Note : Les descriptions sont présentées dans la langue officielle dans laquelle elles ont été soumises.
gL8
. .
PHN. 8906.
GL/I~JM.
4~4-1978.
Catho~e foll for electrolytic capacitors.
The lnvention rela-tes to aluminu~ cathode
foil for an electrolytic capacitor and to the capacitor
provided with such a cathode foi].
An electrolytic capacitor consists of an
aluminum anode provided by means of anodic oxidation
with a dielectric aluminium o~ide skin, an aluminium
cathode provided by means of etching with a large surface
area and an electrolyte solution. The most customary
embodiment is the aluminium wound capacitor, wherein the
anode foil and the cathode foil are rolled with an inter-
leaved, so-~called separator of an insulating material
into a wound body. The wound body is impregnated with
an electrolyte solution and encapsulated.
It is importan-t to have the desired capa-
citance at as smal] a surface area as possible, which
means that the metal surface to be oxidi~ed (forming)
must be as large as possible. To this end the surface
of the anode is subjected to an etching operation, which
is usually effected electrolytically. To obtain a large
capacitance per surface unit it is important that the
surface area of the ca-thode foil W}liC}l iS encapsulated
in the non~fornled st~te in normal capaci-tors is l:ike~:ise
increased by etching and that :in such a way that roughetl-
ing and capaci-tance respectively are compar~b]e to the
-- 2 ~
PHN. 8906.
L~_4-1978~
'~ roughening and capaci.tance of the anode foil. In this
way ;.t is achieved that the total capacitance of -the
capacitor is determined to an increased e~tent by the
anode capaci,tance alone, in accordance as the cathode
capacitance increa,ses.
An aluMinium of a very high purity, namely
Al 99. 99%, wllich can be formed very satisfactorily is
usua]ly used for the anode foil. That is to say that a
good dielectric oxide layer is obtainable thereon by
means of anodic oxidation.
~or cathode foil preference is glven to
aluminium foil which in the contrary is less easy to be
- formed. In accordance with US Patent Specifi.cation
3,899,723 an aluminium-manganese alloy having a content
of between 0.2 and 2 weight % of Mn is a sa-tisfactory
alloy for cathode foil. Th.is foil has a considerably
higher capacitanoe and impact strength than pure aluminium
foil ~
It is an object of the invention to pro-
vide alumini1lm foil for an electrolytic capacitor having
a still higher capacitance value.
The cathode foi,l according to the invention
is therefore characteri.~ed in that it consists of aluminium
having a copper content be-tweell 0.15 alld ~.7 wei.gllt -~o
and a total of contamina-tiolls of` not mo:re than 2 weight ~.
The basic material sat:isfies e~cept,for
-- 3 --
i; ~9~B
PIIN. 8go6.
4_1~_1978.
copper, for exarnple, DIN-stan.dard 1712 with the foll.ow-
ing max:imum values: (weight %)
si 6 0 ~ 8% Ti < 0105 %
' ~e ~ 1,0% Zn C 0,10 %
Mn ~ 0, 1% remain:ing elements ~ o,o60/0 each.
Relative to the foil in accordance with
the above-mentioned US Specification a cathode in the
~:~ electrolytic capaci.tor according to the i.nvention has,
after etching of the foil with a given number of Coulombs/
10 cm2 a capacitance which is 2 to 3 times hi~her. Conse-
quently the capacitor itself has', compared to the capa-
citor provided with a cathode in accordance with the
; above-mentioned US Specification a corresponding impro-
' vement of the total capacitance. This furthermore means
that the thickness of the foil and/or the quantity of
etching energy for obtalning a given "etching factor'l
can be reduced9 which results in a capacitor having a
:~ more favourable capacitance value per volume unit and
a'lower energy consumption during etching respectively.
The impact strength of the foil after etch-
: ing with a given number of Coulombs/cm is approximately
of the same value as that of the known foil.
By way of non-limita-tive example there now
follows a comparison between foi.l in accordance with the
above-mentioned US Specifi.cation (1) wit'h foil according
to the invention (2). The relevant compositi.ons are:
z~
:
PHN. 8906.
t 4~ 197S.
