstream region in the cooling-water passage
160b. Therefore, the differential pressure between the fuel gas
pressure and the cooling water pressure can be made larger from
the upstream side to the downstream side in the fuel-electrode
passage 140, thereby providing an effect that humidification of the
fuel gas progresses more at the first inlet 14b and absorption of the
condensed water progresses more at the second outlet 14e.
[0046]
(First modification of first embodiment)
The fuel cell stack 1 according to a first modification of the
first embodiment is different from the fuel cell stack 1 according to
the first embodiment in that the oxidant-electrode passage 160a is
formed in the first porous separator 14 and the fuel-electrode
passage 140 is formed in the first porous separator 16. The
following descriptions are provided to explain the differences from
the fuel cell stack 1 according to the first embodiment.
[0047]
The electrolyte membrane 12 (FIG. 2) is different from that
in the first embodiment in that an oxidant electrode is formed on a
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
vertically upper main surface and a fuel electrode is formed on the
other main surface.
FIG. 13 is a schematic diagram illustrating a shape of a main
surface of the first porous separator 14 on a side close to an oxidant
5 electrode of the electrolyte membrane 12. The oxidant-electrode
passage 160a along the oxidant electrode is formed on the main
surface 16a on the side close to the oxidant electrode of the
electrolyte membrane 12.
[0048]
10 FIG. 14 is a diagram illustrating a shape of the main surface
14a of the second porous separator 16. As illustrated in FIG. 14,
the fuel-electrode passage 140 along a fuel electrode is formed in
the main surface 14a on a side close to a fuel electrode of the
electrolyte membrane 12. Also in a case where the oxidant-
15 electrode passage 160a is formed in the first porous separator 14
and the fuel-electrode passage 140 is formed in the second porous
separator 16 as described above, an arrangement equivalent to that
in FIG. 8 can be obtained as viewed from vertically above. The first
porous separator 14 and the second porous separator 16 according
20 to the present embodiment respectively correspond to a fuel-
electrode porous passage plate and a fuel-electrode porous passage
plate.
[0049]
As described above, according to the first modification, the
first fuel gas passage connecting the first inlet 14b and the first
outlet 14c to each other is arranged vertically above or below an
upstream region in the cooling-water passage 160b, and the second
fuel gas passage connecting the second inlet 14d and the second
outlet 14e to each other is arranged vertically above or below a
downstream region in the cooling-water passage 160b. Therefore,
a differential pressure between a fuel gas pressure and a cooling
water pressure can be made larger from the upstream side to the
downstream side in the fuel-electrode passage 140, thereby
providing an effect that humidification of a fuel gas progresses more
at the first inlet 14b and absorption of condensed water progresses
more at the second outlet 14e.
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
21
[0050]
(Second modification of first embodiment)
The fuel cell stack 1 according to a second modification of the
first embodiment is different from the fuel cell stack 1 according to
the first embodiment in that the direction of a fuel gas flowing in the
fuel-electrode passage 140 is reversed, the direction of an oxidant
electrode gas flowing in the oxidant-electrode passage 160a is
reversed, and the direction of cooling water flowing in the cooling-
water passage 160b is reversed. The following descriptions are
provided to explain the differences from the fuel cell stack 1
according to the first embodiment.
[0051]
FIG. 15 is a diagram illustrating a state where a manifold is
attached to a side surface along a stacking direction of fuel-cell cells
of the fuel-cell cell stack 1 according to the second modification. As
illustrated in FIG. 15, an operation is performed in which, with
respect to the fuel-cell cell stack 1 according to the first embodiment,
the direction of a fuel gas flowing in the fuel-electrode passage 140
is reversed, the direction of an oxidant gas flowing in the oxidant-
electrode passage 160a is reversed, and the direction of cooling
water flowing in the cooling-water passage 160b is reversed.
[0052]
As described above, according to the present modification, an
operation method for the fuel-cell cell stack 1 is changed in such a
manner that, with respect to the fuel-cell cell stack 1 according to
the first embodiment, the direction of a fuel gas flowing in the fuel-
electrode passage 140 is reversed, the direction of an oxidant gas
flowing in the oxidant-electrode passage 160a is reversed, and the
direction of cooling water flowing in the cooling-water passage 160b
is reversed. Also in this operation method, it is possible to make a
differential pressure between a fuel gas pressure at the first inlet
14b in the fuel-electrode passage 140 and a cooling water pressure
in the cooling-water passage 160b corresponding to the first inlet
14b smaller than a differential pressure between the fuel gas
pressure at the second outlet 14e in the fuel-electrode passage 140
and the cooling water pressure in the cooling-water passage 160b
Date Recue/Date Received 2022-01-26
CA 03148862 2022-01-26
22
corresponding to the second outlet 14e. This configuration provides
an effect that humidification of the fuel gas progresses more at the
first inlet 14b and absorption of condensed water progresses more
at the second outlet 14e. Since the fuel gas can be humidified at
the first inlet 14b as described above, deterioration of the electrolyte
membrane 12 due to drying is suppressed. Further, since the
differential pressure becomes larger toward the second outlet 14e,
retention of the condensed water can be suppressed.
[0053]
Further, by changing an operation method of the fuel-cell cell
stack 1, it is possible to arrange the first fuel gas passage connecting
the first inlet 14b and the first outlet 14c to each other vertically
above an upstream region in the cooling-water passage 160b and
arrange the second fuel gas passage connecting the second inlet 14d
and the second outlet 14e to each other vertically above a
downstream region in the cooling-water passage 160b. Therefore,
it is possible to make the differential pressure between the fuel gas
pressure and the cooling water pressure from the upstream side to
the downstream side in the fuel-electrode passage 140, providing an
effect that humidification of the fuel gas progresses more at the first
inlet 14b and absorption of the condensed water progresses more at
the second outlet 14e.
[0054]
While certain embodiments of the present invention have
been described, these embodiments have been presented by way of
example only, and are not intended to limit the scope of the
invention. The novel embodiments described herein may be
embodied in a variety of other forms, and various omissions,
substitutions, and changes may be made without departing from the
spirit of the invention. These embodiments and modifications
thereof would fall within the scope and spirit of the invention, and
would fall within the invention described in the accompanying claims
and their equivalents.
Date Recue/Date Received 2022-01-26