(W~ig~lt /0)
(1) Mn 1,0 o~h (2) Mn 0,04 ~o
Cu 0,10 % Cu 3,95
Ti 0,02 % Ti 0,003
~e o,6 % ~e o,OIt
Si 0,3 % ~i 0,07
Zn 0,1 % Zn ~ 0,01
Mg 0,2 % Mg o,o4
Cr 0,04 % Cr < 0,01
remaining contaminations:
eaeh ~ 0,05 yO ~ 0,01
together . ~ 0,15 % ~ 0~05
- Al remainder Al remainder.
Both foils 7 having a thiekness of 60 /um
were electrolytieally etched in an aqueous solutiGn of
250 g/l NaCl with an electric chQrge of 9.4 and lS.S
Coulombs/cm2.
- ~ The capacitance values were measured in a
liclui.d cons;.sting of a 5~o solution of ammonium-pentaborate
in water (resisti.v:i.ty 100 5l cm) versus a silver-platecl
, . . . .
counter electrode.
After heating for 1 hour at 240 C foil (1)
had after e-tc~-ling a stabili7;ecl capac:itance of approximately
100 /UF/cm (at 9,4 Coulomb.s/cm ) and 180 /uI~`/elll (~t lS.~.
Cou:Lombs/cl~ lowever, foil (2) hacl, af-l;er etclling witl
: an elec-tric charge of 9.4 Cou:l.ombs/cm , a capaci.t;clllce o:~
~ ,, 3L~9~
:
PHN. 8906.
~ 4_1978.
240 /UF/cm
The impact strength was 350 n)J~15 mm foil
width (9.4 Coulombs/em ) and 250 mJ/15 mm of foil width ~
(18.8 ~oulombs/cm ) for foil (1) and 450 mJ/15 mm foil
width after etching with an electric charge of 9.4
Coulombs/cm for foil (2).
EYarn~le 2.
; The capacitance of wound bod:ies as a
funetion of .the operating voltage Or eleetrolytie eapaei-
10- tors is stated having foil (1) and (2) respectively as
cat]lode ~
__ . . ~........... ... .~
Operating CapacitanGe wound bodygain in volume
.. voltagewith cathode - ~ per eap.unit
",,~,~, .. . .. _. __ _
~ (~olts?(1)of 1~0 /uF/em(2)of 240/uF/eIII of wound bod~, .
. _ -- !
15 - 6~3 36~3 luF/em 46,1 /uF/Cm 27
28,6 /uF/cm 34,3 /uFjcm 20
: 25 14,5 /uE'/Cm 15,9 /uF/em
9,75/u~/cm 10,33/UF/Cm 6
63 5~66/uF/em 5~85/uFjem
:By. redue:ing the thickness of the foil from
60 /um to 30 /um at the same capaeitanee a gai.n in volume
of 12~ is obtained.
The following tab~e ls a surve~r of a 10
volt capac:itor whel~ein th.e wound section is impl~egrlat:e~l
with a eonventj.ona:L glycol-ammo1lia-boric acid-elèetloL~rt:e
:~ .
:` -
PHN. 8906.
4-4-1978.
solution.
_ ~
Cath- 60/unl foil 1oo/uF/cn' . 240/UF/cm
30/um foil loo /UF/cm 2Llo/uF/cm
Anode ~OOjulll foil40/1lF/Clll 40 /uF/cm 40/UF/Cm 40/uF/cM
Paper .
; 2 x 60 /um body . . .
thickness ~ound body 280 /um 250 /um 280 /um 250 /um
cap/cm wound body 28~6/uF/crn 28, 6/UF/cm 3LI~ 3/u~/cm 34, 3/uF/cm
,. , .
: Because the cathode capacitarlce of 240/uF/cm
is attained on etching with an electric charge of onl-y
9.4 Coulombs/cm the decrease in strength of the foil
is so small that foil hav:ing this capacitance can be
. . made with a thickness of 30 /um.
- ' ,
.
